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At least 991 records · Page 55Linked to original sources

Geology and MER target site characteristics along the southern rim of Isidis Planitia, Mars

The southern rim of the Isidis basin contains one of the highest densities of valley networks, several restricted paleolake basins, and the stratigraphically lowest (oldest) terrain on Mars. Geologic mapping in Viking, MGS/MOC, and MOLA data, Odyssey/THEMIS data, and other multispectral data products supports the presence of extensive fans of debris and sediments deposited along the inner rim of the Isidis basin where large valleys enter the lowlands. Additional processes subsequent to the period of intense fluvial activity, including mass flow analogous to some glacial processes, have contributed to the materials accumulated on the margins of the Isidis basin. These have occurred along preexisting channels and valleys at the termini of major channels where they enter the plains along the highland-lowland boundary. If the abundant valley networks in highland terrains are the result of runoff accompanied by saturated groundwater flow, as has been suggested in previous studies of ancient fluvial highland terrains, then the extreme age and abundance of early valley networks in the Libya Montes highland rocks should have resulted in deposition of materials that record evidence for the long-term presence of water in the form of aqueous alteration of polycrystalline constituents. The material deposited along the basin margin is likely to consist of ancient altered highland rocks in several physical states (weathered, rounded, and angular) exposing both weathered and altered surfaces, and exposures of alteration profiles in fractured faces and unweathered material from rock interiors. Debris fans shed off the southern rim of Isidis Planitia should contain materials that have experienced possible saturated groundwater flow, residence within paleolake basins, and derivative materials deposited during the most fluvially intensive part of Martian geologic history. Many of these materials have also been reworked by ice-related processes. In situ measurements of the ancient crustal materials, in the form of rocks within the debris fans, and the weathered condition of the rocky material are potential sources for mineralogical evidence of climatic conditions in earliest Martian geologic history. The absence of alteration within rocks would, on the other hand, support the hypothesis that fluvial runoff during the earliest history of Mars was geologically brief rather than long-term and that long-term saturated groundwater flow was not present. Determination of the presence or absence of alteration would have corresponding implications for hypotheses requiring the long-term presence of aqueous solutions (i.e., complex organic compounds and life). A proposed MER site along the margin addresses realistic field science objectives of the Mars Exploration Rover mission and the current goals of the Mars Exploration Program. In situ measurements may be important in deriving estimates of the longevity and intensity of past wetter climates.

Journal of Geophysical Research E: Planets↗

Posteruption suspended sediment transport at Mount St. Helens: Decadal‐scale relationships with landscape adjustments and river discharges

Widespread landscape disturbance by the cataclysmic 1980 eruption of Mount St. Helens abruptly increased sediment supply in surrounding watersheds. The magnitude and duration of the redistribution of sediment deposited by the eruption as well as decades‐ to centuries‐old sediment remobilized from storage have varied chiefly with the style of disturbance. Posteruption suspended sediment transport has been greater and more persistent from zones of channel disturbance than from zones of hillslope disturbance. Despite the severe landscape disturbances caused by the eruption, relationships between discharge magnitudes and frequencies and suspended sediment transport have been remarkably consistent. Discharges smaller than mean annual flows generally have transported <5%, but locally ∼15%, of the annual suspended sediment loads, and infrequent ( p < 0.01), large floods have transported as much as 50% of the annual suspended sediment loads in a single day. However, moderate‐magnitude discharges (those greater than mean annual flows but less than 2‐year floods) have transported the greatest amounts of sediment from all disturbance zones. Such discharges have transported, on average, 60% to ∼95% of the annual suspended sediment loads, usually within cumulative periods of 1–3 weeks each year. Although small‐magnitude and large‐magnitude discharges have locally and episodically transported considerable amounts of suspended sediment, there has not been any notable change in the overall nature of the effective discharges; moderate‐magnitude flows have been the predominant discharges responsible for transporting the majority of suspended sediment during 20 years of posteruption landscape adjustment.

Washington↗

Stress field variations in the Swiss Alps and the northern Alpine foreland derived from inversion of fault plane solutions

This study is devoted to a systematic analysis of the state of stress of the central European Alps and northern Alpine foreland in Switzerland based on focal mechanisms of 138 earthquakes with magnitudes between 1 and 5. The most robust feature of the results is that the azimuth of the minimum compressive stress, S 3 , is generally well constrained for all data subsets and always lies in the NE quadrant. However, within this quadrant, the orientation of S 3 changes systematically both along the structural strike of the Alpine chain and across it. The variation in stress along the mountain belt from NE to SW involves a progressive, counterclockwise rotation of S 3 and is most clear in the foreland, where it amounts to 45°–50°. This pattern of rotation is compatible with the disturbance to the stress field expected from the indentation of the Adriatic Block into the central European Plate, possibly together with buoyancy forces arising from the strongly arcuate structure of the Moho to the immediate west of our study area. Across the Alps, the variation in azimuth of S 3 is defined by a progressive, counterclockwise rotation of about 45° from the foreland in the north across the Helvetic domain to the Penninic nappes in the south and is accompanied by a change from a slight predominance of strike-slip mechanisms in the foreland to a strong predominance of normal faulting in the high parts of the Alps. The observed rotation can be explained by the perturbation of the large-scale regional stress by a local uniaxial deviatoric tension with a magnitude similar to that of the regional differential stress and with an orientation perpendicular to the strike of the Alpine belt. The tensile nature and orientation of this stress is consistent with the “spreading” stress expected from lateral density changes due to a crustal root beneath the Alps.

European Alps↗

Transient volcano deformation sources imaged with interferometric synthetic aperture radar: Application to Seguam Island, Alaska

Thirty interferometric synthetic aperture radar (InSAR) images, spanning various intervals during 1992&ndash;2000, document coeruptive and posteruptive deformation of the 1992&ndash;1993 eruption on Seguam Island, Alaska. A procedure that combines standard damped least squares inverse methods and collective surfaces, identifies three dominant amorphous clusters of deformation point sources. Predictions generated from these three point source clusters account for both the spatial and temporal complexity of the deformation patterns of the InSAR data. Regularized time series of source strength attribute a distinctive transient behavior to each of the three source clusters. A model that combines magma influx, thermoelastic relaxation, poroelastic effects, and petrologic data accounts for the transient, interrelated behavior of the source clusters and the observed deformation. Basaltic magma pulses, which flow into a storage chamber residing in the lower crust, drive this deformational system. A portion of a magma pulse is injected into the upper crust and remains in storage during both coeruption and posteruption intervals. This injected magma degasses and the volatile products accumulate in a shallow poroelastic storage chamber. During the eruption, another portion of the magma pulse is transported directly to the surface via a conduit roughly centered beneath Pyre Peak on the west side of the island. A small amount of this magma remains in storage during the eruption, and posteruption thermoelastic contraction ensues. This model, made possible by the excellent spatial and temporal coverage of the InSAR data, reveals a relatively simple system of interrelated predictable processes driven by magma dynamics.

Journal of Geophysical Research B: Solid Earth↗

Crystallographic controls on the frictional behavior of dry and water-saturated sheet structure minerals

We compare the frictional strengths of 17 sheet structure mineral powders, measured under dry and water-saturated conditions, to identify the factors that cause many of them to be relatively weak. The dry coefficient of friction μ ranges upward from 0.2 for graphite, leveling off at 0.8 for margarite, clintonite, gibbsite, kaolinite, and lizardite. The values of μ (dry) correlate directly with calculated (001) interlayer bond strengths of the minerals. This correlation occurs because shear becomes localized along boundary and Riedel shears and the platy minerals in them rotate into alignment with the shear planes. For those gouges with μ (dry) < 0.8, shear occurs by breaking the interlayer bonds to form new cleavage surfaces. Where μ (dry) = 0.8, consistent with Byerlee's law, the interlayer bonds are sufficiently strong that other frictional processes dominate. The transition in dry friction mechanisms corresponds to calculated surface energies of 2–3 J/m 2 . Adding water causes μ to decrease for every mineral tested except graphite. If the minerals are separated into groups with similar crystal structures, μ (wet) increases with increasing interlayer bond strength within each group. This relationship also holds for the swelling clay montmorillonite, whose water-saturated strength is consistent with the strengths of nonswelling clays of similar crystal structure. Water in the saturated gouges forms thin, structured films between the plate surfaces. The polar water molecules are bonded to the plate surfaces in proportion to the mineral's surface energy, and μ (wet) reflects the stresses required to shear through the water films.

Journal of Geophysical Research B: Solid Earth↗

Stress triggering in thrust and subduction earthquakes and stress interaction between the southern San Andreas and nearby thrust and strike-slip faults

We argue that key features of thrust earthquake triggering, inhibition, and clustering can be explained by Coulomb stress changes, which we illustrate by a suite of representative models and by detailed examples. Whereas slip on surface-cutting thrust faults drops the stress in most of the adjacent crust, slip on blind thrust faults increases the stress on some nearby zones, particularly above the source fault. Blind thrusts can thus trigger slip on secondary faults at shallow depth and typically produce broadly distributed aftershocks. Short thrust ruptures are particularly efficient at triggering earthquakes of similar size on adjacent thrust faults. We calculate that during a progressive thrust sequence in central California the 1983 M w = 6.7 Coalinga earthquake brought the subsequent 1983 M w = 6.0 Nuñez and 1985 M w = 6.0 Kettleman Hills ruptures 10 bars and 1 bar closer to Coulomb failure. The idealized stress change calculations also reconcile the distribution of seismicity accompanying large subduction events, in agreement with findings of prior investigations. Subduction zone ruptures are calculated to promote normal faulting events in the outer rise and to promote thrust-faulting events on the periphery of the seismic rupture and its downdip extension. These features are evident in aftershocks of the 1957 M w = 9.1 Aleutian and other large subduction earthquakes. We further examine stress changes on the rupture surface imparted by the 1960 M w = 9.5 and 1995 M w = 8.1 Chile earthquakes, for which detailed slip models are available. Calculated Coulomb stress increases of 2–20 bars correspond closely to sites of aftershocks and postseismic slip, whereas aftershocks are absent where the stress drops by more than 10 bars. We also argue that slip on major strike-slip systems modulates the stress acting on nearby thrust and strike-slip faults. We calculate that the 1857 M w = 7.9 Fort Tejon earthquake on the San Andreas fault and subsequent interseismic slip brought the Coalinga fault ∼1 bar closer to failure but inhibited failure elsewhere on the Coast Ranges thrust faults. The 1857 earthquake also promoted failure on the White Wolf reverse fault by 8 bars, which ruptured in the 1952 M w = 7.3 Kern County shock but inhibited slip on the left-lateral Garlock fault, which has not ruptured since 1857. We thus contend that stress transfer exerts a control on the seismicity of thrust faults across a broad spectrum of spatial and temporal scales.

California↗

Strain accumulation across the Coast Ranges at the latitude of San Francisco, 1994-2000

A 66-monument geodetic array spanning the Coast Ranges near San Francisco has been surveyed more than eight times by GIPS between late 1993 and early 2001. The measured horizontal velocities of the monuments are well represented by uniform, right-lateral, simple shear parallel to N29°W. (The local strike of the San Andreas Fault is ∼N34°W.) The observed areal dilatation rate of 6.9 ± 10.0 nstrain yr −1 (quoted uncertainty is one standard deviation and extension is reckoned positive) is not significantly different from zero, which implies that the observed strain accumulation could be released by strike-slip faulting alone. Our results are consistent with the slip rates assigned by the Working Group on California Earthquake Probabilities [2003] to the principal faults (San Gregorio, San Andreas, Hayward-Rodgers Creek, Calaveras-Concord-Green Valley, and Greenville Faults) cutting across the GPS array. The vector sum of those slip rates is is 39.8 ± 2.6 mm yr −1 N29.8°W ± 2.8°, whereas the motion across the GPS array (breadth 120 km) inferred from the uniform strain rate approximation is 38.7 ± 1.2 mm yr −1 N29.0°W ± 0.9° right-lateral shear and 0.4 ± 0.9 mm yr −1 N61°E ± 0.9° extension. We interpret the near coincidence of these rates and the absence of significant accumulation of areal dilatation to imply that right-lateral slip on the principal faults can release the accumulating strain; major strain release on reverse faults subparallel to the San Andreas Fault within the Coast Ranges is not required.

California↗

Recalculated probability of M ≥ 7 earthquakes beneath the Sea of Marmara, Turkey

New earthquake probability calculations are made for the Sea of Marmara region and the city of Istanbul, providing a revised forecast and an evaluation of time-dependent interaction techniques. Calculations incorporate newly obtained bathymetric images of the North Anatolian fault beneath the Sea of Marmara [Le Pichon et al., 2001; Armijo et al., 2002]. Newly interpreted fault segmentation enables an improved regional A.D. 1500-2000 earthquake catalog and interevent model, which form the basis for time-dependent probability estimates. Calculations presented here also employ detailed models of coseismic and postseismic slip associated with the 17 August 1999 M = 7.4 Izmit earthquake to investigate effects of stress transfer on seismic hazard. Probability changes caused by the 1999 shock depend on Marmara Sea fault-stressing rates, which are calculated with a new finite element model. The combined 2004-2034 regional Poisson probability of M≥7 earthquakes is ~38%, the regional time-dependent probability is 44 ± 18%, and incorporation of stress transfer raises it to 53 ± 18%. The most important effect of adding time dependence and stress transfer to the calculations is an increase in the 30 year probability of a M ??? 7 earthquake affecting Istanbul. The 30 year Poisson probability at Istanbul is 21%, and the addition of time dependence and stress transfer raises it to 41 ± 14%. The ranges given on probability values are sensitivities of the calculations to input parameters determined by Monte Carlo analysis; 1000 calculations are made using parameters drawn at random from distributions. Sensitivities are large relative to mean probability values and enhancements caused by stress transfer, reflecting a poor understanding of large-earthquake aperiodicity.

Sea Of Marmara↗

Interseismic strain and rotation rates in the northeast Mojave domain, eastern California

The northeast Mojave domain, a type locality for bookshelf faulting, is a region of east striking, left-lateral faults in the northeast corner of the Mojave block, a block otherwise dominated by ∼N40°W striking, right-lateral faults. Paleomagnetic evidence suggests that blocks within the domain have rotated clockwise about a vertical axis as much as 60° since 12.8 Ma [Schermer et al., 1996] . In 1994, and again in 2002, the U.S. Geological Survey surveyed an array of 14 geodetic monuments distributed across the northeast Mojave domain. The 2002 survey results were adjusted to remove the coseismic offsets imposed by the nearby Hector Mine earthquake (16 October 1999, M w = 7.1). The adjusted deformation across the array appears to be uniform and can be approximated by the principal strain rates ε 1 = 28.9 ± 9.1 N77.2°W ± 4.8° and ε 2 = −48.2 ± 8.9 N12.8°E ± 4.8° nstrain yr −1 ; extension reckoned positive, and quoted uncertainties are standard deviations. That strain accumulation could be released by slip on faults striking N32°W but not by bookshelf faulting on the east striking faults alone. The vertical axis rotation rate of the northeast Mojave domain as a whole relative to fixed North America is 71.0 ± 6.4 nrad yr −1 (4.07° ± 0.37° Myr −1 ) clockwise, about twice the maximum tensor shear strain rate. The observed rotation rate acting over 12.8 Myr would produce a clockwise rotation of 52.1° ± 4.7°, exclusive of possible coseismic rotations. That rotation is in rough agreement with the paleomagnetic rotation accumulated in the individual fault blocks within the northeast Mojave domain since 12.8 Ma.

California↗

Contemporary tectonic deformation of the Basin and Range province, western United States: 10 years of observation with the Global Positioning System

[1] We have estimated patterns and rates of crustal movement across 800 km of the Basin and Range at ∼39° north latitude with Global Positioning System surveys in 1992, 1996, 1998, and 2002. The total rate of motion tangent to the small circle around the Pacific‐North America pole of rotation is 10.4 ± 1.0 mm/yr, and motion normal to this small circle is 3.9 ± 0.9 mm/yr compared to the east end of our network. On the Colorado Plateau the east end of our network moves by ∼1–2 mm/yr westerly with respect to North America. Transitions in strain rates delimit six major tectonic domains within the province. These deformation zones coincide with areas of modern seismicity and are, from east to west, (1) east‐west extension in the Wasatch Fault zone, (2) low rate east‐west extension centered near the Nevada‐Utah border, (3) low rate east‐west contraction between 114.7°W and 117.9°W, (4) extension normal to and strike‐slip motion across the N10°E striking Central Nevada Seismic Zone, (5) right lateral simple shear oriented N13°W inside the Walker Lane Belt, and (6) shear plus extension near the Sierra Nevada frontal faults. Concentration of shear and dilatational deformation across the three westernmost zones suggests that the Walker Lane Belt lithosphere is rheologically weak. However, we show that linear gradients in viscosity and gravitational potential energy can also effectively concentrate deformation. In the Basin and Range, gradients in gravitational potential are spatially anticorrelated with dilatational strain rates, consistent with the presence of horizontal variations in viscosity of the lithosphere.

Arizona, California, Nevada, Utah↗

Noise in two-color electronic distance meter measurements revisited

Frequent, high-precision geodetic data have temporally correlated errors. Temporal correlations directly affect both the estimate of rate and its standard error; the rate of deformation is a key product from geodetic measurements made in tectonically active areas. Various models of temporally correlated errors are developed and these provide relations between the power spectral density and the data covariance matrix. These relations are applied to two-color electronic distance meter (EDM) measurements made frequently in California over the past 15-20 years. Previous analysis indicated that these data have significant random walk error. Analysis using the noise models developed here indicates that the random walk model is valid for about 30% of the data. A second 30% of the data can be better modeled with power law noise with a spectral index between 1 and 2, while another 30% of the data can be modeled with a combination of band-pass-filtered plus random walk noise. The remaining 10% of the data can be best modeled as a combination of band-pass-filtered plus power law noise. This band-pass-filtered noise is a product of an annual cycle that leaks into adjacent frequency bands. For time spans of more than 1 year these more complex noise models indicate that the precision in rate estimates is better than that inferred by just the simpler, random walk model of noise.

Journal of Geophysical Research B: Solid Earth↗

New constraints on the active tectonic deformation of the Aegean

Site velocities from six separate Global Positioning System (GPS) networks comprising 374 stations have been referred to a single common Eurasia-fixed reference frame to map the velocity distribution over the entire Aegean. We use the GPS velocity field to identify deforming regions, rigid elements, and potential microplate boundaries, and build upon previous work by others to initially specify rigid elements in central Greece, the South Aegean, Anatolia, and the Sea of Marmara. We apply an iterative approach, tentatively defining microplate boundaries, determining best fit rigid rotations, examining misfit patterns, and revising the boundaries to achieve a better match between model and data. Short-term seismic cycle effects are minor contaminants of the data that we remove when necessary to isolate the long-term kinematics. We find that present day Aegean deformation is due to the relative motions of four microplates and straining in several isolated zones internal to them. The RMS misfit of model to data is about 2-sigma, very good when compared to the typical match between coseismic fault models and GPS data. The simplicity of the microplate description of the deformation and its good fit to the GPS data are surprising and were not anticipated by previous work, which had suggested either many rigid elements or broad deforming zones that comprise much of the Aegean region. The isolated deforming zones are also unexpected and cannot be explained by the kinematics of the microplate motions. Strain rates within internally deforming zones are extensional and range from 30 to 50 nanostrain/year (nstrain/year, 10-9/year), 1 to 2 orders of magnitude lower than rates observed across the major microplate boundaries. Lower strain rates may exist elsewhere withi the microplates but are only resolved in Anatolia, where extension of 13 ?? 4 nstrain/ year is required by the data. Our results suggest that despite the detailed complexity of active continental deformation revealed by seismicity, active faulting, fault geomorphology, and earthquake fault plane solutions, continental tectonics, at least in the Aegean, is to first order very similar to global plate tectonics and obeys the same simple kinematic rules. Although the widespread distribution of Aegean seismicity and active faulting might suggest a rather spatially homogeneous seismic hazard, the focusing of deformation near microplate boundaries implies the highest hazard is comparably localized.

Journal of Geophysical Research B: Solid Earth↗

Precise relocation of earthquakes following the 15 June 1991 eruption of Mount Pinatubo (Philippines)

The 15 June 1991 climactic eruption of Mount Pinatubo (Philippines) was followed by intense seismicity that remained at a high level for several months. We located 10,839 events recorded between 1 July and mid-December 1991. In contrast to the preeruptive seismicity which was focused in two groups below the summit area, posteruptive events were widely distributed below and around the volcano. The classification of the events indicates the presence of several large multiplets, and the application of relative relocation techniques to the similar events by calculating high-precision delays between traces outlines a number of clear seismogenic structures. We used different methods to confirm the validity of our results; these tests indicate that reliable features can be detected with a small monitoring network. While the main cluster of activity can be attributed to an intrusive process starting from below the 15 June crater, the volcanic origin of the seismic activity in the other areas is more difficult to establish. Away from the summit, relocations define streaks or planes which are oriented predominantly southwest-northeast, with in several cases the presence of northwest-southeast conjugate structures. Most of the composite focal mechanisms that we could determine indicate predominantly strike-slip, right-lateral faulting. Our results indicate that most of the seismicity that occurred after the 15 June eruption is related to the east-west regional compressional stress field related to the subduction. We suggest that the regional stress field induces seismicity along new or preexisting faults in the medium surrounding the volcano where the stress field was locally disturbed by the volcanic eruption.

Mount Pinatubo↗

Suspended sediment and hydrodynamics above mildly sloped long wave ripples

We investigate the spatial and temporal distribution of suspended sediment and the associated hydrodynamics over mildly sloped long wave ripples on the inner shelf. These bedforms had wavelengths of approximately 1 m and heights of approximately 5 cm, in a mean water depth of 4 m. The vertical and temporal structures of the suspended sediment concentration (SSC) are consistent with the entrainment of sediment on the offshore flank of the ripple, and rapid vertical mixing at the time of flow reversal, followed by advection onshore by the onshore fluid motion. This work confirms that the mechanism for sediment suspension above low-amplitude, long wave ripples is similar to the vortex formation process expected over steeper vortex ripples. Numerical simulations of the flow using the Dune2d model indicate that a separated rotational flow structure is generated at the flank of the ripple on the seaward side of the ripple crest, near the time of flow reversal. The simulations indicate that only one vortex is formed during each wave period, in agreement with the field observations. This asymmetry is due mainly to the presence of an offshore mean near-bed current of approximately 6 to 8 cm/s. The SSC is calculated by the model and compared to the field observations. A hydraulic bed roughness of 10 to 15 median grain diameters ( d 50 ) was used in order to match the model prediction to the observed SSC approximately 1 cm above the seabed (cab). However, the modeled SSC and turbulent kinetic energy were significantly lower than the field observations at elevations exceeding approximately 2 cab.

North Carolina↗

Effects of the fungicides mancozeb and chlorothalonil on fluxes of CO2, N2O, and CH4 in a fertilized Colorado grassland soil

[1] Management of agricultural soil plays an important role in present and future atmospheric concentrations of the greenhouse gases carbon dioxide (CO 2 ), nitrous oxide (N 2 O), and methane (CH 4 ). Pesticides are used as management tools in crop production, but little is known about their effects on soil‐atmosphere exchange of CO 2 , N 2 O, and CH 4 . Field studies described in this paper determined the effect of two commonly used fungicides, mancozeb and chlorothalonil, on trace gas exchange. Separate experimental plots, 1 m 2 , were established in nitrogen fertilized no‐tilled native grassland and tilled soils with and without fungicide application. Two studies were conducted. The first study was initiated in June 1999 and lasted for 1 year with monthly flux measurements from tilled and no‐till soils. The second study commenced in August 2001 with twelve weekly measurements from tilled soils only. From both studies mancozeb suppressed emissions of CO 2 and N 2 O in the tilled soil by an average of 28% and 47%, respectively. This suppression corresponded with efficacy periods of 14–29 and 56–77 days, respectively. From the no‐till soils mancozeb decreased CO 2 and N 2 O emissions by 33% and 80% for periods of 29 and 94 days, respectively. Mancozeb inhibited CH 4 consumption in the first study by 46% and 71% in the tilled and no‐till soil for periods of 8 and 29 days, respectively, but had no effect in the second study. From both studies chlorothalonil initially suppressed CO 2 and N 2 O emissions and enhanced CH 4 uptake in the tilled soil by an average of 37%, 40%, and 115%, respectively. These effects corresponded with efficacy periods of 14–29, 21–56, and 1–14 days, respectively. In the no‐till soil chlorothalonil inhibited CO 2 and N 2 O emissions and enhanced CH 4 uptake by 29%, 48%, and 86% for periods of 29, 56, and 56 days, respectively. Following the initial period of suppression, chlorothalonil subsequently enhanced N 2 O emissions in the tilled soil by an average of 51% and in the no‐till soil by 81% before returning to near background levels. The beginning of increased N 2 O emissions from the chlorothalonil‐amended plots corresponded with a maximum soil concentration of the chlorothalonil degradate, 4‐hydroxy‐2, 5, 6‐trichloroisophthalonitrile. The site specific global warming potential (GWP) resulting from the fluxes of CO 2 , N 2 O, and CH 4 from all soils was determined to decrease by an average 26% and 21% as a result of a single application of mancozeb or chlorothalonil, respectively. The decrease in CO 2 emissions in the fungicide‐amended plots potentially could result in the conservation of as much as 1200 and 2400 kg C ha −1 yr −1 organic carbon in the tilled and no‐till plots, respectively. Therefore it is feasible that application of certain fungicides to agricultural soil might lead to enhanced soil carbon sequestration and thus have additional positive effects on atmospheric CO 2 concentrations.

Journal of Geophysical Research D: Atmospheres↗

Effects of the herbicides prosulfuron and metolachlor on fluxes of CO2,N2O, and CH4 in a fertilized Colorado grassland soil

The effect that pesticides have on trace gas production and consumption in agricultural soils is often overlooked. Independent field and laboratory experiments were used to measure the effects that the commonly used herbicides prosulfuron and metolachlor have on trace gas fluxes (CO 2 , N 2 O, and CH 4 ) from fertilized soil of the Colorado shortgrass steppe. Separate sample plots (1 m 2 ) on tilled and no-till soil at the sites included the following treatments: 1) a control without fertilizer or herbicide, 2) a fertilized (NH 4 NO 3 equivalent to 244 kg ha −1 ) control without herbicide, 3) and fertilized plots amended with an herbicide (prosulfuron equivalent to 0.46 kg ha −1 57% by weight active ingredient or metolachlor equivalent to 5.7 L ha −1 , 82.4% by weight active ingredient). During an initial study of one year duration, measurement of gas exchange revealed that prosulfuron-amendment stimulated N 2 O emissions and CH 4 consumption by as much as 1600% and 1300% during a single measurement, respectively. During a second set of flux measurements beginning in August 2001, more frequent weekly measurements were made during a twelve week period. From this second study an increased N 2 O efflux and CH 4 uptake occurred after a 7-week lag period that persisted for about 5 weeks. These changes in gas flux amounted to an overall increase of 41% and 30% for N 2 O emission and CH 4 consumption, respectively. The co-occurrence of stimulated N 2 O and CH 4 fluxes suggests a similar cause that is related to prosulfuron degradation. Evidence suggested that prosulfuron degradation stimulated microbial activity responsible for trace gas flux. Ultimately, prosulfuron-amendment led to an ∼50% reduction in the global warming potential from N 2 O and CH 4 fluxes at this field site, which is equivalent to a reduction of the global warming potential of 0.18 mols CO 2 m −2 d −1 from these gases. Metolachlor application did not significantly affect the trace gas fluxes measured. These results demonstrate the potential impact that pesticides have on trace gas fluxes from agricultural soils, which could mean that the effects of other agricultural practices have been over or under estimated.

Colorado↗

Geology of the MER 2003 "Elysium" candidate landing site in southeastern Utopia Planitia, Mars

The NASA Mars Exploration Rover (MER) Project has been considering a landing-site ellipse designated EP78B2 in southeastern Utopia Planitia, southwest of Elysium Mons. The site appears to be relatively safe for a MER landing site because of its predicted low wind velocities in mesoscale atmospheric circulation models and its low surface roughness at various scales as indicated by topographic and imaging data sets. Previously, the site's surface rocks have been interpreted to be marine sediments or lava flows. In addition, we suggest that Late Noachian to Early Hesperian collapse and mass wasting of Noachian highland rocks contributed to the deposition of detritus in the area of the ellipse. Furthermore, we document partial Late Hesperian to Early Amazonian resurfacing of the ellipse by flows and vents that may be of mud or silicate volcanic origin. A rover investigation of the Utopia landing site using the MER Athena instrument package might address some fundamental aspects of Martian geologic evolution, such as climate change, hydrologic evolution, and magmatic and tectonic history.

Journal of Geophysical Research E: Planets↗