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At least 973 records · Page 54Linked to original sources

Viking landing sites, remote-sensing observations, and physical properties of Martian surface materials

Important problems that confront future scientific exploration of Mars include the physical properties of Martian surface materials and the geologic processes that formed the materials. The design of landing spacecraft, roving vehicles, and sampling devices and the selection of landing sites, vehicle traverses, and sample sites will be, in part, guided by the physical properties of the materials. Four materials occur in the sample fields of the Viking landers: (1) drift, (2) crusty to cloddy, (3) blocky, and (4) rock. The first three are soillike. Drift materials is weak, loose, and porous. We estimate that it has a dielectric constant near 2.4 and a thermal inertia near 1 × 10 −3 to 3 × 10 −3 ( cal cm −2 sec 1 2 K −1 ) "> 1 × 10 −3 to 3 × 10 −3 (cal cm −2 sec 12 K −1 ) because of its low bulk density, fine grain size, and small cohesion. Crusty to cloddy material is expected to have a dielectric constant near 2.8 and a thermal inertia near 4 × 10 −3 to 7 × 10 −3 because of its moderate bulk density and cementation of grains. Blocky material should have a dielectric constant near 3.3 and a thermal inertia near 7 × 10 −3 to 9 × 10 −3 because of its moderate bulk density and cementation. Common basaltic rocks have dielectric constants near 8 and thermal inertias near 30 × 10 −3 to 60 × 10 −3 . Comparisons of estimated dielectric constants and thermal inertias of the materials at the landing sites with those obtained remotely by Earth-based radars and Viking Orbiter thermal sensors suggest that the materials at the landing sites are good analogs for materials elsewhere on Mars. Correlation of remotely estimated dielectric constant and thermal inertias indicates two modal values for paired values of dielectric constants and thermal inertias near (A) 2 and 2 × 10 −3 and (B) 3 and 6 × 10 −3 , respectively. These two modes are comparable to the dielectric constants and thermal inertias for drift and crusty to cloddy material, respectively. Dielectric constants and thermal inertias for blocky material are larger but consistent with values in the northern plains. Our interpretations are compatible with an aeolian origin for drift and similar materials elsewhere on Mars. The postulate that moderate dielectric constants and thermal inertias larger than 3 or 4 × 10 −3 are produced by cementation of soillike materials is partly consistent with the data. The average dielectric constant and thermal inertia and their correlation with one another suggest that most of the surface of Mars should present few difficulties to future surface exploration, but some surfaces may present difficulties for spacecraft that are not suitably designed.

Icarus↗

Triton's surface-atmosphere energy balance

We explore the energetics of Triton's surface-atmosphere system using a model that includes the turbulent transfer of sensible heat as well as insolation, reradiation, and latent heat transport. The model relies on a 1° by 1° resolution hemispheric bolometric albedo map of Triton for determining the atmospheric temperature, the N 2 frost emissivity, and the temperatures of unfrosted portions of the surface consistent with a frost temperature of ≅38 K. For a physically plausible range of heat transfer coefficients, we find that the atmospheric temperature roughly 1 km above the surface is approximately 1 to 3 K hotter than the surface. Atmospheric temperatures of 48 K suggested by early analysis of radio occultation data cannot be obtained for plausible values of the heat transfer coefficients. Our calculations indicate that Triton's N 2 frosts must have an emissivity well below unity in order to have a temperature of ≅38 K, consistent with previous results. We also find that convection over small hot spots does not significantly cool them off, so they may be able to act as continous sources of buoyancy for convective plumes, but have not explored whether the convection is vigorous enough to entrain particulate matter thereby forming a dust devil. Our elevated atmospheric temperatures make geyser driven plumes with initial upward velocities ≤10 m s −1 stagnate in the lower atmosphere. These “wimpy” plumes provide a possible explanation for Triton's “wind streaks.”

Icarus↗

On the nature of persistence in dendrochronologic records with implications for hydrology

Hydrologic processes are generally held to be persistent and not secularly independent. Impetus for this view was given by Hurst in his work which dealt with properties of the rescaled range of many types of long geophysical records, in particular dendrochronologic records, in addition to hydrologic records. Mandelbrot introduced an infinite memory stationary process, the fractional Gaussian noise process (F), as an explanation for Hurst's observations. This is in contrast to other explanations which have been predicated on the implicit non-stationarity of the process underlying the construction of the records. In this work, we introduce a stationary finite memory process which arises naturally from a physical concept and show that it can accommodate the persistence structures observed for dendrochronological records more successfully than an F or any other of a family of related processes examined herein. Further, some question arises as to the empirical plausibility of an F process. Dendrochronologic records are used because they are widely held to be surrogates for records of average hydrologic phenomena and the length of these records allows one to explore questions of stochastic process structure which cannot be explored with great validity in the case of generally much shorter hydrologic records.

Journal of Hydrology↗

Metal stable isotopes in weathering and hydrology

This chapter highlights some of the major developments in the understanding of the causes of metal stable isotope compositional variability in and isotope fractionation between natural materials and provides numerous examples of how that understanding is providing new insights into weathering and hydrology. At this stage, our knowledge of causes of stable isotope compositional variability among natural materials is greatest for the metals lithium, magnesium, calcium, and iron, the isotopes of which have already provided important information on weathering and hydrological processes. Stable isotope compositional variability for other metals such as strontium, copper, zinc, chromium, barium, molybdenum, mercury, cadmium, and nickel has been demonstrated but is only beginning to be applied to questions related to weathering and hydrology, and several research groups are currently exploring the potential. And then there are other metals such as titanium, vanadium, rhenium, and tungsten that have yet to be explored for variability of stable isotope composition in natural materials, but which may hold untold surprises in their utility. This impressive list of metals having either demonstrated or potential stable isotope signals that could be used to address important unsolved questions related to weathering and hydrology, constitutes a powerful toolbox that will be increasingly utilized in the coming decades.

Book chapter↗

Chemical mixtures in potable water in the U.S.

In recent years, regulators have devoted increasing attention to health risks from exposure to multiple chemicals. In 1996, the US Congress directed the US Environmental Protection Agency (EPA) to study mixtures of chemicals in drinking water, with a particular focus on potential interactions affecting chemicals' joint toxicity. The task is complicated by the number of possible mixtures in drinking water and lack of toxicological data for combinations of chemicals. As one step toward risk assessment and regulation of mixtures, the EPA and the Agency for Toxic Substances and Disease Registry (ATSDR) have proposed to estimate mixtures' toxicity based on the interactions of individual component chemicals. This approach permits the use of existing toxicological data on individual chemicals, but still requires additional information on interactions between chemicals and environmental data on the public's exposure to combinations of chemicals. Large compilations of water-quality data have recently become available from federal and state agencies. This chapter demonstrates the use of these environmental data, in combination with the available toxicological data, to explore scenarios for mixture toxicity and develop priorities for future research and regulation. Occurrence data on binary and ternary mixtures of arsenic, cadmium, and manganese are used to parameterize the EPA and ATSDR models for each drinking water source in the dataset. The models' outputs are then mapped at county scale to illustrate the implications of the proposed models for risk assessment and rulemaking. For example, according to the EPA's interaction model, the levels of arsenic and cadmium found in US groundwater are unlikely to have synergistic cardiovascular effects in most areas of the country, but the same mixture's potential for synergistic neurological effects merits further study. Similar analysis could, in future, be used to explore the implications of alternative risk models for the toxicity and interaction of complex mixtures, and to identify the communities with the highest and lowest expected value for regulation of chemical mixtures.

Book chapter↗

Sea otter-mediated linkages among oceanic, nearshore, and terrestrial ecosystems

Seemingly distinct ecological communities are often linked by both direct and indirect interactions that can be difficult to discern. A widely recognized interecosystem linkage is the transfer of marine-derived nutrients to terrestrial systems via anadromous fish. In this chapter, we explore other linkages that move marine-derived nutrients between ocean and terrestrial ecosystems, focusing on the role of nearshore marine ecosystems . Through oceanic nutrients and biomass that originate from phytoplankton, and nearshore nutrients and biomass that derive mainly from macroalgae, there are multiple pathways to subsidize terrestrial ecosystems. We discuss various pathways identified through multiple independent studies and explore how those subsidies may be related to sea otter presence. Recovery of sea otters and subsequent changes to nearshore communities, for example, changes in kelp, invertebrate and vertebrate abundance, and diversity, may in turn influence coastal terrestrial ecosystems and species including bears, wolves, foxes, river otters, shorebirds, and other consumers. As offshore oceanic productivity declines globally, we ask how the return of the sea otter reinvigorates diminished and lost linkages between marine and terrestrial environments through direct predator–prey linkages, and indirectly through the enhancement of the nearshore marine environment.

Book chapter↗

Pleistocene Lake Bonneville as an analog for extraterrestrial lakes and oceans

Geomorphic confirmation for a putative ancient Mars ocean relies on analog comparisons of coastal-like features such as shoreline feature attributes and temporal scales of process formation. Pleistocene Lake Bonneville is one of the few large, geologically young, terrestrial lake systems that exemplify well-preserved shoreline characteristics that formed quickly, on the order of a thousand years or less. Studies of Lake Bonneville provide two essential analog considerations for interpreting shorelines on Mars: (1) morphological variations in expression depend on constructional vs erosional processes, and (2) shorelines are not always correlative at an equipotential elevation across a basin due to isostasy, heat flow, wave setup, fetch, and other factors. Although other large terrestrial lake systems display supporting evidence for geomorphic comparisons, Lake Bonneville encompasses the most integrated examples of preserved coastal features related to basin history, sediment supply, climate, and fetch, all within the context of a detailed hydrograph. These collective terrestrial lessons provide a framework to evaluate possible boundary conditions for ancient Mars hydrology and large water body environmental feedbacks. This knowledge of shoreline characteristics, processes, and environments can support explorations of habitable environments and guide future mission explorations.

Book chapter↗

The influence of floral resources and microclimate on pollinator visitation in an agro-ecosystem

As agriculture expands to meet the needs of a growing global population, natural ecosystems are threatened by deforestation and habitat fragmentation. Tropical agroforestry systems offer a sustainable alternative to traditional agriculture by providing food for production while also supporting biodiversity and ecosystem services. Previous studies have shown that these systems may even improve crop pollination, but the mechanisms of how these improvements occur are still poorly understood. Using coffee as a focal crop, we explored how microclimatic conditions affected nectar traits (sugar and caffeine concentration) important for pollinator visitation. We also studied how microclimate, floral traits, floral availability at the coffee plant level, availability of floral resources provided by other plant species in the agroecosystem (neighborhood floral availability), and the presence of other bees affected the amount of time bees spent foraging on coffee flowers and the proportion of coffee pollen carried on their bodies. We explored these factors using the two dominant coffee species farmed on Puerto Rico, Coffea canephora and C. arabica , under sun and shade management. We found that high nectar sugar concentration and temperature were important predictors of short floral visits (<15 seconds), while increased number of bees and open coffee flowers were important predictors of longer floral visits (16-180 seconds). High nectar caffeine concentration was an important predictor of longer visits on C. arabica flowers while the opposite was observed for C. canephora flowers. For both species, high coffee floral availability was the main predicting factor for the proportion of coffee pollen on the bees bodies. Surprisingly, neither neighborhood floral availability nor the type of coffee plantation (agroforest/shade or sun) were important predictors of bee visitation. These results suggest non-coffee flowering plants in coffee plantations were neither competitors nor facilitators of coffee plantes for pollinators. Additionally, most of the bees surveyed were carrying 80% pollen from one species ( C. arabica or C. canephora ), likely resulting in little heterospecific pollen deposition between Coffea and non-Coffea flowers. Shade trees in coffee plantations do not detract from pollinator visitation to coffee flowers, suggesting that the provision of multiple ecological and wildlife conservation benefits by shade trees is not in conflict with a growers ability to maximize the benefits of insect pollination on fruit production.

Adjuntas Lares,Las Marias, Maricao, Puerto Rico Ut↗

Climate change and human health: Spatial modeling of water availability, malnutrition, and livelihoods in Mali, Africa

This study develops a novel approach for projecting climate trends in the Sahel in relation to shifting livelihood zones and health outcomes. Focusing on Mali, we explore baseline relationships between temperature, precipitation, livelihood, and malnutrition in 407 Demographic and Health Survey (DHS) clusters with a total of 14,238 children, resulting in a thorough spatial analysis of coupled climate-health dynamics. Results suggest links between livelihoods and each measure of malnutrition, as well as a link between climate and stunting. A ‘front-line’ of vulnerability, related to the transition between agricultural and pastoral livelihoods, is identified as an area where mitigation efforts might be usefully targeted. Additionally, climate is projected to 2025 for the Sahel, and demographic trends are introduced to explore how the intersection of climate and demographics may shift the vulnerability ‘front-line’, potentially exposing an additional 6 million people in Mali, up to a million of them children, to heightened risk of malnutrition from climate and livelihood changes. Results indicate that, holding constant morbidity levels, approximately one quarter of a million children will suffer stunting, nearly two hundred thousand will be malnourished, and over one hundred thousand will become anemic in this expanding arid zone by 2025. Climate and health research conducted at finer spatial scales and within shorter projected time lines can identify vulnerability hot spots that are of the highest priority for adaptation interventions; such an analysis can also identify areas with similar characteristics that may be at heightened risk. Such meso-scale coupled human-environment research may facilitate appropriate policy interventions strategically located beyond today’s vulnerability front-line.

Applied Geography↗

Probabilities of detecting submersed aquatic vegetation species using a rake method may vary with biomass

Levels of submersed aquatic vegetation (SAV) are commonly assessed using a modified garden rake. However, the utility of the rake sampling method relative to methods that are typically viewed as more definitive (and expensive) such as snorkeling and coring remains a matter of debate. This study explores whether probabilities of species detections for four SAV species varied among sampling units in a rake-biomass study and, if so, whether such variation reflected variation in species abundance. Variation in detection probabilities, when unaddressed, may yield biased estimators of percent frequency of occurrence (“occupancy”) and of occurrence-habitat associations. Biomass-driven variation in detection probabilities is important because such variation may not be explainable using covariates typically measured when sampling using the rake method. This study found substantial among-unit variation in detection probabilities, with majorities of that variation on the logit or modeling scale being associated with biomass but not with the non-biomass covariates substrate type, water depth and day of study. The study closes by exploring sampling protocols and modeling methods that may yield improved SAV occupancy estimates.

Aquatic Botany↗

Predicted connectivity pathways between grizzly bear ecosystems in western Montana

Habitat and corridor mapping are key components of many conservation programs. Grizzly bear populations in the continental US are fragmented and connectivity among federal recovery areas is a conservation goal. Building on recent work, we modeled movements to predict areas of connectivity, using integrated step selection functions (iSSFs) developed from GPS-collared grizzly bears (F = 46, M = 19) in the Northern Continental Divide Ecosystem (NCDE). We applied iSSFs in a >300,000 km 2 area including the NCDE, Cabinet–Yaak (CYE), Bitterroot (BE), and Greater Yellowstone (GYE) Ecosystems. First, we simulated directed movements (randomized shortest paths with 3 levels of exploration) between start and end nodes across populations. Second, we simulated undirected movements from start nodes in the NCDE, CYE, or GYE (no predetermined end nodes). We summarized and binned results as classes 1 (lowest relative predicted use) – 10 (highest relative predicted use) and evaluated predictions using 127 outlier grizzly bear locations. Connectivity pathways were primarily associated with mountainous areas and secondarily with river and stream courses in open valleys. Values at outlier locations indicated good model fit and mean classes at outlier locations (≥7.4) and Spearman rank correlations (≥0.87) were highest for undirected simulations and directed simulations with the highest level of exploration. Our resulting predictive maps can facilitate on-the-ground application of this research for prioritizing habitat conservation, human-bear conflict mitigation, and transportation planning. Additionally, our overall modeling approach has utility for myriad species and conservation applications.

Montana↗

Isotopic characterization of late Neogene travertine deposits at Barrancas Blancas in the eastern Atacama Desert, Chile

Here we explore the potential of spring-related, surface and subsurface carbonates as an archive of paleoenvironmental change at Barrancas Blancas, located in the broadest and driest sector of the Atacama Desert at 24.5°S. From these deposits we present a new stable isotopic record of paleoenvironmental conditions over portions of the past ~ 11.5 Ma. U-Pb dates from the carbonates, both surface and subsurface, demonstrate that springs have discharged at this location over much of the last 11.5 Ma, attesting to the exceptional geomorphic stability of the central Atacama. Many of the sampled vein systems line vertical fissures, and formed within the aquifer before groundwater discharged at the surface. Carbonates in such circumstances should not undergo off-gassing and kinetic fractionation prior to formation, simplifying the interpretation of their isotopic composition. Oxygen isotopic compositions of carbonates are generally high (>− 5‰VPDB), and using paleospring water temperatures of 3–13 °C reconstructed from clumped isotopes, point to strongly (up to 50%) evaporated water isotope values, like those associated with the hyperarid core of the Atacama Desert today. Carbon isotopic compositions are also high (≥+3‰ PDB), reflecting a recharge area essentially devoid of plants and dominated by volcanic CO 2 , as is the case today. Our isotopic results are very similar to those from the Calama Basin to the north, suggesting that the western face of the Andes between 21 and 25°S has been highly evaporative and nearly plantless when these springs discharged over the last 11.5 Ma. The spring carbonates at Barrancas Blancas strongly resemble those found at Devils Hole and Furnace Creek in Death Valley, USA, and as such warrant further exploration as potential archives of climate change.

Atacama Desert↗

The petrology of dispersed organic matter in sedimentary rocks: Review and update

Organic petrology developed from coal petrology, and, in the 1960s, it began to be applied to the study of dispersed organic matter (DOM) in sedimentary rocks other than coal. Over the last few decades, the petrology of DOM has been used to characterize organic matter in sedimentary basins with an emphasis on fossil fuel resource exploration. Today, due to the global research shift on topics related to climate, organic petrology has expanded into new application areas, such as geothermal exploration, biological carbon storage (biochar), disposal, and management of radioactive waste. From the publication of the International Handbook of Coal Petrology (mid-20th century) to the present day, a large number of standards, books, and articles have been published as a result of the work of organic petrographers and petrologists around the world and efforts of the International Committee for Coal and Organic Petrology (ICCP) and The Society for Organic Petrology (TSOP) to promote the study of organic petrology. The current fundamentals and standards of organic petrology provide the international scientific community with well-informed guidance and recommendations to promote in-depth research. However, this information is currently widely scattered, leading to discrepancies in methodology and terminology. Therefore, this paper aims to present a comprehensive review of the main analytical standard test methods and techniques currently used in the petrology of DOM under reflected white light and UV and blue-light excitation, and to provide an efficient and well-defined reference guide. Furthermore, considering the important role of the ICCP in the development of organic petrology since the 1950s, a brief review of the ongoing activities of ICCP dealing with DOM is also presented.

International Journal of Coal Geology↗

The influence of shelf bathymetry and beach topography on extreme total water levels: Linking large-scale changes of the wave climate to local coastal hazards

Total water levels (TWLs) at the coast are driven by a combination of deterministic (e.g., tides) and stochastic (e.g., waves, storm surge, and sea level anomalies) processes. The contribution of each process to TWLs varies depending on regional differences in climate and framework geology, as well as local-scale variations in beach morphology, coastal orientation, and shelf bathymetry. Large-scale changes to the climate altering the frequency, direction, and intensity of storms, may therefore propagate to the nearshore differently, amplifying or suppressing local coastal hazards and changing the exposure of coastal communities to extreme TWLs. This study investigates the hydrodynamic and geomorphologic factors controlling local TWLs along high-energy United States coastlines where wave-influences dominate TWLs. Three study sites in the states of Washington, Oregon, and California are chosen to explore how regional and local differences in beach topography and wave transformation over shelf bathymetry drives variations in the magnitude and impacts of extreme TWLs. Results indicate that TWLs are most influenced by wave transformation processes in locations with steep beach slopes (which drive larger relative contributions of wave runup) and complex offshore bathymetry, while beach topography influences the severity of coastal impacts. Once the relative morphologic controls on TWLs are better understood, hypothetical future climate scenarios are explored to assess how changes to the average deepwater wave climate (height, period, and direction) may alter local TWLs when compared to estimates of likely sea level rise and future coastal management strategies. Changes to the wave climate are found to be as detrimental to the coastline as sea level rise in some locations, where small variations of the TWL drive large, nonlinear changes in hours of impact to the backshore beach. Overall, this study develops an approach for quantifying the range of hydrodynamic and morphologic controls on the magnitude of TWLs which will ultimately better prepare coastal communities for uncertain changes to the global climate.

California, Oregon, Washington↗

The geochemistry of deep-sea coral skeletons: a review of vital effects and applications for palaeoceanography

Deep-sea corals were discovered over a century ago, but it is only over recent years that focused efforts have been made to explore the history of the oceans using the geochemistry of their skeletal remains. They offer a promising archive of past oceanic environments given their global distribution, layered growth patterns, longevity and preservation as well as our ability to date them using radiometric techniques. This paper provides an overview of the current state-of-the-art in terms of geochemical approaches to using deep-sea coral skeletons to explore the history of the ocean. Deep-sea coral skeletons have a wide array of morphologies (e.g. solitary cup corals, branching colonial corals) and materials (calcite, aragonite and proteins). As such their biomineralization strategies are diverse, leading to complex geochemistry within coral skeletons. Notwithstanding these complications, progress has been made on developing methods for reconstructing the oceanographic environment in the past using trace elements and isotopic methods. Promising approaches within certain coral groups include clumped isotopes and Mg/Li for temperature reconstructions, boron isotopes and radiocarbon for carbon cycling, εNd, and radiocarbon for circulation studies and δ 15 N, P/Ca and Ba/Ca for nutrient tracer studies. Likewise there is now a range of techniques for dating deep-sea corals skeletons (e.g. U-series, radiocarbon), and determining their growth rates (e.g. radiocarbon and 210 Pb). Dating studies on historic coral populations in the Atlantic, Southern Ocean and Pacific point to climate and environmental changes being dominant controls on coral populations over millennial and orbital timescales. This paper provides a review of a range of successes and promising approaches. It also highlights areas in which further research would likely provide new insights into biomineralization, palaeoceanography and distribution of past coral populations.

Deep-Sea Research Part II: Topical Studies in Ocea↗

Seafloor fluid seeps on Kimki Ridge, offshore southern California: Links to active strike-slip faulting

The Kimki Ridge fluid seeps are located in western Catalina Basin about 60 km southwest of the southern California mainland and at a water depth of approximately 1100 m. Multichannel seismic reflection profiles collected by the U.S. Geological Survey (USGS) in 2014 show acoustic transparency within the Kimki Ridge, suggesting the possibility of fluid seeps and possible sub-seafloor fluid pathways. Subsequent multibeam bathymetric and backscatter intensity data collected during a cooperative University of Washington/USGS cruise in early 2016 show subtle seafloor buildups with high acoustic backscatter (reflectivity) in three places along Kimki Ridge, supporting the existence of fluid seepage. A Remotely Operated Vehicle (ROV) dive, conducted as part of the Nautilus Exploration Program, took place in August 2016 to confirm the presence of these previously unknown seeps and document their characteristics as well as those of any associated biological communities. Two of the three seeps were explored by ROV, and showed abundant evidence of fluid seepage, including characteristic algal mats, chemosynthetic clams, and authigenic carbonate formation. The seeps are comprised of carbonate buildups 1–3 m thick and 300–500 m across. Within these areas, we interpret broad crater-like depressions 30–50 m across and 1–2 m deep to be individual seep vents. The seep areas appear to be broad zones of diffuse seepage that support chemosynthetic biologic communities; however, active venting was not observed. Geochemical analyses of rock samples collected from the seeps indicate microbially driven anaerobic oxidation of methane at or near the sediment water interface. Seismic-reflection profiles show chimney-like fluid pathways along the limbs and in the axis of the fold forming Kimki Ridge, and evidence of methane in shallow sediments can be traced into the adjacent Catalina Basin. A system of closely spaced faults located at the axis of the Kimki Ridge anticline may serve as pathways to allow fluid flow to the seafloor. Our data are consistent with other studies that suggest that transpression is an important component in the formation and localization of fluid seeps in a strike-slip setting, implying that seep formation may be a common occurrence at fault stepovers or transpressional bends in strike-slip systems.

California↗

Watershed Continuum Monitoring Approach: Combining multiple water quality patterns along stream and river flowpaths to track sources, pathways, and processing of pollutants

There is a growing need to improve and expand water quality monitoring approaches to more accurately track the sources, fate, and transport of multiple chemicals and pollutants holistically and quantify the effects of best management practices (BMPs) at the watershed scale. An overarching question raised by scientists, environmental managers, and the general public is: how far can water quality impacts from disturbances or benefits from watershed management and restoration propagate along stream and river flowpaths? Many studies using the classic watershed approach focus on analyzing changes in water quality over time at one or a few sampling stations, whereas theories such as the River Continuum Concept focus on predicting shifts in energy sources and biological communities along rivers but have not been directly applied to water quality. We propose to merge these concepts to create a Watershed Continuum Monitoring Approach (WCMA) that combines both spatial and temporal monitoring in order to better detect and quantify trends and transitions in multiple water quality indicators along flowpaths. Specifically, an array of multiple water quality indicators are analyzed at multiple downstream points along a watershed flowpath over time. These multiple water quality indicators are analyzed together for making comparisons to infer hydrological, biological, and geochemical processes controlling sources, transport, and attenuation of pollutants ( e.g. , analagous to stream tracer studies at the watershed scale). The WCMA leverages the natural expansion of watershed areas along a flowpath, which reflect transitions in land use, land cover, and environmental management across spatial and temporal dimensions for making direct comparisons across different stream reaches and spatial trend analysis. WCMA facilitates monitoring of multiple water quality indicators together, and identifcation of hot spots in sources and attenuation of pollutants or mixtures of pollutants. We illustrate practical applications of the WCMA to analyze water quality trends, transitions, and tradeoffs ( i.e. , a tradeoff occurs when one pollutant is reduced but another is directly or indirectly increased downstream). We explore case studies that quantify: (1) downstream reductions in concentrations of multiple pollutants along a stream flowing to a major drinking water source due to engineered and nature-based solutions, (2) downstream reductions in multiple pollutants and water quality tradeoffs along streams experiencing stormwater BMPs and stream restoration, (3) comparisons in downstream reductions of multiple pollutants and nutrient uptake along streams draining into major drinking water sources based on types of stream restoration, (4) comparisons of downstream pollutant reductions along streams experiencing riparian forest conservation vs. stream restoration, and (5) mapping and visualizing hot spots of increasing water quality problems such as hypoxia, contaminant mobilization, and freshwater salinization that extend downstream to tidal rivers of the Chesapeake Bay. We explore future applications of WCMA for tracking decreasing trends in salinity, E. coli , and other pollutants of emerging concern. WCMA can holistically inform progress towards achieving multiple water quality goals and also be used as a screening tool for selecting monitoring sites and targeting management in strategic locations. Overall, WCMA enables the simultaneous quantification and comparison of sources and transport and attenuation rates for different chemicals and pollutants across a broader range of watershed sizes and flowpath lengths, which is critical for understanding ecological, hydrological, geochemical, and biogeochemical processes along human-impacted streams and rivers.

Ecological Engineering↗

Variation in fish mercury concentrations in streams of the Adirondack region, New York: A simplified screening approach using chemical metrics

Simple screening approaches for the neurotoxicant methylmercury (MeHg) in aquatic ecosystems may be helpful in risk assessments of natural resources. We explored the development of such an approach in the Adirondack Mountains of New York, USA, a region with high levels of MeHg bioaccumulation. Thirty-six perennial streams broadly representative of 1st and 2nd order streams in the region were sampled during summer low flow and analyzed for several solutes and for Hg concentrations in fish. Several landscape and chemical metrics that are typically strongly related to MeHg concentrations in aquatic biota were explored for strength of association with fish Hg concentrations. Data analyses were based on site mean length-normalized and standardized Hg concentrations (assumed to be dominantly MeHg) in whole juvenile and adult Brook Trout Salvelinus fontinalis , Creek Chub Semotilus atromaculatus , Blacknose Dace Rhinichthys atratulus , and Central Mudminnow Umbra limi , as well as on multi-species z-scores. Surprisingly, none of the landscape metrics was related significantly to regional variation in fish Hg concentrations or to z-scores across the study streams. In contrast, several chemical metrics including dissolved organic carbon (DOC) concentrations, sulfate concentrations (SO 4 2− ), pH, ultra-violet absorbance (UV 254 ), and specific ultra-violet absorbance were significantly related to regional variation in fish Hg concentrations. A cluster analysis based on DOC, SO 4 2− , and pH identified three distinct groups of streams: (1) high DOC, acidic streams, (2) moderate DOC, slightly acidic streams, and (3) low DOC circum-neutral streams with relatively high SO 4 2− . Preliminary analysis indicated no significant difference in fish Hg z-scores between the moderate and high DOC groups, so these were combined for further analysis. The resulting two groups showed strong differences (p < 0.001) in DOC and SO 4 2− concentrations as well as in pH and UV 254 values. Median fish z-scores were significantly higher (p = 0.002) in the group of streams with higher DOC and UV 254 and lower pH and SO 4 2− . Screening values of DOC >6.9 mg/L, SO 4 2− <2.8 mg/L, pH <6.6, and UV 254 >0.31 cm −1 were tested as thresholds to identify Adirondack stream sites likely to have higher fish Hg concentrations. By applying a combined threshold of exceedance for either pH or UV 254 , sites with fish Hg concentrations that exceeded a wildlife guideline of 100 ng/g were correctly identified about 75% of the time among the 36 study streams. An estimate of Hg risk applied to a data set of 391 streams based on DOC concentrations showed that about 28% were likely to pose high risk to wildlife; most of these streams were located in the western Adirondacks.

New York↗