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At least 919 records · Page 51Linked to original sources

Seismic site characterization of an urban dedimentary basin, Livermore Valley, California: Site tesponse, basin-edge-induced surface waves, and 3D simulations

Thirty‐two accelerometers were deployed in the Livermore Valley, California, for approximately one year to study sedimentary basin effects. Many local and near‐regional earthquakes were recorded, including the 24 August 2014 M w 6.0 Napa, California, earthquake. The resulting ground‐motion data set is used to quantify the seismic response of the Livermore basin, a major structural depression in the California Coast Range Province bounded by active faults. Site response is calculated by two methods: the reference‐site spectral ratio method and a source‐site spectral inversion method. Longer‐period (≥1  s) amplification factors follow the same general pattern as Bouguer gravity anomaly contours. Site response spectra are inverted for shallow shear‐wave velocity profiles, which are consistent with independent information. Frequency–wavenumber analysis is used to analyze plane‐wave propagation across the Livermore Valley and to identify basin‐edge‐induced surface waves with back azimuths different from the source back azimuth. Finite‐element simulations in a 3D velocity model of the region illustrate the generation of basin‐edge‐induced surface waves and point out strips of elevated ground velocities along the margins of the basin.

Bulletin of the Seismological Society of America↗

Preliminary description and interpretation of cores and radiographs from Clear Lake, Lake County, California: Core 7

Clear Lake, California is located in the California Coast Ranges about 120 km north of San Francisco and is the largest freshwater lake wholly within California. The lake basin is tectonically controlled (Anderson, 1936; Brice, 1953, Sims and Rymer, 1974) and the area seismically active (Coffman and von Hake, 1973). Interest in this lake was stimulated by hypotheses developed from a study of sediments in Van Norman Reservoir after the 1971 San Fernando earthquake (Sims, 1973). During this study three zones of deformational structures were found in the 1 m-thick sequence of sediments exposed over about 2 km 2 of the reservoir bottom. These zones were correlated with moderate earthquakes that shook the San Fernando area in 1930, 1952, and 1971. Results of this study, coupled with the experimental formation of deformational structures similar to those from Van Norman Reservoir, led to a search for similar structures in Pleistocene and Holocene lakes and lake sediments in other seismically active areas. Clear Lake, California was chosen specifically because of .:s location near the San Andreas fault and the San Francisco-Oakland urban complex, and the probability of obtaining an uninterrupted sediment record from the present into Pleistocene time. Eight 12 to 15 cm diameter continuous cores were taken from the lake sediments (fig. 1) as part of a study of earthquake induced structures in sediments and the tectonic framework of the Clear Lake basin. The eight cores range in length from 13.87 m to 133.09 m (Table 1).

California↗

Preliminary description and interpretation of cores and radiographs from Clear Lake, Lake County, California: Core 3

Clear Lake, California is located in the California Coast Ranges about 120 km north of San Francisco and is the largest freshwater lake wholly within California. The lake basin is tectonically controlled (Anderson, 1936; Brice, 1953; Sims and Rymer, 1974) and the area seismically active (Coffman and von Hake, 1973). Interest in this lake was stimulated by hypotheses developed from a study of sediments in Van Norman Reservoir after the 1971 San Fernando earthquake (Sims, 1973). During this study three zones of deformational structures were found in the 1 m-thick sequence of sediments exposed over about 2 km2 of the reservoir bottom. These zones were correlated with moderate earthquakes that shook the San Fernando area in 1930, 1952, and 1971. Results of this study, coupled with the experimental formation of deformational structures similar to those from Van Norman Reservoir, led to a search for similar structures in Pleistocene and Holocene lakes and lake sediments in other seismically active areas. Clear Lake, California was chosen specifically because of its location near the San Andreas fault and the San Francisco-Oakland urban complex, and the probability of obtaining an uninterrupted sediment record from the present into Pleistocene time. Eight 12 to 15 cm diameter continuous cores were taken from the lake sediments (fig. 1) as part of a study of earthquake induced structures in sediments and the tectonic framework of the Clear Lake basin. The eight cores range in length from 13.87 m to 115.21 m (Table 1).

California↗

Monitoring and characterizing multi-decadal variations of urban thermal condition using time-series thermal remote sensing and dynamic land cover data

Urban development and associated land cover and land use change alter the thermal, hydrological, and physical properties of the land surface. Assessments of surface urban heat island (UHI) usually focused on using remote sensing and land cover data to quantify UHI intensity and spatial distribution within a certain period. However, the mechanisms and complex interactions in landscape dynamics and land surface thermal features are still being assessed. In this study, we developed and implemented a novel approach to characterize landscape thermal conditions by focusing on UHI intensity and its spatiotemporal variation using the recently available time series of Landsat land surface temperature and land cover change products. We analyzed land surface temperature changes in urban and surrounding non-urban lands to quantify the UHI intensity and landscape thermal conditions in the Atlanta and Minneapolis metropolitan areas of the United States. Our results revealed that UHI intensities had averages of 3.4 °C and 3.3 °C in the Atlanta and Minneapolis metropolitan areas, respectively. The dominant land cover type in rural areas and urban imperviousness cover determines the UHI intensity. Increasing trends of 0.04 °C/year and 0.01 °C/year in UHI intensity between 1985 and 2018 were found in Atlanta and Minneapolis, respectively. The UHI intensity variations in 1985 and 2018 suggest that the magnitudes and temporal variations of UHI intensity averaged from all urban land cover classes are close to the UHI intensity estimated from the low intensity urban area only while the UHI intensities are more than 2 °C larger in medium to high and high intensity urban areas. The UHI intensities estimated from the maximum temperature that have statistically significant increasing trends suggest that the maximum temperature is a good element for measuring UHI effect. Urban land cover dynamics play an important role in controlling temporal variation of UHI and the UHI hotspots. Our findings support the scientific value of implementing the prototype approach as an objective framework to quantify and monitor UHI intensity at a large geographic extent.

Remote Sensing of Environment↗

Summary of information on aquatic biota and their habitats in the Willamette Basin, Oregon, through 1995

Available information on aquatic biota of the Willamette Basin was reviewed and summarized to describe current and historical conditions as part of the U.S. Geological Survey's National Water-Quality Assessment Program. Biological parameters emphasized include the status, distribution, and trends of aquatic biota, particularly algae, macroinvertebrates, and fish; the condition of aquatic and riparian habitat in which these biota reside; and the response of these biota to natural and human-associated impacts, including the level, type, and effect of contaminants. Considerable data are available on aquatic biota in the Willamette Basin, although the information is highly uneven relative to taxa and spatial scope. Extensive information exists for high-profile taxa, such as salmonid fishes, but less information is available for macroinvertebrates, and relatively little data exist for algae. Additionally, some areas such as the H.J. Andrews Experimental Forest and the main stem Willamette River have been extensively studied, whereas data are limited for many other areas. The basin supports a diverse aquatic macroinvertebrate fauna. Available data indicate a relatively high diversity of taxa and a high richness of Ephemeroptera, Plecoptera, Trichoptera (EPT) taxa in the upper reaches of the basin. In the lower main stem reaches, macroinvertebrate assemblages are dominated by pollution tolerant organisms and those adapted to low dissolved oxygen levels. Most of the limited data on algae are from sampling in the main stem Willamette River. Diatoms and blue-green algae are the dominant algal forms. Approximately 61 fish species occur in the basin, although nearly half are introduced. Species richness and distribution are highly correlated with elevation, stream gradient, and water temperature. High elevation, cold water, mountain streams are characterized by a few species of salmonids, sculpins, suckers, and whitefish. Low elevation, main stem reaches of major rivers and streams are dominated by warm water species, such as bass, catfish, and several species in the pan fish group. The only species of fish listed as threatened or endangered is the Oregon chub (Oregonichthys crameri). The effect of an expanding human presence in the Willamette Basin has substantially altered aquatic and riparian habitats, and the biota that use or reside in these habitats. Construction of dams, channelization and bank stabilization of rivers, species introductions, supplementations of fisheries through aquaculture, timber harvesting, agricultural activities, and urbanization have contributed to changes in aquatic habitats and biota from historical conditions. Aquatic toxicological investigations in the basin have focused primarily on fish. These studies have addressed chlorinated pesticides, polychlorinated biphenyls (PCBs), dioxins and furans, polycyclic aromatic hydrocarbons (PAHs), and trace elements in aquatic tissue, as well as fish health assessments, skeletal abnormalities, and aquatic toxicological responses. Several pesticides exceeded U.S. Environmental Protection Agency and State water-quality criteria for the protection of aquatic life. Elevated PCB, dioxin, and furan concentrations were associated with point sources, such as pulp and paper mills. Elevated concentrations of mercury in aquatic tissue were associated with several reservoirs. Fish health assessments and skeletal abnormality studies detected high levels of abnormalities in fish from the main stem Willamette River. Few investigations have examined aquatic toxicological responses, such as enzyme induction assays, growth assays, and biomarker studies.

Oregon↗

Using semi-permeable membrane devices and stable nitrogen isotopes to detect anthropogenic influences on the Truckee River, USA

Stable nitrogen isotopes (??15N) and semipermeable membrane devices (SPMDs) were used together to provide evidence of potential anthropogenic connections to aquatic organisms in the Truckee River, which flows through the Reno/Sparks metropolitan area in Nevada. Crayfish, snail, and periphyton ??15N values, and SPMD toxicity data collected during high and low flow periods at seven primary sites on the river were used with water quality and flow data for the assessment. All biota showed an increase of ??15N on both dates at sites downstream of inflows of a water-quality impaired tributary and urban drain relative to upstream. In addition, most of the lowest ??15N values on each date occurred at the most downstream site on the river. SPMDs sample lipophilic organic contaminants and can be used to assess organic contaminant toxicity to aquatic organisms because they use a membrane that mimics organic contaminant uptake by fish. In this study, results from a fluoroscan test [pyrene index (PI)] of SPMD extracts that responds to higher molecular weight polycyclic aromatic hydrocarbons (PAHs) showed patterns similar to stable isotope data, although observed peaks in PI values occurred in the urban area upstream of where peak ??15N values occurred. The CYP1A biomarker test, which responds to PAHs, certain polychlorinated biphenyls (PCBs), and organochlorines, showed peak toxic equivalents (TEQ) values farther downstream of the urban area. Thus, it is likely that PAHs were contributing to toxicity in the urban area, whereas other nonurban sources of organic carbon may have been present farther downstream. The combined use of stable isotope measurements and SPMDs provided a means of simultaneously examining whether aquatic biota are incorporating constituents from potential food sources (via stable isotopes) or exposure through water (via SPMDs). ?? Mary Ann Liebert, Inc. 2008.

Environmental Engineering Science↗

Central Colorado Assessment Project - Application of integrated geologic, geochemical, biologic, and mineral resource studies

Central Colorado is one of the fastest-growing regions in the Western United States. Population along the Front Range increased more than 30 percent between 1990 and 2000 (http://www.demographia.com/db-metro3newworld.htm) with some counties within the study area, such as Park County, experiencing greater than 100-percent growth (http://www.censusscope.org/us/s8/rank_popl_growth.html). This growth has caused tremendous demand for natural resources and has created challenging land-management issues related to the interface between wilderness and urban expansion. Management of this wilderness/urban interface will benefit from current digital geoscience information collected by the U.S. Geological Survey (USGS) Central Colorado Assessment Project that began in 2003. Approximately 20,800 square miles (53,800 km2) of land divided almost equally between the public and private sectors were part of the assessment. The study area includes much of the Colorado Mineral Belt, a northeast-trending zone that contains 30 economically significant metal deposits. Historically, the area provided much of Colorado's metal production. The only active gold and molybdenum mines in Colorado lie within the study area. Recently, metal and uranium exploration activity has increased sharply in response to record prices for metals and uranium. This further underscores the need for up-to-date geoscience information presented in compatible GIS databases to facilitate rapid land-management decisions. Cooperative studies by USDA Forest Service, National Park Service supported by the USGS Mineral Resources Program (MRP), and National Cooperative Geologic Mapping Programs (NCGMP) contributed to the mineral-resource assessment and included regional geologic mapping at the scale 1:100,000, collection and geochemical studies of stream sediments, surface water, and bedrock samples, macroinvertebrate and biofilm studies in the riparian environment, remote-sensing studies, and geochronology. Geoscience information available as GIS layers has improved understanding of the distribution of metallic, industrial, and aggregate resources, location of areas that have potential for their discovery or development, helped to understand the relation of tectonics, magmatism, and paleohydrology to the genesis of the metal deposits in the region, and provided insight on the geochemical and environmental effects that historical mining and natural, mineralized rock exposures have on surface water, ground water, and aquatic life.

Fact Sheet↗

The development of long-term mean annual total nitrogen and total phosphorus load models for Mississippi, U.S., using RSPARROW

Water-quality degradation from nutrient pollution remains a major challenge for resource managers. Developing effective strategies requires tools to characterize nutrient sources and transport. This study used the RSPARROW framework to develop and assess new, smaller-scale models for Total Nitrogen (TN) and Total Phosphorus (TP) transport across Mississippi (MS). These state-level models were built using 15 years (2005–2020) of observation data and considered variables including multiple nutrient sources, land characteristics, and attenuation processes. The MS models demonstrated comparable accuracy to larger regional SPARROW models, validating the use of smaller-scale models for local management. Results showed agricultural sources are the major contributors to TN, dominated by fertilizer in northern MS and livestock manure in the south. Urban land cover also significantly influenced TN and was the second most significant source of TP, following geologic material (background P). Fertilizer and manure were also important TP sources. This study provides valuable, spatially explicit data on nutrient distribution in MS streams, supporting the state’s nutrient reduction planning. It concludes by highlighting the need for future model improvements via updated source data and mean annual flow estimates.

Alabama, Georgia, Louisiana, Mississippi, North Ca↗

Effects of urbanization, construction activity, management practices, and impoundments on suspended-sediment transport in Johnson County, northeast Kansas, February 2006 through November 2008

The U.S. Geological Survey, in cooperation with the Johnson County, Kansas, Stormwater Management Program, investigated the effects of urbanization, construction activity, management practices, and impoundments on suspended-sediment transport in Johnson County from February 2006 through November 2008. Streamgages and continuous turbidity sensors were operated at 15 sites within the urbanizing 57-square-mile Mill Creek Basin, and 4 sites downstream from the other largest basins (49 to 66 square miles) in Johnson County. The largest sediment yields in Johnson County were observed downstream from basins with increased construction activity. Sediment yields attributed to the largest (68 acre) active construction site in the study area were 9,300 tons per square mile in 2007 and 12,200 tons per square mile in 2008; 5 to 55 times larger than yields observed at other sampling sites. However, given erodible soils and steep slopes at this site, sediment yields were relatively small compared to the range in historic values from construction sites without erosion and sediment controls in the United States (2,300 to 140,000 tons per square mile). Downstream from this construction site, a sediment forebay and wetland were constructed in series upstream from Shawnee Mission Lake, a 120-acre reservoir within Shawnee Mission Park. Although the original intent of the sediment forebay and constructed wetland were unrelated to upstream construction, they were nonetheless evaluated in 2008 to characterize sediment removal before stream entry into the lake. The sediment forebay was estimated to reduce 33 percent of sediment transported to the lake, whereas the wetland did not appear to decrease downstream sediment transport. Comparisons of time-series data and relations between turbidity and sediment concentration indicate that larger silt-sized particles were deposited within the sediment forebay, whereas smaller silt and clay-sized sediments were transported through the wetland and into the lake. Data collected at sites up and downstream from the constructed wetland indicated that hydraulic retention alone did not substantially reduce sediment loading to Shawnee Mission Lake. Mean-daily turbidity values at sampling sites downstream from basins with increased construction activity were compared to U.S. Environmental Protection Agency turbidity criteria designed to reduce discharge of pollutants from construction sites. The U.S. Environmental Protection Agency numeric turbidity criteria specifies that effluent from construction sites greater than 20 acres not exceed a mean-daily turbidity value of 280 nephelometric turbidity units beginning in 2011; this criteria will apply to sites greater than 10 acres beginning in 2014. Although numeric criteria would not have been applicable to data from sampling sites in Johnson County because they were not directly downstream from construction sites and because individual states still have to determine additional details as to how this criteria will be enforced, comparisons were made to characterize the potential of construction site effluent in Johnson County to exceed U.S. Environmental Protection Agency Criteria, even under extensive erosion and sediment controls. Numeric criteria were exceeded at sampling sites downstream from basins with increased construction activity for multiple days during the study period, potentially indicating the need for additional erosion and sediment controls and (or) treatment to bring discharges from construction sites into compliance with future numeric turbidity criteria. Among sampling sites in the Mill Creek Basin, sediment yields from the urbanizing Clear Creek Basin were approximately 2 to 3 times those from older, more stable urban or rural basins. Sediments eroded from construction sites adjacent to or surrounding streams appear to be more readily transported downstream, whereas sediments eroded from construction sites in headwater areas are more likely to

Scientific Investigations Report↗

Widespread occurrence of Magnéli phases in wildland-urban interface fire ashes

The increasing activity of wildland–urban interface (WUI) fires has raised concerns regarding the potential environmental and human health impacts of residual ash remaining after burning. In this study, we investigated the concentration and speciation of titanium in WUI fire ash. Total titanium concentrations in WUI fire ash ranged from 0.53 to 80 g kg –1 . Synchrotron-based macro- and microscale X-ray absorption near-edge structure (XANES and μXANES, respectively) spectroscopy were used to quantify the relative abundance of major Ti phases in the fire ash, and the results were corroborated by high resolution-transmission electron microscopy (HR-TEM) measurements. Rutile (α-TiO 2 ), anatase (β-TiO 2 ), ilmenite (FeTiO 3 ), and titanium(III) oxide (Ti 2 O 3 ) were detected in all 20 ashes investigated by XANES and accounted for 0.26–0.83, 0.19–0.83, 0.33, and 0.17–0.72 of the spectral weight, respectively. Deeper analysis by μXANES of one sample demonstrated that Ti-bearing particles occurred as a mixture of rutile (α-TiO 2 ), anatase (β-TiO 2 ), ilmenite (FeTiO 3 ), and titanium(III) oxide Ti 2 O 3, with the absence of a pure Ti 2 O 3 phase. The presence of Ti 2 O 3 in the WUI fire ash is ascribed to the reduction of rutile and anatase to Magnéli titania (Ti n O 2 n– 1 , n = 4–9), which is estimated to be the dominant phase of titanium in the 20 WUI fire ashes investigated by XANES. The occurrence of Magnéli titania was corroborated by HR-TEM. Our findings demonstrate the impact of WUI fires on titanium speciation; fires convert titanium dioxides (e.g., rutile and anatase) to reduced titanium phases (e.g., Magnéli titania). Based on HR-TEM analyses, most of the titanium-bearing particles were less than 500 nm in size. Magnéli particles have been shown to be more toxic than rutile and anatase and have been linked to reduced lung function. Therefore, this study provides critical insights into the pollution characteristics and potential health risks of WUI fire ashes and associated particles, which are currently poorly understood.

California↗

Preliminary Geologic Map of the Lake Mead 30' X 60' Quadrangle, Clark County, Nevada, and Mohave County, Arizona

Introduction The geologic map of the Lake Mead 30' x 60' quadrangle was completed for the U.S. Geological Survey's Las Vegas Urban Corridor Project and the National Parks Project, National Cooperative Geologic Mapping Program. Lake Mead, which occupies the northern part of the Lake Mead National Recreation Area (LAME), mostly lies within the Lake Mead quadrangle and provides recreation for about nine million visitors annually. The lake was formed by damming of the Colorado River by Hoover Dam in 1939. The recreation area and surrounding Bureau of Land Management lands face increasing public pressure from rapid urban growth in the Las Vegas area to the west. This report provides baseline earth science information that can be used in future studies of hazards, groundwater resources, mineral and aggregate resources, and of soils and vegetation distribution. The preliminary report presents a geologic map and GIS database of the Lake Mead quadrangle and a description and correlation of map units. The final report will include cross-sections and interpretive text. The geology was compiled from many sources, both published and unpublished, including significant new mapping that was conducted specifically for this compilation. Geochronologic data from published sources, as well as preliminary unpublished 40Ar/39Ar ages that were obtained for this report, have been used to refine the ages of formal Tertiary stratigraphic units and define new informal Tertiary sedimentary and volcanic units.

Open-File Report↗

Trends in water quality of selected streams and reservoirs used for water supply in the Triangle area of North Carolina, 1989–2013

As the population of the Triangle area in central North Carolina increases, the demand for good quality drinking water from streams and lakes within the upper Neuse and upper Cape Fear River Basins also increases. The Triangle area includes Raleigh, Cary, Research Triangle Park, Durham, Chapel Hill, and the surrounding communities. The U.S. Geological Survey examined temporal trends in water quality for 13 stream and 8 reservoir sites in the two basins on the basis of data collected during 1989–2013. Trends were analyzed using a fitted time-series model that accommodated for shifting trends and variations in streamflow at multiple time scales. Seventeen water-quality properties and constituents were evaluated, including specific conductance and major ions, nutrients, and organic carbon. Suspended solids and suspended sediment were examined at stream sites; chlorophyll a and Secchi transparency were examined at lake sites. The investigation identified considerable changes in population, land cover, streamflow, and selected water-quality characteristics in the study area over the 25-year period. Specific conductance and concentrations of calcium, magnesium, potassium, sodium, and chloride tended to increase throughout the study area. Area-wide increases were also observed for organic nitrogen. Trends for other water-quality constituents varied on a more site-specific basis because of local watershed influences such as changes to wastewater-treatment processes and substantial shifts from rural to urban land use. Water quality is influenced by multiple, often confounding factors, and thus may change in a non-uniform manner over time. Long-term monitoring is critical for tracking these trends and ensuring resiliency of water supplies for the future. Results from this study may promote the understanding of water-quality response to a growing population and land-cover changes and can assist water-resource managers in the Triangle area in tracking progress toward water-quality goals.

North Carolina↗

Golden eagle occupancy surveys and monitoring strategy in coastal southern California, United States

Golden eagles ( Aquila chrysaetos ) are of increasing conservation concern in western North America. Effective conservation measures for this wide-ranging, federally protected raptor species require monitoring frameworks that accommodate strong inference on the status of breeding populations across vast landscapes. We used a broad-scale sampling design to identify relationships between landscape conditions, detection rates, and site occupancy by territorial pairs of golden eagles in coastal southern California, United States. In 2016 and 2017, we surveyed 175 territory-sized sample sites (13.9-km 2 randomly selected grid cells) up to four times each year and detected a pair of eagles at least once in 22 (12.6%) sites. The probability of detecting pairs of eagles varied substantially between years and declined with increasing amounts of forest cover at survey sites, which obscured observations of eagles during ground-based surveys. After accounting for variable detection, the mean estimate of expected site occupancy by eagle pairs was 0.156 (SE = 0.081). Site-level estimates of occupancy were greatest (>0.30) at sample sites with more rugged terrain conditions, <20% human development, and lower amounts of scrubland vegetation cover. The proportion of a sample site with open grassland or forest cover was not strongly correlated with occupancy. We estimated that approximately 16% of the 5,338-km 2 sampling frame was used by resident pairs of golden eagles, corresponding to a sparsely distributed population of about 60 pairs (95% CI = 19 – 151 pairs). Our study provided baseline data for future surveys of golden eagles along with a widely applicable monitoring framework for identifying spatial conservation priorities in urbanizing landscapes.

California↗

Contaminant baselines and sediment provenance along the Puget Sound Energy Transport Corridor, 2015

The transport of coal and oil can result in contaminated soil, water, and organisms from unintended releases. Trains carrying coal and crude oil regularly pass through Puget Sound, Washington, and an increase in the number of coal and oil trains is expected in the future. This study characterized levels of potentially toxic contaminants in sediment in September 2015: arsenic, metals, and polycyclic aromatic hydrocarbons (PAHs) at four sites with fine-grained sediment (Chuckanut Bay, Padilla Bay, Snohomish River Delta, Nisqually River Delta) adjacent to the Burlington Northern Santa Fe (BNSF) rail line in the Puget Sound region. Arsenic (As) and metals levels were compared to those measured at a fifth site, urban Saltwater State Park, which was expected to show contaminants associated with urbanization but not rail transport of coal and oil because it is not adjacent to the BNSF rail line. Knowledge about current properties of soil and sediment is essential for quantifying impacts of spills and other releases, and for setting remediation or restoration targets. For the sampling effort and timing of this study, all five sites had fine sediment contents of cadmium (Cd), mercury (Hg), lead (Pb), and zinc (Zn) below minimal effects levels. Pb and Zn appeared to be urban sourced. Median As, chromium (Cr), copper (Cu), and nickel (Ni) levels were in the range where adverse biological effects would possibly occur; however, Cr and Ni were geologically sourced and unlikely to be bioavailable to organisms. As, Cu, and antimony (Sb) levels were highly correlated, an association that is characteristic of legacy smelting operations; however, total sediment contents of these three elements, along with Hg and As/Sb ratios, were near natural levels and could indicate river-borne inputs. Median total PAH concentrations were highest at Snohomish River Delta, but were below minimal effects levels at all sites. Diagnostic PAH ratios were indicative of PAHs sourced from petroleum combustion and coal/biomass burning, rather than from spilled petroleum or coal. Rare earth element patterns were distinct among watersheds with Cascade volcanoes, granitic rocks, or non-volcanic sediments, making them promising sediment provenance indicators. Knowledge about sediment sources and contaminant distributions could provide unique insights about sediment-bound contaminant sourcing, delivery, and dispersal in nearshore regions.

Washington↗

Occurrence and distribution of nutrients, suspended sediment, and pesticides in the Mobile River Basin, Alabama, Georgia, Mississippi, and Tennessee, 1999-2001

The Mobile River Basin is one of more than 50 river basins and aquifer systems being investigated as part of the U.S. Geological Survey's National Water- Quality Assessment (NAWQA) Program. This basin is the sixth largest river basin in the United States and the fourth largest in terms of streamflow. The Mobile River Basin encompasses parts of Alabama, Georgia, Mississippi, and Tennessee, and almost two-thirds of the 44,0000-square-mile basin is located in Alabama. The extensive water resources of the Mobile River Basin are influenced by an array of natural and cultural factors, which impart unique and variable qualities to the streams, rivers, and aquifers and provide abundant habitat to sustain the diverse aquatic life in the basin. From January 1999 to December 2001, a study was conducted of the occurrence and distribution of nutrients, suspended sediment, and pesticides in surface water of the Mobile River Basin. Nine sampling sites were selected on the basis of land use. The nine sites included two streams draining agricultural areas, two urban streams, and five large rivers with mixed land use. Surface-water samples were collected from one to four times each month to characterize the spatial and temporal variation in nutrient and pesticide concentrations. Nutrient and suspended-sediment concentrations were highest in watersheds dominated by urban or agricultural land uses. Forty-two percent of the total phosphorus concentrations at all nine sites exceeded the U.S. Environmental Protection Agency's recommended maximum concentration of 0.1 milligram per liter. Flow-weighted mean concentrations at the Mobile River Basin sites generally were in the lower to middle percentile ranges compared with data from other NAWQA studies across the Nation. However, flow-weighted mean concentrations of ammonia, total nitrogen, orthophosphate, and total phosphorus at Bogue Chitto Creek, an agricultural watershed, ranked in the upper 20th percentile of agricultural sites sampled across the Nation as part of the NAWQA Program. Nutrient loads in the Tombigbee River were nearly twice as high compared with nutrient loads in the Alabama River. Nutrient yields were highest in Bogue Chitto Creek, Cahaba Valley Creek, and Threemile Branch because of agricultural and urban land uses in these watersheds. Of the 104 pesticides and degradation products analyzed in the stream samples, 69 were detected in one or more samples. Of the 69 detected pesticides, 51 were herbicides, 15 were insecticides, and 3 were fungicides. A relatively small number of heavily used herbicides accounted for most of the detections, including atrazine and its metabolites (deethylatrazine, 2-hydroxyatrazine, deisopropylatrazine, and deethyldeisopropylatrazine), simazine, metolachlor, tebuthiuron, prometon, diuron, and 2,4-D. Diazinon, chlorpyrifos, and carbaryl were the most frequently detected insecticides; metalaxyl was the most frequently detected fungicide in the Mobile River Basin. Concentrations of pesticides detected in surface water of the Mobile River Basin were among the highest concentrations recorded nationally by the NAWQA Program during 1991 to 2001. The three highest concentrations of atrazine detected at sites across the country were recorded at Bogue Chitto Creek; the highest concentrations of 2,4-D, imazaquin, and malathion recorded nationally were detected at Threemile Branch. Aquatic-life criteria were exceeded by concentrations of five herbicides (2,4-D, atrazine, cyanazine, diuron, and metolachlor), six insecticides (carbaryl, chlorpyrifos, diazinon, dieldrin, malathion, and p,p'-DDE), and one fungicide (chlorothalonil). Drinking-water standards were exceeded by concentrations of four herbicides (2,4-D, atrazine, cyanazine, and simazine), three insecticides (alpha- HCH, diazinon, and dieldrin), and one fungicide (chlorothalonil). The types and concentrations of pesticides found in surface water are linked to land use and to the types of pesti

Alabama, Georgia, Mississippi, Tennessee↗

A geographic information systems technique for monitoring contaminants in Galveston Bay, Texas

A geographic information system (GIS) was used to compile a series of databases containing details concerning metal contamination and pollution sources to study their impacts on the Galveston Bay (TX) ecosystem. Using these databases, a series of maps with various overlays was created with ARC/INFO software. These maps allowed patterns of spatial distribution of numerous variables to be easily visualized so that the impacts of urbanization and industrialization on the natural resources could be examined. Resource managers can use these capabilities in their comprehensive plans for managing individual activities within an overall regulatory framework. The visual displays and cartographic output of the system can be used to locate and identify ecologically sensitive areas and to study trends in these areas over time. These vector GIS techniques have the potential to be more integrated with aerial photography and other remotely sensed data for a more extensive overview of the environment and patterns of interaction

Texas↗

Assessment of the presence of sewage in the Mill River under low-flow conditions, Springfield, Massachusetts, 2010–11

The U.S. Geological Survey, in cooperation with the Pioneer Valley Planning Commission, the U.S. Environmental Protection Agency, and the Massachusetts Department of Environmental Protection Senator William X. Wall Experiment Station, assessed the presence of 14 commonly used human-health pharmaceutical compounds, fecal indicator bacteria, and other man-made compounds indicative of the presence of human sewage in the lower reach of the Mill River near its confluence with the Connecticut River in Springfield, Massachusetts. The study was part of the Tri-State Connecticut River Targeted Watershed Initiative and involved the collection and analysis of raw river water at three sites along the reach, extending from Watershops Pond to the mouth, over the course of a low-flow period, July through November 2010. Previous studies in the region indicated that nonpoint or undocumented sources of wastewater contributed a variety of organic contaminants and potentially harmful bacteria to rivers under both high- and low-flow conditions. Additional samples, including a raw sewage sample collected near a Mill River combined sewer overflow during a non-overflow period, were collected in March 2011. The study was designed to determine if city sewage or other domestic sources of wastewater were entering the river within this reach during low-flow conditions. No definitive evidence of sewage was measured in Mill River water samples collected during the study period. Fecal indicator bacteria, including Escherichia coli ( E. coli ) and enterococci bacteria, were detected in all Mill River water samples. In the DNA analysis of enterococci cultures from the Mill River, samples generally tested negative for the Enterococcus faecium ( esp ) human-specific genetic marker, whereas the raw sewage sample tested positive. Samples also generally tested negative in the human-specific rDNA marker assay for the anaerobic bacterium Bacteroidetes . Samples tested negative in 2010 for two Bacteroidetes human-specific genetic markers, HF134 and HF183, except samples from near the mouth of the Mill River, which tested positive. Samples collected in March 2011 from all three measurement sites tested positive for both markers. The results of bacterial analyses suggest that the fecal bacteria in summer and fall months are most likely of animal origin rather than human. Despite the urban setting, long history of development, and many potential sources of man-made contamination in the Mill River, none of the 12 water samples collected during the study contained targeted pharmaceutical compounds at concentrations greater than the analytical reporting levels. Other man-made compounds, like fluorescent whitening agents, were measured and detected in samples at low concentrations 4 out of 5 times the samples were collected; however, the other lines of evidence do not support a sewer source but rather other nonpoint sources upstream in the watershed. The results of this study do not support the hypothesis that aging sewer lines or combined sewer overflow infrastructure leak into the Mill River as tested during the low-flow conditions during sampling for this study. None of the results from Mill River samples offer conclusive evidence of the presence of sewage. Some low-level detections of pharmaceutical compounds, other man-made chemicals, and bacteria suggest an upstream, nonpoint source. A single raw sewage sample was collected, diluted, and examined for comparison with Mill River water samples and to ensure that the analytical methods could detect typical wastewater constituents. High levels of bacteria were measured, and low levels of three anthropogenic pharmaceutical compounds were detected, confirming the effectiveness of the sub-part-per-million method. The concentration of fluorescent whitening agent-1 in the sewage sample was 90,000 times greater than the median concentration in the Mill River samples.

Massachusetts↗

Hierarchical patch delineation in fragmented landscapes

Purpose We developed a tool, FragPatch (FP), to delineate habitat patches for highly fragmented landscapes from a user-defined suitability map and two landscape perception values for a species of interest. Methods We wrote a Python script in ArcGIS to delineate habitat patch networks using the user inputs and ArcGIS tools such as Euclidean distance, focal maximum, and reclassify. We validated the tool from mapped locations of urban deer and classified imagery for Syracuse, New York, USA. Results FP successfully delineated salient patch networks and functional connectivity for white-tailed deer ( Odocoileus virginianus borealis ) in our fragmented study area, and complements a similar tool, PatchMorph (PM), developed for rural landscape with more uniform land cover. Conclusions A trade-off exists when choosing to use FP or PM and the decision must rely upon a well-defined research question. FP is better suited for isolating patches of habitat when the surrounding matrix is of low quality and suitable areas are highly scattered on the landscape. PM is able to identify patches when the matrix is more uniform, and is better at identifying broader scale connectivity than FP. We expect species biologists and urban landscape planners to use FP to better define patch networks and to understand the implications of fragmentation on a range of species population concerns, including conflicts with human uses.

Landscape Ecology↗