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At least 937 records · Page 52Linked to original sources

238U-230Th dating of chevkinite in high-silica rhyolites from La Primavera and Yellowstone calderas

Application of 238 U- 230 Th disequilibrium dating of accessory minerals with contrasting stabilities and compositions can provide a unique perspective on magmatic evolution by placing the thermochemical evolution of magma within the framework of absolute time. Chevkinite, a Th-rich accessory mineral that occurs in peralkaline and metaluminous rhyolites, may be particularly useful as a chronometer of crystallization and differentiation because its composition may reflect the chemical changes of its host melt. Ion microprobe 128 U- 230 Th dating of single chevkinite microphenocrysts from pre- and post-caldera La Primavera, Mexico, rhyolites yields model crystallization ages that are within 10's of k.y. of their corresponding K-Ar ages of ca. 125 ka to 85 ka, while chevkinite microphenocrysts from a post-caldera Yellowstone, USA, rhyolite yield a range of ages from ca. 110 ka to 250 ka, which is indistinguishable from the age distribution of coexisting zircon. Internal chevkinite-zircon isochrons from La Primavera yield Pleistocene ages with ~5% precision due to the nearly two order difference in Th/U between both minerals. Coupling chevkinite 238 U- 230 Th ages and compositional analyses reveals a secular trend of Th/U and rare earth elements recorded in Yellowstone rhyolite, likely reflecting progressive compositional evolution of host magma. The relatively short timescale between chevkinite-zircon crystallization and eruption suggests that crystal-poor rhyolites at La Primavera were erupted shortly after differentiation and/or reheating. These results indicate that 238 U- 230 Th dating of chevkinite via ion microprobe analysis may be used to date crystallization and chemical evolution of silicic magmas.

Jalisco, Wyoming↗

Relating systematic molecular and textural properties of graptolite pyrolyzed via gold tube hydrous pyrolysis: Implications for thermal proxies in lower Paleozoic marine shales

A series of gold tube pyrolysis experiments (72 h, 300–550 °C, 50 MPa) conducted on a graptolite-rich lower Paleozoic marine shale generated pyrolysis residues for a comprehensive evaluation of the molecular and structural variability of three types of graptolite periderm. Organic petrology, Raman spectroscopy, and field emission scanning electron microscopy (FE-SEM) with energy dispersive spectroscopy (EDS) were combined to evaluate the thermal evolution process. The three types of graptolite periderm, namely granular, non-granular, and nodular graptolite, were analyzed by Raman spectroscopy wherein point measurements were obtained after the maceral was identified and the location verified by organic petrology. Distinct thermal evolution pathways among non-granular, granular, and nodular graptolite periderms were recorded. The evolution patterns of the Raman parameters, particularly D1 and G bands, highlight the differences in geochemical composition of the graptolite periderm types and the alteration of molecular structure with increasing thermal maturity. Raman parameters D1 (position of the D1 peak), G-FWHM (full width at half maximum of the G peak), and ratios D1-FWHM/G-FWHM (full width at half maximum of the D1 peak ratioed to G-FWHM) and A D1 /A G (ratio of D1 and G peak intensities) showed effectiveness in assessing thermal maturity. Bireflectance with increasing gold tube pyrolysis temperature followed a hierarchy: non-granular > granular > nodular, reflecting different molecular alignment intensities. Qualitative FE-SEM evaluation showed that fine-grained mineral inclusions (primarily Fe-sulfide as determined via EDS) were associated with the graptolite populations, with granular graptolite containing greater amounts of coarser-grained (e.g., ∼300–1400 nm) mineral inclusions relative to non-granular and nodular graptolite, which contain finer-grained (e.g., ∼100–200 nm) inclusions difficult to resolve with optical microscopy. These findings are investigated to highlight the mechanisms that drive organic matter evolution within graptolite during thermal maturation, as well as to explore some of the limitations of using spectroscopic parameters as thermal maturity proxies.

International Journal of Coal Geology↗

Modeling aqueous ferrous iron chemistry at low temperatures with application to Mars

Major uncertainties exist with respect to the aqueous geochemical evolution of the Martian surface. Considering the prevailing cryogenic climates and the abundance of salts and iron minerals on Mars, any attempt at comprehensive modeling of Martian aqueous chemistry should include iron chemistry and be valid at low temperatures and high solution concentrations. The objectives of this paper were to (1) estimate ferrous iron Pitzer-equation parameters and iron mineral solubility products at low temperatures (from < 0 ??C to 25 ??C), (2) incorporate these parameters and solubility products into the FREZCHEM model, and (3) use the model to simulate the surficial aqueous geochemical evolution of Mars. Ferrous iron Pitzer-equation parameters were derived in this work or taken from the literature. Six new iron minerals [FeCl2??4H2O, FeCl2??6H2O, FeSO4??H2O, FeSO4??7H2O, FeCO3, and Fe(OH)3] were added to the FREZCHEM model bringing the total solid phases to 56. Agreement between model predictions and experimental data are fair to excellent for the ferrous systems: Fe-Cl, Fe-SO4, Fe-HCO3, H-Fe-Cl, and H-Fe-SO4. We quantified a conceptual model for the aqueous geochemical evolution of the Martian surface. The five stages of the conceptual model are: (1) carbonic acid weathering of primary ferromagnesian minerals to form an initial magnesium-iron-bicarbonate-rich solution; (2) evaporation and precipitation of carbonates, including siderite (FeCO3), with evolution of the brine to a concentrated NaCl solution; (3) ferrous/ferric iron oxidation; (4) either evaporation or freezing of the brine to dryness; and (5) surface acidification. What began as a dilute Mg-Fe-HCO3 dominated leachate representing ferromagnesian weathering evolved into an Earth-like seawater composition dominated by NaCl, and finally into a hypersaline Mg-Na-SO4-Cl brine. Weathering appears to have taken place initially under conditions that allowed solution of ferrous iron [low O2(g)], but later caused oxidation of iron [high O2(g)]. Surface acidification and/or sediment burial can account for the minor amounts of Martian surface carbonates. This model rests on a large number of assumptions and is therefore speculative. Nevertheless, the model is consistent with current understanding concerning surficial salts and minerals based on Martian meteorites, Mars lander data, and remotely-sensed spectral analyses. ?? 2003 Elsevier Ltd.

Geochimica et Cosmochimica Acta↗

Genetic features of petroleum systems in rift basins of eastern China

Most oil-bearing basins in eastern China are Mesozoic-Cenozoic continental rifts which have played a habitat for oil and gas in China. Investigation of the petroleum systems may give a better understanding of the oil and gas habitats in these basins. Of the essential elements of the petroleum system, the source rock is the most important in rift basins. However, rift tectonic evolution controls all the essential elements and processes nevessary for a petroleum system. A four stage evolution model is suggested for the controls in the rift basin. A rift basin may consist of sub-basins, depressions, sub-depressions, and major, moderate, and minor uplifts. A depression or sub-depression has its own depocentre (mainly occupied by source rock) and all kinds of lacustrine sediments, and thus has all the essential elements of a petroleum system. However, only those depressions or sub-depressions which are rich in organic matter and deeply buried to generate oil and gas form petroleum systems. Immature oil, another characteristic, complicates the petroleum system in the rift basins. Three types of oil and gas habitats are described as a result of this analysis of the petroleum systems of the 26 largest oil and gas fields discovered in eastern China rift basins: uplifts between oil source centres are the most prospective areas for oil and gas accumulations, slopes connecting oil source centres and uplifts are the second, and the third type is subtle traps in the soil source centre.Most oil-bearing basins in eastern China are Mesozoic-Cenozoic continental rifts which have played a habitat for oil and gas in China. Investigation of the petroleum systems may give a better understanding of the oil and gas habitats in these basins. Of the essential elements of the petroleum system, the source rock is the most important in rift basins. However, rift tectonic evolution controls all the essential elements and processes necessary for a petroleum system. A four stage evolution model is suggested for the controls in the rift basin. A rift basin may consist of sub-basins, depressions, sub-depressions, and major, moderate, and minor uplifts. A depression or sub-depression has its own depocentre (mainly occupied by source rock) and all kinds of lacustrine sediments, and thus has all the essential elements of a petroleum system. However, only those depressions or sub-depressions which are rich in organic matter and deeply buried to generate oil and gas form petroleum systems. Immature oil, another characteristic, complicates the petroleum system in the rift basins. Three types of oil and gas habitats are described as a result of this analysis of the petroleum systems of the 26 largest oil and gas fields discovered in eastern China rift basins: uplifts between oil source centres are the most prospective areas for oil and gas accumulations, slopes connecting oil source centres and uplifts are the second, and the third type is subtle traps in the oil source centre.

Marine and Petroleum Geology↗

Biomorphodynamics: Physical-biological feedbacks that shape landscapes

Plants and animals affect morphological evolution in many environments. The term "ecogeomorphology" describes studies that address such effects. In this opinion article we use the term "biomorphodynamics" to characterize a subset of ecogeomorphologic studies: those that investigate not only the effects of organisms on physical processes and morphology but also how the biological processes depend on morphology and physical forcing. The two-way coupling precipitates feedbacks, leading to interesting modes of behavior, much like the coupling between flow/sediment transport and morphology leads to rich morphodynamic behaviors. Select examples illustrate how even the basic aspects of some systems cannot be understood without considering biomorphodynamic coupling. Prominent examples include the dynamic interactions between vegetation and flow/sediment transport that can determine river channel patterns and the multifaceted biomorphodynamic feedbacks shaping tidal marshes and channel networks. These examples suggest that the effects of morphology and physical processes on biology tend to operate over the timescale of the evolution of the morphological pattern. Thus, in field studies, which represent a snapshot in the pattern evolution, these effects are often not as obvious as the effects of biology on physical processes. However, numerical modeling indicates that the influences on biology from physical processes can play a key role in shaping landscapes and that even local and temporary vegetation disturbances can steer large-scale, long-term landscape evolution. The prevalence of biomorphodynamic research is burgeoning in recent years, driven by societal need and a confluence of complex systems-inspired modeling approaches in ecology and geomorphology. To make fundamental progress in understanding the dynamics of many landscapes, our community needs to increasingly learn to look for two-way, biomorphodynamic feedbacks and to collect new types of data to support the modeling of such emergent interactions. Copyright 2008 by the American Geophysical Union.

Water Resources Research↗

A comparison of Sr-Nd-Pb isotopes in young and old continental lithospheric mantle: Patagonia and eastern China

It is commonly accepted that beneath the continental crust lies a keel of lithospheric mantle, which extends 50–200 kilometres downward to a transition zone into the asthenosphere. The chemical and physical properties of this reservoir are best known through studies of the basalts and xenoliths that provide samples of the subcrustal mantle. Although sharing many characteristics with oceanic island basalts, some continental basalts become increasingly distinct isotopically as crustal age increases, strongly supporting a permanent association between crust and mantle. Consequently, the distinctive trace element and isotope composition of the lithospheric mantle is able to give important clues to its origin and evolution. The mantle under newly‐created crust is typified by a radiogenic isotope variability that emphasizes the materials from which the continental lithosphere is assembled. Old lithospheric mantle, on the other hand, exhibits more evolved isotopic patterns that attest to the existence of long‐lived, chemically complex systems. A comparison of the Pb, Sr and Nd isotopes in alkalic to sub‐alkalic basalt derived from Phanerozoic (Patagonia) and Middle Archaean to Early Proterozoic (eastern China) subcrustal mantle is useful for identifying ‘end‐member’ components of the lithosphere. One component, having an isotopic composition close to PREMA, either continues to evolve virtually unchanged after incorporation into the lithosphere or is, itself, a relatively new addition even to old lithosphere. Another component, beginning with the isotopic composition of BSE, undergoes significant reduction in U/Pb and Sm/Nd (but not Rb/Sr) upon incorporation into the lithosphere and, with time, shows an increasingly retarded evolution of 206 Pb/ 204 Pb and negative ε Nd‐values approaching the isotopic composition of EMI. Five models are discussed that relate the isotopic composition of the continental lithospheric mantle to that of other parts of the terrestrial system, which may be involved in its origin and evolution. The potential locations of the contributing components and the mechanisms and timing of their assembly into lithosphere are considered. Current knowledge, however, does not allow us to distinguish unequivocally among the various scenarios for the creation and evolution of this reservoir.

Australian Journal of Earth Sciences↗

Intra- and interspecific variation in production of bile acids that act as sex pheromones in lampreys

Pheromones are important sexual signals in most animals, but research into their evolution is largely biased toward insects. Lampreys are a jawless fish with a relatively well-understood pheromone communication system and offer a useful opportunity to study pheromone evolution in a vertebrate. Once sexually mature, male sea lamprey (Petromyzon marinus), and likely other lampreys, produce and release bile acids that act as sex pheromones. Spawning males do not feed and therefore produce bile acids primarily for sexual communication whereas larvae produce the same bile acids but for digestion, offering an opportunity to compare the evolution of bile acids produced for sexual versus nonsexual functions. We profiled eight pheromone-related bile acids in livers from larvae and males and determined the effect of life stage on intra- and interspecific variation in bile acid production. Our results indicate less variation among males than larvae within P. marinus but more variation among species for males than larvae. We postulate that bile acid production in males is shaped by directional or stabilizing selection that reduces variance within P. marinus and directional or disruptive selection that promotes diversification across species. Although our results offer support for a role of sexual selection in the evolution of a lamprey pheromones, they do not eliminate possible roles of other aspects of lamprey ecology.

Physiological and Biochemical Zoology↗

Barrier displacement on a neutral landscape: Towards a theory of continental biogeography

Macroevolutionary theory posits three processes leading to lineage diversification and the formation of regional biotas: dispersal (species geographic range expansion), speciation (species lineage splitting), and extinction (species lineage termination). The Theory of Island Biogeography (TIB) predicts species richness values using just two of these processes; dispersal and extinction. Yet most species on Earth live on continents or continental shelves, and the dynamics of evolutionary diversification at regional and continental scales are qualitatively different from those that govern the formation of species richness on biogeographic islands. Certain geomorphological processes operating perennially on continental platforms displace barriers to gene flow and organismal dispersal, and affect all three terms of macroevolutionary diversification. For example, uplift of a dissected landscape and river capture both merge and separate portions of adjacent areas, allowing dispersal and larger geographic ranges, vicariant speciation and smaller geographic ranges, and extinction when range sizes are subdivided below a minimum persistence threshold. The TIB also does not predict many biogeographic and phylogenetic patterns widely observed in continentally distributed taxa, including: 1, power function-like species-area relationships; 2, log-normal distribution of species geographic range sizes, in which most species have restricted ranges (are endemic) and few species have broad ranges (are cosmopolitan); 3, mid-domain effects with more species towards the geographic center, and more early-branching, species-poor clades towards the geographic periphery; 4, exponential rates of net diversification with log-linear accumulation of lineages through geological time; and 5, power function-like relationships between species-richness and clade diversity, in which most clades are species-poor and few clades are species-rich. Current theory does not provide a robust mechanistic framework to connect these seemingly disparate patterns. Here we present SEAMLESS (Spatially-Explicit Area Model of Landscape Evolution by SimulationS) that generates clade diversification by moving geographic barriers on a continuous, neutral landscape. SEAMLESS is a neutral Landscape Evolution Model (LEM) that treats species and barriers as functionally equivalent with respect to model parameters. SEAMLESS differs from other model-based biogeographic methods (e.g. Lagrange, GeoSSE, BayArea, BioGeoBEARS) by modeling properties of dispersal barriers rather than areas, and by modeling the evolution of species lineages on a continuous landscape, rather than the evolution of geographic ranges along branches of a phylogeny. SEAMLESS shows how dispersal is required to maintain species richness and avoid clade-wide extinction, demonstrates that ancestral range size does not predict species richness, and provides a unified explanation for the suite of commonly observed biogeographic and phylogenetic patterns listed above. SEAMLESS explains how a simple barrier-displacement mechanism affects lineage diversification under neutral conditions, and is advanced here towards the formulation of a general theory of continental biogeography.

Systematic Biology↗

The roles of environmental variation and parasite survival in virulence–transmission relationships

Disease outbreaks are a consequence of interactions among the three components of a host–parasite system: the infectious agent, the host and the environment. While virulence and transmission are widely investigated, most studies of parasite life-history trade-offs are conducted with theoretical models or tractable experimental systems where transmission is standardized and the environment controlled. Yet, biotic and abiotic environmental factors can strongly affect disease dynamics, and ultimately, host–parasite coevolution. Here, we review research on how environmental context alters virulence–transmission relationships, focusing on the off-host portion of the parasite life cycle, and how variation in parasite survival affects the evolution of virulence and transmission. We review three inter-related ‘approaches’ that have dominated the study of the evolution of virulence and transmission for different host–parasite systems: (i) evolutionary trade-off theory, (ii) parasite local adaptation and (iii) parasite phylodynamics. These approaches consider the role of the environment in virulence and transmission evolution from different angles, which entail different advantages and potential biases. We suggest improvements to how to investigate virulence–transmission relationships, through conceptual and methodological developments and taking environmental context into consideration. By combining developments in life-history evolution, phylogenetics, adaptive dynamics and comparative genomics, we can improve our understanding of virulence–transmission relationships across a diversity of host–parasite systems that have eluded experimental study of parasite life history.

Royal Society Open Science↗

A century of intermittent eco‐evolutionary feedbacks resulted in novel trait combinations in invasive Great Lakes alewives (Alosa pseudoharengus)

Species introductions provide opportunities to quantify rates and patterns of evolutionary change in response to novel environments. Alewives ( Alosa pseudoharengus ) are native to the East Coast of North America where they ascend coastal rivers to spawn in lakes and then return to the ocean. Some populations have become landlocked within the last 350 years and diverged phenotypically from their ancestral marine population. More recently, alewives were introduced to the Laurentian Great Lakes (~150 years ago), but these populations have not been compared to East Coast anadromous and landlocked populations. We quantified 95 years of evolution in foraging traits and overall body shape of Great Lakes alewives and compared patterns of phenotypic evolution of Great Lakes alewives to East Coast anadromous and landlocked populations. Our results suggest that gill raker spacing in Great Lakes alewives has evolved in a dynamic pattern that is consistent with responses to strong but intermittent eco‐evolutionary feedbacks with zooplankton size. Following their initial colonization of Lakes Ontario and Michigan, dense alewife populations likely depleted large‐bodied zooplankton, which drove a decrease in alewife gill raker spacing. However, the introduction of large, non‐native zooplankton to the Great Lakes in later decades resulted in an increase in gill raker spacing, and present‐day Great Lakes alewives have gill raker spacing patterns that are similar to the ancestral East Coast anadromous population. Conversely, contemporary Great Lakes alewife populations possess a gape width consistent with East Coast landlocked populations. Body shape showed remarkable parallel evolution with East Coast landlocked populations, likely due to a shared response to the loss of long‐distance movement or migrations. Our results suggest the colonization of a new environment and cessation of migration can result in rapid parallel evolution in some traits, but contingency also plays a role, and a dynamic ecosystem can also yield novel trait combinations.

Great Lakes↗

Pb isotope geochemistry of stratabound Zn-Pb(-Ag-Au-Ba-F) deposits and occurrences in the Nome Complex, Seward Peninsula, Alaska: Metal sources and regional comparisons

A detailed study of the Pb isotope geochemistry of Zn-Pb(-Ag-Au-Ba-F) stratabound sulfide deposits within metasedimentary rocks of the Neoproterozoic to Mississippian(?) Nome Complex provides key information for understanding deposit genesis and crustal evolution. A total of 106 new analyses of galena (and other sulfi des) and metasedimentary rocks hosting the deposits shows that (1) Pb isotope signatures of the deposits are heterogeneous when considered as a group; (2) the stratabound Nelson deposit, and deformed veins at Quarry and Galena, are isotopically similar; (3) stratabound and locally stratiform lenses such as Wheeler North and Aurora Creek had different isotopic evolutions; and (4) the occurrence at Bluff and the postmetamorphic, undeformed Pb-Zn-Ag veins and replacements at Hannum, Independence, Foster, and Omilak show the highest values of 206 Pb/ 204 Pb in the region. Pb isotope data for the stratabound Zn-Pb deposits and occurrences do not lie along similar secondary or anomalous lead evolution lines, and there is no shared, two-stage lead line that would provide intersections with a primary or single-stage lead isotope growth curve. Lead isotopic characteristics of the Nelson stratabound deposit and the deformed veins at Quarry and Galena indicate that they largely shared metal and fluid sources. Quarry and Galena also display sufficient Pb isotopic contrast compared to Aurora Creek and Wheeler North to eliminate such veins as subsurface “feeders” for these stratabound deposits, if the deformed veins and deposits formed as closed isotopic systems (without a contribution from externally derived lead). The Pb isotope composition of galena from Aurora Creek formed by a multistage process. It is thus possible that the Aurora Creek deposit originally contained Pb isotope compositions that resembled those from Quarry and Galena. That early-formed Pb was probably remobilized and mixed with radiogenic lead contributed by Mesozoic hydrothermal fluids similar to those associated with the gold-quartz veins in the region. Values of 207 Pb/ 204 Pb and 206 Pb/ 204 Pb from each of the deposits and occurrences plot within the Pb isotope fields of the host metasedimentary rocks and Mesoproterozoic basement rocks of Seward Peninsula; Pb isotope compositions in the deposits thus reflect a local source control. The processes that generated the premetamorphic Zn-Pb(-Ag-Au-Ba-F) sulfide deposits in the Nome Complex differed from those that generated Zn-Pb-Ag deposits in the western Brooks Range, such as the giant Red Dog ore body. Taken as a group, the stratabound lenses and deformed veins in the Nome Complex did not form in a single, widespread, homogeneous hydrothermal system. The Brooks Range deposits, which consist of a range of host rock types and styles of mineralization distributed over a large area, have a high degree of regional Pb isotope homogeneity. The Wheeler North deposit is isotopically similar to Red Dog and related deposits and may have formed in a related hydrothermal system. A preliminary comparison of the Pb isotope compositions of sedimentary-exhalative (SEDEX)–type deposits within the Arctic Alaska–Chukotka terrane and deposits in crustal blocks of Laurussia shows: (1) noteworthy Pb isotopic overlap exists between some of Zn-Pb-Ag deposits in Ireland and the deposits in Arctic Alaska ; but (2) no exact isotopic match exists between any of the deposits in Arctic Alaska and any deposit in crustal blocks involved in the Paleozoic evolution of Laurussia.

Alaska↗

Water, energy, and biogeochemical budgets investigation at Panola Mountain research watershed, Stockbridge, Georgia; A research plan

The Panola Mountain Research Watershed (PMRW), located in the Panola Mountain State Conservation Park near Stockbridge, Georgia has been selected as a core research watershed under the Water, Energy and Biogeochemical Budgets (WEBB) research initiative of the U.S. Geological Survey (USGS) Global Climate Change Program. This research plan describes ongoing and planned research activities at PMRW from 1984 to 1994. Since 1984, PMRW has been studied as a geochemical process research site under the U.S. Acid Precipitation Thrust Program. Research conducted under this Thrust Program focused on the estimation of dry atmospheric deposition, short-term temporal variability of streamwater chemistry, sulfate adsorption characteristics of the soils, groundwater chemistry, throughfall chemistry, and streamwater quality. The Acid Precipitation Thrust Program continues (1993) to support data collection and a water-quality laboratory. Proposed research to be supported by the WEBB program is organized in 3 interrelated categories: streamflow generation and water-quality evolution, weathering and geochemical evolution, and regulation of soil-water chemistry. Proposed research on streamflow generation and water-quality evolution will focus on subsurface water movement, its influence in streamflow generation, and the associated chemical changes of the water that take place along its flowpath. Proposed research on weathering and geochemical evolution will identify the sources of cations observed in the streamwater at Panola Mountain and quantify the changes in cation source during storms. Proposed research on regulation of soil-water chemistry will focus on the poorly understood processes that regulate soil-water and groundwater chemistry. (USGS)

Georgia↗

Geologic map of the Agnesi quadrangle (V-45), Venus

The Agnesi quadrangle (V&ndash;45), named for centrally located Agnesi crater, encompasses approximately 6,500,000 km 2 extending from lat 25&deg; to 50&deg; S. and from long 30&deg; to 60&deg; E. The V&ndash;45 quadrangle lies within Venus&rsquo; lowland broadly between highlands Ovda Regio to the northeast and Alpha Regio to the west. The region ranges in altitude from 6,051 to 6,054 km, with an average of ~6,052 km, which is essentially mean planetary radius. The quadrangle displays a wide range of features including large to small arcuate exposures of ribbon-tessera terrain (Hansen and Willis, 1998), ten lowland coronae, two montes, 13 pristine impact craters, and long but localized volcanic flows sourced to the west in V&ndash;44. Shield terrain (Hansen, 2005) occurs across much of the V&ndash;45 quadrangle. Although V&ndash;45 lies topographically within the lowland, it includes only one planitia (Fonueha Planitia), perhaps because the features mentioned decorate it. Geologic mapping of the Agnesi quadrangle (V&ndash;45) provides an opportunity (1) to examine the nature of lowland ribbon-tessera terrain, as compared to highland ribbon-tessera terrain; (2) to examine the nature and history of lowland coronae and montes to evaluate hypotheses for the evolution of these features; and (3) to evaluate global catastrophic/episodic resurfacing hypotheses. Ribbon-tessera terrain (Hansen and Willis, 1998), a structurally distinctive terrain marked by roughly orthogonal fold axes and ribbon troughs, characterizes Venusian crustal plateaus (Hansen and others, 1999), although this distinctive fabric is also variably preserved across some lowland regions (Hansen and Willis, 1996, 1998), including the Agnesi quadrangle. Isolated kipukas of ribbon-tessera terrain protrude through the shield-terrain veneer and preserve evidence of local surface processes that predated shield-terrain emplacement, including those leading to regional development of tessera terrain fabrics. The ribbon-tessera fabrics are similar to the fabrics that characterize high-standing crustal plateaus, such as nearby Ovda and Alpha Regiones. Ribbon-bearing kipukas may preserve evidence of ancient collapsed crustal plateaus (Phillips and Hansen, 1994; Ivanov and Head, 1996; Hansen and Willis, 1998; Ghent and Tibuleac, 2002), or they may record different, but rheologically similar, processes. Geologic mapping of the V&ndash;45 quadrangle constrains the geologic history of 12 lowland coronae and montes. Lowland coronae are relatively rare (10% of coronae); they do not form chains, typical of mesoland coronae (Phillips and Hansen, 1994), nor do they cluster, typical of highland coronae associated with volcanic rises (Stofan and others, 2001). The evolution of all coronae, whether by a single mechanism or a range of mechanisms, is a topic of debate (for example, Stofan and others, 1992, 2001; Vita-Finzi and others, 2005; Hamilton, 2005). The V&ndash;45 quadrangle hosts about 20 percent of the lowland coronae on Venus; the geologic history of these features should provide critical insight toward understanding coronae evolution. Two general classes of hypotheses have emerged to address the near random spatial distribution of ~970 apparently pristine impact craters across the surface of Venus: (1) catastrophic/episodic resurfacing and (2) equilibrium/evolutionary resurfacing. Catastrophic/episodic hypotheses propose that a global-scale, temporally punctuated event or events dominated Venus&rsquo; evolution and that the generally uniform impact crater distribution (Schaber and others, 1992; Phillips and others, 1992; Herrick and others, 1997) reflects craters that accumulated during relative global quiescence since that event (for example, Strom and others, 1994; Herrick, 1994; Turcotte and others, 1999). Equilibrium/evolutionary hypotheses suggest instead that the near random crater distribution results from relatively continuous, but spatially localized, resurfacing in which volcanic and (or) tectonic processes occur across the planet through time, although the style of operative processes may have varied temporally and spatially (for example, Phillips and others, 1992; Guest and Stofan, 1999; Hansen and Young, 2007). Geologic relations within the map area allow us to test the catastrophic/episodic versus equilibrium/evolutionary resurfacing hypotheses.

Scientific Investigations Map↗

Geologic map of the Castle Rock 7.5' quadrangle, Arizona and California

The Castle Rock quadrangle is in the northeast corner of Chemehuevi Valley, California and Arizona. It includes the Colorado River’s entrance to the valley at the mouth of Topock Gorge and the northern outskirts of Lake Havasu City, Arizona, and the Chemehuevi Indian Tribe community of Havasu Lake, California. The map includes large parts of the Chemehuevi Indian Reservation and the Havasu National Wildlife Refuge. Upon its exit through the mouth of Topock Gorge, the Colorado River enters Chemehuevi Valley where its floodplain (now submerged under Lake Havasu) is flanked by alluvial piedmonts of the Chemehuevi and Mohave Mountains to the west and east, respectively. This abrupt transition offers a useful perspective into the structural evolution of the Colorado River extensional corridor and of the Colorado River itself. It contains key structural and stratigraphic elements recording a complex history of Cretaceous plutonism and deformation, significant tectonic extension, volcanism, and sedimentation in the Miocene, and, ultimately, the evolution of the Colorado River from the latest Miocene to the present. Lake Havasu submerged the axis of Chemehuevi Valley following the completion of Parker Dam in 1938, and the Colorado River now feeds a verdant delta marsh that composes part of the map. Important bedrock units include the Cretaceous Chemehuevi Mountains Plutonic Suite, the 18.78 Ma Peach Spring Tuff, and thick overlying sequences of interlayered Miocene megabreccia and fanglomerate. The exposure of these units is closely linked to extension along the Chemehuevi-Whipple Mountains detachment fault system. The complex bedrock geologic framework serves as the structural and topographic foundation for the key strata chronicling the evolution of the lower Colorado River. Important stratigraphic units that bear on its evolution to the present day include the Bouse Formation, the Bullhead Alluvium, and the Chemehuevi Formation. The map area also contains the river’s modern delta at the head of Lake Havasu.

Arizona, California↗

Methodologies for extraction of dissolved inorganic carbon for stable carbon isotope studies: Evaluation and alternatives

The gas evolution and the strontium carbonate precipitation techniques to extract dissolved inorganic carbon (DIC) for stable carbon isotope analysis were investigated. Theoretical considerations, involving thermodynamic calculations and computer simulation pointed out several possible sources of error in delta carbon-13 measurements of the DIC and demonstrated the need for experimental evaluation of the magnitude of the error. An alternative analytical technique, equilibration with out-gassed vapor phase, is proposed. The experimental studies revealed that delta carbon-13 of the DIC extracted from a 0.01 molar NaHC03 solution by both techniques agreed within 0.1 per mil with the delta carbon-13 of the DIC extracted by the precipitation technique, and an increase of only 0.27 per mil in that extracted by the gas evolution technique. The efficiency of extraction of DIC decreased with sulfate concentration in the precipitation technique but was independent of sulfate concentration in the gas evolution technique. Both the precipitation and gas evolution technique were found to be satisfactory for extraction of DIC from different kinds of natural water for stable carbon isotope analysis, provided appropriate precautions are observed in handling the samples. For example, it was found that diffusion of atmospheric carbon dioxide does alter the delta carbon-13 of the samples contained in polyethylene bottles; filtration and drying in the air change the delta carbon-13 of the samples contained in polyethylene bottles; filtration and drying in the air change the delta carbon-13 of the precipitation technique; hot manganese dioxide purification changes the delta carbon-13 of carbon dioxide. (USGS)

Water-Resources Investigations Report↗

Age of ground water in basalt aquifers near Spring Creek National Fish Hatchery, Skamania County, Washington

Water samples from four springs and five wells in basalt aquifers near Spring Creek National Fish Hatchery in Skamania County, Washington, were collected and analyzed for selected inorganic ions and stable isotopes. Eight samples were analyzed for carbon-14 (14C), carbon-13 ([3C), and either chlorofluorocarbons (CFCs) or tritium. This work was done to estimate the age (residence time, or time elapsed since recharge) of water issuing from springs at the hatchery. If CFCs are present in ground water, the presence of at least a component of modem (post- 1944) water is indicated. CFC-dating suggests that ground water several hundred feet below land surface in the Underwood Heights area noah of the hatchery, including ground water discharging from the hatchery springs, contains modem water. In contrast, CFC-dating suggests that deeper ground water such as that withdrawn from the Hatchery Well may contain little or no modem water. Concentrations of 14C in water can yield 14C-based ground-water ages, termed 14C-model ages. Unadjusted 14C-model ages (14C-model ages unadjusted for carbon mass transfers) for water discharging from the hatchery springs are on the order of several hundred years. Ground-water samples from three wells in the Underwood Heights area yielded 14C-model ages ranging from modem to several hundred years. Unadjusted 14C-model ages for deep ground water pumped by the Hatchery Well indicate an overall age of several thousand years. However, 14C concentrations may be affected by transfers of carbon into and out of solution. The 13C values of the downgradient ground waters ranged from - 16.4 (per mil) to -18.2 per rail, isotopically heavier than expected for ground water that obtains carbon solely from root respiration in a temperate climate and undergoes no subsequent carbon-isotope fractionation or exchange. Such 13C values in the ground water near the hatchery suggest the possibility of carbon mass transfers during the evolution of these waters. Geochemical mass-transfer modeling suggests that carbon dioxide may degas and calcite may dissolve during the evolution of the modeled ground waters, but that degassing of carbon dioxide is the dominant carbon mass transfer in these ground waters. In addition, modeling results also suggest that, although some calcite may dissolve during the evolution of the water produced by the Hatchery Well, and possibly during the evolution of the shallower ground waters, the amount of calcite dissolution is small. Model testing suggests that the quantity of 14C-dead carbon added from calcite dissolution may not be sufficient to greatly affect the 14C-model ages of these ground waters. In other words, the 14C-model ages that were adjusted for various modeled carbon mass transfers are similar to the unadjusted 14C-model ages. A comparison of CFC data with both adjusted and unadjusted 14C data suggests that water discharging at the hatchery springs contains a mixture of modem and old water, where old water is defined as water recharged prior to 1944. The CFC data support a component of modem water, whereas the 14C data suggest a component of old water. Similar results were obtained from a comparison of CFC data with adjusted and unadjusted 14C data for water collected from Well 3. Well 3 is north of the hatchery springs, on a flow path that appears to be parallel to and similar in length to the flow path leading to the hatchery springs. Water from the Hatchery Well, however, may be devoid of modem water and appears to have an overall age on the order of thousands of years.

Washington↗

Historical coast snaps: Using centennial imagery to track shoreline change

Understanding long-term coastal evolution requires historical data, yet accessing reliable information becomes increasingly challenging for extended periods. While vertical aerial imagery has been extensively used in coastal studies since the mid-20th century, and satellite-derived shoreline measurements are now revolutionizing shoreline change studies, ground-based images, such as historical photographs and picture postcards, provide an alternative source of shoreline data for earlier periods when other datasets are scarce. Despite their frequent use for documenting qualitative morphological changes, these valuable historical data sources have rarely supported quantitative assessments of coastal evolution. This study demonstrates the potential of historical ground-oblique images for quantitatively assessing shoreline position and long-term change. Using Conceição-Duquesa Beach (Cascais, Portugal) as a case study, we analyze shoreline evolution over 92 years by applying a novel methodology to historical photographs and postcards. The approach combines image registration, shoreline detection, coordinate transformation, and rectification while accounting for positional uncertainty. Results reveal a significant counterclockwise rotation of the shoreline between the 20th and 21st centuries, exceeding estimated uncertainty thresholds. This study highlights the feasibility of using historical ground-based imagery to reconstruct shoreline positions and quantify long-term coastal change. The methodology is straightforward, adaptable, and offers a promising avenue for extending the temporal range of shoreline datasets, advancing our understanding of coastal evolution.

Cascais↗

A Next Generation Lunar Orbiter mission

The Moon is the scientific foundation for our knowledge of the early evolution and impact history of the terrestrial planets. Over the last decades the lunar science community has made significant progress in addressing key lunar science and exploration goals, while defining many new high-priority scientific questions regarding the formation and evolution of the Moon. On a broad scale, the last Planetary Decadal Survey defined three scientific objectives to guide studies of the inner planets and Moon. These objectives address the origins and diversity of terrestrial planets, the evolution of life on terrestrial planets, and climate processes on Earth-like planets [1]. Many of these objectives carry forward into exploration goals of a renewed lunar human exploration program, and urgently addressing these objectives will enable the rapid development of exploration plans. A large (Flagship or New Frontiers class) Next Generation Lunar Orbiter (NGLO) mission would address the last Planetary Decadal Survey objective of understanding the origin and diversity of terrestrial planets by studying the geochemistry and geology of the Moon at an unparalleled resolution compared to other lunar mission datasets. Also, NGLO would address the objective of studying the evolution of life on terrestrial planets by furthering knowledge about the composition and distribution of volatile elements on the lunar surface and better characterizing the past and present-day impact rates in the inner Solar System in order to better understand the original delivery of water to Earth. Key exploration goals, including identifying the nature and distribution of lunar volatiles (i.e., water, ice), mapping and characterizing potentially valuable lunar resources, and establishing a human presence on the Moon, also would be addressed by NGLO.

Bulletin of the AAS↗