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Preliminary lithostratigraphy, interpreted geophysical logs and hydrogeologic characteristics of the 98th Street core hole, Albuquerque, New Mexico

Core samples, cuttings, and numerous geophysical logs obtained from the 1560 ft (475.5 m) core hole drilled at 98th Street on the west side of Albuquerque provide key stratigraphic and hydraulicproperty information for the upper clastic sediments of the Santa Fe Group, which form the principal aquifer in the region. The core hole and an adjacent water-level monitoring well were drilled cooperatively by the U.S. Geological Survey (USGS) and the City of Albuquerque and investigated in collaboration with the New Mexico Bureau of Mines and Mineral Resources and the New Mexico Office of the State Engineer to improve understanding of aquifer characteristics and controls on ground-water availability and quality. The 751.5 ft (229 m) of core samples recovered from the core hole are the only undisturbed samples of nonlithified sediments of the upper part of the Santa Fe Group that have been collected in this area. These samples have allowed us, for the first time, to directly observe and characterize the lithic and sedimentologic features of this part of the section, and to correlate the detailed geologic features with geophysical-log characteristics, magnetic susceptibility measurements, hydraulic variables, and trace-element geochemistry. The adjacent well was designed to be an areally representative ground-water level and water-quality monitoring well for the Santa Fe Group aquifer. This report chiefly addresses the lithologic, stratigraphic, and hydrogeologic features determined from the 98th Street core hole; other reports address related characteristics. Previous geologic studies predicted the stratigraphy at the site to be, from the land surface downward: 1) Quaternary alluvial and eolian valley-border sediments; 2) fluvial sand and gravel of the upper unit of the Santa Fe Group (Ceja Member of the Santa Fe Formation of Kelly, 1978; equivalent to the Sierra Ledrones Formation of Machette (1978a); 3) downward-fining basin-floor silty clay deposits and 4) fluvial sandy and silty facies of the middle unit of the Santa Fe Group (the Middle Red Member of Bryan and McCann, 1937, and Lambert, 1968). New geologic interpretations indicate that the drill site is in a fault block bounded by east-dipping normal faults and the oblique Atrisco-Rincon fault zone. Core-hole sampling recovered 760.6 ft (231.8 m) of core, in core segments 2.1-2.375 in. (5.3-6 cm) in diameter, and 0.2-10 ft (6.1 cm-3 m) long. The core hole was cased with centered 3-in. PVC casing, and is available for geophysical logging. The monitoring-well hole contains four piezometers at depths of 1544 ft (470.6 m), 1112 ft (338.9 m), 749 ft (228.3 m), and 458 ft (139.6 m). Sediments in the core are loose to weakly cemented gravel, sand, silt, and clay, and lithified sandstone. Laboratory analyses of particle-size distributions of 28 channel samples show that most silty sand samples are uniformly graded and poorly sorted; medium sand samples are moderately sorted. Six principal sediment types are used to describe the core; these sediment types are repeated in various combinations throughout the core and are used to define 22 lithologic units in the cored interval. The six principal sediment types contain sequences of beds having similar modal grain size and sedimentary structure, and are listed in decreasing abundance: 1) Silty fine sand, poorly sorted, containing a coarse silt matrix. Geophysical logs show highly variable baselines with deflections that are related to clay beds and sequences of silt, clay, and sorted fine sand. Density values of 2.12-2.25 g/cc and porosity values of 30-35 percent are typical. 2) Medium sand, moderately to poorly sorted. Geophysical logs show baselines of low variability with deflections that are related to clay beds and sequences of silt, clay, and sorted fine sand. Density values of 2.05-2.20 g/cc and porosity values of 30-35 percent are typical. 3) Clayey sandy silt, poorly sorted, locally microlaminated clay and silt, generally nonplastic. Geophysical logs show highly variable baselines with deflections that are related to sequences of clay and fine sand. Density values of 2.1-2.2 g/cc and porosity values of 30-40 percent are typical. 4) Silt and clay, characteristically red to reddish brown and medium to high plasticity, massive to indistinctly microlaminated. Geophysical logs show variable baselines with broad, high-amplitude compound spikes that are related to sequences of silt and fine sand. Density values of 2.12-2.25 g/cc and porosity values of >45 percent are typical. 5) Sand and gravel, poorly sorted. Geophysical logs show variable baselines with deflections that are related to sequences of silty and sorted fine sand. 6) Sandstone, fine-to-medium grained, poorly sorted, cemented chiefly by calcite, which fills the original pore space. Geophysical logs show density values >2.25 g/cc and porosity values <30 percent. The 22 lithologic units are correlated with recognized basin-floor fluvial lithofacies (Hawley, 1996), which include sand and gravel (lithofacies I), sand with lenses of pebbly sand, silt, and silty clay (lithofacies II), and interbedded sand, silt, and silty clay (modified lithofacies III, IV, IX). The sediments in the core hole are correlated with three informal lithostratigraphic units. The top unit, 0-19 ft (0-5.8 m) depth, consists of Quaternary eolian sand and valley-border alluvium. Coarsegrained deposits in the 19-97 ft (5.8-29.6 m) interval are correlated with the upper unit of the Santa Fe Group. The fine-grained section in the 97-787 ft (29.6-239.9 m) interval is correlated tentatively with the middle unit of the Santa Fe Group. This section contains thick sequences of laminated red and olivebrown clay and silt overbank deposits (441-787 ft) in the distinctive Atrisco member of Connell and others (1998). The Atrisco is correlated with fine-grained zones in numerous wells throughout the central Albuquerque metropolitan area, and is recognized as a zone that separates the upper Santa Fe aquifer from underlying middle Santa Fe deposits. The lower section of the middle unit of the Santa Fe, 787-1500 ft (239.9-457.2 m) depth, includes an upper sequence of moderately sorted channel-fill medium sand, and a lower sequence of sand, silt, and clay overbank deposits. The age of the cored interval is not known precisely. The upper Santa Fe gravel is related regionally to a through-flowing river system that was established in the Rio Grande rift valleys in Early Pliocene time, >4.5 MA. The middle Santa Fe unit is dated tentatively by correlation with a fossiliferous section, in which sandy beds that directly underlie the upper Santa Fe are Late Miocene (Hemphellian), 4.6- 8.9 MA. Further, the middle Santa Fe unit, with dominantly normal magnetic polarity, may have been deposited during closely spaced normal magnetic chrons 5.9-8.3 Ma. Four hydrostratigraphic units summarize the hydrogeologic framework for the 98th Street site: 1) Quaternary valley-border deposits, 2) upper Santa Fe sand and gravel deposits, 3) middle Santa Fe overbank deposits, and 4) middle Santa Fe channel-sand deposits. Empirical values of horizontal hydraulic conductivity estimated from core samples reveal a previously unknown contrast in hydraulic conductivity in the lowest two hydrostratigraphic units. Correlations among numerous wells show that the distinctively fine-grained Atrisco member, with estimated hydraulic conductivities (K) of <0.02-17 ft/day, is a laterally extensive barrier to vertical ground-water flow. The underlying unit that contains moderately sorted medium sand is a potential aquifer production zone that should be investigated further. Laboratory determination of vertical hydraulic conductivity values for fine-grained core samples range from 10 -2 to 10 -7 ft/day; recompacted sandy samples have K values of 1 to 10 -2 ft/day. Results of tests conducted with increasing effective stress show that K values of all samples decrease with decreasing porosity. Comparison of K values from laboratory, empirical, and calculated geophysical values shows discrepancies of 1-3 orders of magnitude (ft/day), indicating that additional analyses of core samples and geophysical data are necessary for future characterization of the Santa Fe Group aquifer.

New Mexico↗

The life cycle of a mineral deposit: a teacher's guide for hands-on mineral education activities

This teacher's guide defines what a mineral deposit is and how a mineral deposit is identified and measured, how the mineral resources are extracted, and how the mining site is reclaimed; how minerals and mineral resources are processed; and how we use mineral resources in our every day lives. Included are 10 activitybased learning exercises that educate students on basic geologic concepts; the processes of finding, identifying, and extracting the resources from a mineral deposit; and the uses of minerals. The guide is intended for K through 12 Earth science teachers and students and is designed to meet the National Science Content Standards as defined by the National Research Council (1996). To assist in the understanding of some of the geology and mineral terms, see the Glossary (appendix 1) and Minerals and Their Uses (appendix 2). The process of finding or exploring for a mineral deposit, extracting or mining the resource, recovering the resource, also known as beneficiation, and reclaiming the land mined can be described as the “life cycle” of a mineral deposit. The complete process is time consuming and expensive, requiring the use of modern technology and equipment, and may take many years to complete. Sometimes one entity or company completes the entire process from discovery to reclamation, but often it requires multiple groups with specialized experience working together. Mineral deposits are the source of many important commodities, such as copper and gold, used by our society, but it is important to realize that mineral deposits are a nonrenewable resource. Once mined, they are exhausted, and another source must be found. New mineral deposits are being continuously created by the Earth but may take millions of years to form. Mineral deposits differ from renewable resources, such as agricultural and timber products, which may be replenished within a few months to several years.

General Information Product↗

The Hydrogeology of the San Juan Mountains Chapter 5

Knowledge of the occurrence, storage, and flow of groundwater in mountainous regions is limited by the lack of integrated data from wells, streams, springs, and climate. In his comprehensive treatment of the hydrogeology of the San Luis Valley, Huntley (1979) hypothesized that the underlying, fractured volcanic bedrock of the San Juan Mountains has relatively high bulk permeability and a regional-scale water table with a low hydraulic gradient. Other (some more recent) studies of fractured crystalline bedrock in mountainous terrain indicate that these rock units can act as aquifers (Kahn et al. 2008; Manning and Caine 2007; Robinson 1978; Stober and Bucher 2005). The body of recent work also suggests that the conception that fractured crystalline bedrock is of such low permeability that it constitutes a “no-flow zone” may be inappropriate. In addition to establishing a new baseline, the data presented here are used to test Huntley’s (1979) hypotheses that suggest that the San Juan Mountains may be underlain by a substantial groundwater system. With the advent of computers and digital databases, many types of publicly available data can be used to test hypotheses and provide new insights into mountain hydrogeology at the regional scale in the San Juan Mountains. Plate 16 illustrates processes that suggest several fundamental questions arising from our lack of knowledge of mountain hydrogeology. These questions include: What are the dynamic interrelationships among the tectonics of mountain building, climate, and groundwater, and what are the time scales over which associated processes operate? How does extreme topographic relief allow for groundwater recharge along steep surfaces rather than simply causing precipitation to run off ? How does extreme relief translate into hydraulic gradients that drive groundwater flow? Can extreme gradients drive large volumes of meteoric water deep into the Earth’s upper crust? Once in the subsurface, what are the residence times of these waters? Finally, how does complex geology, commonly associated with mountainous terrain, influence these processes and control potentially heterogeneous and tortuous flow pathways? This chapter presents a synthesis of hydrogeological data, in a reconnaissance style, at the regional scale for the San Juan Mountains. Analyses of these data shed some light on the questions posed earlier for the San Juan Mountains and on mountain hydrogeologic processes in general. These analyses are based on public digital data from geologic and topographic maps, precipitation networks, stream gauges, groundwater wells, and springs. These data can be integrated using the hydrologic cycle expressed as a mass balance between inputs and outputs. The data types noted earlier form the basic set of measurements used to explore, characterize, and quantify elements of the hydrologic cycle. This exploration at a variety of scales yields insight into the relationships among the physical geological framework, climatological and hydrological budgets, and the hydraulic properties of the major aquifers in the San Juan Mountains. Each of these factors has been broken down and investigated separately and then integrated at the end of the chapter, using a conceptual model. Although the San Juan Mountains contain extensive precious- and base-metal deposits that have led to natural and mining-related groundwater contamination, this topic is not addressed here. Interested readers should refer to the extensive body of US Geological Survey work in Gray et al. (1994), Plumlee et al. (1995), Wirt et al. (1999), Johnson and Yager (2006), Johnson et al. (2007), and Church, von Guerard, and Finger (2007). Huntley (1979) also provided a large database for regional hydro-geochemistry of the San Juan Mountains (SJM).

Colorado↗

Metallogeny of the Great Basin: Crustal evolution, fluid flow, and ore deposits

The Great Basin physiographic province in the Western United States contains a diverse assortment of world-class ore deposits. It currently (2006) is the world’s second leading producer of gold, contains large silver and base metal (Cu, Zn, Pb, Mo, W) deposits, a variety of other important metallic (Fe, Ni, Be, REE’s, Hg, PGE) and industrial mineral (diatomite, barite, perlite, kaolinite, gallium) resources, as well as petroleum and geothermal energy resources. Ore deposits are most numerous and largest in size in linear mineral belts with complex geology. U.S. Geological Survey (USGS) scientists are in the final year of a research project initiated in the fall of 2001 to increase understanding of relations between crustal evolution, fluid flow, and ore deposits in the Great Basin. Because of its substantial past and current mineral production, this region has been the focus of numerous investigations over the past century and is the site of ongoing research by industry, academia, and state agencies. A variety of geoinformatic tools was used to organize, reinterpret, and display, in space and time, the large amounts of geologic, geophysical, geochemical, and hydrologic information deemed pertinent to this problem. This information, in combination with concentrated research on (1) critical aspects of the geologic history, (2) an area in northern Nevada that encompasses the major mineral belts, and (3) important mining districts and deposits, is producing new insights about the interplay between key tectonic events, hydrothermal fluid flow, and ore genesis in mineral belts. The results suggest that the Archean to Holocene history of the Great Basin was punctuated by several tectonic events that caused fluids of different origins (sea water, basinal brine, meteoric water, metamorphic water, magmatic water) to move through the crust. Basement faults reactivated during these events localized deformation, sedimentation, magmatism, and hydrothermal fluid flow in overlying rocks to form mineral belts that contain ore deposits of different types and ages that are locally superimposed (demonstrating inheritance). Fluid flow in these systems also was influenced by the distribution of permeable lithologies and paleotopographic highs and lows. Hydrothermal fluids evolved from their initial chemistries towards compositions that reflect the ƒ O 2 and ƒ S 2 buffering capacity of, and the ligands and metals present in, the rocks (±older mineralization) through which they moved. In northern Nevada, where gold deposits are relatively common, carbonaceous, pyritic strata buffered fluids of diverse origins to H 2 S-rich compositions so they could transport gold repeatedly over Paleozoic-Cenozoic time (convergent evolution). Ore formed where metal-laden fluids encountered effective physicochemical traps. Maps of Neogene basin fill and erosion surfaces identify areas where preexisting ore deposits have been progressively exposed or concealed. Comparisons with analogous terrains and deposit types in other parts of the world provide global context. The initial findings and some of the databases, geologic maps, sections, reconstructions, hydrogeologic models, topical syntheses, regional overviews, short courses, field guides, and deposit comparisons produced by project staff and associated managers, contractors, and collaborators have been presented in numerous abstracts, symposia, USGS publications, and professional journals over the last 5 years (see the extensive bibliography). Notable among these was the 2005 Geological Society of Nevada symposium in Reno, Nevada, and the 2005 Geological Society of America annual meeting in Salt Lake City, Utah, where project results were presented to audiences from around the nation and world. The final results of the project will be submitted for publication in 2007 to appropriate USGS and professional journals. A special issue of GEOSPHERE, scheduled for publication in 2007, will be devoted to the results of this project and related work. This special issue will reach an international audience and be available worldwide on the internet. Much of the research for this project has concentrated on areas that will receive the focused attention of the mining industry in the future. As such, the data and interpretations generated by this project have direct use for land-use managers in Federal, State, and local agencies. Improved hydrogeologic models developed by this project will considerably enhance ongoing and future water resource investigations in the region. The increased understanding of when, where, and how hydrothermal systems produce significant economic deposits has direct uses for mineral exploration and for future USGS mineral resource assessments in the Great Basin and other parts of the world.

Great Basin↗

Geologic insights and suggestions on mineral potential based on analyses of geophysical data for the southern Toquima Range, Nye County, Nevada

Aeromagnetic and gravity data provide confirmation of major structural and lithologic units in the southern Toquima Range, Nevada. These units include Cretaceous granite plutons and Tertiary calderas. In addition, the geophysical maps pinpoint numerous faults and lesser intrusions, and they suggest locations of several inferred subsurface intrusions. They also corroborate a system of northwesterly and northeasterly conjugate structures that probably are fundamental to the structural framework of the Toquima Range. A combination of geophysical, geochemical, and geologic data available for the widely mineralized and productive area suggests additional mineral resource potential, especially in and (or) adjacent to the Round Mountain, Jefferson, Manhattan, and Belmont mining districts. Also, evidence for mineral potential exists for areas near the Flower mercury mine south of Mount Jefferson caldera, and in the Bald Mountain Canyon belt of gold-quartz veins in the Manhattan caldera. A few other areas also show potential for mineral resources. The various geologic environments indicated within the map area suggest base- and precious-metal potential in porphyry deposits as well as in quartz-vein and skarn deposits associated with intrusive stocks.

Nevada↗

Simulation of rainfall-runoff response in mined and unmined watersheds in coal areas of West Virginia

Meteorologic and hydrologic data from five small watersheds in the coal areas of West Virginia were used to calibrate and test the U.S. Geological Survey Precipitation-Runoff Modeling System for simulating streamflow under various climatic and land-use conditions. Three of the basins--Horsecamp Run, Gilmer Run, and Collison Creek--are primarily forested and relatively undisturbed. The remaining basins--Drawdy Creek and Brier Creek-are extensively mined, both surface and underground above stream drainage level. Low-flow measurements at numerous synoptic sites in the mined basins indicate that coal mining has substantially altered the hydrologic system of each basin. The effects of mining on streamflow that were identified are (1) reduced base flow in stream segments underlain by underground mines, (2) increased base flow in streams that are downdip and stratigraphically below the elevation of the mined coal beds, and (3) interbasin transfer of ground water through underground mines. These changes probably reflect increased permeability of surface rocks caused by subsidence fractures associated with collapsed underground mines in the basin. Such fractures would increase downward percolation of precipitation, surface and subsurface flow, and ground-water flow to deeper rocks or to underground mine workings. Model simulations of the water budgets for the unmined basins during the 1972-73 water years indicate that total annual runoff averaged 60 percent of average annual precipitation; annual evapotranspiration losses averaged 40 percent of average annual precipitation. Of the total annual runoff, approximately 91 percent was surface and subsurface runoff and 9 percent was groundwater discharge. Changes in storage in the soil zone and in the subsurface and ground-water reservoirs in the basins were negligible. In contrast, water-budget simulations for the mined basins indicate significant differences in annual recharge and in total annual runoff. Model simulations of the water budget for Drawdy Creek basin indicate that total annual runoff during 1972-73 averaged only 43 percent of average annual precipitation--the lowest of all study basins; annual evapotranspiration losses averaged 49 percent, and interbasin transfer of ground-water losses averaged about 8 percent. Of the total annual runoff, approximately 74 percent was surface and subsurface flow and 26 percent was ground-water discharge. The low total annual runoff at Drawdy Creek probably reflects increased recharge of precipitation and surface and subsurface flow losses to ground water. Most of the increase in ground-water storage is, in turn, lost to a ground-water sink--namely, interbasin transfer of ground water by gravity drainage and (or) mine pumpage from underground mines that extend to adjacent basins. Hypothetical mining situations were posed for model analysis to determine the effects of increased mining on streamflow in the mined basins. Results of model simulations indicate that streamflow characteristics, the water budget, and the seasonal distribution of streamflow would be significantly modified in response to an increase in mining in the basins. Simulations indicate that (1) total annual runoff in the basins would decrease because of increased surface- and subsurface-flow losses and increased recharge of precipitation to ground water (these losses would tend to reduce medium to high flows mainly during winter and spring when losses would be greatest), (2) extreme high flows in response to intense rainstorms would be negligibly affected, regardless of the magnitude of mining in the basins, (3) ground-water discharge also would decrease during winter and spring, but the amount and duration of low flows during summer and fall would substantially increase in response to increased ground-water storage in rocks and in underground mines, and (4) the increase in ground-water storage in the basins would be depleted, mostly by increased losses to a grou

Water Supply Paper↗

Digital Map of Surficial Geology, Wetlands, and Deepwater Habitats, Coeur d'Alene River Valley, Idaho

The Coeur d'Alene (CdA) River channel and its floodplain in north Idaho are mostly covered by metal-enriched sediments, partially derived from upstream mining, milling and smelting wastes. Relative to uncontaminated sediments of the region, metal-enriched sediments are highly enriched in silver, lead, zinc, arsenic, antimony and mercury, copper, cadmium, manganese, and iron. Widespread distribution of metal-enriched sediments has resulted from over a century of mining in the CdA mining district (upstream), poor mine-waste containment practices during the first 80 years of mining, and an ongoing series of over-bank floods. Previously deposited metal-enriched sediments continue to be eroded and transported down-valley and onto the floodplain during floods. The centerpiece of this report is a Digital Map Surficial Geology, Wetlands and Deepwater Habitats of the Coeur d'Alene (CdA) River valley (sheets 1 and 2). The map covers the river, its floodplain, and adjacent hills, from the confluence of the North and South Forks of the CdA River to its mouth and delta front on CdA Lake, 43 linear km (26 mi) to the southwest (river distance 58 km or 36 mi). Also included are the following derivative theme maps: 1. Wetland System Map; 2. Wetland Class Map; 3. Wetland Subclass Map; 4. Floodplain Map; 5. Water Regime Map; 6. Sediment-Type Map; 7. Redox Map; 8. pH Map; and 9. Agricultural Land Map. The CdA River is braided and has a cobble-gravel bottom from the confluence to Cataldo Flats, 8 linear km (5 mi) down-valley. Erosional remnants of up to four alluvial terraces are present locally, and all are within the floodplain, as defined by the area flooded in February of 1996. High-water (overflow) channels and partly filled channel scars braid across some alluvial terraces, toward down-valley marshes and (or) oxbow ponds, which drain back to the river. Near Cataldo Flats, the river gradient flattens, and the river coalesces into a single channel with a large friction-dominated central sand bar at Cataldo Landing. Metal-enriched sediments that were dredged from the central sand bar were deposited on Cataldo Flats, to form extensive dredge-spoil deposits. From the central sand bar to CdA Lake, thick deposits of metal-enriched sand partially fill the middle of the pre-mining-era channel along straight reaches, and form point-bars along the inside margins of meander bends. Metal-enriched sand and silt form oxidized bank-wedge deposits along riverside margins of pre-mining-era levees of gray silty mud. Metal-enriched levee sand deposits extend across bank wedges and natural levees, generally thinning and fining away from the river, toward lateral marshes and lakes, where dark gray metal-enriched silt and mud overlie silty peat, deposited before the mining era. Distributary streams and man-made canals locally diverge from the river, connecting it to lateral marshes and lakes, and metal-enriched sand splays locally fan out across the floodplain. At the mouth of the river, a bouyancy-dominated river-mouth bar crests beyond the ends of the emergent levees. Thick delta-front deposits of metal-enriched sand slope from the river-mouth bar to the bottom of CdA Lake.

Open-File Report↗

A review of lignite resources of western Tennessee and the Jackson Purchase area, western Kentucky

This review of the lignite deposits of western Tennessee and the Jackson Purchase area in western Kentucky (Figure 1) is an updated report on part of the U.S. Geological Survey's National Coal Resource Assessment of the Gulf Coastal Plain Coal Province (see Ruppert et al., 2002; Hackley et al., 2006; Dennen, 2009; and other chapters of this publication). Lignite deposits of western Kentucky and Tennessee are an extension of the Gulf Coastal Plain Coal Province (Cushing et al., 1964), and currently are not economic to mine. These deposits have not been extensively investigated or developed as an energy resource. This review includes a description of the geology of the lignite-bearing units, a discussion of the available coal quality data, and information on organic petrology. Palynological data for lignite samples collected in Kentucky and Tennessee as part of this work are presented in Table 1. Lignite trace element data originally presented in Hackley et al. (2006) are not included in this report due to potential laboratory quality control issues during the time the samples were analyzed (U.S. Geological Survey Energy Resources Program, 2010).

Kentucky, Tennessee↗

Preliminary analysis of cores from north San Francisco Bay, California

During the mid-to late-1800's, large quantities of tailings from hydraulic gold mining in the Sierra Nevada were deposited in San Francisco Bay (Gilbert, 1917; Jaffe et al., 1998; Capiella et al., 1999). This rapid deposition also choked river systems and deposited mercury-contaminated sediments in the rivers and Bay. Hydraulic mining was stopped in 1884 by a California Supreme Court decision. Deposition in the Bay slowed in the late 1800's and early 1900's as a result of this decrease in sediment supply (Jaffe et al., 1998; Capiella et al., 1999). During the mid-1900's, sediment supply was further reduced by water works projects (dams, diversions, etc.), creating an erosional system in the study area by the late 1900's. The re-working of these sediments poses environmental and biological concerns regarding mercury in the bay. The location of these deposits is important for understanding the health of the bay waters. In March 2000, the U.S. Geological Survey collected sediment cores in the study area to determine the location of mercury-contaminated hydraulic mining debris. The study area (Figure 1) comprises 400 km2 and consists of San Pablo Bay and Suisun Bay, both of which are part of the San Francisco Bay estuary. Grizzly Bay, a subembayment of Suisun Bay, is also part of the study area. For the purpose of this report the term Suisun Bay will be used collectively for both areas. The present channel system in Suisun Bay is composed of three channels that flow through the bay. The primary channel runs in the southern section of Suisun Bay. A smaller channel flows between Roe Island and Ryer Island. The deepest channel flows through Suisun Cutoff, north of Ryer Island, and past Grizzly Bay. All three channels join at Carquinez Strait where they continue through the southern section of San Pablo Bay, and into San Francisco Bay. The average depths in San Pablo and Suisun Bays at mean sea level are 3.7 m and 5.8 m, respectively (Smith et al., 2002).

California↗

Stratigraphic section and selected semiquantitative chemistry, Meade Peak phosphatic shale member of Permian Phosphoria Formation, central part of Rasmussen Ridge, Caribou County, Idaho

The U.S. Geological Survey (USGS) has studied the Permian Phosphoria Formation in southeastern Idaho and the entire Western U.S. Phosphate Field throughout much of the twentieth century. In response to a request by the U.S. Bureau of Land Management, a new series of resource, geological, and geoenvironmental studies was undertaken by the USGS in 1998. To accomplish these studies, the USGS has formed cooperative research relationships with two Federal agencies, the Bureau of Land Management and the U.S. Forest Service, tasked with land management and resource conservation on public lands; and with five private companies currently leasing or developing phosphate resources in southeastern Idaho. The companies are Agrium U.S. Inc. (Rasmussen Ridge mine) , Astaris LLC (Dry Valley mine), Rhodia Inc. (Wooley Valley mine, inactive), J.R. Simplot Company (Smoky Canyon mine), and Monsanto Co. (Enoch Valley mine). Some of the mineralogical research associated with this project is supported through a cooperative agreement with the Department of Geology and Geological Enginee ring, University of Idaho. Present studies consist of integrated, multidisciplinary research directed toward (1) resource and reserve estimations of phosphate in selected 7.5-minute quadrangles; (2) elemental residence, mineralogical and petrochemical characteristics; (3) mobilization and reaction pathways, transport, and fate of potentially toxic elements associated with the occurrence, development, and societal use of phosphate; (4) geophysical signatures; and (5) improving the understanding of deposit origin. Because raw data acquired during the project will require time to interpret, the data are released in open-file reports for prompt availability to other workers. Open-file reports associated with this series of studies are submitted to each of the Federal and industry cooperators for comment; however, the USGS is solely responsible for the data contained in the reports.

Idaho↗

Geochemical Results of Lysimeter Sampling at the Manning Canyon Repository in the Mercur Mining District, Utah

This report presents chemical characteristics of transient unsaturated-zone water collected by lysimeter from the Manning Canyon repository site in Utah. Data collected by U.S. Geological Survey and U.S. Department of the Interior, Bureau of Land Management scientists under an intragovernmental order comprise the existing body of hydrochemical information on unsaturated-zone conditions at the site and represent the first effort to characterize the chemistry of the soil pore water surrounding the repository. Analyzed samples showed elevated levels of arsenic, barium, chromium, and strontium, which are typical of acidic mine drainage. The range of major-ion concentrations generally showed expected soil values. Although subsequent sampling is necessary to determine long-term effects of the repository, current results provide initial data concerning reactive processes of precipitation on the mine tailings and waste rock stored at the site and provide information on the effectiveness of reclamation operations at the Manning Canyon repository.

Data Series↗

Surface-water quality and suspended-sediment quantity and quality within the Big River Basin, southeastern Missouri, 2011-13

Missouri was the leading producer of lead in the United States&mdash;as well as the world&mdash;for more than a century. One of the lead sources is known as the Old Lead Belt, located in southeast Missouri. The primary ore mineral in the region is galena, which can be found both in surface deposits and underground as deep as 200 feet. More than 8.5 million tons of lead were produced from the Old Lead Belt before operations ceased in 1972. Although active lead mining has ended, the effects of mining activities still remain in the form of large mine waste piles on the landscape typically near tributaries and the main stem of the Big River, which drains the Old Lead Belt. Six large mine waste piles encompassing more than 2,800 acres, exist within the Big River Basin. These six mine waste piles have been an available source of trace element-rich suspended sediments transported by natural erosional processes downstream into the Big River. A study was performed by the U.S. Geological Survey in cooperation with U.S. Environmental Protection Agency, Region 7, to calculate and characterize suspended-sediment quantity and quality within the Big River basin after reclamation of the mine waste piles ended in 2012. Streamflow and suspended sediments were quantified and sampled at two locations along a 68-mile reach of the Big River between Bonne Terre and Byrnes Mill, Missouri. The results will help regulatory agencies, such as the U.S. Environmental Protection Agency and U.S. Fish and Wildlife Service, determine impaired reaches and ecosystems for remedial and restoration efforts. Continuous stream stage, water temperature, and turbidity, and discrete suspended-sediment concentration data were collected at the two sites between October 2011 and September 2013. Suspended-sediment samples were collected during various hydrologic conditions to develop a regression model between discrete suspended-sediment concentration and continuous turbidity. Suspended sediments collected during stormflow events were analyzed for concentrations of trace elements such as barium, cadmium, lead, and zinc within two sediment size fractions. Event loads and annual loads of suspended sediment and select trace elements in suspended sediments also were calculated. Suspended-sediment loads computed by the regression model increased downstream from about 201,000 tons at the upstream site to about 355,000 tons at the downstream site during the study period. Stormflow-event-based (hereinafter referred to as &ldquo;event-based&rdquo;) suspended-sediment loads ranged from 180 to 32,000 tons at the upstream sampling site and 390 to 53,000 tons at the downstream site along the Big River. Although only seven stormflow events at the upstream site and six at the downstream site were sampled, the event-based suspended-sediment loads accounted for nearly 30 percent of the total suspended-sediment loads computed at both sites, indicating most of the suspended sediment transported through the Big River occurs during higher streamflows. Sediment quality guidelines, known as the threshold effect concentration and the probable effect concentration, used to assess toxicity of trace-element concentrations in sediments were compared to the cadmium, lead, and zinc concentrations in suspended sediment samples collected during stormflow events. All concentrations of cadmium, lead, and zinc in event-based suspended sediment samples exceeded the threshold and probable effect concentrations. Lead and zinc concentrations in the sediment size fraction less than 0.063 millimeters also exceeded the toxic effect threshold, above which sediment is considered to be heavily polluted causing adverse effects on sediment-dwelling organisms. Concentrations of cadmium and zinc in event-based suspended sediment samples were notably higher in samples from the upstream site than samples from the downstream site, indicating the sources of sediments enriched in these trace elements decrease in the downstream area of the watershed. The reduction in concentration of cadmium and zinc could be from dissolution of the constituents during transport or possibly a decrease in downstream source material. The lead concentration exceedance of the probable effects concentration as well as the threshold effects concentration indicates that lead-rich suspended sediments in the fraction less than 0.063 millimeters are readily available within the Big River Basin for transport. These sediments remain in the system from historical mining, and as the reclamation of mine waste piles in the upstream area of the watershed reduce additional sediment loadings, these fine sediments may be continually released as the river scours the streambed and erodes stream banks causing the lead-rich suspended sediment to remain in a state of equilibrium. Barium concentrations in suspended-sediments were nearly twice as high in stormflow event samples collected at the downstream site as compared to samples from the upstream site. The source of barium in the Big River could be from Mineral Fork and Mill Creek, which flow through the historical barite (barium sulfate, also known as tiff) mining district in Washington County, and discharge into the Big River between the two study sites. Total trace-element loads and yields in suspended sediments were computed from the sampled events for each year in the study. The total barium loads in suspended sediments were higher for sampled events collected at the downstream site than the upstream site during both study years. Cadmium and zinc loads in suspended sediments were lower at the downstream site than the upstream site, although the decrease in total load was not substantial during the study period. Lead loads in suspended sediments were lower at the downstream site during the first study year, with a slightly higher load downstream in the second year though the increase from upstream to downstream was small. Event-based yields were higher at the upstream site, indicating that readily available sediment sources are closer to the upstream site where more mining affected areas are located. The estimates determined during large precipitation events indicate that large sources of suspended sediments with large concentrations of trace elements are still available for transport within the Big River.

Missouri↗

Hydrology and ground-water quality in the mine workings within the Picher Mining District, Northeastern Oklahoma, 2002-03

The Picher mining district of northeastern Ottawa County, Oklahoma, was a major site of mining for lead and zinc ores in the first half of the 20th century. The primary source of lead and zinc were sulfide minerals disseminated in the cherty limestones and dolomites of the Boone Formation of Mississippian age, which comprises the Boone aquifer. Ground water in the aquifer and seeping to surface water in the district has been contaminated by sulfate, iron, lead, zinc, and several other metals. The U.S. Geological Survey, in cooperation with the Oklahoma Department of Environmental Quality, investigated hydrology and ground-water quality in the mine workings in the mining district, as part of the process to aid water managers and planners in designing remediation measures that may restore the environmental quality of the district to pre-mining conditions. Most ground-water levels underlying the mining district had similar altitudes, indicating a large degree of hydraulic connection in the mine workings and overlying aquifer materials. Recharge-age dates derived from concentrations of chlorofluorocarbons and other dissolved gases indicated that water in the Boone aquifer may flow slowly from the northeast and southeast portions of the mining district. However, recharge-age dates may have been affected by the types of sites sampled, with more recent recharge-age dates being associated with mine-shafts, which are more prone to atmospheric interactions and surface runoff than the sampled airshafts. Water levels in streams upstream from the confluence of Tar and Lytle Creeks were several feet higher than those in adjacent portions of the Boone aquifer, perhaps due to low-permeability streambed sediments and indicating the streams may be losing water to the aquifer in this area. From just upstream to downstream from the confluence of Tar and Lytle Creeks, surface-water elevations in these streams were less than those in the surrounding Boone aquifer, indicating that seepage from the aquifer to downstream portions of Tar Creek was much more likely. Water properties and major-ion concentrations indicate that water in the mining area was very hard, with large concentrations of dissolved solids that increased from areas of presumed recharge toward areas with older ground water. Most of the ground-water samples, particularly those from the airshafts, had dissolved-oxygen concentrations less than 1.0 milligram per liter. Small concentrations of dissolved oxygen may have been introduced during the sampling process. The small dissolved-oxygen concentrations were associated with samples containing large iron concentrations that indicates possible anoxic conditions in much of the aquifer. Ground water in the mining district was dominated by calcium, magnesium, and sulfate. Sodium concentrations tended to increase relative to calcium and magnesium concentrations. Ground-water samples collected in 2002-03 had large concentrations of many trace elements. Larger concentrations of metals and sulfate occurred in ground water with smaller pHs and dissolved-oxygen concentrations. Iron was the metal with the largest concentrations in the ground-water samples, occurring at concentrations up to 115,000 micrograms per liter. Cadmium, lead, manganese, zinc, and the other analyzed metals occurred in smaller concentrations in ground water than iron. However, larger cadmium concentrations appeared to be associated with sites that have small iron concentrations and more oxygenated waters. This is noteworthy because the small sulfate and iron concentrations in these waters could lead to conclusions that the waters are less contaminated than waters with large sulfate and iron concentrations. Ground-water quality in the mining district was compared with subsets of samples collected in 1983-85 and in 2002.

Oklahoma↗

Geologic occurrences of erionite in the United States: an emerging national public health concern for respiratory disease

Erionite, a mineral series within the zeolite group, is classified as a Group 1 known respiratory carcinogen. This designation resulted from extremely high incidences of mesothelioma discovered in three small villages from the Cappadocia region of Turkey, where the disease was linked to environmental exposures to fibrous forms of erionite. Natural deposits of erionite, including fibrous forms, have been identified in the past in the western United States. Until recently, these occurrences have generally been overlooked as a potential hazard. In the last several years, concerns have emerged regarding the potential for environmental and occupational exposures to erionite in the United States, such as erionite-bearing gravels in western North Dakota mined and used to surface unpaved roads. As a result, there has been much interest in identifying locations and geologic environments across the United States where erionite occurs naturally. A 1996 U.S. Geological Survey report describing erionite occurrences in the United States has been widely cited as a compilation of all US erionite deposits; however, this compilation only focused on one of several geologic environments in which erionite can form. Also, new occurrences of erionite have been identified in recent years. Using a detailed literature survey, this paper updates and expands the erionite occurrences database, provided in a supplemental file (US_erionite.xls). Epidemiology, public health, and natural hazard studies can incorporate this information on known erionite occurrences and their characteristics. By recognizing that only specific geologic settings and formations are hosts to erionite, this knowledge can be used in developing management plans designed to protect the public.

Arizona;California;Colorado;Idaho;Montana;New Mexi↗

Time-lapse analysis of methane quantity in Mary Lee group of coal seams using filter-based multiple-point geostatistical simulation

Coal seam degasification and its success are important for controlling methane, and thus for the health and safety of coal miners. During the course of degasification, properties of coal seams change. Thus, the changes in coal reservoir conditions and in-place gas content as well as methane emission potential into mines should be evaluated by examining time-dependent changes and the presence of major heterogeneities and geological discontinuities in the field. In this work, time-lapsed reservoir and fluid storage properties of the New Castle coal seam, Mary Lee/Blue Creek seam, and Jagger seam of Black Warrior Basin, Alabama, were determined from gas and water production history matching and production forecasting of vertical degasification wellbores. These properties were combined with isotherm and other important data to compute gas-in-place (GIP) and its change with time at borehole locations. Time-lapsed training images (TIs) of GIP and GIP difference corresponding to each coal and date were generated by using these point-wise data and Voronoi decomposition on the TI grid, which included faults as discontinuities for expansion of Voronoi regions. Filter-based multiple-point geostatistical simulations, which were preferred in this study due to anisotropies and discontinuities in the area, were used to predict time-lapsed GIP distributions within the study area. Performed simulations were used for mapping spatial time-lapsed methane quantities as well as their uncertainties within the study area. The systematic approach presented in this paper is the first time in literature that history matching, TIs of GIPs and filter simulations are used for degasification performance evaluation and for assessing GIP for mining safety. Results from this study showed that using production history matching of coalbed methane wells to determine time-lapsed reservoir data could be used to compute spatial GIP and representative GIP TIs generated through Voronoi decomposition. Furthermore, performing filter simulations using point-wise data and TIs could be used to predict methane quantity in coal seams subjected to degasification. During the course of the study, it was shown that the material balance of gas produced by wellbores and the GIP reductions in coal seams predicted using filter simulations compared very well, showing the success of filter simulations for continuous variables in this case study. Quantitative results from filter simulations of GIP within the studied area briefly showed that GIP was reduced from an initial ∼73 Bcf (median) to ∼46 Bcf (2011), representing a 37 % decrease and varying spatially through degasification. It is forecasted that there will be an additional ∼2 Bcf reduction in methane quantity between 2011 and 2015. This study and presented results showed that the applied methodology and utilized techniques can be used to map GIP and its change within coal seams after degasification, which can further be used for ventilation design for methane control in coal mines.

Alabama↗

Descriptive and geoenvironmental model for Co-Cu-Au deposits in metasedimentary rocks

Introduction This report is a revised model for a specific type of cobalt-copper-gold (Co-Cu-Au) deposit that will be evaluated in the next U.S. Geological Survey (USGS) assessment of undiscovered mineral resources in the United States (see Ferrero and others, 2012). Emphasis is on providing an up-to-date deposit model that includes both geologic and geoenvironmental aspects. The new model presented here supersedes previous USGS models by Earhart (1986) and Evans and others (1995), which are based solely on deposits in the Blackbird mining district of central Idaho. This report is a broader synthesis of information on 19 Co-Cu-Au deposits occurring in predominantly metasedimentary successions worldwide (table 1–1) that generally share common geologic, mineralogical, and geochemical features; preliminary summary versions were presented in Slack and others (2010) and Slack and others (2011), which are superseded by this report. As defined herein, the individual Co-Cu-Au deposits are located more than 500 meters from similar deposits and contain 0.1 percent or more by weight of Co in ore or mineralized rock; some deposits included in the database lack reported average Co grades, but they contain high Co concentrations, at least locally. Most of the deposits also have high As contents, present in Co arsenide and sulfarsenide minerals. Type examples of the Co-Cu-Au deposits are those in the Blackbird district, Skuterud in Norway, and Kouvervarra and Juomasuo in Finland. Some deposits in the database have low grades for Cu (for example, NICO in Canada) or Au (for example, Lemmonlampi in Finland), but these deposits are included because their geological, mineralogical, and alteration features are similar to those of the type examples. Several deposits included in the model are partly hosted by metavolcanic or metaigneous rocks (including granite), but regionally these deposits are within metasedimentary successions; no deposits are wholly within granite or other plutonic igneous intrusions. Despite having a lower average Co grade, the Mt. Cobalt deposit in Australia is included here because it has past Co production from higher-grade ore zones (Nisbet and others, 1983). The Black Pine deposit in the Idaho cobalt belt is included because it contains mineable Co- and Au-rich lenses within Cu-rich mineralized zones (Formation Metals, Inc., 2012). Six deposits that lack data for average Co grades are also included because each reportedly contains abundant Co (>0.1 weight percent Co), at least locally. Many of the deposits are noteworthy as possible resources of Ag, Bi, W, Ni, Y, REE, and (or) U. Detailed data on the deposits listed in table 1–1, including references, are available in appendix 1. Significantly, the grouping in this report of Co-Cu-Au deposits in metasedimentary rocks into a single model includes deposits that other workers have previously classified in different ways. For background information, a global overview of different types of Co deposits worldwide is given in Smith (2001). Additional geologically and compositionally similar deposits are known, but have average Co grades less than 0.1 percent. Most of these deposits contain cobalt-rich pyrite and lack appreciable amounts of distinct Co sulfide and (or) sulfarsenide minerals. Such deposits are not discussed in detail in the following sections, but these deposits may be relevant to the descriptive and genetic models presented below. Examples include the Scadding Au-Co-Cu deposit in Ontario, Canada; the Vähäjoki Co-Cu-Au deposit in Finland; the Tuolugou Co-Au deposit in Qinghai Province, China; the Lala Co-Cu-UREE deposit in Sichuan Province, China; the Guelb Moghrein Cu-Au-Co deposit in Mauritania; and the Great Australia Co-Cu, Greenmount Cu-Au-Co, and Monakoff Cu-Au-Co-UAg deposits in Queensland, Australia. Detailed information on these deposits is presented in appendix 2.

Scientific Investigations Report↗

Environmental assessment of water, sediment, and biota collected from the Bear Creek watershed, Colusa County, California

The Cache Creek watershed lies within California's North Coast Range, an area with abundant geologic sources of mercury (Hg) and a long history of Hg contamination (Rytuba, 2000). Bear Creek, Cache Creek, and the North Fork of Cache Creek are the major streams of the Cache Creek watershed, encompassing 2978 km 2 . The Cache Creek watershed contains soils naturally enriched in Hg as well as natural springs (both hot and cold) with varying levels of aqueous Hg (Domagalski and others, 2004, Suchanek and others, 2004, Holloway and others 2009). All three tributaries are known to be significant sources of anthropogenically derived Hg from historic mines, both Hg and gold (Au), and associated ore storage/processing sites and facilities (Slotton and others, 1995, 2004; CVRWQCB, 2003; Schwarzbach and others, 2001; Gassel and others, 2005; Suchanek and others., 2004, 2008a, 2009). Historically, two of the primary sources of mercury contamination in the upper part of Bear Creek have been the Rathburn and Petray Hg Mines. The Rathburn Hg mine was discovered and initially mined in the early 1890s. The Rathburn and the more recently developed Petray open pit mines are localized along fault zones in serpentinite that has been altered and cut by quartz and chalcedony veins. Cold saline-carbonate springs are located perepheral to the Hg deposits and effluent from the springs locally has high concentrations of Hg (Slowey and Rytuba, 2008). Several ephemeral tributaries to Bear Creek drain the mine area which is located on federal land managed by the U.S. Bureau of Land Management (USBLM). The USBLM requested that the U.S. Geological Survey (USGS) measure and characterize Hg and other geochemical constituents in sediment, water, and biota to establish baseline information prior to remediation of the Rathburn and Petray mines. Samples sites were established in Bear Creek upstream and downstream from the mine area. This report is made in response to the USBLM request, the lead agency mandated to conduct a Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) - Removal Site Investigation (RSI). The RSI applies to the possible removal of Hg-contaminated mine waste from Bear Creek. This report summarizes data obtained from field sampling of water, sediment, and biota in Bear Creek, above input from the mine area and downstream from the Rathburn-Petray mine area to the confluence with Cache Creek. Our results permit a preliminary assessment of the chemical constituents that could elevate levels of monomethyl Hg (MMeHg) in Bear Creek and its uptake by biota and provide baseline information for comparison to conditions after mine remediation is completed.

California↗