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At least 973 records · Page 54Linked to original sources
USGS2018

Ore-forming adakitic porphyry produced by fractional crystallization of oxidized basaltic magmas in a subcrustal chamber (Jiamate, East Junggar, NW China)

Adakitic intrusions are supposed to have a close genetic and spatial relationship to porphyry Cu deposits. However, the genesis of adakitic intrusions is still under dispute. Here, we describe newly discovered intrusive complex rocks, which are composed of ore-bearing, layered magnetite-bearing gabbroic and adakitic rocks in Jiamate, East Junggar, NW China. These Jiamate Complex intrusions have diagnostic petrologic, geochronologic and geochemical signatures that indicate they were all generated from the same oxidized precursor magma source. Additionally, these layered rocks underwent the same fractional crystallization process as the ore-bearing adakitic rocks in the adjacent Kalaxiangar Porphyry Cu Belt (KPCB) in an oceanic island arc (OIA) setting. The rocks studied for this paper include layered magnetite-bearing gabbroic intrusive rocks that contain: (1) gradual contact changes between lithological units of mafic and intermediate rocks, (2) geochemical signatures that are the same as those found in oceanic island arc (OIA) rocks, (3) typical adakitic geochemistry, and (4) similar characteristics and apparent fractional crystallization relationships of ultra-basic to basic rocks to those in the nearby Beitashan Formation and to ore-bearing adakitic rocks in the KPCB. They also display similar zircon U-Pb and zircon Hf model ages. The Jiamate Complex intrusions contain intergrowths of magnetite and layered gabbro, and the intermediate-acidic intrusions of the Complex display typical adakitic affinities. Moreover, in conjunction with previously published geochronological and geochemistry data of the mafic rocks in the Beitashan Formation and in the KPCB area, additional data generated for the Jiamate Complex intrusions rocks indicate that they were formed from fractional crystallization processes. The Jiamate Complex intrusions most likely were derived from a metasomatized mantle wedge that was underplated at the root of the Saur oceanic island arc (Saur OIA). The ore-bearing adakitic intrusions in the KPCB and the adakitic Jiamate Complex intrusions were both probably generated from the same basaltic parental magmas through fractional crystallization. In addition, characteristics of the layered, magnetite-bearing, oxidized, basaltic Jiamate Complex intrusive rocks indicate that they are likely to be the parental arc magmas for the nearby porphyry Cu deposits. This conclusion is based on new interpretations of the regional and local geology, on interpretation of new geochemical analysis, new stable isotope analysis, new geothermobarometry, and new zircon age dating as well as other techniques and interpretations.

LITHOS↗
USGS1969

The Cloudy Pass epizonal batholith and associated subvolcanic rocks

The Cloudy Pass batholith, one of several small epizonal Tertiary batholiths in the Northern Cascade Mountains, discordantly intrudes metamorphic rocks of pre-Late Cretaceous age. The batholith is remarkable for its chilled borders, associated porphyry plugs, and intrusive breccias. The main body of the batholith consists largely of labradorite granodiorite. Part of the northeast side of the batholith is bordered by a complex more than half a mile thick of chilled rocks of Hart Lake that consists of separately injected, contrasting layers of porphyry. At lower levels these are an early, outer layer of dacite; a younger, inner layer of dacite and labradorite-by-townite andesite; and a middle, still younger layer of autobreccia compositionally similar to the inner layer. Contacts between layers are complex and consist at lower levels of intermixed zones, suggesting that at these levels the early rocks were still molten when injected by the later rocks. At higher levels the younger rocks split into separate dikes, and contacts between younger and older rocks are sharp, suggesting that at these levels the older rocks had solidified before they were intruded by the younger rocks. The border complex is thought to have been cooled largely by expanding gases which were released from the batholith and which escaped to the surface through this zone. The contact between the labradorite granodiorite and the inner layer is gradational locally, but in most places the granodiorite intrudes the inner layer, and the contact is sharp. Where the middle and inner layers of the complex are absent, the contact of granodiorite and dacite of the outer layer is gradational. Porphyry plugs which puncture the adjacent metamorphic rocks, although more siliceous than the rocks of the complex, consist largely of dacite and are petrographically indistinguishable from dacite of the complex. Intrusive breccias are of two types: one consists of rounded fragments of batholithic rocks in a “marble cake” mixture of calcic quartz diorite and white quartz monzonite and is confined to the core of the batholith; the other consists of fragments of batholithic rocks and gneiss in a matrix of varying proportions of igneous and finely comminuted materials and is confined to the porphyry plugs and gneiss. This second type seems to have been injected explosively, probably accompanying “second boiling” of the labradorite granodiorite. Plagioclases range from high- to low-temperature varieties. The transitional and high-temperature plagioclases are confined to the deuterically least-altered parts of the chilled margins. The low-temperature plagioclase occurs in the batholithic core and the complex of Hart Lake, and is thought to have inverted from an original high-temperature form because of long-continued existence at elevated, although subsolidus, temperatures, or because of the action of volatile constituents, or both. The batholith seems to have made room for itself by lifting its roof, and the complex of Hart Lake developed along the upfaulted eastern side.

Washington↗
USGS1995

Largemouth bass response to habitat and water quality rehabilitation in a backwater of the upper Mississippi River

Severe sedimentation since lock and dam construction in the 1930s has reduced water depth in Upper and Lower Brownˈs lakes, a backwater complex in Pool 13 of the upper Mississippi River, and resulted in periods of chronic anoxia. This backwater complex was rehabilitated by construction of a deflection levee, installation of a water control structure, and excavation of canals through the area. Water quality variables inside and outside the project area, movement of radio-tagged largemouth bass in response to changing oxygen concentrations, and creel statistics were used to evaluate the success of the improvements. Turbidity was significantly less in the Brownˈs Lake complex than in the main channel. Oxygen concentrations were allowed to deteriorate to 3 ppm before the water control structures were opened during the winter; within 7 d, oxygen concentrations as high as 10 ppm were found in the top strata in most of the Brownˈs Lake complex. Chemical and thermal stratification observed in the dredge canal water column were caused by colder (32°F), highly oxygenated water from the main channel moving over denser, warmer (36–38°F) water in the dredge canals. Water in the dredge canals remained stratified until ice-out, with colder, oxygenated water in the surface stratum; warmer, but anoxic, water in the bottom stratum; and a mixture (3–7 ppm oxygen and 35–36°F) in the middle stratum. Fourteen radio-tagged largemouth bass Micropterus salmoides were located in the Brownˈs Lake complex in December before oxygen concentrations began to decline, Concurrent with oxygen declines, most radio-tagged fish exited the complex through a slough connected to the main channel and returned when the water control structure was opened and oxygen concentrations increased. Some radio-tagged largemouth bass moved 4 mi under ice to return to the complex. Estimated angler effort and catch increased 58 and 117%, respectively, in the Lower Brownˈs Lake–Lainesville Slough complex following rehabilitation. A 10-fold increase in angler effort and catch was estimated for Upper Brownˈs Lake after the project was completed.

Iowa↗
USGS2009

Ultra-deep oxidation and exotic copper formation at the late pliocene boyongan and bayugo porphyry copper-gold deposits, surigao, philippines: Geology, mineralogy, paleoaltimetry, and their implications for Geologic, physiographic, and tectonic controls

The Boyongan and Bayugo porphyry copper-gold deposits are part of an emerging belt of intrusion-centered gold-rich deposits in the Surigao district of northeast Mindanao, Philippines. Exhumation and weathering of these Late Pliocene-age deposits has led to the development of the world's deepest known porphyry oxidation profile at Boyongan (600 m), and yet only a modest (30-70 m) oxidation profile at adjacent Bayugo. Debris flows, volcanic rocks, and fluviolacustrine sediments accumulating in the actively extending Mainit graben subsequently covered the deposits and preserved the supergene profiles. At Boyongan and Bayugo, there is a vertical transition from shallower supergene copper oxide minerals (malachite + azurite + cuprite) to deeper sulfide-stable assemblages (chalcocite ?? hypogene sulfides). This transition provides a time-integrated proxy for the position of the water table at the base of the saturated zone during supergene oxidation. Contours of the elevation of the paleopotentiometric surface based on this min- eralogical transition show that the thickest portions of the unsaturated zone coincided with a silt-sand matrix diatreme breccia complex at Boyongan. Within the breccia complex, the thickness of the unsaturated zone approached 600 in, whereas outside the breccia complex (e.g., at Bayugo), the thickness averaged 50 m. Contours of the paleopotentiometric surface suggest that during weathering, groundwater flowed into the breccia complex from the north, south, and east, and exited along a high permeability zone to the west. The high relief (>550 m) on the elevation of the paleopotentiometric surface is consistent with an environment of high topographic relief, and the outflow zone to the west of the breccia complex probably reflects proximity to a steep scarp intersecting the western breccia complex margin. Stable isotope paleoaltimetry has enabled estimation of the elevation of the land surface, which further constrains the physiographic setting during supergene oxidation. Isotopic measurements of oxygen in supergene kaolinite from Boyongan suggest that local paleometeoric water involved in weathering had a ??180 composition of approximately -5.7 per mil. At the latitude of the southern Philippines, this value corresponds to Pleistocene rain water condensing at elevations between 750 and 1,050 m above contemporary sea level, providing a maximum estimate for the surface elevation during weathering of the porphyry systems. Physiographic reconstuctions suggest that the deep oxidation profile at Boyongan formed in an environment of high topographic relief immediately east of a prominent (>550 m) escarpment. The high permeability contrast between the breccia complex and the surrounding wall rocks, coupled with the proximity of the breccia complex to the escarpment, led to a depressed groundwater table and a vertically extensive unsaturated zone in the immediate vicinity of Boyongan. This thick vadose zone and the low hypogene pyrite/copper sulfide ratios (0.6) at Boyongan promoted in situ oxidation of copper sulfides with only modest (<200 m) supergene remobilization of copper. In contrast, higher hypogene pyrite/chalcopyrite ratios (2.3) at Bayugo led to greater acid production during weathering and more complete leaching of copper above the base of oxidation. This process promoted significant (600 m) lateral dispersion of copper down the paleohydraulic gradient into the diatreme breccia comple, ultimately leading to the formation of an exotic copper deposit. ?? 2009 Society of Economices Geologists, Inc.

Economic Geology↗
USGS2024

Physics to fish—Understanding the factors that create and sustain native fish habitat in the San Francisco Estuary

Executive Summary The Bureau of Reclamation (Reclamation) operates the Central Valley Project (CVP), one of the nation’s largest water projects. Reclamation has an ongoing need to improve the scientific basis for adaptive management of the CVP and, by extension, joint operations with California’s State Water Project. The U.S. Geological Survey (USGS) works cooperatively with the Bureau of Reclamation to provide scientific support for the management of Reclamation’s CVP project. Major habitat restoration efforts and a new water-diversion point are planned to benefit delta smelt ( Hypomesus transpacificus ) and other species of concern while ensuring the reliability of water supply. In addition, various flow actions and management activities have been identified as possible methods to increase populations of delta smelt and salmonid ( Oncorhynchus spp.) runs of concern. The overarching goal of this cooperative project was to provide Reclamation with the scientific information needed to evaluate the efficacy of ongoing and future adaptive management actions and to improve the scientific basis for more flexible CVP operations that would achieve water-supply reliability and fish protection. The research and monitoring described in this report comprises the period 2015–19 and focuses on management issues related to native fish species of concern, especially delta smelt. Conserving the delta smelt population while providing a reliable water supply is a primary management and policy issue in California. Our approach for this cooperative project is based on the “physics to fish” concept, the idea that high-quality habitat is generated and sustained by the interaction between physical processes and the landscape. These interactions create a template for chemical and biological processes that can change across a variety of spatial and temporal scales. Following this concept, this project (hereafter referred to as “the physics to fish project”) included monitoring and studies of water flows, sediments, water quality, and invertebrate and fish dynamics across a range of spatial and temporal scales and in regions relevant to resource managers tasked with managing water supplies and ecosystem health in the San Francisco Estuary. The intent of this approach was to document the habitat conditions, important processes, and interactions among them that create high-quality habitat for native fishes so that the likely effects of future management actions (for example, habitat restoration) can be objectively assessed at the local (site-specific), regional (within subregions of the estuary), and landscape (across the entire estuary and beyond) scales. Hydrodynamically, the upper estuary (landward of Carquinez Strait) is characterized by a fixed volume of tidally exchanged water (for example, tidal prism) that interacts with the existing channel network and bathymetry to create regions with differing hydrodynamics. Our results indicate that careful study of construction or reoperation of existing infrastructure to perform management actions can help (1) improve the accuracy of hydrodynamic models; (2) further understanding of ecological effects; and (3) enhance abilities to predict ecological outcomes. At the local scale, we developed a new concept called the Lagrangian to Eulerian (LE) ratio that can be used as a tool for understanding the importance of various hydrodynamic processes in specific channels or channel networks and for forecasting transport dynamics. Channels with LE ratios<1 in a channel network or in a dead-end slough are hydrodynamically able to develop an exchange zone between two parcels of water that may have different chemical and physical properties. In a dead-end channel, there is a landward region with long residence time (no-exchange zone) and a seaward region with short residence time (high-exchange zone) that are well mixed with seaward waters. At the transition (exchange zone) between the high and no-exchange regions, a gradient will form in water-quality constituents that differ in concentration between the landward and seaward waters. Turbidity affects fish habitat and has declined through time in the San Francisco Estuary. Average turbidity across the Sacramento–San Joaquin Delta (hereafter referred to as “the Delta”) is dependent on annual hydrology. In dry years, the region around Cache Slough (known regionally as the “Cache Slough Complex”) in the northern Delta is generally more turbid than Suisun Bay and the lower Sacramento River. When the Yolo By-Pass (known regionally as “Yolo Bypass”), a large flood bypass that runs parallel to the Sacramento River in the northern Delta, is not flooding and river flows are lower, sediment is usually transported into the Cache Slough Complex because flood tides dominate ebb tides, resulting in transport of suspended sediment from seaward areas of the upper estuary into the Cache Slough Complex. These hydrodynamic conditions also favor the formation of turbidity maximums (TMs) in the Cache Slough Complex. The TMs are areas of higher suspended-sediment concentration, providing higher-turbidity habitat favored by some fishes, including delta smelt, and they can also concentrate other constituents, including phytoplankton and organic carbon that can be important in food webs. Pelagic primary production by phytoplankton is the basis for Delta food webs supporting pelagic fishes such as delta smelt; however, phytoplankton abundance in the Delta has declined during recent decades. We examined how nutrients, hydrodynamics, and other factors affect phytoplankton blooms. Based on our results, we developed three new concepts of phytoplankton bloom formation in the Delta, each associated with a distinct set of hydrologic conditions. First, productivity cascades highlighted how local processes can contribute to phytoplankton blooms observed at the regional scale. Second, we observed phytoplankton blooms in the upper San Francisco Estuary that were associated with transport out of Yolo By-Pass (transport blooms). Third, we also documented a series of phytoplankton blooms that were in the confluence area at the landward edge of Suisun Bay. The conditions leading to creation of confluence phytoplankton blooms are not yet understood, but the confluence region connects the Cache Slough Complex with Suisun Marsh. Therefore, blooms in this area have the potential to spread to large areas of the Delta. At the landscape scale, the distribution of the invasive clams ( Potamocorbula amurensis and Corbicula fluminea , hereafter referred to as “ Corbicula ”) is driven by salinity. At smaller spatial scales, the distribution of either species is sensitive to multiple factors affecting survival and reproduction, complicating efforts to predict distribution and abundance without considering local-scale conditions across the area of interest. In the Cache Slough Complex, the area landward of the exchange zone in regions with LE ratio<1 were characterized by low abundances of Corbicula probably because recruits from seaward areas are not transported past the exchange zone and because there are no landward tributaries with adult Corbicula to provide an upstream source of recruits. Corbicula biomass was highest near or downstream from the exchange zone consistent with Corbicula grazing on phytoplankton produced in the exchange zone or transported from the no-exchange zone. The severity of Corbicula grazing could be reduced by manipulating the hydrodynamic characteristics of waterways; however, the beneficial and harmful effects on the organisms meant to benefit from increased phytoplankton production, including zooplankton and fish species of concern, should be thoroughly examined before manipulating hydrodynamic characteristics. The distribution of fishes at the landscape scale is generally driven by the position of the salinity field in the estuary. The physics to fish project compared distributions of fishes at Ryer Island, a tidal wetland in Suisun Bay and a region of variable salinity, with fish distributions at the Cache Slough Complex, a freshwater region. At Ryer Island, there was an absence of freshwater invasive species and an abundance of native species, such as Sacramento splittail ( Pogonichthys macrolepidotus ), tule perch ( Hysterocarpus traskii ), and Sacramento pikeminnow ( Ptychocheilus grandis ). The native species were almost exclusively captured in wetland and nearshore shallow-water habitat regardless of water-quality conditions. In the Cache Slough Complex, our regional scale objective was to elucidate how hydrodynamic-physical habitat interactions drive fish-community structure. Our studies showed that dendritic channel systems were better able to support native species, while intertidal habitats supported those species best able to exploit the transient character of the habitat. Habitats upstream from the exchange zone were especially important in supporting high numbers of native fishes relative to within or downstream from the exchange zone. Many of the native species were associated with tidal marsh in the no-exchange zone. More pelagic-oriented, mobile species, such as Striped Bass ( Morone saxatilis ), threadfin shad ( Dorosoma petenense ), and Sacramento pikeminnow, were more affected by water-quality conditions, such as turbidity. The physics to fish concept developed in this project provides a framework for designing individual projects and for considering the cumulative effects of multiple projects in a region, using the LE ratio as a guiding metric. The physics to fish concept may also provide a suitable framework for coordinating management actions. Tidal wetlands can function in several ways in the hydrodynamic framework. Relatively small tidal wetlands with short channel networks and with LE ratios>1 are not able to maintain a landward no-exchange zone or an exchange zone. This likely means that any contributions to pelagic food webs would be limited to resources derived from wetland vegetation, which can include dissolved and particulate organic matter (detritus) and populations of consumers that can increase in abundance based on those resources. The fate of the contributed production from these channels depends on the characteristics of the receiving waters seaward of the tidal wetland. If these channels join a large system such as Suisun Bay, then any contribution is likely to be rapidly dispersed in the larger volume; however, the channel junction might provide a focal point for consumers, such as fishes, to congregate and feed on material leaving the wetland on ebb tides before it is dispersed in the larger volume. Fishes might also access these resources by entering the wetland. The physics to fish project has established a foundation and several new concepts for understanding how habitat restoration can benefit native fish populations at the local and regional levels. Many of the ideas regarding habitat restoration and channel modifications outlined in this report could help guide management actions that could improve conditions for native fishes at little or no water cost beyond water already dedicated to other management actions. A complete list of products originating from this work is provided in appendix 1.

California↗
USGS2015

Geologic Map of Baranof Island, southeastern Alaska

This map updates the geology of Baranof Island based on fieldwork, petrographic analyses, paleontologic ages, and isotopic ages. These new data provide constraints on depositional and metamorphic ages of lithostratigraphic rock units and the timing of structures that separate them. Kinematic analyses and thermobarometric calculations provide insights on the regional tectonic processes that affected the rocks on Baranof Island. The rocks on Baranof Island are components of a Paleozoic to Early Tertiary oceanic volcanic arc complex, including sedimentary and volcanic rocks that were deposited on and adjacent to the arc complex, deformed, and accreted. The arc complex consists of greenschist to amphibolite facies Paleozoic metavolcanic and metasedimentary rocks overlain by lower-grade Triassic metasedimentary and metavolcanic rocks and intruded by Jurassic calc-alkaline plutons. The Paleozoic rocks correlate well in age and lithology with rocks of the Sicker and Buttle Lake Groups of the Wrangellia terrane on Vancouver Island and differ from rocks of the Skolai Group that constitute basement to type-Wrangellia in the Wrangell Mountains. The Jurassic intrusive rocks are correlative with plutons that intrude the Wrangellia terrane on Vancouver Island but are lacking in the Wrangell Mountains. The rocks accreted beneath the arc complex are referred to as the Baranof Accretionary Complex in this report and are correlated with the Chugach Accretionary Complex of southern and southeastern Alaska and with the Pacific Rim Complex on Vancouver Island. Stratigraphic correlations between upper- and lower-plate rocks on Baranof Island and western Chichagof Island with rocks on Haida Gwaii and Vancouver Island, in addition to correlative ages of intrusive rocks and restorations of the Fairweather-Queen Charlotte, Chatham Strait, and Peril Strait Faults that define the Baranof-Chichagof block, suggest Baranof Island was near Vancouver Island at the time of initiation of arc magmatism in the Early Jurassic. Early Eocene plutons that intruded the accretionary complex outboard of the arc on Baranof Island are attributed to anatectic melting of trench sediments resulting from subduction of a spreading center. Oligocene intrusive rocks on Baranof Island correlate in age and composition with intrusive rocks in the Kano Plutonic Suite on Haida Gwaii, and similar magmatic sources are inferred.

Alaska↗
USGS2012

Sources and sinks of filtered total mercury and concentrations of total mercury of solids and of filtered methylmercury, Sinclair Inlet, Kitsap County, Washington, 2007-10

The majority of filtered total mercury in the marine water of Sinclair Inlet originates from salt water flowing from Puget Sound. About 420 grams of filtered total mercury are added to Sinclair Inlet each year from atmospheric, terrestrial, and sedimentary sources, which has increased filtered total mercury concentrations in Sinclair Inlet (0.33 nanograms per liter) to concentrations greater than those of the Puget Sound (0.2 nanograms per liter). The category with the largest loading of filtered total mercury to Sinclair Inlet included diffusion of porewaters from marine sediment to the water column of Sinclair Inlet and discharge through the largest stormwater drain on the Bremerton naval complex, Bremerton, Washington. However, few data are available to estimate porewater and stormwater releases with any certainty. The release from the stormwater drain does not originate from overland flow of stormwater. Rather total mercury on soils is extracted by the chloride ions in seawater as the stormwater is drained and adjacent soils are flushed with seawater by tidal pumping. Filtered total mercury released by an unknown freshwater mechanism also was observed in the stormwater flowing through this drain. Direct atmospheric deposition on the Sinclair Inlet, freshwater discharge from creek and stormwater basins draining into Sinclair Inlet, and saline discharges from the dry dock sumps of the naval complex are included in the next largest loading category of sources of filtered total mercury. Individual discharges from a municipal wastewater treatment plant and from the industrial steam plant of the naval complex constituted the loading category with the third largest loadings. Stormwater discharge from the shipyard portion of the naval complex and groundwater discharge from the base are included in the loading category with the smallest loading of filtered total mercury. Presently, the origins of the solids depositing to the sediment of Sinclair Inlet are uncertain, and consequently, concentrations of sediments can be qualitatively compared only to total mercury concentrations of solids suspended in the water column. Concentrations of total mercury of suspended solids from creeks, stormwater, and even wastewater effluent discharging into greater Sinclair Inlet were comparable to concentrations of solids suspended in the water column of Sinclair Inlet. Concentrations of total mercury of suspended solids were significantly lower than those of marine bed sediment of Sinclair Inlet; these suspended solids have been shown to settle in Sinclair Inlet. The settling of suspended solids in the greater Sinclair Inlet and in Operable Unit B Marine of the naval complex likely will result in lower concentrations of total mercury in sediments. Such a decrease in total mercury concentrations was observed in the sediment of Operable Unit B Marine in 2010. However, total mercury concentrations of solids discharged from several sources from the Bremerton naval complex were higher than concentrations in sediment collected from Operable Unit B Marine. The combined loading of solids from these sources is small compared to the amount of solids depositing in OU B Marine. However, total mercury concentration in sediment collected at a monitoring station just offshore one of these sources, the largest stormwater drain on the Bremerton naval complex, increased considerably in 2010. Low methylmercury concentrations were detected in groundwater, stormwater, and effluents discharged from the Bremerton naval complex. The highest methylmercury concentrations were measured in the porewaters of highly reducing marine sediment in greater Sinclair Inlet. The marine sediment collected off the largest stormwater drain contained low concentrations of methylmercury in porewater because these sediments were not highly reducing.

Washington↗
USGS1971

Origin and emplacement of the ultramafic rocks of the Emigrant Gap area, California

The ultramafic bodies of the Emigrant Gap area are part of a mafic complex within a large composite pluton of the northern Sierra Nevada. The pluton was magmatically emplaced and is surrounded by an aureole of hornblende-hornfels facies rocks. Inclusions of country rock in ultramafic rock are of pyroxene-hornfels facies and appear to have been partly melted. Gravity studies indicate that the ultramafic bodies have near-vertical contacts extending to depths of at least 1½ to 2½ km. The mafic complex shows rough concentric zoning of rock types: ultramafic bodies occur at the core; gabbro forms a discontinuous intermediate unit; and diorite, tonalite, and granodiorite occur at the margins. Within the ultramafic bodies, unserpentinized wehrlitic peridotite is dominant; dunite and olivine clinopyroxenite are present but greatly subordinate. The ultramafic rocks consist almost entirely of olivine (FO 80 ) and diopside (Ca 46 Mg 46 Fe 8 ); orthopyroxene, hornbolende, and plagioclase occur locally. The gabbro, diorite, tonalite, and granodiorite contain both ortho- and clinopyroxene. Both ultramafic and two-pyroxene-bearing rocks were emplaced nearly simultaneously, as partly crystallized magmas and magmatic crystal mushes that had similar temperature. In all the rocks the structures are dominantly magmatic and were produced by sorting and orientation of crystals by magmatic flow. Structures produced by post-consolidation deformation and replacement are minor and local. The structural and chemical relations within the mafic complex suggest that all the rocks are derived from a single gabbroic magma by crystal fractionation, with the ultramafic rocks formed by mechanical accumulation of early crystallized mafic minerals, and the two pyroxene-bearing granodiorite crystallized from a felsic differentiate. It is likely that flowage differentiation was the dominant process of crystal segregation. The Emigrant Gap mafic complex is similar in structure, rock texture, and mineralogy to zoned ultramafic complexes, such as those of south-eastern Alaska, and is very different from either stratiform or alpine-type bodies. Though unlike the Alaskan bodies in detail, it appears that this complex should be classed with the zoned complexes in any broad grouping of ultramafic occurrences.

California↗
USGS1994

Hydrogeology and hydrochemistry of dunes and wetlands along the southern shore of Lake Michigan, Indiana

The dunes and the wetlands along the southern shore of Lake Michigan are underlain by a complex aquifer system composed of unconsolidated glacial, lacustrine, and eolian deposits. Surficial dune, beach, and glacial lacustrine sands compose an extensive surficial aquifer. The underlying drift contains three major confined sand aquifers. Potentiometric and hydrochemical data are consistent with a conceptual model in which regional and intermediate flow systems, recharged in end moraines south of the dune-beach complexes, discharge into Lake Michigan and the Great Marsh by upward leakage through unconsolidated sediments. Local flow systems in the surficial aquifer, recharged in the major dune-beach complexes, discharge into streams, ditches, and ponded areas in the adjacent interdunal wetlands. Shallow ground water discharges directly into Lake Michigan only north of a water-table divide that underlies the dune-beach complex along the shoreline. The position of ground-water seepage faces is affected by transient water-table mounds observed in the dune-beach complexes at the margins of wetlands. Substantial recharge to the dune complexes probably occurs near these dune-wetland margins. In the dune-beach complexes and intradunal wetlands, the shallow ground and wetland waters are dilute calcium bicarbonate and calcium bicarbonate sulfate types. More mineralized bicarbonate water types having variable proportions of calcium, magnesium, and sodium are found in interior parts of the Great Marsh because this area is probably a discharge zone for the regional and intermediate flow systems.

Open-File Report↗
USGS2009

Geohydrologic Investigations and Landscape Characteristics of Areas Contributing Water to Springs, the Current River, and Jacks Fork, Ozark National Scenic Riverways, Missouri

The Ozark National Scenic Riverways (ONSR) is a narrow corridor that stretches for approximately 134 miles along the Current River and Jacks Fork in southern Missouri. Most of the water flowing in the Current River and Jacks Fork is discharged to the rivers from springs within the ONSR, and most of the recharge area of these springs is outside the ONSR. This report describes geohydrologic investigations and landscape characteristics of areas contributing water to springs and the Current River and Jacks Fork in the ONSR. The potentiometric-surface map of the study area for 2000-07 shows that the groundwater divide extends beyond the surface-water divide in some places, notably along Logan Creek and the northeastern part of the study area, indicating interbasin transfer of groundwater between surface-water basins. A low hydraulic gradient occurs in much of the upland area west of the Current River associated with areas of high sinkhole density, which indicates the presence of a network of subsurface karst conduits. The results of a low base-flow seepage run indicate that most of the discharge in the Current River and Jacks Fork was from identified springs, and a smaller amount was from tributaries whose discharge probably originated as spring discharge, or from springs or diffuse groundwater discharge in the streambed. Results of a temperature profile conducted on an 85-mile reach of the Current River indicate that the lowest average temperatures were within or downstream from inflows of springs. A mass-balance on heat calculation of the discharge of Bass Rock Spring, a previously undescribed spring, resulted in an estimated discharge of 34.1 cubic feet per second (ft3/s), making it the sixth largest spring in the Current River Basin. The 13 springs in the study area for which recharge areas have been estimated accounted for 82 percent (867 ft3/s of 1,060 ft3/s) of the discharge of the Current River at Big Spring during the 2006 seepage run. Including discharge from other springs, the cumulative discharge from springs was over 90 percent of the river discharge at most of the spring locations, and was 92 percent at Big Spring and at the lower end of the ONSR. The discharge from the 1.9-mile long Pulltite Springs Complex measured in the 2006 seepage run was 88 ft3/s. Most of this (77 ft3/s) was from the first approximately 0.25 mi of the Pulltite Springs Complex. It has been estimated that the annual mean discharge from the Current River Springs Complex is 125 ft3/s, based on an apparent discharge of 50 ft3/s during a 1966 U.S. Geological Survey seepage run. However, a reinterpretation of the 1966 seepage run data shows that the discharge from the Current River Springs Complex instead was about 12.6 ft3/s, and the annual mean discharge was estimated to be 32 ft3/s, substantially less than 125 ft3/s. The 2006 seepage run showed a gain of only 12 ft3/s from the combined Round Spring and Current River Springs Complex from the mouth of Sinking Creek to 0.7 mi upstream from Root Hollow. The 2006 temperature profile measurements did not indicate any influx of spring discharge throughout the length of the Current River Springs Complex. The spring recharge areas with the largest number of identified sinkholes are Big Spring, Alley Spring, and Welch Spring. The spring recharge areas with the largest number of sinkholes per square mile of recharge area are Alley Spring, Blue Spring (Jacks Fork), Welch Spring, and Round Spring and the Current River Springs Complex. Using the currently known locations of losing streams, the Big Spring recharge area has the largest number of miles of losing stream, and the Bass Rock Spring recharge area has the largest number of miles of losing stream per unit recharge area. The spring recharge areas with the most open land and the least forested land per unit recharge area are Blue Spring (Jacks Fork), Welch Spring, Montauk Springs, and Alley Spring. The spring recharge areas with the least amount

Scientific Investigations Report↗
USGS2017

Soils as relative-age dating tools

Soils develop at the earth's surface via multiple processes that act through time. Precluding burial or disturbance, soil genetic horizons form progressively and reflect the balance among formation processes, surface age, and original substrate composition. Soil morphology provides a key link between process and time (soil age), enabling soils to serve as both relative and numerical dating tools for geomorphic studies and landscape evolution. Five major factors define the contemporary state of all soils: climate, organisms, topography, parent material, and time. Soils developed on similar landforms and parent materials within a given landscape comprise what we term a soil/landform/substrate complex. Soils on such complexes that differ in development as a function of time represent a soil chronosequence. In a soil chronosequence, time constitutes the only independent formation factor; the other factors act through time. Time dictates the variations in soil development or properties (field or laboratory measured) on a soil/landform/substrate complex. Using a dataset within the chronosequence model, we can also formulate various soil development indices based upon one or a combination of soil properties, either for individual soil horizons or for an entire profile. When we evaluate soil data or soil indices mathematically, the resulting equation creates a chronofunction. Chronofunctions help quantify processes and mechanisms involved in soil development, and relate them mathematically to time. These rigorous kinds of comparisons among and within soil/landform complexes constitute an important tool for relative-age dating. After determining one or more absolute ages for a soil/landform complex, we can calculate quantitative soil formation, and or landform-development rates. Multiple dates for several complexes allow rate calculations for soil/landform-chronosequence development and soil-chronofunction calibration.

Book chapter↗
USGS1990

Adsorption of selenium by amorphous iron oxyhydroxide and manganese dioxide

This work compares and models the adsorption of selenium and other anions on a neutral to alkaline surface (amorphous iron oxyhydroxide) and an acidic surface (manganese dioxide). Selenium adsorption on these oxides is examined as a function of pH, particle concentration, oxidation state, and competing anion concentration in order to assess how these factors might influence the mobility of selenium in the environment. The data indicate that 1. 1) amorphous iron oxyhydroxide has a greater affinity for selenium than manganese dioxide, 2. 2) selenite [Se(IV)] adsorption increases with decreasing pH and increasing particle concentration and is stronger than selenate [Se(VI)] adsorption on both oxides, and 3. 3) selenate does not adsorb on manganese dioxide. The relative affinity of selenate and selenite for the oxides and the lack of adsorption of selenate on a strongly acidic surface suggests that selenate forms outer-sphere complexes while selenite forms inner-sphere complexes with the surfaces. The data also indicate that the competition sequence of other anions with respect to selenite adsorption at pH 7.0 is phosphate > silicate > molybdate > fluoride > sulfate on amorphous iron oxyhydroxide and molybdate ??? phosphate > silicate > fluoride > sulfate on manganese dioxide. The adsorption of phosphate, molybdate, and silicate on these oxides as a function of pH indicates that the competition sequences reflect the relative affinities of these anions for the surfaces. The Triple Layer surface complexation model is used to provide a quantitative description of these observations and to assess the importance of surface site heterogeneity on anion adsorption. The modeling results suggest that selenite forms binuclear, innersphere complexes with amorphous iron oxyhydroxide and monodentate, inner-sphere complexes with manganese dioxide and that selenate forms outer-sphere, monodentate complexes with amorphous iron oxyhydroxide. The heterogeneity of the oxide surface sites is reflected in decreasing equilibrium constants for selenite with increasing adsorption density and both experimental observations and modeling results suggest that manganese dioxide has fewer sites of higher energy for selenite adsorption than amorphous iron oxyhydroxide. Modeling and interpreting the adsorption of phosphate, molybdate, and silicate on the oxides are made difficult by the lack of constraint in choosing surface species and the fact that equally good fits can be obtained with different surface species. Finally, predictions of anion competition using the model results from single adsorbate systems are not very successful because the model does not account for surface site heterogeneity. Selenite adsorption data from a multi-adsorbate system could be fit if the equilibrium constant for selenite is decreased with increasing anion adsorption density.

Geochimica et Cosmochimica Acta↗
USGS2008

Dissolved metals and associated constituents in abandoned coal-mine discharges, Pennsylvania, USA. Part 2: Geochemical controls on constituent concentrations

Water-quality data for discharges from 140 abandoned mines in the Anthracite and Bituminous Coalfields of Pennsylvania reveal complex relations among the pH and dissolved solute concentrations that can be explained with geochemical equilibrium models. Observed values of pH ranged from 2.7 to 7.3 in the coal-mine discharges (CMD). Generally, flow rates were smaller and solute concentrations were greater for low-pH CMD samples; pH typically increased with flow rate. Although the frequency distribution of pH was similar for the anthracite and bituminous discharges, the bituminous discharges had smaller median flow rates; greater concentrations of SO4, Fe, Al, As, Cd, Cu, Ni and Sr; comparable concentrations of Mn, Cd, Zn and Se; and smaller concentrations of Ba and Pb than anthracite discharges with the same pH values. The observed relations between the pH and constituent concentrations can be attributed to (1) dilution of acidic water by near-neutral or alkaline ground water; (2) solubility control of Al, Fe, Mn, Ba and Sr by hydroxide, sulfate, and/or carbonate minerals; and (3) aqueous SO4-complexation and surface-complexation (adsorption) reactions. The formation of AlSO4+ and AlHSO42 + complexes adds to the total dissolved Al concentration at equilibrium with Al(OH)3 and/or Al hydroxysulfate phases and can account for 10-20 times greater concentrations of dissolved Al in SO4-laden bituminous discharges compared to anthracite discharges at pH of 5. Sulfate complexation can also account for 10-30 times greater concentrations of dissolved FeIII concentrations at equilibrium with Fe(OH)3 and/or schwertmannite (Fe8O8(OH)4.5(SO4)1.75) at pH of 3-5. In contrast, lower Ba concentrations in bituminous discharges indicate that elevated SO4 concentrations in these CMD sources could limit Ba concentrations by the precipitation of barite (BaSO4). Coprecipitation of Sr with barite could limit concentrations of this element. However, concentrations of dissolved Pb, Cu, Cd, Zn, and most other trace cations in CMD samples were orders of magnitude less than equilibrium with sulfate, carbonate, and/or hydroxide minerals. Surface complexation (adsorption) by hydrous ferric oxides (HFO) could account for the decreased concentrations of these divalent cations with increased pH. In contrast, increased concentrations of As and, to a lesser extent, Se with increased pH could result from the adsorption of these oxyanions by HFO at low pH and desorption at near-neutral pH. Hence, the solute concentrations in CMD and the purity of associated "ochres" formed in CMD settings are expected to vary with pH and aqueous SO4 concentration, with potential for elevated SO4, As and Se in ochres formed at low pH and elevated Cu, Cd, Pb and Zn in ochres formed at near-neutral pH. Elevated SO4 content of ochres could enhance the adsorption of cations at low pH, but decrease the adsorption of anions such as As. Such information on environmental processes that control element concentrations in aqueous samples and associated precipitates could be useful in the design of systems to reduce dissolved contaminant concentrations and/or to recover potentially valuable constituents in mine effluents.

Applied Geochemistry↗
USGS2018

A sequential selective dissolution method to quantify storage and stability of organic carbon associated with Al and Fe hydroxide phases

Stabilization of SOM (soil organic matter) is regulated in part by sorption and desorption reactions happening at mineral surfaces, as well as precipitation and dissolution of organo-metal complexes. Fe and Al hydroxides play a particularly significant role in SOM stabilization in soils due to their ubiquitous distribution and their highly reactive surface properties. Iron and Al hydroxides exist in soils across a wide spectrum of crystallinity, ranging from dissolved Fe and Al cations which combine with organics to form organo-metal precipitates to the more crystalline end members, goethite and gibbsite, which sorb SOM through a variety of molecular interactions. Though the importance of these sorption and precipitation reactions has long been recognized, the distribution of SOM among Fe and Al hydroxides of differing crystallinity has not been well quantified, nor has the timescale over which these stabilization mechanisms operate. In an attempt to measure the distribution of organic C among (i) Al- and Fe-humus complexes (ii) short-range-order (SRO) Al and Fe hydroxide surfaces and (iii) crystalline Fe oxyhydroxide surfaces, a single method combining several selective mineral dissolutions was applied to soils of four different geneses (a tropical forest Andisol, a temperate forest basaltic Mollisol, a Mediterranean coastal prairie Mollisol, and a northern mixed hardwood forest Spodosol). The traditional reactants used in selective dissolutions were replaced with carbon-free analogues so that the carbon released along with the Fe and Al at each stage of the selective dissolution process could be measured. Selective dissolutions were performed sequentially: Na-pyrophosphate (organo-Al and Fe complexes) followed by hydroxylamine (SRO Al and Fe hydroxides) followed by dithionite-HCl (crystalline Fe hydroxides). Carbon, Al, and Fe concentrations, as well as radiocarbon abundance were measured in the solutions yielded by each stage of the selective dissolution process. Results suggest that precipitation of organo-metal complexes (Na-pyrophosphate extractable C) often accounts for the largest pool of stabilized C among the three selectively dissolved pools, but these complexes were 14 C enriched in comparison to C from the other selectively dissolved pools and the residual C left on crystalline mineral surfaces after all three stages of selective dissolution. Hydroxylamine and dithionite-HCl extractable C pools were, on average, small and often below detection level in temperate soils. However, radiocarbon values for these C pools were generally depleted in comparison to other pools. These results suggest variation in organo-mineral complex stability is associated with degree of crystallinity of the mineral phase. Overall, this work suggests that sequential selective dissolution methods are a promising tool for characterizing the content and isotopic composition of soil C associated with distinct organo-mineral and organo-metal associations.

Geoderma↗
USGS2002

Molecular structure of the decamolybdodicobaltate(III) ion

When solutions of cobalt(II) ion and heptamolybdate ion (Mo₇O₂₄⁶⁻) are mixed in the presence of an oxidizing agent (such as bromine), Kurnakov, Hall, and others found that an emerald green complex is formed as the main product, namely, the heteropoly complex ion hexamolybdocobaltate(III), which forms salts such as (NH₄)₃[H₆CoMo₆O₂₄]·12H₂O. Friedheim and Keller showed that at the same time a small amount of another complex is also formed, having a Co:Mo ratio of 1:5. Tsigdinos, et al., found that if a hot solution of the hexamolybdocobaltate complex ion is treated with activated charcoal or Raney nickel the 1:6 complex is converted almost entirely to the 1:5 complex. These workers proved the latter to be a dimer, and formulated the ammonium salt (earlier prepared by Friedheim and Keller) as (NH₄)₆[Co₂Mo₁₀O₃₆]·10H₂O. We have now completed a crystal structure analysis of this interesting compound, which shows the proper formula to be (NH₄)₆[H₄Co₃Mo₁₀O₃₈]·7H₂O.

Journal of the American Chemical Society↗
USGS1996

Experimental investigation and modeling of uranium (VI) transport under variable chemical conditions

The transport of adsorbing and complexing metal ions in porous media was investigated with a series of batch and column experiments and with reactive solute transport modeling. Pulses of solutions containing U(VI) were pumped through columns filled with quartz grains, and the breakthrough of U(VI) was studied as a function of variable solution composition ( p H, total U(VI) concentration, total fluoride concentration, and p H-buffering capacity). Decreasing p H and the formation of nonadsorbing aqueous complexes with fluoride increased U(VI) mobility. A transport simulation with surface complexation model (SCM) parameters estimated from batch experiments was able to predict U(VI) retardation in the column experiments within 30%. SCM parameters were also estimated directly from transport data, using the results of three column experiments collected at different p H and U(VI) pulse concentrations. SCM formulations of varying complexity (multiple surface types and reaction stoichiometries) were tested to examine the trade-off between model simplicity and goodness of fit to breakthrough. A two-site model (weak- and strong-binding sites) with three surface complexation reactions fit these transport data well. With this reaction set the model was able to predict (1) the effects of fluoride complexation on U(VI) retardation at two different p H values and (2) the effects of temporal variability of p H on U(VI) transport caused by low p H buffering. The results illustrate the utility of the SCM approach in modeling the transport of adsorbing inorganic solutes under variable chemical conditions.

Water Resources Research↗
USGS1945

Petrography, structures, and petrofabrics of the Pinckneyville quartz diorite, Alabama

The Pinckneyville quartz diorite complex underlies an area in eastern Alabama extending from the Coosa River in northwest Elmore County northeast through Coosa and Tallapoosa counties into Clay County. Dark-gray, coarse-grained quartz diorite gneiss constitutes the major part of the complex, but there are smaller amounts of granodiorite and granite gneiss. Hornblende-biotite gneisses also occur and are considered to represent metamorphosed basic sills and dikes intruded before the quartz diorite complex. Schist septa lie within the complex and are usually parallel to the regional strike. The sequence of intrusion as interpreted from inclusions and petrographic data is (1) quartz diorite, (2) granodiorite, (3) granite. Small but persistent amounts of allanite and epidote are characteristic of the rocks of the complex. The texture is subporphyritic and shows evidence of protoclastic deformation. A northeast-southwest trend of inclusions, foliation, lineation, and contacts dominates. Primary flow structures are shown in the orientation of inclusions and micas. Secondary structures were superposed on the original flow structures shortly after intrusion and prior to complete consolidation. A prominent secondary structure is a lineation in b. Stretching in b is indicated by boudinage structures, the lineation, and small displacements of dikes. The intensity of the planar structures in the gneiss grades from strong to indistinct or lacking from east to west. Structures in schist inclusions indicate that some folding had taken place prior to intrusion. Thin pegmatite, granodiorite, and granite dikes are common. Most of them are essentially parallel to the regional strike. The petrographic boundary between gneiss and schist is always sharp. On a large scale, the gneiss structures are essentially parallel to the contacts, but slight to marked discordant relations occur at many localities. The schist structures usually parallel the contacts. Petrofabric analysis confirms the structural field observations. The mica fabrics are ac -girdles and are most complete where the foliation is weakest. Microscopic s -planes do not always coincide with the observed foliation. The quartz fabrics are also ac -girdles but are not so well developed as the mica girdles. Quartz orientations cannot always be related to known s -planes. It is concluded that the Pinckneyville quartz diorite complex represents a syntectonic intrusion—that is, that intrusion took place while external or regional forces were still active. The shape of the intrusion was controlled largely by the wall-rock structures which had developed earlier. The rocks show both igneous and metamorphic characteristics because the intrusion took place under regional metamorphic conditions.

Alabama↗
USGS2020

An analysis of the factors that control fault zone architecture and the importance of fault orientation relative to regional stress

The moment magnitude 7.2 El Mayor−Cucapah (EMC) earthquake of 2010 in northern Baja California, Mexico produced a cascading rupture that propagated through a geometrically diverse network of intersecting faults. These faults have been exhumed from depths of 6−10 km since the late Miocene based on low-temperature thermochronology, synkinematic alteration, and deformational fabrics. Coseismic slip of 1−6 m of the EMC event was accommodated by fault zones that displayed the full spectrum of architectural styles, from simple narrow fault zones (<100 m in width) that have a single high-strain core, to complex wide fault zones (>100 m in width) that have multiple anastomosing high-strain cores. As fault zone complexity and width increase the full spectrum of observed widths (20−200 m), coseismic slip becomes more broadly distributed on a greater number of scarps that form wider arrays. Thus, the infinitesimal slip of the surface rupture of a single earthquake strongly replicates many of the fabric elements that were developed during the long-term history of slip on the faults at deeper levels of the seismogenic crust. We find that factors such as protolith, normal stress, and displacement, which control gouge production in laboratory experiments, also affect the architectural complexity of natural faults. Fault zones developed in phyllosilicate-rich metasedimentary gneiss are generally wider and more complex than those developed in quartzo-feldspathic granitoid rocks. We hypothesize that the overall weakness and low strength contrast of faults developed in phyllosilicate rich host rocks leads to strain hardening and formation of broad, multi-stranded fault zones. Fault orientation also strongly affects fault zone complexity, which we find to increase with decreasing fault dip. We attribute this to the higher resolved normal stresses on gently dipping faults assuming a uniform stress field compatible with this extensional tectonic setting. The conditions that permit slip on misoriented surfaces with high normal stress should also produce failure of more optimally oriented slip systems in the fault zone, promoting complex branching and development of multiple high-strain cores. Overall, we find that fault zone architecture need not be strongly affected by differences in the amount of cumulative slip and instead is more strongly controlled by protolith and relative normal stress.

Baja California↗