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NEPTUNE or Pluto? Since the days of Hutton and Werner, every generation of economic geologists has addressed this question in a new light. Most papers in this special issue deal with the thin and leaky roof of Pluto's underworld. It allows hot emanations from Hades to leak out, only to be quenched and diluted by waters percolating down from Neptune's realm.
Many calderas are located along regionally important fault zones that are intermittently active before and after the caldera cycle. In mineralized calderas, the ore deposits are controlled by structures developed during caldera formation and by regional faults which intersect and reactivate the caldera-related structures. In the earliest phase of the caldera cycle, tumescence occurs over the shallowly emplaced magma chamber and normal faults develop within the structural dome above the magma chamber. This early phase of faulting is disrupted by caldera formation but some of the faults are preserved outside the caldera margin and may become important ore-controlling structures such as the Ruja mercury deposit in the McDermitt caldera complex, Nevada, and the precious metal deposits in the Atlanta district, Nevada, outside the Indian Peak caldera. Caldera-related structures such as ring fracture faults are commonly the most important in controlling the emplacement of resurgent magma, as well as postcollapse intrusions and associated ore deposits. During the resurgence phase of the caldera, faults related to an apical graben, and radial and ring faults and fractures form and may extend outside the collapse structure. Radial and ring faults and fractures provided the structural control for gold alunite-type deposits in the Rodalquilar caldera complex, Spain.At the end of the caldera cycle, the area over the batholith related to the caldera-forming magma chambers is uplifted as isostatic compensation occurs, or subsides if the volcanic field is developed within a rapidly subsiding graben. Volume change resulting from crystallization will also contribute to subsidence. Regional subsidence of the Lake Owyhee volcanic field in southeastern Oregon at the end of the caldera cycle is reflected by arkosic sedimentation in the caldera basins and throughout the eastern part of the volcanic field. Crystallization of the underlying batholith permits the reestablishment of brittle deformation along the regional faults which initially may have controlled magma emplacement. This tectonic activity may reactivate caldera structures and these typically become important for localization of hydrothermal activity. Hot spring-type gold deposits in the Lake Owyhee volcanic field formed when a regional northwest-trending structure reactivated the caldera ring fracture fault zone of the Three Fingers caldera. The formation of hydrothermal ore deposits at the end of the caldera cycle is often related to tectonic reactivation of caldera structures by regional faults and emplacement of small volumes of magma as stocks and vent complexes along these structures.
The Porco Ag-Zn-Pb-Sn deposit, a major Ag producer in the 16th century and currently the major Zn producer in Bolivia, consists of a swarm of fissure-filling veins in the newly recognized Porco caldera. The caldera measures 5 km north-south by 3 km east-west and formed in response to the eruption of the 12 Ma crystal-rich dacitic Porco Tuff. Well-defined topographic walls of the caldera are cut in Ordovician and Cretaceous sedimentary rocks. The mineralization is associated with, and is probably genetically related to, the 8.6 Ma Huayna Porco stock (elev 4,528 m); the deposit is part of a system of radial dikes, metal zonation, and alteration mineral patterns centered on the stock. The outflow Porco Tuff to the north underlies the 6 to 9 Ma ash-flow tuffs of the Los Frailes volcanic field.The Porco deposit consists of steeply dipping irregular and curvilinear veins that cut the intracaldera Porco Tuff about 1 km east of the Huayna Porco stock. Major veins are generally less than a meter wide and as much as 2 km long. Most of the veins, especially the most productive ones, together with a small stock, dike, and breccia pipe, are aligned along the structural margin (ring fracture) of the caldera. The ore deposit is zoned around the Huayna Porco stock--cassiterite is generally close to the stock, and base metals, mostly as sphalerite and galena, are farther away, along the ring fracture veins. The primary Ag minerals, chiefly pyragyrite, acanthite, and stephanite, are most abundant in the upper parts of the veins.Fluid inclusions in sphalerite stalactites have homogenization temperatures of about 225 degrees C and salinities of about 8 wt percent NaCl equiv. The stalactites and the presence of sparse vapor-rich inclusions suggest deposition of sphalerite under boiling conditions. Modeling the depth of formation below the water table indicates that the present ground surface is close to the surface that existed at the time of mineralization.
The North Amethyst vein system, which is hosted by approximately 27 Ma Carpenter Ridge Tuff and approximately 26 Ma Nelson Mountain Tuff, has two mineral associations separated by brecciation and sedimentation in the veins. The early association consists of quartz, rhodonite, hematite, magnetite, electrum (Au (sub 0.3-0.5) Ag (sub 0.7-0.5)) , and Mn carbonate, Au-Ag sulfide, Ag sulfosalt, and base metal sulfide minerals. The later mineral association cuts the Mn- and Au-bearing assemblages and consists of quartz, calcite, sericite, chlorite, hematite, adularia, fluorite, base metal sulfides, and Ag-bearing tetrahedrite.Our detailed studies show that the Pb isotope compositions of paragenetically early galenas associated with Au-rich mineralization in the North Amethyst vein system are relatively unradiogenic ( 206 Pb/ 204 Pb: 18.826-18.881, 207 Pb/ 204 Pb: 15.588-15.602, and 208 Pb/ 204 Pb: 37.790-37.926) compared to Pb isotope compositions of galenas formed later at about 25 Ma during Ag and base metal mineralization ( 206 Pb/ 204 Pb: 19.041-19.115, 207 Pb/ 204 Pb: 15.627- 15.672, and 208 Pb/ 204 Pb: 37.829-38.057). New Pb isotope data for the central and southern parts of the Creede district, which are located 5 to 7 km south of the North Amethyst area, agree with the results of a regional study by Doe et al. (1979) that included five samples from the main part of the Creede district. Galenas and adularia from the central and southern Creede district and galenas from the Bondholder district, 7 km north of the North Amethyst area, are similar to the Pb isotope compositions of galenas formed later in the North Amethyst area during Ag and base metal mineralization. Galenas from the Alpha-Corsair vein, which was mined for Ag prior to 1910, are isotopically similar to galenas associated with North Amethyst Au-stage mineralization. This isotopic similarity suggests that unexplored segments of the Alpha-Corsair structure may have the same mineralogy as the North Amethyst Au stage; thus, the Alpha-Corsair structure has the potential for high gold contents.Pb isotope compositions from the late stage of the North Amethyst vein system and from the Bondholder and central and southern Creede mining districts are more radiogenic than the host volcanic rocks of the central cluster of the San Juan volcanic field. Our Pb isotope results indicate that early Au mineralization of the North Amethyst area may represent the product of an older and relatively local hydrothermal system distinct from that of the younger base metal and Ag mineralization found throughout the region. Fluids that deposited Au minerals may have derived their Pb isotope composition by a greater degree of interaction with shallow, relatively less radiogenic volcanic wall rocks. The younger, base metal and Ag-rich mineralization that overprints the Au mineralization in the North Amethyst area clearly has a more radiogenic isotopic signature, which implies that the later mineralization derived a greater component of its Pb from Proterozoic source rocks, or sediments derived from them.Paragenetically early sulfide-rich vein assemblages have the least radiogenic galenas and generally also have the highest Au contents. Thus, identification of paragenetically early vein assemblages with relatively unradiogenic Pb isotope compositions similar to those of the North Amethyst area provides an additional exploration tool for Au in the central San Juan Mountains area.
The Bulldog Mountain vein system, Creede district, Colorado, is one of four major epithermal vein systems from which the bulk of the district's historical Ag-Pb-Zn-Cu production has come. Ores deposited along the vein system were discovered in 1965 and were mined from 1969 to 1985.Six temporally gradational mineralization stages have been identified along the Bulldog Mountain vein system, each with a characteristic suite of minerals deposited or leached and a characteristic distribution within the vein system; some of these stages are also strongly zoned within the vein system. Stage A was dominated by deposition of rhodochrosite along the lower levels of the Bulldog Mountain ore zone. Stage B in the northern parts of the ore zone is characterized by abundant fine-grained sphalerite and galena, with lesser tetrahedrite and minor chlorite and hematite. With increasing elevation to the south, stage B ores become progressively more barite and silver rich, with alternating barite and fine-grained sphalerite + galena generations; native silver + or - acanthite assemblages are also locally abundant within southern stage B barite sulfide ores, whereas chalcopyrite and other Cu and Ag sulfides and sulfosalts are present erratically in minor amounts. Stage C in the upper and northern portions of the ore zone is characterized by abundant quartz and fluorite, minor adularia, hematite, Mn siderite, sphalerite, and galena, and major leaching of earlier barite; to the south, some barite and sulfides may have been deposited. Stage D sphalerite and galena were deposited in the upper and northern portions of the ore zone; a barite- and silver-rich facies of this stage may also be present in the southern portions of the vein system. Late in stage D, mineralogically complex assemblages containing chalcopyrite, tetrahedrite, polybasite, bornite, pyrargyrite, and a variety of other sulfides and sulfosalts were deposited in modest amounts throughout the vein system. This complex assemblage marked the transition to stage E. During stage E, the final sulfide stage, abundant botryoidal pyrite and marcasite with lesser stibnite, sphalerite, and sulfosalts were deposited primarily along the top of the Bulldog Mountain ore zone. Stage F, the final mineralization stage along the vein system, is marked by wire silver and concurrent leaching of earlier sulfides and sulfosalts; this stage may reflect the transition to a supergene environment.The sequence of mineralization stages identified in this study along the Bulldog Mountain system can be correlated with corresponding stages identified by other researchers along the OH and P veins, and the southern Amethyst vein system. Mineral zoning patterns identified along the Bulldog Mountain vein system also parallel larger scale zoning patterns across the central and southern Creede district.The complex variations in mineral assemblages documented in time and space along the Bulldog Mountain vein system were produced by the combined effects of many processes. Large-scale changes in vein mineralogy over time produced discrete mineralization stages. Short-term mineralogical fluctuations produced complex interbanding of mineralogically distinct generations. Fluid chemistry evolution within the vein system produced large-scale lateral zoning patterns within certain stages. Hypogene leaching substantially modified the distributions of some minerals. Finally, structural activity, mineral deposition, and mineral leaching modified fluid flow pathways repeatedly during mineralization, and so added to the complex mineral distribution patterns within the vein system.
The Laramide San Manuel-Kalamazoo porphyry system of Arizona has been pivotal in concepts of both extensional tectonics and alteration-mineralization zoning. This paper reexamines the tilting history in light of new work in the region and reinterprets the geometry of the deposit. The porphyry mineralization occurs in and near an intrusion of Laramide San Manuel porphyry in Precambrian Oracle Granite. The area has an extremely complicated history of Tertiary crustal extension and fanglomerate deposition, but the blocks containing the two main fragments of the original orebody (separated by the San Manuel fault) were involved in only the later parts of this history and are less tilted than other nearby blocks. Originally horizontal features of mid-Tertiary age are tilted about 30 degrees , those of Laramide age about 35 degrees , and those of pre-Laramide age about 45 degrees to the northeast. Paleomagnetism of the porphyry intrusion itself suggests tilting of about 33 degrees . The data thus suggest that postemplacement tilt of the Laramide porphyry system was 30 degrees to 35 degrees and that virtually all of it was mid-Tertiary in age. An earlier interpretation of greater tilt magnitude was apparently based in part on correlation with adjacent areas showing greater tilt magnitude (as in the Tar Wash allochthon) and in part on a choice of cross section that gives the impression of a nearly recumbent attitude. However, Lowell's sections are oriented along the strike of both the orebodies and the productive porphyry intrusion, which are dipping tablo-cylindroidal bodies. Ore forms a hollow envelope whose inner margin has an aspect ratio of about >4.3 (length)/>2.5 (downdip height)/l (limb separation). The productive intrusion, around which ore is wrapped, has a similar aspect ratio in the same plane (strike N 58 degrees E, dip 47 degrees SE). Reconstruction of the original attitudes of intrusion and ore yields a common strike near N 75' E and a steep dip to the south. This is a common attitude for undisturbed productive porphyry dikes of Laramide age.
Over 62 percent of the 193,000 metric tons of gold discovered to date is located in four countries and more than 68 percent occurs in four types of mineral deposits. About 55 percent of the 1,740,000 metric tons of silver found is in four countries and 45 percent is in four types of deposits. Fifty-six percent of the 1.52 billion metric tons of discovered copper is from four countries and four types of deposits contain 88 percent of the total. Over 50 percent of both the 713,000,000 metric tons of zinc and 349,000,000 metric tons of lead discovered to date come from four countries and 70 percent of both metals occur in four types of deposits. All discovered gold would fit in a cube with a height oF 22 m, silver in a 55-m cube, copper in a 550-m cube, zinc in a 460-m cube, and lead in a 310-m cube. At least 74 percent of gold, silver, zinc, and lead is in deposits having average grades above the respective median grades and 44 percent of copper is in deposits with average grades above the median grade of all deposits. Lower grade deposits contain less total metal than higher grade deposits. Tonnage of mineralized rock is an even better predictor of contained metal with over 96 percent of each metal's total residing in deposits having greater than median size and between 47 and 79 percent of metal contained in the largest 10 percent of deposits. World class deposits, defined as the upper 10 percent of deposits in terms of contained metal, account for over 86 percent of all gold, 79 percent of silver, 84 percent of copper, 71 percent of zinc, and 73 percent of lead. These giant deposits contain at least 100 metric tons (3.2 Moz) gold, 2,400 metric tons (77 Moz) silver, 2 million metric tons copper, 1.7 million metric tons zinc, or 1 million metric tons lead. Mineral deposits occur rarely in the earth's crust and large ones are especially uncommon. This analysis shows that only the unusually large deposits can significantly affect supply.
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The Al Wajh gold district contains small deposits of gold-bearing quartz veins located in sheared and altered Neoproterozoic mafic lavas and volcaniclastic sandstone and siltstone. The veins formed during multiple episodes of deformation and have structual and mineralogic features characteristic of mesothermal, low sulfide, gold-bearing quartz veins. Three early deformation episodes (D 1 , D 2 , D 3 ) are interpreted as progressive phases of a major deformation event that culminated about 660 Ma; episode D 4 makes up part of a later event about 620 Ma. The bulk of the gold-bearing veins in the district are located in D 2 and D 3 structures. D 1 veins consist of thin quartz veins in phyllite, D 2 veins are located in throughgoing, steeply dipping sinistral shear zones and in the crests of folds along the shears. D 3 veins, typically associated with carbonate alteration, are concentrated in small thrust faults that in places modify earlier D 2 shears. -from Authors
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The Cierco Pb-Zn-Ag vein deposits, located in the central Pyrenees of Spain, crosscut Paleozoic metasedimentary rocks and are in close proximity to Hercynian granodiorite dikes and plutons. Galena and sphalerite in the deposits have average delta 34 S values of - 4.3 and - 0.8 per mil (CDT), respectively. Coexisting mineral pairs give an isotopic equilibration temperature range of 89 degrees to 163 degrees C which overlaps with the 112 degrees to 198 degrees C range obtained from primary fluid inclusions. Coexisting quartz has a delta 18 O value of 19 + or - 1 per mil (VSMOW). The fluid which deposited these minerals is inferred to have had delta 18 O (sub H 2 ) O and delta 34 S (sub H 2 ) S values of 5 + or - 1 and -1 + or - 1 per mil, respectively. Chemical and microthermometric analyses of fluid inclusions in quartz and sphalerite indicate salinities of 3 to 29 wt percent NaCl equiv with Na (super +) and Ca (super 2+) as the dominant cations in solution. The Br/Cl and I/Cl ratios differ from those characteristic of magmatic waters and pristine seawater, but show some similarity to those observed in deep ground waters in crystalline terranes, basinal brines, and evaporated seawater. Barite, which postdates the sulfides, spans isotopic ranges of 13 to 21 per mil, 10 to 15 per mil, and 0.7109 to 0.7123 for delta 34 S, delta 18 O, and 87 Sr/ 86 Sr, respectively. The three parameters are correlated providing strong evidence that the barites are products of fluid mixing.We propose that the Cierco deposits formed along an extensional fault system at the margin of a marine basin during the breakup of Pangea at some time between the Early Triassic and Early Cretaceous. Sulfide deposition corresponded to an upwelling of hydrothermal fluid from the Paleozoic basement and was limited by the amount of metals carried by the fluid. Barite deposition corresponded to the waning of upward flow and the collapse of sulfate-rich surface waters onto the retreating hydrothermal plume. Calcite precipitated late in the paragenesis as meteoric or marine waters descended into the fault system, possibly during a regression in the overlying basin.There are other deposits resembling Cierco elsewhere in the Iberian peninsula. Taken as a group, they are evidence that hydrothermal circulation systems were widespread during Mesozoic extension. Differences among the deposits can be related to the fact that H 2 S and other solutes had local and variable sources.
Trace element contents of tourmalines from massive sulfide deposits and tourmalinites have been determined in situ by proton microprobe; >390 analyses were acquired from 32 polished thin sections. Concentrations of trace elements in the tourmalines vary widely, from <40 to 3,770 ppm Mn, <4 to 1,800 ppm Ni, <2 to 1,430 ppm CU, <9 to 4,160 ppm Zn, 3 to 305 ppm Ga, <6 to 1,345 ppm Sr, <10 to 745 ppm Sn, <49 to 510 ppm Ba, and <3 to 4,115 ppm Pb. Individual grains and growth zones are relatively homogeneous, suggesting that these trace elements are contained within the crystal structure of the tourmaline, and are not present in inclusions. The highest base metal contents are in ore-related tourmaline samples from Kidd Creek (Ontario), Broken Hill (Australia), and Sazare (Japan). Tourmaline data from these and many other massive sulfide deposits cluster by sample and display broadly linear trends on Zn vs. Fe plots, suggesting chemical control by temperature and hydrothermal and/or metamorphic fluid-mineral equilibria. Significant Ni occurs only in samples from the Kidd Creek Cu-Zn-Pb-Ag deposit, which is associated with a large footwall ultramafic body. An overall antithetic relationship between Zn and Ni probably reflects fluid source controls. Mn is correlated with Fe in tourmalines from barren associations, and possibly in some tourmalines associated with sulfide vein deposits. Sn increases systematically with Fe content irrespective of association; the highest values are found in schorls from granites. Other trace elements are generally uncorrelated with major element concentrations (e.g., Sr-Ca). Base metal proportions in the tourmalines show systematic patterns on ternary Cu-Pb-Zn diagrams that correlate well with the major commodity metals in the associated massive sulfide deposits. For example, data for tourmalines from Cu-Zn deposits (e.g., Ming mine, Newfoundland) fall mainly on the Cu-Zn join, whereas those from Pb-Zn deposits (e.g., Broken Hill, Australia) plot on the Pb-Zn join; no data fall on the Cu-Pb join, consistent with the lack of this metal association in massive sulfide deposits. The systematic relationship between base metal proportions in the tourmalines and the metallogeny of the host massive sulfide deposits indicates that the analyzed tourmalines retain a strong chemical signature of their original hydrothermal formation, in spite of variable metamorphic recrystallization. Such trace element patterns in massive sulfide tourmalines may be useful in mineral exploration, specifically for the evaluation of tourmaline concentrations in rocks, soils, and stream sediments.
Lode gold mineralization in the Blue Ridge of the southernmost Appalachians is hosted by metavolcanic rocks (e.g., Anna Howe mine, AL; Royal Vindicator mine, GA), metaplutonic rocks (e.g., Hog Mountain mine, AL), and metasedimentary rocks (e.g., Lowe, Tallapoosa, and Jones Vein mines, AL). Most gold occurs in synkinematic quartz + or - plagioclase + or - pyrite + or - pyrrhotite + or - chlorite veins localized along polydeformational faults that juxtapose rocks with significantly different peak metamorphic mineral assemblages.Mineralogy, chemistry, and O and H isotope studies suggest that the three types of host rocks have undergone differing amounts and types of alteration during mineralization. Limited wall-rock alteration in metavolcanic- and metasediment-hosted deposits, and relatively extensive wall-rock alteration in granitoid-hosted deposits, suggests that most deposits formed from fluids that were close to equilibrium with metavolcanic and metasedimentary rocks. Stable isotope compositions of the fluids calculated from vein minerals and vein selvages are consistent with a predominantly metasedimentary fluid source, but vary from deposit to deposit (-22 to -47ppm delta D, 4-5ppm, delta 18 O, and 5-7ppm delta 34 S at Anna Howe and Royal Vindicator; -48 to -50ppm delta D, 9-13ppm delta 18 O, and ca. 19ppm delta 34 S at Lowe and Jones Vein; and -22 to -23ppm delta D, 8-11ppm delta 18 O, 9-10ppm delta 34 S, and -6 delta 13 C at Hog Mountain). Silicate mineral thermobarometry of vein, vein selvage, and wall-rock mineral assemblages indicate that mineralization and regional metamorphism occured at greenschist to amphibolite facies (480 degrees + or - 75 degrees C at Anna Howe, 535 degrees + or - 50 degrees C at 6.4 + or - 1 kbars at Lowe, 530 degrees + or - 50 degrees C at 6.9 + or - 1 kbars at Tallapoosa, and 460 degrees + or - 50 degrees C at 5.5 + or - 1 kbars at Hog Mountain). Oxygen isotope fractionation between vein minerals and selvage minerals consistently records equilibration temperatures that are similar to or slightly lower than those estimated from silicate thermometry.Auriferous veins contain numerous fluid inclusions that were emplaced in several stages and can be subdivided into five compositional types based on salt and CO 2 concentrations. Fluid inclusion isochores for early formed inclusions from these veins intercept the pressure and temperature conditions estimated from silicate mineral thermobarometry and stable isotope thermometry, and are compatible with entrapment at those conditions. These fluids exhibit significant variation in salinity (X (sub NaCl equiv ) ) = 0.0-0.2) and CO 2 (X (sub CO 2 ) = 0.0-0.2), suggesting variation in fluid-wall-rock interaction that accompanied gold deposition during declining temperatures. Less abundant and later fluids within the veins are dominantly CO 2 .The association of gold mineralization with structurally controlled concordant and discordant quartz sulfide veins, and the temperatures and pressures of wall-rock alteration and regional metamorphism indicate that the present distribution of gold is a result of metamorphism during progressive D 2 -D 3 deformation. Isotopic data for alteration envelopes date this event as Alleghanian: 279 + or - 14 Ma (K-Ar whole rock) and 343 + or - 18 Ma (K-Ar biotite) at Lowe; and 315 + or - 18 Ma (Rb-Sr whole-rock isochron; 87 Sr/ 86 Sr i = 0.7061 + or - 0.0008) and 294 + or - 16 Ma (K-Ar whole-rock) at Hog Mountain. Available data are compatible with development of the lodes during early Alleghanian overthrusting of allochthons over sedimentary rocks of the autochthonous North American margin. The implication is that the fluids were derived from metasedimentary and/or metavolcanic formations in the lower parts of the crystalline thrust stack (or possibly from underlying autochthonous sedimentary formations), ascended along permeable fault zones, and were emplaced as veins into dilatent areas in and adjacent to the fault zones.
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