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At least 955 records · Page 53Linked to original sources
USGS2002

Steady subsidence of Medicine Lake volcano, northern California, revealed by repeated leveling surveys

Leveling surveys of a 193‐km circuit across Medicine Lake volcano (MLV) in 1954 and 1989 show that the summit area subsided by as much as 302 ± 30 mm (−8.6 ± 0.9 mm/yr) with respect to a datum point near Bartle, California, 40 km to the southwest. This result corrects an error in the earlier analysis of the same data by Dzurisin et al. [1991] , who reported the subsidence rate as −11.1 ± 1.2 mm/yr. The subsidence pattern extends across the entire volcano, with a surface area of nearly 2000 km 2 . Two areas of localized subsidence by as much as 20 cm can be attributed to shallow normal faulting near the volcano's periphery. Surveys of an east–west traverse across Lava Beds National Monument on the north flank of the volcano in 1990 and of a 23‐km traverse across the summit area in 1999 show that subsidence continued at essentially the same rate during 1989–1999 as 1954–1989. Volcano‐wide subsidence can be explained by either a point source of volume loss (Mogi) or a contracting horizontal rectangular dislocation (sill) at a depth of 10–11 km. Volume loss rate estimates range from 0.0013 to 0.0032 km 3 /yr, depending mostly on the source depth estimate and source type. Based on first‐order quantitative considerations, we can rule out that the observed subsidence is due to volume loss from magma withdrawal, thermal contraction, or crystallizing magma at depth. Instead, we attribute the subsidence and faulting to: (1) gravitational loading of thermally weakened crust by the mass of the volcano and associated intrusive rocks, and (2) thinning of locally weakened crust by Basin and Range deformation. The measured subsidence rate exceeds long‐term estimates from drill hole data, suggesting that over long timescales, steady subsidence and episodic uplift caused by magmatic intrusions counteract each other to produce the lower net subsidence rate.

California↗
USGS2002

Preeruptive inflation and surface interferometric coherence characteristics revealed by satellite radar interferometry at Makushin Volcano, Alaska: 1993-2000

Pilot reports in January 1995 and geologic field observations from the summer of 1996 indicate that a relatively small explosive eruption of Makushin, one of the more frequently active volcanoes in the Aleutian arc of Alaska, occurred on 30 January 1995. Several independent radar interferograms that each span the time period from October 1993 to September 1995 show evidence of ???7 cm of uplift centered on the volcano's east flank, which we interpret as preeruptive inflation of a ???7-km-deep magma source (??V = 0.022 km3). Subsequent interferograms for 1995-2000, a period that included no reported eruptive activity, show no evidence of additional ground deformation. Interferometric coherence at C band is found to persist for 3 years or more on lava flow and other rocky surfaces covered with short grass and sparsely distributed tall grass and for at least 1 year on most pyroclastic deposits. On lava flow and rocky surfaces with dense tall grass and on alluvium, coherence lasts for a few months. Snow and ice surfaces lose coherence within a few days. This extended timeframe of coherence over a variety of surface materials makes C band radar interferometry an effective tool for studying volcano deformation in Alaska and other similar high-latitude regions.

Journal of Geophysical Research B: Solid Earth↗
USGS2002

Post-1906 stress recovery of the San Andreas fault system calculated from three-dimensional finite element analysis

The M = 7.8 1906 San Francisco earthquake cast a stress shadow across the San Andreas fault system, inhibiting other large earthquakes for at least 75 years. The duration of the stress shadow is a key question in San Francisco Bay area seismic hazard assessment. This study presents a three-dimensional (3-D) finite element simulation of post-1906 stress recovery. The model reproduces observed geologic slip rates on major strike-slip faults and produces surface velocity vectors comparable to geodetic measurements. Fault stressing rates calculated with the finite element model are evaluated against numbers calculated using deep dislocation slip. In the finite element model, tectonic stressing is distributed throughout the crust and upper mantle, whereas tectonic stressing calculated with dislocations is focused mostly on faults. In addition, the finite element model incorporates postseismic effects such as deep afterslip and viscoelastic relaxation in the upper mantle. More distributed stressing and postseismic effects in the finite element model lead to lower calculated tectonic stressing rates and longer stress shadow durations (17–74 years compared with 7–54 years). All models considered indicate that the 1906 stress shadow was completely erased by tectonic loading no later than 1980. However, the stress shadow still affects present-day earthquake probability. Use of stressing rate parameters calculated with the finite element model yields a 7–12% reduction in 30-year probability caused by the 1906 stress shadow as compared with calculations not incorporating interactions. The aggregate interaction-based probability on selected segments (not including the ruptured San Andreas fault) is 53–70% versus the noninteraction range of 65–77%.

California↗
USGS2002

Fault structure and kinematics of the Long Valley Caldera region, California, revealed by high-accuracy earthquake hypocenters and focal mechanism stress inversions

We have determined high-resolution hypocenters for 45,000+ earthquakes that occurred between 1980 and 2000 in the Long Valley caldera area using a double-difference earthquake location algorithm and routinely determined arrival times. The locations reveal numerous discrete fault planes in the southern caldera and adjacent Sierra Nevada block (SNB). Intracaldera faults include a series of east/west-striking right-lateral strike-slip faults beneath the caldera's south moat and a series of more northerly striking strike-slip/normal faults beneath the caldera's resurgent dome. Seismicity in the SNB south of the caldera is confined to a crustal block bounded on the west by an east-dipping oblique normal fault and on the east by the Hilton Creek fault. Two NE-striking left-lateral strike-slip faults are responsible for most seismicity within this block. To understand better the stresses driving seismicity, we performed stress inversions using focal mechanisms with 50 or more first motions. This analysis reveals that the least principal stress direction systematically rotates across the studied region, from NE to SW in the caldera's south moat to WNW-ESE in Round Valley, 25 km to the SE. Because WNW-ESE extension is characteristic of the western boundary of the Basin and Range province, caldera area stresses appear to be locally perturbed. This stress perturbation does not seem to result from magma chamber inflation but may be related to the significant (???20 km) left step in the locus of extension along the Sierra Nevada/Basin and Range province boundary. This implies that regional-scale tectonic processes are driving seismic deformation in the Long Valley caldera.

California↗
USGS2003

A revised dislocation model of interseismic deformation of the Cascadia subduction zone

CAS3D‐2, a new three‐dimensional (3‐D) dislocation model, is developed to model interseismic deformation rates at the Cascadia subduction zone. The model is considered a snapshot description of the deformation field that changes with time. The effect of northward secular motion of the central and southern Cascadia forearc sliver is subtracted to obtain the effective convergence between the subducting plate and the forearc. Horizontal deformation data, including strain rates and surface velocities from Global Positioning System (GPS) measurements, provide primary geodetic constraints, but uplift rate data from tide gauges and leveling also provide important validations for the model. A locked zone, based on the results of previous thermal models constrained by heat flow observations, is located entirely offshore beneath the continental slope. Similar to previous dislocation models, an effective zone of downdip transition from locking to full slip is used, but the slip deficit rate is assumed to decrease exponentially with downdip distance. The exponential function resolves the problem of overpredicting coastal GPS velocities and underpredicting inland velocities by previous models that used a linear downdip transition. A wide effective transition zone (ETZ) partially accounts for stress relaxation in the mantle wedge that cannot be simulated by the elastic model. The pattern of coseismic deformation is expected to be different from that of interseismic deformation at present, 300 years after the last great subduction earthquake. The downdip transition from full rupture to no slip should take place over a much narrower zone.

Journal of Geophysical Research B: Solid Earth↗
USGS2002

Undrained poroelastic response of sandstones to deviatoric stress change

Deformation of porous crustal rock through diagenesis, tectonic loading, or other processes can change pore volume and affect fluid pressure. The largest stress-induced pore pressure changes occur when fluid is trapped in pores in an “undrained” condition. We have measured the undrained poroelastic response of two sandstones to changes in mean and deviatoric stress. Pore pressure was found to respond to mean stress σ m in the usual manner: Δ p = B Δσ m ( B ranging from 0.4 to 0.7), nearly independent of the ambient deviatoric stress state. However, variations in deviatoric stress (σ d = (σ 1 − σ 3 )/2) at constant mean stress were also found to induce a reversible (elastic) pore pressure response to stress levels up to and exceeding 80% failure stress (i.e., Δ p = = const.). The coefficient η became more negative with increasing deviatoric stress level in sandstone and Ottawa sand samples. That is, η represents a dilatant response where increased deviatoric stress causes a decrease in pore pressure. The poroelastic response to deviatoric stress is explained in terms of anisotropic matrix stiffening due to closure of crack-like pore space or flattening of grain contacts at high ambient stress levels and can be important in calculations of earthquake stress transfer.

Journal of Geophysical Research B: Solid Earth↗
USGS2002

Concordant paleolatitudes for Neoproterozoic ophiolitic rocks of the Trinity Complex, Klamath Mountains, California

New paleomagnetic results from the eastern Klamath Mountains of northern California show that Neoproterozoic rocks of the Trinity ophiolitic complex and overlying Middle Devonian volcanic rocks are latitudinally concordant with cratonal North America. Combining paleomagnetic data with regional geologic and faunal evidence suggests that the Trinity Complex and related terranes of the eastern Klamath plate were linked in some fashion to the North American craton throughout that time, but that distance between them may have varied considerably. A possible model that is consistent with our paleomagnetic results and the geologic evidence is that the Trinity Complex formed and migrated parallel to paleolatitude in the basin between Laurasia and Australia–East Antarctica as the Rodinian supercontinent began to break up. It then continued to move parallel to paleolatitude at least through Middle Devonian time. Although the eastern Klamath plate served as a nucleus against which more western components of the Klamath Mountains province amalgamated, the Klamath superterrane was not accreted to North America until Early Cretaceous time.

California↗
USGS2002

Episodic thermal perturbations associated with groundwater flow: An example from Kilauea Volcano, Hawaii

Temperature measurements in deep drill holes on volcano summits or upper flanks allow a quantitative analysis of groundwater induced heat transport within the edifice. We present a new temperature-depth profile from a deep well on the summit of Kilauea Volcano, Hawaii, and analyze it in conjunction with a temperature profile measured 26 years earlier. We propose two groundwater flow models to interpret the complex temperature profiles. The first is a modified confined lateral flow model (CLFM) with a continuous flux of hydrothermal fluid. In the second, transient flow model (TFM), slow conductive cooling follows a brief, advective heating event. We carry out numerical simulations to examine the timescales associated with each of the models. Results for both models are sensitive to the initial conditions, and with realistic initial conditions it takes between 750 and 1000 simulation years for either model to match the measured temperature profiles. With somewhat hotter initial conditions, results are consistent with onset of a hydrothermal plume ∼550 years ago, coincident with initiation of caldera subsidence. We show that the TFM is consistent with other data from hydrothermal systems and laboratory experiments and perhaps is more appropriate for this highly dynamic environment. The TFM implies that volcano-hydrothermal systems may be dominated by episodic events and that thermal perturbations may persist for several thousand years after hydrothermal flow has ceased.

Hawaii↗
USGS2003

Importance of a stochastic distribution of floods and erosion thresholds in the bedrock river incision problem

Fluvial erosion of bedrock occurs during occasional flood events when boundary shear stress exceeds a critical threshold to initiate incision. Therefore efforts to model the evolution of topography over long timescales should include an erosion threshold and should be driven by a stochastic distribution of erosive events. However, most bedrock incision models ignore the threshold as a second‐order detail. In addition, climate is poorly represented in most landscape evolution models, so the quantitative relationship between erosion rate and measurable climatic variables has been elusive. Here we show that the presence of an erosion threshold, when combined with a well‐constrained, probabilistic model of storm and flood occurrence, has first‐order implications for the dynamics of river incision in tectonically active areas. First, we make a direct calculation of the critical shear stress required to pluck bedrock blocks for a field site in New York. Second, we apply a recently proposed stochastic, threshold, bedrock incision model to a series of streams in California, with known tectonic and climatic forcing. Previous work in the area has identified a weak relationship between channel gradient or relief and rock uplift rate that is not easily explained by simpler detachment‐limited models. The results with the stochastic threshold model show that even low erosion thresholds, which are exceeded in steep channels during high‐frequency flood events, fundamentally affect the predicted relationship between gradient and uplift rate in steady state rivers, in a manner consistent with the observed topography. This correspondence between theory and data is, however, nonunique; models in which a thin alluvial cover may act to inhibit channel incision in the low uplift rate zone also provide plausible explanations for the observed topography. Third, we explore the broader implications of the stochastic threshold model to the development of fluvial topography in active tectonic settings. We suggest that continued field applications of geomorphic models, including physically meaningful thresholds and stochastic climate distributions, are required to advance our knowledge of interactions among surficial, climatic, and crustal processes.

California↗
USGS2002

Waveform inversion of oscillatory signatures in long-period events beneath volcanoes

The source mechanism of long-period (LP) events is examined using synthetic waveforms generated by the acoustic resonance of a fluid-filled crack. We perform a series of numerical tests in which the oscillatory signatures of synthetic LP waveforms are used to determine the source time functions of the six moment tensor components from waveform inversions assuming a point source. The results indicate that the moment tensor representation is valid for the odd modes of crack resonance with wavelengths 2 L / n , 2 W / n , n = 3, 5, 7, …, where L and W are the crack length and width, respectively. For the even modes with wavelengths 2 L / n , 2 W / n , n = 2, 4, 6, …, a generalized source representation using higher-order tensors is required, although the efficiency of seismic waves radiated by the even modes is expected to be small. We apply the moment tensor inversion to the oscillatory signatures of an LP event observed at Kusatsu-Shirane Volcano, central Japan. Our results point to the resonance of a subhorizontal crack located a few hundred meters beneath the summit crater lakes. The present approach may be useful to quantify the source location, geometry, and force system of LP events, and opens the way for moment tensor inversions of tremor.

Journal of Geophysical Research B: Solid Earth↗
USGS2002

Fire dynamics and implications for nitrogen cycling in boreal forests

We used a dynamic, long-term mass balance approach to track cumulative carbon (C) and nitrogen (N) losses to fire in boreal Manitoba over the 6500 years since deglaciation. Estimated C losses to decomposition and fire, combined with measurements of N pools in mature and burned forest floors, suggest that loss of N by combustion has likely resulted in a long-term loss that exceeds the amount of N stored in soil today by 2 to 3 times. These estimates imply that biological N fixation rates could be as high as 5 to 10 times atmospheric deposition rates in boreal regions. At the site scale, the amount of N lost is due to N content of fuels, which varies by stand type and fire severity, which in turn vary with climate and fire dynamics. The interplay of fire frequency, fire severity, and N partitioning during regrowth are important for understanding rates and sustainability of nutrient and carbon cycling over millenia and over broad regions.

Manitoba↗
USGS2002

Stable isotope composition of waters in the Great Basin, United States 1. Air-mass trajectories

Isentropic trajectories, calculated using the NOAA/Climate Monitoring and Diagnostics Laboratory's isentropic transport model, were used to determine air-parcel origins and the influence of air mass trajectories on the isotopic composition of precipitation events that occurred between October 1991 and September 1993 at Cedar City, Utah, and Winnemucca, Nevada. Examination of trajectories that trace the position of air parcels backward in time for 10 days indicated five distinct regions of water vapor origin: (1) Gulf of Alaska and North Pacific, (2) central Pacific, (3) tropical Pacific, (4) Gulf of Mexico, and (5) continental land mass. Deuterium (??D) and oxygen-18 (??18O) analyses were made of precipitation representing 99% of all Cedar City events. Similar analyses were made on precipitation representing 66% of the precipitation falling at Winnemucca during the same period. The average isotopic composition of precipitation derived from each water vapor source was determined. More than half of the precipitation that fell at both sites during the study period originated in the tropical Pacific and traveled northeast to the Great Basin; only a small proportion traversed the Sierra Nevada. The isotopic composition of precipitation is determined by air-mass origin and its track to the collection station, mechanism of droplet formation, reequilibration within clouds, and evaporation during its passage from cloud to ground. The Rayleigh distillation model can explain the changes in isotopic composition of precipitation as an air mass is cooled pseudo-adiabatically during uplift. However, the complicated processes that take place in the rapidly convecting environment of cumulonimbus and other clouds that are common in the Great Basin, especially in summer, require modification of this model because raindrops that form in the lower portion of those clouds undergo isotopic change as they are elevated to upper levels of the clouds from where they eventually drop to the ground.

Journal of Geophysical Research D: Atmospheres↗
USGS2002

Stable isotope compositions of waters in the Great Basin, United States 2. Modern precipitation

Precipitation was collected between 1991 and 1997 at 41 locations within and adjacent to parts of the Great Basin lying in California, Oregon, Nevada, and Utah. These samples were analyzed for their deuterium (??D) and oxygen-18 (??18O) contents. Separate collections were made of summer and winter season precipitation at stations ranging in elevation from -65 m to 3246 m. The ??D per mil values of stations that were closely spaced but at different elevations showed an average ??D decrease of approximately 10???/km rise in elevation. Data for all samples representing winter precipitation, when plotted on a ??D versus ??18O plot, fall close to the Meteoric Water Line (??D = 8 ??18O + 10); samples representing summer precipitation define a line of slightly lower slope due to evaporation of the raindrops during their passage from cloud to ground. Comparison of our 1991-1997 ??D data with those from the same three stations reported by an earlier study in the southeastern California shows seasonal differences ranging from 0 per mil to 19??? (average: 15) and annual differences ranging from 0 to 13 per mil (average: 2), illustrating the degree of annual and seasonal variability in this region. When contoured, the ??D values display gradients indicating a north to northwest decrease in deuterium, with values ranging from -60 to -125??? in winter precipitation and from -40 to -110??? in summer precipitation. These gradient trends can be explained by the predominance of air mass trajectories originating in the tropical Pacific, the Gulf of California, and (in summer) the Gulf of Mexico.

Journal of Geophysical Research D: Atmospheres↗
USGS2002

Stable isotope compositions of waters in the Great Basin, United States 3. Comparison of groundwaters with modern precipitation

Groundwater samples from wells and springs, scattered over most of the Great Basin province, were collected and analyzed for their isotopic makeup. They were augmented by previously published isotopic data on groundwaters from southeast California and by several hundred unpublished isotopic analyses. The ratio of 2H (deuterium, D) to 1H, in water samples from valleys in parts of California, Idaho, Nevada, Oregon, and Utah, are here compared with the winter, summer, and annual isotopic compositions of precipitation falling in or near the sampled areas. The main goal of this study was to identify basins where the groundwaters have isotopic compositions that are "lighter" (depleted in the heavier isotope, D) relative to modern winter precipitation. Where these basins do not adjoin substantially higher terrain, we consider those light groundwaters to be of Pleistocene age and thus more than 10,000 years old. Where the groundwater is 10 to 19??? lighter than local winter precipitation, we consider it to be possibly an indication of Pleistocene water; where the ??D makeup is >20??? lighter, we consider it to be probably Pleistocene water. More than 80 sites underlain by waters of possible or probable Pleistocene age were identified.

Journal of Geophysical Research D: Atmospheres↗
USGS2002

Ice core evidence of rapid air temperature increases since 1960 in alpine areas of the Wind River Range, Wyoming, United States

Site-specific transfer functions relating delta oxygen 18 (δ 18 O) values in snow to the average air temperature ( T A ) during storms on Upper Fremont Glacier (UFG) were used in conjunction with δ 18 O records from UFG ice cores to reconstruct long-term trends in air temperature from alpine areas in the Wind River Range, Wyoming. Transfer functions were determined by using data collected from four seasonal snowpacks (1989–1990, 1997–1998, 1998–1999, and 1999–2000). The timing and amount of each storm was determined from an automated snowpack telemetry (SNOTEL) site, 22 km northeast of UFG, and ∼1060 m in elevation below UFG. Statistically significant and positive correlations between δ 18 O values in the snow and T A were consistently found in three of the four seasonal snowpacks. The snowpack with the poor correlation was deposited in 1997–1998 during the 1997–1998 El Niño Southern Oscillation (ENSO). An ultrasonic snow-depth sensor installed on UFG provided valuable insights into site-specific storms and postdepositional processes that occur on UFG. The timing of storms recorded at the UFG and Cold Springs SNOTEL sites were similar; however, selected storms did not correlate. Snow from storms occurring after mid-October and followed by high winds was most susceptible to redeposition of snow. This removal of lower temperature snowfall could potentially bias the δ 18 O values preserved in ice core records to environmental conditions reflecting higher air temperatures and lower wind speeds. Transfer functions derived from seasonal snow cover on UFG were used to reconstruct T A values from δ 18 O values determined from two ice cores collected from UFG. Reconstructed air temperatures from the ice core data indicate an increase in T A of ∼3.5°C from the mid-1960s to the early 1990s in the alpine areas of northwestern Wyoming. Reconstructed T A from the ice core records between the end of the Little Ice Age (LIA), mid-1800s, and the early 1990s indicate a T A increase of ∼5°C. The historically reconstructed T A values from the UFG were significantly higher than the global average observed during the 20th Century but were in agreement with T A increases observed at selected, high-altitude and high-latitude sites in other parts of the world. Additional research is required to determine if part of the observed trend toward heavier δ 18 O values in ice from the UFG since the LIA (and increased T A ) is due to an increased proportion of snowfall from southerly storm tracks and moisture sources, as seems to have been the situation in 1997–1998.

Wyoming↗
USGS2002

Modeling soil thermal and carbon dynamics of a fire chronosequence in interior Alaska

In this study, the dynamics of soil thermal, hydrologic, and ecosystem processes were coupled to project how the carbon budgets of boreal forests will respond to changes in atmospheric CO 2 , climate, and fire disturbance. The ability of the model to simulate gross primary production and ecosystem respiration was verified for a mature black spruce ecosystem in Canada, the age-dependent pattern of the simulated vegetation carbon was verified with inventory data on aboveground growth of Alaskan black spruce forests, and the model was applied to a postfire chronosequence in interior Alaska. The comparison between the simulated soil temperature and field-based estimates during the growing season (May to September) of 1997 revealed that the model was able to accurately simulate monthly temperatures at 10 cm ( R > 0.93) for control and burned stands of the fire chronosequence. Similarly, the simulated and field-based estimates of soil respiration for control and burned stands were correlated ( R = 0.84 and 0.74 for control and burned stands, respectively). The simulated and observed decadal to century-scale dynamics of soil temperature and carbon dynamics, which are represented by mean monthly values of these variables during the growing season, were correlated among stands ( R = 0.93 and 0.71 for soil temperature at 20- and 10-cm depths, R = 0.95 and 0.91 for soil respiration and soil carbon, respectively). Sensitivity analyses indicate that along with differences in fire and climate history a number of other factors influence the response of carbon dynamics to fire disturbance. These factors include nitrogen fixation, the growth of moss, changes in the depth of the organic layer, soil drainage, and fire severity.

Alaska↗
USGS2001

Dating the Vostok ice core record by importing the Devils Hole chronology

The development of an accurate chronology for the Vostok record continues to be an open research question because these invaluable ice cores cannot be dated directly. Depth-to-age relationships have been developed using many different approaches, but published age estimates are inconsistent, even for major paleoclimatic events. We have developed a chronology for the Vostok deuterium paleotemperature record using a simple and objective algorithm to transfer ages of major paleoclimatic events from the radiometrically dated 500,000-year δ 18 O-paleotemperature record from Devils Hole, Nevada. The method is based only on a strong inference that major shifts in paleotemperature recorded at both locations occurred synchronously, consistent with an atmospheric teleconnection. The derived depth-to-age relationship conforms with the physics of ice compaction, and internally produces ages for climatic events 5.4 and 11.24 which are consistent with the externally assigned ages that the Vostok team needed to assume in order to derive their most recent chronology, GT4. Indeed, the resulting V-DH chronology is highly correlated with GT4 because of the unexpected correspondence even in the timing of second-order climatic events that were not constrained by the algorithm. Furthermore, the algorithm developed herein is not specific to this problem; rather, the procedure can be used whenever two paleoclimate records are proxies for the same physical phenomenon, and paleoclimatic conditions forcing the two records can be considered to have occurred contemporaneously. The ability of the algorithm to date the East Antarctic Dome Fuji core is also demonstrated.

Journal of Geophysical Research D: Atmospheres↗
USGS2002

Thermal infrared spectroscopy of experimentally shocked anorthosite and pyroxenite: Implications for remote sensing of Mars

The feldspar and pyroxene mineralogies on Mars revealed by the Thermal Emission Spectrometer (TES) on Mars Global Surveyor likely record a variety of shock effects, as suggested by petrologic analyses of the Martian meteorites and the abundance of impact craters on the planet's surface. To study the effects of shock pressures on thermal infrared spectra of these minerals, we performed shock recovery experiments on orthopyroxenite and anorthosite samples from the Stillwater Complex (Montana) over peak pressures from 17 to 63 GPa. We acquired emissivity and hemispherical reflectance spectra (350–1400 cm −1 ; ∼7–29 μm) of both coherent chips and fine-grained powders of shocked and unshocked samples. These spectra are more directly comparable to remotely sensed data of Mars (e.g., TES) than previously acquired absorption or transmission spectra of shocked minerals. The spectra of experimentally shocked feldspar show systematic changes with increasing pressure due to depolymerization of the silica tetrahedra. For the spectra of chips, this includes the disappearance of small bands in the 500–650 cm −1 region and a strong band at 1115 cm −1 , and changes in positions of a strong band near 940 cm −1 and the Christiansen feature near 1250 cm −1 . Spectra of the shocked powders show the gradual disappearance of a transparency feature near 830 cm −1 . Fewer changes are observed in the pyroxene spectra at pressures as high as 63 GPa. Spectra of experimentally shocked minerals will help identify more precisely the mineralogy of rocks and soils not only from TES but also from Mars instruments such as miniTES and THEMIS.

Journal of Geophysical Research E: Planets↗