SEARCH · Geology Reports

Results for “Modern Geology”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

SourceResearch connectionFrom yearThrough year

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 973 records · Page 54Linked to original sources

USGS1991

Shoreline deposits and diagenesis resulting from two Late Pleistocene highstands near +5 and +6 metres, Durban, South Africa

In exposures of Pleistocene rocks on the east coast of South Africa, eight sedimentary facies were distinguished on the basis of petrology, grain size, internal structures and field relationships. These are interpreted as deposits of surf zone, breaker zone, swash zone, backbeach, boulder beach and dune environments. Three phases of deposition and diagenesis are recognized. As a result of the stabilising effect of pre-existing coastal facies, the deposits from successive sea level stands are stacked vertically in a narrow coast-normal strip. Early cementation prevented erosion of the deposits during subsequent transgressions. Deposition of subsequent facies took place on an existing coastal dune (Facies 1). A terrace was cut into this dune at a sea level 4.5 to 5 m above present. At this sea level, clastic shoreline sediments were deposited which make up the main sedimentary sequence exposed (Facies 2–7). The steep swash zone, coarse grain size, and comparison with modern conditions in the study area indicate clastic deposition on a high-energy, wave-dominated, microtidal coastline. Vertical stacking of progressively shallower water facies indicates progradation associated with slightly regressive conditions, prior to stranding of the succession above sea level. During a subsequent transgression to 5.5 or 6 m above present sea level, a second terrace was cut across the existing facies, which by then were partly lithified. A boulder beach (Facies 8) deposited on this terrace is indicative of high wave energy and a rocky coastline, formed by existing cemented coastal facies. Comparison with dated deposits from other parts of the South African coast suggest a Late Pleistocene age for Facies 2–8. Deposition was terminated by subsequent regression and continuing low sea levels during the remainder of the Pleistocene. Cementation of the facies took place almost entirely by carbonate precipitation. The presence of isopachous fibrous cements suggests early cementation of Facies 1, 2, 3 and 4 under marine conditions, initially as aragonite which has since inverted to calcite. Facies 5, 6 and 7 are cemented only by equant calcite spar, evidence of cementation in the meteoric phreatic and vadose zones. Lowering of the water table during regression caused the remaining pore space in Facies 1, 2, 3 and 4 to be filled with equant calcite spar. Decementation in a 130 cm wide zone is attributed to water table shifts associated with the later transgression which deposited Facies 8. The vertical stacking of the two depositional sequences may be attributed to rapid cementation of Facies 2, 3, 4, 5, 6 and 7 under humid, subtropical conditions. This lithified sequence then acted as a focus for deposition of coarse-grained shoreline facies (Facies 8) during the subsequent transgression.

Marine Geology↗

USGS1963

Two pollen diagrams from southeastern Minnesota: Problems in the regional late-glacial and postglacial vegetational history

Kirchner Marsh and Lake Carlson are located 3 miles apart in Dakota County about 15 miles south of Minneapolis in the St. Croix moraine, which was formed by the Superior lobe during the Gary phase of the Wisconsin glaciation. During the Mankato phase that followed, the Des Moines lobe advanced to within a few miles of the sites. The region today is in a mixed-oak forest, with a maplebasswood forest 15 miles to the west and a re-entrant of the prairie on the sand plain south of the moraine. The general limit of coniferous trees is about 50 miles northeast of the sites, although outliers, especially of Pinus strobus, may be found along the Mississippi Valley a few miles to the east. One sediment core 12-13 m long from each site was analyzed for pollen content at 5-25-cm intervals. Diagrams based on percentage of total pollen (trees, shrubs, wind-pollinated herbs) show essentially identical sequences at the two sites, starting with the late-glacial phase of ice retreat. The diagrams have been subdivided into pollen zones according to the A-B-C sequence introduced by Deevey for New England. The late-glacial pollen record starts at Kirchner Marsh with a short Picea-Cyperaceae-Gramineae phase (Zone K), believed to represent a spruce parkland. Its C-14 date of 13,270 BP and the stratigraphy indicate a pre- Two Creeks and post- Gary correlation. Apparently the Kirchner site did not become established as a lake until this time owing to persistence of dead ice in the moraine. The absence of pollen of specific tundra indicators and the presence of pollen of such thermophilous plants as Fraxinus, Quercus, Corylus, Ambrosia, Humulus, and Typha latifolia imply that the climate was cool rather than cold. Zone A-a, which follows, correlates with the Two Creeks interstade. It is marked by the dominance of Picea, with appreciable percentages of Fraxinus and Ambrosia and with minor amounts of other thermophilous plants and the normal boreal associates of spruce like Betula, Larix, and Salix. Zone A-b, starting 12,050 C-14 years ago, correlates with the Valders ice advance. It is represented at both Kirchner and Carlson and shows the withdrawal of Fraxinus and Ambrosia and the slight rise of Artemisia. Except for the absence of pine in the late-glacial assemblage the vegetation implied by these three zones seems to have its closest modern counterpart in the southern fringe of the Boreal Forest of the Riding Mountain region of southwest Manitoba. It is concluded that pine did not migrate southward with the spruce during the Wisconsin glaciation, at least in the western Great Lakes region, and was thus eliminated from this region. During the lateglacial phases of ice retreat, herbs and spruce pioneered on the deglaciated terrain; pine did not follow until the destruction of the spruce forest at the end of the late-glacial phase. Zone B introduces postglacial time. It represents the time of rapid Vegetational succession following the deterioration of the spruce forest. Simultaneous maxima of Betula, Alnus, Fraxinus, and Abies occurred 10,230 years ago at Kirchner Marsh. These were followed rapidly by a Pinus maximum and then a rise of Ulmus, Quercus, and other deciduous types, dated as 9300 years ago at the correlative site of Madeha. This succession may represent differential rates of migration from refuges south and east of Minnesota . Deciduous trees dominate the C Zones. Zone C-a shows Ulmus and Ostrya /Carpinus followed by Quercus; it probably represents principally a mesic maple-basswood forest changing to oak. Zone C-b represents the advance of prairie into the region at the expense of the oak woodland or savanna. The large and abrupt fluctuations in the curves for Ambrosia-type and Chenopodiineae, especially at the Carlson site, may record encroachment of annual weeds onto intermittently dried lake bottoms. C-14 dates place Zone C-b between 7100 and 5100 years ago. In Zone C-c the Quercus again dominates until the abrupt increase in Ambrosiatype and Chenopodiineae that marks the time of forest clearance and land settlement 50-75 years ago.

Minnesota↗

USGS2000

Hydrologic budget of the late Oligocene Lake Creede and the evolution of the upper Rio Grande drainage system

The filling history, hydrologic budget, and geomorphic development of ancient Lake Creede and its tributary basin are evaluated to determine the factors that controlled its character. The lake filled the Creede caldera that formed in the late Oligocene as a consequence of the eruption of the Snowshoe Mountain Tuff. The caldera's sedimentary fill accumlated to a depth of about 1.26 km and had a volume of about 89 km 3 . The highest lake level was ~3300 m (10,800 ft) present altitude before it drained eastward across a broad volcanic plateau as the ancestral Rio Grande. A tributary canyon several hundred meters deep was cut into hard rhyolite in the north wall of the caldera before the lake was more than half full; its presence demonstrates that ancient Lake Creede filled slowly and thus occupied a long-lived, closed basin. The slow filling rate is incompatible with the present water flux through the Creede caldera basin, because such a flow would fill the basin geologically instantaneously. This mismatch, together with the recognition that the Oligocene climate was similar to that of today, forces the reexamination of the hydrologic and geomorphic history of the caldera. That appraisal shows that the caldera cannot have resurged rapidly immediately after caldera collapse, and that ancient watershed must have been lass than half as large as the present upper Rio Grande basin. The ancient lake had a more or less constant surface area of about 200 km 2 that approximated a steady-state condition between inflow and evaporation. Although the lake level fluctuated with climatic variations, its surface elevation steadily climbed as sediment accumulated, accelerating as resurgance and dome growth usurped spacewithin the basin. It could have had one playa stage early in its development and another after the basin had nearly filled with sediment, but there is no direct evidence for either. At least the lower half of the sedimentary column (the part sampled by the scientific drilling) formed in an euxinic environment. This argues against a persistent early playa, although evaporative accumulation of brine was inevitable. When the rate of resurgance was rapid relative to sedimentary infilling, the lake would have been deep (i.e., bordered by bedrock rather than sedimentary fans). The geomorphic evolution of the Creede caldera and its watershed tracks a two-phase topographic history, the first the Oligocene through Miocene, and the second for Pliocene to the recent. In Oligocene time, the San Juan volcanic field was a hydrologically immature, gently undulating, and outward sloping, constructional volcanic plateau straddling the ancient Continental Divide. West of the Creede caldera, a dendritic drainage discharged northeastward into ancestral Cebolla Creek (a tributary of the ancestral Gunnison River) through an early stage of the Clear Creek graben in the vicinity of Spring Creek Pass. Miocene basalt choked, but did not reconstruct, the drainage. By the end of Miocene time a mature topography of moderate relief developed, exposing some of the higher ores in the Creede district to weathering. In the late Miocene-early Pliocene time the San Juan Mountains were uplifted and titled eastward; the ancestral Rio Grande was revitalized and cut deeply into the older terrain, excavating much of the accessible sediment from the moat of the Creede caldera and exposing successively lowe levels in the Creede district to oxidation. Simultaneously, the southeast end of the Clear Creek graben was reactivated and breached the southwest wall of the Creede caldera. The rejuvenated Rio Grande captured the formerly northeast-directed headwaters of ancestral Cebolla Creek, shifting more than 1000 km 2 from the Pacific-directed drainage to the Atlantic. The water budget for ancient Lake Creede was strictly limited by the early stages of the fist geomorphic cycle; the modern water budget is the product of the second cycle.

Colorado↗

USGS2018

Promoting synergy in the innovative use of environmental data—Workshop summary

From December 2 to 4, 2015, NatureServe and the U.S. Geological Survey organized and hosted a biodiversity and ecological informatics workshop at the U.S. Department of the Interior in Washington, D.C. The workshop objective was to identify user-driven future directions and areas of collaboration in advanced applications of environmental data applied to forecasting and decision making for the sustainability of biodiversity and ecosystem services. Substantial effort to recruit attendees from diverse Federal, State, and private sector organizations successfully attracted participants from 20 Federal agencies and 48 different institutions in the academic, nonprofit, State government, and commercial sectors; the total number of attendees ranged from 100 to 144 during the 3-day workshop. The first one-half of the workshop was divided into 7 plenary sessions and 3 sets of lightning talk sessions organized by sector, providing 48 oral and visual plenary presentations that shared diverse perspectives on biodiversity and ecological informatics, including original biospatial analyses from 6 graduate student map contest winners. The second one-half of the workshop focused on 10 breakout sessions with participant-driven themes from the environmental data sphere and concluded with an address by the Director of the U.S. Fish and Wildlife Service. The workshop was structured to encourage interactivity. About 80–90 percent of attendees provided direct feedback using clicker devices for specific questions related to biodiversity and ecological data uses and needs, and 10 breakout session leaders shared the highlights of their group discussions during the final workshop plenary sessions. Participants were encouraged to use the Twitter hashtag #ShareUrData. Over lunch on day 2 there were 20 simultaneous presentations of tools and apps during a special “Tools Café” session. The 10 participant-defined breakout session topics are listed below: Ecosystem services and ecological indicators Inventory and monitoring Biogeographic map of the Nation Pollinators Invasive species Remote sensing Drivers of agricultural change Citizen science Climate Hydrology and watersheds Numerous common themes that emerged from the workshop include the following: The vital importance of completing foundational environmental datasets that are nationally consistent and are essential to multiple sectors, such as the Soil Survey Geographic database high-resolution soils data, a minimum 5-meter resolution digital elevation model, national hydrographic data, high-resolution land cover data, time series high-resolution spatial climate data from historical to future time steps, and a national wetland inventory. Improved, nationally consistent environmental datasets (integrated with targeted observations) will dramatically advance forecasting capacity and support early warning systems (that is, drought, forest disease); however, multiagency coordination should focus on decision support tools that convey appropriate actions and responses to adapt to, and mitigate, potential negative consequences. Digitizing and providing access to the vast stores of underused historical data that can be leveraged for this purpose is of national importance. Modern computational techniques and the ever-increasing flow of environmental data from ground and remote observations can support improved understanding of environmental change. Success of understanding patterns of change for decision making requires establishing baselines from which change can be measured. The value of digitized historical data is greater than ever before. There is a need to recognize the multifaceted potential of citizen science to engage the public in resource stewardship, to create the next generation of science, technology, engineering, math, and environmental leaders, and to have sufficient field personnel to monitor environmental trends, including early detection of alien invasive species, phenological shifts, shifting distribution and abundance of indicator species, and species inventories. The Federal government has an essential role in creating the infrastructure to dramatically improve mobilization of citizen science (and other) data by fostering the following: creation of data standards, creation of nationally consistent framework datasets, vertical integration of observation data, visualization and dissemination of aggregated datasets, and calculation and communication of derived trends. Current and near future trends in the availability of remotely sensed data (rapid expansion of satellite fleets and drones) is revolutionizing access to near-real-time ecological data. Targeted integration with ground-based observations and instrumentation has an extremely valuable role in validating remotely sensed data, filling data gaps, improving data quality, and fully realizing the potential of the near-real-time monitoring of environmental indicator trends. Integrated management of environmental data at the landscape scale is required even as specific actions on the ground are largely local in nature. The workshop highlighted numerous success stories; however, almost every breakout group pointed out the still-too-fragmented nature of the current data landscape. Management and delivery of the necessary data, tools, and analyses to sustain our Nation’s environmental capital must be a collaborative effort between Federal, State, and local governments, academia, nonprofits, and the commercial sector, even though the responsibilities of each sector are different.

Open-File Report↗

USGS1973

Geology and mineral resources of central Antioquia Department (Zone IIA), Colombia

This report summarizes the geology of an area of some 6000 square kilometers in the northern part of the Central Cordillera of the Colombian Andes. The area, in north-central Department of Antioquia, was mapped between 1964 and 1968 as part of the Inventario Minero Nacional (IMN) project. Mineral resources are summarized within a larger area, designated as subzone ILK of IMN Zone If, which comprises almost 22,000 sq. kin, including the area mapped geologically by IMN and additional areas mapped by other agencies. The oldest formation is a micaceous paragneiss of early Paleozoic or possibly late Precambrian age. A thick geosynclinal sedimentary series accumulated during the Paleozoic Era and became regionally metamorphosed to greenschist (locally amphibolite) facies during the Permian or early Triassic; these schists and gneisses are designated collectively as the Valdivia Group. The Permian(?) orogenic episode included intrusion of concordant syntectonic plutons, mostly of tonalitic composition. Rocks of unequivocal Triassic or Jurassic age are not recognized. The Cretaceous is well represented by both igneous and sedimentary assemblages. Eugeosynclinal alpine ophiolites comprising submarine basalt flows and numerous intrusions of gabbro and serpentinite are prominent in the Lower Cretaceous, together with flysch composed of marine shale and lesser sandstone and conglomerate. The Upper Cretaceous is represented along the west border of the mapped area by submarine basalt flows and pyroclastic rocks, locally Interbedded with fine-grained clastic sedimentary beds, and lenses of dark laminated chert, at least part of which is radiolarian. The Late Cretaceous was marked by an orogenic event that profoundly folded and faulted all rocks and in the Central Cordillera caused low-grade metamorphism, the overprint of which is hardly observable in pre-Cretaceous rocks elsewhere. The Late Cretaceous orogeny culminated with discordant intrusion of the epizonal tonalitic Antioquian batholith. Displacement along the great Romeral wrench fault may have begun in the Cretaceous. Plutonism continued into the Cenozoic, exemplified by the hornblende-diorite Sabanalarga pluton. Intermontane basins were filled with molasse derived from the erosion of adjacent highlands; Tertiary sedimentation in marshy areas included organic carboniferous matter subsequently converted to lignite or subbituminous coal. The Sabanalarga fault system originated in the Late Tertiary; intermittent displacement continued on the older wrench faults such as the Romeral. Epeirogenic uplift, which probably began in the Pliocene and continued through the Pleistocene and Holocene, brought on renewed erosion which has sculptured the mountains into their present form. Mineral resources in subzone IIA are varied but not of outstanding importance. Gold and silver mining, significant in past centuries, is minor today. Ferruginous laterite on serpentinite once considered as a potential source of iron ore is not economically exploitable. IMN has explored nickeliferous laterite at the extreme northwest corner of subzone IIA; this is a potential resource, exploitable only after exhaustion of the larger and richer nickel laterite deposit at Cerro Matoso, farther to the north and outside the boundaries of Zone If. Known deposits of mercury, chromium, manganese, and copper are small, with limited economic potential. Nonmetallic resources include raw materials for cement, including portland cement. Saprolite clay is widely used in making common red brick and tile, still a dominant construction material in all but the most modern multistory buildings. Aggregate materials are varied and abundant. Kaolin of good quality near La Union is important as a ceramic raw mineral filler. Tertiary subbituminous coal beds are an important energy resource in western subzone IIA, and have a good potential for greater development. Deposits of sodic feldspar, talc, decorative stone, and silica a

Open-File Report↗

USGS2025

Insights and strategic opportunities from the USGS 2024 Per- and Polyfluoroalkyl Substances (PFAS) Interagency Workshop

Introduction In 2021, the U.S. Geological Survey (USGS) published Circular 1490 titled, “Integrated Science for the Study of Perfluoroalkyl and Polyfluoroalkyl Substances (PFAS) in the Environment: A Strategic Science Vision for the U.S. Geological Survey” (Tokranov and others, 2021). Circular 1490 was created to be a resource for USGS scientists prioritizing and planning research related to per- and polyfluoroalkyl substances (PFAS) and to be a guide for developing partnerships with other scientists, State and Federal agencies, and stakeholders engaged in PFAS research and management and mitigation of the environmental and human-health effects of PFAS. This USGS PFAS Strategic Science Vision document was intended to be the foundation for a “living strategic vision,” periodically providing updates on the state of USGS PFAS research, emerging PFAS data gaps and needs, and progress on interagency and stakeholder PFAS partnerships and priorities. To meet this objective, the USGS planned to host an Interagency and Stakeholder PFAS Workshop every 2–3 years. During September 10–12, 2024, the USGS hosted the first Interagency and Stakeholder PFAS Workshop in Reston, Virginia. The Workshop brought together experts from other Federal agencies (U.S. Environmental Protection Agency, National Institute of Environmental Health Sciences, Food and Drug Administration, Department of Defense [Air Force, Army]), State agencies (Washington Fish and Wildlife, Virginia Department of Transportation), and academia (Harvard University, University of Maryland) to address key challenges relating to the measurement and modeling of PFAS and the implications for environmental health. Participants engaged in in-depth discussions centered around six pivotal topics related to PFAS: (1) sampling protocols, methods and interpretation; (2) environmental sources, source apportionment, and occurrence; (3) environmental fate and transport; (4) human and wildlife exposure routes and risk; (5) bioconcentration, bioaccumulation, and biomagnification; and (6) ecotoxicology and effects. Each topic had three breakout sessions. A recurrent theme of workshop discussions was how data on a nationwide scale for PFAS occurrence in various environmental matrices, including air, water, food crops, biota, soil, and streambed sediment could help to advance scientific understanding. Participants noted significant geospatial data gaps, particularly in the midwestern and southern United States and the Pacific Northwest. PFAS data collection tends to be more robust along the eastern seaboard and in California. Participants stressed how enhancing the integration of large and small datasets across various agencies could help to support national scale understanding of PFAS. To address these gaps, attendees suggested leveraging datasets from Federal entities like the USGS and the U.S. Department of Defense, State agencies, and municipal utility services to develop predictive contaminant detection and transport models. Improved coordination between water quality programs and USGS research could help to facilitate access to valuable data, leading to comprehensive databases that inform PFAS point (wastewater treatment plants and landfills) and nonpoint (runoff from land, atmospheric deposition, food packaging) sources, environmental transport mechanisms, environmental detection and concentrations, potential exposure routes, and health effects on different biota, including humans. A specific request was made to develop a map demarking the depth of modern (1953 or later) groundwater, which is susceptible to surface-derived anthropogenic (that is, human-made) contamination, based on tritium-age dating. Emphasis was placed on incorporation of hydrology, groundwater flow paths, groundwater–surface water interactions, and landscape factors in predictive statistical models as a step to improve contaminant source identification and tracking. Molecular fingerprinting approaches garnered attention as techniques to link specific PFAS mixtures detected in a sample to environmental sources and levels in biota (Dávila-Santiago and others, 2022). Integrating data from abiotic (that is, water, soil, and air) and biotic (that is, living organisms) systems identified as a research opportunity. For example, understanding the composition of soils and sediments, which include a mixture of mineral, plant, and animal components, could advance understanding of exposure pathways. The discussions highlighted opportunities to explore and understand the potential redistribution and biotic exposures of PFAS from biosolid and wastewater treatment plant effluent land application practices, in addition to atmospheric releases and discharges from landfill and wastewater treatment plants. Participants identified research gaps surrounding how these sources may contribute to contamination and may affect surrounding ecosystems, including a better definition of anthropogenic background concentrations. Moving forward, the collection of co-occurrence data was noted as a means to improve understanding of complex mixtures and to leverage companion modeling efforts focused on areas with high and low contamination levels to identify areas of concern and unaffected resources. Participants emphasized how centralized USGS databases and the establishment of sample-metadata archives can help to ensure that samples are preserved and accessible for future research. In conclusion, the workshop participants identified opportunities to bridge data gaps and improve measurement techniques, modeling frameworks, databases, and communication, to enhance the understanding of PFAS and their effects on environmental and human health. Upon completion of the workshop, participants indicated an interest in developing strategic data collection, modeling, and analytical approaches to address these challenges.

Open-File Report↗

USGS2010

Estimates of groundwater age from till and carbonate bedrock hydrogeologic units at Jefferson Proving Ground, Southeastern Indiana, 2007-08

During 2007-08, the U.S. Geological Survey, in cooperation with the U.S. Department of the Army, conducted a study to evaluate the relative age of groundwater in Pre-Wisconsinan till and underlying shallow and deep carbonate bedrock units in and near an area at Jefferson Proving Ground (JPG), southeastern Indiana, which was used during 1984-94 to test fire depleted uranium (DU) penetrators. The shallow carbonate unit includes about the upper 40 feet of bedrock below the bedrock-till surface; the deeper carbonate unit includes wells completed at greater depth. Samples collected during April 2008 from 15 wells were analyzed for field water-quality parameters, dissolved gases, tritium, and chlorofluorocarbon (CFC) compounds; samples from 14 additional wells were analyzed for tritium only. Water-level gradients in the Pre-Wisconsinan till and the shallow carbonate unit were from topographically higher areas toward Big Creek and Middle Fork Creek, and their tributaries. Vertical gradients were strongly downward from the shallow carbonate unit toward the deep carbonate unit at 3 of 4 paired wells where water levels recovered after development; indicating the general lack of flow between the two units. The lack of post development recovery of water levels at 4 other wells in the deep carbonate unit indicate that parts of that unit have no appreciable permeability. CFC and tritium-based age dates of Pre-Wisconsinan till groundwater are consistent with infiltration of younger (typically post-1960 age) recharge that 'mixes' with older recharge from less permeable or less interconnected strata. Part of the recharge to three till wells dated from the early to mid-1980s (JPG-DU-03O, JPG-DU-09O, and JPG-DU-10O). Age dates of young recharge in water from two till wells predated 1980 (JPG-DU-04O and JPG-DU-06O). Tritium-based age dates of water from seven other till wells indicated post-1972 age recharge. Most wells in the Pre-Wisconsinan till have the potential to produce groundwater that partially was recharged during or after DU penetrator testing; their water quality can indicate the presence of DU-related contaminants. The shallow carbonate unit near Big Creek is a karst flow system that may be recharged in part from areas with smaller thicknesses of overlying till or through more permeable parts of the till. This is indicated by CFC- and tritium-based piston-flow (non-mixing) model age dates of early-1980s for water from JPG-DU-02I, similar tritium-based ages of water produced from nearby wells MW-5 and MW-11, and cave development along the creek. The CFC and tritium-based age dates indicate that water samples from JPG-DU-01I and JPG-DU-03I were best described as mixtures of post-1984 modern recharge and submodern (1953 or older) recharge. These five wells produced groundwater that was recharged, at least partially, during or after DU-penetrator testing and are within or downgradient from the DU Impact Area with respect to groundwater flow directions inferred from water-level contours. Wells with groundwater age dates that are near to or after the onset (1984) of DU penetrator testing and that have a plausible connection to a contaminant source can be used to indicate the presence or absence of contaminants from DU penetrator or DU-related corrosion products in groundwater. Groundwater-age dates indicate that the ages of recharge sampled from shallow carbonate unit wells JPG-DU-04I, JPG-DU-05I, JPG-DU-06I, JPG-DU-09I, and JPG-DU-10D in easternmost (upgradient) and southernmost wells in the shallow carbonate unit are submodern (1953 or older) and predate the DU testing by at least 30 or more years. Water-quality data from these five wells are not likely to represent effects from DU-projectile testing or corrosion for years. Well JPG-DU-09D in the deep carbonate unit produced groundwater samples with a submodern (1953 or older) age date. The slow recovery of water levels in most wells in the deep carbonate unit is consis

Indiana↗

USGS2015

Organic sedimentation in modern lacustrine systems: A case study from Lake Malawi, East Africa

This study examines the relationship between depositional environment and sedimentary organic geochemistry in Lake Malawi, East Africa, and evaluates the relative significance of the various processes that control sedimentary organic matter (OM) in lacustrine systems. Total organic carbon (TOC) concentrations in recent sediments from Lake Malawi range from 0.01 to 8.80 wt% and average 2.83 wt% for surface sediments and 2.35 wt% for shallow core sediments. Hydrogen index (HI) values as determined by Rock-Eval pyrolysis range from 0 to 756 mg HC g−1 TOC and average 205 mg HC g−1 TOC for surface sediments and 228 mg HC g−1 TOC for shallow core samples. On average, variations in primary productivity throughout the lake may account for ~33% of the TOC content in Lake Malawi sediments (as much as 1 wt% TOC), and have little or no impact on sedimentary HI values. Similarly, ~33% to 66% of the variation in TOC content in Lake Malawi sediments appears to be controlled by anoxic preservation of OM (~1–2 wt% TOC), although some component of the water depth–TOC relationship may be due to physical sediment transport processes. Furthermore, anoxic preservation has a minimal effect on HI values in Lake Malawi sediments. Dilution of OM by inorganic sediment may account for ~16% of variability in TOC content in Lake Malawi sediments (~0.5 wt% TOC). The effect of inputs of terrestrial sediment on the organic character of surface sediments in these lakes is highly variable, and appears to be more closely related to the local depositional environment than the regional flux of terrestrial OM. Total nitrogen and TOC content in surface sediments collected throughout the lake are found to be highly correlated (r2 = 0.95), indicating a well-homogenized source of OM to the lake bottom. The recurring suspension and deposition of terrestrial sediment may account for significant amounts of OM deposited in offshore regions of the lake. This process effectively separates denser inorganic sediment from less dense OM and allows terrestrial OM to preferentially be transported farther offshore. The conclusion is that for the organic carbon content in these regions to be elevated a mixed terrestrial-lacustrine origin is required. The hydrodynamic separation of mineral and organic constituents is most pronounced in regions with shallow bathymetric gradients, consistent with previous findings from Lake Tanganyika.

Lake Malawi↗

USGS2011

Peninsular terrane basement ages recorded by Paleozoic and Paleoproterozoic zircon in gabbro xenoliths and andesite from Redoubt volcano, Alaska

Historically Sactive Redoubt volcano is an Aleutian arc basalt-to-dacite cone constructed upon the Jurassic–Early Tertiary Alaska–Aleutian Range batholith. The batholith intrudes the Peninsular tectonostratigraphic terrane, which is considered to have developed on oceanic basement and to have accreted to North America, possibly in Late Jurassic time. Xenoliths in Redoubt magmas have been thought to be modern cumulate gabbros and fragments of the batholith. However, new sensitive high-resolution ion microprobe (SHRIMP) U-Pb ages for zircon from gabbro xenoliths from a late Pleistocene pyroclastic deposit are dominated by much older, ca. 310 Ma Pennsylvanian and ca. 1865 Ma Paleoproterozoic grains. Zircon age distributions and trace-element concentrations indicate that the ca. 310 Ma zircons date gabbroic intrusive rocks, and the ca. 1865 Ma zircons also are likely from igneous rocks in or beneath Peninsular terrane basement. The trace-element data imply that four of five Cretaceous–Paleocene zircons, and Pennsylvanian low-U, low-Th zircons in one sample, grew from metamorphic or hydrothermal fluids. Textural evidence of xenocrysts and a dominant population of ca. 1865 Ma zircon in juvenile crystal-rich andesite from the same pyroclastic deposit show that this basement has been assimilated by Redoubt magma. Equilibration temperatures and oxygen fugacities indicated by Fe-Ti–oxide minerals in the gabbros and crystal-rich andesite suggest sources near the margins of the Redoubt magmatic system, most likely in the magma accumulation and storage region currently outlined by seismicity and magma petrology at ∼4–10 km below sea level. Additionally, a partially melted gabbro from the 1990 eruption contains zircon with U-Pb ages between ca. 620 Ma and ca. 1705 Ma, as well as one zircon with a U-Th disequilibrium model age of 0 ka. The zircon ages demonstrate that Pennsylvanian, and probably Paleoproterozoic, igneous rocks exist in, or possibly beneath, Peninsular terrane basement. Discovery of Pennsylvanian gabbro similar in age to Skolai arc plutons 500 km to the northeast indicates that the Peninsular terrane, along with the Wrangellia and Alexander terranes, has been part of the Wrangellia composite terrane since at least Pennsylvanian time. Moreover, the zircon data suggest that a Paleoproterozoic continental fragment may be present in the mid-to-upper crust in southern Alaska.

Alaska↗

USGS2008

Hydrogeology, Chemical Characteristics, and Transport Processes in the Zone of Contribution of a Public-Supply Well in York, Nebraska

In 2001, the U.S. Geological Survey, as part of the National Water Quality Assessment (NAWQA) Program, initiated a topical study of Transport of Anthropogenic and Natural Contaminants (TANC) to PSW (public-supply wells). Local-scale and regional-scale TANC study areas were delineated within selected NAWQA study units for intensive study of processes effecting transport of contaminants to PSWs. This report describes results from a local-scale TANC study area at York, Nebraska, within the High Plains aquifer, including the hydrogeology and geochemistry of a 108-square-kilometer study area that contains the zone of contribution to a PSW selected for study (study PSW), and describes factors controlling the transport of selected anthropogenic and natural contaminants to PSWs. Within the local-scale TANC study area, the High Plains aquifer is approximately 75 m (meter) thick, and includes an unconfined aquifer, an upper confining unit, an upper confined aquifer, and a lower confining unit with lower confined sand lenses (units below the upper confining unit are referred to as confined aquifers) in unconsolidated alluvial and glacial deposits overlain by loess and underlain by Cretaceous shale. From northwest to southeast, land use in the local-scale TANC study area changes from predominantly irrigated agricultural land to residential and commercial land in the small community of York (population approximately 8,100). For the purposes of comparing water chemistry, wells were classified by degree of aquifer confinement (unconfined and confined), depth in the unconfined aquifer (shallow and deep), land use (urban and agricultural), and extent of mixing in wells in the confined aquifer with water from the unconfined aquifer (mixed and unmixed). Oxygen (delta 18O) and hydrogen (delta D) stable isotopic values indicated a clear isotopic contrast between shallow wells in the unconfined aquifer (hereinafter, unconfined shallow wells) and most monitoring wells in the confined aquifers (hereinafter, confined unmixed wells). Delta 18O and delta D values for a minority of wells in the confined aquifers were intermediate between those for the unconfined shallow wells and those for the confined unmixed wells. These intermediate values were consistent with mixing of water from unconfined and confined aquifers (hereinafter, confined mixed wells). Oxidation-reduction conditions were primarily oxic in the unconfined aquifer and variably reducing in the confined aquifers. Trace amounts of volatile organic compounds (VOC), particularly tetrachloroethylene (PCE) and trichloroethylene (TCE), were widely detected in unconfined shallow urban wells and indicated the presence of young urban recharge waters in most confined mixed wells. The presence of degradation products of agricultural pesticides (acetochlor and alachlor) in some confined mixed wells suggests that some fraction of the water in these wells also was the result of recharge in agricultural areas. In the unconfined aquifer, age-tracer data (chlorofluorocarbon and sulfur hexafluoride data, and tritium to helium-3 ratios) fit a piston-flow model, with apparent recharge ages ranging from 7 to 48 years and generally increasing with depth. Age-tracer data for the confined aquifers were consistent with mixing of 'old' water, not containing modern tracers recharged in the last 60 years, and exponentially-mixed 'young' water with modern tracers. Confined unmixed wells contained less than (<) 3 percent (%) young water mixed with a much larger fraction greater than or equal to (>=) 97% of old water. Confined mixed wells contained >30% young water and mean ages ranged from 12 to 14 years. Median concentrations of nitrate (as nitrogen, hereinafter, nitrate-N) were 17.3 and 16.0 mg/L (milligram per liter) in unconfined shallow urban and agricultural wells, respectively, indicating a range of likely nitrate sources. Septic systems are most numerous near the edge of the urban area and appear to be

Scientific Investigations Report↗

USGS2010

Hydrogeomorphic segments and hydraulic microhabitats of the Niobrara River, Nebraska— With special emphasis on the Niobrara National Scenic River

The Niobrara River is an ecologically and economically important resource in Nebraska. The Nebraska Department of Natural Resources’ recent designation of the hydraulically connected surface- and groundwater resources of the Niobrara River Basin as “fully appropriated” has emphasized the importance of understanding linkages between the physical and ecological dynamics of the Niobrara River so it can be sustainably managed. In cooperation with the Nebraska Game and Parks Commission, the U.S. Geological Survey investigated the hydrogeomorphic and hydraulic attributes of the Niobrara River in northern Nebraska. This report presents the results of an analysis of hydrogeomorphic segments and hydraulic microhabitats of the Niobrara River and its valley for the approximately 330-mile reach from Dunlap Diversion Dam to its confluence with the Missouri River. Two spatial scales were used to examine and quantify the hydrogeomorphic segments and hydraulic microhabitats of the Niobrara River: a basin scale and a reach scale. At the basin scale, digital spatial data and hydrologic data were analyzed to (1) test for differences between 36 previously determined longitudinal hydrogeomorphic segments; (2) quantitatively describe the hydrogeomorphic characteristics of the river and its valley; and (3) evaluate differences in hydraulic microhabitat over a range of flow regimes among three fluvial geomorphic provinces. The statistical analysis of hydrogeomorphic segments resulted in reclassification rates of 3 to 28 percent of the segments for the four descriptive geomorphic elements. The reassignment of classes by discriminant analysis resulted in a reduction from 36 to 25 total hydrogeomorphic segments because several adjoining segments shared the same ultimate class assignments. Virtually all of the segment mergers were in the Canyons and Restricted Bottoms (CRB) fluvial geomorphic province. The most frequent classes among hydrogeomorphic segments, and the dominant classes per unit length of river, are: a width-restricted valley confinement condition, sinuous-planview pattern, irregular channel width, and an alternate bar configuration. The Niobrara River in the study area flows through a diversity of fluvial geomorphic settings in its traverse across northern Nebraska. In the Meandering Bottoms (MB) fluvial geomorphic province, river discharge magnitudes are low, and the valley exerts little control on the channel-planview pattern. Within the CRB province, the river flows over a diversity of geologic formations, and the valley and river narrow and expand in approximate synchronicity. In the Braided Bottoms (BB) fluvial geomorphic province, the river primarily flows over Cretaceous Pierre Shale, the valley and channel are persistently wide, and the channel slope is generally uniform. The existence of vegetated islands and consequent multithread channel environments, indicated by a higher braided index, mostly coincided with reaches having gentler slopes and less unit stream power. Longitudinal hydrology curves indicate that the flow of the Niobrara River likely is dominated by groundwater as far downstream as Norden. Unit stream power values in the study area vary between 0 and almost 2 pounds per foot per second. Within the MB province, unit stream power steadily increases as the Niobrara gains discharge from groundwater inflow, and the channel slope steepens. The combination of steep slopes, a constrained channel width, and persistent flow within the CRB province results in unit stream power values that are between three and five times greater than those in less confined segments with comparable or greater discharges. With the exception of hydrogeomorphic segment 3, which is affected by Spencer Dam, unit stream power values in the BB province are generally uniform. Channel sinuosity values in the study area varied generally between 1 and 2.5, but with locally higher values measured in the MB province and at the entrenched bedrock meanders of hydrogeomorphic segment 18 in the CRB province. The differences in channel morphology and hydraulic geometries between fluvial geomorphic provinces are evident in the types, relative abundance, and response of hydraulic microhabitats to changing discharges. The four gaging stations chosen for hydraulic microhabitat analysis are distributed among three different fluvial geomorphic provinces. In the MB province, the smaller channel and lower discharges resulted in the dominance of shallow and intermediate-depth hydraulic environments with the vast majority of hydraulic microhabitat restricted to shallow categories even during upper-decile discharges. In the CRB province, intermediate depth hydraulic conditions, particularly intermediate-swift, dominate over all ranges of discharge. Hydraulic microhabitat conditions were most diverse in the BB province, with most hydraulic microhabitat categories present over the entire range of discharges analyzed. The calculated differences in hydraulic microhabitat distributions, abundance, and adjustments between streamflow-gaging stations were the result of differences in physical structure of the channel and subsequent channel hydraulic geometry. At the reach scale, field measurements made in water years 2008 and 2009 in four study reaches within the Scenic Reach were used to (1) characterize the elevation and geomorphic processes associated with fluvial landforms, (2) build hydraulic geometry relations, (3) examine flow hydraulics over a range of discharges, and (4) examine the types and responses of hydraulic microhabitats to a range of flow magnitudes. Four landform groups were identified and named in order of increasing elevation: low flood plains, intermediate flood plains, low terraces, and high terraces. The terraces were poorly characterized because the surveys did not extend across the full width of the alluvial valley bottom. The two lowest fluvial landforms are likely active in the modern hydroclimatic regime. Sediment samples obtained in the study reaches indicate that the primary bed material in the active channel ranged in size from coarse silt to coarse sand. Grain-size distributions from samples also indicate that the bed of the Niobrara River among the study reaches coarsens and has increasing grainsize variability in the downstream direction. Values of at-a-station hydraulic geometry exponents indicate that the Niobrara River in the study reaches adjusts its geometry to changing discharges primarily through increases in flow depth and velocity. Relations at one cross section indicated that, at least locally, changes in width were also an important channel adjustment mechanism. Hydraulic behavior over the range of flows measured was not consistent among all study reaches, but two general modes of hydraulic behavior were observed in the reaches with substantial coverage of the bed by fine sediment. At the Sunny Brook and Muleshoe study reaches, average boundary-shear stress remained approximately constant, and hydraulic resistance decreased, for discharges below 900 cubic feet per second (ft 3 /s). Above 900 ft 3 /s, average boundary shear stress and hydraulic resistance both increased. The Rock Barn study reach did not exhibit the same two-mode hydraulic behavior observed at the Sunny Brook and Muleshoe reaches. The coincident increase in boundary shear stress above 900 ft 3 /s observed at the Sunny Brook and Muleshoe study reaches represents a potential hydraulic threshold above which bedload transport rates were likely to increase markedly. No consistent bed-adjustment pattern (scour or fill) was identified in the study reaches over the range of flows or over the measurement season. Analysis of hydraulic microhabitats over the range of discharges measured at the study reaches indicates that some percentage of most habitat niche categories was available for at least one discharge condition, but the majority of hydraulic habitat available was within the intermediate-swift and deepswift habitat niche categories. Deep-swift conditions dominated nearly all study reaches under all measured discharge conditions. Slight differences in habitat distributions were observed between the study reaches with substantial coverage of the bed by fine sediment—Sunny Brook, Muleshoe, and Rock Barn—and the bedrock-dominated reach, Crooked Creek. Although the four study reaches occupy three different hydrogeomorphic segments, the types, relative abundance, and response of hydraulic microhabitat niche distributions to changing discharge conditions generally were similar among all reaches.

Nebraska↗

USGS2022

Early Neoproterozoic gold deposits of the Alto Guaporé province, southwestern Amazon craton, western Brazil

The Alto Guaporé gold province, southwestern Amazon craton, contains gold deposits that have been mined since the beginning of the 18th century and these deposits, together, have modern-day, pre-mining gold resources of at least 1.8 Moz. The ore is associated with quartz vein systems along the southeastern part of the Aguapei belt, a ~35-km-wide and ~500-km-long, NNW-trending shear zone formed due to reactivation of a terrane-bounding suture. The Aguapei belt evolved by ca. 1150 to 1100 Ma rifting and deposition of siliciclastic sediments in an aulacogen basin, followed by deformation and low-grade metamorphism of the sedimentary sequences during 1100 to 900 Ma terrane collision along the craton margin. The deformation was characterized by a compressional regime until ca. 950 Ma and transition to a transpressional setting during the final 50 m.y. The gold deposits are hosted in a variety of structures that are second-order to the main Aguapei shear zone. The Ernesto and Pau-a-Pique deposits are located ~40 km apart and at jogs along the Aguapei belt. They are marginal to pre-ore igneous rocks, with Ernesto hosted in the basal part of the metasedimentary Fortuna Formation that overlies tonalite and Pau-a-Pique at the contact between metasedimentary rocks and diorite. Three deformational phases comprise the compressional (D 1 to D 2 ) to transpressional (D 3 ) tectonic events. In the Pau-a-Pique deposit and the deeper level of the Ernesto deposit, the ore-bearing veins are bedding parallel and follow D 2 strike-slip and reverse fault zones, respectively. However, the veins formed during D 3 reactivation of the older structures by an array of oblique accommodation faults. In contrast, ores at shallower levels of Ernesto, both in discordant and bedding-parallel veins, are hosted within a ~20-m-thick rigid metaconglomerate with associated dilation due to the structural complexity as sedimentary rocks of the Aguapei Group were folded around the dome-shaped roof of the pre-ore tonalite. The ores in both deposits, as well as in many other deposits of the province, are characterized by disseminated and vein-hosted pyrite. Gold occurs mainly as inclusions in the pyrite, with other hydrothermal phases comprising muscovite, Fe-Ti oxides, and minor apatite, chalcopyrite, and galena. Fluid inclusion data, coupled with stable isotope geochemistry and geothermometry, indicate that gold precipitated from a low-salinity, CO 2 -rich fluid at ~300°C and ~2.5 kbar. The source for the fluid and gold was the interbedded pelites during devolatilization of the Aguapei Group sequence. The aqueous-carbonic fluid inclusions and the narrow range of δ 18 O values of quartz (12 ± 1 ‰ ) from many auriferous veins from the central part of the province represent a regional ore-forming fluid. The broad range of δ D for hydrous minerals (–116 to –55 ‰ ) reflects influx of small amounts of meteoric water into the steeply dipping shear zones during postgold exhumation. The 40 Ar/ 39 Ar geochronology from hydrothermal muscovite indicates a widespread hydrothermal event along the belt between 928 and 920 Ma. Collectively, the geological, geochronological, and geochemical data suggest that metamorphic fluids migrated laterally into and then upward along the Aguapei belt and deposited gold in lower-order structures where strain gradients existed between lithounits. The province has many characteristics of large orogenic gold provinces worldwide and represents a highly prospective and underexplored target region for early Neoproterozoic gold, a time period that generally is not well endowed in gold ores.

Alto Guaporé gold province, Amazon craton↗

USGS2014

A reconnaissance spatial and temporal assessment of methane and inorganic constituents in groundwater in bedrock aquifers, Pike County, Pennsylvania, 2012-13

Pike County in northeastern Pennsylvania is underlain by the Devonian-age Marcellus Shale and other shales, formations that have potential for natural gas development. During 2012–13, the U.S. Geological Survey in cooperation with the Pike County Conservation District conducted a reconnaissance study to assess baseline shallow groundwater quality in bedrock aquifers prior to possible shale-gas development in the county. For the spatial component of the assessment, 20 wells were sampled in summer 2012 to provide data on the occurrence of methane and other aspects of existing groundwater quality throughout the county, including concentrations of inorganic constituents commonly present at low levels in shallow, fresh groundwater but elevated in brines. For the temporal component of the assessment, 4 of the 20 wells sampled in summer 2012 were sampled monthly from July 2012 through June 2013 to provide data on seasonal variability in groundwater quality. All water samples were analyzed for major ions, nutrients, selected inorganic trace constituents (including metals and other elements), stable isotopes of water, radon-222, gross alpha- and gross beta-particle activity, dissolved gases (methane, ethane, and ethene), and, if possible, isotopic composition of methane. Additional analyses for boron and strontium isotopes, age-dating of water, and radium-226 were done on water samples collected from six wells in June 2013. Results of the summer 2012 sampling show that water from 16 (80 percent) of 20 wells had detectable concentrations of methane, but concentrations were less than 0.1 milligram per liter (mg/L) in most well-water samples; only two well-water samples had concentrations greater than 1 mg/L. The groundwater with elevated methane also had a chemical composition that differed in some respects (pH, selected major ions, and inorganic trace constituents) from groundwater with low methane concentrations. The two well-water samples with the highest methane concentrations (about 3.7 and 5.8 mg/L) also had the highest pH values (8.7 and 8.3, respectively) and the highest concentrations of sodium, lithium, boron, fluoride, and bromide. Elevated concentrations of some other constituents, such as barium, strontium, and chloride, were not limited to well-water samples with elevated methane, although the two samples with elevated methane also had among the highest concentrations of these constituents. One sample with elevated methane concentrations also had elevated arsenic concentrations, with the arsenic concentration of 30 micrograms per liter (μg/L) exceeding the drinking-water standard of 10 µg/L for arsenic. No other sample from the 20 wells sampled in summer 2012 had concentrations of constituents that exceeded any established primary drinking-water standards. However, radon-222 activities ranging up to 4,500 picocuries per liter (pCi/L) exceeded the proposed drinking-water standard of 300 pCi/L in 85 percent of the 20 well-water samples. The isotopic composition methane in the two high-methane samples (δC CH4 values of -64.55 and -64.41 per mil and δD CH4 values of -216.9 and -201.8 per mil, respectively) indicates a predominantly microbial source for the methane formed by a carbon dioxide reduction process. The stable isotopic composition of water (δD H20 and δ 18 O H20 ) in samples from all 20 wells falls on the local meteoric line, indicating water in the wells was of relatively recent meteoric origin (modern precipitation), including samples with elevated methane concentrations. Analytical results for 4 of the 20 wells sampled monthly for 1 year ending June 2013 in order to assess temporal variability in groundwater quality show that concentrations of major ions generally varied by less than 20 percent, with most differences less than 4 mg/L. Concentrations of methane varied by less than 1 μg/L (0.001 mg/L) in samples from three wells with low methane and by as much as 1 mg/L (1,000 μg/L) in samples from one well with relatively high methane. The isotopic composition of methane in the one well with relatively high methane varied slightly in the monthly samples, ranging from about -64.5 to -64.8 per mil for δ 13 C CH4 and from about -217 to -228 per mil for δD CH4 . The δ 13 C values for dissolved inorganic carbon (DIC) in water from this well were consistent with microbial methane formation by carbon dioxide reduction (drift-type methane) and varied little in the temporal samples, ranging from -10.5 to -10.1 per mil. Additional analyses of samples collected in late June 2013 from six wells with a range of methane and trace constituent concentrations provided baseline data on strontium and boron isotopic compositions ( 87 Sr/ 86 Sr ratios and δ 11 B, respectively) that potentially may be used to differentiate among sources of these constituents. The strontium and boron isotopic composition determined in the six shallow Pike County groundwater samples had 87 Sr/ 86 Sr ratios of 0.71426 to 0.71531 and δ 11 B values of 11.7 to 27.0 per mil, which differ from those reported for brines in Devonian-age formations in Pennsylvania. The June 2013 samples were also analyzed for radium-226 and age-dating dissolved gases. Activities of radium-226 ranged from 0.041 to 0.29 pCi/L in water samples from the six wells and were less than the drinking-water standard of 5 pCi/L for combined radium-226 and radium-228. Age-dating of groundwater using a method based on the presence of anthropogenic gases (chlorofluorocarbons and sulfur hexafluoride) released into the atmosphere yielded estimated recharge dates for water from these six wells that ranged from the 1940s to early 2000s. The oldest water was in samples from wells that had the highest methane concentrations and the youngest water was in samples from a continuously pumped 300-foot deep production well.

Pennsylvania↗

USGS1971

A geochemical hypothesis for dolomitization by ground water

Most modern disordered dolomite has been found in dynamic environments. However, solutions associated with modern dolomite formation do not have a common Mg/Ca ratio; the ratio ranges from about 3 to 100. Ground-water circulation may have a significant role in formation of regional dolomites; one of the primary requirements for regional dolomite formation is a large supply of magnesium ions. An X-ray study of well cuttings from the Tertiary limestone aquifer of central Florida indicates that it is composed primarily of calcite and dolomite with minor amounts of quartz and apatite. The magnesium content of the calcite is slightly lower (0-2 percent MgC03) in the recharge areas than in the deeper confined parts of the aquifer system (2-4 percent MgC03). Our data support other recent work and indicate an equilibrium constant for dolomite of 2 X 10-17. Inasmuch as this value is exactly the square of the calcite equilibrium constant (10~8-35), the Mg/Ca ratio must be unity for the three-phase equilibrium, calcite-dolomite-water. The Mg/Ca ratio in water from the aquifer is as low as 0.05 in the recharge area where the water is also undersaturated with respect to both calcite and dolomite. With time and length of travel path in the system, the water increases systematically in Mg/Ca ratio, which approaches unity; saturation with respect to the two carbonates also increases downgradient until the solution apparently becomes over-saturated with respect to both carbonates. In Tertiary limestones of the Yucatan Peninsula, the Mg/Ca range in water is similar to that for Florida. The small amount of magnesium available from the solution of magnesium calcites and dolomite in the potable zone of active circulation is insufficient to provide the amount required for extensive dolomitization unless enormous quantities of rock are available for dissolution. However, dolomite may be forming in the zones of brackish water that underlie the Florida and Yucatan Peninsulas. The required magnesium may be derived from the readily available ocean water or reflux brines as the hydrologic regimen is changed because of relative fluctuations of sea level.

Florida↗

USGS1989

Studies of geology and hydrology in the Basin and Range Province, Southwestern United States, for isolation of high-level radioactive waste - Basis of characterization and evaluation

The geologic and hydrologic factors in selected regions of the Basin and Range province were examined to identify prospective areas for further study that may provide isolation of high-level radioactive waste from the accessible environment. The six regions selected for study were characterized with respect to the following guidelines: (1) Potential repository media; (2) Quaternary tectonic conditions; (3) climatic change and geomorphic processes; (4) ground-water conditions; (5) ground-water quality; and (6) mineral and energy resources. The repository medium will function as the first natural barrier to radionuclide travel by virtue of associated slow ground-water velocity. The principal rock types considered as host media include granitic, intermediate, and mafic intrusive rocks; argillaceous rocks; salt and anhydrite; volcanic mudflow (laharic) breccias; some intrusive rhyolitic plugs and stocks; partially zeolitized tuff; and metamorphic rocks. In the unsaturated zone, the permeability and hydrologic properties of the rocks and the hydrologic setting are more important than the rock type. Media ideally should be permeable to provide drainage and should have a minimal water flux The ground-water flow path from a repository to the accessible environment needs to present major barriers to the transport of radionuclides. Factors considered in evaluating the ground-water conditions include ground-water traveltimes and quality, confining beds, and earth materials favorable for retardation of radionuclides. Ground-water velocities in the regions were calculated from estimated hydraulic properties of the rocks and gradients. Because site-specific data on hydraulic properties are not available, data from the literature were assembled and synthesized to obtain values for use in estimating ground-water velocities. Hydraulic conductivities for many rock types having granular and fracture permeability follow a log-normal distribution. Porosity for granular and very weathered crystalline rock tends to be normally distributed; porosity of fractured crystalline rock probably follows a log-normal distribution. The tectonic setting needs to prevent an increase in radionuclides to the accessible environment. Data on historic seismicity and heat flow, Quaternary faults, volcanism, and uplift were used to assess the tectonic conditions. Long-term late Cenozoic rates of vertical crustal movement in the Basin and Range province range from less than 2 meters per 104 years to greater than 20 meters per 104 years. Shortterm rates of vertical movement may be more than an order of magnitude greater, based on geodetic leveling. Changes in tectonic and climatic processes may potentially cause changes in hydrologic conditions and geomorphology that could affect the integrity of a deep, mined repository either adversely or beneficially. The transition from a full-glacial climate to the current interglacial condition has occurred within the past 15,000 years. Reconstructions of the last full-glacial climate indicate that, at that time, there was greater water availability for runoff and vegetation growth than there is now. Based on the increased water availability and depending on seasonal distribution of precipitation, on soil characteristics, on topography, and on other characteristics, ground-water recharge during the full-glacial climate is estimated to have been possibly 2 to 10 or more times the modern rate. During the full-glacial climate, more than 100 lakes occupied closed basins in the province. Any increase in ground-water recharge and refilling of Pleistocene lakes will tend to decrease the distance of ground-water flow and its time of travel. The unsaturated zone this zone is considered a potential host medium where the thickness is greater than 150 m will be decreased by these changes. In contrast, incision of streams and other geomorphic, tectonic, or climatically induced changes that lower the ground-water discharge level will tend to increase the thickness of the unsaturated zone. Aggradation in basinal troughs may either decrease or increase the thickness of the unsaturated zone. Aggradation in basins that causes the ground-water discharge level to rise will tend to decrease the thickness of unsaturated zone in the adjacent uplands; aggradation in basins where the ground-water discharge level remains the same or is lowered will increase the unsaturated thickness of basin fill. Records show that, throughout late Cenozoic time in the Basin and Range province, continued vertical crustal movements have tended to maintain mountain ranges and closed basins, whereas aggradation of the basins and erosion of the mountain ranges have tended to decrease the topographic relief. Maximum rates of denudation for small basins in areas climatically similar to the Basin and Range province are about 2 meters per 104 years. For sites unaffected by stream incision and scarp retreat, a conservative estimate of erosion affecting long-term changes in depth of burial would appear to be 2 meters per 104 years, or, equal to the long-term rate of vertical crustal movement where greater than 2 meters per 104 years. The response of the ground-water conditions to climatic and geomorphically induced boundary conditions is significant from the points of: (1) The potential maximum change in the ground-water flow system; (2) the time of response of the ground-water system; and (3) the present state of the ground-water system as a result of past changes. Effects of longterm climatic and tectonic changes on hydrologic and geomorphic conditions differ from area to area, and rates of change of geomorphic and hydrologic conditions may vary significantly. Therefore, sitespecific studies need to be made to assess the long-term integrity of deep, mined repositories.

Arizona, California, Idaho, Nevada, New Mexico, Te↗

USGS2003

Sediment-starved sand ridges on a mixed carbonate/siliciclastic inner shelf off west-central Florida

High-resolution side-scan mosaics, sediment analyses, and physical process data have revealed that the mixed carbonate/siliciclastic, inner shelf of west-central Florida supports a highly complex field of active sand ridges mantled by a hierarchy of bedforms. The sand ridges, mostly oriented obliquely to the shoreline trend, extend from 2 km to over 25 km offshore. They show many similarities to their well-known counterparts situated along the US Atlantic margin in that both increase in relief with increasing water depth, both are oriented obliquely to the coast, and both respond to modern shelf dynamics. There are significant differences in that the sand ridges on the west-central Florida shelf are smaller in all dimensions, have a relatively high carbonate content, and are separated by exposed rock surfaces. They are also shoreface-detached and are sediment-starved, thus stunting their development. Morphological details are highly distinctive and apparent in side-scan imagery due to the high acoustic contrast. The seafloor is active and not a relict system as indicated by: (1) relatively young AMS 14C dates (< 1600 yr BP) from forams in the shallow subsurface (1.6 meters below seafloor), (2) apparent shifts in sharply distinctive grayscale boundaries seen in time-series side-scan mosaics, (3) maintenance of these sharp acoustic boundaries and development of small bedforms in an area of constant and extensive bioturbation, (4) sediment textural asymmetry indicative of selective transport across bedform topography, (5) morphological asymmetry of sand ridges and 2D dunes, and (6) current-meter data indicating that the critical threshold velocity for sediment transport is frequently exceeded. Although larger sand ridges are found along other portions of the west-central Florida inner shelf, these smaller sand ridges are best developed seaward of a major coastal headland, suggesting some genetic relationship. The headland may focus and accelerate the N-S reversing currents. An elevated rock terrace extending from the headland supports these ridges in a shallower water environment than the surrounding shelf, allowing them to be more easily influenced by currents and surface gravity waves. Tidal currents, storm-generated flows, and seasonally developed flows are shore-parallel and oriented obliquely to the NW-SE trending ridges, indicating that they have developed as described by the Huthnance model. Although inner shelf sand ridges have been extensively examined elsewhere, this study is the first to describe them in a low-energy, sediment-starved, dominantly mixed siliciclastic/carbonate sedimentary environment situated on a former limestone platform. ?? 2003 Elsevier B.V. All rights reserved.

Florida↗

USGS1993

The analysis of forms of sulfur in ancient sediments and sedimentary rocks: comments and cautions

Assumptions commonly made during analysis of the amount of monosulfides [acid-volatile sulfides (AVS)] and disulfides in modern sediments, may not be valid for ancient sedimentary rocks. It is known that ferric iron can oxidize H2S during AVS analysis unless a reducing agent such as stannous chloride is added to the treatment. In addition, some monosulfides such as greigite and pyrrhotite require heat during the AVS analysis in order to dissolve completely. However, the use of heat and/or stannous chloride in the AVS treatment may partially dissolve disulfides and it is generally recommended that stannous chloride not be used in the AVS treatment for modern sediments. Most of the monosulfides are assumed to be recovered as AVS without the addition of stannous chloride. This study investigates the recovery of monosulfides during sulfur speciation analysis with application to ancient sedimentary rocks. Sulfur in samples containing naturally occurring greigite and mackinawite or pyrite was measured using variations of a common sulfur-speciation scheme. The sulfur-speciation scheme analyzes for monosulfide sulfur, disulfide sulfur, elemental sulfur, inorganic sulfate and organically bound sulfur. The effects of heat, stannous chloride and ferric iron on the amounts of acid-volatile sulfide and disulfide recovered during treatment for AVS were investigated. Isotopic compositions of the recovered sulfur species along with yields from an extended sulfur-speciation scheme were used to quantify the effects. Hot 6 N HCl AVS treatment recovers > 60% of the monosulfides as AVS in samples containing pure greigite and mackinawite. The remaining monosulfide sulfur is recovered in a subsequent elemental sulfur extraction. Hot 6 N HCl plus stannous chloride recovers 100% of the monosulfides as AVS. The addition of ferric iron to pure greigite and mackinawite samples during AVS treatment without stannous chloride decreased the amount of monosulfides recovered as AVS and, if present in great enough concentration, oxidized some of the AVS to a form not recovered in later treatments. The hot stannous chloride AVS treatments dissolve <5% of well-crystallized pyrite in this study. The amount of pyrite dissolved depends on grain size and crystallinity. Greigite in ancient sedimentary rocks was quantitatively recovered as AVS only with hot 6 N HCl plus stannous chloride. Hot 6 N HCl AVS treatment of these rocks did not detect any monosulfides in most samples. A subsequent elemental sulfur extraction did not completely recover the oxidized monosulfides. Therefore, the use of stannous chloride plus heat is recommended in the AVS treatment of ancient sedimentary rocks if monosulfides are present and of interest. All assumptions about the amount of monosulfides and disulfides recovered with the sulfur-speciation scheme used should be verified by extended sulfur-speciation and/or isotopic analysis of the species recovered. ?? 1993.

Chemical Geology↗

USGS2014

Hydrogeology and hydrology of the Punta Cabullones wetland area, Ponce, southern Puerto Rico, 2007-08

The U.S. Geological Survey, in cooperation with the Municipio Autónomo de Ponce and the Puerto Rico Department of Natural and Environmental Resources, conducted a study of the hydrogeology and hydrology of the Punta Cabullones area in Ponce, southern Puerto Rico. (Punta Cabullones is also referred to as Punta Cabullón.) The Punta Cabullones area is about 9 square miles and is an ecological system made up of a wetland, tidal flats, saltflats, mangrove forests, and a small fringing reef located a short distance offshore. The swales or depressions between successive beach ridges became development avenues for saline to hypersaline wetlands. The Punta Cabullones area was designated by the U.S. Fish and Wildlife Service as a coastal barrier in the 1980s because of its capacity to act as a buffer zone to ameliorate the impacts of natural phenomenon such as storm surges. Since 2003, Punta Cabullones has been set aside for preservation as part of the mitigation effort mandated by Federal and State laws to compensate for the potential environmental effects that might be caused by the construction of the Las Américas Transshipment Port. Total rainfall measured during 2008 within the Punta Cabullones area was 36 inches, which is slightly greater than the long-term annual average of 32 inches for the coastal plain near Ponce. Two evapotranspiration estimates, 29 and 37 inches, were obtained for the subarea of the Punta Cabullones area that is underlain by fan-delta and alluvial deposits by using two variants of the Penman semi-empirical equation. The long-term water stage and chemical character of the wetland in Punta Cabullones are highly dependent on the seasonal and annual variations of both rainfall and sea-wave activity. Also, unseasonal short-term above-normal rainfall and sea-wave events resulting from passing storms may induce substantial changes in the water stage and the chemical character of the wetland. In general, tidal fluctuations exert a minor role in modifying the water quality and stage of the wetland in Punta Cabullones. The role of the tidal fluctuations becomes important during those times when the outlets/inlets to the sea are not blocked by a sand bar and is allowed to freely flow into the wetland interior. The salinity of the wetland varies from brackish to hypersaline. The hypersaline conditions, including the occurrence of saltflats, within the Punta Cabullones wetland area result from a high evapotranspiration rate. The hypersaline conditions are further enhanced by a sand bar that blocks the inlet/outlet of the wetland’s easternmost channel, particularly during the dry season. Groundwater in Punta Cabullones mostly is present within beds of silisiclastic sand and gravel. During the study period, the depth to groundwater did not exceed 4 feet below land surface. The movement and direction of the groundwater flow in Punta Cabullones are driven by density variations that in turn result from the wide range of salinities in the groundwater. The salinity of the groundwater decreases within the first 60 to 100 feet of depth and decreases outward from a mound of hypersaline groundwater centered on piezometer nest PN2. The main groundwater types within the Punta Cabullones area vary from calcium-bicarbonate type in the northernmost part of the study area to a predominantly sodium-potassium-chloride groundwater type southward. According to stable-isotope data, groundwater within the study area is both modern meteoric water and seawater highly affected by evaporation. The chemical and stable-isotopic character of local groundwater is highly influenced by evapotranspiration because of its shallow depth. Equivalent freshwater heads indicate groundwater moves away from a mound centered on piezometer nest PN2, in a pattern similar to the spatial distribution of groundwater salinity. Vertical groundwater flow occurs in Punta Cabullones due to local differences in density. In the wetland subarea of Punta Cabullones, groundwater and surface water are hydraulically coupled. Locally, surface-hypersaline water sinks into the aquifer, providing recharge and serving as a mechanism to redistribute salt throughout the study area. The evapotranspiration in the wetland subarea is estimated at about 11 million gallons per day (Mgal/d) that is equivalent to about 12,586 acre-feet per year. The balance of evapotranspiration, in excess of the about 0.5 Mgal/d of groundwater flow within the wetland, is supplied by saline to hypersaline surface water that may include seawater and meteoric water highly affected by evaporation with dissolved salts. In one of the extreme scenarios in which no groundwater is intercepted by pumpage at the Restaurada well field, the amount of saline to hypersaline water in the wetland consumed by evapotranspiration is about 10.5 Mgal/d. In the opposite extreme in which the entire regional groundwater flow is intercepted by pumpage in the Restaurada well field, the entire evapotranpiration requirement is met by saline to hypersaline water. Hydrologic, isotopic, and chemical data indicate that all of, or a large portion of, the historical groundwater flow to Punta Cabullones is being captured by the Puerto Rico Aqueducts and Sewer Authority pumpage at the Restaurada well field at a rate of about 2 Mgal/d. As a consequence, seawater intrusion into the aquifer at the Punta Cabullones area seems to be occurring, while the current pumpage at the Restaurada well field is sustained by storage depletion of the aquifer.

Puerto Rico↗