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At least 955 records · Page 53Linked to original sources
USGS2012

The use of MAGSAT data to determine secular variation

A combined spatial and secular variation model of the geomagnetic field, labeled M061581, is derived from a selection of Magsat data. Secular variation (SV) data computed from linear fits to midnight hourly values from 19 magnetic observatories were also included in the analysis but were seen to have little effect on the model. The SV patterns from this new model are compared with those from the 1980 IGRF and with those for 1970 computed by the DGRF and with the 1960 patterns computed using the GSFC(12/66) model. Most of the features of the M061581 are identical in location and level with those of the 1980 IGRF. Together they confirm that the reversals in sign of field change seen over Asia and North America between 1965 and 1975 are reverting to the pre-1965 states. The M061581 model gives −32 nT/yr for the dipole decay rate, larger than the 70% increase already reported since 1965. This abnormally high value is interpreted as being a defect of the model because it appears to result from a much larger (−100 nT/yr) drop in field over the polar regions not indicated by the 1980 IGRF. This north polar decrease is shown to be of external origin as the result of a combination of the seasonal effect of the north polar ionospheric (counterclockwise) afternoon Sq p cell increasing in intensity from the beginning (November 1979) to the end (June 1980) of the Magsat data collection period, coupled with an enhancement of its effect as the orbit lowered from the 350– 550 km initial altitudes to near 200 km just prior to burnup. This experiment indicates that secular variation can be obtained from satellite data for intervals of less than a full year if corrections can be made for seasonal effects and that ‘annual snapshots’ of the field by a satellite would allow easy and accurate models of secular change without the use of any surface data.

Journal of Geophysical Research Solid Earth↗
USGS1999

The idea of magma mixing: History of a struggle for acceptance

In 1851, chemist Robert Bunsen suggested that the mixing of two magmas, one mafic and the other felsic, in various proportions might account for the wide range of chemical compositions of igneous rocks. Based on flaws in several of its secondary provisions, the whole hypothesis was rejected by a succession of influential critics and remained in disrepute for a hundred years. Meanwhile, studies of composite dikes and sills indicated that, indeed, mafic and felsic magmas had coexisted at close quarters and had been emplaced in quick succession. This interpretation was also used by some investigators to explain the intimate association of mafic and felsic rock types in the commonly occurring igneous complexes. Others believed that the mafic components of these complexes were derived from geologically older mafic formations. By the early 1900s it had become apparent that mafic magmas crystallized at higher temperatures than felsic magmas. This knowledge was not immediately applied to the problem of magma mixing, however, due in part to the popularity of the newly validated process of fractional crystallization and to the implication that the diversity of igneous rocks could be accounted for by that process alone. Not until the 1950s was the attention of the geological community drawn to the fact that disparate magmas mix in a special manner: they mingle, the mafic magma being quenched to a fracturable solid upon contact with the cooler felsic magma. This explanation set in motion a series of studies of other igneous complexes, confirming the concept and adding other identifying features of the process.

Journal of Geology↗
USGS1989

Characterization of coal-derived hydrocarbons and source-rock potential of coal beds, San Juan Basin, New Mexico and Colorado, U.S.A.

Coal beds are considered to be a major source of nonassociated gas in the Rocky Mountain basins of the United States. In the San Juan basin of northwestern New Mexico and southwestern Colorado, significant quantities of natural gas are being produced from coal beds of the Upper Cretaceous Fruitland Formation and from adjacent sandstone reservoirs. Analysis of gas samples from the various gas-producing intervals provided a means of determining their origin and of evaluating coal beds as source rocks. The rank of coal beds in the Fruitland Formation in the central part of the San Juan basin, where major gas production occurs, increases to the northeast and ranges from high-volatile B bituminous coal to medium-volatile bituminous coal ( R m values range from 0.70 to 1.45%). On the basis of chemical, isotopic and coal-rank data, the gases are interpreted to be thermogenic. Gases from the coal beds show little isotopic variation ( δ 13 C 1 values range −43.6 to −40.5 ppt), are chemically dry (C 1 /C 1–5 values are > 0.99), and contain significant amounts of CO 2 (as much as 6%). These gases are interpreted to have resulted from devolatilization of the humic-type bituminous coal that is composed mainly of vitrinite. The primary products of this process are CH 4 , CO 2 and H 2 O. The coal-generated, methane-rich gas is usually contained in the coal beds of the Fruitland Formation, and has not been expelled and has not migrated into the adjacent sandstone reservoirs. In addition, the coal-bed reservoirs produce a distinctive bicarbonate-type connate water and have higher reservoir pressures than adjacent sandstones. The combination of these factors indicates that coal beds are a closed reservoir system created by the gases, waters, and associated pressures in the micropore coal structure. In contrast, gases produced from overlying sandstones in the Fruitland Formation and underlying Pictured Cliffs Sandstone have a wider range of isotopic values ( δ 13 C 1 values range from −43.5 to −38.5 ppt), are chemically wetter (C 1 /C 1–5 values range from 0.85 to 0.95), and contain less CO 2 (< 2%). These gases are interpreted to have been derived from type III kerogen dispersed in marine shales of the underlying Lewis Shale and nonmarine shales of the Fruitland Formation. In the underlying Upper Cretaceous Dakota Sandstone and Tocito Sandstone Lentil of the Mancos Shale, another gas type is produced. This gas is associated with oil at intermediate stages of thermal maturity and is isotopically lighter and chemically wetter at the intermediate stage of thermal maturity as compared with gases derived from dispersed type III kerogen and coal; this gas type is interpreted to have been generated from type II kerogen. Organic matter contained in coal beds and carbonaceous shales of the Fruitland Formation has hydrogen indexes from Rock-Eval pyrolysis between 100 and 350, and atomic H:C ratios between 0.8 and 1.2. Oxygen indexes and atomic O:C values are less than 24 and 0.3, respectively. Extractable hydrocarbon yields are as high as 7,000 ppm. These values indicate that the coal beds and carbonaceous shales have good potential for the generation of liquid hydrocarbons. Voids in the coal filled with a fluorescent material that is probably bitumen is evidence that liquid hydrocarbon generation has taken place. Preliminary oil-source rock correlations based on gas chromatography and stable carbon isotope ratios of C 15+ hydrocarbons indicate that the coals and (or) carbonaceous shales in the Fruitland Formation may be the source of minor amounts of condensate produced from the coal beds at relatively low levelsof thermal maturity ( R m =0.7).

International Journal of Coal Geology↗
USGS2006

Application of environmental tracers to mixing, evolution, and nitrate contamination of ground water in Jeju Island, Korea

Tritium/helium-3 ( 3 H/ 3 He) and chlorofluorocarbons (CFCs) were investigated as environmental tracers in ground water from Jeju Island (Republic of Korea), a basaltic volcanic island. Ground-water mixing was evaluated by comparing 3 H and CFC-12 concentrations with lumped-parameter dispersion models, which distinguished old water recharged before the 1950s with negligible 3 H and CFC-12 from younger water. Low 3 H levels in a considerable number of samples cannot be explained by the mixing models, and were interpreted as binary mixing of old and younger water; a process also identified in alkalinity and pH of ground water. The ground-water CFC-12 age is much older in water from wells completed in confined zones of the hydro-volcanic Seogwipo Formation in coastal areas than in water from the basaltic aquifer. Major cation concentrations are much higher in young water with high nitrate than those in uncontaminated old water. Chemical evolution of ground water resulting from silicate weathering in basaltic rocks reaches the zeolite–smectite phase boundary. The calcite saturation state of ground water increases with the CFC-12 apparent (piston flow) age. In agricultural areas, the temporal trend of nitrate concentration in ground water is consistent with the known history of chemical fertilizer use on the island, but increase of nitrate concentration in ground water is more abrupt after the late 1970s compared with the exponential growth of nitrogen inputs.

Jeju Island↗
USGS2012

Seismicity and detection/location threshold in the southern Great Basin seismic network

A spatially varying model of the detection/location capabilities of the Southern Great Basin seismic network (SGBSN) has been derived that is based on simple empirical relations and statistics. This permits use of almost all the catalog data gathered; instead of ignoring data that are below the threshold of completeness, a spatially varying threshold model is developed so that subregions having lower completeness levels than the network as a whole can be outlined and the completeness level of each sub-region determined. Such a model is required to unambiguously identify regions that are aseismic due to natural processes rather than to limited detection and/or location capabilities. Accounting for spatial variations in detection/location threshold is also important for studies in which magnitude-frequency distributions are interpreted in terms of source scaling properties. The characteristics of the spatial distribution of earthquakes, where earthquake clusters and aseismic regions locate, appear to be stable at all magnitude levels so that inferences about where strain is being accommodated will be the same whether numbers of earthquakes or strain estimated from seismic moments are examined. For the southern Great Basin region these principal characteristics include clusters at the northern end of the Furnace Creek fault and in the Pahranagat Shear Zone, and a relatively large number of earthquakes in the northern and southeastern portions of the Nevada Test Site. These clusters cover regions much larger than the surface projections of any of the mapped faults. The extent to which seismicity is induced by nuclear testing is unclear. The predominantly aseismic regions include the area west of the Death Valley/Furnace Creek fault system and an almost complete absence of events at Yucca Mountain. Finally, a considerable number of isolated events in the SGBSN catalog cannot be correlated with mapped faults.

Journal of Geophysical Research↗
USGS2014

Three-dimensional seismic velocity structure of Mauna Loa and Kilauea volcanoes in Hawaii from local seismic tomography

We present a new three-dimensional seismic velocity model of the crustal and upper mantle structure for Mauna Loa and Kilauea volcanoes in Hawaii. Our model is derived from the first-arrival times of the compressional and shear waves from about 53,000 events on and near the Island of Hawaii between 1992 and 2009 recorded by the Hawaiian Volcano Observatory stations. The V p model generally agrees with previous studies, showing high-velocity anomalies near the calderas and rift zones and low-velocity anomalies in the fault systems. The most significant difference from previous models is in V p / V s structure. The high- V p and high- V p / V s anomalies below Mauna Loa caldera are interpreted as mafic magmatic cumulates. The observed low- V p and high- V p / V s bodies in the Kaoiki seismic zone between 5 and 15 km depth are attributed to the underlying volcaniclastic sediments. The high- V p and moderate- to low- V p / V s anomalies beneath Kilauea caldera can be explained by a combination of different mafic compositions, likely to be olivine-rich gabbro and dunite. The systematically low- V p and low- V p / V s bodies in the southeast flank of Kilauea may be caused by the presence of volatiles. Another difference between this study and previous ones is the improved V p model resolution in deeper layers, owing to the inclusion of events with large epicentral distances. The new velocity model is used to relocate the seismicity of Mauna Loa and Kilauea for improved absolute locations and ultimately to develop a high-precision earthquake catalog using waveform cross-correlation data.

Hawaii↗
USGS2020

Using seasonal rainfall clusters to explain the interannual variability of the rain belt over the Greater Horn of Africa

The seasonal cycle of rainfall over the Greater Horn of Africa (GHA) is dominated by the latitudinal migration and activity of the tropical rain belt (TRB). The TRB exhibits high interannual variability in the GHA and the reasons for the recent dry period in the Long Rains (March–May) are poorly understood. In addition, few studies have addressed the rainfall fluctuations during the Msimu Rains (Dec.–Mar.) in the southern GHA region. Interannual variations of the seasonal cycle of the TRB between 1981 and 2018 were analysed using two statistical indices. The Rainfall Cluster Index (RCI) describes the seasonal cycle as a succession of six characteristic rainfall patterns, while the Seasonal Location Index (SLI) captures the latitudinal location of the TRB. The SLI and RCI depict the full seasonal cycle of the TRB supporting interpretations of the interannual variations and trends. The Msimu Rains are dominated by two clusters with opposite rainfall characteristics between the Congo Basin and Tanzania. The associated anomalies in moisture flux and divergence indicate variations in the location of the TRB originating from an interplay between low‐level air flows from the Atlantic and Indian Oceans and tropical and subtropical teleconnections. The peak period of the Long Rains shows a complex composition of five clusters, which is tightly connected to intraseasonal and interannual variability of latitudinal locations of the TRB. A persistent location of the TRB near the equator, evidenced in a frequent occurrence of a cluster related to an anomalously weak Walker circulation, is associated with wet conditions over East Africa. Dry Long Rains are associated with strong and frequent latitudinal variations of the TRB position with a late onset and intermittent rainfall. These results offer new opportunities to understand recent variability and trends in the GHA region.

International Journal of Climatology↗
USGS2009

Tracking magma volume recovery at Okmok Volcano using GPS and an unscented kalman filter

Changes beneath a volcano can be observed through position changes in a GPS network, but distinguishing the source of site motion is not always straightforward. The records of continuous GPS sites provide a favorable data set for tracking magma migration. Dense campaign observations usually provide a better spatial picture of the overall deformation field, at the expense of an episodic temporal record. Combining these observations provides the best of both worlds. A Kalman filter provides a means for integrating discrete and continuous measurements and for interpreting subtle signals. The unscented Kalman filter (UKF) is a nonlinear method for time‐dependent observations. We demonstrate the application of this technique to deformation data by applying it to GPS data collected at Okmok volcano. Seven years of GPS observations at Okmok are analyzed using a Mogi source model and the UKF. The deformation source at Okmok is relatively stable at 2.5 km depth below sea level, located beneath the center of the caldera, which means the surface deformation is caused by changes in the strength of the source. During the 7 years of GPS observations more than 0.5 m of uplift has occurred, a majority of that during the time period January 2003 to July 2004. The total volume recovery at Okmok since the last eruption in 1997 is ∼60–80%. The UKF allows us to solve simultaneously for the time‐dependence of the source strength and for the location without a priori information about the source. 2009 by the American Geophysical Union.

Alaska↗
USGS1997

Coseismic deformation of the Wrights tunnel during the 1906 San Francisco earthquake: A key to understanding 1906 fault slip and 1989 surface ruptures in the southern Santa Cruz Mountains, California

The Wrights tunnel is an abandoned railroad tunnel that crosses the San Andreas fault in the southern Santa Cruz Mountains in the vicinity of the 1989 Loma Prieta earthquake. The tunnel was damaged and deformed during the 1906 San Francisco earthquake and a plot showing postearthquake measurements made in the tunnel is given by Lawson [1908]. The amount of offset shown on this plot (1.5 m) has been used in several studies as being representative of the amount of fault offset along this segment of the San Andreas fault in 1906. Our historical research shows that different observers reported different amounts of fault offset in the tunnel and that the 1.5 m given on the plot is not a surveyed measurement. In addition, the plot of the tunnel has been interpreted in several previous studies as evidence of a broad (1.5 km) zone of faulting beneath Summit Ridge. Our analysis shows that this plot need not indicate a broad zone of deformation. Our historical research and modeling of the tunnel measurements indicate that faulting was confined to a zone less than 400 m wide and that 60–85% of the coseismic slip occurred across a single fault plane. There is no evidence for offset across a second shear zone beneath Summit Ridge in 1906. This implies that surface fractures reported on Summit Ridge in 1906 were not associated with significant deformation of the tunnel, implying that they were shallow, surficial features. By analogy, the very similar fractures that occurred on Summit Ridge in 1989 were also probably the result of shallow gravitational, rather than deep-seated tectonic, processes. Our modeling also indicates that total coseismic, near-surface slip across the San Andreas fault zone in the Wrights tunnel in 1906 was at least 1.7–1.8 m.

Journal of Geophysical Research B: Solid Earth↗
USGS2002

Seismic anisotropy and mantle creep in young orogens

Seismic anisotropy provides evidence for the physical state and tectonic evolution of the lithosphere. We discuss the origin of anisotropy at various depths, and relate it to tectonic stress, geotherms and rheology. The anisotropy of the uppermost mantle is controlled by the orthorhombic mineral olivine, and may result from ductile deformation, dynamic recrystallization or annealing. Anisotropy beneath young orogens has been measured for the seismic phase Pn that propagates in the uppermost mantle. This anisotropy is interpreted as being caused by deformation during the most recent thermotectonic event, and thus provides information on the process of mountain building. Whereas tectonic stress and many structural features in the upper crust are usually orientated perpendicular to the structural axis of mountain belts, Pn anisotropy is aligned parallel to the structural axis. We interpret this to indicate mountain-parallel ductile (i.e. creeping) deformation in the uppermost mantle that is a consequence of mountain-perpendicular compressive stresses. The preferred orientation of the fast axes of some anisotropic minerals, such as olivine, is known to be in the creep direction, a consequence of the anisotropy of strength and viscosity of orientated minerals. In order to explain the anisotropy of the mantle beneath young orogens we extend the concept of crustal 'escape' (or 'extrusion') tectonics to the uppermost mantle. We present rheological model calculations to support this hypothesis. Mountain-perpendicular horizontal stress (determined in the upper crust) and mountain-parallel seismic anisotropy (in the uppermost mantle) require a zone of ductile decoupling in the middle or lower crust of young mountain belts. Examples for stress and mountain-parallel Pn anisotropy are given for Tibet, the Alpine chains, and young mountain ranges in the Americas. Finally, we suggest a simple model for initiating mountain parallel creep.

Geophysical Journal International↗
USGS1985

Forecasts and predictions of eruptive activity at Mount St. Helens, USA: 1975-1984

Public statements about volcanic activity at Mount St. Helens include factual statements, forecasts, and predictions. A factual statement describes current conditions but does not anticipate future events. A forecast is a comparatively imprecise statement of the time, place, and nature of expected activity. A prediction is a comparatively precise statement of the time, place, and ideally, the nature and size of impending activity. A prediction usually covers a shorter time period than a forecast and is generally based dominantly on interpretations and measurements of ongoing processes and secondarily on a projection of past history. The three types of statements grade from one to another, and distinctions are sometimes arbitrary. Forecasts and predictions at Mount St. Helens became increasingly precise from 1975 to 1982. Stratigraphic studies led to a long-range forecast in 1975 of renewed eruptive activity at Mount St. Helens, possibly before the end of the century. On the basis of seismic, geodetic and geologic data, general forecasts for a landslide and eruption were issued in April 1980, before the catastrophic blast and landslide on 18 May 1980. All extrusions except two from June 1980 to the end of 1984 were predicted on the basis of integrated geophysical, geochemical, and geologic monitoring. The two extrusions that were not predicted were preceded by explosions that removed a substantial part of the dome, reducing confining pressure and essentially short-circuiting the normal precursors.

Journal of Geodynamics↗
USGS2004

Structural model of the San Bernardino basin, California, from analysis of gravity, aeromagnetic, and seismicity data

The San Bernardino basin is an area of Quaternary extension between the San Jacinto and San Andreas Fault zones in southern California. New gravity data are combined with aeromagnetic data to produce two- and three-dimensional models of the basin floor. These models are used to identify specific faults that have normal displacements. In addition, aeromagnetic maps of the basin constrain strike-slip offset on many faults. Relocated seismicity, focal mechanisms, and a seismic reflection profile for the basin area support interpretations of the gravity and magnetic anomalies. The shape of the basin revealed by our interpretations is different from past interpretations, broadening its areal extent while confining the deepest parts to an area along the modern San Jacinto fault, west of the city of San Bernardino. Through these geophysical observations and related geologic information, we propose a model for the development of the basin. The San Jacinto fault-related strike-slip displacements started on fault strands in the basin having a stepping geometry thus forming a pull-apart graben, and finally cut through the graben in a simpler, bending geometry. In this model, the San Bernardino strand of the San Andreas Fault has little influence on the formation of the basin. The deep, central part of the basin resembles classic pull-apart structures and our model describes a high level of detail for this structure that can be compared to other pull-apart structures as well as analog and numerical models in order to better understand timing and kinematics of pull-apart basin formation. Copyright 2004 by the American Geophysical Union.

Journal of Geophysical Research B: Solid Earth↗
USGS1998

Viscoelastic coupling model of the San Andreas fault along the Big Bend, southern California

The big bend segment of the San Andreas fault is the 300-km-long segment in southern California that strikes about N65°W, roughly 25° counterclockwise from the local tangent to the small circle about the Pacific-North America pole of rotation. The broad distribution of deformation of trilateration networks along this segment implies a locking depth of at least 25 km as interpreted by the conventional model of strain accumulation (continuous slip on the fault below the locking depth at the rate of relative plate motion), whereas the observed seismicity and laboratory data on fault strength suggest that the locking depth should be no greater than 10 to 15 km. The discrepancy is explained by the viscoelastic coupling model which accounts for the viscoelastic response of the lower crust. Thus the broad distribution of deformation observed across the big bend segment can be largely associated with the San Andreas fault itself, not subsidiary faults distributed throughout the region. The Working Group on California Earthquake Probabilities [1995] in using geodetic data to estimate the seismic risk in southern California has assumed that strain accumulated off the San Andreas fault is released by earthquakes located off the San Andreas fault. Thus they count the San Andreas contribution to total seismic moment accumulation more than once, leading to an overestimate of the seismicity for magnitude 6 and greater earthquakes in their Type C zones.

Journal of Geophysical Research B: Solid Earth↗
USGS1999

Chemical, multispectral, and textural constraints on the composition and origin of rocks at the Mars Pathfinder landing site

Rocks at the Mars Pathfinder site are probably locally derived. Textures on rock surfaces may indicate volcanic, sedimentary, or impact-generated rocks, but aeolian abration and dust coatings prevent unambiguous interpretation. Multispectral imaging has resolved four spectral classes of rocks: gray and red, which occur on different surfaces of the same rocks; pink, which is probably soil crusts; and maroon, which occurs as large boulders, mostly in the far field. Rocks are assigned to two spectral trends based on the position of peak reflectance: the primary spectral trend contains gray, red, and pink rocks; maroon rocks constitute the secondary spectral trend. The spatial pattern of spectral variations observed is oriented along the prevailing wind direction. The primary spectral trend arises from thin ferric coatings of aeolian dust on darker rocks. The secondary spectral trend is apparently due to coating by a different mineral, probably maghemite or ferrihydrite. A chronology based on rock spectra suggests that rounded maroon boulders constitute the oldest petrologic unit (a flood deposit), succeeded by smaller cobbles possibly deposited by impact, and followed by aeolian erosion and deposition. Nearly linear chemical trends in alpha proton X-ray spectrometer rock compositions are interpreted as mixing lines between rock and adhering dust, a conclusion supported by a correlation between sulfur abundance and red/blue spectral ratio. Extrapolations of regression lines to zero sulfur give the composition of a presumed igneous rock. The chemistry and normative mineralogy of the sulfur-free rock resemble common terrestrial volcanic rocks, and its classification corresponds to andesite. Igneous rocks of this composition may occur with clastic sedimentary rocks or impact melts and breccias. However, the spectral mottling expected on conglomerates or breccias is not observed in any APXS-analyzed rocks. Interpretation of the rocks as andesites is complicated by absence of a "1 μm" pyroxene absorption band. Plausible explanations include impact glass, band masking by magnetite, or presence of calcium- and iron-rich pyroxenes and olivine which push the absorption band minimum past the imager's spectral range. The inferred andesitic composition is most similar to terrestrial anorogenic icelandites, formed by fractionation of tholeiitic basaltic magmas. Early melting of a relatively primitive Martian mantle could produce an appropriate parent magma, supporting the ancient age of Pathfinder rocks inferred from their incorporation in Hesperian flood deposits. Although rocks of andesitic composition at the Pathfinder site may represent samples of ancient Martian crust, inferences drawn about a necessary role for water or plate tectonics in their petrogenesis are probably unwarranted.

Journal of Geophysical Research E: Planets↗
USGS2012

Chemistry of rock-forming minerals of the Cretaceous-Paleocene batholith in southwestern Japan and implications for magma genesis

Petrographic descriptions and electron microprobe analyses of minerals are presented for 35 specimens from seven suites chosen to examine the transition from magnetite series to ilmenite series granitoids along two transects across the Cretaceous-Paleocene Inner Zone batholith of southwestern Japan. Regularities in chemical compositions of amphiboles, biotites, and feldspars suggest that fundamentally similar processes produced the magmas that formed the two series. Constant or decreasing Fe/(Fe+Mg) for biotites and amphiboles with increasing host rock silica content, coupled with the absence of early formed magnetite and sphene, suggest that magnetite series rocks may have become oxidized during crystallization near the level of intrusion, through the processes of second boiling and differential loss of hydrogen. For the Daito-Yokota, magnetite series suite, Fe/(Fe+Mg) for biotites decreased from 0.48 to 0.37 as SiO 2 content of the host rock increased from 55.3 to 75.5 wt %; for an ilmenite series suite from the Takanawa Peninsula, Fe/(Fe+Mg) for biotites increased from 0.51 to 0.77 with an increase in host rock SiO 2 from 53.4 to 75.5. Detailed consideration of amphibole chemistry shows predominance of edenitic and tschermakitic substitution schemes as well as coupling between substitutions of Ti in octahedral sites and Al IV . Interrelations between amphibole and biotite chemistry show that Fe/(Fe+Mg) and Mn contents can be interpreted in terms of equilibration, whereas Ti content cannot. The chemistry of chlorites correlates well with that of biotites; primary and secondary muscovites are distinct in composition. Plagioclase in all studied suites shows igneous zoning appropriate to host rock composition; perthitic alkali feldspars in all samples have lost albite component, and temperatures based on the two-feldspar geothermometer are low. The biotite-apatite geothermometer is also inoperative for this group of samples because fully fluorinated apatites typically occur in biotites of modest F content. Whereas magnetites have reequilibrated, analyses of ilmenites for the representative Daito-Yokota and Takanawa suites corroborate biotite compositional data and suggest that f O2 probably differed by 2 to 3 orders of magnitude during crystallization of silica-rich magnetite and ilmenite series granites. Whole-rock chemistry supports mineral chemistry in suggesting that the studied granitoids have crystallized from magmas generated in a lower crustal environment in which mantle-derived magmas partially melted source materials with igneous characteristics.

Journal of Geophysical Research Solid Earth↗
USGS1989

Sensitive strata in Bootlegger Cove Formation

Sensitivity magnitudes are interpreted from remolded strength values in recent subsurface geologic, geotechnical, and geochemical data from the Bootlegger Cove Formation adjacent to the Turnagain Heights Landslide. The results show that strata composed of highly sensitive clays occur in both the middle and lower zones of the formation, and that between these strata the clays are generally of low-to-medium sensitivity. The most sensitive stratum is in the middle zone between two sand layers, and its sensitivity increases from both clay-sand interfaces to a maximum at the center of the stratum. The pore fluid chemistry of the highly sensitive materials differs from that in the materials of low to medium sensitivity only in their concentrations of organic carbon, chloride, bicarbonate, and sulfate. The total dissolved solids concentration is low, and the ratio of monovalent to divalent cations is very high throughout the middle and lower zones of the formation. Of the known causes of high and extremely high sensitivities, only organic and/or anionic dispersants are consistent with these findings.

Journal of Geotechnical Engineering↗
USGS1997

Acidic deposition, cation mobilization, and biochemical indicators of stress in healthy red spruce

Dendrochemical and biochemical markers link stress in apparently healthy red spruce trees ( Picea rubens ) to acidic deposition. Acidic deposition to spruce forests of the northeastern USA increased sharply during the 1960s. Previous reports related visible damage of trees at high elevations to root and soil processes. In this report, dendrochemical and foliar biochemical markers indicate perturbations in biological processes in healthy red spruce trees across the northeastern USA. Previous research on the dendrochemistry of red spruce stemwood indicated that under uniform environmental conditions, stemwood concentrations of Ca and Mg decreased with increasing radial distance from the pith. For nine forest locations, frequency analysis shows that 28 and 52% of samples of red spruce stemwood formed in the 1960s are enriched in Ca and Mg, respectively, relative to wood formed prior to and after the 1960s. This enrichment in trees throughout the northeastern USA may be interpretable as a signal of increased availability of essential cations in forest soils. Such a temporary increase in the availability of Ca and Mg could be caused by cation mobilization, a consequence of increased acidic deposition. During cation mobilization, essential Ca and Mg as well as potentially harmful Al become more available for interaction with binding sites in the soil and absorbing roots. As conditions which favor cation mobilization continue, Ca and Mg can be leached or displaced from the soil. A measure of the interaction between Ca and Al is the Al/Ca binding ratio (molar charge ratio of exchangeable Al to exchangeable Ca). As the Al/Ca binding ratio in the root zone increased from 0.3 to 1.9, the foliar concentration of the biochemical stress marker putrescine also increased from 45 to 145 nm g −1 . The correlation of the putrescine concentration to the Al/Ca binding ratio (adj. r 2 = 0.68, P < 0.027) suggests that foliar stress may be linked to soil chemistry.

Journal of Environmental Quality↗
USGS1996

40Ar/39Ar whole-rock data constraints on Acadian diagenesis and Alleghanian cleavage in the Martinsburg formation, eastern Pennsylvania

A comparison of 40 Ar/ 39 Ar age spectra of whole-rock mudstone and slate samples from the Ordovician Martinsburg Formation at Lehigh Gap, Pennsylvania and stratigraphic and thermal constraints support Alleghanian age for regional slaty cleavage and a late Acadian age for diagenesis in these rocks. Age spectra from mud-stones have a sigmodal shape, with slopes that climb steeply from apparent Mesozoic ages to intermediate saddle regions with Devonian apparent ages, and then climb steeply again to Late Proterozoic apparent ages. The steps with these oldest apparent ages are interpreted to be dominated by late Proterzoic detrial muscovite. The saddle region of the mudstone samples gives very Late Silurian to earliest Devonian ages, which are maximum ages of diagenetic micas and which eliminate a Taconic age for the cleavage. The ages of saddle regions of the slate samples constraining cleavage-forming muscovite is <~375. This is the maximum age of this mica and requires an Alleghanian age for the cleavage. These age constraints are supported by ages of individual mica components calculated with knowledge of the total gas ages and mass fractions of the micas and by predictions from thermal modeling. We conclude that the Taconic orogeny in the Martinsburg Formation in eastern Pennsylvania was a very mild event. Not only is the cleavage in these rocks not Taconic in age, but even the mild (~100C) diagenetic growth of illite was Silurian of younger. Thus the Taconic event in these rocks in limited to loading of lass than about 3 km.

Connecticut, Delaware, Maryland, Pennsylvania, New↗