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Geohydrology and limnology of Walden Pond, Concord, Massachusetts

The trophic ecology and ground-water contributing area of Walden Pond, in Concord and Lincoln, Mass., were investigated by the U.S. Geological Survey in cooperation with the Massachusetts Department of Environmental Management from April 1997 to July 2000. Bathymetric investigation indicated that Walden Pond (24.88 hectares), a glacial kettle-hole lake with no surface inlet or outlet, has three deep areas. The maximum depth (30.5 meters) essentially was unchanged from measurements made by Henry David Thoreau in 1846. The groundwater contributing area (621,000 square meters) to Walden Pond was determined from water-table contours in areas of stratified glacial deposits and from land-surface contours in areas of bedrock highs. Walden Pond is a flow-through lake: Walden Pond gains water from the aquifer along its eastern perimeter and loses water to the aquifer along its western perimeter. Walden Pond contributing area also includes Goose Pond and its contributing area. A water budget calculated for Walden Pond, expressed as depth of water over the lake surface, indicated that 45 percent of the inflow to the lake was from precipitation (1.215 meters per year) and 55 percent from ground water (1.47 meters per year). The groundwater inflow estimate was based on the average of two different approaches including an isotope mass-balance approach. Evaporation accounted for 26 percent of the outflow from the lake (0.71 meters per year) whereas lake-water seepage to the groundwater system contributed 74 percent of the outflow (1.97 meters per year). The water-residence time of Walden Pond is approximately 5 years. Potential point sources of nutrients to ground water, the Concord municipal landfill and a trailer park, were determined to be outside the Walden Pond groundwater contributing area. A third source, the septic leach field for the Walden Pond State Reservation facilities, was within the groundwater contributing area. Nutrient budgets for the lake indicated that nitrogen inputs (858 kilograms per year) were dominated (30 percent) by plume water from the septic leach field and, possibly, by swimmers (34 percent). Phosphorus inputs (32 kilograms per year) were dominated by atmospheric dry deposition, background ground water, and estimated swimmer inputs. Swimmer inputs may represent more than 50 percent of the phosphorus load during the summer. The septic-system plume did not contribute phosphorus, but increased the nitrogen to phosphorus ratio for inputs from 41 to 59, on an atom-to-atom basis. The ratio of nitrogen to phosphorus in input loads and within the lake indicated algal growth would be strongly phosphorus limited. Nitrogen supply in excess of plant requirements may mitigate against nitrogen fixing organisms including undesirable blooms of cyanobacteria. Based on areal nutrient loading, Walden Pond is a mesotrophic lake. Hypolimnetic oxygen demand of Walden Pond has increased since a profile was measured in 1939. Currently (1999), the entire hypolimnion of Walden Pond becomes devoid of dissolved oxygen before fall turnover in late November; whereas historical data indicated dissolved oxygen likely remained in the hypolimnion during 1939. The complete depletion of dissolved oxygen likely causes release of phosphorus from the sediments. Walden Pond contains a large population of the deep-growing benthic macro alga Nitella, which has been hypothesized to promote water clarity in other clear-water lakes by sequestering nutrients and keeping large areas of the sediment surface oxygenated. Loss of Nitella populations in other lakes has correlated with a decline in water quality. Although the Nitella standing crop is large in Walden Pond, Nitella still appears to be controlled by nutrient availability. Decreasing phosphorus inputs to Walden Pond, by amounts under anthropogenic control would likely contribute to the stability of the Nitella population in the metalimnion, may reverse oxygen depletion in the hypolimnion, and decreas

Water-Resources Investigations Report↗

Relation between selected well-construction characteristics and occurrence of bacteria in private household-supply wells, south-central and southeastern Pennsylvania

Total coliform and Escherichia coli ( E. coli ) bacteria were analyzed in ground water sampled from 78 private household-supply wells as part of a study by the U.S. Geological Survey in cooperation with the Pennsylvania Department of Environmental Protection to evaluate the relation between well construction characteristics and the occurrence of bacteria in ground water. Sampling was done in eight counties in south-central and southeastern Pennsylvania from September 2000 to March 2001. All samples were collected from wells in close proximity to agricultural land-use areas. Total coliform bacteria were found in water from 62 percent (48 of 78) of the wells, and bacteria were just as likely to be found in sanitary wells (grouted/loose-fitting well cap or grouted/sanitary sealed well cap) as in nonsanitary wells (nongrouted/ loose-fitting well cap). The areas underlain by carbonate bedrock had the highest percentages of total coliform detected (about 75 percent). Nearly half of the samples collected in the areas underlain by noncarbonate bedrock also were found to have total coliform present. E. coli bacteria were found in water from 10 percent of the wells. Seventeen percent of the samples that were positive for total coliform also were positive for E. coli . The presence of E. coli bacteria was more likely in water from nonsanitary wells. Additionally, the presence of E. coli bacteria was more likely in ground water from wells underlain by carbonate bedrock. A further breakdown of the data into four groups on the basis of sanitary construction and bedrock type indicated the presence of E. coli was more likely in water from nonsanitary wells in areas underlain by carbonate bedrock. Statistical analysis of other well-construction characteristics that might relate to occurrence of bacteria showed that the presence of total coliform bacteria was related to the depth to water-bearing zone in both sanitary and nonsanitary wells in areas underlain by carbonate bedrock. Relations also are present between the presence of total coliform bacteria and casing length in nonsanitary wells in areas underlain by noncarbonate bedrock. Bacteria were found in wells both with and without insects observed on the underside of the well cap. Because of the small number of wells sampled that had sanitary sealed caps, it is uncertain whether installation of sanitary sealed well caps would reduce the incidence of bacteria in ground water from wells or if the presence of bacteria is because of a combination of well-construction characteristics or aquifer-wide contamination of limited or broad areal extent.

Pennsylvania↗

Microbiological quality of water from noncommunity supply wells in carbonate and crystalline aquifers of Pennsylvania

Samples were collected from 59 noncommunity water supplies in the Commonwealth of Pennsylvania from September 2000 to January 2001 and analyzed for pathogens and microbiological indicator organisms. The pathogens sampled were culturable viruses and Helicobacter pylori (H. pylori). The indicator organisms sampled were total coliform, Escherichia coli ( E. coli ), Clostridium perfringens ( C. perfringens ), somatic coliphage, male- specific coliphage, and enterococcus. The two primary areas sampled for the project completed by the U.S. Geological Survey, in cooperation with the Pennsylvania Department of Environmental Protection (PaDEP), were carbonate aquifers and crystalline aquifers. The results of all sampling showed culturable viruses were detected in 8 percent of the wells, H. pyloriin 7 percent of the wells, E. coli in 12 percent of the wells, total coliform in 46 percent of the wells, C. perfringens in 15 percent of the wells, somatic coliphage in 8 percent of the wells, male-specific coliphage in 5 percent of the wells, and enterococcus in 14 percent of the wells. Carbonate aquifers tended to have higher detection rates for the pathogens and indicators sampled than the crystalline aquifers. Detections of the pathogens and indicator organisms were not related statistically to the amounts of urban, agricultural, or forested area in a 1,500-foot radius around the sampled well. Somatic and male-specific coliphage showed the best relation to occurrence of culturable viruses. Culturable viruses and H. pylori were detected in wells in which no indicator organisms were present; therefore, none of the indicator organisms sampled provide complete assurance of pathogenfree water. The best predictive tool for virus screening was a combination of indicator organisms.

Water-Resources Investigations Report↗

Assessment of fish assemblages and minimum sampling effort required to determine botic integrity of large rivers in southern Idaho, 2002

A critical issue surrounding biomonitoring in large rivers (fifth- through seventh-order) is the minimum sampling-reach distance required to collect an adequate number of fish to represent the fish assemblage within a reach. Excessive sampling effort (excessive reach length) is costly in terms of work hours, reduces the number of sites that can be visited, can compromise field-crew safety, can be logistically unfeasible, and can cause unnecessary injury to captured fish. On the other hand, inadequate sampling effort can produce considerable variability in multiple samples collected at a site and may underrepresent the species or river condition present. During the summer of 2002, the U.S. Geological Survey, in cooperation with the Idaho Department of Environmental Quality, determined the minimum sampling effort required to characterize fish assemblages at 17 large-river sites in southern Idaho. The study was done as part of the U.S. Environmental Protection Agency's Environmental Monitoring and Assessment Program. Electrofishing methods and multiple gear types were used to collect sample populations of fish in river reach lengths representing 40 and 100 times the wetted channel width. Minimum sampling effort was assessed by comparing the relation between reach length and the number of species collected, total individuals collected, and final Index of Biotic Integrity (IBI) scores. Thirty-two species of fish in the families Catostomidae, Centrarchidae, Cottidae, Cyprinidae, Ictaluridae, Percidae, and Salmonidae were collected. Of these, 12 alien species were collected, representing about 38 percent of all species collected during the study. Wetted channel width was determined to be sufficient for collecting an adequate number of fish to estimate species richness and evaluate biotic integrity. At most sites, about 250 fish were needed to effectively represent 95 percent of the species present. Fifty-three percent of the sites assessed, using an IBI developed specifically for large Idaho rivers, received scores of less than 50, indicating poor biotic integrity.

Idaho↗

Organic carbon trends, loads, and yields to the Sacramento-San Joaquin Delta, California, water years 1980 to 2000

Organic carbon, nutrient, and suspended sediment concentration data were analyzed for the Sacramento and San Joaquin River Basins for the period 1980-2000. The data were retrieved from three sources: the U.S. Geological Survey's National Water Information System, the U.S. Environmental Protection Agency's Storage and Retrieval System, and the California Interagency Ecological Program's relational database. Twenty sites were selected, all of which had complete records of daily streamflow data. These data met the minimal requirements of the statistical programs used to estimate trends, loads, and yields. The seasonal Kendall program was used to estimate trends in organic carbon, nutrient, and suspended sediment. At all 20 sites, analyses showed that in the 145 analyses for the seven constituents, 95 percent of the analyses had no significant trend. Dissolved organic carbon (DOC) concentrations were significant only for four sites: the American River at Sacramento, the Sacramento River sites near Freeport, Orestimba Creek at River Roads near Crows Landing, and the San Joaquin River near Vernalis. Loads were calculated using two programs, ESTIMATOR and LOADEST2. The 1998 water year was selected to describe loads in the Sacramento River Basin. Organic carbon, nutrient, and suspended sediment loads at the Sacramento River sites near Freeport included transported loads from two main upstream sites: the Sacramento River at Verona and the American River at Sacramento. Loads in the Sacramento River Basin were affected by the amount of water diverted to the Yolo Bypass (the amount varies annually, depending on the precipitation and streamflow). Loads at the Sacramento River sites near Freeport were analyzed for two hydrologic seasons: the irrigation season (April to September) and the nonirrigation season (October to March). DOC loads are lower during the irrigation season then they are during the nonirrigation season. During the irrigation season, water with low concentrations of DOC is released from reservoirs and used for irrigation. On the other hand, during the nonirrigation season, streamflow results from surface water runoff and has higher concentrations of organic carbon, nutrients, and suspended sediment. The 1986 and 1987 water years were selected to describe loads in the San Joaquin River Basin. Organic carbon, nutrient, and suspended sediment loads in the San Joaquin River near Vernalis included transported loads from upstream sites, such as the Mud and Salt Sloughs, the Merced River at River Roads Bridge near Newman, the Tuolumne River at Modesto, and the Stanislaus River at Ripon. Loads at the San Joaquin River near Vernalis also were analyzed for the two seasons. The DOC load for the San Joaquin River at Vernalis is slightly higher during the irrigation season. Yields were calculated in an attempt to rank the subbasins in the Sacramento and San Joaquin River Basins. Five sites delivered streamflow from agricultural and urban sources that had relatively high yields of organic carbon: Sacramento Slough near Knights Landing, Arcade Creek near Del Paso Heights, Salt Slough, Mud Slough, and Colusa Basin Drain at Road 99E near Knights Landing.

California↗

An evaluation of water-quality data from Hydrologic Accounting Unit 051100, Green River Basin, Kentucky

Streamflow and water quality data collected by the U.S. Geological Survey (USGS) and the Kentucky Natural Resources and Environmental Protection Cabinet from 37 sites in the Green River basin were compared to data from the USGS National Stream Quality Accounting Network (NASQAN) Station, Green River near Beech Grove, Kentucky. This comparison was used to determine variability of water quality data throughout the basin, and to determine if water quality data from the NASQAN station were representative of water quality data upstream. Water quality concentrations, yields, and trends were studied. Water quality data from the NASQAN station were fairly representative conditions throughout the basin for specific conductance, pH, phosphorus and nitrogen, but were not representative for chloride, sulfate, iron, and water temperature. Water quality characteristics which were not representative can generally be attributed to impacts of specific land uses such as coal mining or oil production. Mean concentrations of suspended sediment were similar, but extreme concentrations varied throughout the basin. There were no temporal trends detected in instantaneous streamflow, sulfate, or total iron concentrations. Specific conductance was increasing at three stations and decreasing at one, chloride was increasing at two stations and decreasing at one, phosphorus was increasing at two stations, dissolved iron was increasing at one station and decreasing at one, pH was increasing at three stations and decreasing at two, suspended sediment was increasing at one station and decreasing at one, and water temperature was decreasing at two stations. The NASQAN station had increasing trends in chloride, phosphorus, pH, and suspended sediment, and a decreasing trend in water temperature with time. (Author 's abstract)

Water-Resources Investigations Report↗

Suspended-sediment yields from an unmined area and from mined areas before and after reclamation in Pennsylvania, June 1978-September 1983

The U.S. Geological Survey, in cooperation with the Pennsylvania Department of Environmental Resources, has collected hydrologic data from areas in Tioga, Clearfield, and Fayette Counties to determine the effects of surface coal mining on sediment yields. The data were collected from June 1978 through September 1983. Rainfall, streamflow and suspended-sediment data were collected with automatic recording and sampling equipment. Data were collected in Tioga County from an agricultural area that was unaffected by mining and from a forested area prior to surface mining. Data were collected from two areas affected by active surface mining in Tioga County and from an area in Clearfield County being mined by the contour-surface method. Data also were collected from three areas, Tioga, Clearfield, and Fayette Counties, during and after reclamation. The efficiencies of sediment-control pounds in Clearfield and Fayette Counties also were determined. The average annual sediment yield from the agricultural area in Tioga County, which was 35 percent forested, was 0.48 ton per acre per year, and the yield from the forested area prior to mining was 0.0036 ton per acre per year. The average annual sediment yields from the areas affected by active surface mining were 22 tons per acre from the improved haul road and 148 tons per acre from the unimproved haul road. The average annual sediment yield from the site in Clearfield County that had been prepared for mining was 6.3 tons per acre. The average annual sediment yield from the same site while it was being mined by the contour method was 5.5 tons per acre per year. The sediment-control pond reduced the average annual sediment yield to 0.50 ton per acre while the site was prepared for mining and to 0.14 ton per acre while the site was being mined. Because the active surface mining reduced the effective drainage area to the pond, the sediment yield decreased from 0.50 to 0.14 ton per acre. Average annual suspended-sediment yields from the reclaimed site in Tioga County were 1.0 ton per acre during the first year, when vegetation was becoming established, and 0.037 ton per acre during the second year, when vegetation was well established. The average annual sediment yield below a 21.2-acre, reclaimed, surface mine in Clearfield County that had been mined by the contour method was 15 tons per acre during the first year when vegetation was becoming established. However, the average annual sediment yield below a sediment-control pond at this reclaimed site in Clearfield County was 0.30 ton per acre. Data collected from a 4.2-acre reclaimed area that had been surface mined by the block-cut method in Fayette County showed that annual sediment yields from the area were 77 tons per acre in 1981 (no vegetation), 32 tons per acre in 1982 (sparse vegetation), and 1.0 ton per acre in 1983 (well-esatablished vegetation). The average annual yield below a sediment-control pond at the mine site in Fayette County was 0.19 ton per acre during the 27 months of data collection.

Water-Resources Investigations Report↗

Geohydrology and susceptibility of aquifers to surface contamination in Alabama; area 5

The U.S. Geological Survey, in cooperation with the Alabama Department of Environmental Management, is conducting a series of geohydrologic studies to delineate the major aquifers and their susceptibility to contamination in Alabama. This report delineates and describes the geohydrology and susceptibility of the major aquifers to contamination in Area 5--Chambers, Clay, Cleburne, Coosa, Lee, Randolph, and Tallapoosa Counties. Little groundwater is used for public water supplies in Area 5. Groundwater withdrawals for public supply in 1985 were 0.88 million gal/day. Most cities and towns that formerly used groundwater presently use surface water. None of the sedimentary rocks or unconsolidated deposits is tapped by public supply wells. None of the igneous and metamorphic rocks are considered a major aquifer because of low yields. Aquifers in the study area are susceptible to surface contamination throughout their entire outcrop area. Areas that are highly faulted and valley areas where groundwater is at or near land surface have potential to be highly susceptible to surface contamination. (USGS)

Water-Resources Investigations Report↗

Hydrology, vegetation, and soils of four north Florida River flood plains with an evaluation of state and federal wetland determinations

A study of hydrologic conditions, vegetation, and soils was made in wetland forests of four north Florida streams from 1987 to 1990. The study was conducted by the U.S. Geological Survey in cooperation with the Florida Department of Environmental Regulation to support State and Federal efforts to improve wetland delineation methodology in flood plains. Plant communities and soils were described and related to topographic position and long-term hydrologic conditions at 10 study plots located on 4 streams. Detailed appendixes give average duration, frequency, and depth of flooding; canopy, subcanopy, and ground-cover vegetation; and taxonomic classification, series, and profile descriptions of soils for each plot. Topographic relief, range in stage, and depth of flooding were greatest on the alluvial flood plain of the Ochlockonee River, the largest of the four streams. Soils were silty in the lower elevations of the flood plain, and tree communities were distinctly different in each topographic zone. The Aucilla River flood plain was dominated by levees and terraces with very few depressions or low backwater areas. Oaks dominated the canopy of both lower and upper terraces of the Aucilla flood plain. Telogia Creek is a blackwater stream that is a major tributary of the Ochlockonee River. Its low, wet flood plain was dominated by Wyssa ogeche (Ogeechee tupelo) trees, had soils with mucky horizons, and was inundated by frequent floods of very short duration. The St. Marks River, a spring-fed stream with high base flow, had the least topographic relief and lowest range in stage of the four streams. St. Marks soils had a higher clay content than the other streams, and limestone bedrock was relatively close to the surface. Wetland determinations of the study plots based on State and Federal regulatory criteria were evaluated. Most State and Federal wetland determinations are based primarily on vegetation and soil characteristics because hydrologic records are usually not available. In this study, plots were located near long-term gaging stations, thus wetland determinations based on plant and soil characteristics could be evaluated at sites where long-term hydrologic conditions were known. Inconsistencies among hydrology, vegetation, and soil determinations were greatest on levee communities of the Ochlockonee and Aucilla River flood plains. Duration of average annual longest flood was almost 2 weeks for both plots. The wetland species list currently used (1991) by the State lacks many ground-cover species common to forested flood plains of north Florida rivers. There were 102 ground-cover species considered upland plants by the State that were present on the nine annually flooded plots of this study. Among them were 34 species that grew in areas continuously flooded for an average of 5 weeks or more each year. Common flood-plain species considered upland plants by the State were: Hypoxis leptocarpa (yellow star-grass), and two woody vines, Brunnichia ovata (ladies' eardrops) and Campsis radican s (trumpet-creeper), which were common in areas flooded continuously for 6 to 9 weeks a year; Sebastiania fruticosa (Sebastian-bush), Chasmanthium laxum (spikegrass), and Panicum dichotomum (panic grass), which typically grew in areas flooded an average of 2 to 3 weeks or more per year; Vitis rotundifolia (muscadine) and Toxicodendron radicans (poison-ivy), usually occurring in areas flooded an average of 1 to 2 weeks a year; and Quercus virginiana (live oak) present most often in areas flooded approximately 1 week a year. Federal wetland regulations (1989) limited wetland jurisdiction to only those areas that are inundated or saturated during the growing season. However, year-round hydrologic records were chosen in this report to describe the influence of hydrology on vegetation, because saturation, inundation, or flowing water can have a variety of both beneficial and adverse effects on flood-plain vegetation at any time of the year. These effects can occur because: (1) Soil temperatures in north Florida are probably high enough in winter for anaerobic conditions to develop in saturated soils. (2) Many plants in the flood plains of north Florida are active in the nongrowing season and might be adapted to anaerobic conditions in winter. (3) Other effects of standing water, such as decreased light penetration, prevention of seed germination, and protection of seeds from herbivores; and effects of flowing water, such as scouring and deposition of sediments, seed dispersal, and mechanical injury, can occur any time of year.

Florida↗

Evaluation of agricultural best-management practices in the Conestoga River headwaters, Pennsylvania: Characterization of surface-runoff and ground-water quantity and quality in a small carbonate basin near Churchtown, Pennsylvania, prior to terracing and implementation of nutrient management: Water-quality study of the Conestoga River headwaters, Pennsylvania

The U.S. Geological Survey, in cooperation with the Pennsylvania Department of Environmental Protection1 , conducted a study as part of the U.S. Department of Agriculture's Rural Clean Water Program to determine the effects of agricultural best-management practices on surface-water and ground-water quality in the Conestoga River headwaters basin. This report describes Field-Site 1 and characterizes the surface-runoff and ground-water quantity and quality at the site from January 1983 through September 1984, before the implementation of terracing and nutrient-management best-management practices. The 22.1-acre site, part of two dairy farms, was cropland used primarily for the production of corn and alfalfa, and is underlain by carbonate rock. During the 21-month study period, 91.2 inches of precipitation fell, of which 66 percent occurred during the 1984 water year. Of the 169 storms of 0.10 inch or larger, 97 produced measurable runoff. The average annual application of nutrients to the 14.4 acres of cornfields was 410 pounds per acre of nitrogen and 110 pounds per acre of phosphorus. About three times more nutrients were applied during 1984 water year than during the 1983 water year. The approximate soil-nitrate concentration as nitrogen for the study period was 8.2 milligrams per kilogram in the top 8 inches of soil. Runoff for the study period totalled 714,000 cubic feet, or 9.8 percent of total precipitation. Eighty-eight percent of the runoff occurred during the 1984 water year. Regression analyses indicate that total runoff was controlled primarily by total precipitation amounts during storms and by antecedent moisture conditions; mean event and maximum instantaneous discharges are controlled by precipitation intensity and by antecedent moisture conditions. Regression analyses also suggest that crop cover on the corn acreage affected runoff amounts and rates. Mean concentrations in runoff ranged from 24 to 73,000 milligrams per liter for suspended sediment, 0.45 to 24 milligrams per liter for total phosphorus, and 1.5 to 55 milligrams per liter for total nitrogen. Of the total nitrogen in instantaneous runoff samples, a median of 72 percent was total organic nitrogen. Results of multiple regression analyses suggest that mean nitrogen concentrations in runoff (1) increased with increased surface-nitrogen applications made prior to runoff, and (2) were diluted with increased precipitation duration. Runoff from storms on frozen ground produced the highest loads of nitrogen in runoff. Over the 21-month study period, an estimated 258 tons of suspended sediment, 314 pounds of nitrogen, and 176 pounds of phosphorus were transported with runoff from the site. Of this, 88 percent of the nitrogen and phosphorus loads and 94 percent of the suspended-sediment load were discharged during the wet 1984 water year. The loads for the study period represent 2.5 percent of the total nitrogen and 5.5 percent of the total phosphorus applied to the site as manure and commercial fertilizer. The ground-water basin at the site is slightly larger than the surface-water basin. Ground-water levels, except at one well, responded quickly to recharge; water levels peaked several hours to a day after precipitation. Surface-applied materials moved rapidly to the water table through macropores and slowly by transport through micropores in the unsaturated zone. Median concentrations of dissolved nitrate ranged from 9.2 to 13 milligrams per liter as nitrogen for ground-water samples collected monthly from five wells and a spring. Dissolved nitrate comprised 93 percent (median percentage) of the total nitrogen in ground-water samples. The effect of recharge on ground-water nitrate concentrations was affected by variations in nutrient availability at the land surface and in the unsaturated zone. A lag time of 1 to 3 months was observed between the time that nitrogen was applied to the land surface and local maximums in nitrate concentrations were detected in ground water unaffected by recharge events. Approximately 3,187,000 cubic feet of ground water and an associated 2,200 pounds of nitrate-nitrogen discharged from the site during the study period. For the study period, 42 percent of the precipitation recharged to ground water, 10 percent became runoff, and 48 percent evapotranspired. Inputs of nitrogen to the study area were estimated to be 93 percent from manure, 5 percent from commercial fertilizer, and 2 percent from precipitation. Nitrogen outputs from the system were estimated to be 38 percent to crop uptake, 39 percent to volatilization, 20 percent to ground-water discharge, and 3 percent to surface runoff.

Pennsylvania↗

Relation of stream quality to streamflow, and estimated loads of selected water-quality constituents in the James and Rappahannock rivers near the fall line of Virginia, July 1988 through June 1990

This report presents the results of a study by the U.S. Geological Survey, in cooperation with the Virginia Department of Environmental Quality-- Division of Intergovernmental Coordination to monitor and estimate loads of selected nutrients and suspended solids discharged to Chesapeake Bay from two major tributaries in Virginia. From July 1988 through June 1990, monitoring consisted of collecting depth-integrated, cross-sectional samples from the James and Rappahannock Rivers during storm- flow conditions and at scheduled intervals. Water- quality constituents that were monitored included total suspended solids (residue, total at 105 degrees Celsius), dissolved nitrite plus nitrate, dissolved ammonia, total Kjeldahl nitrogen (ammonia plus organic), total nitrogen, total phosphorus, dissolved orthopohosphorus, total organic carbon, and dissolved silica. Daily mean load estimates of each constituent were computed by month, using a seven-parameter log-linear-regression model that uses variables of time, discharge, and seasonality. Water-quality data and constituent- load estimates are included in the report in tabular and graphic form. The data and load estimates provided in this report will be used to calibrate the computer modeling efforts of the Chesapeake Bay region, evaluate the water quality of the Bay and the major effects on the water quality, and assess the results of best-management practices in Virginia.

Water-Resources Investigations Report↗

Estimated availability of water from stratified-drift aquifers in the Concord River Basin, Massachusetts

An understanding of water availability in the Concord River Basin for public and private supply requires an understanding of the interaction between surface-water and ground-water systems. This understanding is needed because excessive ground-water withdrawals may reduce streamflows to unacceptable levels. The U.S. Geological Survey, in cooperation with the Massachusetts Department of Environmental Management, Office of Water Resources, studied the Concord River Basin to estimate the volume of water available from stratified-drift aquifers. A combined hydrograph-separation and streamflow-duration-curve analysis indicates that 20.8 million cubic feet of water could be withdrawn from the stratified-drift aquifer above the South Acton streamflow-gaging station during a 102-day period of no recharge before streamflow would be reduced to a prescribed minimum level. This volume, which equals 2.85 million cubic feet per square mile of stratified drift, was used to estimate volume of available water in 17 aquifer areas in the Concord River Basin. The total volume of available water in the Concord River Basin is estimated to be 561 million cubic feet. Finite-difference ground-water-flow models for the River Meadow Brook aquifer area and the Sudbury and Concord aquifer area quantified the current and potential water availability. The results of three withdrawal simulations for each aquifer area indicate that the 1989 ground-water withdrawal rates would not exceed the volume of water that would be available during a 102-day period of no recharge if water-table drawdowns were not considered. However, results do indicate that volumes of withdrawn water would exceed the available water in the two aquifer areas if maximum lowering of the water table as a percentage of total saturated thickness were 10 and 65 percent at existing and hypothetical wells.

Massachusetts↗

Water-quality characteristics of selected public recreational lakes and ponds in Connecticut

Reconnaissance limnological and lakebed-sediment surveys were conducted in Connecticut during 1989-91 by the U.S. Geological Survey, in cooperation with the Connecticut Department of Environmental Protec- tion, to evaluate water-quality characteristics of selected public recreational lakes and ponds in the State. Limnological surveys were conducted on 49 lakes and ponds selected from a list of 105 publicly owned waterbodies that qualified for water- quality assessments under Section 314 of the Federal Clean Water Act. Lakebed-sediment surveys were conducted in 9 river impoundments and 1 riverine lake below industrial areas and 2 headwater lakes in relatively pristine areas. The limnological surveys consisted of two sampling events--during spring turnover and during the summer stratifi- cation. Each sampling event included depth profiles of water temperature, specific conductance, hydrogen-ion activity, and dissolved oxygen concen- trations; measurements of Secchi disc transparency; and the collection of samples for the analyses of alkalinity, chlorophyll, phosphorus, and nitrogen concentrations. Areal extent and population density of the dominant aquatic macrophytes were qualita- tively noted during the summer sampling event. These water-quality data were used to determine the trophic classification and acidification status of the 49 lakes. The trophic classification yielded the following results: 2 oligotrophic, 8 early mesotrophic, 13 mesotrophic, 5 late mesotrophic, 10 eutrophic, and 11 highly eutrophic lakes. In terms of acidification status, 7 lakes were classified as acid threatened and 42 as not threatened. A Wilcoxon two-tailed signed rank test was used to compare data for 13 lakes and ponds from the present survey with data from the 1973-75 or 1978-79 surveys conducted by the Connecticut Agricultural Experiment Station and Connecticut Department of Environmental Protection. The test showed no significant difference at the 90 percent confidence level for spring nitrogen and summer chlorophyll-a concen- trations, a significant increase at the 90 percent confidence level in summer phosphorus concentra- tions, and a significant decrease at the 95 percent confidence level in summer transparency. For the lakebed-sediment surveys, composite-grab samples were collected from the deepest part of each lake. Samples were analyzed for arsenic, cyanide, organic and inorganic carbon, selected metals, and methylene-extractable, synthetic organic compounds classified by the U.S. Environmental Protection Agency as semi-volatile priority pollutants. Hanover Pond, Eagleville Lake, and West Thompson Lake had three of the four highest concentrations of cadmium, chromium, copper, lead, nickel, zinc, and cyanide. The four lakes with the highest concentrations of arsenic (Aspinook Pond, Fitchville Pond, Mashapaug Pond, and West Thompson Lake) are located in the eastern part of Connecticut. The three samples with the highest mercury concentrations were from Lake Lillinonah and Lake Zoar. There appears to be a positive correlation between the concentrations of cadmium, chromium, copper, lead, nickel, zinc, and cyanide. Only 15 of the 54 synthetic organic compounds analyzed for were detected in 9 of the 12 lakes sampled. Of these 15 compounds, 14 are polycyclic aromatic hydrocarbons and the 15th is a phthalate ester. Hanover Pond had the most compounds detected (9), and phenanthrene was the compound detected in the most lakes (8).

Water-Resources Investigations Report↗

Changes in the volume of water in the Mississippi River alluvial aquifer in the Delta, northwestern Mississippi, 1980-94

The U.S. Geological Survey, in cooperation with the Mississippi Department of Environmental Quality, Office of Land and Water Resources, and the Natural Resources Conservation Service, estimated the volumetric changes of water in the Mississippi River alluvial aquifer in northwestern Mississippi from 1980 through 1994. Volumetric changes of water in the alluvial aquifer were estimated for the entire Delta and for five selected areas within the Delta. The volume of water per square mile in the alluvial aquifer in the Delta changed from 17,886 acre-feet during fall 1980 to 17,719 acre-feet during fall 1994, a decrease in volume per square mile of 167 acre-feet. The minimum volume of water per square mile in the alluvial aquifer in the Delta during 1980-94 was 17,640 acre-feet during fall 1988. Of five selected areas within the Delta, an area near Cleveland in Bolivar County had the greatest change in volume of water in the alluvial aquifer. During fall 1980 this area had 20,790 acre-feet of water per square mile in the aquifer; by fall 1994, the volume had decreased to 19,947 acre-feet of water per square mile. An area located in the vicinity of the Sunflower-Leflore County line has within its boundaries a large cone of depression in the potentiometric surface of the alluvial aquifer. The volume of water per square mile in this area decreased from 17,857 acre-feet during fall 1980 to 17,075 acre-feet during fall 1994.

Mississippi↗

Pesticides in surface water of the Mid-Atlantic region

Water-quality data from 463 surface-water sites were compiled and analyzed to document the occurrence and distribution of pesticides in surface water of the Mid-Atlantic region as part of the Mid-Atlantic Integrated Assessment program of the U.S. Environmental Protection Agency. Those data collected by the U.S. Geological Survey from October 1973 through March 1997 were used in the analyses. Data are available for a large part of the Mid-Atlantic region, but large spatial gaps in the data do exist. USGS data bases contained analyses of surface-water samples for 127 pesticide compounds, including 12 degradates, but only 16 of the compounds were commonly detected. Atrazine, metolachlor, simazine, prometon, alachlor, tebuthiuron, cyanazine, diazinon, carbaryl, chlorpyrifos, pendimethalin, 2,4-D, dieldrin, DCPA, metribuzin, and desethylatrazine (an atrazine degradate) were detected in more than 100 of the samples analyzed. At least one pesticide was detected in about 75 percent of the samples collected and at more than 90 percent of the sites sampled. Concentrations greater than the Federal Maximum Contaminant Level (MCL) for drinking water of 3 micrograms per liter (ug/L) for atrazine were found in 67 of 2,076 samples analyzed; concentrations greater than the MCL of 2ug/L for alachlor were found in 13 of 1,693 samples analyzed, and concentrations greater than the MCL of 4 ug/L for simazine were found in 17 of 1,995 samples analyzed. Concentrations of four pesticides were greater than Federal Health Advisory levels for drinking water, and concentrations of nine pesticides were greater than Federal Ambient Water-Quality Criteria for the Protection of Aquatic Organisms. Streams draining basins with different land uses tend to have different pesticide detection frequencies and median concentrations. Median concentrations of herbicides tend to be highest in streams draining basins in which the major land use is agriculture, whereas median concentrations of insecticides tend to be highest in streams draining extensively urbanized basins. Concentrations of both herbicides and insecticides are usually highest during the spring and summer, although many pesticides are present at low concentrations in surface water throughout the year. Pesticide concentrations vary greatly seasonally and over different hydrologic conditions, with overall variation sometimes exceeding four orders of magnitude. During periods of pesticide application (typically spring and summer), the occurrence of selected pesticides in some streams in the Mid-Atlantic region is related to streamflow. Correlations between concentrations of selected pesticides and streamflow are statistically significant during spring and summer for small (draining less than 55 square miles) streams. Concentrations of selected pesticides in small streams increase during high flows in the growing season, up to 30 times the concentrations present during low-flow conditions in the growing season. In small streams draining urban areas, concentrations of atrazine decrease during high-flow events but concentrations of the insecticides diazinon and chlorpyrifos increase. This may be due to the differences in the pesticides used in agricultural and urban areas and the amounts applied.

Water-Resources Investigations Report↗

Hydrology and sedimentation of Bixler Run Basin, central Pennsylvania

Rainfall, streamflow, stream chemical, and sediment discharge data were collected from Bixler Run near Loysville, Pa., during the period from February 1954 to September 1969 as part of a project to evaluate sediment discharge from an agricultural area in which soil-conservation techniques were being adopted at a moderate rate. The study was conducted by the U.S. Geological Survey in cooperation with the Pennsylvania Department of Environmental Resources, State Conservation Commission. Sediment yields from the basin averaged 64 tons per square mile (22 tonnes per square kilometre) per year, approximately 25 percent less than yields from the surrounding area. The relation between water discharge and suspended-sediment discharge remained constant during the study. Suspended-sediment concentrations in the streamflow were less than 10 milligrams per litre 70 percent of the time. The concentration of chloride ions in the streamflow increased from 1959 to 1969. Ground water maintained flows at the gaging location at a rate of 1.9 cubic feet per second (0.054 cubic metres per second) during the period of data collection.

Water Supply Paper↗

Monitoring changes in Landsat thermal features in urban and non-urban interfaces from 1986 to 2023 in two international urban centers: Implications for climate and global issues

Rapid urbanization is reshaping thermal environments worldwide, with the strongest impacts occurring at the interface between urban and non-urban areas. Impervious surfaces, as key indicators of urban expansion, are critical for monitoring urban growth and assessing surface urban heat island (SUHI) effects. Land use and land cover change (LULCC) provides an essential link between urban dynamics and their environmental and societal consequences. Here, we integrated the U.S. Geological Survey (USGS) Climate Global Issues (CGI) Land Cover Product with Landsat thermal time-series to investigate SUHI evolution in two contrasting metropolitan regions: Wuhan, China, and Brasília, Brazil. Using data spanning 1986–2023, we analyzed the relationships between land cover, Landsat-based land surface temperature (LST), and SUHI intensity, and identified persistent thermal hotspots. Results demonstrate that the land cover data utilized increases the accuracy of impervious surface mapping along urban–rural gradients. Average SUHI intensities were 3.4 °C in Wuhan and 3.3 °C in Brasília, with statistically significant warming trends of 0.04 °C/year and 0.01 °C/year, respectively. Maximum temperature proved to be a robust indicator of SUHI intensification, capturing long-term upward trends. Our findings highlight the important role of urban land cover dynamics in shaping temporal SUHI variability and hotspot emergence. This prototype framework demonstrates the scientific and policy value of combining long-term land cover monitoring information with satellite thermal monitoring to quantify and track SUHI at city scale, supporting sustainable urban planning and climate adaptation strategies.

Remote Sensing↗

UTILIZATION OF GEOGRAPHIC INFORMATION SYSTEMS TECHNOLOGY IN THE ASSESSMENT OF REGIONAL GROUND-WATER QUALITY.

The U. S. Geological Survey (USGS) in cooperation with the U. S. Environmental Protection Agency Office of Pesticide Programs and several State agencies in Oregon has prepared a digital spatial database at 1:500,000 scale to be used as a basis for evaluating the potential for ground-water contamination by pesticides and other agricultural chemicals. Geographic information system (GIS) software was used to assemble, analyze, and manage spatial and tabular environmental data in support of this project. Physical processes were interpreted relative to published spatial data and an integrated database to support the appraisal of regional ground-water contamination was constructed. Ground-water sampling results were reviewed relative to the environmental factors present in several agricultural areas to develop an empirical knowledge base which could be used to assist in the selection of future sampling or study areas.

Conference Paper↗