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Formation of miarolitic-class, segregation-type pegmatites in the Taishanmiao batholith, China: The role of pressure fluctuations and volatile exsolution during pegmatite formation in a closed, isochoric system

The Taishanmiao granitic batholith, located in the Eastern Qinling Orogen in Henan Province, China, contains numerous small (mostly tens of centimeters in maximum dimension) bodies exhibiting textures and mineralogy characteristics of simple quartz and alkali feldspar pegmatites. Analysis of melt inclusions (MI) and fluid inclusions (FI) in pegmatitic quartz, combined with Rhyolite-MELTS modeling of the crystallization of the granite, have been applied to develop a conceptual model of the physical and geochemical processes associated with the formation of the pegmatites. These results allow us to consider the formation of the Taishanmiao pegmatites within the context of varios models that have been proposed for pegmatite formation. Field observations and geochemical data indicate that the pegmatites represent the latest stage in the crystallization of the Taishanmiao granite and occupy ≤4 vol% of the syenogranite phase of the batholith. Results of Rhyolite-MELTS modeling suggest that the pegmatite-forming melts can be produced through continuous fractional crystallization of the Taishanmiao granitic magma, consistent with the designation of the pegmatites as a miarolitic class, segregation-type pegmatites rather than the more common intrusive-type of pegmatite. The mineral assemblage predicted by Rhyolite-MELTS after ~96% of the original granite-forming melt had crystallized consists of ~51 vol% alkali feldspar, 34 vol% quartz, 14 vol% plagioclase, 0.1 vol% biotite, and 1 vol% magnetite, similar to the alkali feldspar + quartz dominated mineralogy of the pegmatites. Moreover, the modeled residual melt composition following crystallization of ~96% of the original melt is similar to the composition of homogenized MI in quartz within the pegmatite. Rhyolite-MELTS predicts that the granite-forming melt remained volatile-undersaturated during crystallization of the batholith and contained ~6.3 wt% H 2 O and ~500 ppm CO 2 after ~96% crystallization when the pegmatites began to develop. The Rhyolite-MELTS prediction that the melt was volatile-undersaturated at the time the pegmatites began to form, but became volatile-saturated during the early stages of pegmatite formation, is consistent with the presence of some inclusion assemblages consisting of only MI, while others contain co-existing MI and FI. The relationship between halogen (F and Cl) and Na abundances in MI is also consistent with the interpretation that the very earliest stages of pegmatite formation occurred in the presence of a volatile-undersaturated melt and that the melt became volatile saturated as crystallization progressed. We propose a closed system, isochoric model for the formation of the pegmatites. Accordingly, the Taishanmiao granite crystallized isobarically at ~3.3 kbar, and the pegmatites began to form at ~734 °C and ~ 3.3 kbar, after ~96% of the original granitic melt had crystallized. During the final stages of crystallization of the granite, small pockets of the remaining residual melt became isolated within the enclosing granite and evolved as constant mass (closed), constant volume (isochoric) systems, similar to the manner in which volatile-rich melt inclusions in igneous phenocrysts evolve during post-entrapment crystallization under isochoric conditions. As a result of the negative volume change associated with crystallization, pressure in the pegmatite initially decreases as crystals form, and this leads to volatile exsolution from the melt phase. The changing PTX conditions produce a pressure-induced “liquidus deficit” that is analogous to liquidus undercooling and results in crystal growth as required to return the system to equilibrium PTX conditions. Owing to the complex closed system, isochoric PVTX evolution of the melt-crystal-volatile system, the pressure does not decrease rapidly or monotonically during pegmatite formation but, rather, gradually fluctuates such that at some stages in the evolution of the pegmatite the pressure is decreasing while at other times the pressure increases as the system cools to maintain mass and volume balance. This behavior, in turn, leads to alternating episodes of precipitation and dissolution that serve to coarsen (ripen) the crystals to produce the pegmatitic texture. The evolution of the pegmatitic melt described here is analogous to that which has been well-documented to occur in volatile-rich MI that undergo closed system, isochoric, post-entrapment crystallization.

American Mineralogist↗

Approaches to modeling weathered regolith

Sustainable soils are a requirement for maintaining human civilizations ( Carter and Dale 1974 ; Lal 1989 ). However, as the “most complicated biomaterial on the planet” ( Young and Crawford 2004 ), soils represent one of the most difficult systems to understand and model with respect to chemical, physical, and biological coupling over time (Fig. 1 ). Despite the complexity of these interactions, certain patterns in soil properties and development are universally observed and have been used in soil science as a means for classification. Elemental, mineralogical, or isotopic concentrations in soils plotted versus depth beneath the land surface comprise such patterns. Soil depth profiles are often reported for solid soil materials, and, less frequently, for solutes in soil pore waters. These profiles cross a large range in spatial scales that traditionally have been studied by different disciplines. For example, shallow, biologically active horizons are commonly defined as the soil zone in agronomic studies whereas the mobile layer of the regolith is referred to as soil in geomorphological studies. In contrast, many geochemical studies target chemical weathering to tens or even hundreds of meters in depth, sometimes extending the definition of “soils” to include the entire regolith down to parent bedrock or alluvium. Soil profiles also exhibit a large range in temporal scales ( Amundson 2004 ; Brantley 2008b ). Solid-state profiles document chemical and mineralogical changes integrated over the time scales of evolution of regolith from protolith. This “geologic time” can vary from tens to hundreds of years for weathered material developed on moraines deposited by active glaciers ( Anderson et al. 1997 ), to millions or possibly hundreds of millions of years of regolith evolution as documented in laterites and bauxites on stable cratons ( Nahon 1986 ). In contrast, solute profiles reflect much shorter time scales corresponding to the residence time of the soil water which commonly ranges from days to decades ( Stonestrom et al. 1998 ). Factors impacting soil minerals can therefore be related to geologically old processes while those impacting pore waters are related to contemporary processes. We first discuss a geochemical frame work for modeling soil profiles, including a simple scheme that depends on the extent of enrichment or depletion. Such profiles are comprised of reaction fronts affected by chemical, hydrologic, geologic and biologic processes that control soil evolution. We then present a hierarchy of models that have been used to interpret both solid state and solute compositions in regolith. The more simple approaches to model depletion in soils, using analytical models, are first described. The most elementary of these is a linear model that calculates rate constants from the slopes of either solid or solute weathering gradients: these rate constants represent lumped parameters that describe weathering in terms of an integrated reaction rate. Two other analytical models are then presented that have been used to fit solid state elemental profiles with exponential and sigmoidal functions. All of these analytical approaches are derived for models of soils as containing a limited number of components, phases, and species. At a more complex level, numerical models are then presented to elucidate how kinetic and transport parameters as well as chemical, hydrologic, and physical soil data can be incorporated. We consider two forms of these models, first relatively simple spreadsheet calculators and then more sophisticated multi-component, multi-phase reactive-transport numerical codes. Our treatment of reactive transport modeling is relatively cursory, in recognition of the treatment in the chapter by Steefel and Maher (2009 , this volume). Because these models incorporate more phases, components, and species than the other approaches and explicitly model the more fundamental reaction mechanisms involved, they generally have a greater need for parameterization. In our conclusion section, we discuss how this hierarchy of approaches can yield generalizations about soils that are often complementary.

Reviews in Mineralogy and Geochemistry↗

The early Earth as an analogue for exoplanetary biogeochemistry

Planet Earth has evolved over the past 4.5 billion years from an entirely anoxic planet with possibly a different tectonic regime to the oxygenated world with horizontal plate tectonics that we know today. For most of this time, Earth has been inhabited by a purely microbial biosphere albeit with seemingly increasing complexity over time. A rich record of this geobiological evolution over most of Earth’s history thus provides insights into the remote detectability of microbial life under a variety of planetary conditions. Here we leverage Earth’s geobiological record with the aim of (a) illustrating the current state of knowledge and key knowledge gaps about the early Earth as a reference point in exoplanet science research; (b) compiling biotic and abiotic mechanisms that controlled the evolution of the atmosphere over time; and (c) reviewing current constraints on the detectability of Earth’s early biosphere with state-of-the-art telescope technology. We highlight that life may have originated on a planet with a different (stagnant lid) tectonic regime and strong hydrothermal activity, and under these conditions, biogenic CH 4 gas was perhaps the most detectable atmospheric biosignature. Oxygenic photosynthesis, which is responsible for essentially all O 2 gas in the modern atmosphere, appears to have emerged concurrently with the establishment of modern plate tectonics and the emergence of continental crust, but O 2 accumulation to modern levels only occurred late in Earth’s history, perhaps tied to the rise of land plants. Nutrient limitation in anoxic oceans, promoted by hydrothermal Fe fluxes, may have limited biological productivity and O 2 production. N 2 O is an alternative biosignature that was perhaps significant on the redox-stratified Proterozoic Earth. We conclude that the detectability of atmospheric biosignatures on Earth was not only dependent on biological evolution but also strongly controlled by the evolving tectonic context.

Reviews in Mineralogy and Geochemistry↗

Coastal bathymetry data collected in 2013 from the Chandeleur Islands, Louisiana

As part of the Barrier Island Evolution Research Project, scientists from the U.S. Geological Survey (USGS) St. Petersburg Coastal and Marine Science Center conducted nearshore geophysical surveys around the northern Chandeleur Islands, Louisiana, in July and August of 2013. The objective of the study is to better understand barrier-island geomorphic evolution, particularly storm-related depositional and erosional processes that shape the islands over annual to interannual timescales (1‒5 years). Collecting geophysical data will allow us to identify relationships between the geologic history of the island and its present day morphology and sediment distribution. This mapping effort was the third in a series of three planned surveys in this area. High resolution geophysical data collected in each of three consecutive years along this rapidly changing barrier island system will provide a unique time-series dataset that will significantly further the analyses and geomorphological interpretations of this and other coastal systems, improving our understanding of coastal response and evolution over short time scales (1‒5 years). This data series includes the geophysical data that were collected during two cruises (USGS Field Activity Numbers (FAN) 13BIM02, 13BIM03, and 13BIM04, in July 2013; and FANs 13BIM07 and 13BIM08 in August 2013) aboard the R/V Sallenger , the R/V Jabba Jaw , and the R/V Shark along the northern portion of the Chandeleur Islands, Breton National Wildlife Refuge, Louisiana. Primary data were acquired with the following equipment: (1) a Systems Engineering and Assessment, Ltd., SWATHplus interferometric sonar (468 kilohertz [kHz]), (2) an EdgeTech 424 (4‒24 kHz) chirp sub-bottom profiling system, and (3) two Odom Hydrographic Systems, Incorporated, Echotrach CV100 single beam echosounders. This data series report serves as an archive of processed interferometric swath and single-beam bathymetry data. Geographic information system data products include an interpolated digital elevation model, trackline maps, and point data files. Additional files include error analysis maps, Field Activity Collection System logs, and formal Federal Geographic Data Committee metadata.

Louisiana↗

Chirp subbottom profile data collected in 2015 from the northern Chandeleur Islands, Louisiana

As part of the Barrier Island Evolution Research project, scientists from the U.S. Geological Survey (USGS) St. Petersburg Coastal and Marine Science Center conducted a nearshore geophysical survey around the northern Chandeleur Islands, Louisiana, in September 2015. The objective of the project is to improve the understanding of barrier island geomorphic evolution, particularly storm-related depositional and erosional processes that shape the islands over annual to interannual time scales (1–5 years). Collecting geophysical data can help researchers identify relations between the geologic history of the islands and their present day morphology and sediment distribution. High-resolution geophysical data collected along this rapidly changing barrier island system can provide a unique time-series dataset to further the analyses and geomorphological interpretations of this and other coastal systems, improving our understanding of coastal response and evolution over medium-term time scales (months to years). Subbottom profile data were collected in September 2015 offshore of the northern Chandeleur Islands, during USGS Field Activity Number 2015-331-FA. Data products, including raw digital chirp subbottom data, processed subbottom profile images, survey trackline map, navigation files, geographic information system data files and formal Federal Geographic Data Committee metadata, and Field Activity Collection System and operation logs are available for download.

Louisiana↗

Coastal vulnerability to sea-level rise: a preliminary database for the U.S. Atlantic, Pacific, and Gulf of Mexico coasts

The prediction of coastal evolution is not straightforward. There is no standard methodology, and even the kind of data required to make such predictions are the subject of much scientific debate. Since a viable, quantitative predictive model for coastal evolution is not available. The relative susceptibility of the Nation's coastline to sea-level rise is quantified here at a regional to national scale using basic information on coastal geomorphology, rate of sea-level rise, past shoreline evolution and other factors. This approach combines the coastal system's susceptibility to change with its natural ability to adapt to changing environmental and conditions, and yields a relative measure of the system's natural vulnerability to the effects of sea-level rise. This information has immediate application to many of the decisions our society will be making regarding coastal development in both the short- and long-term.

Data Series↗

Coastal bathymetry and backscatter data collected in 2012 from the Chandeleur Islands, Louisiana

As part of the Barrier Island Evolution Research Project, scientists from the U.S. Geological Survey St. Petersburg Coastal and Marine Science Center conducted nearshore geophysical surveys off the northern Chandeleur Islands, Louisiana, in July and August of 2012. The objective of the study is to better understand barrier island geomorphic evolution, particularly storm-related depositional and erosional processes that shape the islands over annual to interannual timescales (1-5 years). Collecting geophysical data will allow us to identify relationships between the geologic history of the island and its present day morphology and sediment distribution. This mapping effort was the second in a series of three planned surveys in this area. High resolution geophysical data collected in each of 3 consecutive years along this rapidly changing barrier island system will provide a unique time-series dataset that will significantly further the analyses and geomorphological interpretations of this and other coastal systems, improving our understanding of coastal response and evolution over short time scales (1-5 years). This Data Series report includes the geophysical data that were collected during two cruises ( USGS Field Activity Numbers 12BIM03 and 12BIM04 ) aboard the RV Survey Cat and the RV Twin Vee along the northern portion of the Chandeleur Islands, Breton National Wildlife Refuge, Louisiana. Data were acquired with the following equipment: a Systems Engineering and Assessment, Ltd., SWATHplus interferometric sonar (468 kilohertz (kHz)), an EdgeTech 424 (4-24 kHz) chirp sub-bottom profiling system, and a Knudsen 320BP (210 kHz) echosounder. This report serves as an archive of processed interferometric swath and single-beam bathymetry data. Geographic information system data products include an interpolated digital elevation model, an acoustic backscatter mosaic, trackline maps, and point data files. Additional files include error analysis maps, Field Activity Collection System logs, and formal Federal Geographic Data Committee metadata. NOTE: These data are scientific in nature and are not to be used for navigation.

Louisiana↗

Coastal bathymetry data collected in 2011 from the Chandeleur Islands, Louisiana

As part of the Barrier Island Evolution Research project, scientists from the U.S. Geological Survey St. Petersburg Coastal and Marine Science Center conducted nearshore geophysical surveys off the northern Chandeleur Islands, Louisiana, in June of 2011. The overall objectives of the study are to better understand barrier-island geomorphic evolution, particularly storm-related depositional and erosional processes that shape the islands over annual to interannual timescales (1-5 years). Collection of geophysical data will allow us to identify relationships between the geologic history of the island and its present day morphology and sediment distribution. This mapping effort was the first in a series of three planned surveys in this area. High resolution geophysical data collected in each of three consecutive years along this rapidly changing barrier-island system will provide a unique time-series dataset that will significantly further the analyses and geomorphological interpretations of this and other coastal systems, improving our understanding of coastal response and evolution over short time scales (1-5 years). This data series includes the bathymetric data that were collected during two cruises ( USGS Field Activity Numbers 11BIM01 and 11BIM02 ) aboard the Research Vessel (R/V) SurveyCat and the R/V TwinVee along the northern portion of the Chandeleur Islands, Breton National Wildlife Refuge , Louisiana. Data were acquired with the following equipment: a Systems Engineering and Assessment, Ltd., SWATH plus interferometric sonar (234 kilohertz), an EdgeTech 424 (4-24 kHz) chirp sub-bottom profiling system, and a Marimatech E-SEA Sound 206 (200 kHz) echosounder. This report serves as an archive of processed interferometric swath and single-beam bathymetry data. Geographic Iinformation System data products include a 50-meter cell-size interpolated bathymetry grid surface, trackline maps, and point data files. Additional files include error analysis maps, Field Activity Collection System logs, and formal Federal Geographic Data Committee metadata.

Louisiana↗

Sediment data collected in 2012 from the northern Chandeleur Islands, Louisiana

As part of the Barrier Island Evolution Research project, scientists from the U.S. Geological Survey St. Petersburg Coastal and Marine Science Center collected sediment samples from the northern Chandeleur Islands in March and September 2012. The overall objective of this project, which integrates geophysical (bathymetric, seismic, and topographic) and sedimentologic data, is to better understand the depositional and erosional processes that drive the morphologic evolution of barrier islands over annual to interannual timescales (1 to 5 years). Between June 2010 and April 2011, in response to the Deepwater Horizon oil spill, the State of Louisiana constructed a sand berm extending more than 14 kilometers along the northern Chandeleur Islands platform. The construction of the berm provided a unique opportunity to investigate how this new sediment source will interact with and affect the morphologic evolution of the barrier-island system. Data collected from this study will be used to describe differences in the physical characteristics and spatial distribution of sediments both along the axis of the berm and also along transects across the berm and onto the adjacent barrier island. Comparison of these data with data from subsequent sampling efforts will provide information about sediment interactions and movement between the berm and the natural island platform, improving our understanding of short-term morphologic change and processes in this barrier-island system. This data series serves as an archive of sediment data collected in March and September 2012 from the Chandeleur Islands sand berm and adjacent barrier-island environments. Data products include descriptive core logs, core photographs and x-radiographs, results of sediment grain-size analyses, sample location maps, and Geographic Information System data files with accompanying formal Federal Geographic Data Committee metadata.

Louisiana↗

Sediment data collected in 2013 from the northern Chandeleur Islands, Louisiana

As part of the Barrier Island Evolution Research project, scientists from the U.S. Geological Survey St. Petersburg Coastal and Marine Science Center collected sediment samples from the northern Chandeleur Islands in July 2013. The overall objective of this project, which integrates geophysical (bathymetric, seismic, and topographic) and sedimentologic data, is to better understand the depositional and erosional processes that drive the morphologic evolution of barrier islands over annual to interannual timescales (1 to 5 years). Between June 2010 and April 2011, in response to the Deepwater Horizon oil spill, the State of Louisiana constructed a sand berm extending more than 14 kilometers along the northern Chandeleur Islands platform. The construction of the berm provided a unique opportunity to investigate how this new sediment source will interact with and affect the morphologic evolution of the barrier-island system. Data collected from this study will be used to describe differences in the physical characteristics and spatial distribution of sediments both along the axis of the berm and also along transects across the berm and onto the adjacent barrier island. Comparison of these data with data from previous sampling efforts will provide information about sediment interactions and movement between the berm and the natural island platform, improving our understanding of short-term morphologic change and processes in this barrier-island system. This data series serves as an archive of sediment data collected in July 2013 from the Chandeleur Islands sand berm and adjacent barrier-island environments. Data products include descriptive core logs, core photographs and x-radiographs, results of sediment grain-size analyses, sample location maps, and Geographic Information System data files with accompanying formal Federal Geographic Data Committee metadata.

Louisiana↗

Dynamic computer model for the metallogenesis and tectonics of the Circum-North Pacific

The digital files on this report consist of a dynamic computer model of the metallogenesis and tectonics of the Circum-North Pacific, and background articles, figures, and maps. The tectonic part of the dynamic computer model is derived from a major analysis of the tectonic evolution of the Circum-North Pacific which is also contained in directory tectevol. The dynamic computer model and associated materials on this CD-ROM are part of a project on the major mineral deposits, metallogenesis, and tectonics of the Russian Far East, Alaska, and the Canadian Cordillera. The project provides critical information on bedrock geology and geophysics, tectonics, major metalliferous mineral resources, metallogenic patterns, and crustal origin and evolution of mineralizing systems for this region. The major scientific goals and benefits of the project are to: (1) provide a comprehensive international data base on the mineral resources of the region that is the first, extensive knowledge available in English; (2) provide major new interpretations of the origin and crustal evolution of mineralizing systems and their host rocks, thereby enabling enhanced, broad-scale tectonic reconstructions and interpretations; and (3) promote trade and scientific and technical exchanges between North America and Eastern Asia.

Open-File Report↗

A detailed taxonomy of Upper Cretaceous and lower Tertiary Crassatellidae in the eastern United States: An example of the nature of extinction at the boundary

Current theories on the causes of extinction at the Cretaceous-Tertiary boundary have been based on previously published data; however, few workers have stopped to ask the question, 'How good is the basic data set?' To test the accuracy of the published record, a quantitative and qualitative analysis of the Crassatellidae (Mollusca, Bivalvia) of the Gulf and Mid-Atlantic Coastal Plains of the United States for the Upper Cretaceous and lower Tertiary was conducted. Thirty-eight species names and four generic names are used in publications for the Crassatellidae within the geographic and stratigraphic constraints of this analysis. Fourteen of the 38 species names are represented by statistically valid numbers of specimens and were tested by using canonical discriminant analysis. All 38 names, with the exception of 1 invalid name and 4 names for which no representative specimen could be located, were evaluated qualitatively. The results show that the published fossil record is highly inaccurate. Only 8 valid, recognizable species exist in the Crassatellidae within the limits of this study, 14 names are synonymized, and 11 names are represented by indeterminate molds or poorly preserved specimens. Three of the four genera are well founded; the fourth is based on the juvenile of another genus and therefore synonymized. This detailed taxonomic analysis of the Crassatellidae illustrates that the published fossil record is not reliable. Calculations of evolutionary and paleobiologic significance based on poorly defined, overly split fossil groups, such as the Crassatellidae, are biased in the following ways: Rates of evolution and extinction are higher, Faunal turnover at mass extinctions appears more catastrophic, Species diversity is high, Average species durations are shortened, and Geographic ranges are restricted. The data on the taxonomically standardized Crassatellidae show evolutionary rates one-quarter to one-half that of the published fossil record; faunal change at the Cretaceous-Tertiary boundary that was not catastrophic; a constant number of species on each side of the Cretaceous-Tertiary boundary; a decrease in abundance in the Tertiary; and lower species diversity, longer average species durations, and expanded geographic ranges. Similar detailed taxonomic studies need to be conducted on other groups of organisms to test the patterns illustrated for the Crassatellidae and to determine the extent and direction of the bias in the published fossil record. Answers to our questions about evolutionary change cannot be found in the literature but rather with the fossils themselves. Evolution and extinction occur within small populations of species groups, and it is only through detailed analysis of these groups that we can achieve an understanding of the causes and effects of evolution and extinction.

Professional Paper↗

Geologic Map of the MTM -30262 and -30267 Quadrangles, Hadriaca Patera Region of Mars

Introduction Mars Transverse Mercator (MTM) -30262 and -30267 quadrangles cover the summit region and east margin of Hadriaca Patera, one of the Martian volcanoes designated highland paterae. MTM -30262 quadrangle includes volcanic deposits from Hadriaca Patera and Tyrrhena Patera (summit northeast of map area) and floor deposits associated with the Dao and Niger Valles canyon systems (south of map area). MTM -30267 quadrangle is centered on the caldera of Hadriaca Patera. The highland paterae are among the oldest, central-vent volcanoes on Mars and exhibit evidence for explosive eruptions, which make a detailed study of their geology an important component in understanding the evolution of Martian volcanism. Photogeologic mapping at 1:500,000-scale from analysis of Viking Orbiter images complements volcanological studies of Hadriaca Patera, geologic investigations of the other highland paterae, and an analysis of the styles and evolution of volcanic activity east of Hellas Planitia in the ancient, cratered highlands of Mars. This photogeologic study is an extension of regional geologic mapping east of Hellas Planitia. The Martian highland paterae are low-relief, areally extensive volcanoes exhibiting central calderas and radial channels and ridges. Four of these volcanoes, Hadriaca, Tyrrhena, Amphitrites, and Peneus Paterae, are located in the ancient cratered terrains surrounding Hellas Planitia and are thought to be located on inferred impact basin rings or related fractures. Based on analyses of Mariner 9 images, Potter (1976), Peterson (1977), and King (1978) suggested that the highland paterae were shield volcanoes formed by eruptions of fluid lavas. Later studies noted morphologic similarities between the paterae and terrestrial ash shields and the lack of primary lava flow features on the flanks of the volcanoes. The degraded appearances of Hadriaca and Tyrrhena Paterae and the apparently easily eroded materials composing their low, broad shields further suggest that the highland paterae are composed predominantly of pyroclastic deposits. Analyses of eruption and flow processes indicate that the distribution of units at Hadriaca and Tyrrhena Paterae is consistent with emplacement by gravity-driven pyroclastic flows. Detailed geologic study of the summit caldera and flanks of Hadriaca Patera is essential to determine the types of volcanic materials exposed, the nature of the processes forming these deposits, and the role of volcanism in the evolution of the cratered highlands that are characteristic of the southern hemisphere of Mars.

Scientific Investigations Map↗

Geologic map of the Topock 7.5’ quadrangle, Arizona and California

The Topock quadrangle exposes a structurally complex part of the Colorado River extensional corridor and also exposes deposits that record landscape evolution during the history of the Colorado River. Paleoproterozoic gneisses and Mesoproterozoic granitoids and intrusive sheets are exposed through tilted cross-sectional thicknesses of many kilometers. Intruding them are a series of Mesozoic to Tertiary igneous rocks including dismembered parts of the Late Cretaceous Chemehuevi Mountains Plutonic Suite. Plutons of this suite in Arizona, if structurally restored for Miocene extension, formed cupolas capping the Chemehuevi Mountains batholith in California. Thick (1–3 km) Miocene sections of volcanic rocks, sedimentary breccias, conglomerate, and sandstone rest nonconformably on the Proterozoic rocks and record the structural and depositional evolution of the Colorado River extensional corridor. Four major Miocene low-angle normal faults and a steep block-bounding fault that developed during this episode divide the deformed rocks of the quadrangle into major structural plates and tilted blocks in and east of the Chemehuevi Mountains core complex. The low-angle faults attenuate crustal section, superposing supracrustal and upper crustal rocks against gneisses and granitoids originally from deeper crustal levels. The transverse block-bounding Gold Dome Fault Zone juxtaposes two large hanging-wall blocks, each tilted 90°, and the fault zone splays at its tip into folds in layered Miocene rocks. A synfaulting intrusion occupies the triangular zone where the folded strata detached from an inside corner along this fault between the tilt blocks. Post-extensional upper Miocene to Quaternary strata, locally deformed, record post-extensional landscape evolution, including several Pliocene and younger aggradational episodes in the Colorado River valley and intervening degradation episodes. The aggradational sequences include (1) the Bouse Formation, (2) fluvial deposits correlated with the alluvium of Bullhead City, (3) the younger fluvial boulder conglomerate of Bat Cave Wash, (4) the fluvial Chemehuevi Formation and related valley-margin deposits, and (5) fluvial Holocene deposits under the river and the valley floor. These fluvial records of Colorado River deposition are interspersed with piedmont alluvial fan deposits of several ages.

Arizona, California↗

Flow paths in the Edwards aquifer, northern Medina and northeastern Uvalde Counties, Texas, based on hydrologic identification and geochemical characterization and simulation

The U.S. Geological Survey, in cooperation with the San Antonio Water System, conducted a 4-year study during 2001– 04 to identify major ground-water flow paths in the Edwards aquifer in northern Medina and northeastern Uvalde Counties, Texas. The study involved use of geologic structure, surfacewater and ground-water data, and geochemistry to identify ground-water flow paths. Relay ramps and associated faulting in northern Medina County appear to channel ground-water flow along four distinct flow paths that move water toward the southwest. The northwestern Medina flow path is bounded on the north by the Woodard Cave fault and on the south by the Parkers Creek fault. Water moves downdip toward the southwest until the flow encounters a cross fault along Seco Creek. This barrier to flow might force part or most of the flow to the south. Departure hydrographs for two wells and discharge departure for a streamflow-gaging station provide evidence for flow in the northwestern Medina flow path. The north-central Medina flow path (northern part) is bounded by the Parkers Creek fault on the north and the Medina Lake fault on the south. The adjacent north-central Medina flow path (southern part) is bounded on the north by the Medina Lake fault and on the south by the Diversion Lake fault. The north-central Medina flow path is separated into a northern and southern part because of water-level differences. Ground water in both parts of the northcentral Medina flow path moves downgradient (and down relay ramp) from eastern Medina County toward the southwest. The north-central Medina flow path is hypothesized to turn south in the vicinity of Seco Creek as it begins to be influenced by structural features. Departure hydrographs for four wells and Medina Lake and discharge departure for a streamflow-gaging station provide evidence for flow in the north-central Medina flow path. The south-central Medina flow path is bounded on the north by the Seco Creek and Diversion Lake faults and on the south by the Haby Crossing fault. Because of bounding faults oriented northeast-southwest and adjacent flow paths directed south by other geologic structures, the south-central Medina flow path follows the configuration of the adjacent flow paths—oriented initially southwest and then south. Immediately after turning south, the south-central Medina flow path turns sharply east. Departure hydrographs for four wells and discharge departure for a streamflow-gaging station provide evidence for flow in the south-central Medina flow path. Statistical correlations between water-level departures for 11 continuously monitored wells provide additional evidence for the hypothesized flow paths. Of the 55 combinations of departure dataset pairs, the stronger correlations (those greater than .6) are all among wells in the same flow path, with one exception. Simulations of compositional differences in water chemistry along a hypothesized flow path in the Edwards aquifer and between ground-water and surface-water systems near Medina Lake were developed using the geochemical model PHREEQC. Ground-water chemistry for samples from five wells in the Edwards aquifer in the northwestern Medina flow path were used to evaluate the evolution of ground-water chemistry in the northwestern Medina flow path. Seven simulations were done for samples from pairs of these wells collected during 2001–03; three of the seven yielded plausible models. Ground-water samples from 13 wells were used to evaluate the evolution of ground-water chemistry in the north-central Medina flow path (northern and southern parts). Five of the wells in the most upgradient part of the flow path were completed in the Trinity aquifer; the remaining eight were completed in the Edwards aquifer. Nineteen simulations were done for samples from well pairs collected during 1995–2003; eight of the 19 yielded plausible models. Ground-water samples from seven wells were used to evaluate the evolution of ground-water chemistry in the south-central Medina flow path. One well was the Trinity aquifer end-member well upgradient from all flow paths, and another was a Trinity aquifer well in the most upgradient part of the flow path; all other wells were completed in the Edwards aquifer. Nine simulations were done for samples from well pairs collected during 1996–2003; seven of the nine yielded plausible models. The plausible models demonstrate that the four hypothesized flow paths can be partially supported geochemically.

Texas↗

Porphyry copper assessment of the Central Asian Orogenic Belt and eastern Tethysides: China, Mongolia, Russia, Pakistan, Kazakhstan, Tajikistan, and India: Chapter X in Global mineral resource assessment

The U.S. Geological Survey collaborated with international colleagues to assess undiscovered resources in porphyry copper deposits in the Central Asian Orogenic Belt and eastern Tethysides. These areas host 20 known porphyry copper deposits, including the world class Oyu Tolgoi deposit in Mongolia that was discovered in the late 1990s. The study area covers major parts of the world’s largest orogenic systems. The Central Asian Orogenic Belt is a collage of amalgamated Precambrian through Mesozoic terranes that extends from the Ural Mountains in the west nearly to the Pacific Coast of Asia in the east and records the evolution and final closure of the Paleo-Asian Ocean in Permian time. The eastern Tethysides, the orogenic belt to the south of the Central Asian Orogenic Belt, records the evolution of another ancient ocean system, the Tethys Ocean. The evolution of these orogenic belts involved magmatism associated with a variety of geologic settings appropriate for formation of porphyry copper deposits, including subduction-related island arcs, continental arcs, and collisional and postconvergent settings. The original settings are difficult to trace because the arcs have been complexly deformed and dismembered by younger tectonic events. Twelve mineral resource assessment tracts were delineated to be permissive for the occurrence of porphyry copper deposits based on mapped and inferred subsurface distributions of igneous rocks of specific age ranges and compositions. These include (1) nine Paleozoic tracts in the Central Asian Orogenic Belt, which range in area from about 60,000 to 800,000 square kilometers (km 2 ); (2) a complex area of about 400,000 km 2 on the northern margin of the Tethysides, the Qinling-Dabie tract, which spans central China and areas to the west, encompassing Paleozoic through Triassic igneous rocks that formed in diverse settings; and (3) assemblages of late Paleozoic and Mesozoic rocks that define two other tracts in the Tethysides, the 100,000 km 2 Jinsajiang tract and the 300,000 km 2 Tethyan-Gangdese tract. Assessment participants evaluated applicable grade and tonnage models and estimated numbers of undiscovered deposits at different confidence levels for each permissive tract. The estimates were then combined with the selected grade and tonnage models using Monte Carlo simulations to generate probabilistic estimates of undiscovered resources. Additional resources in extensions of deposits with identified resources were not specifically evaluated. Assessment results, presented in tables and graphs, show amounts of metal and rock in undiscovered deposits at selected quantile levels of probability (0.95, 0.9, 0.5, 0.1, and 0.05 confidence levels), as well as the arithmetic mean and associated standard deviations and variances for each tract. This assessment estimated a total of 97 undiscovered porphyry copper deposits within the assessed permissive tracts. This represents nearly five times the 20 known deposits. Predicted mean resources that could be associated with these undiscovered deposits are about 370,000,000 metric tons (t) of copper, 10,000 t of gold, 7,700,000 t of molybdenum, and 120,000 t of silver. The assessment area is estimated to contain about five times as much copper in undiscovered deposits as has been identified to date. This report includes a summary of the data used in the assessment, a brief overview of the geologic framework of the area, descriptions of permissive tracts and known deposits, maps, and tables. A geographic information system database that accompanies this report includes the tract boundaries and known porphyry copper deposits, significant prospects, and prospects. Assessments of overlapping younger rocks and adjacent areas are included in separate reports available on-line at http://minerals.usgs.gov/global/ .

Scientific Investigations Report↗

Field-trip guide to continental arc to rift volcanism of the southern Rocky Mountains—Southern Rocky Mountain, Taos Plateau, and Jemez Mountains volcanic fields of southern Colorado and northern New Mexico

The southern Rocky Mountains of northern New Mexico and southern Colorado preserve the Oligocene to Pleistocene record of North American continental arc to rift volcanism. The 35–23 million year old (Ma) southern Rocky Mountain volcanic field (SRMVF), spectacularly preserved in the San Juan Mountains of southern Colorado, records the evolution of large andesitic stratovolcanoes to complex caldera clusters, from which at least 22 major ignimbrite sheets (each 150–5,000 cubic kilometers) were erupted. Outflow deposits of the SRMVF preserved along the broadly uplifted northwest flank of the northern Rio Grande rift basin (the San Luis Valley) provide critical structural and temporal constraints on the inception of crustal extension. Coincident with waning stages of SRMVF caldera-forming volcanism (~25.4 Ma), extensional tectonism was accompanied by a transition from bimodal early Miocene to intermediate-composition late Miocene and dominantly basaltic Pliocene rift volcanism of the Taos Plateau in the southern San Luis Basin. Concomitant rift volcanism in the Española Basin and bordering Jemez Mountains of northern New Mexico records a similar Miocene eruptive history dominated by intermediate-composition volcanism that transitioned locally to Pliocene rift-related basaltic volcanism of the Cerros del Rio volcanic field and culminated in eruptions of the iconic rhyolitic Pleistocene Bandelier Tuff and formation of the Valles Caldera along the northwestern rift-basin margin. This 6-day, 7-night field trip will focus, in broadly equal proportions, on rift-related extensional volcanism of the Jemez Mountains and Taos Plateau regions during the first half of the trip, and on caldera-forming volcanism of the southern Rocky Mountain volcanic field during the second half of the trip. The 35-million-year volcanic history of the region highlighted by new geologic mapping, high-resolution geochronology, petrologic, geochemical, and geophysical data facilitates discussion of (1) the magmatic response to the tectonic transition from subducted-slab arc to continental-rift volcanism; (2) the nature and temporal evolution of rift magmas; (3) fault controls on the spatial evolution of rift magmatism; (4) the diversity of continental-arc ignimbrite volcanism and associated lavas; (5) ignimbrite caldera structure and associated intrusions in three-dimension; (6) the role of recycled crystal mush and magmatic cumulates during growth of Cordilleran batholiths; and (7) high-precision geochronologic contributions to interpretation of relations between regional tectonic and volcanic processes. Most stops will be along roads, but there will be moderate hikes on trails of less than 1-hour duration covering 1–2 kilometers (0.6–1.2 miles) with modest elevation gain of <150 meters (<492 feet). The route will progress in reverse stratigraphic order, starting in the Jemez Mountains of New Mexico and proceed northward to San Luis Basin and San Luis Hills before turning west to the southeast and central San Juan Mountains. Our last full day takes us to the little-visited and only recently mapped, Bonanza caldera of the northeastern San Juan Mountains and on the final day, we leave the San Luis Valley to briefly explore the Tertiary subvolcanic plutons of the Collegiate Range along the west side of the Arkansas Valley rift valley, en route to Denver. The authors of all daily contributions acknowledge the helpful reviews by Amy Gilmer and Joe Colgan and thank Christine Chan and Jeremy Havens for assistance with figures, tables, and guidebook text.

Colorado, New Mexico↗

Episodic sediment-discharge events in Cascade Springs, southern Black Hills, South Dakota

Cascade Springs is a group of artesian springs in the southern Black Hills, South Dakota, with collective flow of about 19.6 cubic feet per second. Beginning on February 28, 1992, a large discharge of red suspended sediment was observed from two of the six known discharge points. Similar events during 1906-07 and 1969 were documented by local residents and newspaper accounts. Mineralogic and grain-size analyses were performed to identify probable subsurface sources of the sediment. Geochemical modeling was performed to evaluate the geochemical evolution of water discharged from Cascade Springs. Interpretations of results provide a perspective on the role of artesian springs in the regional geohydrologic framework. X-ray diffraction mineralogic analyses of the clay fraction of the suspended sediment were compared to analyses of clay-fraction samples taken from nine geologic units at and stratigraphically below the spring-discharge points. Ongoing development of a subsurface breccia pipe(s) in the upper Minnelusa Formation and/or Opeche Shale was identified as a likely source of the suspended sediment; thus, exposed breccia pipes in lower Hell Canyon were examined. Upper Minnelusa Formation breccia pipes in lower Hell Canyon occur in clusters similar to the discrete discharge points of Cascade Springs. Grain-size analyses showed that breccia masses lack clay fractions and have coarser distributions than the wall rocks, which indicates that the red, fine-grained fractions have been carried out as suspended sediment. These findings support the hypothesis that many breccia pipes were formed as throats of abandoned artesian springs. Geochemical modeling was used to test whether geochemical evolution of ground water is consistent with this hypothesis. The evolution of water at Cascade Springs could not be suitably simulated using only upgradient water from the Minnelusa aquifer. A suitable model involved dissolution of anhydrite accompanied by dedolomitization in the upper Minnelusa Formation, which is caused by upward leakage of relatively fresh water from the Madison aquifer. The anhydrite dissolution and dedolomitization account for the net removal of minerals that would lead to breccia pipe formation by gravitational collapse. Breccia pipes in the lower Minnelusa Formation are uncommon; however, networks of interconnected breccia layers and breccia dikes are common. These networks, along with vertical fractures and faults, are likely pathways for transmitting upward leakage from the Madison aquifer. It is concluded that suspended sediment discharged at Cascade Springs probably results from episodic collapse brecciation that is caused by subsurface dissolution of anhydrite beds and cements of the upper Minnelusa Formation, accompanied by replacement of dolomite by calcite. It is further concluded that many breccia pipes probably are the throats of artesian springs that have been abandoned and exposed by erosion. The locations of artesian spring-discharge points probably have been shifting outwards from the center of the Black Hills uplift, essentially keeping pace with regional erosion over geologic time. Thus, artesian springflow probably is a factor in controlling water levels in the Madison and Minnelusa aquifers, with hydraulic head declining over geologic time, in response to development of new discharge points. Development of breccia pipes as throats of artesian springs would greatly enhance vertical hydraulic conductivity in the immediate vicinity of spring-discharge points. Horizontal hydraulic conductivity in the Minnelusa Formation also may be enhanced by dissolution processes related to upward leakage from the Madison aquifer. Potential processes could include dissolution resulting from leakage in the vicinity of breccia pipes that are abandoned spring throats, active spring discharge, development of subsurface breccias with no visible surface expression or spring discharge, as well as general areal leakage from the Madison aquifer into the Minnelusa Formation.

South Dakota↗