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Status Assessment of Laysan and Black-Footed Albatrosses, North Pacific Ocean, 1923-2005

Over the past century, Laysan (Phoebastria immutabilis) and black-footed (Phoebastria nigripes) albatrosses have been subjected to high rates of mortality and disturbance at the breeding colonies and at sea. Populations were greatly reduced and many colonies were extirpated around the turn of the 20th century as a result of feather hunting. Populations were recovering when military occupation of several breeding islands during World War II led to new population declines at these islands and additional colony extirpations. At sea, thousands of Laysan and black-footed albatrosses were killed each year in high-seas driftnet fisheries, especially from 1978 until the fisheries were banned in 1992. Through the 1990s, there was a growing awareness of the large numbers of albatrosses that were being killed in longline fisheries. During the 1990s, other anthropogenic factors, such as predation by non-native mammals and exposure to contaminants, also were documented to reduce productivity or increase mortality. In response to the growing concerns over the impacts of these threats on albatross populations, the U.S. Fish and Wildlife Service contracted with the U.S. Geological Survey to conduct an assessment of Laysan and black-footed albatross populations. This assessment includes a review of the taxonomy, legal status, geographic distribution, natural history, habitat requirements, threats, and monitoring and management activities for these two species. The second part of the assessment is an analysis of population status and trends from 1923 to 2005. Laysan and black-footed albatrosses forage throughout the North Pacific Ocean and nest on tropical and sub-tropical oceanic islands from Mexico to Japan. As of 2005, 21 islands support breeding colonies of one or both species. The core breeding range is the Hawaiian Islands, where greater than 99 percent of the World's Laysan albatrosses and greater than 95 percent of the black-footed albatrosses nest on the small islands and atolls of the Northwestern Hawaiian Islands. These islands are all protected as part of the Papahanaumokuakea Marine National Monument. Albatrosses are long-lived seabirds with deferred maturity, low fecundity, and high rates of adult survival. Their life history characteristics make populations especially vulnerable, to small increases in adult mortality. The primary threats to Laysan and black-footed albatrosses include interactions with commercial fisheries, predation by introduced mammals, reduced reproductive output due to contaminants, nesting habitat loss and degradation due to human development and invasive plant species, and potential loss and degradation of habitat due to climate change and sea-level rise. Incidental mortality (bycatch) in commercial fisheries is the greatest anthropogenic source of mortality (post-fledging) for both species. We found that longline fishing effort prior to the 1980s was greater than previously estimated and a very significant source of mortality. Regulations to minimize and monitor albatross mortality have been enacted in most U.S. and Canadian longline fisheries, but monitoring of bycatch rates and regulations to minimize seabird mortality are extremely limited in the much larger multinational longline fleets. Management to address threats at the breeding colonies is ongoing and includes eradication or control of non-native species, habitat management, and abatement programs to reduce impacts of contaminants. Effective long-term conservation and management of the Laysan and black-footed albatrosses require management and monitoring at the breeding colonies and at sea and continued assessment of population status and trends. We evaluated the status and trends of Laysan and black-footed albatross populations using linear regression, population viability analysis (PVA), and age-structured matrix models. Analyses were predominantly based on nest-count data gathered at French Frigate Shoals, Laysan Island, and Midw

Scientific Investigations Report↗

Shallow hydrogeologic framework of the Tully Valley mudboil area, Onondaga County, New York

Mudboils have been documented in the Tully Valley in southern Onondaga County, New York, since the late 1890s. Sediment-laden water from the mudboils flows into Onondaga Creek, which empties into Onondaga Lake at Syracuse 15 miles to the north. Turbidity from the mudboils has degraded the water quality of Onondaga Creek despite a series of mitigation efforts that began in the early 1990s. Turbidity mitigation actions presently (2025) being considered include creek relocation and offline sediment settling. In support of these proposed actions during 2021–23, the U.S. Geological Survey, in cooperation with the New York State Department of Environmental Conservation, U.S. Environmental Protection Agency, Onondaga Nation, Onondaga Environmental Institute, and Central New York Regional Planning and Development Board, collected and analyzed geologic, hydrologic, geophysical, and geotechnical data to characterize the shallow hydrogeology along four proposed creek-relocation paths and in the proposed offline settling basin area. The investigation indicated that the four proposed creek-relocation paths, two east of Onondaga Creek and two west of Onondaga Creek, are underlain by sediments including muck, alluvium, mudboil deposits, alluvial-fan sand and gravel, and lacustrine fines. The proposed excavations would penetrate partially to fully saturated conditions: generally, the water table is shallow near the creek and deep on the alluvial fans. The shallowest excavation, about 5 feet below land surface, would be near the creek and primarily in alluvium, and the deepest excavation, as much as 30 feet below land surface, would be in the alluvial-fan deposits. Brackish waters would be penetrated by proposed channel excavations on the eastern side of Onondaga Creek in an area downgradient from a potentially leaking historical salt-exploration borehole and near the main mudboil area. Excavation in these areas likely would provide a continuous source of brackish groundwater to the relocated creek. Proposed channel excavations of muck, soft to very soft lacustrine fines, and mudboil-type sediments in mudboil and suspected mudboil areas would pose an excavation and slope stability challenge and would have the greatest potential to create new mudboils. Proposed channel excavations below the water table on the Rattlesnake Gulf and Rainbow Creek alluvial fans would intercept groundwater and make the constructed streambank susceptible to seepage-induced slope instability. The substantial water-level fluctuation in the sediments of both alluvial fans would aggravate the stability condition. In addition, excavation on the Rattlesnake Gulf alluvial fan would have the potential to affect water-supply springs at the toe of the fan. The proposed offline settling basin area is in the northern part of the Rattlesnake Gulf alluvial fan. Natural and man-made diversions of Rattlesnake Gulf have resulted in saturated conditions in the general area of the proposed basin. The proposed offline settling basin would be excavated in, and berms would be constructed on, alluvial-fan deposits and lacustrine fines. In the proposed basin area, the alluvial deposits overlying the lacustrine fines are less than 10 feet thick. Excavation, berm construction, and loading of the saturated, soft to very soft lacustrine fines may be problematic and require soil strengthening.

New York↗

Surficial geologic map of the Evansville, Indiana, and Henderson, Kentucky, area

The geologic map of the Evansville, Indiana, and Henderson, Kentucky, area depicts and describes surficial deposits according to their origin and age. Unconsolidated alluvium and outwash fill the Ohio River bedrock valley and attain maximum thickness of 33-39 m under Diamond Island, Kentucky, and Griffith Slough, south of Newburgh, Indiana. The fill is chiefly unconsolidated, fine- to medium-grained, lithic quartz sand, interbedded with clay, clayey silt, silt, coarse sand, granules, and gravel. Generally, the valley fill fines upward from the buried bedrock surface: a lower part being gravelly sand to sandy gravel, a middle part mostly of sand, and a surficial veneer of silt and clay interspersed with sandy, natural levee deposits at river's edge. Beneath the unconsolidated fill are buried and discontinuous, lesser amounts of consolidated fill unconformably overlying the buried bedrock surface. Most of the glaciofluvial valley fill accumulated during the Wisconsin Episode (late Pleistocene). Other units depicted on the map include creek alluvium, slackwater lake (lacustrine) deposits, colluvium, dune sand, loess, and sparse bedrock outcrops. Creek alluvium underlies creek floodplains and consists of silt, clayey silt, and subordinate interbedded fine sand, granules, and pebbles. Lenses and beds of clay are present locally. Silty and clayey slackwater lake (lacustrine) deposits extensively underlie broad flats northeast of Evansville and around Henderson and are as thick as 28 m. Fossil wood collected from an auger hole in the lake and alluvial deposits of Little Creek, at depths of 10.6 m and 6.4 m, are dated 16,650+-50 and 11,120+-40 radiocarbon years, respectively. Fossil wood collected from lake sediment 16 m below the surface in lake sediment was dated 33,100+-590 radiocarbon years. Covering the hilly bedrock upland is loess (Qel), 3-7.5 m thick in Indiana and 9-15 m thick in Kentucky, deposited about 22,000-12,000 years before present. Most mapped surficial deposits in the quadrangle are probably no older than about 55,000 years. Lithologic logs, shear-wave velocities, and other cone penetrometer data are used to interpret depositional environments and geologic history of the surficial deposits. This map, which includes an area of slightly more than seven 7.5-minute quadrangles, serves several purposes. It is a tool for assessing seismic and flood hazards of a major urban area; aids urban planning; conveys geologic history; and locates aggregate resources. The map was produced concurrently with research by seismologists to determine places where the surficial deposits may tend to liquefy and (or) to amplify ground motions during strong earthquakes. Such hazardous responses to shaking are related to the characteristics of the geologic materials and topographic position, which the geologic map depicts. The geologic map is an element in the cooperative seismic hazard assessment program among the States of Indiana, Kentucky, and Illinois and the U.S. Geological Survey, funded by the National Earthquake Hazards Reduction Program and National Cooperative Geologic Mapping Program of the U.S. Geological Survey.

Indiana, Kentucky↗

Determination of time-of-travel, dispersion characteristics, and oxygen reaeration coefficients during low streamflows--Lower Tacony/Frankford Creek, Philadelphia, Pennsylvania

Time-of-travel, dispersion characteristics, and oxygen reaeration coefficients were determined by use of dye and gas tracing for a 2-mile reach of Tacony/Frankford Creek in Philadelphia, southeastern Pennsylvania. The reach frequently has concentrations of dissolved oxygen (DO) below the water-quality standard of 4 milligrams per liter during warm months. Several large combined sewer overflows (CSOs), including one of the largest in Philadelphia (former Wingohocking Creek), discharge to the study reach in this urbanized watershed, affecting water quality and the timing and magnitude of storm peaks. In addition, a dam that commonly results in backwater conditions and reduced natural reaeration is present a few hundred feet from the end of the study reach. Time-of-travel and reaeration data were collected under base-flow conditions in August and September 2009 for three sub-reaches from Roosevelt Boulevard (U.S. Route 1) to Castor Avenue. Determination of traveltimes to the centroid of the dye cloud were needed for calculation of the reaeration coefficients. Results of the dye study in Tacony/Frankford Creek indicate that traveltimes were affected by the presence of man-made structures, such as the large scour hole and pool developed at the outfall of the T14 CSO and the dam, both of which reduce stream velocities. Mean stream velocities during the dye-tracer tests ranged from a maximum of 0.44 to 0.04 foot per second through a large pool. The dispersion efficiency of the stream was determined from relations between normalized unit concentrations to time to peak for use in water-quality modeling. Oxygen reaeration coefficients determined by a constant rate-injection method using propane as the tracer gas were as low as 0.04 unit per hour in a long pool affected by backwater conditions behind a dam. The highest reaeration coefficient was 2.29 units per hour for a steep-gradient reach with multiple winding channels through gravel deposits, just downstream of a large scour pool developed at the outlet of the T14 CSO. Reaeration coefficients determined from the field tracer-gas method were compared to values calculated by two other methods, one that is based on theoretical equations using physical properties of the stream as variables and the other that is based on equations using the timing of measured daily maximum DO concentrations in the stream. Reaeration coefficients from the two alternate methods were most similar to values determined from the field tracer-gas method for the upstream portion of the study reach, characterized by free-flowing riffle and pools. Values of reaeration coefficients determined by the tracer-gas method were 2 to 10 times higher than values determined by 2 alternate methods for most subreaches hydraulically affected by man-made structures. In addition to the tracer gas, propane, the gas analysis also included methane, ethane, and ethene, of which only methane was measured in concentrations above a few micrograms per liter. Methane, thought to occur naturally or because of ongoing processes in the stream, was measured in concentrations ranging from 6.6 to 78 micrograms per liter; the concentrations were greatest in sub-reaches dominated by pools.

Pennsylvania↗

Status and understanding of groundwater quality in the Sacramento Metropolitan Domestic-Supply Aquifer study unit, 2017—California GAMA Priority Basin Project

Groundwater quality in the Sacramento Metropolitan Domestic-Supply Aquifer study unit (SacMetro-DSA) was studied from August to November 2017 as part of the second phase of the Priority Basin Project of the California Groundwater Ambient Monitoring and Assessment (GAMA) Program. The study unit is in parts of Amador, Placer, Sacramento, and Sutter Counties, and the extent of the study unit was defined by the location of three California Department of Water Resources groundwater subbasins: the North American, the South American, and the Cosumnes. The SacMetro-DSA focused on groundwater resources used for domestic drinking-water supply, which generally correspond to shallower parts of aquifer systems than those of groundwater resources used for public drinking water supply in the same area. The assessments characterized the quality of untreated groundwater, not the quality of drinking water. This study included two components: (1) a status assessment, which characterized the status of the quality of the groundwater resources used for domestic supply and (2) an understanding assessment, which evaluated the natural and human factors potentially affecting water quality in those resources. The first component of this study—the status assessment—was based on water-quality data collected from 49 sites sampled by the U.S. Geological Survey for the GAMA Priority Basin Project in 2017. The samples were analyzed for volatile organic compounds, pesticides, and naturally present inorganic constituents, such as major ions and trace elements. To provide context, concentrations of constituents measured in groundwater were compared to U.S. Environmental Protection Agency and California State Water Resources Control Board Division of Drinking Water regulatory and non-regulatory benchmarks for drinking-water quality. The status assessment used a grid-based method to estimate the proportion of the groundwater resources that had concentrations of water-quality constituents approaching or above benchmark concentrations. This method provides statistically unbiased results at the study-area scale and permits comparisons to other GAMA Priority Basin Project study areas. The second component of this study—the understanding assessment—identified the natural and human factors that potentially affect groundwater quality by evaluating land-use characteristics, groundwater age, and geochemical and hydrologic conditions of the domestic-supply aquifer and related these data to constituents identified in the status assessment for further evaluation. In the SacMetro-DSA study unit, arsenic was the only inorganic constituent detected above health-based benchmarks and was detected in 10 percent of the domestic-supply aquifer system. Inorganic constituents were detected above the non-health-based California State Water Resources Control Board—Division of Drinking Water secondary maximum contaminant levels (SMCL-CA) in 16 percent of the system. The inorganic constituents detected above the SMCL-CA were chloride, iron, manganese, and total dissolved solids (TDS). Organic constituents (volatile organic compounds and pesticides) with health-based benchmarks were not detected above health-based benchmarks; however, chloroform was detected at concentrations higher than 10 percent of the health-based benchmark (80 micrograms per liter) in 2 percent of the domestic-supply aquifer system. Of the 310 organic constituents analyzed, 16 constituents were detected; however, only bentazon and chloroform had detection frequencies greater than 10 percent. Inorganic constituents with health-based benchmarks that were evaluated in the understanding assessment included arsenic and hexavalent chromium. Arsenic and hexavalent chromium are natural constituents of aquifer sediments in the study unit and did not appear to be influenced by anthropogenic processes; rather, the presence of arsenic and hexavalent chromium appeared to be related to geochemical conditions controlled by oxidation–reduction reactions in the aquifer system. Naturally occurring inorganic constituents with SMCL-CAs evaluated in the understanding assessment were the trace elements iron and manganese, the major ion chloride, and TDS. Like arsenic and hexavalent chromium, the presence of iron and manganese was most strongly related to geochemical conditions in the aquifer system, specifically reducing conditions, which were most common near the western edge of the study unit close to the Sacramento River. Concentrations of chloride and TDS are indicators of salinity and were correlated with variables related to well location and included redox, agricultural land use, and elevation. Chloride and TDS were positively correlated to reducing conditions, and agricultural land use was negatively correlated to elevation and well depth. Observed correlations among variables were likely driven by the characteristics of the western part of the study unit, such as its higher proportion of agricultural land use and its relatively low elevation. A large portion of the western edge of the study unit is located in the center of the Sacramento Valley, defined by the location of the Sacramento River. The special-interest constituent perchlorate, also included in the understanding assessment, has natural and anthropogenic sources. Perchlorate was detected frequently and at moderate relative concentrations. In some areas of the study unit, concentrations of perchlorate were higher than what might be expected in nature; therefore, anthropogenic introduction of perchlorate or anthropogenically induced migration of native perchlorate could be occurring.

California↗

Ground-Water Storage Change and Land Subsidence in Tucson Basin and Avra Valley, Southeastern Arizona, 1998-2002

Gravity and land subsidence were measured annually at wells and benchmarks within two networks in Tucson Basin and Avra Valley from 1998 to 2002. Both networks are within the Tucson Active Management Area. Annual estimates of ground-water storage change, ground-water budgets, and land subsidence were made based on the data. Additionally, estimates of specific yield were made at wells within the monitored region. Increases in gravity and water-level rises followed above-average natural recharge during winter 1998 in Tucson Basin. Overall declining gravity and water-level trends from 1999 to 2002 in Tucson Basin reflected general declining ground-water storage conditions and redistribution of the recent recharge throughout a larger region of the aquifer. The volume of stored ground-water in the monitored portion of Tucson Basin increased 200,000 acre-feet from December 1997 to February 1999; however, thereafter an imbalance in ground-water pumpage in excess of recharge led to a net storage loss for the monitoring period by February 2002. Ground-water storage in Avra Valley increased 70,000 acre-feet during the monitoring period, largely as a result of artificial and incidental recharge in the monitored region. The water-budget for the combined monitored regions of Tucson Basin and Avra Valley was dominated by about 460,000 acre-feet of recharge during 1998 followed by an average-annual recharge rate of about 80,000 acre-feet per year from 1999 to 2002. Above-average recharge during winter 1998, followed by average-annual deficit conditions, resulted in an overall balanced water budget for the monitored period. Monitored variations in storage compared well with simulated average-annual conditions, except for above-average recharge from 1998 to 1999. The difference in observed and simulated conditions indicate that ground-water flow models can be improved by including climate-related variations in recharge rates rather than invariable rates of average-annual recharge. Observed land-subsidence during the monitoring period was less than 1 inch except in the central part of Tucson Basin where land subsidence was about 2-3 inches. Correlations of gravity-based storage and water-level change at 37 wells were variable and illustrate the complex nature of the aquifer system. Storage and water-level variations were insufficient to estimate specific yield at many wells. Correlations at several wells were poor, inverse, or resulted in unreasonably large values of specific yield. Causes of anomalously correlated gravity and water levels include significant storage change in thick unsaturated zones, especially near major ephemeral channels, and multiple aquifers that are poorly connected hydraulically. Good correlation of storage and water-level change at 10 wells that were not near major streams where significant changes in unsaturated zone storage occur resulted in an average specific-yield value of 0.27.

Scientific Investigations Report↗

Hydrology, Water Quality, and Surface- and Ground-Water Interactions in the Upper Hillsborough River Watershed, West-Central Florida

A study of the Hillsborough River watershed was conducted between October 1999 through September 2003 to characterize the hydrology, water quality, and interaction between the surface and ground water in the highly karstic uppermost part of the watershed. Information such as locations of ground-water recharge and discharge, depth of the flow system interacting with the stream, and water quality in the watershed can aid in prudent water-management decisions. The upper Hillsborough River watershed covers a 220-square-mile area upstream from Hillsborough River State Park where the watershed is relatively undeveloped. The watershed contains a second order magnitude spring, many karst features, poorly drained swamps, marshes, upland flatwoods, and ridge areas. The upper Hillsborough River watershed is subdivided into two major subbasins, namely, the upper Hillsborough River subbasin, and the Blackwater Creek subbasin. The Blackwater Creek subbasin includes the Itchepackesassa Creek subbasin, which in turn includes the East Canal subbasin. The upper Hillsborough River watershed is underlain by thick sequences of carbonate rock that are covered by thin surficial deposits of unconsolidated sand and sandy clay. The clay layer is breached in many places because of the karst nature of the underlying limestone, and the highly variable degree of confinement between the Upper Floridan and surficial aquifers throughout the watershed. Potentiometric-surface maps indicate good hydraulic connection between the Upper Floridan aquifer and the Hillsborough River, and a poorer connection with Blackwater and Itchepackesassa Creeks. Similar water level elevations and fluctuations in the Upper Floridan and surficial aquifers at paired wells also indicate good hydraulic connection. Calcium was the dominant ion in ground water from all wells sampled in the watershed. Nitrate concentrations were near or below the detection limit in all except two wells that may have been affected by fertilizer or animal waste. Wells at the Blackwater Creek and Hillsborough River at State Road 39 transects showed little seasonal variation in dissolved organic carbon. Dissolved organic carbon concentrations, however, were greater during the wet season than during the dry season at the Hillsborough River Tract transect, indicating some influence from surface-water sources. During dry periods, streamflow in the upper Hillsborough River was sustained by ground water from the underlying Upper Floridan aquifer. During wet periods, streamflow had additional contributions from runoff, and release of water from extensive riverine wetlands, and by overflow from the Withlacoochee River. In contrast, streamflow in Blackwater and Itchepackesassa Creeks was less constant, with many no-flow days occurring during dry periods. During wet season storm events, streamflow peaks occur more rapidly because there is greater confinement between the surficial deposits and the Upper Floridan aquifer, and these creeks have been highly channelized, leaving less of the adjacent wetlands intact. During dry periods, Blackwater Creek is dry upstream from its confluence with Itchepackesassa Creek, and all downstream flow is from Itchepackesassa Creek. Much of the dry season flow in Itchepackesassa Creek originates from a treated wastewater effluent outfall located on East Canal. Long-term streamflow at the Hillsborough River and Blackwater Creek stations was greater than the discharge observed during the study period. Water quality in the upper Hillsborough River is influenced by ground-water discharge. The chemical composition of water from Blackwater Creek, Itchepackesassa Creek, and East Canal was more variable because there was less ground-water discharge to these creeks than to the upper Hillsborough River, and because of the influence of wastewater effluent. Strontium isotope data indicated that the source of the water at all Hillsborough River sites during the dry season was the Oli

Scientific Investigations Report↗

Wildland fire effects on sediment, salinity, and selenium yields in a basin underlain by Cretaceous marine shales near Rangely, Colorado

Understanding and quantifying soil erosion from rangelands is a high priority for land managers, especially in areas underlain by Cretaceous Mancos Shale, which is a natural source of sediment, salinity, and selenium to surface waters in many areas of western Colorado and eastern Utah. The purpose of this report is to present the results of a U.S. Geological Survey study that assessed sediment, salinity, and selenium yields after the Dead Dog wildfire (fire began June 11, 2017) in northwestern Colorado. Two methodologies were used to quantify erosion, with different data requirements and analytical complexity. The first approach was the use of a process-based erosion model, the Watershed Erosion Prediction Project, which uses inputs of climate, topography, vegetation, and soils data from existing datasets to predict erosion, making this approach easily extensible to other areas. The second approach required more complex data collection and was used to measure erosion and deposition by differencing digital elevation models created from uncrewed aerial vehicle imagery collected in 2016 (pre-fire) and 2021 (post-fire). Sediment, salinity, and selenium yields were calculated from the volumetric estimates of erosion from both methods, and a discussion of factors that may have contributed to overall findings, including vegetation, fire effects, and soil characteristics, is included. The two approaches yielded different outputs. Results from the Watershed Erosion Prediction Project model indicated that almost no erosion occurred after the Dead Dog fire. However, morphological changes in the study basin after the Dead Dog fire were visible in the pre- and post-fire imagery and measured in the digital elevation model differencing technique, with net erosion occurring in channel and landscape extents, though calculated erosion rates and salinity and selenium yields were relatively small. Visible and measured morphological changes consisted primarily of incision and deposition within stream channels and rill incision and expansion on steeper slopes. Widespread sheet erosion was not evident. Much of the new erosion originated within, and immediately below, previously vegetated areas that were then burned by the wildfire. Greater erosion rates and salinity and selenium yields were measured in the channel extent relative to the landscape extent. Calculated erosion rates ranged from 0.24 to 0.45 megagrams per hectare per year. These results indicate that the Dead Dog fire resulted in increased erosion in the study basin, yet these effects were relatively small based on the overall magnitude of modeled and measured erosion from the Watershed Erosion Prediction Project and the digital elevation model differencing technique. Minimal erosion in the basin is likely due to local site characteristics typical of soils derived from Mancos Shale, including the presence of robust physical crusts and biological soil crusts, and limitations of the methods based on data availability. Focusing uncrewed aerial vehicle flights on key areas (individual steep slopes, high-intensity burn areas, specific stream reaches) could likely increase understanding of erosional process with less effort and error than doing landscape-level flights.

Colorado↗

A revised logistic regression equation and an automated procedure for mapping the probability of a stream flowing perennially in Massachusetts

A revised logistic regression equation and an automated procedure were developed for mapping the probability of a stream flowing perennially in Massachusetts. The equation provides city and town conservation commissions and the Massachusetts Department of Environmental Protection a method for assessing whether streams are intermittent or perennial at a specific site in Massachusetts by estimating the probability of a stream flowing perennially at that site. This information could assist the environmental agencies who administer the Commonwealth of Massachusetts Rivers Protection Act of 1996, which establishes a 200-foot-wide protected riverfront area extending from the mean annual high-water line along each side of a perennial stream, with exceptions for some urban areas. The equation was developed by relating the observed intermittent or perennial status of a stream site to selected basin characteristics of naturally flowing streams (defined as having no regulation by dams, surface-water withdrawals, ground-water withdrawals, diversion, wastewater discharge, and so forth) in Massachusetts. This revised equation differs from the equation developed in a previous U.S. Geological Survey study in that it is solely based on visual observations of the intermittent or perennial status of stream sites across Massachusetts and on the evaluation of several additional basin and land-use characteristics as potential explanatory variables in the logistic regression analysis. The revised equation estimated more accurately the intermittent or perennial status of the observed stream sites than the equation from the previous study. Stream sites used in the analysis were identified as intermittent or perennial based on visual observation during low-flow periods from late July through early September 2001. The database of intermittent and perennial streams included a total of 351 naturally flowing (no regulation) sites, of which 85 were observed to be intermittent and 266 perennial. Stream sites included in the database had drainage areas that ranged from 0.04 to 10.96 square miles. Of the 66 stream sites with drainage areas greater than 2.00 square miles, 2 sites were intermittent and 64 sites were perennial. Thus, stream sites with drainage areas greater than 2.00 square miles were assumed to flow perennially, and the database used to develop the logistic regression equation included only those stream sites with drainage areas less than 2.00 square miles. The database for the equation included 285 stream sites that had drainage areas less than 2.00 square miles, of which 83 sites were intermittent and 202 sites were perennial. Results of the logistic regression analysis indicate that the probability of a stream flowing perennially at a specific site in Massachusetts can be estimated as a function of four explanatory variables: (1) drainage area (natural logarithm), (2) areal percentage of sand and gravel deposits, (3) areal percentage of forest land, and (4) region of the state (eastern region or western region). Although the equation provides an objective means of determining the probability of a stream flowing perennially at a specific site, the reliability of the equation is constrained by the data used in its development. The equation is not recommended for (1) losing stream reaches or (2) streams whose ground-water contributing areas do not coincide with their surface-water drainage areas, such as many streams draining the Southeast Coastal Region-the southern part of the South Coastal Basin, the eastern part of the Buzzards Bay Basin, and the entire area of the Cape Cod and the Islands Basins. If the equation were used on a regulated stream site, the estimated intermittent or perennial status would reflect the natural flow conditions for that site. An automated mapping procedure was developed to determine the intermittent or perennial status of stream sites along reaches throughout a basin. The procedure delineates the drainage area boundaries, determines values for the four explanatory variables, and solves the equation for estimating the probability of a stream flowing perennially at two locations on a headwater (first-order) stream reach-one near its confluence or end point and one near its headwaters or start point. The automated procedure then determines the intermittent or perennial status of the reach on the basis of the calculated probability values and a probability cutpoint (a stream is considered to flow perennially at a cutpoint of 0.56 or greater for this study) for the two locations or continues to loop upstream or downstream between locations less than and greater than the cutpoint of 0.56 to determine the transition point from an intermittent to a perennial stream. If the first-order stream reach is determined to be intermittent, the procedure moves to the next downstream reach and repeats the same process. The automated procedure then moves to the next first-order stream and repeats the process until the entire basin is mapped. A map of the intermittent and perennial stream reaches in the Shawsheen River Basin is provided on a CD-ROM that accompanies this report. The CD-ROM also contains ArcReader 9.0, a freeware product, that allows a user to zoom in and out, set a scale, pan, turn on and off map layers (such as a USGS topographic map), and print a map of the stream site with a scale bar. Maps of the intermittent and perennial stream reaches in Massachusetts will provide city and town conservation commissions and the Massachusetts Department of Environmental Protection with an additional method for assessing the intermittent or perennial status of stream sites.

Scientific Investigations Report↗

Impact of wildfire on levels of mercury in forested watershed systems: Voyageurs National Park, Minnesota

Atmospheric deposition of mercury to remote lakes in mid-continental and eastern North America has increased approximately threefold since the mid-1800s (Swain and others, 1992; Fitzgerald and others, 1998; Engstrom and others, 2007). As a result, concerns for human and wildlife health related to mercury contamination have become widespread. Despite an apparent recent decline in atmospheric deposition of mercury in many areas of the Upper Midwest (Engstrom and Swain, 1997; Engstrom and others, 2007), lakes in which fish contain levels of mercury deemed unacceptable for human consumption and possibly unacceptable for fish-consuming wildlife are being detected with increasing frequency. In northern Minnesota, Voyageurs National Park (VNP) (fig. 1) protects a series of southern boreal lakes and wetlands situated on bedrock of the Precambrian Canadian Shield. Mercury contamination has become a significant resource issue within VNP as high concentrations of mercury in loons, bald eagle eaglets, grebes, northern pike, and other species of wildlife and fish have been found. The two most mercury-contaminated lakes in Minnesota, measured as methylmercury in northern pike ( Esox lucius ), are in VNP. Recent multidisciplinary U.S. Geological Survey (USGS) research demonstrated that the bulk of the mercury in lake waters, soils, and fish in VNP results from atmospheric deposition (Wiener and others, 2006). The study by Wiener and others (2006) showed that the spatial distribution of mercury in watershed soils, lake waters, and age-1 yellow perch ( Perca flavescens ) within the Park was highly variable. The majority of factors correlated for this earlier study suggested that mercury concentrations in lake waters and age-1 yellow perch reflected the influence of ecosystem processes that affected within-lake microbial production and abundance of methylmercury (Wiener and others, 2006), while the distribution of mercury in watershed soils seemed to be partially dependent on forest disturbance, especially the historic forest fire pattern (Woodruff and Cannon, 2002). Forest fire has an essential role in the forest ecosystems of VNP (Heinselman, 1996). Because resource and land managers need to integrate both natural wildfire and prescribed fire in management plans, the potential influence of fire on an element as sensitive to the environment as mercury becomes a critical part of their decisionmaking. A number of recent studies have shown that while fire does have a significant impact on mercury at the landscape level, the observed effects of fire on aquatic environments are highly variable and unpredictable (Caldwell and others, 2000; Garcia and Carrigan, 2000; Kelly and others, 2006; Nelson and others, 2007). Caldwell and others (2000) described an increase in methylmercury in reservoir sediments resulting from mobilization and transport of charred vegetative matter following a fire in New Mexico. Krabbenhoft and Fink (2000) attributed increases in total mercury concentrations in young-of-the-year fish in the Florida Everglades to release of mercury resulting from peat oxidation following fires. A fivefold increase in whole-body mercury accumulation by rainbow trout ( Oncorhynchus mykiss ) following a fire in Alberta, Canada, apparently resulted from increased nutrient concentrations that enhanced productivity and restructured the food web of a lake within the fire’s burn footprint (Kelly and others, 2006). For this study, we determined the short-term effects of forest fire on mercury concentrations in terrestrial and aquatic environments in VNP by comparing and contrasting mercury concentrations in forest soils, lake waters, and age-1 yellow perch for a burned watershed and an adjacent lake, with similar samples from watersheds and lakes with no fire activity (control watersheds and lakes). The concentration of total mercury in whole, 1-year-old yellow perch serves as a good biological indicator for monitoring trends in methylmercury concentrations in food webs of lakes in North America (Wiener and others, 2007). With a limited gape, age-1 yellow perch that hatched the previous year and resided in a lake for 1 year feed largely on zooplankton and small benthic invertebrates. Thus, age-1 yellow perch provide a baseline for methylmercury concentrations for individual lakes that can be compared across spatial areas. The nine appendixes that accompany this report contain the complete datasets for soils, lake waters, and age-1 yellow perch collected for this study. This report uses data from these three media to provide a framework for evaluating short-term effects of fire on mercury in forested soils and possible effects of the mobilization of mercury from soils on lake water quality and aquatic health.

Minnesota↗

Evaluation of potential stresses and hydrologic conditions driving water-level fluctuations in well ER-5-3-2, Frenchman Flat, southern Nevada

Well ER-5-3-2 is part of a well network designed to monitor long-term water levels and radionuclide concentrations downgradient from underground nuclear tests that occurred in Frenchman Flat, an area of the U.S. Department of Energy Nevada National Security Site in southern Nevada. Interpretation of monitoring records for well ER-5-3-2 was confounded by previously unexplained water-level fluctuations in the well hydrograph. This study integrated geologic, hydrologic, and water-chemistry data to evaluate potential stresses and hydrologic conditions that likely affected the well ER-5-3-2 hydrograph. Numerical groundwater models were applied to evaluate four model scenarios: (1) wellbore leakage without recharge, (2) wellbore leakage with recharge, (3) equilibration to vertical heterogeneities between shallow (low transmissivity) and deep (higher transmissivity) carbonate zones, and (4) equilibration to lateral heterogeneities in carbonate rocks. Meteoric recharge was not the cause of the 21-foot (ft) water-level rise in well ER-5-3-2 from 2001 to 2011 or the 4-ft decline from 2012 to 2016. Based on observed water-level fluctuations in nearby wells, the water-level rise and decline from recharge for these periods was less than 3 and 1 ft, respectively. The lateral-heterogeneity scenario is based on the assumption that the 21-ft water-level rise from 2001 to 2011 was a natural water-level reequilibration following the pumping-induced depressurization of a large volume of high transmissivity and low-storage carbonate rock that is surrounded by low transmissivity and high-storage carbonate rock. The lateral-heterogeneity scenario was discounted because simulated water levels cannot match the well ER-5-3-2 hydrograph. Underground nuclear testing and temperature effects were discounted based on hydraulic connections and water-temperature data. Wellbore-leakage scenarios are based on the assumption that the water-level rise was sustained from leakage rates required to cause a localized mounding in the carbonate system near well ER-5-3-2, where the carbonate transmissivity is 530 square feet per day. Even though simulated and measured water levels compare favorably for scenarios of wellbore leakage with and without recharge, large volumes (178–184 million gallons) of groundwater from volcanic rocks would be required to leak into the carbonate system, which is not supported by water-chemistry data. An alternative conceptualization of wellbore leakage is based on the assumption that the 21-ft water-level rise from 2001 to 2011 was sustained by the hydraulic disconnection of well ER-5-3-2 from the carbonate system. The disconnection occurred several months after a constant-rate test in well ER-5-3-2 when carbonate rocks were hydraulically disconnected from the well by either (1) the shifting of sloughed fill in the open hole or (2) the encrusting of carbonate precipitate in the well screen. The hydraulic disconnection effectively sealed the well and caused a 21-ft water-level rise from wellbore leakage during 2001–11. In this case, total wellbore leakage from 2001 to 2011 was about 50 gallons. The 4-ft water-level decline from 2012 to 2016 was conceptualized to have occurred from the slow breaking of the seal and reconnection of the well to the carbonate system. This alternative conceptualization of wellbore leakage was consistent with water-chemistry analyses because the computed wellbore leakage (50 gallons) was small relative to purged volumes (30,000–40,000 gallons) for sampling, and the water chemistry would not be expected to change. The shallow-deep carbonate scenario provided another explanation for the well ER-5-3-2 hydrograph. This scenario is based on the assumption that well-construction effects and vertical heterogeneity of the carbonate system explain the ER-5-3-2 water-level trend. Well-construction effects are attributed to a temporary clogging of the open interval below the well screen that was opened during pumping events, which affected the hydraulic connection of deep transmissive carbonate rocks to the wellbore. The 21-ft water-level rise from 2001 to 2011 was a natural equilibration to shallow, low-transmissivity carbonate rocks during a period when the lower open interval was clogged. The 4-ft decline from 2012 to 2016 represents equilibration between the shallow and deep intervals, because of a partial unclogging of the connection between the two intervals. The low water levels from 2016 to 2021 resulted from pumping for sampling and an unclogging of the open interval so that the low head in the deep carbonate dominated the water level. Despite potential well-construction effects, from either a wellbore leakage or shallow-deep carbonate scenario, samples collected from well ER-5-3-2 are representative of the carbonate system.

Nevada↗

Geochemical evolution processes and water-quality observations based on results of the National Water-Quality Assessment Program in the San Antonio segment of the Edwards aquifer, Texas, 1996-2006

As part of the National Water-Quality Assessment Program, the U.S. Geological Survey collected and analyzed groundwater samples during 1996-2006 from the San Antonio segment of the Edwards aquifer of central Texas, a productive karst aquifer developed in Cretaceous-age carbonate rocks. These National Water-Quality Assessment Program studies provide an extensive dataset of groundwater geochemistry and water quality, consisting of 249 groundwater samples collected from 136 sites (wells and springs), including (1) wells completed in the shallow, unconfined, and urbanized part of the aquifer in the vicinity of San Antonio (shallow/urban unconfined category), (2) wells completed in the unconfined (outcrop area) part of the regional aquifer (unconfined category), and (3) wells completed in and springs discharging from the confined part of the regional aquifer (confined category). This report evaluates these data to assess geochemical evolution processes, including local- and regional-scale processes controlling groundwater geochemistry, and to make water-quality observations pertaining to sources and distribution of natural constituents and anthropogenic contaminants, the relation between geochemistry and hydrologic conditions, and groundwater age tracers and travel time. Implications for monitoring water-quality trends in karst are also discussed. Geochemical and isotopic data are useful tracers of recharge, groundwater flow, fluid mixing, and water-rock interaction processes that affect water quality. Sources of dissolved constituents to Edwards aquifer groundwater include dissolution of and geochemical interaction with overlying soils and calcite and dolomite minerals that compose the aquifer. Geochemical tracers such as magnesium to calcium and strontium to calcium ratios and strontium isotope compositions are used to evaluate and constrain progressive fluid-evolution processes. Molar ratios of magnesium to calcium and strontium to calcium in groundwater typically increase along flow paths; results for samples of Edwards aquifer groundwater show an increase from shallow/urban unconfined, to unconfined, to confined groundwater categories. These differences are consistent with longer residence times and greater extents of water-rock interaction controlling fluid compositions as groundwater evolves from shallow unconfined groundwater to deeper confined groundwater. Results for stable isotopes of hydrogen and oxygen indicate specific geochemical processes affect some groundwater samples, including mixing with downdip saline water, mixing with recent recharge associated with tropical cyclonic storms, or mixing with recharge water than has undergone evaporation. The composition of surface water recharging the aquifer, as well as mixing with downdip water from the Trinity aquifer or the saline zone, also might affect water quality. A time-series record (1938-2006) of discharge at Comal Springs, one of the major aquifer discharge points, indicates an upward trend for nitrate and chloride concentrations, which likely reflects anthropogenic activities. A small number of organic contaminants were routinely or frequently detected in Edwards aquifer groundwater samples. These were the pesticides atrazine, its degradate deethylatrazine, and simazine; the drinking-water disinfection byproduct chloroform; and the solvent tetrachloroethene. Detection of these contaminants was most frequent in samples of the shallow/urban unconfined groundwater category and least frequent in samples of the unconfined groundwater category. Results indicate that the shallow/urban unconfined part of the aquifer is most affected by anthropogenic contaminants and the unconfined part of the aquifer is the least affected. The high frequency of detection for these anthropogenic contaminants aquifer-wide and in samples of deep, confined groundwater indicates that the entire aquifer is susceptible to water-quality changes as a result of anthropogenic activities. L

Texas↗

Surficial sediment character of the New York-New Jersey offshore continental shelf region: A GIS compilation

Broad continental shelf regions such as the New York Bight are the product of a complex geologic history and dynamic oceanographic processes, dominated by the Holocene marine transgression (>100 m sea-level rise) following the end of the last Pleistocene ice advance ~ 20,000 years ago. The area of the U.S. Exclusive Economic Zone (U.S. EEZ) territory, extending 200 nautical miles seaward from the coast, is larger than the continental U.S. and contains submerged landforms that provide a variety of natural functions and societal benefits, such as: critical habitats for fisheries, ship navigation and homeland security, and engineering activities (i.e. oil and gas platforms, pipeline and cable routes, potential wind-energy-generation sites). Some parts of the continental margins, particularly inner-continental shelf regions, also contain unconsolidated hard-mineral deposits such as sand and gravel that are regarded as potential aggregate resources to meet or augment needs not met by onshore deposits (Williams, 1992). The present distribution of surficial sediment off the northeastern United States is shaped from the deposits left by the last glaciation and reflects the cumulative effects of sediment erosion, transport, sorting, and deposition by storm and tidal processes during the Holocene rise in sea level. As a result, the sediments on the sea floor represent both an historical record of former conditions and a guide to possible future sedimentary environments. The U.S. Geological Survey (USGS) through the Coastal and Marine Geology Program, in cooperation with the University of Colorado and other partners, has compiled extant sediment character and textural data as well as other geologic information on the sea floor from all regions around the U.S. into the usSEABED data system (Reid and others, 2005; Buczkowski and others, 2006; Reid and others, 2006). The usSEABED system, which contains information on sediment grain size and lithology for more than 340,500 stations within the U.S. EEZ. has been developed and populated with data as part of the USGS Marine Aggregate Resources and Processes and the National Benthic Habitats projects in order to provide the base-line data needed to update the current maps of offshore surficial geologic character and sediment distribution. The maps are also used to characterize benthic sea floor environments important for marine ecosystems. U.S. Geological Survey, Data Series 118 (Reid and others, 2005), of the usSEABED data release series, represents the combined efforts of the USGS and several other government agencies to provide a unified resource for accessing and preserving records of U.S. east coast sea floor geologic information and sediment texture data. For this present report, we have chosen to focus on the New York-New Jersey region, an area that has been intensely studied by the USGS for many years to address many complex issues. This report illustrates the uses of the usSEABED database for GIS applications, while offering additional insight into the resources and data available from the USGS and its collaborative institutions. This report is based on data contained in U.S. Geological Survey Data Series 118 (Reid and others, 2005) and shows an assortment of example GIS products that are possible using usSEABED. All data are intended to be GIS-ready and should not require any additional cleanup, formatting, or renaming of fields in order to use the data in a Geographic Information System. This project employs the Environmental Systems Research Institute's (ESRI) ArcView™ software. Many of these maps were made as part of the ongoing USGS study to assess marine aggregate resources offshore New York and New Jersey, but these maps can serve many other purposes. The marine science community, educators, students and others are encouraged to use these data to generate GIS products for their own purposes. The objectives of the Marine Aggregate Resources and Processes project are to produce a series of new geologic maps and reports of the sea floor that will provide scientific insights into the character and geologic development of U.S. continental margins and to use these maps and information to assess the potential availability of offshore sand and gravel resources. The mapping and aggregate resource assessments are being conducted on a national scale using the usSEABED data base as described in Williams and others (2003). Potential uses for these data include: (1) defining the geological variability of the sea floor in relation to benthic habitat diversity; (2) improving our understanding of the processes that control the distribution and transport of bottom sediments and benthic habitats; (3) locating aggregate resources for beach nourishment and industrial applications; and (4) providing a detailed geospatial framework for future marine science research, monitoring, and management activities. The initial assessments are in progress for the New York Bight and Louisiana offshore areas.

New Jersey, New York↗

Hydrogeology of the West Branch Delaware River basin, Delaware County, New York

In 2009, the U.S. Geological Survey, in cooperation with the New York State Department of Environmental Conservation, began a study of the hydrogeology of the West Branch Delaware River (Cannonsville Reservoir) watershed. There has been recent interest by energy companies in developing the natural gas reserves that are trapped within the Marcellus Shale, which is part of the Hamilton Group of Devonian age that underlies all the West Branch Delaware River Basin. Knowing the extent and thickness of stratified-drift (sand and gravel) aquifers within this basin can help State and Federal regulatory agencies evaluate any effects on these aquifers that gas-well drilling might produce. This report describes the hydrogeology of the 455-square-mile basin in the southwestern Catskill Mountain region of southeastern New York and includes a detailed surficial geologic map of the basin. Analysis of surficial geologic data indicates that the most widespread surficial geologic unit within the basin is till, which is present as deposits of ablation till in major stream valleys and as thick deposits of lodgment till that fill upland basins. Till and colluvium (remobilized till) cover about 89 percent of the West Branch Delaware River Basin, whereas stratified drift (outwash and ice-contact deposits) and alluvium account for 8.9 percent. The Cannonsville Reservoir occupies about 1.9 percent of the basin area. Large areas of outwash and ice-contact deposits occupy the West Branch Delaware River valley along its entire length. These deposits form a stratified-drift aquifer that ranges in thickness from 40 to 50 feet (ft) in the upper West Branch Delaware River valley, from 70 to 140 ft in the middle West Branch Delaware River valley, and from 60 to 70 ft in the lower West Branch Delaware River valley. The gas-bearing Marcellus Shale underlies the entire West Branch Delaware River Basin and ranges in thickness from 600 to 650 ft along the northern divide of the basin to 750 ft thick along the southern divide. The depth to the top of the Marcellus Shale ranges from 3,240 ft along the northern basin divide to 4,150 ft along the southern basin divide. Yields of wells completed in the aquifer are as high as 500 gallons per minute (gal/min). Springs from fractured sandstone bedrock are an important source of domestic and small municipal water supplies in the West Branch Delaware River Basin and elsewhere in Delaware County. The average yield of 178 springs in Delaware County is 8.5 gal/min with a median yield of 3 gal/min. An analysis of two low-flow statistics indicates that groundwater contributions from fractured bedrock compose a significant part of the base flow of the West Branch Delaware River and its tributaries.

New York↗

Occurrence of Pesticides in Ground Water of Wyoming, 1995-2006

Little existing information was available describing pesticide occurrence in ground water of Wyoming, so the U.S. Geological Survey, in cooperation with the Wyoming Department of Agriculture and the Wyoming Department of Environmental Quality on behalf of the Wyoming Ground-water and Pesticides Strategy Committee, collected ground-water samples twice (during late summer/early fall and spring) from 296 wells during 1995-2006 to characterize pesticide occurrence. Sampling focused on the State's ground water that was mapped as the most vulnerable to pesticide contamination because of either inherent hydrogeologic sensitivity (for example, shallow water table or highly permeable aquifer materials) or a combination of sensitivity and associated land use. Because of variations in reporting limits among different compounds and for the same compound during this study, pesticide detections were recensored to two different assessment levels to facilitate qualitative and quantitative examination of pesticide detection frequencies - a common assessment level (CAL) of 0.07 microgram per liter and an assessment level that differed by compound, referred to herein as a compound-specific assessment level (CSAL). Because of severe data censoring (fewer than 50 percent of the data are greater than laboratory reporting limits), categorical statistical methods were used exclusively for quantitative comparisons of pesticide detection frequencies between seasons and among various natural and anthropogenic (human-related) characteristics. One or more pesticides were detected at concentrations greater than the CAL in water from about 23 percent of wells sampled in the fall and from about 22 percent of wells sampled in the spring. Mixtures of two or more pesticides occurred at concentrations greater than the CAL in about 9 percent of wells sampled in the fall and in about 10 percent of wells sampled in the spring. At least 74 percent of pesticides detected were classified as herbicides. Considering only detections using the CAL, triazine pesticides were detected much more frequently than all other pesticide classes, and the number of different pesticides classified as triazines was the largest of all classes. More pesticides were detected at concentrations greater than the CSALs in water from wells sampled in the fall (28 different pesticides) than in the spring (21 different pesticides). Many pesticides were detected infrequently as nearly one-half of pesticides detected in the fall and spring at concentrations greater than the CSALs were detected only in one well. Using the CSALs for pesticides analyzed for in 11 or more wells, only five pesticides (atrazine, prometon, tebuthiuron, picloram, and 3,4-dichloroaniline, listed in order of decreasing detection frequency) were each detected in water from more than 5 percent of sampled wells. Atrazine was the pesticide detected most frequently at concentrations greater than the CSAL. Concentrations of detected pesticides generally were small (less than 1 microgram per liter), although many infrequent detections at larger concentrations were noted. All detected pesticide concentrations were smaller than U.S. Environmental Protection Agency (USEPA) drinking-water standards or applicable health advisories. Most concentrations were at least an order of magnitude smaller; however, many pesticides did not have standards or advisories. The largest percentage of pesticide detections and the largest number of different pesticides detected were in samples from wells located in the Bighorn Basin and High Plains/ Casper Arch geographic areas of north-central and southeastern Wyoming. Prometon was the only pesticide detected in all eight geographic areas of the State. Pesticides were detected much more frequently in samples from wells located in predominantly urban areas than in samples from wells located in predominantly agricultural or mixed areas. Pesticides were detected distinctly less often in sa

Scientific Investigations Report↗

Geochemical effects of induced stream-water and artificial recharge on the Equus Beds Aquifer, South-Central Kansas, 1995-2004

Artificial recharge of the Equus Beds aquifer is part of a strategy implemented by the city of Wichita, Kansas, to preserve future water supply and address declining water levels in the aquifer of as much as 30 feet caused by withdrawals for water supply and irrigation since the 1940s. Water-level declines represent a diminished water supply and also may accelerate migration of saltwater from the Burrton oil field to the northwest and the Arkansas River to the southwest into the freshwater of the Equus Beds aquifer. Artificial recharge, as a part of the Equus Beds Ground-Water Recharge Project, involves capturing flows larger than base flow from the Little Arkansas River and recharging the water to the Equus Beds aquifer by means of infiltration or injection. The geochemical effects on the Equus Beds aquifer of induced stream-water and artificial recharge at the Halstead and Sedgwick sites were determined through collection and analysis of hydrologic and water-quality data and the application of statistical, mixing, flow and solute-transport, and geochemical model simulations. Chloride and atrazine concentrations in the Little Arkansas River and arsenic concentrations in ground water at the Halstead recharge site frequently exceeded regulatory criteria. During 30 percent of the time from 1999 through 2004, continuous estimated chloride concentrations in the Little Arkansas River at Highway 50 near Halstead exceeded the Secondary Drinking-Water Regulation of 250 milligrams per liter established by the U.S. Environmental Protection Agency. Chloride concentrations in shallow monitoring wells located adjacent to the stream exceeded the drinking-water criterion five times from 1995 through 2004. Atrazine concentrations in water sampled from the Little Arkansas River had large variability and were at or near the drinking-water Maximum Contaminant Level of 3.0 micrograms per liter as an annual average established by the U.S. Environmental Protection Agency. Atrazine concentrations were much smaller than the drinking-water criterion and were detected at much smaller concentrations in shallow monitoring wells and diversion well water located adjacent to the stream probably because of sorption on aquifer sediment. Before and after artificial recharge, large, naturally occurring arsenic concentrations in the recharge water for the Halstead diversion well and recharge site exceeded the Maximum Contaminant Level of 10 micrograms per liter established by the U.S. Environmental Protection Agency for drinking water. Arsenic and iron concentrations decreased when water was recharged through recharge basins or a trench; however, chemical precipitation and potential biofouling eventually may decrease the artificial recharge efficiency through basins and trenches. At the Sedgwick site, chloride concentrations infrequently exceeded regulatory criteria. Large concentrations of atrazine were treated to decrease concentrations to less than regulatory criteria. Recharge of treated stream water through recharge basins avoids potentially large concentrations of arsenic and iron that exist at the Halstead diversion site. Results from a simple mixing model using chloride as a tracer indicated that the water chemistry in shallow monitoring well located adjacent to the Little Arkansas River was 80 percent of stream water, demonstrating effective recharge of the alluvial aquifer by the stream. Results also indicated that about 25 percent of the water chemistry of the diversion well water was from the shallow part of the aquifer. Additionally, diverting water through a diversion well located adjacent to the stream removed about 75 percent of the atrazine, probably through sorption to aquifer sediment, and decreased the need for additional water treatment to remove atrazine.

Kansas↗

Uranium concentrations in groundwater, northeastern Washington

A study of uranium in groundwater in northeastern Washington was conducted to make a preliminary assessment of naturally occurring uranium in groundwater relying on existing information and limited reconnaissance sampling. Naturally occurring uranium is associated with granitic and metasedimentary rocks, as well as younger sedimentary deposits, that occur in this region. The occurrence and distribution of uranium in groundwater is poorly understood. U.S. Environmental Protection Agency (EPA) regulates uranium in Group A community water systems at a maximum contaminant level (MCL) of 30 μg/L in order to reduce uranium exposure, protect from toxic kidney effects of uranium, and reduce the risk of cancer. However, most existing private wells in the study area, generally for single family use, have not been sampled for uranium. This document presents available uranium concentration data from throughout a multi-county region, identifies data gaps, and suggests further study aimed at understanding the occurrence of uranium in groundwater. The study encompasses about 13,000 square miles (mi 2 ) in the northeastern part of Washington with a 2010 population of about 563,000. Other than the City of Spokane, most of the study area is rural with small towns interspersed throughout the region. The study area also includes three Indian Reservations with small towns and scattered population. The area has a history of uranium exploration and mining, with two inactive uranium mines on the Spokane Indian Reservation and one smaller inactive mine on the outskirts of Spokane. Historical (1977–2016) uranium in groundwater concentration data were used to describe and illustrate the general occurrence and distribution of uranium in groundwater, as well as to identify data deficiencies. Uranium concentrations were detected at greater than 1 microgram per liter (μg/L) in 60 percent of the 2,382 historical samples (from wells and springs). Uranium concentrations ranged from less than 1 to 88,600 μg/L, and the median concentration of uranium in groundwater for all sites was 1.4 μg/L. New (2017) uranium in groundwater concentration data were obtained by sampling 13 private domestic wells for uranium in areas without recent (2000s) water-quality data. Uranium was detected in all 13 wells sampled for this study; concentrations ranged from 1.03 to 1,180 μg/L with a median of 22 μg/L. Uranium concentrations of groundwater samples from 6 of the 13 wells exceeded the MCL for uranium. Uranium concentrations in water samples from two wells were 1,130 and 1,180 μg/L, respectively; nearly 40 times the MCL. Additional data collection and analysis are needed in rural areas where self-supplied groundwater withdrawals are the primary source of water for human consumption. Of the roughly 43,000 existing water wells in the study area, only 1,755 wells, as summarized in this document, have available uranium concentration data, and some of those data are decades old. Furthermore, analysis of area groundwater quality would benefit from a more extensive chemical-analysis suite including general chemistry in order to better understand local geochemical conditions that largely govern the mobility of uranium. Although the focus of the present study is uranium, it also is important to recognize that there are other radionuclides of concern that may be present in area groundwater.

Washington↗

Fire rehabilitation effectiveness: a chronosequence approach for the Great Basin

Federal land management agencies have invested heavily in seeding vegetation for emergency stabilization and rehabilitation (ES&R) of non-forested lands. ES&R projects are implemented to reduce post-fire dominance of non-native annual grasses, minimize probability of recurrent fire, quickly recover lost habitat for sensitive species, and ultimately result in plant communities with desirable characteristics including resistance to invasive species and resilience or ability to recover following disturbance. Land managers lack scientific evidence to verify whether seeding non-forested lands achieves their desired long-term ES&R objectives. The overall objective of our investigation is to determine if ES&R projects increase perennial plant cover, improve community composition, decrease invasive annual plant cover and result in a more desirable fuel structure relative to no treatment following fires while potentially providing habitat for Greater Sage-Grouse, a species of management concern. In addition, we provide the locations and baseline vegetation data for further studies relating to ES&R project impacts. We examined effects of seeding treatments (drill and broadcast) vs. no seeding on biotic and abiotic (bare ground and litter) variables for the dominant climate regimes and ecological types within the Great Basin. We attempted to determine seeding effectiveness to provide desired plant species cover while restricting non-native annual grass cover relative to post-treatment precipitation, post-treatment grazing level and time-since-seeding. Seedings were randomly sampled from all known post-fire seedings that occurred in the four-state area of Idaho, Nevada, Oregon and Utah. Sampling locations were stratified by major land resource area, precipitation, and loam-dominated soils to ensure an adequate spread of locations to provide inference of our findings to similar lands throughout the Great Basin. Nearly 100 sites were located that contained an ES&R project. Of these sites, 61 were seeded by using a drill, 27 were broadcast aerially, and 12 had a combination of both. We randomly sampled three burned and seeded, burned and unseeded, and unburned and unseeded locations in the vicinity of the fire, each within the same ecological site. We measured foliar cover of all plant functional groups (perennial or annual, shrub, grass, forb, native or introduced), biological soil crusts, and abiotic (bare soil and litter) variables using the line-point intercept protocol. Fuel loads and horizontal fuel continuity were measured. We applied linear mixed models to response variables (cover and density of plant groups) relative to the dependent variables (seeding treatments and precipitation/temperature relationships. Post-fire strengths with native perennial grasses or shrubs in mixes did not increase density or cover of these groups significantly relative to unseeded, burned areas. Seeded non-native perennial grasses and the shrub Bassia prostrata were effective in providing more cover in aerial and drill seedings. Seeded non-native perennial grass cover increased with increased annual precipitation regardless of seeding type. Seeding native shrubs, particularly Artemisia tridentata, did not significantly increase shrub cover in burned areas. Cover of undesirable non-native annual grasses was lower in drill seedings relative to unseeded areas but only at higher elevations. Seeding effectiveness after wildfire is unpredictable in drier, low elevation environments, and our findings indicate management objectives are more likely met when focusing efforts on higher elevation or higher precipitation locations where establishment of perennial grasses is more likely. On sites where potential for invasion and dominance of non-native annuals is high, such as lower and drier sites, intensive methods of restoration that include invasive plant control before seeding may be required. Where establishment of native perennial plants is the goal, managers might consider using native-only seed mixtures, because we found that the non-native perennials typically used in Great Basin restoration efforts are selected for their competitive nature and may reduce establishment of less competitive native species. Although we attempted to include information on livestock grazing history after seedings, we were unable to extract sufficient data from files to address this topic that may play an additional role in understanding native plant abundance post-fire seeding. Evaluation of drill and aerial seeding effects on fuel characteristics focused on two metrics that are standard inputs for fire behavior models, fuel load and fuel continuity. Fuel loads were evaluated separately for total fuel load biomass, and the individual components that sum to total biomass, namely herbaceous, shrub, shrub:herbaceous ratio, litter, 10-hour, and 100-hour fuel biomasses. Fuel continuity was evaluated using the following cover categories, total, annual grass, annual forb, perennial forb perennial grass, shrub, litter, vegetative interspace, and perennial interspace. Drill seeding did not affect fuel loads, except to reduce 10-hour fuels, probably due to mechanical destruction of dead and down fuels by the drill seeding equipment. Drill seeding did affect fuel continuity, specifically decreasing total plant cover by increasing perennial grass cover which suppressed annual grass and litter production resulting in a net decrease in continuity, but only at the elevations above approximately 1500m. Aerial seeding had no effect on any fuel load or fuel continuity category. For the Greater Sage-Grouse habitat study, we developed multi-scale empirical models of sage-grouse occupancy in 211 randomly located plots within a 40 million ha portion of the species’ range. We then used these models to predict sage-grouse habitat quality at 101 ES&R seeding projects. We compared conditions at restoration sites to published habitat guidelines. Sage-grouse occupancy was positively related to plot- and landscape-level dwarf sagebrush (Artemisia arbuscula, A. nova, A. tripartita) and big sagebrush steppe, and negatively associated with non-native grass and human development. The predicted probability of sage-grouse occupancy at treated plots was low on average (0.07–0.09) and was not significantly different from burned areas that had not been treated. Restoration was more often successful at higher elevation sites with low annual temperatures, high spring precipitation, and high plant diversity. No plots seeded after fire (n=313) met all overstory guidelines for breeding habitats, but approximately 50% met understory guidelines, particularly for perennial grasses. This trend was similar for summer habitat. Ninety-eight percent of treated plots did not meet winter habitat guidelines. Restoration actions in burned areas did not increase the probability of meeting most guideline criteria. The probability of meeting guidelines was influenced by a latitudinal gradient, local climate, and topography. Post-fire seeding treatments in Great Basin sagebrush shrublands generally have not created high quality habitat for sage-grouse. Understory conditions are more likely to be adequate than those of overstory, but in unfavorable climates, establishing forbs and reducing cheatgrass dominance is unlikely. Reestablishing sagebrush cover will require more than 20 years using the restoration methods of the past two decades. Given current fire frequencies and restoration capabilities, protection of landscapes containing a mix of dwarf sagebrush and big sagebrush steppe, minimal human development, and low non-native plant cover may provide the best opportunity for conservation of sage-grouse habitats. Our database of ES&R locations has used the Land Treatment Digital Library to archive data and location information regarding our study (see Pilliod and Welty 2013). This has contributed to two additional studies. One examined the potential spread of Bassia prostrata (aka Kochia prostrata; forage kochia) from ES&R project locations (Gray and Muir 2013). The second used remote sensing to determine the phenology of vegetation green-up on post-fire seeded sites (Sankey et al. 2013).

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