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Geochronology of augen gneiss and related rocks, Yukon-Tanana terrane, east-central Alaska

Using several isotopic techniques, we have determined the ages of selected metamorphic rocks in the Yukon-Tanana terrane (YTT) of east-central Alaska. U-Pb zircon data from an augen gneiss body in the Big Delta quadrangle indicate that the granitoid protolith of the gneiss was intruded 341 ± 3 m.y. ago (lower intercept age). An upper intercept age of 2,136 ± 31 m.y. indicates an inherited early Proterozoic component in these zircons. This inheritance age is substantiated by a Sm-Nd whole-rock model age of 2.09 ± 0.08 b.y. from the Big Delta augen gneiss body. Detrital zircons from quartzitic wall rocks to this body were also derived from an early Proterozoic (∼2.1 to 2.3 b.y. old) crustal source(s). Zircons from three other augen gneisses occurring in an east-west belt which extends into the southern Yukon Territory, Canada, have similar Mississippian and early Proterozoic intercept ages. A Rb-Sr whole-rock isochron from widely separated bodies of augen gneiss has an age of 333 ± 26 m.y. and an initial 87 Sr/ 86 Sr ratio of 0.728 ± 0.002, confirming the Mississippian intrusive age for the protolith. The high initial 87 Sr/ 86 Sr ratio further indicates an old crustal component in these rocks. A Rb-Sr mineral isochron (115 ± 4 m.y.), K-Ar data from hornblende and micas (128 to 107 m.y.), and U-Pb data from sphene (134. m.y.) from augen gneiss and related rocks are similar to many K-Ar ages in this region and confirm the occurrence of an early Cretaceous thermal event. U-Pb ages of zircons from three metavolcanic units in the YTT suggest that extrusion of the protoliths of these rocks occurred 360–380 m.y. ago. Scatter in the data is caused by ubiquitous inheritance and multiple lead-loss events.

Alaska↗

Geologic interpretation of reconnaissance aeromagnetic survey of northeastern Alaska

Aeromagnetic reconnaissance of northeastern Alaska in 1965 covered approximately 100,000 square miles, from lat 64° N. to the Arctic Ocean and from the Alaska-Yukon boundary to long 148°30' W. A magnetic contour map was compiled from data from the 1965 survey and earlier surveys. On the basis of these data, northeastern Alaska may be divided into five areas, each having a distinct magnetic character. A study of specific anomalies within these areas led to the tracing of such features as the Tintina fault zone, Ruby uplift, and Kobuk trench for more than 100 miles. Other features, such as inferred north-trending faults and serpentine belts, had not been identified previously by surface geologic methods. The probable extension of volcanic rocks beneath the Yukon Flats limits the size of a possible Tertiary petroleum basin. Discovery of large magnetic anomalies in the Yukon-Tanana Upland provides new possibilities for exploration for mineral deposits associated with ultramafic rocks.

Alaska↗

Some mineral deposits of Glacier Bay and vicinity, Alaska

Prospecting in the Glacier Bay National Monument has been confined so far to granitic rocks near contacts with Paleozoic sediments, which they intrude.Near Reid Glacier thin veins, a few of which are traceable for about 300 feet both horizontaliy and vertically, trend northerly and carry sphalerite, galena, and pyrite. Gold was panned from some of the better looking material.Near Sandy Cove, 30 miles away, more irregular, but locally thicker, veins appear to carry only pyrite. Here pyrite also occurs along the contact between the granitic rocks and the intruded limestone.Sparse ore minerals have been seen at other places in and near the monument. As yet, no large mineral deposits have been found there, but many miles of igneous contacts have not been prospected. In southeastern Alaska, as elsewhere, such contacts are considered favorable places in which to search for mineral deposits.

Alaska↗

Ground-water quality and geochemistry, Carson Desert, western Nevada

Aquifers in the Carson Desert are the primary source of drinking water, which is highly variable in chemical composition. In the shallow basin-fill aquifers, water chemistyr varies from a dilute calcium bicarbonate-dominated water beneath the irrigated areas to a saline sodium chloride- dominated water beneath unirrigated areas. Water samples from the shallow aquifers commonly have dissolved solids, chloride, magnesium, sulfate, arsenic, and manganese concentrations that exceed State of Nevada drinking-water standards. Water in the intermediante basin-fill aquifers is a dilute sodium bicarbonate type in the Fallon area and a distinctly more saline sodium chloride type in the Soda Lake-Upsal Hogback area. Dissolved solids, chloride, arsenic, fluoride, and manganese concen- trations commonly exceed drinking-water standards. The basalt aquifer contains a dilute sodium bicarbonate chloride water. Arsenic concentrations exceed standards in all sampled wells. The concen- trations of major constituents in ground water beneath the southern Carson Desert are the result of evapotranspiration and natural geochemical reactions with minerals derived mostly from igneous rocks. Water with higher concentrations of iron and manganese is near thermodynamic equilibrium with siderite and rhodochrosite and indicates that these elements may be limited by the solubility of their respective carbonate minerals. Naturally occurring radionuclides (uranium and radon-222) are present in ground water from the Carson Desert in concen- tratons higher than proposed drinking-water standards. High uranium concentrations in the shallow aquifers may be caused by evaporative concentration and the release of uranium during dissolution of iron and manganese oxides or the oxidation of sedimentary organic matter that typically has elevated uranium concentrations. Ground water in the Carson Desert does not appear to have be contaminated by synthetic organic chemicals.

Open-File Report↗

Sm-Nd, K-Ar and petrologic study of some kimberlites from eastern United States and their implication for mantle evolution

We provide new data on Sm-Nd systematics, K-Ar dating and the major element chemistry of kimberlites from the eastern United States (mostly from central New York State) and their constituent mineral phases of olivine, clinopyroxene, garnet, phlogopite and perovskite. In addition, we report Nd-isotopes in a few kimberlites from South Africa, Lesotho and from the eastern part of China. The major element compositions of the New York dike rocks and of their constituent minerals including a xenolith of eclogite are comparable with those from the Kimberley area in South Africa. The K-Ar age of emplacement of the New York dikes is further established to be 143 Ma. We have analyzed the Nd-isotopic composition of the following kimberlites and related rocks: Nine kimberlite pipes from South Africa and Lesotho, two from southern India; one from the U.S.S.R., fifteen kimberlite pipes and related dike rocks from eastern and central U.S. and two pipes from the Shandong Province of eastern China. The age of emplacement of these kimberlites ranges from 1300 million years to 90 million years. The initial Nd-isotopic compositions of these kimberlitic rocks expressed as e{open}NdIwith respect to a chondritic bulk-earth growth-curve show a range between 0 and +4, with the majority of the kimberlites being in the range 0 to +2. This range is not matched by any other suite of mantle-derived igneous rocks. This result strengthens our earlier conclusion that kimberlitic liquids are derived from a relatively primeval and unique mantle reservoir with a nearly chondritic Sm/Nd ratio. ?? 1984 Springer-Verlag.

Contributions to Mineralogy and Petrology↗

Hydrogeology of the Chickasaw National Recreation Area, Murray County, Oklahoma

The Travertine District (Park) of the Chickasaw National Recreation Area, operated and maintained by the National Park Service, is near the City of Sulphur in south-central Oklahoma. The Park was established in 1902 because of its unique hydrologic setting, which includes Rock Creek, Travertine Creek, numerous mineralized and freshwater springs, and a dense cover of riparian vegetation. Since the turn of the century several flowing artesian wells have been drilled within and adjacent to the Park. Discharge from many of these springs and the numbers of flowing wells have declined substantially during the past 86 years. To determine the cause of these declines, a better understanding of the hydrologic system must be obtained. The U.S. Geological Survey, in cooperation with the National Park Service, has appraised hydrologic information obtained for the Park from several studies conducted during 1902-87. The principal geologic units referred to in this report are the Arbuckle Group and the overlying Simpson Group. These rocks are of Upper Cambrian to Middle Ordovician age and are composed of dolomitic limestone, with some sandstones and shales in the Simpson Group. Surface geologic maps give a general understanding of the regional subsurface geology, but information about the subsurface geology within the Park is poor. The Simpson and Arbuckle aquifers are the principal aquifers in the study area. The two aquifers are not differentiated readily in some parts of the study area because of the similarity of the Simpson and Arbuckle rocks; thus, both water-bearing units are referred to frequently as the Arbuckle-Simpson aquifer. The aquifers are confined under the Park, but are unconfined east and south of the Park. Precipitation on the outcrop area of the Arbuckle aquifer northeast and east of the Park recharges the freshwater springs (Antelope and Buffalo Springs) near the east boundary of the Park. The source of water from mineralized springs located in the central part of the Park, and flowing wells within and north of the Park, is believed to be a mix of waters from rocks of the Arbuckle and Simpson Groups. The source of water from two highly mineralized springs, Bromide and Medicine, that ceased to flow in the early 1970’s is believed to be from the Simpson Group. Water-quality characteristics reflect the sources of ground water in the study area. The highly mineralized springs near the western end of the Park are a sodium chloride type with dissolved solids greater than 4,500 mg/L. The freshwater springs near the eastern end of the Park are a calcium bicarbonate type with total dissolved solids of less than 400 mg/L. Flow from the artesian wells has declined substantially during the past 86 years and the wells are estimated to currently discharge only about 10 percent of the total flow reported in 1939. The depletion is believed to be caused by a gradual lowering of the hydraulic head within the aquifer. The influence on the hydrologic system of local municipal and industrial pumping from the Arbuckle-Simpson aquifer is difficult to discern because the system is much more sensitive to precipitation than to pumpage. Ground-water levels and spring flows in this region respond rapidly to precipitation. The effects of withdrawals from the City of Sulphur and Oklahoma Gas and Electric Company power-plant water-well fields are not discernible at wells and springs. The hydrologic system may be influenced by pumping, particularly during extended dry periods of several years, but the impact of pumping on the system cannot be determined without further investigation.

Oklahoma↗

Improved Automated Identification and Mapping of Iron Sulfate Minerals, Other Mineral Groups, and Vegetation using Landsat 8 Operational Land Imager Data, San Juan Mountains, Colorado, and Four Corners Region

Multispectral remote sensing data acquired by the Landsat 8 Operational Land Imager (OLI) sensor were analyzed using a new, automated technique to generate a map of exposed mineral and vegetation groups in the western San Juan Mountains, Colo., and the Four Corners Region of the United States. Band ratio results were combined into displayed mineral and vegetation groups using Boolean algebra. New analysis logic has been implemented to exploit the coastal aerosol band in Landsat 8 OLI data and identify concentrations of iron sulfate minerals. These may indicate the presence of near-surface pyrite, which can be a potential nonpoint source of acid rock drainage. Zoned occurrences of iron sulfate minerals in areas surrounding and down gradient of known sources of pyrite have been mapped using this technique. They show high correlation with occurrences of jarosite-bearing mineral assemblages, as mapped using airborne imaging spectrometer data and supporting field verification surveys. Mapping the occurrence of iron sulfate minerals produced by the weathering and oxidation of pyrite in exposed hydrothermally altered rocks can also provide an important indicator of the genetic environment of alteration and the associated mineral deposit type. The automated analysis methodology is being employed to rapidly and cost-effectively generate maps of large regions of the United States in support of U.S. Geological Survey mineral resource and mineral-environmental assessments. This map, which includes the ERDAS IMAGINE thematic raster format in the data release, has been attributed by pixel value with mineral and vegetation group classification data, which can be queried in most image processing and GIS software packages.

Colorado, Utah↗

Regional mapping of hydrothermally altered igneous rocks along the Urumieh-Dokhtar, Chagai, and Alborz Belts of western Asia using Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) data and Interactive Data Language (IDL) logical operators: a tool for porphyry copper exploration and assessment

Regional maps of phyllic and argillic hydrothermal alteration were compiled using Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) data and logical operator algorithms. The area mapped extends from northwestern Iran to southeastern Pakistan and includes volcanic and magmatic arcs that make up the Urumieh-Dokhtar volcanic belt (UDVB), the Chagai volcanic belt (CVB), and the central part of the Alborz magmatic belt (AMB). The volcanic belts span the Zagros-Makran transform zone and the present day Baluchistan (Makran) volcanic arc. ASTER visible near infrared (VNIR) data contain three bands between 0.52 and 0.86 micrometers (μm) and the short-wave infrared (SWIR) data consist of six bands spanning 1.6 to 2.43 μm with 15-meter (m), and 30-m resolution, respectively. During the 8-year project, three different calibration methods were used to correct ASTER SWIR anomalies and produce ASTER calibrated reflectance data, which were then used to map hydrothermally altered rocks. Logical operators, used to map hydrothermally altered rocks, perform multiple band ratios and thresholds that can be applied to multiple ASTER scenes using a single algorithm, thus eliminating separate production and application of vegetation and dark pixel masks. Argillic and phyllic band ratio logical operators use band ratios that define the 2.17- and 2.20-μm absorption features to map kaolinite and alunite, typical in argillized rocks, and muscovite, which is a common mineral in phyllic alteration. Band thresholds for ratios in argillic and phyllic logical operator algorithms were determined by mapping known argillic and phyllic rocks at a calibration test site in Cuprite, Nevada, in the United States. The regional argillic and phyllic hydrothermal alteration map and geologic and deposit maps of the study area illustrate that distinct patterns of altered rocks are typically associated with certain types of mineral deposits. The central part of the UDVB contains numerous circular to elliptical patterns (1 to 5 kilometers in diameter) of mapped phyllic- and argillic-altered rocks associated with Eocene to Miocene intrusive igneous rocks, some of which host known porphyry copper deposits such as at Meiduk, Sar Cheshmeh, and Seridune in Iran. The Zagros-Makran transform zone and areas adjacent to the Saindak porphyry deposit and Taftan Volcano contain primarily phyllic-altered rocks that form linear patterns associated with extensive faulting and fractures indicative of epithermal and (or) polymetallic vein deposits. The ASTER alteration map and corresponding geologic maps were used to select circular to elliptical patterns of argillic- and phyllic-altered volcanic and intrusive rocks as potential porphyry copper sites. One hundred and seventy eight potential porphyry copper sites were mapped along the UDVB, and 23 sites were mapped along the CVB. The potential sites were selected to assist in further exploration and assessments of undiscovered porphyry copper deposits.

Scientific Investigations Report↗

Tungsten resources of the northern Rocky Mountains, Montana and Idaho— A synthesis and quantitative assessment of skarn-hosted resources

Mineral resource assessments performed by the U.S. Geological Survey provide a synthesis of available information about the location of known and suspected mineral deposits. This study focuses on skarn-hosted tungsten resources in the northern Rocky Mountain region of east-central Idaho and western Montana which have seen moderate tungsten trioxide production in the past from a variety of mineralization styles including skarn, vein and replacement, and wolframite-quartz veins. The area’s geology is dominated by large Cretaceous and Tertiary plutons that are emplaced into a belt of Mesoproterozoic to Permian sedimentary rock and affected by tectonism related to the Sevier and later Laramide orogenies. Known tungsten skarn mineral sites are associated with contacts between Cretaceous plutons and calcareous and argillaceous sedimentary or metasedimentary rocks, including two skarn deposits in Montana (Calvert and Browns Lake) that are consistent with an updated grade and tonnage model. This study (1) delineates permissive tracts where undiscovered tungsten skarn deposits may occur within 1 kilometer of the surface; (2) presents a tungsten mineral site dataset from a variety of public sources; (3) evaluates currently available geochemical, geophysical, and radiometric age data in support of tract delineation; (4) provides probabilistic estimates of the amount of tungsten and tungsten-mineralized rock that could be contained in undiscovered deposits within one major tract; (5) estimates the value of total undiscovered deposits using economic filter analysis; and (6) provides a synthesis of metallogenic controls on regional tungsten skarn and granitoid-related mineral deposits. Two permissive tracts were delineated: the Great Falls tectonic zone (GFTZ)-Cretaceous tract, for which a quantitative assessment was performed, and the Bitterroot tract, which was assessed in a qualitative manner. The quantitative three-part assessment, conducted in August 2019, indicates that undiscovered tungsten resources might exist in skarn-type deposits within the study area. Using a negative binomial function, a mean of 4 undiscovered deposits was calculated from panel estimates. Simulation results that combine an updated grade and tonnage model with estimates of undiscovered deposits include the amounts of ore and contained tungsten trioxide at different levels of uncertainty. A mean of 250,000 metric tons and median of 200,000 metric tons contained tungsten trioxide was calculated for the undiscovered deposits within the GFTZ-Cretaceous tract. The value of undiscovered deposits was estimated using a new economic filter that considers factors such as mine type, deposit depth, deposit geometry, metallurgical recovery rate, cutoff grade, and tract area. A review of the regional Archean to Paleogene geology suggests that ore metal (copper, molybdenum, and tungsten) variations in intrusion-related deposits of Montana and Idaho may be controlled by a number of factors including the age and composition of underlying basement terranes, depth of emplacement, pluton chemistry and degree of fractionation, redox conditions, and aqueous fluid-melt partition coefficients.

Idaho, Montana↗

A preliminary evaluation of stream sediment sampling for the detection of cobalt mineralization in the Bou Azzer District, Morocco

Analyses of 28 stream sediment samples collected in the Bou Azzer district, Morocco, show that this sampling technique may be useful in locating the cobalt arsenide mineralization that exists in this area. The absence of exceptionally high values of cobalt and arsenic, the nearly lognormal distribution of cobalt values, and the lack of correlation between the highest values of cobalt and arsenic were unanticipated results that do not support the use of this sampling technique. However, highest values of several metals, including cobalt, were associated with an identified area of cobalt mineralization, and high cobalt was present near a second area in which cobalt mineralization is suspected. Although probably mostly reflecting the geochemistry of unexposed ultramafic rocks, the association of these metals with mineralization shows that this type of sampling can independently locate areas of known or potential cobalt mineralization.

Open-File Report↗

Lead isotopic compositions of soil and near-surface till profiles from a watershed containing arsenic-enriched groundwater in coastal Maine

Lead isotope compositions of soils and near-surface tills from an area of coastal Maine known to have groundwater with anomalously high arsenic contents were measured in order to determine the source of the lead and, by inference, possible sources of arsenic. Five soil and till sites were selected for detailed chemical and isotopic analysis. To construct profiles of the soil and till horizons, five samples were collected at 10-cm intervals from the surface to the base of each horizon. Total lead and arsenic concentrations and lead isotopic compositions were measured for 48 leaches and bulk residues. The soils and tills are underlain by sulfidic schists of the Penobscot Formation. Several generations of minerals containing arsenic and lead exist in the regional bedrock, including rock-forming silicates (feldspar and micas), sulfide minerals formed during diagenesis (for example, arsenic-rich pyrite), and sulfide and oxide minerals that formed as a result of Silurian metamorphic and igneous events (for example, arsenopyrite, galena, iron-oxides, and arsenic-sulfides). A young group of secondary minerals (for example, iron-hydroxides, arsenic-hydroxides, lead-sulfate, and arsenic-jarosite) formed from recent weathering and pedogenic processes.

Maine↗

Mineral resources of the southern half of Zone III Santander, Norte de Santander and Boyaca, Colombia

The areas covered by this report lies in the eastern Cordillera of the Colombian Andes in the region around Bucaramanga. This part of the eastern Cordillera consists of a structurally complex core of metamorphic and igneous rocks of Precambrian to Mesozoic age, flanked to east and west by faulted and folded sedimentary strata of late Paleozoic to Tertiary age. Infaulted blocks of sedimentary rocks are locally present in the massif. Unconsolidated deposits of Quaternary age, primarily terraced alluvium, are 10cally extensive in valleys on the flanks of the range. The crystalline central core of the range is called the Santander massif. In it are located the principal sold deposits and scattered deposits of copper, lead, zinc, and fluorite. The sedimentary rocks flanking the massif contain significant deposits of phosphate rock and gypsum, as well as other nonmetallic industrial minerals such as limestone, barite, glass sand, and coal. A belt of lead-zinc prospects in carbonate and sandstone beds of Cretaceous age on the east side of the range warrants further investigation. Gold and silver are the only important metallic minerals that have been produced in the Santander massif. Mining dates back to colonial and possibly to pre-colonial times and continues on a small scale at present. The California and Vetas district was the main area of investigation of metallic minerals during the present project. Results of geochemical sampling of stream sediments and assays of vein material indicate that the main potential of the area is in gold with lesser potentials in copper, lead, zinc, and silver. Mineralization of the district is probably younger than Early Cretaceous. Although no copper minerals have been mined elsewhere in the massif, small amounts of copper minerals in various rocks in scattered areas is revealed by green and blue stains of copper carbonates and sulfates. Deposits of greatest areal extent are in arkosic conglomeratic beds of the Giron Formation. These are being explored and sampled at the present time (1969). A little lead has been mined and smelted in the past but operations were on a very small scale and of short duration. Small amounts of lead, zinc, and copper minerals accompany dolomite replacement of Cretaceous limestone in a few scattered places, and several promising prospects are being investigated by means of trenches and drilling. One magnetite and several hematite prospects were examined but none offers any potential for economic development. Thick beds of gypsum in Lower Cretaceous limestone on Mesa de Los Santos, south of Bucaramanga are being quarried from outcrops for use in cement manufacture. The deposit was discovered shortly before the present project began, and although its extent beneath overlying strata is not yet determined by drilling, it appears to be in a small evaporite basin of about three kilometers in radius. Reserves of gypsum are large, but future development will have to be by underground mining. Outcrops of Cretaceous limestone of high purity are widespread and are more than adequate to meet all demands, which at present are for cement and calcined lime, road construction material, and to a small extent for agricultural lime and polished decorative stone. Upper Paleozoic limestone of the Diamante Formation crops out in a few places; it has been used near Bucaramanga for cement manufacture. Marble is present in several localities of the Santander massif in Lower Paleozoic and Devonian rocks. Impurities, fractures, and solution cavities render most of it unsuitable for decorative purposes, but selected parts are used in floor tile and terrazo. Recrystallized limestone of the Diamante Formation in the same area, usually referred to as marble, is of uniform high purity throughout a thick and uninterrupted section, and offers a good source of limestone raw material. A little is now used for agricultural lime. The potential of this resource has not been fully evalua

Open-File Report↗

Porphyry copper assessment of Europe, exclusive of the Fennoscandian Shield: Chapter K in Global mineral resource assessment

The U.S. Geological Survey (USGS) collaborated with European geologists to assess resources in porphyry copper deposits in Europe, exclusive of Scandinavia (Sweden, Denmark, Norway, and Finland) and Russia. Porphyry copper deposits in Europe are Paleozoic and Late Cretaceous to Miocene in age. A number of the 31 known Phanerozoic deposits contain more than 1 million metric tons of contained copper, including the Majdanpek deposit, Serbia; Assarel, Bulgaria; Skouries, Greece; and Rosia Poeni, Romania. Five geographic areas were delineated as permissive tracts for post-Paleozoic porphyry copper deposits. Two additional tracts were delineated to show the extent of permissive igneous rocks associated with porphyry copper mineralization related to the Paleozoic Caledonian and Variscan orogenies. The tracts are based on mapped and inferred subsurface distributions of igneous rocks of specific age ranges that define areas where the occurrence of porphyry copper deposits within 1 kilometer of the Earth’s surface is possible. These tracts range in area from about 4,000 to 93,000 square kilometers. Although maps at a variety of different scales were used in the assessment, the final tract boundaries are intended for use at a scale of 1:1,000,000. The post-Paleozoic deposits in Europe all formed in conjunction with the tectonic evolution of southern Europe as the former Tethyan Ocean closed by convergence of the African and Arabian Plates with Europe, accompanied by accretion of microcontinents to the southern Eurasian Plate and development and demise of magmatic arcs and ocean basins. Many of the deposits formed in extensional or post-collisional settings; these tectonic environments are increasingly being recognized as environments where porphyry copper deposits occur. Probabilistic estimates of undiscovered porphyry copper deposits were made for four Phanerozoic permissive tracts; the other tracts are discussed qualitatively. Assessment participants estimated numbers of undiscovered deposits at different levels of confidence for the four tracts. These estimates were then combined with grade and tonnage models using Monte Carlo simulation to generate probabilistic estimates of amounts of in-place undiscovered resources. Additional resources that may be present in extensions of known deposits were not evaluated. Assessment results are reported in tables and graphs as expected amounts of metal and rock in undiscovered deposits at different quantile levels, as well as the arithmetic mean for each commodity for each tract. This assessment estimated a mean of 14 undiscovered porphyry copper deposits within the four permissive tracts for which estimates were made. On the basis of global grade and tonnage models, mean (arithmetic) estimated resources that could be associated with undiscovered deposits are about 46 million metric tons of copper and about 2,600 metric tons of gold, as well as byproduct molybdenum and silver. Reliable reported identified resources for the 27 deposits in the assessed areas total about 44 million metric tons of copper and about 2,300 metric tons of gold. Exploration for gold-rich porphyry systems is ongoing in some parts of historical copper mining districts in central Europe and in northwesternmost (European) Turkey. Political and social conflicts, environmental concerns associated with historical mining, and the global economic situation have had negative effects on exploration, development, and mining in Europe for many years. The assessment includes an overview with summary tables. Detailed descriptions of each tract, including the rationales for delineation and assessment, are given in appendixes A–G. Appendix H describes a geographic information system (GIS) that includes tract boundaries and point locations of known porphyry copper deposits and significant prospects.

Scientific Investigations Report↗

Low-grade, M1 metamorphism of the Douglas Island Volcanics, western metamorphic belt near Juneau, Alaska

The western metamorphic belt is part of the Coast plutonic-metamorphic complex of western Canada and southeastern Alaska that developed during collision of the Alexander terrane and Gravina assemblage on the west against the Yukon Prong and Stikine terranes to the east. Deformation, metamorphism, and plutonism range from about 120 to 50 Ma. Subgreenschist to lower greenschist facies metabasalts exposed along the west end of the western metamorphic belt near Juneau, Alaska, record the earliest metamorphic event (M 1 ). The protolith of the M 1 , low-grade metamorphic mineral assemblages is mostly arc-affinity basaltic rocks of the Douglas Island Volcanics. The most common metamorphic mineral assemblages are chlorite-epidote-actinolite with or without pumpellyite and stilpnomelane. There is no systematic distribution of metamorphic mineral assemblages in the study area, and all assemblages are in the pumpellyite-actinolite facies near the transition to the lower greenschist facies. Different low variance assemblages can be attributed to minor differences in pressure ( P ), temperature ( T ), or X CO2 . Mineral chemistry and phase equilibria suggest that thermal peak metamorphism of pumpellyite-bearing assemblages occurred at about 325 °C and 2 to 4.8 kbar.

Alaska↗

Zirconium and hafnium in the southeastern Atlantic States

The principal source of zirconium and hafnium is zircon, though a minor source is baddeleyite, mined only in Brazil. Zircon is an accessory mineral in igneous, metamorphic, and sedimentary rocks, but rarely occurs in hardrock in minable quantities. The principal sources of zircon are therefore alluvial deposits, which are mined in many countries of five continents. The principal commercial deposits in the United States are in Florida, though others exist elsewhere in the southeastern Coastal Plain. The evidence indicates that conditions for the accumulation of workable deposits of heavy minerals were more favorable during the interglacial stages of the Pleistocene epoch than during Recent time. Therefore detrital ores of large volume and high tenor are more likely to be found in the terrace deposits than along the present beaches. Other concentrations of heavy minerals, however, are possible at favored sites close to the Fall Line where the Tuscaloosa formation rests upon the crystalline rocks of the Piedmont province. A score of heavy and semiheavy minerals occur in the detrital deposits of Florida, but the principal salable minerals are ilmenite, leucoxene, rutile, and zircon, though monazite and staurolite are saved at some mining plants. Commercial deposits of heavy minerals are generally required to have a tenor of 4 percent, though ores with a lower tenor can be mined at a profit if the content of monazite is notably high. The percentages of zircon in the concentrates ranges from 10 to 16 percent, and in eastern Florida from 13 to 15 percent. Thus the tenor in zircon of the ore-bearing sands ranges from 0.4 to 0.6 percent. The content of hafnium in zircon is immaterial for many uses, but for some purposes very high or very low tenors in hafnium are required. Alluvial zircon cannot be separated into such varieties, which, if needed, must be obtained from sources in bedrock. It thus becomes necessary to determine the Hf : Zr ratios in zircon from many kinds of bedrock. Granitic rocks are the principal sources of zircon, though not the best sources of zircon with a high tenor in hafnium. A general study by the Geological Survey of the granitic rocks of the Southeastern Atlantic States has been in progress for 10 years, and hundreds of samples of granitic accessory minerals have been acquired. Thirty samples of zircon from these collections were selected for spectrographic and X-ray determinations of their tenors in hafnium. Nine other samples of alluvial zircon were included, of which three are from Florida and six from foreign countries. No domestic zircon was discovered with very high or very low tenors in hafnium. The volume of zircon in the southeastern Coastal Plain is enormous, but most of it is not recoverable. The minable reserves of heavy minerals, however, are very large, and from these it is estimated conservatively that 10 million short tons of zircon can be obtained. The corresponding amounts of zirconium and hafnium, using the mean Hf:Zr ratio of the deposits in Florida, are 4,868,000 and 112,000 tons, respectively. These reserves could be delivered, if needed, at the rate of 100,000 tons a year.

Florida, Georgia, North Carolina, South Carolina, ↗

Genesis of the Questa Mo porphyry deposit and nearby polymetallic mineralization, New Mexico, USA

The Oligocene Latir magmatic center in northern New Mexico is an exceptionally well-exposed volcanoplutonic complex that hosts a variety of magmatic-hydrothermal deposits, ranging from relatively deep, F-rich porphyry Mo mineralization to shallower epithermal deposits. We present new whole-rock chemical and isotopic data for plutonic rocks from the Latir magmatic center, including extensive sampling of drill core samples of intrusive rocks from the Questa porphyry Mo deposit. These data document temporal chemical trends of porphyry-related mineralization that occurred after caldera-forming magmatism and during postcaldera batholith assembly. Silicic magmas were generated multiple times throughout the history of the Latir magmatic center, but few are associated with the formation of a mineral deposit. Whole-rock trace element ratios and Sr, Nd, and Pb isotope compositions vary throughout the protracted history of silicic magmatism. The caldera-forming ignimbrite and early phase of postcaldera intrusions are unmineralized, more enriched in high field strength elements, and generally contain less radiogenic Sr and Pb and more radiogenic Nd than later intrusions. The Questa porphyry Mo deposit formed immediately after the most isotopically primitive phase of the batholith was assembled, ruling out simple reworking of juvenile mantle-derived crust as the source for mineralizing magmas. Rhyolite dikes associated with polymetallic sulfide deposits intruded ~800 k.y. after Mo mineralization, and Nd isotope data indicate that these dikes are associated with different batches of magma and are unrelated to the Mo-mineralizing intrusions at the Questa mine. Together, these data indicate that the source of magmas changed significantly throughout the 10-m.y. history of the magmatic center. We assess multiple genetic models for porphyry-related magmatism against this data set, favoring models with discrete periods of magma genesis from a deep hybridized zone in the lower crust giving rise to the punctuated periods of mineralization. These observations suggest that the formation of mineral deposits within a central magmatic locus is likely the result of the piecemeal assembly of individual hydrothermal-magmatic systems, and that distal and younger polymetallic mineralization commonly observed near known porphyry deposits represents decoupled processes.

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