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USGS1950

Geology and paleontology of the Santa Maria district, California

Stratigraphy, paleontology, and geologic history.-A basement' consisting of igneous rocks of the Jurassic(?) Franciscan formation and sediments of the Upper Jurassic Knoxville formation, and formations of Tertiary and Quaternary age are exposed in the Santa Maria district. The outcrop section, exclusive of the Franciscan, has a maximum thickness of about 10,000 feet, the subsurface section about 27,000 feet. At no locality, however, is either outcrop or subsurface section as thick as the total maxima for the formations. The outcrop Franciscan is made up of altered basalt, gabbro (generally- greatly altered), and minor areas of peridotite and serpentine. The marine Knoxville formation, consisting of shale, thin-bedded calcareous sandstone, and conglomerate, was deposited on the igneous rocks of the Franciscan. It has an outcrop thickness of about 500 feet and a known subsurface thickness of at least 1,250 feet. Aucella cf. A. piochii, which occurs in both outcrop and subsurface sections, suggests late Jurassic age. The Franciscan and Knoxville were probably uplifted during Taliaferro's Diablan orogeny at the close of the Jurassic and formed a land area that presumably endured during early Cretaceous and perhaps during much of late Cretaceous time. If sediments were laid down while 10,000 feet of Upper Cretaceous were deposited in the adjoining San Rafael Mountains, they were eroded following uplift at the close of the Cretaceous, when Reed and Hollister's San Rafael uplift was formed. The district is inferred to have been part of a Franciscan and Knoxville land area at the south border of the San Rafael uplift during all of early Tertiary time. The known history of the district as part of a Tertiary basin began in the early Miocene(?), possibly a little earlier or possibly 3: little later, when the nonmarine sediments of the early Miocene(?) Lospe formation were deposited. The Lospe formation has a maximum thickness of 2, 700 feet, and is made up of coarse-grained reddish sandstone and conglomerate, and greenish sandstone, gypsiferous siltstone, and mudstone. White tuff is a minor but conspicuous constituent. The Lospe formation overlies the Knoxville, or· overlaps it and rests on the Franciscan. The first known Tertiary invasion of the sea took place immediately thereafter in early middle Miocene time, and from then on until approximately the end of the Pliocene the sea occupied continuously at least most of the region. The extent of the Miocene basin is not certainly known, but it was part of an extensive· basin that has been designated the Santa Barbara embayment. The early middle Miocene Point Sal formation is the earliest marine Tertiary formation. It has an outcrop thickness of as much as 1,500 feet and a maximum subsurface thickness of 3,600 feet, and consists of siltstone, mudstone, and thin beds of sandstone. The Point Sal formation overlies the Lospe formation without marked discontinuity, or overlaps it and rests on Knoxville or Franciscan. It contains a large foraminiferal fauna representing the Siphogenerina hughesi zone, or the lower part of Kleinpell's Relizian stage. The Monterey shale overlies the Point Sal formation without noticeable discontinuity, or overlaps all the older sedimentary formations and rests on the Franciscan. It has a maximum outcrop thickness of 2,100 feet, but is as much as 5,000 feet thick in some subsurface sections. The Monterey is divided into three mapped members. The lower member is characterized by phosphatic shale and somewhat porcelaneous shale; the middle member by chert and cherty shale; and the upper member by porcelaneous shale, or by both porcelaneous shale and diatomaceous strata. The lower member contains Foraminifera representing the upper part of Kleinpell's Relizian stage and all of his Luisian stage, the middle member a few species indicating the lower part of his Mohnian stage, and the upper member a fauna representing the upper part of the Bolivina hughesi zone, at the top of the Mohnian, and in part a younger unnamed faunal division; that is, the Monterey is of late middle and late Miocene age. The diverse stratigraphic relations of the Lospe and Point Sal formations and Monterey shale along the borders of the Franciscan rocks forming Point Sal Ridge are inferred to be the result of repeated movements during Miocene time in the area of basement rocks west of the district, presumably extending westward beyond the present coast. Toward the close of the Miocene, low ridges appeared on the floor of the sea, ridges that grew during Pliocene time and were destined to become anticlines. At the same time deformation took place in the northeastern part of the district, and elsewhere on some anticlines, or on other structural highs bounded by faults. In those areas the Sisquoc formation overlies the Monterey shale with marked discordance; elsewhere there is no discordance. Two facies of the Sisquoc formation are mapped: a marginal sandstone facies, designated the Tinaquaic sandstone member, and a basin facies. The Tinaquaic sandstone member is 1,400 feet thick and contains megafossils of middle Pliocene age (also early Pliocene just east of the mapped area). It is unconformable on the Monterey. The basin facies, at least 3,000 feet thick in outcrop sections and 5,000 in some subsurface sections, consists of diatomaceous mudstone, other types of diatomaceous ·strata, somewhat porcelaneous mudstone, and porcelaneous shale-deposits that are ordinarily characteristic of the Monterey shale. Even in areas where the two formations are lithologically indistinguishable and conformable, a field basis for differentiating them has been established. The basin facies of the Sisquoc conformably overlies the Monter.ey in outcrop sections, but in some subsurface sections the formations are unconformable, and on the north limb of the Santa Maria Valley syncline the basin facies of the Sisquoc overlaps the Monterey onto the basement, thus forming the overlap trap for the oil in the Monterey in the Santa Maria Valley field. The lower and middle parts of the basin facies contain Foraminifera of the Bolivina obliqua zone. Kleinpell assigned that zone to the lower part of his late upper Miocene Delmontian stage. Assignment to the upper Delmontian, however, appears to be preferable. The upper few hundred feet of the basin facies contain Foraminifera similar to those in the overlying Foxen mudstone and megafossils of middle Pliocene affinities. The basin facies is therefore considered late upper Miocene to middle Pliocene. The submarine ridges were growing during Pilocene time. The Foxen mudstone is missing on them and in the northeastern part of the district. On the north limb of the Santa Maria Valley syncline, the Foxen overlaps the Sisquoc formation and rests on the basement. In the basins between the submarine ridges, the mudstone, siltstone, and fine-grained sandstone of the Foxen (800 feet thick in outcrop sections and as much as 2, 750 in subsurface sections) overlie conformably the Sisquoc formation. In some of the areas where the Foxen is missing as a lithologic unit, it appears to be represented by condensed deposits of phosphatic pellets, mapped with the underlying or overlying Formation, depending on the matrix, or by a condensed section of fine-grained sand, mapped with lithologically indistinguishable sand in the basal part of the overlying formation. Though foraminifera are abundant in the Foxen mudstone, relatively few species are represented. Those from the lower part of the formation may be of middle Pliocene age. Megafossils from the upper part of the Foxen are considered late Pliocene. The formation is therefore assigned to the middle(?) and upper Pliocene. Movements during Pliocene time in the basement area west of Point Sal Ridge are indicated by the occurrence in the western Casmalia Hills of coarse detritus from the Monterey in the upper part of the Sisquoc formation and in the Foxen mudstone. During late Pliocene time, when the Careaga sandstone was deposited, the Pliocene sea had its greatest extent. The region then flooded may be referred to as the Santa Maria basin. Throughout most of the district two mapped members of the Careaga sandstone are differentiated: the Cebada fine-grained member, which has a maximum outcrop thickness of 1,000 feet, and the Graciosa coarse-grained member, 50 to 425 feet thick. Mild deformation continued during the late Pliocene. The Cebada fine-grained member is missing on the embryonic anticlines, where it is overlapped by the Graciosa coarse-grained member. Both members of the Careaga sandstone contain a large megafauna. The nonmarine Paso Robles formation conformably overlies the Careaga sandstone. The Paso Robles consists chiefly of sand and gravel, but clay, marl, and limestone are the most characteristic constituents. The maximum outcrop thickness is 2,000 feet, the estimated maximum subsurface thickness 4,500 feet. The Paso Robles fresh-water fauna is meager, consisting of a few species similar to living forms. The formation is currently assigned to the interval including late Pliocene and early Pleistocene(?). The age assignment late Pliocene(?) and early Pleistocene, however, may be preferable for the Santa Maria district. Then followed the only period of strong general deformation in the known Tertiary and Pleistocene history of the district. The present structural features of the district were formed at that time, and the submarine ridges appeared as fully formed anticlines. Dating of the deformation is uncertain, because of uncertainty concerning the age of the Paso Robles formation. It is, however, without much doubt of the same age as the welldated strong middle Pleistocene deformation in the Ventura basin. Terrace deposits, laid down on both wave-cut and stream-cut platforms, are rather arbitrarily assigned to the late Pleistocene. The oldest and most extensive terrace deposits, not more than 100 feet thick, are designated the Orcutt sand. The Orcutt sand itself is tilted as much as 12° on the limbs of anticlines and is faulted on the north limb of the Graciosa anticline, indicating renewed growth of the anticlines, presumably in late Pleistocene time. Terrace deposits apparently younger than the Orcutt sand are arched in a low anticline west of lower Foxen Canyon. Structure.-Santa Maria Valley is the boundary between two structural provinces. To the north, valleys and hills are either synclines or anticlines. To the south, on the contrary, major valleys coincide generally with major synclines, and the hills are anticlinal. Santa Maria Valley itself is a syncline. Unlike valleys farther south in the district, however, it lies athwart an older uplift. Also unlike most of the valleys farther south, the axis of the syncline is not in the middle of the valley, but is far to the south near the bordering hills. Indeed, in the western Casmalia Hills, the anticline in the bordering hills is overturned and overrides the axis of the syncline. The major structural features of the district have a general west-northwestward trend parallel to the trend of the basin. Minor westward-trending and northward-trending folds and faults, however, extend across the trend of the major features. The district includes areas of wide, open folds and also areas of narrow, closely spaced, and steeply tilted folds, as well as some major overturned anticlines, most of the latter overturned northward. The closely spaced folds coincide almost invariably with outcrops of the Monterey shale and Point Sal formation. Physiography.-The surface on which the terrace deposits, designated the Orcutt sand, were deposited is extensive but is locally deformed, and only remnants are preserved. Toward the coast it changes from a stream-cut surface to a wave-cut surface. In the coastal area three main marine terraces are recognized: the high terrace (altitude about 800 feet), the intermediate terrace (altitude about 600 feet), and the low terrace (altitude 50 to 125 feet). An indurated layer is present at or near the surface at many localities scattered throughout the district. It is suggested that the indurated layer is an ancient hardpan, the incomplete skeleton of a former soil profile developed on a former surface of less relief than the present surface. Sand dunes extend inland from the coast at the north and south borders of the mapped area. They are classified under three age groups: old, intermediate, and modern. The old dunes, which have a protective cover of natural vegetation and are now inactive, are far more extensive than those of the other two groups. They cover many square miles on a terrace bordering Santa Maria Valley, and extend 20 miles inland. It has not been determined whether their inactivity is due to a cutting off of the supply of sand, or to a climatic change. Occurrence of oil.--Oil has been produced in the Santa Maria district since 1901, the total production to the end of 1947 being 269,657,000 barrels. Throughout the district most of the oil is heavy. Seven producing fields are located in the mapped area. In order of discovery from oldest to youngest the fields are as follows: Orcutt, Lompoc, West Cat Canyon, East Cat Canyon, Casmalia, Gato Ridge, and Santa Maria Valley. The Santa Maria Valley field is the largest in both area and productive capacity. It is the largest overlap field in coastal California, and one of the last major fields found in the State up to 1947. The Las Flores (Monterey) pool is transforming the West Cat Canyon field into one of the major fields of the district. The Monterey shale is the chief oil-bearing formation, and the principal reservoir in the Monterey consists of fractured chert and cherty shale. Sand in the Sisquoc formation is the sole reservoir in the minor East Cat Canyon field and in the Pliocene pool of the West Cat Canyon field. The Point Sal formation yields some oil in the southeastern part of the Santa Maria Valley field (the only part of that field where the formation is present) and a recent well in the Casmalia field is producing a small amount of relatively light oil from the Point Sal. The Lospe formation is also productive in a recent well in the Casmalia field. The Knoxville formation is productive in three areas in the northern part of the Santa Maria Valley field. The Point Sal formation offers the greatest promise for deeper-zone production. The Lospe and Knoxville formations can no longer be ignored in areas where younger marine formations overlap against them. Oil possibilities in undeveloped areas.--Two matters weigh heavily in prospecting in the Santa Maria district: the degree of fracturing of chert and cherty shale in the Monterey shale, and the gravity of the oil. Other things being equal, the productivity of the Monterey varies directly with the amount of fracturing. Very heavy oil, too heavy to produce commercially under present conditions, has befln found ii the Monterey in the northeastern part of the district, where five discoveries (one east of the mapped area) have been made in recent years. Among areas of possible interest, three appear to be favorable for prospecting on the basis of surface geology: an area east of Foxen Canyon, where oil may be trapped in the basal part of the Tinaquaic sandstone member of the Sisquoc formation by westward overlap of successively higher Tinaquaic strata onto the Monterey shale; an area so1tth of the I ... ions Head fault, where oil may be trapped by the fault; and the offshore extension of the north border of Point Sal Ridge, where oil may possibly be trapped in the Monterey by overlap of the Sisquoc formation.

California↗
USGS1963

Surficial geology and soils of the Elmira-Williamsport region, New York and Pennsylvania, with a section on forest regions and great soil groups

The Elmira-Williamsport region, lying south of the Finger Lakes in central New York and northern Pennsylvania, is part of the Appalachian Plateaus physiographic province. A small segment of the Valley and Ridge province is included near the south border. In 1953 and 1954, the authors, a geologist and a soil scientist, made a reconnaissance of about 5,000 square miles extending southward from the Finger Lakes, N.Y., to Williamsport, Pa., and eastward from Wellsboro, Pa., to Towanda, Pa. Glacial drift of Wisconsin age, covering the central and most of the northern parts of the region, belongs to the Olean substage of MacClintock and Apfel. This drift is thin and patchy, is composed of the relatively soft sandstones, siltstone, shales, and conglomerates of the plateaus, commonly has a low calcium carbonate content, and is deeply leached. Mantling its surface are extensive rubbly colluvial deposits. No conspicuous terminal moraine marks the relatively straight border of Olean drift. The Valley Heads moraine of Fairchild near the south ends of the Finger Lakes is composed of relatively thick drift containing a considerable amount of somewhat resistant sedimentary and crystalline rocks. Commonly this drift has a relatively high carbonate content and is leached to only shallow depths. The Valley Heads drift is younger than Olean, but its precise age is undetermined. The age of the Olean is perhaps between Sangamon and Farmdale, on the basis of, in part, a carbon-14 date from peat at Otto, N.Y. All differences in soil development on these two Wisconsin drifts are clearly related to the lithology of the parent material or the drainage, rather than to weathering differing in kind or in duration. The authors believe that the soils are relatively young, are in equilibrium with the present environment, and contain few, if any, features acquired during past weathering intervals. The effect of tree throw on soil profiles and the presence of soils on slopes clearly indicate that soils form rapidly. Sols Bruns Acides are the most extensive great soil group occurring throughout the region. Podzols and Gray-Brown Podzolic soils are also widespread, and on long, smooth slopes Low Humic-Gley soils are common. Organic soils are of small extent. South of the Wisconsin drift border, the surficial mantle consists chiefly of alluvial, colluvial, or residual deposits of Wisconsin or of Recent age, but there are many small isolated patches of older, strongly weathered materials of pre-Wisconsin age. Although such older materials are commonly overlain or mixed with less weathered mantle, the yellowish-red color, characteristic of the strongly weathered material, is generally not masked. Some of the older material is drift, presumed to be of Illionian age, that was probably strongly weathered to a considerable depth in Sangamon time and has been greatly eroded since the last interglacial period. No clear-cut exposure of Wisconsin drift resting on older drift or other strongly weathered mantle has been found. The old drift and the other strongly weathered materials apparently acquired their present red color in pre-Wisconsin time. Where exposed at the surface, such strongly weathered mantle is the parent material of modern Red-Yellow Podzolic soils. Sols Bruns Acides and Gray-Brown Podzolic soils, developed on slightly weathered parent materials, are found adjacent to these red soils. This suggests that these Red-Yellow Podzolic soils probably developed from strongly weathered parent materials. No buried soils were found nor were any soils recognized as relics from pre-Wisconsin time. Comparison of a map of the great soil groups with a map of the vegetation of the region, prepared by John C. Goodlett, does not reveal a close relation. Laboratory analyses of samples collected furnish data on textural, mineralogical, and chemical changes caused by weathering and soil formation. The results indicate that the amount of chemical weathering which the Wisconsin drift has undergone is slight. The Red-Yellow Podzolic soils on strongly weathered pre-Wisconsin drift have B2 horizons that have a finer texture than the A2 or C horizons. The parent materials of these soils seem to be strongly weathered because of the high chromas, reddish hues, friable condition of most rock fragments, relatively high kaolinite content, and presence of gibbsite in the clay fraction. Measurements at numerous localities show that the depth of leaching increases with decreasing carbonate content and is not a criterion of the age of the drift. Pebble counts of gravels also show that the depth of leaching of gravel is related to its limestone content. The location of the gravel deposits is probably due primarily to the presence of pebbles of resistant rock rather than to ice wastage involving abundant glacial melt water. The region is in the Susquehanna drainage basin except for its north fringe, which drains to Lake Ontario. Most of the region is a dissected plateau ranging in altitude from 700 to 2,500 feet and underlain by gently folded sedimentary rocks of Paleozoic age. Much of the region slopes moderately or steeply; the most extensive areas of gently sloping land are 011 the uplands. In the northern part are several straight and deep valleys the southern extension of the Finger Lakes basins separated by uplands with several low cuestas that face north. Similarly, some streams such as the Canisteo, Cohocton, and Chemung Rivers, and the part of the Susquehanna River that is in New York, trend at right angles to the Finger Lakes, flowing in valleys that parallel the regional strike of the bedrock. The Olean drift border is marked by a change from drift containing very few rounded or striated rock fragments to a mantle containing only angular rock fragments and traces of red, strongly weathered materials. A reconstruction of the surface of the ice sheet, at its maximum extent shows an inferred slope of its distal margin ranging from 100 to 500 feet per mile

New York, Pennsylvania↗
USGS2023

High-precision ID-TIMS U-Pb geochronology of perovskite (CaTiO3) from the Ice River Complex, southeastern British Columbia

Uranium‑lead perovskite in situ geochronology has become a cornerstone technique for determining the emplacement timing of alkaline, ultrapotassic, and silica-undersaturated igneous rocks, kimberlites, and carbonatites. Accurate in situ dates are dependent on the availability of matrix matched mineral reference materials which themselves are chemically well characterized and dated accurately to the highest possible precision. When dating perovskite to high precision, such as by isotope dilution thermal ionization mass spectrometry (ID-TIMS), appropriately accounting and correcting for the quantity and isotopic composition of Pb incorporated into the crystal upon crystallization (Pb i ) is a large source of uncertainty and potential inaccuracy. Unfortunately, although ultra-high precision perovskite dates are attainable with modern mass spectrometry techniques, the accuracy of applied Pb i compositions, which can be a considerable percentage of total Pb in a crystal, has not kept pace, resulting in percent level inaccuracy on precisely measured isotopic ratios. In an effort to characterize the age and initial Pb isotopic composition of a readily available, relatively pure perovskite endmember (93–98%) which will be useful as a matrix matched age reference material for in situ U-Pb geochronology, we date crystals isolated from three samples from the Ice River Complex (samples 81IR6, I90.3, and I92.30) by ID-TIMS and evaluate their suitability as known-age reference materials. We directly determine the isotopic composition of Pb i in each sample by ID-TIMS measurement of cogenetic low 238 U/ 204 Pb (μ < 500) phlogopite, apatite, and/or clinopyroxene. Using these initial common Pb isotopic compositions, which are significantly more radiogenic than those predicted by age appropriate Pb evolution models, we obtain ultra-precise weighted-mean 206 Pb/ 238 U perovskite dates of 355.83 ± 0.14, 355.04 ± 0.15, and 357.34 ± 0.12 Ma on the three Ice River samples, respectively. These dates are consistent with the relative emplacement ages previously established for units in the Ice River layered ultramafic series based on field relationships. They also demonstrate the feasibility of attaining accurate perovskite dates in instances when maximum precision is critical by utilizing ID-TIMS analysis of cogenetic low uranium phases for direct measurement of Pb i .

British Columbia↗
USGS2006

Rates of evapotranspiration, recharge from precipitation beneath selected areas of native vegetation, and streamflow gain and loss in Carson Valley, Douglas County, Nevada, and Alpine County, California

Rapid growth and development in Carson Valley is causing concern over the continued availability of water resources to sustain such growth into the future. A study to address concerns over water resources and to update estimates of water-budget components in Carson Valley was begun in 2003 by the U.S. Geological Survey, in cooperation with Douglas County, Nevada. This report summarizes micrometeorologic, soil-chloride, and streambed-temperature data collected in Carson Valley from April 2003 through November 2004. Using these data, estimates of rates of discharge by evapotranspiration (ET), rates of recharge from precipitation in areas of native vegetation on the eastern and northern sides of the valley, and rates of recharge and discharge from streamflow infiltration and seepage on the valley floor were calculated. These rates can be used to develop updated water budgets for Carson Valley and to evaluate potential effects of land- and water-use changes on the valley's water budget. Data from eight ET stations provided estimates of annual ET during water year 2004, the sixth consecutive year of a drought with average or below average precipitation since 1999. Estimated annual ET from flood-irrigated alfalfa where the water table was from 3 to 6 feet below land surface was 3.1 feet. A similar amount of ET, 3.0 feet, was estimated from flood-irrigated alfalfa where the water table was about 40 feet below land surface. Estimated annual ET from flood-irrigated pasture ranged from 2.8 to 3.2 feet where the water table ranged from 2 to 5 feet below land surface, and was 4.4 feet where the water table was within 2 feet from land surface. Annual ET estimated from nonirrigated pasture was 1.7 feet. Annual ET estimated from native vegetation was 1.9 feet from stands of rabbitbrush and greasewood near the northern end of the valley, and 1.5 feet from stands of native bitterbrush and sagebrush covering alluvial fans along the western side of the valley. Uncertainty in most ET estimates is about 12 percent, but ranged from +30 and +50 percent to -20 and -40 percent for nonirrigated pasture and native bitterbrush and sagebrush. Estimated rates for water year 2004 likely are less than those during years of average, or above average precipitation when the water table would be closer to land surface. Test holes drilled in areas of native vegetation on the northern and eastern sides of Carson Valley had high concentrations of soil chloride at depths ranging from 4 to 18 feet below land surface at six locations on the eastern side of the valley. The high chloride concentrations indicate that modern-day precipitation at the six locations does not percolate deeper than the root zone of native vegetation. Estimates of the time required to accumulate the measured amount of chloride to depths of about 30 feet below land surface at the six test holes ranged from about 3,000 to 12,000 years. Low concentrations of soil chloride in two test holes on the northern end of Carson Valley and in a test hole on the eastern side of Fish Spring Flat indicate that a small amount of recharge from modern-day precipitation is taking place. Estimated annual recharge from precipitation at the two locations was 0.03 and 0.04 foot on the northern end of the valley and 0.02 foot on the eastern side of Fish Spring Flat. Uncertainty in the estimated recharge rates was about ?0.01 foot. Estimates of the time required to accumulate the measured amount of chloride to depths of about 30 feet below land surface at the three test holes ranged from about 100 to 700 years. The two test holes near the northern end of the valley are in gravel and eolian sand deposits and recharge from precipitation may be taking place at similar rates in other areas with gravel and eolian sand deposits. Based on results from other test holes, recharge at the rate estimated for the test hole on the eastern side of Fish Spring Flat is not likely applicable to a large area. Data from 37 site

Scientific Investigations Report↗
USGS2004

Hydrogeologic characteristics of four public drinking-water supply springs in northern Arkansas

In October 2000, a study was undertaken by the U.S. Geological Survey (USGS) in cooperation with the Arkansas Department of Health to determine the hydrogeologic characteristics, including the extent of the recharge areas, for Hughes Spring, Stark Spring, Evening Shade Spring, and Roaring Spring, which are used for public-water supply in northern Arkansas. Information pertaining to each spring can be used to enable development of effective management plans to protect these water resources and public health. An integrated approach to determine the ground-water characteristics and the extent of the local recharge areas of the four springs incorporated tools and methods of hydrology, structural geology, geomorphology, geophysics, and geochemistry. Analyses of discharge, temperature, and water quality were completed to describe ground-water flow characteristics, source-water characteristics, and connectivity of the ground-water system with surface runoff. Water-level contour maps were constructed to determine ground-water flow directions and ground-water tracer tests were conducted to determine the extent of the recharge areas and ground-water flow velocities. Hughes Spring supplies water for the city of Marshall, Arkansas, and the surrounding area. The mean annual discharge for Hughes Spring was 2.9 and 5.2 cubic feet per second for water years 2001 and 2002, respectively. Recharge to the spring occurs mainly from the Boone Formation (Springfield Plateau aquifer). Ground-water tracer tests indicate the recharge area for Hughes Spring generally coincides with the surface drainage area (15.8 square miles) and that Hughes Spring is connected directly to the surface flow in Brush Creek. The geochemistry of Hughes Spring demonstrated variations with flow conditions and the influence of surface-runoff in the recharge area. Calcite saturation indices, total dissolved solids concentrations, and hardness demonstrate noticeable differences with flow conditions reflecting the reduced residence time and interaction of water with the source rock within the ground-water system at higher discharges for Hughes Spring. Concentrations of fecal indicator bacteria also demonstrated a substantial increase during high-flow conditions, suggesting that a non-point source of bacteria possibly from livestock may enter the system. Conversely, nutrient concentrations did not vary with flow and were similar to concentrations reported for undeveloped sites in the Springfield Plateau and Ozark aquifers in northern Arkansas and southern Missouri. Deuterium and oxygen-18 data show that the Hughes Spring discharge is representative of direct precipitation and not influenced by water enriched in oxygen-18 through evaporation. Discharge data show that Hughes Spring is dominated by conduit type ground-water flow, but a considerable component of diffuse flow also exists in the ground-water system. Carbon-13 data indicate a substantial component of the recharge water interacts with the surface material (soil and regolith) in the recharge area before entering the ground-water system for Hughes Spring. Tritium data for Hughes Spring indicate that the discharge water is a mixture of recent recharge and sub-modern water (recharged prior to 1952). Stark Spring supplies water for the city of Cushman, Arkansas, and the surrounding area. 2 Hydrogeologic Characteristics of Four Public Drinking-Water Supply Springs in Northern Arkansas The mean annual discharge for Stark Spring was 0.5 and 1.5 cubic feet per second for water years 2001 and 2002, respectively. The discharge and water-quality data show the ground-water system for Stark Spring is dominated by rapid recharge from surface runoff and mainly consists of a conduit- type flow system with little diffuse-type flow. Analyses of discharge data show that the estimated recharge area (0.79 square mile) is larger than the surface drainage area (0.34 square mile). Ground-water tracer tests and the outcrop of the

Water-Resources Investigations Report↗
USGS2008

Bioassay for estimating the biogenic methane-generating potential of coal samples

Generation of secondary biogenic methane in coal beds is likely controlled by a combination of factors such as the bioavailability of coal carbon, the presence of a microbial community to convert coal carbon to methane, and an environment supporting microbial growth and methanogenesis. A set of treatments and controls was developed to bioassay the bioavailability of coal for conversion to methane under defined laboratory conditions. Treatments included adding a well-characterized consortium of bacteria and methanogens (enriched from modern wetland sediments) and providing conditions to support endemic microbial activity. The contribution of desorbed methane in the bioassays was determined in treatments with bromoethane sulfonic acid, an inhibitor of microbial methanogenesis. The bioassay compared 16 subbituminous coal samples collected from beds in Texas (TX), Wyoming (WY), and Alaska (AK), and two bituminous coal samples from Pennsylvania (PA). New biogenic methane was observed in several samples of subbituminous coal with the microbial consortium added, but endemic activity was less commonly observed. The highest methane generation [80 µmol methane/g coal (56 scf/ton or 1.75 cm 3 /g)] was from a south TX coal sample that was collected from a non-gas-producing well. Subbituminous coals from the Powder River Basin, WY and North Slope Borough, AK contained more sorbed (original) methane than the TX coal sample and generated 0–23 µmol/g (up to 16 scf/ton or 0.5 cm 3 /g) new biogenic methane in the bioassay. Standard indicators of thermal maturity such as burial depth, nitrogen content, and calorific value did not explain differences in biogenic methane among subbituminous coal samples. No original methane was observed in two bituminous samples from PA, nor was any new methane generated in bioassays of these samples. The bioassay offers a new tool for assessing the potential of coal for biogenic methane generation, and provides a platform for studying the mechanisms involved in this economically important activity.

International Journal of Coal Geology↗
USGS2014

Water movement through the unsaturated zone of the High Plains Aquifer in the Central Platte Natural Resources District, Nebraska, 2008-12

Uncertainty about the effects of land use and climate on water movement in the unsaturated zone and on groundwater recharge rates can lead to uncertainty in water budgets used for groundwater-flow models. To better understand these effects, a cooperative study between the U.S. Geological Survey and the Central Platte Natural Resources District was initiated in 2007 to determine field-based estimates of recharge rates in selected land-use areas of the Central Platte Natural Resources District in Nebraska. Measured total water potential and unsaturated-zone profiles of tritium, chloride, nitrate as nitrogen, and bromide, along with groundwater-age dates, were used to evaluate water movement in the unsaturated zone and groundwater recharge rates in the central Platte River study area. Eight study sites represented an east-west precipitation contrast across the study area—four beneath groundwater-irrigated cropland (sites 2, 5, and 6 were irrigated corn and site 7 was irrigated alfalfa/corn rotation), three beneath rangeland (sites 1, 4, and 8), and one beneath nonirrigated cropland, or dryland (site 3). Measurements of transient vertical gradients in total water potential indicated that periodic wetting fronts reached greater mean maximum depths beneath the irrigated sites than beneath the rangeland sites, in part, because of the presence of greater and constant antecedent moisture. Beneath the rangeland sites, greater temporal variation in antecedent moisture and total water potential existed and was, in part, likely a result of local precipitation and evapotranspiration. Moreover, greater variability was noticed in the total water potential profiles beneath the western sites than the corresponding eastern sites, which was attributed to less mean annual precipitation in the west. The depth of the peak post-bomb tritium concentration or the interface between the pre-bomb/post-bomb tritium, along with a tritium mass balance, within sampled soil profiles were used to estimate water fluxes in the unsaturated zone at three of the eight study sites: site 2 (irrigated), site 3 (dryland), and site 8 (rangeland). Estimates for recharge were about 68 millimeters per year [(mm/yr), post-bomb peak], 133 to 159 mm/yr (tritium interface), and 137 mm/yr (mass balance) at site 2 (irrigated); about 63 mm/yr (tritium interface) and 12 mm/yr (mass balance) at site 3 (dryland); and about 53 mm/yr (tritium interface) and 10 mm/yr (mass balance) at site 8 (rangeland). Recharge values from the mass balance at site 2 were more than an order of magnitude greater than recharge values at site 3, suggesting irrigation is an important control on water movement through the unsaturated zone. For the remaining five sites, the post-bomb tritium had flushed through the system and recharge was considered modern (within 10 years of sampling). The chloride mass-balance method was used to determine water fluxes below the root zone (less than 2 meters below land surface) at the rangeland sites: sites 1, 4, and 8. At these rangeland sites, water fluxes ranged from 1.8 to 96 mm/yr at site 1, 1.1 to 9.6 mm/yr at site 4, and 1.1 to 68 mm/yr at site 8, with mean rates of 21, 4.3, and 13 mm/yr, respectively. Site 1 had a greater mean water flux, which was consistent with the greater precipitation in the east than at site 8 in the west. Chloride mass balance was not calculated at the irrigated and dryland sites because of uncertainty about additional sources of chloride. Concentrations of nitrate as nitrogen in pore water in the unsaturated zone were larger beneath the irrigated and dryland (agricultural) sites compared with the rangeland sites. The larger concentrations at the agricultural sites are consistent with the application of nitrogen fertilizer at the agricultural sites and no substantial accumulation at the rangeland sites. The shape of the nitrate as nitrogen and chloride concentration profiles at site 1 (rangeland) indicate a reasonably larger and more consistent water flux in the UZ than beneath the other two rangeland sites (sites 4 or 8). Excluding site 7, the general shape of the nitrate as nitrogen profiles was similar beneath the agricultural sites and supports the estimates of water movement and recharge rates determined from the tritium and chloride methods. Movement of bromide through the unsaturated zone indicated greater water fluxes are found beneath irrigated lands than beneath rangeland. Bromide profiles in the unsaturated zone, determined from center of mass and peak displacement methods, document water fluxes ranged from 58 to 394 mm/yr beneath irrigated sites and 9 to 201 mm/yr beneath rangeland sites. Water-flux estimates from the potassium bromide tests at most sites did not represent overall recharge rates because the bromide remained primarily in the root zone. Apparent groundwater age was used to determine the groundwater residence time at the eight sites and to estimate recharge rates. Groundwater ages in the study area ranged from old water (defined here as groundwater that was recharged more than 50 years ago) to modern (defined here as groundwater that has recharged within the past 10 years). Groundwater ages indicated that the shallow monitoring wells generally had younger residence times, whereas the deeper monitoring wells generally had the older residence times. Groundwater dates from the shallowest monitoring wells were used to determine recharge rates at the water table. These rates generally were similar to recharge rates determined from tritium and chloride mass-balance methods. Groundwater recharge rates generally increased with well depth, and the deeper monitoring wells likely do not represent local recharge conditions but recharge from a regional flow system that receives recharge from distant sources. Overall, these data generally indicate that water movement within the unsaturated zone primarily is affected by spatial contrasts in mean annual precipitation and by the land use or land cover. The eight unsaturated-zone sites each generated unique, valuable datasets that likely will improve the understanding of water movement and recharge rates in the central Platte River valley.

Nebraska↗
USGS2021

Tectonic and magmatic controls on the metallogenesis of porphyry deposits in Alaska

Porphyry Cu and Mo deposits and occurrences are found throughout Alaska; they formed episodically during repeated subduction and arc-continent collisions spanning the Silurian to Quaternary. Porphyry systems occur in continental-margin and island arcs, which are broadly grouped into pre-accretionary or post-accretionary arcs. Pre-Mesozoic occurrences formed in continental or island arcs prior to accretion onto the margin of North America, whereas Mesozoic and younger systems formed in arcs that developed after terrane fragments were accreted to the margin of North America. As a result, older porphyry systems are typically in the interior and northern metallogenic belts, whereas the younger porphyry systems are predominantly found in the southern third of the state, closer to the modern continental margin. Alaska porphyry formation peaked in the mid-Cretaceous and continued through the Late Cretaceous to Tertiary, in association with continental-margin arcs extending from the eastern interior, into southwest Alaska and along the Alaska Peninsula and Aleutian Islands. Porphyry system formation is not generally recognized in the Early Cretaceous, Triassic, or early Paleozoic – time periods that coincide with continental collisional events or extension. Relatively few pre-accretionary porphyry systems are documented in more deeply exhumed arc segments due to low preservation potential in areas of rapid or repeated bedrock uplift and associated erosion that occurred during later tectonic events. Significant diversity is observed in porphyry occurrences across the state and even within the same region. Occurrences form in association with arc-related intrusions or intrusive complexes, that range in composition from diorite to syenite, but are commonly monzonitic to granitic. Some porphyry occurrences are associated with alkaline intrusive belts that exhibit a stronger crustal contribution to magmatic sources. Intrusions associated with porphyry formation in Alaska are commonly moderately oxidized, however, a distinct group of porphyry systems are associated with more-reduced magmas. Hydrothermal alteration described at many occurrences exhibits zoning from proximal potassic alteration to typically peripheral and(or) later sericitic alteration, that is flanked by large zones of propylitic alteration. Diversity in alteration is observed where sodic and sodic-calcic alteration is present, commonly in more-enigmatic deposits, such as Island Mountain and Chicken Mountain. Advanced argillic alteration is rare, but present in notable examples, such as the Pebble porphyry Cu(-Au-Mo) deposit. Sulfide mineralization is characterized by pyrite, chalcopyrite, molybdenite, and rare bornite hosted in veinlets, veins and disseminations in wallrocks and causative intrusions. Some porphyry systems contain abundant pyrrhotite and(or) arsenopyrite in the mineral assemblages. Systems that exhibit bornite-bearing assemblages containing abundant molybdenite are commonly arsenic- and gold-poor and tend to be associated with more oxidized arc magmas. In contrast, those systems that are pyrrhotite and(or) arsenopyrite dominant tend to be gold, arsenic, and bismuth bearing, and are commonly associated with more-reduced magmas. Exploration for porphyry occurrences in Alaska has experienced a resurgence and currently constitutes about 20% of exploration dollars in the state. Many systems lack complete descriptions, and coupled with the cost of exploration, remain incompletely explored. Additional understanding of known occurrences combined with a framework geologic understanding of porphyry-bearing metallogenic belts will likely result in new discoveries in the future.

Alaska↗
USGS1993

Inorganic geochemistry of domed peat in Indonesia and its implication for the origin of mineral matter in coal

The inorganic geochemistry of three domed ombrogenous peat deposits in Riau and West Kalimantan provinces, Indonesia, was investigated as a possible modern analogue for certain types of low-ash, low-sulfur coal. Mineral matter entering the deposits is apparently limited to small amounts from the allogenic sources of dryfall, rainfall, and diffusion from substrate pore water. In the low-ash peat in the interior of the deposits, a large portion of the mineral matter is authigenic and has been mobilized and stabilized by hydrological, chemical, and biological processes and conditions. Ash yield and sulfur content are low through most of the peat deposits and average 1.1% and 0.14%, respectively, on a moisture-free basis. Ash and sulfur contents only exceed 5% and 0.3%, respectively, near the base of the deposits, with maximum concentrations of 19.9% ash and 0.56% sulfur. Peat water in all three deposits has a low pH, about 4 units, and low dissolved cation concentration, averaging 14 ppm. Near the base, in the geographic interior of each peat deposit, pH is about two units higher and dissolved cation concentration averages 110 ppm. Relative concentrations of the inorganic constituents vary, resulting in chemical facies in the peat. In general, Si, Al, and Fe are the abundant inorganic constituents, although Mg, Ca, and Na dominate in the middle horizon in the geographic interior of coastal peat deposits. The composition of the three deposits reported in this paper indicates that domed ombrogenous peat deposits will result in low ash and sulfur coal, probably less than 10% ash and 1% sulfur, even if marine rocks are laterally and vertically adjacent to the coal.

Special Paper of the Geological Society of America↗
USGS1999

Preliminary geologic map of the San Guillermo Mountain Quadrangle, Ventura County, California

New 1:24,000-scale geologic mapping in the Cuyama 30' x 60' quadrangle, in support of the USGS Southern California Areal Mapping Project (SCAMP), is contributing to a more complete understanding of the stratigraphy, structure, and tectonic evolution of the complex junction area between the NW-striking Coast Ranges and EW-striking western Transverse Ranges. The 1:24,000-scale geologic map of the San Guillermo Mountain quadrangle is one of six contiguous 7 1/2' quadrangle geologic maps in the eastern part of the Cuyama map area being compiled for a more detailed portrayal and reevaluation of geologic structures and rock units shown on previous geologic maps of the area (e.g., Dibblee, 1979). The following observations and interpretations are based on the new San Guillermo Mountain geologic compilation: (1) The new geologic mapping in the northern part of the San Guillermo Mountain quadrangle allows for reinterpretation of fault architecture that bears on potential seismic hazards of the region. Previous mapping had depicted the eastern Big Pine fault (BPF) as a northeast-striking, sinistral strike-slip fault that extends for 30 km northeast of the Cuyama River to its intersection with the San Andreas fault (SAF). In contrast the new mapping indicates that the eastern BPF is a thrust fault that curves from a northeast strike to an east strike, where it is continuous with the San Guillermo thrust fault, and dies out further east about 15 km south of the SAF. This redefined segment of the BPF is a south-dipping, north-directed thrust, with dominantly dip slip components (rakes > 60 deg.), that places Middle Eocene marine rocks (Juncal and Matilija Formations) over Miocene through Pliocene(?) nonmarine rocks (Caliente, Quatal, and Morales Formations). Although a broad northeast-striking fault zone, exhibiting predominantly sinistral components of slip (rakes < 45 deg.), extends to the SAF as previously mapped, the fault zone does not connect to the southwest with the BPF but instead curves into a southwest-directed thrust fault system a short distance north of the BPF. Oligocene to Pliocene(?) nonmarine sedimentary and volcanic rocks of the Plush Ranch, Caliente, and Morales(?) Formations are folded on both sides of this fault zone (informally named the Lockwood Valley fault zone [LVFZ] on the map). South-southeast of the LVFZ overturned folds have southward vergence. Several moderate-displacement (< 50 m), mainly northwest-dipping thrust and reverse faults, exhibiting mostly sinistral-oblique slip, flank and strike parallel to the overturned folds. The fold vergence and thrust direction associated with the LVFZ is opposite to that of the redefined BPF, providing further evidence that the two faults are distinct structures. These revised fault interpretations bring into question earlier estimates of net sinistral strike-slip displacement of as much as 13 km along the originally defined eastern BPF, which assumed structural connection with the LVFZ. Also, despite sparse evidence for repeated Quaternary movement on the LVFZ (e.g., Dibblee, 1982), the potential for a large earthquake involving coseismic slip on both the LVFZ and the central BPF to the southwest may not be as great as once believed. (2) Several generations of Pleistocene and younger dissected alluvial terrace and fan deposits sit at various levels above modern stream channels throughout the quadrangle. These deposits give testimony to the recent uplift and related fault deformation that has occurred in the area. (3) A vast terrane of Eocene marine sedimentary rocks (Juncal and Matilija Formations and Cozy Dell Shale) exposed south of the Big Pine fault forms the southern two-thirds of the San Guillermo Mountain quadrangle. Benthic foraminifers collected from various shale intervals within the Juncal Formation indicate a Middle Eocene age (Ulatisian) for the entire formation (K. McDougall, unpub. data, 1998) and deposition at paleodepths as great as 2,000 m (i.e., lowe

California↗
USGS2022

Hydrogeology and groundwater quality in the San Agustin Basin, New Mexico, 1975–2019

This report describes the findings of a U.S. Geological Survey study, completed in cooperation with the Bureau of Land Management, focused on better understanding the present-day (1975–2019) hydrogeology and groundwater quality of the San Agustin Basin in west-central New Mexico to support sustainable groundwater resource management. The basin hosts a relatively undeveloped basin-fill and alluvium aquifer system and is topographically divided into east and west subbasins by the McClure Hills. Groundwater chemistry and groundwater elevation data were compiled, collected, and interpreted in the context of groundwater flow and quality. The analyses presented in this report consider groundwater chemistry data collected within the last decade (2010–19) and groundwater elevation data collected from 1975 through 2019 to provide insight into present-day conditions. Groundwater elevations show that groundwater typically moves from the highlands to the lowlands, with a prominent east to west regional trend. Groundwater elevations were lowest in the southwestern portion of the west subbasin, where estimated flow directions suggest underflow through the local highlands into the northern East Fork Gila River watershed, which is further supported by historical groundwater elevation data from the northern East Fork Gila River watershed. Gradual groundwater elevation gradients (about 2 feet per mile) near the east and west subbasin divide suggest that groundwater slowly flows from the east subbasin to the west subbasin. Quantitative analyses of groundwater chemistry data show that groundwater in both subbasins has similar chemical characteristics. A systematic east to west groundwater evolution in water chemistry was not observed despite evidenced subbasin connectivity. The absence of this pattern suggests that groundwater mixing is regionally prevalent, sediment reactivity is low and variable, and (or) recharge conditions are comparable in both subbasins. Groundwater chemistry was generally independent of aquifer type, suggesting that the aquifers are hydrologically well connected. Corrected carbon-14 groundwater age estimates in the basin ranged from 232 to 13,916 years before present with a median of 5,409 years. A wide range of groundwater ages is therefore present in the basin, with waters commonly being thousands of years old, thereby supporting generally slow regional groundwater movement. A component of relatively young groundwater, for which estimated ages could not be accurately computed, is also present in the basin, and it may commonly mix with older waters. The spatial distribution of categorical and quantitative groundwater ages indicates that most recharge likely occurs in the highlands through mountain-block recharge and as focused recharge within arroyos, although evidence of modern (1953 and after) groundwater was minimal at sampled sites. Median annual gradients (groundwater elevation change over time) indicate that most groundwater elevations in the lowlands changed little (−0.2 to 0.2 foot per year) from 1975 through 2019. Groundwater elevations in the highlands varied more annually, which is likely due to recharge from precipitation events. These more variable groundwater elevations in the highlands compared with the lowlands, along with groundwater ages, provide further evidence that most groundwater recharge takes place in the highlands, with minimal recharge in the lowlands. Median groundwater elevation change for all sites was −0.05 foot per year. Temporal consistency of lowland groundwater elevations suggests that regional groundwater dynamics have been more or less stable through time under current climate and development conditions, although median annual gradients indicate that groundwater elevations may have slightly declined on average between 1975 and 2019.

New Mexico↗
USGS1984

Models for the deposition of Mesozoic-Cenozoic fine-grained organic-carbon-rich sediment in the deep sea

The widespread occurrence of organic-carbon-rich strata (‘black shales’) in certain portions of Jurassic, Cretaceous and Cenozoic sequences has been well-documented from Deep Sea Drilling Project sites in the Atlantic and Pacific Oceans and from sequences, now exposed on land, originally deposited in the Tethyan ocean. These ancient black shales usually have been explained by analogy with examples of modern deep-sea sediments in which organic matter locally is preserved by (1) increasing the supply of organic matter, (2) increasing the rate of sedimentation, and/or (3) decreasing the oxygen content of the bottom water. However, detailed examination of many black shales reveals characteristics that cannot be explained by simple local models, including: their approximate coincidence in time globally; their occurrence in a variety of different environments, including open oxygenated oceans, restricted basins, deep and shallow water; their interbedding with organic-carbonpoor strata which often dominate a so-called black shale sequence; their deposition by pelagic, hemipelagic, turbiditic and other processes; and the variations in type and amount of organic matter that occur even within the same sequence. A more complex model for the origin of black shales therefore appears most appropriate, in which the cyclic preservation of organic matter depends on the interplay of the three main variables, namely supply of organic matter, sedimentation rate, and deep-water oxygenation, each of which varies independently to some extent. The variation and relative importance of these parameters in individual basins and widespread black shale deposition in general are linked globally and temporally by changes in global sea-level, climate and related changes in oceanic circulation. An important and often overlooked factor for the supply of organic matter to deep-basin sediments is the frequency and magnitude of redepositional processes. The interplay of these variables is discussed in relation to the middle Cretaceous and Cenozoic organic-carbon-rich strata, in particular, which show marked differences in the relative importance of the different variables.

Geological Society of London Special Publications↗
USGS2012

Geohydrology of Big Bear Valley, California: phase 1--geologic framework, recharge, and preliminary assessment of the source and age of groundwater

The Big Bear Valley, located in the San Bernardino Mountains of southern California, has increased in population in recent years. Most of the water supply for the area is pumped from the alluvial deposits that form the Big Bear Valley groundwater basin. This study was conducted to better understand the thickness and structure of the groundwater basin in order to estimate the quantity and distribution of natural recharge to Big Bear Valley. A gravity survey was used to estimate the thickness of the alluvial deposits that form the Big Bear Valley groundwater basin. This determined that the alluvial deposits reach a maximum thickness of 1,500 to 2,000 feet beneath the center of Big Bear Lake and the area between Big Bear and Baldwin Lakes, and decrease to less than 500 feet thick beneath the eastern end of Big Bear Lake. Interferometric Synthetic Aperture Radar (InSAR) was used to measure pumping-induced land subsidence and to locate structures, such as faults, that could affect groundwater movement. The measurements indicated small amounts of land deformation (uplift and subsidence) in the area between Big Bear Lake and Baldwin Lake, the area near the city of Big Bear Lake, and the area near Sugarloaf, California. Both the gravity and InSAR measurements indicated the possible presence of subsurface faults in subbasins between Big Bear and Baldwin Lakes, but additional data are required for confirmation. The distribution and quantity of groundwater recharge in the area were evaluated by using a regional water-balance model (Basin Characterization Model, or BCM) and a daily rainfall-runoff model (INFILv3). The BCM calculated spatially distributed potential recharge in the study area of approximately 12,700 acre-feet per year (acre-ft/yr) of potential in-place recharge and 30,800 acre-ft/yr of potential runoff. Using the assumption that only 10 percent of the runoff becomes recharge, this approach indicated there is approximately 15,800 acre-ft/yr of total recharge in Big Bear Valley. The INFILv3 model was modified for this study to include a perched zone beneath the root zone to better simulate lateral seepage and recharge in the shallow subsurface in mountainous terrain. The climate input used in the INFILv3 model was developed by using daily climate data from 84 National Climatic Data Center stations and published Parameter Regression on Independent Slopes Model (PRISM) average monthly precipitation maps to match the drier average monthly precipitation measured in the Baldwin Lake drainage basin. This model resulted in a good representation of localized rain-shadow effects and calibrated well to measured lake volumes at Big Bear and Baldwin Lakes. The simulated average annual recharge was about 5,480 acre-ft/yr in the Big Bear study area, with about 2,800 acre-ft/yr in the Big Bear Lake surface-water drainage basin and about 2,680 acre-ft/yr in the Baldwin Lake surface-water drainage basin. One spring and eight wells were sampled and analyzed for chemical and isotopic data in 2005 and 2006 to determine if isotopic techniques could be used to assess the sources and ages of groundwater in the Big Bear Valley. This approach showed that the predominant source of recharge to the Big Bear Valley is winter precipitation falling on the surrounding mountains. The tritium and uncorrected carbon-14 ages of samples collected from wells for this study indicated that the groundwater basin contains water of different ages, ranging from modern to about 17,200-years old.The results of these investigations provide an understanding of the lateral and vertical extent of the groundwater basin, the spatial distribution of groundwater recharge, the processes responsible for the recharge, and the source and age of groundwater in the groundwater basin. Although the studies do not provide an understanding of the detailed water-bearing properties necessary to determine the groundwater availability of the basin, they do provide a framework for the future development of a groundwater model that would help to improve the understanding of the potential hydrologic effects of water-management alternatives in Big Bear Valley.

California↗
USGS2005

"Sour gas" hydrothermal jarosite: Ancient to modern acid-sulfate mineralization in the southern Rio Grande Rift

As many as 29 mining districts along the Rio Grande Rift in southern New Mexico contain Rio Grande Rift-type (RGR) deposits consisting of fluorite-barite??sulfide-jarosite, and additional RGR deposits occur to the south in the Basin and Range province near Chihuahua, Mexico. Jarosite occurs in many of these deposits as a late-stage hydrothermal mineral coprecipitated with fluorite, or in veinlets that crosscut barite. In these deposits, many of which are limestone-hosted, jarosite is followed by natrojarosite and is nested within silicified or argillized wallrock and a sequence of fluorite-barite??sulfide and late hematite-gypsum. These deposits range in age from ???10 to 0.4 Ma on the basis of 40Ar/39Ar dating of jarosite. There is a crude north-south distribution of ages, with older deposits concentrated toward the south. Recent deposits also occur in the south, but are confined to the central axis of the rift and are associated with modern geothermal systems. The duration of hydrothermal jarosite mineralization in one of the deposits was approximately 1.0 my. Most ??18OSO4-OH values indicate that jarosite precipitated between 80 and 240 ??C, which is consistent with the range of filling temperatures of fluid inclusions in late fluorite throughout the rift, and in jarosite (180 ??C) from Pen??a Blanca, Chihuahua, Mexico. These temperatures, along with mineral occurrence, require that the jarosite have had a hydrothermal origin in a shallow steam-heated environment wherein the low pH necessary for the precipitation of jarosite was achieved by the oxidation of H2S derived from deeper hydrothermal fluids. The jarosite also has high trace-element contents (notably As and F), and the jarosite parental fluids have calculated isotopic signatures similar to those of modern geothermal waters along the southern rift; isotopic values range from those typical of meteoric water to those of deep brine that has been shown to form from the dissolution of Permian evaporite by deeply circulating meteoric water. Jarosite ??34S values range from -24??? to 5???, overlapping the values for barite and gypsum at the high end of the range and for sulfides at the low end. Most ??34S values for barite are 10.6??? to 13.1???, and many ??34S values for gypsum range from 13.1??? to 13.9??? indicating that a component of aqueous sulfate was derived from Permian evaporites (??34 S=12??2???). The requisite H2SO4 for jarosite formation was derived from oxidation of H2S which was likely largely sour gas derived from the thermochemical reduction of Permian sulfate. The low ??34S values for the precursor H2S probably resulted from exchange deeper in the basin with the more abundant Permian SO42- at ???150 to 200 ??C. Jarosite formed at shallow levels after the pH buffering capacity of the host rock (typically limestone) was neutralized by precipitation of earlier minerals. Some limestone-hosted deposits contain caves that may have been caused by the low pH of the deep basin fluids due to the addition of deep-seated HF and other magmatic gases during periods of renewed rifting. Caves in other deposits may be due to sulfuric acid speleogenesis as a result of H2S incursion into oxygenated groundwaters. The isotopic data in these "sour gas" jarosite occurrences encode a record of episodic tectonic or hydrologic processes that have operated in the rift over the last 10 my. ?? 2004 Elsevier B.V. All rights reserved.

Chemical Geology↗
USGS2012

Refining the model of barrier island formation along a paraglacial coast in the Gulf of Maine

Details of the internal architecture and local geochronology of Plum Island, the longest barrier in the Gulf of Maine, have refined our understanding of barrier island formation in paraglacial settings. Ground-penetrating radar and shallow-seismic profiles coupled with sediment cores and radiocarbon dates provide an 8000-year evolutionary history of this barrier system in response to changes in sediment sources and supply rates as well as variability in the rate of sea-level change. The barrier sequence overlies tills of Wisconsinan and Illinoian glaciations as well as late Pleistocene glaciomarine clay deposited during the post-glacial sea-level highstand at approximately 17 ka. Holocene sediment began accumulating at the site of Plum Island at 7–8 ka, in the form of coarse fluvial channel-lag deposits related to the 50-m wide erosional channel of the Parker River that carved into underlying glaciomarine deposits during a lower stand of sea level. Plum Island had first developed in its modern location by ca. 3.6 ka through onshore migration and vertical accretion of reworked regressive and lowstand deposits. The prevalence of southerly, seaward-dipping layers indicates that greater than 60% of the barrier lithosome developed in its modern location through southerly spit progradation, consistent with a dominantly longshore transport system driven by northeast storms. Thinner sequences of northerly, landward-dipping clinoforms represent the northern recurve of the prograding spit. A 5–6-m-thick inlet-fill sequence was identified overlying the lower stand fluvial deposit; its stratigraphy captures events of channel migration, ebb-delta breaching, onshore bar migration, channel shoaling and inlet infilling associated with the migration and eventual closure of the inlet. This inlet had a maximum cross-sectional area of 2800 m2 and was active around 3.5–3.6 ka. Discovery of this inlet suggests that the tidal prism was once larger than at present. Bay infilling, driven by the import of sediment into the backbarrier environment through tidal inlets, as well as minor sediment contribution from local rivers, led to a vast reduction in the bay tidal prism. This study demonstrates that, prior to about 3 ka, Plum Island and its associated marshes, tidal flats, and inlets were in a paraglacial environment; that is, their main source of sediment was derived from the erosion and reworking of glaciogenic deposits. Since that time, Plum Island has been in a state of dynamic equilibrium with its non-glacial sediment sources and therefore can be largely considered to be in a stable, “post-paraglacial” state. This study is furthermore the first in the Gulf of Maine to show that spit accretion and inlet processes were the dominant mechanisms in barrier-island formation and thus serves as a foundation for future investigations of barrier development in response to backbarrier infilling.

Massachusetts↗
USGS2015

Late Holocene sea- and land-level change on the U.S. southeastern Atlantic Coast

Late Holocene relative sea-level (RSL) reconstructions can be used to estimate rates of land-level (subsidence or uplift) change and therefore to modify global sea-level projections for regional conditions. These reconstructions also provide the long-term benchmark against which modern trends are compared and an opportunity to understand the response of sea level to past climate variability. To address a spatial absence of late Holocene data in Florida and Georgia, we reconstructed ~ 1.3 m of RSL rise in northeastern Florida (USA) during the past ~ 2600 years using plant remains and foraminifera in a dated core of high salt-marsh sediment. The reconstruction was fused with tide-gauge data from nearby Fernandina Beach, which measured 1.91 ± 0.26 mm/year of RSL rise since 1900 CE. The average rate of RSL rise prior to 1800 CE was 0.41 ± 0.08 mm/year. Assuming negligible change in global mean sea level from meltwater input/removal and thermal expansion/contraction, this sea-level history approximates net land-level (subsidence and geoid) change, principally from glacio-isostatic adjustment. Historic rates of rise commenced at 1850–1890 CE and it is virtually certain ( P = 0.99) that the average rate of 20th century RSL rise in northeastern Florida was faster than during any of the preceding 26 centuries. The linearity of RSL rise in Florida is in contrast to the variability reconstructed at sites further north on the U.S. Atlantic coast and may suggest a role for ocean dynamic effects in explaining these more variable RSL reconstructions. Comparison of the difference between reconstructed rates of late Holocene RSL rise and historic trends measured by tide gauges indicates that 20th century sea-level trends along the U.S. Atlantic coast were not dominated by the characteristic spatial fingerprint of melting of the Greenland Ice Sheet.

Florida↗
USGS1996

Character, paleoenvironment, rate of accumulation, and evidence for seismic triggering of Holocene turbidites, Canada Abyssal Plain, Arctic Ocean

Four box cores and one piston core show that Holocene sedimentation on the southern Canada Abyssal Plain for the last 8010 ± 120 yr has consisted of a continuing rain of pelagic organic and ice-rafted clastic sediment with a net accumulation rate during the late Holocene of ⩽10 mm/1000 yr, and episodically emplaced turbidites 1–5 m thick deposited at intervals of 830 to 3450 yr (average 2000 yr). The average net accumulation rate of the mixed sequence of turbidites and thin pelagite interbeds in the cores is about 1.2 m/1000 yr. Physiography suggests that the turbidites originated on the Mackenzie Delta or its clinoform, and δ 13 C values of −27 to −25%. in the turbidites are compatible with a provenance on a delta. Extant displaced neritic and lower slope to basin plain calcareous benthic foraminifers coexist in the turbidite units. Their joint occurence indicates that the turbidites originated on the modern continental shelf and entrained sediment from the slope and rise enroute to their final resting place on the Canada Abyssal Plain. The presence of Middle Pleistocene diatoms in the turbidites suggests, in addition, that the turbidites may have originated in shallow submarine slides beneath the upper slope or outer shelf. Small but consistent differences in organic carbon content and δ 13 C values between the turbidite units suggest that they did not share an identical provenance, which is at least compatible with an origin in slope failures. The primary provenance of the ice-rafted component of the pelagic beds was the glaciated terrane of northwestern Canada; and the provenance of the turbidite units was Pleistocene and Holocene sedimentary deposits on the outer continental shelf and upper slope of the Mackenzie Delta. Largely local derivation of the sediment of the Canada Abyssal Plain indicates that sediment accumulation rates in the Arctic Ocean are valid only for regions with similar depositional sources and processes, and that these rates cannot be extrapolated regionally. The location of an elliptical zone of active seismicity over the inferred provenance of the turbidites suggests that they were triggered by large earthquakes. Distal turbidite sediment accumulation rates were more than two orders of magnitude greater than pelagic sediment accumulation rates on the Canada Abyssal Plain during the last 8000 years. This disparity reconciles the discrepancy between the high accumulation rates assumed by some for the Arctic Ocean because of the numerous major rivers and large ice sheets that discharge into this small mediterranean basin and the low pelagic sedimentation rates that have been reported from the Arctic Ocean.

Marine Geology↗
USGS2007

The Yellowstone hotspot, Greater Yellowstone ecosystem, and human geography

Active geologic processes associated with the Yellowstone hotspot are fundamental in shaping the landscapes of the greater Yellowstone ecosystem (GYE), a high volcanic plateau flanked by a crescent of still higher mountainous terrain. The processes associated with the Yellowstone hotspot are volcanism, faulting, and uplift and are observed in the geology at the surface. We attribute the driving forces responsible for the northeastward progression of these processes to a thermal plume rising through the Earth&rsquo;s mantle into the base of the southwest-moving North American plate. This progression began 16 million years ago (Ma) near the Nevada-Oregon border and arrived at Yellowstone about 2 Ma. Before arrival of the hotspot, an older landscape existed, particularly mountains created during the Laramide orogeny about 70&ndash;50 Ma and volcanic terrain formed by Absaroka andesitic volcanism mostly between 50&ndash;45 Ma. These landscapes were more muted than the present, hotspot-modified landscape because the Laramide-age mountains had worn down and an erosion surface of low relief had developed on the Absaroka volcanic terrain. The Yellowstone Plateau was built by hotspot volcanism of rhyolitic lavas and caldera-forming rhyolite tuffs (ignimbrites). Streams eroding back into the edges of this plateau have created scenic waterfalls and canyons such as the Grand Canyon of the Yellowstone and Lewis Canyon. Rhyolite is poor in plant nutrients and forms sandy, well-drained soils that support the monotonous, fire-adapted lodgepole pine forests of the Yellowstone Plateau. Non-rhyolitic rocks surround this plateau and sustain more varied vegetation, including spruce, fir, and whitebark pine forests broken by grassy meadows. Heat from the hotspot rises upward and drives Yellowstone&rsquo;s famed geysers, hot springs, and mudpots. These thermal waters are home to specialized, primitive ecosystems, rich in algae and bacteria. The rock alteration associated with hydrothermal systems creates the bright colors of Yellowstone&rsquo;s Grand Canyon. Basin-and-range-style faulting has accompanied migration of the hotspot to Yellowstone and formed the linear mountains and valleys that occur north and south of the hotspot track, which is the present-day eastern Snake River Plain. High rates of basin-and-range faulting occurred adjacent to the migrating Yellowstone hotspot, creating distinctive landscapes within the GYE such as the Teton Range/Jackson Hole, with characteristic rugged, forested ranges and adjacent flat-floored grassy valleys. The difference in altitude between the mountains and valleys provides a topographic gradient in which vegetation maturation advances with altitude; animal-migration patterns also follow this trend. The valleys provide natural meadows, agricultural land, town sites, and corridors for roads. Uplift of the GYE by as much as 1 km (3,000 ft) during the last 5 million years has resulted in ongoing erosion of deep, steep-walled valleys. Many prominent ecological characteristics of Yellowstone derive from this hotspot-induced uplift, including the moderate- to high- altitude terrain and associated cool temperatures and deep snowfall. Modern and Pleistocene climate and associated vegetation patterns strongly relate to the topography created by the hotspot and its track along the eastern Snake River Plain. Winter air masses from the moist northern Pacific Ocean traverse the topographic low of the Snake River Plain to where orographic rise onto the Yellowstone Plateau and adjacent mountains produces deep snow. A winter precipitation shadow forms on the lee (eastern) sides of the GYE. During Pleistocene glacial times, this moisture conduit provided by the hotspot-track-produced ice-age glaciers that covered the core of the present GYE. These glaciers sculpted bedrock and produced glacial moraines that are both forested and unforested, sand and gravel of ice-marginal streams and outwash gravels that are commonly covered with sagebrush-grassland, and silty lake sediments that are commonly covered by lush grassland such as Hayden Valley. The effects of the Yellowstone hotspot also profoundly shaped the human history in the GYE. Uplift associated with the hotspot elevates the GYE to form the Continental Divide, and streams drain radially outward like spokes from a hub. Inhabitants of the GYE 12,000&ndash;10,000 years ago, as well as more recent inhabitants, followed the seasonal green-up of plants and migrating animals up into the mountain areas. During European immigration, people settled around Yellowstone in the lower parts of the drainages and established roads, irrigation systems, and cultural associations. The core Yellowstone highland is too harsh for agriculture and inhospitable to people in the winter. Beyond this core, urban and rural communities exist in valleys and are separated by upland areas. The partitioning inhibits any physical connection of communities, which in turn complicates pursuit of common interests across the whole GYE. Settlements thus geographically isolated evolved as diverse, independent communities

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