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Tales from a distant swamp: Petrological and paleobotanical clues for the origin of the sand coal lithotype (Mississippian, Valley Fields, Virginia)

Tournasian (Mississippian) Price Formation semianthracites (Rmax = 2.40%) in the Valley Fields of southwestern Virginia contain a lithotype described in an early-20th-century report as a "sand" coal. The Center for Applied Energy Research inherited a collection of coals containing sand coal specimens, making it possible to study the lithotype from the long-closed mines. The sand coal consists of rounded quartz sand and maceral assemblages (secretinite, corpogelinite, and rounded collotelinite) along with banded collotelinite, vitrodetrinite, and inertodetrinite assemblages. The association of rounded macerals and similar-size quartz grains suggests transport. Oxidation rims surrounding the rounded collotelinite provides further evidence for transport. Due to the semianthracite rank, palynology could not be performed. Stratigraphic evidence indicates that the Lepidodendropsis flora would have been the dominant mire vegetation. Pteridosperms in this assemblage could have contributed resin rodlets, subsequently metamorphosed to collogelinite or secretinite. While a resin rodlet origin is an intriguing possibility for the origin of the rounded macerals (at least some of the rounded maceral, the rounded collotelinite clearly has a different origin), we cannot definitively prove this origin. ?? 2008 Elsevier B.V. All rights reserved.

International Journal of Coal Geology↗

Why the 2002 Denali fault rupture propagated onto the Totschunda fault: implications for fault branching and seismic hazards

The propagation of the rupture of the M w 7.9 Denali fault earthquake from the central Denali fault onto the Totschunda fault has provided a basis for dynamic models of fault branching in which the angle of the regional or local prestress relative to the orientation of the main fault and branch plays a principal role in determining which fault branch is taken. GeoEarthScope LiDAR and paleoseismic data allow us to map the structure of the Denali-Totschunda fault intersection and evaluate controls of fault branching from a geological perspective. LiDAR data reveal the Denali-Totschunda fault intersection is structurally simple with the two faults directly connected. At the branch point, 227.2 km east of the 2002 epicenter, the 2002 rupture diverges southeast to become the Totschunda fault. We use paleoseismic data to propose that differences in the accumulated strain on each fault segment, which express differences in the elapsed time since the most recent event, was one important control of the branching direction. We suggest that data on event history, slip rate, paleo offsets, fault geometry and structure, and connectivity, especially on high slip rate-short recurrence interval faults, can be used to assess the likelihood of branching and its direction. Analysis of the Denali-Totschunda fault intersection has implications for evaluating the potential for a rupture to propagate across other types of fault intersections and for characterizing sources of future large earthquakes.

Alaska↗

Research on genesis of pyrite near the Permian-Triassic boundary in meishan, Zhejiang, China

The content and crystal forms of pyrite and sulfur isotope composition of pyrite sulfur as well as its vertical distribution near the Permian-Triassic (P/T) boundary in the Meishan section, Changxing county, Zhejiang province, China were studied using geological, petrological, mineralogical and geochemical methods (techniques). The result showed that the genesis of abundant pyrites in bed 24e2 at the uppermost part of the Changxing Formation in the Meishan section may be related to volcanic activity. In bed 24e2 of the Meishan section, pyrite has its highest content of 1.84% and the sulfur isotope composition has the highest ??34S value at + 2.2??? which is very similar to that of the average value of volcanic gas. There are some volcanic products such as ??-quartz, siliceous cylinders and siliceous spherules which coexisted with pyrites in beds 24e2 and 24f. It can be concluded that a large quantity of volcanic ash fell into the South China Sea and was incorporated into marine sediments during the formation of limestone at the uppermost part of the Changxing Formation. The volcanic eruption with massive amounts of H2S and S02 gas at the end of the Permian period resulted in the enrichment of H2S in the South China Sea areas. The reaction of H2S with reactive iron minerals formed the mass of abundant pyrites.

Journal of China University of Mining and Technolo↗

Palila restoration research, 1996−2012

The Palila Restoration Project was initiated in 1996 by the U.S. Geological Survey to assist government agencies mitigate the effects of realigning Saddle Road (Highway 200) through Palila Critical Habitat (U.S. Fish and Wildlife Service 1998, Federal Highway Administration 1999). Ecological research on the palila (Loxioides bailleui), an endangered Hawaiian forest bird, carried out by the U.S. Geological Survey (formerly organized as the Research Division of U.S. Fish and Wildlife Service) since 1987 and research conducted by the Palila Restoration Project provided the scientific bases for developing a recovery strategy (U.S. Fish and Wildlife Service 2006) and its adaptive implementation. The main objectives of the Palila Restoration Project were to develop techniques for reintroducing the palila to a portion of its former range, investigate the biological threats to the palila and its habitat, and synthesize the existing body of ecological knowledge concerning the palila. Five broad study themes formed the research framework: 1. Population reintroduction and restoration 2. Demography and breeding ecology 3. Habitat use and food ecology 4. Vegetation ecology 5. Predator ecology and management An element that was not included in the research program of the project was the ecology and management of introduced ungulates, which has historically constituted the single greatest threat to Palila Critical Habitat (Banko et al. 2009). The absence of ungulate studies should not be interpreted to mean that we believe ungulates no longer damage palila habitat. Other research has already established that removing alien browsers and grazers from Mauna Kea is essential for the recovery of the subalpine forest on which palila now depend (Scowcroft and Giffin 1983; Scowcroft and Sakai 1983; Scowcroft and Conrad 1988, 1992; Hess et al. 1999). Moreover, the Federal District Court of Hawai‘i has ordered the state of Hawai‘i to remove browsing ungulates from Palila Critical Habitat (Banko et al. 2009, Hess and Banko 2011). This final report summarizes results of Palila Restoration Project research from December 1996 to December 2012. Even though some results contained in this report have been published in scientific journals and other technical reports (Appendix I), they are included here to provide a comprehensive chronicle of all project activities.

Hawaii↗

Palila Restoration Research, 1996−2012. Summary and management implications

The Palila Restoration Project was initiated in 1996 by the U.S. Geological Survey to assist government agencies mitigate the effects of realigning Saddle Road (Highway 200) through Palila Critical Habitat (U.S. Fish and Wildlife Service 1998, Federal Highway Administration 1999). Ecological research on the palila (Loxioides bailleui), an endangered Hawaiian forest bird, carried out by the U.S. Geological Survey (formerly organized as the Research Division of U.S. Fish and Wildlife Service) since 1987 and research conducted by the Palila Restoration Project provided the scientific bases for developing a recovery strategy (U.S. Fish and Wildlife Service 2006) and its adaptive implementation. The main objectives of the Palila Restoration Project were to develop techniques for reintroducing the palila to a portion of its former range, investigate the biological threats to the palila and its habitat, and synthesize the existing body of ecological knowledge concerning the palila. Five broad study themes formed the research framework: 1. Population reintroduction and restoration 2. Demography and breeding ecology 3. Habitat use and food ecology 4. Vegetation ecology 5. Predator ecology and management An element that was not included in the research program of the project was the ecology and management of introduced ungulates, which has historically constituted the single greatest threat to Palila Critical Habitat (Banko et al. 2009). The absence of ungulate studies should not be interpreted to mean that we believe ungulates no longer damage palila habitat. Other research has already established that removing alien browsers and grazers from Mauna Kea is essential for the recovery of the subalpine forest on which palila now depend (Scowcroft and Giffin 1983; Scowcroft and Sakai 1983; Scowcroft and Conrad 1988, 1992; Hess et al. 1999). Moreover, the Federal District Court of Hawai‘i has ordered the State of Hawai‘i to remove browsing ungulates from Palila Critical Habitat (Banko et al. 2009, Hess and Banko 2011). This final report summarizes results of Palila Restoration Project research from December 1996 to December 2012. Even though some results contained in this report have been published in scientific journals and other technical reports (Appendix I), they are included here to provide a comprehensive chronicle of all project activities.

Hawaii↗

Presentation and analysis of a worldwide database of earthquake-induced landslide inventories

Earthquake-induced landslide (EQIL) inventories are essential tools to extend our knowledge of the relationship between earthquakes and the landslides they can trigger. Regrettably, such inventories are difficult to generate and therefore scarce, and the available ones differ in terms of their quality and level of completeness. Moreover, access to existing EQIL inventories is currently difficult because there is no centralized database. To address these issues, we compiled EQIL inventories from around the globe based on an extensive literature study. The database contains information on 363 landslide-triggering earthquakes and includes 66 digital landslide inventories. To make these data openly available, we created a repository to host the digital inventories that we have permission to redistribute through the U.S. Geological Survey ScienceBase platform. It can grow over time as more authors contribute their inventories. We analyze the distribution of EQIL events by time period and location, more specifically breaking down the distribution by continent, country, and mountain region. Additionally, we analyze frequency distributions of EQIL characteristics, such as the approximate area affected by landslides, total number of landslides, maximum distance from fault rupture zone, and distance from epicenter when the fault plane location is unknown. For the available digital EQIL inventories, we examine the underlying characteristics of landslide size, topographic slope, roughness, local relief, distance to streams, peak ground acceleration, peak ground velocity, and Modified Mercalli Intensity. Also, we present an evaluation system to help users assess the suitability of the available inventories for different types of EQIL studies and model development.

Journal of Geophysical Research F: Earth Surface↗

Deep crustal structure of the Cascade Range and surrounding regions from seismic refraction and magnetotelluric data

Several regional seismic refraction and magnetotelluric (MT) profiles have been completed across the Cascade Range and surrounding geologic provinces in California, Oregon, and Washington. Analysis of three MT and two seismic refraction profiles in Oregon and a coincident MT and refraction profile in northern California show a high degree of correlation between resistivity and velocity models. The main feature that is evident in both data sets is a highly conductive (2-20 ohm m) zone that occurs at depths of 6-20 km and largely within a midcrustal velocity layer of 6.4-6.6 km/s, overlying a lower crust with velocities of 7.0-7.4 km/s. Accretionary structures in the southern Washington Cascades have been shown to be related to stress release in the area of Mount St. Helens. In order to explain the similar structures in the MT and refraction models for Oregon and California, a model is proposed involving the effects of metamorphic zonation to produce the velocity structure, combined with metamorphically produced fluids and partial melt to produce the deep conductor.

California, Oregon, Washington↗

Identifying block structure in the Pacific Northwest, USA

We have identified block structure in the Pacific Northwest (west of 116°W between 38°N and 49°N) by clustering GPS stations so that the same Euler vector approximates the velocity of each station in a cluster. Given the total number k of clusters desired, the clustering procedure finds the best assignment of stations to clusters. Clustering is calculated for k= 2 to 14. In geographic space, cluster boundaries that remain relatively stable as k is increased are tentatively identified as block boundaries. That identification is reinforced if the cluster boundary coincides with a geologic feature. Boundaries identified in northern California and Nevada are the Central Nevada Seismic Belt, the west side of the Northern Walker Lane Belt, and the Bartlett Springs Fault. Three blocks cover all of Oregon and Washington. The principal block boundary there extends west-northwest along the Brothers Fault Zone, then north and northwest along the eastern boundary of Siletzia, the accreted oceanic basement of the forearc. East of this boundary is the Intermountain block, its eastern boundary undefined. A cluster boundary at Cape Blanco subdivides the forearc along the faulted southern margin of Siletzia. South of Cape Blanco the Klamath Mountains-Basin and Range block extends east to the Central Nevada Seismic Belt and south to the Sierra Nevada-Great Valley block. The Siletzia block north of Cape Blanco coincides almost exactly with the accreted Siletz terrane. The cluster boundary in the eastern Olympic Peninsula may mark permanent shortening of Siletzia against the Intermountain block.

California, Idaho, Nevada, Oregon, Washington↗

Causes of two slope-failure types in continental-shelf sediment, northeastern Gulf of Alaska

Slumps and sediment-gravity flows have been identified in Holocene glaciomarine sediment on declivities less than 1.3 degrees on the Gulf of Alaska continental shelf. Geologic and geotechnical investigation suggest that the processes responsible for these slope failures are earthquake and storm-wave loading, coupled with cyclic degradation of the sediment-shear strength. We propose that the failure type is related to the nature of the failure load. For example, a slump that occurs approximately 30 km seaward of Icy Bay in water depth of 70 to 150 m was most likely caused by earthquake loading, whereas sediment-gravity flows on the Alsek prodelta, which occur in water depths of 35 to 80 m, probably were caused primarily by storm-wave loading. Sediment remolding and redistribution and incorporation of water, which occurs more readily during wave loading from a long storm than during the limited number of loading cycles generated by an earthquake, reduces the shear strength and increases the fluidity of the failed sediment mass. Wave-induced slope failures thereby tend to transform into sediment-gravity flows.

Alaska↗

Geologic context of recurring slope lineae in Melas and Coprates Chasmata, Mars

One of the major Mars discoveries of recent years is the existence of recurring slope lineae (RSL), which suggests that liquid water occurs on or near the surface of Mars today. These dark and narrow features emerge from steep, rocky exposures and incrementally grow, fade, and reform on a seasonal basis and are detected in images from the High Resolution Imaging Science Experiment camera. RSL are known to occur at scattered midlatitude and equatorial sites with little spatial connection to one another. One major exception is the steep, low-albedo slopes of Melas and Coprates Chasmata, in Valles Marineris where RSL are detected among diverse geologic surfaces (e.g., bedrock and talus) and landforms (e.g., inselbergs and landslides). New images show topographic changes including sediment deposition on active RSL slopes. Midwall locations in Coprates and Melas appear to have more areally extensively abundant RSL and related fans as compared with other RSL sites found on Mars. Water budget estimates for regional RSL are on the order of 10 5 to 10 6 m 3 of fluid, for depths of 10 to 100mm, and suggest that a significant amount of near-surface watermight be present. Many RSL are concentrated near local topographic highs, such as ridge crests or peaks, which is challenging to explain via groundwater or ice without a recharge mechanism. Collectively, results provide additional support for the notion that significant amounts of near-surface water can be found on Mars today and suggest that a widespread mechanism, possibly related to the atmosphere, is recharging RSL sources.

Journal of Geophysical Research E: Planets↗

Dislocation models of interseismic deformation in the western United States

The GPS-derived crustal velocity field of the western United States is used to construct dislocation models in a viscoelastic medium of interseismic crustal deformation. The interseismic velocity field is constrained by 1052 GPS velocity vectors spanning the ???2500-km-long plate boundary zone adjacent to the San Andreas fault and Cascadia subduction zone and extending ???1000 km into the plate interior. The GPS data set is compiled from U.S. Geological Survey campaign data, Plate Boundary Observatory data, and the Western U.S. Cordillera velocity field of Bennett et al. (1999). In the context of viscoelastic cycle models of postearthquake deformation, the interseismic velocity field is modeled with a combination of earthquake sources on ???100 known faults plus broadly distributed sources. Models that best explain the observed interseismic velocity field include the contributions of viscoelastic relaxation from faulting near the major plate margins, viscoelastic relaxation from distributed faulting in the plate interior, as well as lateral variations in depth-averaged rigidity in the elastic lithosphere. Resulting rigidity variations are consistent with reduced effective elastic plate thickness in a zone a few tens of kilometers wide surrounding the San Andreas fault (SAF) system. Primary deformation characteristics are captured along the entire SAF system, Eastern California Shear Zone, Walker Lane, the Mendocino triple junction, the Cascadia margin, and the plate interior up to ???1000 km from the major plate boundaries.

Journal of Geophysical Research B: Solid Earth↗

Debris-flow origin for the Simud/Tiu deposit on Mars

A late Hesperian smooth plains deposit on Mars interpreted as a debris flow extends more than 2000 km from Hydraotes Chaos, through Simud and Tiu Valles, and into Chryse Planitia. The Simud/Tiu deposit widens out to >1000 km and embays streamlined landforms and knobs made up of sedimentary and perhaps volcanic deposits that were carved by earlier channeling activity. Morphologic features of the Simud/Tiu deposit observed in Viking and Pathfinder images are generally consistent with a debris-flow origin, but some of the deposit's salient features are not readily explained by catastrophic flooding or ice flow. Internal depressions appear to be bounded by linear scarps along flow margins where differential shearing may have occurred and in areas where flow spreading may have produced zones of extensional breakup and thinning within the flow. Possible flow lobes within the deposit may have formed by successive flow surges within the flow unit. The Pathfinder landing site is on the Simud/Tiu deposit, and the observations there are consistent with debris flow. The low, longitudinal ridges at the site may have formed by clast interactions as the flow ground to a halt. Imbricated, planar rocks on the ridges, such as in the Rock Garden, also may have been emplaced by debris or ice flow. However, stream energy calculations at Ares Vallis and channel geology indicate that flooding probably was incapable of emplacing the meter-size boulders observed at the Pathfinder site. Dewatering of pressurized zones in the debris flow or underlying material may be responsible for mud eruptions that formed a couple of patches of low pancakelike shields up to 5 km in diameter and for probable water flows that formed two small rille channels a few kilometers long. Local irregular grooves may be cracks that resulted from later desiccation and contraction of the flow material. The debris-flow unit apparently coalesced from outflows of water-fluidized debris originating from beneath chaotic and hummocky terrains within and along the margins of Simud and Tiu Valles. The deposit is onlapped from the north by another flow deposit originating from Acidalia Planitia. If the Simud/Tiu debris flow had entered a standing body of water, a turbidity current may have arisen from the debris flow and then backflowed over the debris flow to account for the Acidalia deposit.

Journal of Geophysical Research E: Planets↗

Large-magnitude Middle Ordovician volcanic ash falls in North America and Europe: Dimensions, emplacement and post-emplacement characteristics

Middle Ordovician K-bentonites represent some of the largest known fallout ash deposits in the Phanerozoic Era. They cover minimally 2.2 ?? 106 km2 in eastern North America and 6.9 ?? 105 km2 in northwestern Europe, and represents the coeval accumulation of plinian and co-ignimbrite ash on both Laurentia and Baltica during the closure of the Iapetus Ocean. The three most widespread beds are the Deicke and Millbrig K-bentonites in North America and the Kinnekulle K-bentonite in northwestern Europe. The vents were located near the Laurentian margin of Iapetus on an arc or microplate undergoing collision with Laurentia. The volume of ash preserved in the stratigraphic record converted to dense rock equivalent (DRE) of silicic magma is minimally estimated to be 943 km3 for the Deicke, 1509 km3 for the Millbrig and 972 km3 for the Kinnekulle. The Millbrig and Kinnekulle beds are coeval and possibly equivalent, yielding a combined DRE volume of nearly 2500 km3. Some unknown but probably large amount of additional ash fell into oceanic regions of the Iapetus, but these areas became subducted and the ash is not preserved in the geologic record. The symmetry of the thickness contours is suggestive that one or more ash clouds interacting with equatorial stratospheric and tropospheric wind patterns dispersed pyroclastic material to both the northwest and southeast in terms of Ordovician paleogeography. Based on grain size measurements and thickness/area1/2 plots we conclude the three beds were each formed from co-ignimbrite or possibly phreatoplinian eruption columns. Analyses of melt inclusions in primary quartz crystals indicate the parental magma contained approximately 4% dissolved water at the time of the eruption. This water provided the explosive energy during the initial gas thrust phase. The implied fragmentation pressure on the magma would have reduced much of the ejecta to small particles, forming a deposit composed largely of single crystals and glassy dust. Conversion of the ash to K-bentonite resulted in a mass loss of approximately 35%, mostly in the form of Si with lesser amounts of Na and K.

Journal of Volcanology and Geothermal Research↗

Since “Groundwater and surface water–A single resource”: some U.S. Geological Survey advances in modeling groundwater/surface-water interactions

Field and interpretive studies conducted by T.C. Winter and U.S. Geological Survey colleagues, and summarized in the 1998 publication “Groundwater and Surface Water – A Single Resource”, inspired a new generation of research centered on extensions of the groundwater-flow code MODFLOW to more sophisticated simulation of coupled groundwater and surface-water systems. Guided by emerging concerns with water availability, safe yields from wells, health of aquatic habitat, and climate change, the changes to MODFLOW involve: 1) the ability to more precisely and accurately represent the interface between surface and subsurface flows and 2) the consideration of a variety of mechanisms that influence their interaction. A review of the most important changes to the code is supplemented in this article by selected case studies in an effort to show the scope of the advances. The updates discussed include the Streamflow Routing (SFR), Lake (LAK), and Unsaturated-Zone Flow (UZF) Packages in MODFLOW-2005 and the Groundwater Management (GWM), Local Grid Refinement (LGR), and Newton (NWT) formulation versions of MODFLOW-2005. New developments feature the integration of rainfall-runoff modeling with MODFLOW in GSFLOW, coupling of GFLOW and MODFLOW in a hybrid code, and the forthcoming unstructured grid version of MODFLOW. They promise continued advances in the ability to use science to protect the single water resource.

Acque Sotterranee: Italian Journal of Groundwater↗

Utilizing multichannel electrical resistivity methods to examine the dynamics of the fresh water–seawater interface in two Hawaiian groundwater systems

Multichannel electrical resistivity (ER) measurements were conducted at two contrasting coastal sites in Hawaii to obtain new information on the spatial scales and dynamics of the fresh water–seawater interface and rates of coastal groundwater exchange. At Kiholo Bay (located on the dry, Kona side of the Big Island) and at a site in Maunalua Bay (Oahu), there is an evidence for abundant submarine groundwater discharge (SGD). However, the hydrologic and geologic controls on coastal groundwater discharge are likely to be different at these two sites. While at Kiholo Bay SGD is predominantly through lava tubes, at the Maunalua Bay site exchange occurs mostly through nearshore submarine springs. In order to calculate SGD fluxes, it is important to understand the spatial and temporal scales of coastal groundwater exchange. From ER time series data, subsurface salinity distributions were calculated using site-specific formation factors. A salinity mass balance box model was then used to calculate rates of point source (i.e., spatially discreet) and total fresh water discharge. From these data, mean SGD rates were calculated for Kiholo Bay (∼9,200 m 3 /d) and for the Maunalua Bay site (∼5,900 m 3 /d). While such results are on the same order of magnitude to geochemical tracer-derived SGD rates, the ER SGD rates provide enhanced details of coastal groundwater exchange that can enable a more cohesive whole watershed perspective.

Hawai'i↗

Rocky 7 prototype Mars rover field geology experiments: 1. Lavic Lake and Sunshine volcanic field, California

Experiments with the Rocky 7 rover were performed in the Mojave Desert to better understand how to conduct rover-based, long-distance (kilometers) geological traverses on Mars. The rover was equipped with stereo imaging systems for remote sensing science and hazard avoidance and 57 Fe Mössbauer and nuclear magnetic resonance spectrometers for in situ determination of mineralogy of unprepared rock and soil surfaces. Laboratory data were also obtained using the spectrometers and an X ray diffraction (XRD)/XRF instrument for unprepared samples collected from the rover sites. Simulated orbital and descent image data assembled for the test sites were found to be critical for assessing the geologic setting, formulating hypotheses to be tested with rover observations, planning traverses, locating the rover, and providing a regional context for interpretation of rover-based observations. Analyses of remote sensing and in situ observations acquired by the rover confirmed inferences made from orbital and simulated descent images that the Sunshine Volcanic Field is composed of basalt flows. Rover data confirmed the idea that Lavic Lake is a recharge playa and that an alluvial fan composed of sediments with felsic compositions has prograded onto the playa. Rover-based discoveries include the inference that the basalt flows are mantled with aeolian sediment and covered with a dense pavement of varnished basalt cobbles. Results demonstrate that the combination of rover remote sensing and in situ analytical observations will significantly increase our understanding of Mars and provide key connecting links between orbital and descent data and analyses of returned samples.

Journal of Geophysical Research E: Planets↗

Quantitative investigations of the Missouri gravity low: A possible expression of a large, Late Precambrian batholith intersecting the New Madrid seismic zone

Analysis of gravity and magnetic anomaly data helps characterize the geometry and physical properties of the source of the Missouri gravity low, an important cratonic feature of substantial width (about 125 km) and length (> 600 km). Filtered anomaly maps show that this prominent feature extends NW from the Reelfoot rift to the Midcontinent Rift System. Geologic reasoning and the simultaneous inversion of the gravity and magnetic data lead to an interpretation that the gravity anomaly reflects an upper crustal, 11-km-thick batholith with either near vertical or outward dipping boundaries. Considering the modeled characteristics of the batholith, structural fabric of Missouri, and relations of the batholith with plutons and regions of alteration, a tectonic model for the formation of the batholith is proposed. The model includes a mantle plume that heated the crust during Late Precambrian and melted portions of lower and middle crust, from which the low-density granitic rocks forming the batholith were partly derived. The batholith, called the Missouri batholith, may be currently related to the release of seismic energy in the New Madrid seismic zone (earthquake concentrations occur at the intersection of the Missouri batholith and the New Madrid seismic zone). Three qualitative mechanical models are suggested to explain this relationship with seismicity. Copyright 1996 by the American Geophysical Union.

Journal of Geophysical Research B: Solid Earth↗

Field-scale sulfur hexafluoride tracer experiment to understand long distance gas transport in the deep unsaturated zone

A gas-tracer test in a deep arid unsaturated zone demonstrates that standard estimates of effective diffusivity from sediment properties allow a reasonable first-cut assessment of gas contaminant transport. Apparent anomalies in historic transport behavior at this and other waste disposal sites may result from factors other than nonreactive gas transport properties. A natural gradient SF 6 tracer experiment provided an unprecedented evaluation of long distance gas transport in the deep unsaturated zone (UZ) under controlled (known) conditions. The field-scale gas tracer test in the 110-m-thick UZ was conducted at the U.S. Geological Survey’s Amargosa Desert Research Site (ADRS) in southwestern Nevada. A history of anomalous (theoretically unexpected) contaminant gas transport observed at the ADRS, next to the first commercial low-level radioactive waste disposal facility in the United States, provided motivation for the SF 6 tracer study. Tracer was injected into a deep UZ borehole at depths of 15 and 48 m, and plume migration was observed in a monitoring borehole 9 m away at various depths (0.5–109 m) over the course of 1 yr. Tracer results yielded useful information about gas transport as applicable to the spatial scales of interest for off-site contaminant transport in arid unsaturated zones. Modeling gas diffusion with standard empirical expressions reasonably explained SF 6 plume migration, but tended to underpredict peak concentrations for the field-scale experiment given previously determined porosity information. Despite some discrepancies between observations and model results, rapid SF 6 gas transport commensurate with previous contaminant migration was not observed. The results provide ancillary support for the concept that apparent anomalies in historic transport behavior at the ADRS are the result of factors other than nonreactive gas transport properties or processes currently in effect in the undisturbed UZ.

California, Nevada↗