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USGS2015

Nutrient, suspended sediment, and trace element loads in the Blackstone River Basin in Massachusetts and Rhode Island, 2007 to 2009

Nutrients, suspended sediment, and trace element loads in the Blackstone River and selected tributaries were estimated from composite water-quality samples in order to better understand the distribution and sources of these constituents in the river basin. The flow-proportional composite water-quality samples were collected during sequential 2-week periods at six stations along the river’s main stem, at three stations on tributaries, and at four wastewater treatment plants in the Massachusetts segment of the basin from June 2007 to September 2009. Samples were collected at an additional station on the Blackstone River near the mouth in Pawtucket, Rhode Island, from September 2008 to September 2009. The flow-proportional composite samples were used to estimate average daily loads during the sampling periods; annual loads for water years 2008 and 2009 also were estimated for the monitoring station on the Blackstone River near the Massachusetts-Rhode Island border. The effects of hydrologic conditions and net attenuation of nitrogen were investigated for loads in the Massachusetts segment of the basin. Sediment resuspension and contaminant loading dynamics were evaluated in two Blackstone River impoundments, the former Rockdale Pond (a breached impoundment) and Rice City Pond. Total nitrogen and phosphorus loads along the Blackstone River in Massachusetts showed similar general patterns during the sampling periods monitored in this study. Total nitrogen loads were relatively low at the farthest upstream monitoring station in Millbury, Massachusetts (typically less than 430 kilograms per day (kg/d) for total nitrogen and 37 kg/d for total phosphorus). Loads typically increased (5- to 10-fold for nitrogen and 6- to 15-fold for phosphorus) downstream from the first, large wastewater treatment plant along the river, the Upper Blackstone Water Pollution Control Abatement District in Millbury. Further downstream, total nitrogen and phosphorus loads remained elevated but variable (typically about 1,000 to 3,000 kg/d for nitrogen and about 100 to 370 kg/d for phosphorus) from Millbury to the Massachusetts-Rhode Island border near Millville, Mass. Monitored tributaries of the Blackstone River and wastewater treatment plants other than the Upper Blackstone Water Pollution Control Abatement District rarely contributed more than a small fraction of the total nitrogen and phosphorus loads observed at the main stem monitoring stations. Loads of suspended sediment also were substantially larger along the river’s main stem than in tributaries during most sampling periods. Very large loads of suspended sediment from the West River tributary during several sampling periods may have been associated with flood-control operations. The estimated annual load of total nitrogen in the Blackstone River at Millville, about 1.3 miles upstream from the Massachusetts-Rhode Island border, was 936,000 kilograms (kg) (2,600 kg/d) in water year 2008 and 878,000 kg (2,400 kg/d) in water year 2009. The estimated annual load of total phosphorus at Millville was 81,400 kg in water year 2008 (223 kg/d) and 80,900 kg (222 kg/d) in water year 2009. The estimated annual load of suspended sediment in was 4,940,000 kg (13,600 kg/d) in water year 2008 and 7,040,000 kg (19,300 kg/d) in water year 2009. The higher load in water year 2009 likely reflects several large storms in summer 2009, which resulted in streamflows in the Blackstone River that were 10 times the typical July flows. Loads of total nitrogen, total phosphorus, and trace elements were almost always lower in the Blackstone River at Millville than in the river near its mouth at the Pawtucket monitoring station, when loads were monitored at both stations in the latter part of water year 2008 and in water year 2009. Loads of suspended sediment at Millville and Pawtucket varied by about the same range, but were usually lower at Pawtucket than at Millville. Total nitrogen loads were higher during sampling periods when the base-flow contribution to streamflow was substantially less than the runoff contribution than in sampling periods when the base-flow dominated. During these sampling periods when the runoff component of streamflow was relatively large, loads of total nitrogen in wastewater discharge from Upper Blackstone Water Pollution Control Abatement District also were high but also constituted smaller fractions of the total nitrogen loads in the river. Nitrogen attenuation may have occurred during some sampling periods, based on net changes in total nitrogen load between consecutive monitoring stations, especially in the Blackstone River reach between the South Grafton and Uxbridge monitoring stations. Analysis of the representative constituents (total phosphorus, total chromium, and suspended sediment) upstream and downstream of impoundments indicated that the existing impoundments, such as Rice City Pond, can be sources of particulate contaminant loads in the Blackstone River. Loads of particulate phosphorus, particulate chromium, and suspended sediment were consistently higher downstream from Rice City Pond than upstream during high-flow events, and there was a positive, linear relation between streamflow and changes in these constituents from upstream to downstream of the impoundment. Thus, particulate contaminants were mobilized from Rice City Pond during high-flow events and transported downstream. In contrast, downstream loads of particulate phosphorus, particulate chromium, and suspended sediment were generally lower than or equal to upstream loads for the former Rockdale Pond impoundment. Sediments associated with the former impoundment at Rockdale Pond, breached in the late 1960s, did not appear to be mobilized during the high-flow events monitored during this study.

Massachusetts, Rhode Island↗

USGS1994

Hydrologic data for the alluvium and terrace deposits of the Cimarron River from Freedom to Guthrie, Oklahoma

Ground water in the Quaternary alluvium and terrace deposits associated with the Cimarron River in northwestern Oklahoma is used extensively for irrigation, municipal, stock, and domestic supplies. The data in this report were collected as part of an investigation to provide State water managers with the quantitative knowledge necessary to manage the ground-water resource effectively. The investigation was conducted by the U.S. Geological Survey in cooperation with the Oklahoma Geological Survey. The information presented in this report include data collected in the field from 1985 through 1989, and unpublished data compiled from files of the U.S. Geological Survey and the Oklahoma Water Resources Board. Data include well and test-bole records, consisting of ground-water levels, depth of wells, principal aquifer, and primary use of water. Water levels include continuous, daily, monthly, and periodic measure- ments for selected wells. Concentrations of common chemical constituents, selected trace elements, organic analyses, and tritium analyses of water samples from wells completed in the Cimarron River alluvium and terrace deposits and Permian geologic units are reported. Winter and summer base-flow discharge measurements of the Cimarron River and its Tributaries are presented together with water-quality data from the measuring sites. Continuous water-level and precipitation-gage data are presented graphically. Locations of data- collection sites are shown on plates.

Open-File Report↗

USGS2008

Hydrogeochemical investigation of the Standard Mine Vicinity, Upper Elk Creek Basin, Colorado

Ground- and surface-water samples were collected in the vicinity of the Standard Mine in west-central Colorado in order to characterize the local ground-water flow system, determine metal concentrations in local ground water, and better understand factors controlling the discharge of metal-rich waters from the mine. The sampling program included a one-time sampling of springs, mine adits, and exploration pits in Elk Basin and Redwell Basin; repeated sampling throughout one year of Standard Mine Level 1 discharge and Elk Creek near its confluence with Coal Creek; and a one-time sampling of underground sites in Levels 3 and 5 of the Standard Mine. Samples were analyzed for major ions and trace elements, stable isotopes of hydrogen (2H/1H) and oxygen (18O/16O), strontium isotopes, and tritium and dissolved noble gases (including helium isotopes) for tritium/helium-3 age dating. No clear correlations were observed between natural ground-water discharge locations and map-scale faults and lithology. Surface observations and the location of ground-water discharge suggest that simple topography, rather than large-scale geologic features, primarily controls the occurrence and flow of shallow ground water in Elk Basin. Discrete inflows from cross faults or other features were not observed in Levels 3 and 5 of the Standard Mine. Instead, water entered the mine as relatively persistent dripping from gouge and breccia within the Standard fault, which both tunnels follow. Therefore, the Standard fault itself is probably the main pathway of ground-water flow from the shallow subsurface to the mine workings. Low pH (as low as 3.2) and elevated concentrations of zinc, lead, cadmium, copper, and manganese (commonly exceeding water-quality standards for Elk Creek) were measured in samples located within or immediately downgradient of areas where sulfides are abundant, including the Standard fault, the Elk Lode portal, and the breccia pipe in Redwell Basin. Concentrations of these metals were typically low and pH values were circumneutral at surrounding locations. Metal concentrations in samples collected from underground workings in the Standard Mine were also generally higher than in samples collected at aboveground sites located outside of sulfide-rich areas. Metal concentrations in discharge from the Level 1 tunnel were among the highest measured in Elk Basin. All of these observations suggest that sulfide-rich mineralized rock is the primary control on dissolved metal concentrations and pH in ground water in the Standard Mine vicinity. Waste-rock piles apparently exert another major control on metal concentrations and pH; the lowest pH and highest metal concentrations typically are found in discharge from waste-rock piles. Concentrations of several chemical constituents along with strontium isotope data indicate that none of the sampled waters could have been the primary source of metals in discharge from Level 1. Therefore, this study did not identify the primary source location for metals in Level 1 discharge. Possible sources must be located below Levels 3 and 5 or farther back into the mountainside than the ends of Levels 3 and 5. Apparent tritium/helium-3 ground-water ages ranged from 0 to 9 yr, and a considerable majority were <1 yr. Tritium data and computed initial tritium values (measured tritium plus measured tritiogenic helium-3) suggest that much of the ground water in the Standard Mine vicinity was weeks to months old rather than years old. Tritium, d2H, and d18O data from water entering into and discharging from the Standard Mine displayed spatial and temporal patterns indicating that these tracers were influenced by seasonal variations in their concentration in precipitation. The tracer data therefore suggest that ground water entering into and discharging from the Standard Mine was largely composed of water <1 yr old. Pronounced seasonal variations in geochemistry in Level 1 discharge also are consistent with short r

Colorado↗

USGS2017

U-Pb ages and geochemistry of zircon from Proterozoic plutons of the Sawatch and Mosquito ranges, Colorado, U.S.A.: Implications for crustal growth of the central Colorado province

A broad study of zircons from plutonic rocks of the Sawatch and Mosquito ranges of west-central Colorado (U.S.A.) was undertaken to significantly refine the magmatic chronology and chemistry of this under-studied region of the Colorado province. This region was chosen because it lies just to the north of the suspected arc-related Gunnison-Salida volcano-plutonic terrane, which has been the subject of many recent investigations—and whose origin is still debated. Our new results provide important insights into the processes active during Proterozoic crustal evolution in this region, and they have important ramifications for broader-scope crustal evolution models for southwestern North America. Twenty-four new U-Pb ages and sequentially acquired rare-earth element (REE), U, Th, and Hf contents of zircon have been determined using the sensitive high-resolution ion microprobe-reverse geometry (SHRIMP-RG). These zircon geochemistry data, in conjunction with whole-rock major- and trace-element data, provide important insights into zircon crystallization and melt fractionation, and they help to further constrain the tectonic environment of magma generation. Our detailed zircon and whole-rock data support the following three interpretations: (1) The Roosevelt Granite in the southern Sawatch Range was the oldest rock dated at 1,766 ± 7 Ma, and it intruded various metavolcanic and metasedimentary rocks. Geochemistry of both whole-rock and zircon supports the contention that this granite was produced in a magmatic arc environment and, therefore, is likely an extension of the older Dubois Greenstone Belt of the Gunnison Igneous Complex (GIC) and the Needle Mountains (1,770–1,755 Ma). Rocks of the younger Cochetopa succession of the GIC, the Salida Greenstone Belt, and the Sangre de Cristo Mountains (1,740–1,725 Ma) were not found in the Sawatch and Mosquito ranges. This observation strongly suggests that the northern edge of the Gunnison-Salida arc terrane underlies the southern portion of the Sawatch and Mosquito ranges. (2) Calc-alkalic to alkali-calcic magmas intruded this region approximately 55 m.y. after the Roosevelt Granite with emplacement of pre-deformational plutons at ca. 1,710 Ma (e.g., Henry Mountain Granite and diorite of Denny Creek), and this continued for at least 30 m.y., ending with emplacement of post-deformational plutons at ca. 1,680 Ma (e.g., Kroenke Granodiorite, granite of Fairview Peak, and syenite of Mount Yale). The timing of deformation can be constrained to sometime after intrusion of the diorite of Denny Creek and likely before the emplacement of the undeformed granite of Fairview Peak. Geochemistry of both whole-rock and zircon indicates that the older group of ca. 1,710-Ma plutons formed at shallower depths, and then they intruded the younger group of more deeply generated, commonly peraluminous and sodic plutons. Although absent in the Sawatch and Mosquito ranges, Mazatzal-age (ca. 1,680–1,620 Ma) plutonic rocks are present regionally. Inherited zircon components of Mazatzal-age were found as cores in some 1.4-Ga Sawatch and Mosquito Range zircons, indicating the likelihood of a relatively local source. These combined data suggest the possibility that all were produced within a continental-margin magmatic arc created as a result of southward-migrating (slab rollback?), north-dipping subduction to the south of the region. (3) Widespread Mesoproterozoic plutonism—with emplacement at various depths and exhibiting bimodal geochemistry—is recognized in 16 different samples. An older group of predominantly peraluminous, yet magnesian granitoids (e.g., granodiorite of Sayers, granite of Taylor River, and the St. Kevin Granite) were emplaced between ca. 1,450 and 1,425 Ma. These geochemical parameters suggest moderate degrees of partial melting in a low-pressure environment. Three younger metaluminous, but ferroan plutons (diorite of Grottos, diorite of Mount Elbert, and granodiorite of Mount Harvard), probably represent a final magmatic pulse at ca. 1,416 Ma. A comprehensive treatment of zircon REE and whole-rock trace-element behavior from Proterozoic rocks is scarce. Discriminant U/Yb versus Y diagrams using zircon data show that the Sawatch and Mosquito plutons are of continental origin, not oceanic. Additional bivariate diagrams incorporating cation ratio combinations of Gd, Ce, Yb, U, Th, Hf, and Eu offer refined insight into differences in fractionation trends and depth of magma generation for the various plutons. These interpretations, on the basis of zircon trace-element data, are mirrored in the whole-rock geochemistry data.

Colorado↗

USGS1999

Characteristics of water-quality data for Lake Houston, selected tributary inflows to Lake Houston, and the Trinity River near Lake Houston (a potential source of interbasin transfer), August 1983-September 1990

Lake Houston, a reservoir completed in 1954 about 25 miles east-northeast of Houston, Texas, is a principal surface-water source for the city of Houston. The increase in water supply to meet future demands is expected to be accommodated by supplementing surface-water inflows to Lake Houston. The Trinity River is considered a potential source for interbasin transfer of water to Lake Houston. Before beginning to supplement inflows, the City needs to better understand the potential effects on Lake Houston water quality from streams that flow into or might contribute water to Lake Houston. During 1983–90, the USGS collected 3,727 water-quality samples from 27 sites in Lake Houston, 6 of the 7 main tributaries to the lake, and the Trinity River at Romayor. Longitudinal profiles of water temperature, dissolved oxygen, specific conductance, pH, and nutrients from the dam to the East and West Forks of Lake Houston constructed for a winter day and a summer day indicate that in general the lake water is mixed in the winter and stratified in the summer. The results of Mann-Whitney rank-sum tests to determine whether there were significant differences between summer and non-summer field measurements, 5-day biological oxygen demand, bacteria, physical and aesthetic properties, nutrients, organic carbon, chlorophyll a, and trace elements in the lake nearest the dam, the East Fork of the lake, and the West Fork of the lake at the same relative depth showed significant differences between summer and non-summer samples for at least one of the three locations at the same relative depth for all 15 properties and constituents tested except specific conductance. The test results indicate that in general Lake Houston is well mixed in the non-summer period and stratified with respect to selected properties and constituents in the summer. The results of rank-sum tests to determine whether there were significant differences between field measurements, 5-day biological oxygen demand, physical and aesthetic properties, nutrients, organic carbon, and chlorophyll a in the lake nearest the dam, the East Fork of the lake, and the West Fork of the lake for samples collected during the same season at the same relative depth showed that significant differences were common; generally, the West Fork had the largest median concentrations among the three locations. The tests comparing trace element concentrations between the lake nearest the dam and the East Fork showed mixed results—large median dissolved manganese concentrations in lake bottom samples in the summer and in East Fork near-surface samples in the non-summer period. The results of rank-sum tests comparing selected properties, 5-day biological oxygen demand, bacteria, nutrients, and total organic carbon in the eastern tributaries with those in the western tributaries, in the eastern tributaries with those in the Trinity River, and in the western tributaries with those in the Trinity River during the same season (summer or non-summer) at the same relative streamflow (low-medium or high) showed that significant differences were more common than not. In the comparisons of the eastern tributaries with the western tributaries that resulted in significant differences, medians of the western tributaries were larger for all properties and constituents except total organic carbon; in the comparisons of the eastern tributaries with the Trinity River that resulted in significant differences, medians were larger for the Trinity River in about 60 percent of the tests; and in the comparisons of the western tributaries with the Trinity River that resulted in significant differences, medians were larger for the western tributaries in about 60 percent of the tests. In the tests comparing trace elements between the eastern and western tributaries during the same season at the same relative streamflow, five of the eight tests showed no significant differences; between the eastern tributaries and the Trinity River, all eight tests showed significant differences, with eastern tributary medians larger in all tests; and between the western tributaries and the Trinity River, seven of the eight tests showed significant differences, with western tributary medians larger in all seven tests. The tests comparing selected properties, 5-day biological oxygen demand, nutrients, and total organic carbon between the eastern tributaries and the East Fork of Lake Houston, between the western tributaries and the West Fork of Lake Houston, and between the Trinity River and the lake nearest the dam, the East Fork, and the West Fork during the same season (summer or nonsummer) yielded significant differences in about 60 percent of the tests. No discernible pattern emerged to associate significant differences with season. In the tests comparing trace elements between the tributaries and the respective forks of the lake to which the tributaries drain, iron concentrations were significantly different in three of the four tests, with median concentrations larger in the tributaries. All the tests comparing manganese between the Trinity River and the three locations in the lake yielded significant differences, with larger median concentrations in the lake.

Texas↗

USGS1980

Hydrologic data from upper Grange Hall Creek basin, Northglenn, Adams County, Colorado

Hydrologic data collected during 1977-79 as part of a water-resources investigation of storm runoff in Upper Grange Hall Creek basin, Adams County, Colo., are presented in this report. Data presented in tabular form consist of: (1) Estimated daily precipitation at one site (April through October, 1978 and 1979); (2) mean daily streamflow at two sites (December 1977 through September 1979); (3) instantaneous streamflow at two sites along Grange Hall Creek and corresponding cumulative rainfall at one to three sites for 17 storms (April 1, 1978, to August 26, 1979); (4) concentrations of selected major ions, fecal-coliform bacteria, suspended sediment, nutrients, and trace elements at five sites during dry-weather flow, at three sites during rainfall runoff, and at five sites during snowmelt runoff; and (5) concentrations of pesticides and polychlorinated biphenyls at two sites during dry-weather flow and rainfall runoff. (USGS)

Open-File Report↗

USGS2006

Water Quality, Physical Habitat, and Biology of the Kijik River Basin, Lake Clark National Park and Preserve, Alaska, 2004-2005

The U.S. Geological Survey and the National Park Service conducted a water-quality investigation of the Kijik River Basin in Lake Clark National Park and Preserve from June 2004 to March 2005. The Kijik River Basin was studied because it has a productive sockeye salmon run that is important to the larger Kvichak River watershed. Water-quality, physical habitat, and biological characteristics were assessed. Water type throughout the Kijik River Basin is calcium bicarbonate although Little Kijik River above Kijik Lake does have slightly higher concentrations of sulfate and chloride. Alkalinity concentrations are generally less than 28 milligrams per liter, indicating a low buffering capacity of these waters. Lachbuna Lake traps much of the suspended sediment from the glacier streams in the headwaters of the basin as evidenced by low secchi-disc transparency of 1 to 2 meters and low suspended sediment concentrations in the Kijik River downstream from the lake. Kijik Lake is a fed by clearwater streams and has secchi-disc readings ranging from 11 to 15 meters. Streambed sediments collected from four surface sites analyzed for trace elements indicated that arsenic concentrations at all sites were above proposed guidelines. However, arsenic concentrations are due to the local geology, not anthropogenic factors. Benthic macroinvertebrate qualitative multi-habitat samples collected from two sites on the Little Kijik River and two sites on the main stem of the Kijik River indicated a total of 69 taxa present among the four sites. The class Insecta, made up the largest percentage of macroinvertebrates, totaling 70 percent of the families found. The insects were comprised of four orders; Diptera (flies and midges), Ephemeroptera (mayflies), Plecoptera (stoneflies), and Trichoptera (caddisflies). One-hundred twenty-two species of periphytic algae were identified in qualitative multi-habitat samples collected at the four stream sites. Eight species of non-motile, diatoms were collected from all four stream sites suggesting that the areas from which they were collected are relatively stable and unaffected by sedimentation.

Scientific Investigations Report↗

USGS2008

Analytical Results for Municipal Biosolids Samples from a Monitoring Program near Deer Trail, Colorado (U.S.A.), 2007

Since late 1993, the Metro Wastewater Reclamation District of Denver (Metro District), a large wastewater treatment plant in Denver, Colorado, has applied Grade I, Class B biosolids to about 52,000 acres of nonirrigated farmland and rangeland near Deer Trail, Colorado (U.S.A.). In cooperation with the Metro District in 1993, the U.S. Geological Survey (USGS) began monitoring ground water at part of this site. In 1999, the USGS began a more comprehensive monitoring study of the entire site to address stakeholder concerns about the potential chemical effects of biosolids applications to water, soil, and vegetation. This more comprehensive monitoring program recently has been extended through 2010. Monitoring components of the more comprehensive study include biosolids collected at the wastewater treatment plant, soil, crops, dust, alluvial and bedrock ground water, and streambed sediment. Streams at the site are dry most of the year, so samples of streambed sediment deposited after rain were used to indicate surface-water effects. This report will present only analytical results for the biosolids samples collected at the Metro District wastewater treatment plant in Denver and analyzed during 2007. We have presented earlier a compilation of analytical results for the biosolids samples collected and analyzed for 1999 through 2006. More information about the other monitoring components is presented elsewhere in the literature. Priority parameters for biosolids identified by the stakeholders and also regulated by Colorado when used as an agricultural soil amendment include the total concentrations of nine trace elements (arsenic, cadmium, copper, lead, mercury, molybdenum, nickel, selenium, and zinc), plutonium isotopes, and gross alpha and beta activity. Nitrogen and chromium also were priority parameters for ground water and sediment components. In general, the objective of each component of the study was to determine whether concentrations of priority parameters (1) were higher than regulatory limits, (2) were increasing with time, or (3) were significantly higher in biosolids-applied areas than in a similar farmed area where biosolids were not applied. Previous analytical results indicate that the elemental composition of the biosolids from the Denver plant was consistent during 1999-2006 and this consistency continues with the samples for 2007; total concentrations of regulated trace elements remained consistently lower than the regulatory limits for the entire monitoring period. Our previously reported data (1999-2006) and data presented in this report were used to compile an inorganic-chemical biosolids signature that can be contrasted with the geochemical signature for this site. The biosolids signature and an understanding of the geology and hydrology of the site can be used to separate biosolids effects from natural geochemical effects. Elements of particular interest for a biosolids signature include bismuth, copper, silver, mercury, phosphorus, and silver. An alternative method of digestion of biosolids was also recently investigated, and the results are presented in this report. A microwave digestion using only nitric acid at controlled elevated temperature and pressure was tested to replace the much more time-consuming and labor-intensive, traditional four-acid, hotplate method for the preparation of solutions to be analyzed by inductively coupled plasma-mass spectrometry (ICP-MS). Elements of concern determined by ICP-MS following digestion include cadmium, copper, lead, molybdenum, nickel, and zinc. The microwave 'digestion' proved to be a strong acid leach, and it was less efficient at digesting the biosolids samples with consistently lower recoveries (compared to the four-acid digestion value) for most elements, but especially for the elements of concern - copper, nickel, and zinc. Other elements traditionally associated with the silicate or oxide minerals demonstrated low recoveries, especially titaniu

Open-File Report↗

USGS2003

Hydrology and water quality of an urban stream reach in the Great Basin — Little Cottonwood Creek near Salt Lake City, Utah, water years 1999–2000

The hydrology and water quality of an urbanized reach of Little Cottonwood Creek near Salt Lake City, Utah, were examined as part of the Great Salt Lake Basins study, part of the U.S. Geological Survey National Water-Quality Assessment program. Physical and chemical properties of the stream were referenced to established aquatic-life criteria as available. Two fixed sampling sites were established on Little Cottonwood Creek with the purpose of determining the influence of urbanization on the water quality of the stream. The fixed-site assessment is a component of the National Water-Quality Assessment surface-water study design used to assess the spatial and temporal distribution of selected water-quality constituents. The occurrence and distribution of major ions, nutrients, trace elements, dissolved and suspended organic carbon, pesticides, volatile organic compounds, and suspended sediment were monitored during this study. From October 1998 to September 2000, stream samples were collected at regular intervals at the two fixed sites. Additional samples were collected at these sites during periods of high flow, which included runoff from snowmelt in the headwaters and seasonal thunderstorms in the lower basin.

Utah↗

USGS1997

Field screening of water quality, bottom sediment, and biota associated with irrigation drainage in the Yuma Valley, Arizona, 1995

Because of concerns expressed by the U.S. Congress and the environmental community, the Department of the Interior began a program in late 1985 to identify the nature and extent of water-quality problems induced by irrigation that might exist in the western States. Surface water, bottom sediment, and biota were collected from March through September 1995 along the lower Colorado River and in agricultural drains at nine sites in the Yuma Valley, Arizona, and analyzed for selected inorganic and organic constituents. Analyses of water, bottom sediment, and biota were completed to determine if irrigation return flow has caused, or has the potential to cause, harmful effects on human health, fish, and wildlife in the study area. Concentrations of dissolved solids in surface-water samples collected in March generally did not vary substantially from surface-water samples collected in June. Concentrations of dissolved solids ranged from 712 to 3,000 milligrams per liter and exceeded the U.S. Environmental Protection Agency secondary maximum contaminant level of 500 milligrams per liter for drinking water. Concentrations of chloride in 9 of 18 water samples and concentrations of sulfate in 16 of 18 water samples exceeded the U.S. Environmental Protection Agency secondary maximum contaminant level of 250 milligrams per liter for drinking water. Calcium and sodium were the dominant cations, and chloride and sulfate were the dominant anions. The maximum selenium concentration of 8 micrograms per liter exceeded the U.S. Environmental Protection Agency aquatic-life chronic criterion of 5 micrograms per liter. Concentrations of lead in 7 of 18 water samples and concentrations of mercury in 4 of 18 water samples exceeded the aquatic-life cronic criteria of 3.2 and 0.012 micrograms per liter, respectively. Concentrations of antimony, beryllium, cadmium, and silver in the water samples were below analytical reporting limits. Arsenic was detected in 3 of 9 bottom-sediment samples, and concentrations ranged from 11 to 16 micrograms per gram. Concentrations ofaluminum, beryllium, boron, copper, lead, and zinc were highest in samples from Main Drain at southerly international boundary near San Luis, Arizona. Selenium was detected in all bottom-sediment samples, and concentrations ranged from 0.1 to 0.7 micrograms per gram. Concentrations of cadmium, europium, homium, mercury, molybdenum, silver, tantalum, tin, and uranium were below analytical reporting limits in the bottom-sediment samples. Concentrations of trace elements in bottom-sediment samples were within the ranges found in a study of soils of the western United States and did not indicate a significant accumulation of these constituents. p,p'Dichlorodiphenyldichloroethylene (commonly referred to as p,-p'-DDE) was detected in one bottom-sediment sample at a concentration of 1.4 micrograms per gram. No other organochlorine compounds were detected in the bottom-sediment samples. DDE was present in all fish and bird samples. Almost one-half of the fish samples contained DDE residues that were two times higher than the mean calculated for a national study in 1984-85. Twenty-tree percent of the fish contained more than three times the national mean. Fish from downstream parts of the Main Drain had the highest concentrations of DDE. Although concentrations of DDE in fish and in bird carcasses and eggs were above background levels, residues generally were below thresholds associated with chronic poisoning and reproductive problems in figh and wildlife. Concentrations of 18 trace elements were detected in cattail (Typha sp.) roots, freshwater clam (Corbicula fluminea), fish, and bird samples. Selenium in most fish and in livers of red-winged (Agelaius phoeniceus) and yellow-headed (Xanthocephalus xanthocephalus) blackbirds was above background concentrations but below toxic concentrations. In contrast, selenium was present in a killdeer (Charadrium vociferus) liver sample at potentially toxic con

Water-Resources Investigations Report↗

USGS2004

Streamflow and Water-Quality Characteristics for Wind Cave National Park, South Dakota, 2002-03

A 2-year study of streamflow and water-quality characteristics in Wind Cave National Park was performed by the U.S. Geological Survey in cooperation with the National Park Service. During this study, streamflow and water-quality data were collected for three of the park's perennial streams (Cold Spring, Beaver, and Highland Creeks) from January 2002 through November 2003. The potential influence of parking lot runoff on cave drip within Wind Cave also was investigated by collecting and analyzing several time-dependent samples from a drainage culvert downstream from the parking lot and from Upper Minnehaha Falls inside the cave following a series of simulated runoff events. The primary focus of the report is on data collected during the 2-year study from January 2002 to November 2003; however, data collected previously also are summarized. Losing reaches occur on both Beaver and Highland Creeks as these streams flow across outcrops of bedrock aquifers within the park. No streamflow losses occur along Cold Spring Creek because its confluence with Beaver Creek is located upstream from the outcrop of the Madison aquifer, where most streamflow losses occur. Physical properties, major ions, trace elements, nutrients, bacteria, benthic macroinvertebrates, organic (wastewater) compounds, bottom sediment, and suspended sediment are summarized for samples collected from 2 sites on Cold Spring Creek, 2 sites on Beaver Creek, and 1 site on Highland Creek. None of the constituent concentrations for any of the samples collected during 2002-03 exceeded any of the U.S. Environmental Protection Agency drinking-water standards, with the exception of the Secondary Maximum Contaminant Level for pH, which was exceeded in numerous samples from Beaver Creek and Highland Creek. Additionally, the pH values in several of these same samples also exceeded beneficial-use criteria for coldwater permanent fisheries and coldwater marginal fisheries. Water temperature exceeded the coldwater permanent fisheries criterion in numerous samples from all three streams. Two samples from Highland Creek also exceeded the coldwater marginal fisheries criterion for water temperature. Mean concentrations of ammonia, orthophosphate, and phosphorous were higher for the upstream site on Beaver Creek than for other water-quality sampling sites. Concentrations of E. coli, fecal coliform, and total coliform bacteria also were higher at the upstream site on Beaver Creek than for any other site. Samples for the analysis of benthic macroinvertebrates were collected from one site on each of the three streams during July 2002 and May 2003. The benthic macroinvertebrate data showed that Beaver Creek had lower species diversity and a higher percentage of tolerant species than the other two streams during 2002, but just the opposite was found during 2003. However, examination of the complete data set indicates that the quality of water at the upstream site was generally poorer than the quality of water at the downstream site. Furthermore, the quality of water at the upstream site on Beaver Creek is somewhat degraded when compared to the quality of water from Highland and Cold Spring Creeks, indicating that anthropogenic activities outside the park probably are affecting the quality of water in Beaver Creek. Samples for the analysis of wastewater compounds were collected at least twice from four of the five water-quality sampling sites. Bromoform, phenol, caffeine, and cholesterol were detected in samples from Cold Spring Creek, but only phenol was detected at concentrations greater than the minimum reporting level. Concentrations of several wastewater compounds were estimated in samples collected from sites on Beaver Creek, including phenol, para-cresol, and para-nonylphenol-total. Phenol was detected at both sites on Beaver Creek at concentrations greater than the minimum reporting level. Bromoform; para-cresol; ethanol,2-butoxy-phosphate; and cholesterol were detected

Scientific Investigations Report↗

USGS1987

Hydrologic data for selected streams in the coal area of southeastern Oklahoma, July 1978 to September 1982

Hydrologic data on quantity and quality of surface waters were collected in the coal resource area of southeastern Oklahoma during an investigation of the effects of coal surface mining on the hydrology of the area. The objective of the study was to determine the characteristics of the regional hydrologic system and to detect and document changes in the system that may occur as the result of coal surface mining. This report presents data which were collected at 13 sites in 4 counties between July 1978 and September 1982. The data include: (1) mean daily stream discharge; (2) physical properties, selected field constituents, and concentration of suspended sediment of water samples; (3) concentration of selected common constituents, nutrients, and trace elements of water samples; (4) mean daily specific conductance, pH, water temperature, and dissolved oxygen; and (5) analyses of biological samples.

Open-File Report↗

USGS2009

Estimated Loads of Suspended Sediment and Selected Trace Elements Transported through the Milltown Reservoir Project Area Before and After the Breaching of Milltown Dam in the Upper Clark Fork Basin, Montana, Water Year 2008

This report presents estimated daily and cumulative loads of suspended sediment and selected trace elements transported during water year 2008 at three streamflow-gaging stations that bracket the Milltown Reservoir project area in the upper Clark Fork basin of western Montana. Milltown Reservoir is a National Priorities List Superfund site where sediments enriched in trace elements from historical mining and ore processing have been deposited since the construction of Milltown Dam in 1907. Milltown Dam was breached on March 28, 2008, as part of Superfund remedial activities to remove the dam and contaminated sediment that had accumulated in Milltown Reservoir. The estimated loads transported through the project area during the periods before and after the breaching of Milltown Dam, and for the entire water year 2008, were used to quantify the net gain or loss (mass balance) of suspended sediment and trace elements within the project area during the transition from a reservoir environment to a free-flowing river. This study was done in cooperation with the U.S. Environmental Protection Agency. Streamflow during water year 2008 compared to long-term streamflow, as represented by the record for Clark Fork above Missoula (water years 1930-2008), generally was below normal (long-term median) from about October 2007 through April 2008. Sustained runoff started in mid-April, which increased flows to near normal by mid-May. After mid-May, flows sharply increased to above normal, reaching a maximum daily mean streamflow of 16,800 cubic feet per second (ft3/s) on May 21, which essentially equaled the long-term 10th-exceedance percentile for that date. Flows substantially above normal were sustained through June, then decreased through the summer and reached near-normal by August. Annual mean streamflow during water year 2008 (3,040 ft3/s) was 105 percent of the long-term mean annual streamflow (2,900 ft3/s). The annual peak flow (17,500 ft3/s) occurred on May 21 and was 112 percent of the long-term mean annual peak flow (15,600 ft3/s). About 81 percent of the annual flow volume was discharged during the post-breach period. Daily loads of suspended sediment were estimated directly by using high-frequency sampling of the daily sediment monitoring. Daily loads of unfiltered-recoverable arsenic, cadmium, copper, iron, lead, manganese, and zinc were estimated by using regression equations relating trace-element discharge to either streamflow or suspended-sediment discharge. Regression equations for estimating trace-element discharge in water year 2008 were developed from instantaneous streamflow and concentration data for periodic water-quality samples collected during all or part of water years 2004-08. The equations were applied to records of daily mean streamflow or daily suspended-sediment loads to produce estimated daily trace-element loads. Variations in daily suspended-sediment and trace-element loads generally coincided with variations in streamflow. Relatively small to moderately large daily net losses from the project area were common during the pre-breach period when low-flow conditions were prevalent. Outflow loads from the project area sharply increased immediately after the breaching of Milltown Dam and during the rising limb and peak flow of the annual hydrograph. Net losses of suspended sediment and trace elements from the project area decreased as streamflow decreased during the summer, eventually becoming small or reaching an approximate net balance between inflow and outflow. Estimated daily loads of suspended sediment and trace elements for all three stations were summed to determine cumulative inflow and outflow loads for the pre-breach and post-breach periods, as well as for the entire water year 2008. Overall, the mass balance between the combined inflow loads from two upstream source areas (upper Clark Fork and Blackfoot River basins) and the outflow loads at Clark Fork above Missoula indicates net losses

Scientific Investigations Report↗

USGS2021

Long-term African dust delivery to the eastern Atlantic Ocean from the Sahara and Sahel regions: Evidence from Quaternary paleosols on the Canary Islands, Spain

Africa is the most important source of dust in the world today and dust storms from that continent frequently deposit sediment on the nearby Canary Islands. Many investigators have inferred African dust inputs to Canary Islands paleosols based only on the presence of quartz. However, some local rocks do contain this mineral, so quartz alone is insufficient proof of dust deposition. Further, it is not known whether the Sahara Desert or the Sahel region is more important as a dust source. We address these issues by study of sequences of Pleistocene aeolian sands on the islands of Lanzarote and Fuerteventura. Aeolian sands are composed mostly of marine carbonate minerals and locally derived volcanic minerals. They date from the early-middle Pleistocene to the Holocene. Trace element geochemistry shows that the soils formed from both locally derived basalt and African dust. Major element geochemistry and clay mineralogy indicate that dust additions to the Canary Islands likely come from both the Sahara and Sahel. Dust delivered from the Sahel indicates that droughts in that region have had a history extending through much of the Quaternary. Accretionary-inflationary profile development, from dust accretion, is evident in the upward growth of Canary Islands paleosols.

Quaternary Science Reviews↗

USGS2012

Organic contaminants, trace and major elements, and nutrients in water and sediment sampled in response to the Deepwater Horizon oil spill

Beach water and sediment samples were collected along the Gulf of Mexico coast to assess differences in contaminant concentrations before and after landfall of Macondo-1 well oil released into the Gulf of Mexico from the sinking of the British Petroleum Corporation's Deepwater Horizon drilling platform. Samples were collected at 70 coastal sites between May 7 and July 7, 2010, to document baseline, or "pre-landfall" conditions. A subset of 48 sites was resampled during October 4 to 14, 2010, after oil had made landfall on the Gulf of Mexico coast, called the "post-landfall" sampling period, to determine if actionable concentrations of oil were present along shorelines. Few organic contaminants were detected in water; their detection frequencies generally were low and similar in pre-landfall and post-landfall samples. Only one organic contaminant--toluene--had significantly higher concentrations in post-landfall than pre-landfall water samples. No water samples exceeded any human-health benchmarks, and only one post-landfall water sample exceeded an aquatic-life benchmark--the toxic-unit benchmark for polycyclic aromatic hydrocarbons (PAH) mixtures. In sediment, concentrations of 3 parent PAHs and 17 alkylated PAH groups were significantly higher in post-landfall samples than pre-landfall samples. One pre-landfall sample from Texas exceeded the sediment toxic-unit benchmark for PAH mixtures; this site was not sampled during the post-landfall period. Empirical upper screening-value benchmarks for PAHs in sediment were exceeded at 37 percent of post-landfall samples and 22 percent of pre-landfall samples, but there was no significant difference in the proportion of samples exceeding benchmarks between paired pre-landfall and post-landfall samples. Seven sites had the largest concentration differences between post-landfall and pre-landfall samples for 15 alkylated PAHs. Five of these seven sites, located in Louisiana, Mississippi, and Alabama, had diagnostic geochemical evidence of Macondo-1 oil in post-landfall sediments and tarballs. For trace and major elements in water, analytical reporting levels for several elements were high and variable. No human-health benchmarks were exceeded, although these were available for only two elements. Aquatic-life benchmarks for trace elements were exceeded in 47 percent of water samples overall. The elements responsible for the most exceedances in post-landfall samples were boron, copper, and manganese. Benchmark exceedances in water could be substantially underestimated because some samples had reporting levels higher than the applicable benchmarks (such as cobalt, copper, lead and zinc) and some elements (such as boron and vanadium) were analyzed in samples from only one sampling period. For trace elements in whole sediment, empirical upper screening-value benchmarks were exceeded in 57 percent of post-landfall samples and 40 percent of pre-landfall samples, but there was no significant difference in the proportion of samples exceeding benchmarks between paired pre-landfall and post-landfall samples. Benchmark exceedance frequencies could be conservatively high because they are based on measurements of total trace-element concentrations in sediment. In the less than 63-micrometer sediment fraction, one or more trace or major elements were anthropogenically enriched relative to national baseline values for U.S. streams for all sediment samples except one. Sixteen percent of sediment samples exceeded upper screening-value benchmarks for, and were enriched in, one or more of the following elements: barium, vanadium, aluminum, manganese, arsenic, chromium, and cobalt. These samples were evenly divided between the sampling periods. Aquatic-life benchmarks were frequently exceeded along the Gulf of Mexico coast by trace elements in both water and sediment and by PAHs in sediment. For the most part, however, significant differences between pre-landfall and post-landfall samples were limited to concentrations of PAHs in sediment. At five sites along the coast, the higher post-landfall concentrations of PAHs were associated with diagnostic geochemical evidence of Deepwater Horizon Macondo-1 oil.

Alabama, Arkansas, Florida, Georgia, Louisiana, Te↗

USGS2012

Reconnaissance of contaminants in selected wastewater-treatment-plant effluent and stormwater runoff entering the Columbia River, Columbia River Basin, Washington and Oregon, 2008-10

Toxic contamination is a significant concern in the Columbia River Basin in Washington and Oregon. To help water managers and policy makers in decision making about future sampling efforts and toxic-reduction activities, a reconnaissance was done to assess contaminant concentrations directly contributed to the Columbia River through wastewater-treatment-plant (WWTP) effluent and stormwater runoff from adjacent urban environments and to evaluate instantaneous loadings to the Columbia River Basin from these inputs. Nine cities were selected in Oregon and Washington to provide diversity in physical setting, climate characteristics, and population density—Wenatchee, Richland, Umatilla, The Dalles, Hood River, Portland, Vancouver, St. Helens, and Longview. Samples were collected from a WWTP in each city and analyzed for anthropogenic organic compounds, pharmaceuticals, polychlorinated biphenyls (PCBs), polybrominated diphenyl ether (PBDEs [brominated flame-retardants]), organochlorine or legacy compounds, currently used pesticides, mercury, and estrogenicity. Of the 210 compounds analyzed in the WWTP-effluent samples, 112 (53 percent) were detected, and the detection rate for most compound classes was greater than 80 percent. Despite the differences in location, population, treatment type, and plant size, detection frequencies were similar for many of the compounds detected among the WWTPs. By contrast, the occurrence of polycyclic aromatic hydrocarbons (PAHs) was sporadic, and PCBs were detected at only three WWTPs. The stormwater-runoff samples were analyzed for a slightly different set of contaminants, with the focus on those expected to be related to road and land runoff—PCBs, PBDEs, organochlorine compounds, PAHs, currently used pesticides, trace elements, mercury, and oil and grease. A complex mixture of compounds was detected in stormwater runoff, with detections of 114 (58 percent) of the 195 compounds analyzed. The detection patterns and concentrations measured in the stormwater-runoff samples, however, were more heterogeneous than in the WWTP-effluent samples. This reflects differences in various factors, including suspended-sediment concentrations and known contamination sources present in some watersheds. Trace elements and PAHs, which are related to automobiles and impervious surfaces, were the most widespread compound classes detected in stormwater runoff, a typical finding in stormwater runoff in urban areas. With a better understanding of the presence of these contaminants in the environment, future work can focus on developing research to characterize the effects of these contaminants on aquatic life and prioritize toxic-reduction efforts for the Columbia River Basin.

Washington;Oregon↗

USGS2014

Groundwater levels and water quality during a 96-hour aquifer test in Pickaway County, Ohio, 2012

During October–November 2012, a 96-hour aquifer test was performed at a proposed well field in northern Pickaway County, Ohio, to investigate groundwater with elevated nitrate concentrations. Earlier sampling done by the City of Columbus revealed that some wells had concentrations of nitrate that approached 10 milligrams per liter (mg/L), whereas other wells and the nearby Scioto River had concentrations from 2 to 6 mg/L. The purpose of the current test was to examine potential changes in water quality that may be expected if the site was developed into a public water-supply source; therefore, water-transmitting properties determined during a previous test were not determined a second time. Before and during the test, water-level data and water-quality samples were obtained from observation wells while a test production well was pumped at 1,300 gallons per minute. Before the test, local groundwater levels indicated that groundwater was being discharged to the nearby Scioto River, but during the test, the stream was losing streamflow owing to infiltration. Water levels declined in the pumping well, in adjacent observation wells, and in a nearby streambed piezometer as pumping commenced. The maximum drawdown in the pumping well was 29.75 feet, measured about 95 hours after pumping began. Water-quality data, including analyses for field parameters, major and trace elements, nutrients, and stable isotopes of oxygen and nitrogen in nitrate, demonstrated only small variations before and during the test. Concentrations of nitrate in five samples from the pumping well ranged from about 5.10 to 5.42 mg/L before and during the test, whereas concentrations of nitrate in five samples on or about the same sampling dates and times at a monitoring site on the Scioto River adjacent to the pumping well ranged from 3.46 to 4.97 mg/L. Water from two nearby observation wells had nitrate concentrations approaching 10 mg/L, which is the U.S. Environmental Protection Agency’s Maximum Contaminant Level for nitrate. Analysis of isotopes of oxygen and nitrogen in nitrate indicated that the source of nitrate is most likely soil nitrogen and fertilizer, with some denitrification and (or) mixing with some manure and septic waste derived from upstream wastewater-treatment facilities.

Ohio↗

USGS2009

Geochemistry of standard mine waters, Gunnison County, Colorado, July 2009

In many hard-rock-mining districts water flowing from abandoned mine adits is a primary source of metals to receiving streams. Understanding the generation of adit discharge is an important step in developing remediation plans. In 2006, the U.S. Environmental Protection Agency listed the Standard Mine in the Elk Creek drainage basin near Crested Butte, Colorado as a superfund site because drainage from the Standard Mine enters Elk Creek, contributing dissolved and suspended loads of zinc, cadmium, copper, and other metals to the stream. Elk Creek flows into Coal Creek, which is a source of drinking water for the town of Crested Butte. In 2006 and 2007, the U.S. Geological Survey undertook a hydrogeologic investigation of the Standard Mine and vicinity and identified areas of the underground workings for additional work. Mine drainage, underground-water samples, and selected spring water samples were collected in July 2009 for analysis of inorganic solutes as part of a follow-up study. Water analyses are reported for mine-effluent samples from Levels 1 and 5 of the Standard Mine, underground samples from Levels 2 and 3 of the Standard Mine, two spring samples, and an Elk Creek sample. Reported analyses include field measurements (pH, specific conductance, water temperature, dissolved oxygen, and redox potential), major constituents and trace elements, and oxygen and hydrogen isotopic determinations. Overall, water samples collected in 2009 at the same sites as were collected in 2006 have similar chemical compositions. Similar to 2006, water in Level 3 did not flow out the portal but was observed to flow into open workings to lower parts of the mine. Many dissolved constituent concentrations, including calcium, magnesium, sulfate, manganese, zinc, and cadmium, in Level 3 waters substantially are lower than in Level 1 effluent. Concentrations of these dissolved constituents in water samples collected from Level 2 approach or exceed concentrations of Level 1 effluent suggesting that water-rock interaction between Levels 3 and 1 can account for the elevated concentration of metals and other constituents in Level 1 portal effluent. Ore minerals (sphalerite, argentiferous galena, and chalcopyrite) are the likely sources of zinc, cadmium, lead, and copper and are present within the mine in unmined portions of the vein system, within plugged ore chutes, and in muck piles.

Colorado↗