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Iodine-129 in the eastern Snake River Plain aquifer at and near the Idaho National Laboratory, Idaho, 2010-12

From 1953 to 1988, approximately 0.941 curies of iodine-129 ( 129 I) were contained in wastewater generated at the Idaho National Laboratory (INL) with almost all of this wastewater discharged at or near the Idaho Nuclear Technology and Engineering Center (INTEC). Most of the wastewater containing 129 I was discharged directly into the eastern Snake River Plain (ESRP) aquifer through a deep disposal well until 1984; lesser quantities also were discharged into unlined infiltration ponds or leaked from distribution systems below the INTEC. During 2010–12, the U.S. Geological Survey in cooperation with the U.S. Department of Energy collected groundwater samples for 129 I from 62 wells in the ESRP aquifer to track concentration trends and changes for the carcinogenic radionuclide that has a 15.7 million-year half-life. Concentrations of 129 I in the aquifer ranged from 0.0000013±0.0000005 to 1.02±0.04 picocuries per liter (pCi/L), and generally decreased in wells near the INTEC, relative to previous sampling events. The average concentration of 129 I in groundwater from 15 wells sampled during four different sample periods decreased from 1.15 pCi/L in 1990–91 to 0.173 pCi/L in 2011–12. All but two wells within a 3-mile radius of the INTEC showed decreases in concentration, and all but one sample had concentrations less than the U.S. Environmental Protection Agency maximum contaminant level of 1 pCi/L. These decreases are attributed to the discontinuation of disposal of 129 I in wastewater and to dilution and dispersion in the aquifer. The decreases in 129 I concentrations, in areas around INTEC where concentrations increased between 2003 and 2007, were attributed to less recharge near INTEC either from less flow in the Big Lost River or from less local snowmelt and anthropogenic sources. Although wells near INTEC sampled in 2011–12 showed decreases in 129 I concentrations compared with previously collected data, some wells south and east of the Central Facilities Area, near the site boundary, and south of the INL showed small increases. These slight increases are attributed to variable discharge rates of wastewater that eventually moved to these well locations as a pulse of water from a particular disposal period. Wells sampled for the first time around the Naval Reactors Facility had 129 I concentrations slightly greater than background concentrations in the ESRP aquifer. These concentrations are attributed to possible leakage from landfills at the Naval Reactors Facility or seepage from air emission deposits from INTEC, or both. In 2012, the U.S. Geological Survey collected discrete groundwater samples from 25 zones in 11 wells equipped with multilevel monitoring systems to help define the vertical distribution of 129 I in the aquifer. Concentrations ranged from 0.000006±0.000004 to 0.082±0.003 pCi/L. Two new wells completed in 2012 showed variability of up to one order of magnitude of concentrations of 129 I among various zones. Two other wells showed similar concentrations of 129 I in all three zones sampled. Concentrations were well less than the maximum contaminant level in all zones.

Idaho↗

Evaluating the effectiveness of an ultrasonic acoustic deterrent for reducing bat fatalities at wind turbines

Large numbers of bats are killed by wind turbines worldwide and minimizing fatalities is critically important to bat conservation and acceptance of wind energy development. We implemented a 2-year study testing the effectiveness of an ultrasonic acoustic deterrent for reducing bat fatalities at a wind energy facility in Pennsylvania. We randomly selected control and treatment turbines that were searched daily in summer and fall 2009 and 2010. Estimates of fatality, corrected for field biases, were compared between treatment and control turbines. In 2009, we estimated 21–51% fewer bats were killed per treatment turbine than per control turbine. In 2010, we determined an approximate 9% inherent difference between treatment and control turbines and when factored into our analysis, variation increased and between 2% more and 64% fewer bats were killed per treatment turbine relative to control turbines. We estimated twice as many hoary bats were killed per control turbine than treatment turbine, and nearly twice as many silver-haired bats in 2009. In 2010, although we estimated nearly twice as many hoary bats and nearly 4 times as many silver-haired bats killed per control turbine than at treatment turbines during the treatment period, these only represented an approximate 20% increase in fatality relative to the pre-treatment period for these species when accounting for inherent differences between turbine sets. Our findings suggest broadband ultrasound broadcasts may reduce bat fatalities by discouraging bats from approaching sound sources. However, effectiveness of ultrasonic deterrents is limited by distance and area ultrasound can be broadcast, in part due to rapid attenuation in humid conditions. We caution that an operational deterrent device is not yet available and further modifications and experimentation are needed. Future efforts must also evaluate cost-effectiveness of deterrents in relation to curtailment strategies to allow a cost-benefit analysis for mitigating bat fatalities.

Pennsylvania↗

Federal lands greenhouse emissions and sequestration in the United States—Estimates for 2005–14

In January 2016, the Secretary of the U.S. Department of the Interior tasked the U.S. Geological Survey (USGS) with producing a publicly available and annually updated database of estimated greenhouse gas emissions associated with the extraction and use (predominantly some form of combustion) of fossil fuels from Federal lands. In response, the USGS has produced estimates of the greenhouse gas emissions resulting from the extraction and end-use combustion of fossil fuels produced on Federal lands in the United States, as well as estimates of ecosystem carbon emissions and sequestration on those lands. American Indian and Tribal lands were not included in this analysis. The emissions estimates span a 10-year period (2005–14) and are reported for 28 States and two offshore areas. Nationwide emissions from fossil fuels produced on Federal lands in 2014 were 1,279.0 million metric tons of carbon dioxide equivalent (MMT CO 2 Eq.) for carbon dioxide (CO 2 ), 47.6 MMT CO 2 Eq. for methane (CH 4 ), and 5.5 MMT CO 2 Eq. for nitrous oxide (N 2 O). Compared to 2005, the 2014 totals represent decreases in emissions for all three greenhouse gases (decreases of 6.1 percent for CO 2 , 10.5 percent for CH 4 , and 20.3 percent for N 2 O). Emissions from fossil fuels produced on Federal lands represent, on average, 23.7 percent of national emissions for CO 2 , 7.3 percent for CH 4 , and 1.5 percent for N 2 O over the 10 years included in this estimate. In 2005, Federal lands of the conterminous United States stored 82,289 MMT CO 2 Eq. in terrestrial ecosystems. By 2014, carbon storage, or sequestration, was estimated at 83,600 MMT CO 2 Eq., representing an increase of 1.6 percent, or 1,311 MMT CO 2 Eq. Soils stored most of the ecosystem carbon (63 percent), followed by live vegetation (26 percent) and dead organic matter (11 percent). The rate of net carbon uptake in ecosystems ranged from a sink (sequestration) of 475 million metric tons of carbon dioxide per year (MMT CO 2 Eq./yr) to a source (emission) of 51 MMT CO 2 Eq./yr because of annual variability in climate and weather, rates of land-use and land-cover change, and wildfire frequency, among other factors. At the national level, the USGS estimates that terrestrial ecosystems (forests, grasslands, and shrublands) on Federal lands sequestered an average of 195 MMT CO 2 Eq./yr between 2005 and 2014, offsetting approximately 15 percent of the CO 2 emissions resulting from the extraction of fossil fuels on Federal lands and their end-use combustion. The USGS estimates presented in this report represent a first-of-its-kind accounting for the emissions resulting from fossil fuel extraction on Federal lands and the end-use combustion of those fuels, as well as for the sequestration of carbon in terrestrial ecosystems on Federal lands. The net CO 2 emissions estimate, which is the difference between the emitted and sequestered CO 2 , provides an informative combined result describing the emissions (fossil fuel extraction and end-use combustion) associated with a State’s Federal lands and sequestration on those same lands. The estimates included in this report can provide context for future energy decisions, as well as a basis to track change in the future.

Scientific Investigations Report↗

Distal facies variability within the Upper Triassic part of the Otuk Formation in northern Alaska

The Triassic-Jurassic Otuk Formation is a potentially important source rock in allochthonous structural positions in the northern foothills of the Brooks Range in the North Slope of Alaska. This study focuses on three localities of the Upper Triassic (Norian) limestone member, which form a present-day, 110-km-long, east-west transect in the central Brooks Range. All three sections are within the structurally lowest Endicott Mountain allochthon and are interpreted to have been deposited along a marine outer shelf with a ramp geometry. The uppermost limestone member of the Otuk was chosen for this study in order to better understand lateral and vertical variability within carbonate source rocks, to aid prediction of organic richness, and ultimately, to evaluate the potential for these units to act as continuous (or unconventional) reservoirs. At each locality, 1 to 4 m sections of the limestone member were measured and sampled in detail to capture fine-scale features. Hand sample and thin section descriptions reveal four major microfacies in the study area, and one diagenetically recrystallized microfacies. Microfacies 1 and 2 are interpreted to represent redeposition of material by downslope transport, whereas microfacies 3 and 4 have high total organic carbon (TOC) values and are classified as primary depositional organofacies. Microfacies 3 is interpreted to have been deposited under primarily high productivity conditions, with high concentrations of radiolarian tests. Microfacies 4 was deposited under the lowest relative-oxygen conditions, but abundant thin bivalve shells indicate that the sediment-water interface was probably not anoxic. The Otuk Formation is interpreted to have been deposited outboard of a southwest-facing ramp margin, with the location of the three limestone outcrops likely in relatively close proximity during deposition. All three sections have evidence of transported material, implying that the Triassic Alaskan Basin was not a low-energy, deep-water setting, but rather a dynamic system with intermittent, yet significant, downslope flow. Upwelling played an important role in the small-scale vertical variability in microfacies. The zone of upwelling and resultant oxygen-minimum zone may have migrated across the ramp during fourth- or fifth-order sea-level changes.

Alaska↗

Lithium use in batteries

Lithium has a number of uses but one of the most valuable is as a component of high energy-density rechargeable lithium-ion batteries. Because of concerns over carbon dioxide footprint and increasing hydrocarbon fuel cost (reduced supply), lithium may become even more important in large batteries for powering all-electric and hybrid vehicles. It would take 1.4 to 3.0 kilograms of lithium equivalent (7.5 to 16.0 kilograms of lithium carbonate) to support a 40-mile trip in an electric vehicle before requiring recharge. This could create a large demand for lithium. Estimates of future lithium demand vary, based on numerous variables. Some of those variables include the potential for recycling, widespread public acceptance of electric vehicles, or the possibility of incentives for converting to lithium-ion-powered engines. Increased electric usage could cause electricity prices to increase. Because of reduced demand, hydrocarbon fuel prices would likely decrease, making hydrocarbon fuel more desirable. In 2009, 13 percent of worldwide lithium reserves, expressed in terms of contained lithium, were reported to be within hard rock mineral deposits, and 87 percent, within brine deposits. Most of the lithium recovered from brine came from Chile, with smaller amounts from China, Argentina, and the United States. Chile also has lithium mineral reserves, as does Australia. Another source of lithium is from recycled batteries. When lithium-ion batteries begin to power vehicles, it is expected that battery recycling rates will increase because vehicle battery recycling systems can be used to produce new lithium-ion batteries.

Circular↗

Patterns of acoustical activity of bats prior to and following White-nose Syndrome occurrence

White-nose Syndrome (WNS), a wildlife health concern that has decimated cave-hibernating bat populations in eastern North America since 2006, began affecting source-caves for summer bat populations at Fort Drum, a U.S. Army installation in New York in the winter of 2007–2008. As regional die-offs of bats became evident, and Fort Drum's known populations began showing declines, we examined whether WNS-induced change in abundance patterns and seasonal timing of bat activity could be quantified using acoustical surveys, 2003–2010, at structurally uncluttered riparian–water habitats (i.e., streams, ponds, and wet meadows). As predicted, we observed significant declines in overall summer activity between pre-WNS and post-WNS years for little brown bats Myotis lucifugus , northern bats M. septentrionalis , and Indiana bats M. sodalis . We did not observe any significant change in activity patterns between pre-WNS and post-WNS years for big brown bats Eptesicus fuscus , eastern red bats Lasiurus borealis , or the small number of tri-colored bats Perimyotis subflavus . Activity of silver-haired bats Lasionycteris noctivagans increased from pre-WNS to post-WNS years. Activity levels of hoary bats Lasiurus cinereus significantly declined between pre- and post-WNS years. As a nonhibernating, migratory species, hoary bat declines might be correlated with wind-energy development impacts occurring in the same time frame rather than WNS. Intraseason activity patterns also were affected by WNS, though the results were highly variable among species. Little brown bats showed an overall increase in activity from early to late summer pre-WNS, presumably due to detections of newly volant young added to the local population. However, the opposite occurred post-WNS, indicating that reproduction among surviving little brown bats may be declining. Our data suggest that acoustical monitoring during the summer season can provide insights into species' relative abundance on the landscape as affected by the occurrence of WNS.

Journal of Fish and Wildlife Management↗

Sediment characterization and dynamics in Lake Pontchartrain, Louisiana

Lake Pontchartrain in southeastern Louisiana is the largest of several shallow estuaries that together cover over 15,000 km 2 . Wetlands, forests, and large urban areas surround the lake. Primary transport mechanisms of sediments to Lake Pontchartrain include urban runoff, major diversions of the Mississippi River, discharge from streams along the north and west shores, and tidal circulation. Sediments deposited in Lake Pontchartrain are subjected to resuspension and mixing by natural and human activities. Bioturbation and water turbulence throughout the lake are the major mixing agents, and mechanical shell dredging has reworked much of the lake bottom over the last century. Sediment characterization through direct sampling and geophysical surveys indicates that these processes continually rework the top meter of sediment. The lake receives discharge from roadways and industrial and agricultural sources. Contaminants from these sources accumulate in the lake sediments and are an important contributor to the degradation of the estuary. Decline in populations of various benthic organisms, such as shrimp and clams, has been documented in the lake. To characterize the health of this important estuary, the U.S. Geological Survey (USGS) conducted a comprehensive evaluation of the geology, geomorphology, coastal processes, and environmental condition of the Pontchartrain Basin from 1994 to 1997. This report presents an assessment of sediment distribution and quality using a multidisciplinary approach to characterize the influence of various physical and chemical parameters: nearsurface stratigraphy, major trace metal concentrations (Cu, Pb, Zn, and Ni), and short-lived radionuclides ( 210 Pb, 7 Be, and 137 Cs). The results are compared with water-circulation patterns to determine high-resolution sedimentation patterns in the lake. The data show a significant increase in trace metals in the top 1 m of lake sediments. Above this horizon, pollen analysis indicates a correlation with land clearing in the area, a proxy for increasing human development of the surrounding landscape and an increase in surface run-off. The data also show that the top meter of sediment undergoes frequent resuspension during high-energy circulation events and via circulation gyres in the lake. This regular turnover does not allow stratification of recently deposited sediments, restricting the sequestration of contaminated material that enters the lake.

Louisiana↗

Coal and coalbed-methane resources in the Appalachian and Black Warrior basins: maps showing the distribution of coal fields, coal beds, and coalbed-methane fields

The maps contained in this chapter show the locations of coal fields, coal beds assessed by the U.S. Geological Survey (USGS) in 2000, and coalbed-methane fields in the central and southern Appalachian basin study areas, which include the coal-producing parts of the Black Warrior basin. The maps were compiled and modified from a variety of sources such as Tully (1996), Northern and Central Appalachian Basin Coal Regions Assessment Team (2001), Hatch and others (2003), Milici (2004), and unpublished data from the State geological surveys of Pennsylvania, West Virginia, Virginia, and Alabama. The terms “coalbed methane” and “coal-bed gas” are used interchangeably in this report. All of the figures are located at the end of this report. The Appalachian basin historically has been subdivided into three coal regions on the basis of regional geologic structure and stratigraphy: the northern region in western Pennsylvania, eastern Ohio, western Maryland, and northern West Virginia; the central region in west-central and southwestern West Virginia, eastern Kentucky, northern Tennessee, and southwestern Virginia; and the southern region in southern Tennessee, northern Alabama, and northwestern Georgia. The Appalachian basin is one of the most important coal-producing regions in the Nation and the world, and coal has been mined there throughout the last three centuries. The coal is primarily used within the Eastern United States for electrical power generation, but some of it is suitable for metallurgical uses. In 2008, the Appalachian basin produced about 320 million short tons of coal from 1,278 underground and surface coal mines (Energy Information Agency, 2009a). Coalbed-methane production in the Appalachian basin coal regions is an increasingly important resource. In 2008, 247 billion cubic feet (bcf) of coalbed methane was produced in the basin from Alabama (107 bcf), Virginia (101 bcf), West Virginia (28 bcf), and Pennsylvania (11 bcf) (Energy Information Agency, 2009b). Coalbed-methane exploration is ongoing in all of the States in the Appalachian basin coal regions, and production is expected to increase. The study area for most reports in this volume is the Appalachian basin. The term “Appalachian basin study area” (shortened from “Appalachian basin geologic framework study area”) includes all of the Appalachian Basin Province (Province 67) and part of the neighboring Black Warrior Basin Province (Province 65) of Dolton and others (1995). The boundaries for these two provinces and the study area are shown on figure 1.

Appalachian basin↗

Resin rodlets in shale and coal (Lower Cretaceous), Baltimore Canyon Trough

Rodlets, occurring in shale and coal (uppermost Berriasian to middle Aptian, Lower Cretaceous), were identified from drill cuttings taken from depths between 9330 ft (2844 m) and 11, 460 ft (3493 m) in the Texaco et al., Federal Block 598, No. 2 well, in the Baltimore Canyon Trough. Under the binocular microscope, most of the rodlets appear black, but a few are reddish brown, or brownish and translucent on thin edges. They range in diameter from about 0.4 to 1.7 mm and are commonly flattened. The rodlets break with a conchoidal fracture, and some show an apparent cellular cast on their longitudinal surfaces. When polished and viewed in reflected light, the rodlets appear dark gray and have an average random reflectance of less than 0.1% whereas mean maximum reflectances are 0.48–0.55% for vitrinite in the associated shale and coal. These vitrinite reflectances indicate either subbituminous A or high-volatile C bituminous coal. The rodlets fluoresce dull gray yellow to dull yellow. The scanning electron microscope (SEM) and light microscope reveal the presence of swirl-like features in the rodlet interiors. Minerals associated with the rodlets occur as sand-size grains attached to the outer surface, as finely disseminated interior grains, and as fracture fillings. Electron microprobe and SEM-energy-dispersive X-ray (EDX) anlayses indicate that the minerals are dominantly clays (probably illite and chlorite) and iron disulfide; calcium carbonate, silicon dioxide, potassium aluminum silicate (feldspar), titanium dioxide, zinc sulfide, and iron sulfate minerals have been also identified. The rodlets were analyzed directly for C, H, N, O, and total S and are interpreted as true resins on the basis of C and H contents that range from 75.6 to 80.3 and from 7.4 to 8.7 wt. % (dry, ash-free basis), respectively. Elemental and infrared data support a composition similar to that of resinite from bituminous coal. Elements determined to be organically associated in the rodlets include S (0.2–0.5 wt.%), Cl (0.03–0.1 wt.%), and Si (0.05–0.08 wt.%). The ash content of the resin rodlets ranges from 4 to 24 wt.% and averages 12 wt.%. Total sulfur contents range from 1.7 to 3.6 wt.%. Resins of fossil plants are known to have little or no sulfur and ash; therefore, these data and the presence of minerals in fractures indicate that most of the sulfur and mineral matter were introduced into the resin partly or wholly after the time of brittle fracture of the resin. The probable source of the resin rodlets is fossil pinaceous conifer cones, which are known to have resin canals as much as 2400 μm in diameter.

International Journal of Coal Geology↗

Finite-fault analysis of the 1979 March 14 Petatlan, Mexico, earthquake using teleseismic P waveforms

Vertical, teleseismic P waves recorded for the 1979 March 14 Petatlan, Mexico, earthquake were used to derive the distribution of coseismic slip using a linear finite-fault inversion scheme that solves for the amount of slip in each of a series of consecutive time windows. Data recorded by six stations of the Global Digital Seismograph Network were inverted in addition to digitized analogue long-period recordings available from nine Worldwide Standardized Seismograph Network stations. The digital data include four broad-band and short-period velocity waveforms reconstructed from the short- and long-period components. The time-window approach allows for a variable rise time on the fault and accounts for the source multiplicity evident in the recorded P waveforms. Synthetic tests conducted using the inversion method on the limited data set, however, reveal that the data are insufficient to identify the exact dislocation duration on the fault. The method is thus implemented by prescribing the fault rise time using five consecutive 1 s time windows. The coseismic slip inferred from the P waves shows a small 70 cm peak near the earthquake hypocentre and a large zone of dislocation (1.2 m maximum) further south-east. The slip pattern covers depths from 3 to 25 km and is located south-east of other recent large interplate ruptures on the Michoacan segment of the Mexican subduction zone. This result indicates that the 1979 Petatlan earthquake broke an independent, adjacent portion of the Cocos-North America plate boundary. The seismic moment of 1.5 × 10 27 dyn cm inferred from the P waves is approximately one-half the long-period moment estimated by other investigators from the observed surface waves. Although the discrepancy is within the uncertainty of the seismic-moment estimates, it may suggest the presence of a component of slow interplate motion that did not radiate significant P -wave energy.

Geophysical Journal International↗

Emerging investigator series: Atmospheric cycling of indium in the northeastern United States

Indium is critical to the global economy and is used in an increasing number of electronics and new energy technologies. However, little is known about its environmental behavior or impacts, including its concentrations or cycling in the atmosphere. This study determined indium concentrations in air particulate matter at five locations across the northeastern United States over the course of one year, in 1995. Historical records from a Massachusetts bog core showed that indium atmospheric concentrations in this region changed only modestly between 1995 and 2010. Atmospheric indium concentrations varied significantly both geographically and temporally, with average concentrations in PM 3 of 2.1 ± 1.6 pg m −3 (1 standard deviation), and average particle-normalized concentrations of 0.2 ± 0.2 μg In per g PM 3 . Peaks in the particle-normalized concentrations in two New York sites were correlated with wind direction; air coming from the north contributed higher concentrations of indium than air coming from the west. This correlation, along with measurements of indium in zinc smelter emissions and coal fly ash, suggests that indium in the atmosphere in the northeastern United States comes from a relatively constant low-level input from coal combustion in the midwest, and higher but more sporadic contributions from the smelting of lead, zinc, copper, tin, and nickel north of the New York sample sites. Understanding the industrial sources of indium to the atmosphere and how they compare with natural sources can lead to a better understanding of the impact of human activities on the indium cycle, and may help to establish a baseline for monitoring future impacts as indium use grows.

Massachusetts, New York↗

Fluvial sediment of the Mississippi River at St. Louis, Missouri

An investigation of the fluvial sediment of the Mississippi River at St. Louis, Mo., was begun in 1948. Most data have been obtained only to determine the daily suspended-sediment discharge and the particle-size distribution of suspended sediment and bed material, but a few data have been obtained to study the flow resistance, the vertical distribution of sediment and velocity, and the bed-material discharge. The flow of the Mississippi River at St. Louis is made up of the flows from the Missouri River, which had an average flow of 79,860 cubic feet per second for 1897-1958 at Hermann, Mo., and from the upper Mississippi River, which had an average flow of 91,890 cubic feet per second for 1928-58 at Alton, Il. The Missouri River is partly controlled by reservoirs that had a total capacity of 90,300,000 acre-feet in 1956, and the upper Mississippi River is partly controlled by lakes and reservoirs that had a total capacity of 4,890,000 acre-feet in 1956. The flows of the Missouri and upper Mississippi Rivers have not become mixed at St. Louis; so the river has a lateral gradient of suspended-sediment concentration. The concentration near the west bank has been as much as 2,400 parts per million greater than the concentration near the east bank. Suspended-sediment discharges from April 1948 to September 1958 ranged from 4,250 to 7,010,000 tons per day and averaged 496,000 tons per day. Mean concentrations for water years decreased steadily from 1,690 parts per million in 1949 to 403 parts per million in 1956, but they increased to 756 parts per million in 1958. Effects of new reservoirs in the Missouri River basin on the concentration have been obscured by the close relation of concentration to streamflow. Measured suspended-sediment discharge through September 1958 averaged 47 percent clay, 38 percent silt, and 15 percent sand. Variations of particle size were due mainly to differences in the source areas of the sediment. Most of the bed material in the main flow was between 0.125 and 1.000 millimeter in diameter. The average of median diameters was related to the discharge for periods of 1 year and longer. Geometric quartile deviations of the bed material ranged from 1.1 to 2.5 and averaged 1.5. The mean elevation of the bed had a range of almost 10 feet and was related to the median diameter of bed material by the regression equation hb=363.0 - 7.8 d50 for which the standard error of estimate was 0.91 foot. The resistance to flow as measured by Manning's n ranged from 0.024 to 0.041 and was related to the discharge and mean velocity but not to the shear velocity. Normal dune height is 2-8 feet, and average dune length is about 250 feet. When the resistance to flow was low, much of the bed was fairly fiat; a few dunes were present, but they were much longer than the average. For a given discharge during individual rises in stage, the gage height was lower for increasing discharge than for decreasing discharge even though the bed elevation was higher. The changes in gage height were not caused by changes in energy gradient due to changing discharge, by channel storage between the gage and the measuring section, nor by return of overbank flow; but they were probably caused by a combination of changes in roughness due to changing bed configuration and of changes in turbulence constant due to changing sediment concentration. Turbulence constants (Von Karman's k) computed from velocity measurements at 5-10 points in the vertical and from routine velocity measurements at 2 points in the vertical averaged 0.35 and 0.33, respectively. The exponent z1 of the vertical distribution of concentration for different size ranges varied with about the 0.77 power of the fall velocity. Except for the difference between the theoretical variation and the actual variation of z1 with changing fall velocity, the theoretical equation for the vertical distribution of sediment concentration seems to apply reasonably well for the Miss

Water Supply Paper↗

High concentration methane hydrate in a silt reservoir from the deep-water Gulf of Mexico

We present results from 30 quantitative degassing experiments of pressure core sections collected during The University of Texas-Gulf of Mexico 2-1 (UT-GOM2-1) Hydrate Pressure Coring Expedition at Green Canyon Block 955 in the deep-water Gulf of Mexico as part of The University of Texas at Austin–US Department of Energy Deepwater Methane Hydrate Characterization and Scientific Assessment. The hydrate saturation ( S h ), the volume fraction of the pore space occupied by hydrate, is 79% to 93% within sandy silt beds (centimeters to meters in thickness) between 413 and 442 m below seafloor in 2032 m water depth. Sandy silt intervals are characterized by high compressional wave velocity ( V p ) (2515–3012 m s −1 ) and are interbedded with clayey silt sections that have lower S h (2%–35%) and lower V p (1684–2023 m s −1 ). Clayey silt intervals are composed of thin laminae of silts with high S h within clay-rich intervals containing little to no hydrate. Degassing of single-lithofacies sections reveals higher-resolution variation in S h than is possible to observe in well logs; however, the average S h of 64% through the reservoir is similar to well log estimates. Gas recovered from the hydrates during these experiments is composed almost entirely of methane (99.99% CH 4 , <100 ppm C 2 H 6 on average), with an isotopic composition (δ 13 C: −60.4‰ and −63.6‰ Vienna Peedee belemnite and δ 2 H: −178.2‰ and −179.0‰ Vienna standard mean ocean water) that suggests the methane is primarily from a microbial source. A subset of six degassing experiments performed using very small pressure decrements indicates that the salinity within these samples is close to the average seawater concentration, suggesting that hydrate either formed slowly or formed during a rapid event at least tens of thousands of years before present.

Texas, Louisiana↗

Long-term dynamics of production, respiration, and net CO 2 exchange in two sagebrush-steppe ecosystems

We present a synthesis of long-term measurements of CO 2 exchange in 2 US Intermountain West sagebrush-steppe ecosystems. The locations near Burns, Oregon (1995–2001), and Dubois, Idaho (1996–2001), are part of the AgriFlux Network of the Agricultural Research Service, United States Department of Agriculture. Measurements of net ecosystem CO 2 exchange ( F c ) during the growing season were continuously recorded at flux towers using the Bowen ratio-energy balance technique. Data were partitioned into gross primary productivity ( P g ) and ecosystem respiration ( R e ) using the light-response function method. Wintertime fluxes were measured during 1999/2000 and 2000/2001 and used to model fluxes in other winters. Comparison of daytime respiration derived from light-response analysis with nighttime tower measurements showed close correlation, with daytime respiration being on the average higher than nighttime respiration. Maxima of P g and R e at Burns were both 20 g CO 2 ·m −2 ·d −1 in 1998. Maxima of P g and R e at Dubois were 37 and 35 g CO 2 ·m −2 ·d −1 , respectively, in 1997. Mean annual gross primary production at Burns was 1 111 (range 475–1 715) g CO 2 ·m −2 ·y −1 or about 30% lower than that at Dubois (1 602, range 963–2 162 g CO 2 ·m −2 ·y −1 ). Across the years, both ecosystems were net sinks for atmospheric CO 2 with a mean net ecosystem CO 2 exchange of 82 g CO 2 ·m −2 ·y −1 at Burns and 253 g CO 2 ·m −2 ·y −1 at Dubois, but on a yearly basis either site could be a C sink or source, mostly depending on precipitation timing and amount. Total annual precipitation is not a good predictor of carbon sequestration across sites. Our results suggest that F c should be partitioned into P g and R e components to allow prediction of seasonal and yearly dynamics of CO 2 fluxes.

Rangeland Ecology and Management↗

India National Gas Hydrate Program Expedition 02 Summary of Scientific Results: Gas hydrate systems along the eastern continental margin of India

The primary objectives of the India National Gas Hydrate Program Expedition 02 (NGHP-02) were to obtain new data on the occurrence of gas hydrate systems and to advance the understanding of the controls on the formation of gas hydrate accumulations in the offshore of India. In accordance with the ultimate overall goal of the NGHP effort to assess the energy resource potential of marine gas hydrates in India, particular focus was placed on the exploration and evaluation of gas hydrate occurrences at high saturations in sand-rich systems. NGHP-02 operations were conducted from 3-March-2015 to 28-July-2015 off the eastern coast of India and included logging while drilling (LWD) operations at 25 locations, and coring and wireline logging operations at 10 locations, in the Krishna-Godavari and Mahanadi Basins. The formation of highly concentrated gas hydrate accumulations, which are more suitable for energy extraction, requires the presence of relatively coarse-grained sediments with porosity needed to support the migration and accumulation of gas, and the nucleation of gas hydrate. The results of downhole logging, coring and formation pressure testing operations during NGHP-02 have confirmed the presence of extensive sand-rich depositional systems throughout the deepwater portions of the Krishna-Godavari and Mahanadi Basins. Two areas of Krishna-Godavari Basin, referred to as Areas B and C, contain substantial gas hydrate accumulations in sand-rich systems and therefore represent ideal candidate sites for future gas hydrate production testing. This summary and technical report includes a comprehensive synthesis of the geologic, geophysical, geochemical, and physical property data acquired during NGHP-02 as it relates to the controls on gas hydrate occurrence, particularly with regards to sand-hosted accumulations. In the Mahanadi Basin, despite the confirmation of extensive reservoir capacity, gas supply at the NGHP-02 sites was insufficient to charge the reservoirs with gas hydrates. In the Krishna-Godavari Basin, extensive reservoir systems were confirmed with sediment grain-sizes ranging from coarse-silts to gravels. These reservoirs range from fully- to partially filled with gas hydrate. The gas is determined to be from only microbial sources, and in part migrated into the reservoirs from deeper systems. The controls on gas hydrate occurrence are complex and varied; and include substantial reservoir heterogeneity and sufficient permeability throughout the reservoirs and seals that allowed pervasive fluid flow into and through the hydrate-bearing systems. These discoveries are the most significant confirmation of the exploration approach that focuses on direct detection of hydrate reservoirs supported by comprehensive petroleum systems analyses.

Journal of Marine and Petroleum Geology↗

Arctic and boreal ecosystems of western North America as components of the climate system

Synthesis of results from several Arctic and boreal research programmes provides evidence for the strong role of high-latitude ecosystems in the climate system. Average surface air temperature has increased 0.3??C per decade during the twentieth century in the western North American Arctic and boreal forest zones. Precipitation has also increased, but changes in soil moisture are uncertain. Disturbance rates have increased in the boreal forest; for example, there has been a doubling of the area burned in North America in the past 20 years. The disturbance regime in tundra may not have changed. Tundra has a 3-6-fold higher winter albedo than boreal forest, but summer albedo and energy partitioning differ more strongly among ecosystems within either tundra or boreal forest than between these two biomes. This indicates a need to improve our understanding of vegetation dynamics within, as well as between, biomes. If regional surface warming were to continue, changes in albedo and energy absorption would likely act as a positive feedback to regional warming due to earlier melting of snow and, over the long term, the northward movement of treeline. Surface drying and a change in dominance from mosses to vascular plants would also enhance sensible heat flux and regional warming in tundra. In the boreal forest of western North America, deciduous forests have twice the albedo of conifer forests in both winter and summer, 50-80% higher evapotranspiration, and therefore only 30-50% of the sensible heat flux of conifers in summer. Therefore, a warming-induced increase in fire frequency that increased the proportion of deciduous forests in the landscape, would act as a negative feedback to regional warming. Changes in thermokarst and the aerial extent of wetlands, lakes, and ponds would alter high-latitude methane flux. There is currently a wide discrepancy among estimates of the size and direction of CO2 flux between high-latitude ecosystems and the atmosphere. These discrepancies relate more strongly to the approach and assumptions for extrapolation than to inconsistencies in the underlying data. Inverse modelling from atmospheric CO2 concentrations suggests that high latitudes are neutral or net sinks for atmospheric CO2, whereas field measurements suggest that high latitudes are neutral or a net CO2 source. Both approaches rely on assumptions that are difficult to verify. The most parsimonious explanation of the available data is that drying in tundra and disturbance in boreal forest enhance CO2 efflux. Nevertheless, many areas of both tundra and boreal forests remain net sinks due to regional variation in climate and local variation in topographically determined soil moisture. Improved understanding of the role of high-latitude ecosystems in the climate system requires a concerted research effort that focuses on geographical variation in the processes controlling land-atmosphere exchange, species composition, and ecosystem structure. Future studies must be conducted over a long enough time-period to detect and quantify ecosystem feedbacks.

Global Change Biology↗

Metabolic flexibility of aerobic methanotrophs under anoxic conditions in Arctic lake sediments

Methane (CH 4 ) emissions from Arctic lakes are a large and growing source of greenhouse gas to the atmosphere with critical implications for global climate. Because Arctic lakes are ice covered for much of the year, understanding the metabolic flexibility of methanotrophs under anoxic conditions would aid in characterizing the mechanisms responsible for limiting CH 4 emissions from high-latitude regions. Using sediments from an active CH 4 seep in Lake Qalluuraq, Alaska, we conducted DNA-based stable isotope probing (SIP) in anoxic mesocosms and found that aerobic Gammaproteobacterial methanotrophs dominated in assimilating CH 4 . Aerobic methanotrophs were also detected down to 70 cm deep in sediments at the seep site, where anoxic conditions persist. Metagenomic analyses of the heavy DNA from 13 CH 4 -SIP incubations showed that these aerobic methanotrophs had the capacity to generate intermediates such as methanol, formaldehyde, and formate from CH 4 oxidation and to oxidize formaldehyde in the tetrahydromethanopterin (H 4 MPT)-dependent pathway under anoxic conditions. The high levels of Fe present in sediments, combined with Fe and CH 4 profiles in the persistent CH 4 seep site, suggested that oxidation of CH 4 , or, more specifically, its intermediates such as methanol and formaldehyde might be coupled to iron reduction. Aerobic methanotrophs also possessed genes associated with nitrogen and hydrogen metabolism, which might provide potentially alternative energy conservation options under anoxic conditions. These results expand the known metabolic spectrum of aerobic methanotrophs under anoxic conditions and necessitate the re-assessment of the mechanisms underlying CH 4 oxidation in the Arctic, especially under lakes that experience extended O 2 limitations during ice cover.

Alaska↗

Evaluation of quality-control data collected by the U.S. Geological Survey for routine water-quality activities at the Idaho National Laboratory and vicinity, southeastern Idaho, 2002-08

Quality-control (QC) samples were collected from 2002 through 2008 by the U.S. Geological Survey, in cooperation with the U.S. Department of Energy, to ensure data robustness by documenting the variability and bias of water-quality data collected at surface-water and groundwater sites at and near the Idaho National Laboratory. QC samples consisted of 139 replicates and 22 blanks (approximately 11 percent of the number of environmental samples collected). Measurements from replicates were used to estimate variability (from field and laboratory procedures and sample heterogeneity), as reproducibility and reliability, of water-quality measurements of radiochemical, inorganic, and organic constituents. Measurements from blanks were used to estimate the potential contamination bias of selected radiochemical and inorganic constituents in water-quality samples, with an emphasis on identifying any cross contamination of samples collected with portable sampling equipment. The reproducibility of water-quality measurements was estimated with calculations of normalized absolute difference for radiochemical constituents and relative standard deviation (RSD) for inorganic and organic constituents. The reliability of water-quality measurements was estimated with pooled RSDs for all constituents. Reproducibility was acceptable for all constituents except dissolved aluminum and total organic carbon. Pooled RSDs were equal to or less than 14 percent for all constituents except for total organic carbon, which had pooled RSDs of 70 percent for the low concentration range and 4.4 percent for the high concentration range. Source-solution and equipment blanks were measured for concentrations of tritium, strontium-90, cesium-137, sodium, chloride, sulfate, and dissolved chromium. Field blanks were measured for the concentration of iodide. No detectable concentrations were measured from the blanks except for strontium-90 in one source solution and one equipment blank collected in September and October 2004, respectively. The detectable concentrations of strontium-90 in the blanks probably were from a small source of strontium-90 contamination or large measurement variability, or both. Order statistics and the binomial probability distribution were used to estimate the magnitude and extent of any potential contamination bias of tritium, strontium-90, cesium-137, sodium, chloride, sulfate, dissolved chromium, and iodide in water-quality samples. These statistical methods indicated that, with (1) 87 percent confidence, contamination bias of cesium-137 and sodium in 60 percent of water-quality samples was less than the minimum detectable concentration or reporting level; (2) 92‒94 percent confidence, contamination bias of tritium, strontium-90, chloride, sulfate, and dissolved chromium in 70 percent of water-quality samples was less than the minimum detectable concentration or reporting level; and (3) 75 percent confidence, contamination bias of iodide in 50 percent of water-quality samples was less than the reporting level for iodide. These results support the conclusion that contamination bias of water-quality samples from sample processing, storage, shipping, and analysis was insignificant and that cross-contamination of perched groundwater samples collected with bailers during 2002–08 was insignificant.

Idaho↗