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Water-resources activities of the U.S. Geological Survey in Texas– Fiscal year 1987

The U.S. Geological Survey (USGS) was established by an act of Congress on March 3, 1879, to provide a permanent Federal agency to conduct the systematic and scientific classification of the public lands and to examine the geological structure, mineral resources, and products of national domain. An integral part of that original mission includes publishing and disseminating the earth science information needed to understand, to plan the use of, and to manage the Nation's energy, land, mineral, and water resources. Since 1879, the research and fact-finding role of the USGS has grown and been modified to meet the changing needs of the Nation it serves. As part of that evolution, the USGS has become the Federal Government's largest earthscience research agency, the Nation's largest civilian mapmaking agency, the primary source of data on the Nation's surface- and ground-water resources, and the employer of the largest number of professional earth scientists. Today's programs serve a diversity of needs and users. Programs include: Conducting detailed assessments of the energy and mineral potential of the Nation's land and offshore areas. Investigating and issuing warnings of earthquakes, volcanic eruptions, landslides, and other geologic and hydrologic hazards. Conducting research on the geologic structure of the Nation. Studying the geologic features, structure, processes, and history of the other planets of our solar system. Conducting topographic surveys of the Nation and preparing topographic and thematic maps and related cartographic products. Developing and producing digital cartographic data bases and products. Collecting data on a routine basis to determine the quantity, quality, and use of surface and ground water. Conducting water-resources appraisals in order to describe the consequences of alternative plans for developing land and water resources. Conducting research in hydraulics and hydrology and coordinating all Federal water-data acquisition. Using remotely sensed data to develop new cartographic, geologic, and hydrologic research techniques for natural resources planning and management. Providing earth-science information through an extensive publications program and a network of public access points. Along with its continuing commitment to meet the growing and changing earthscience information needs of the Nation, the USGS remains dedicated to its original mission to collect, analyze, interpret, publish, and disseminate information about the natural resources of the Nation providing "earth science in the public service."

Texas↗

Hydrogeologic terranes and potential yield of water to wells in the Valley and Ridge Physiographic Province in the eastern and southeastern United States

The Valley and Ridge Physiographic Province is underlain by deformed sedimentary rock of Paleozoic age including dolomite, limestone, shale, and sandstone. Regolith (soil, sediment, and weathered rock) covers the Paleozoic rock throughout most of the province. Local differences in lithology, structure, and weathering can result in four orders of magnitude variation in the water-yielding properties of the geologic units that underlie the area. Selected rock types, however, can account for a substantial part of this variation because of the unique way in which these dense, consolidated sedimentary rock types deform and weather to produce secondary openings. On the basis of relations among rock type, water-yielding openings, and water-yielding properties (as indicated by specific capacity), the regolith and consolidated rock were classified and mapped as five hydrogeologic terranes alluvium, dolomite, limestone, argillaceous carbonate rock, and siliciclastic rock. The hydrogeologic terranes are named after the predominant outcrop lithology within them. The western toe of the Blue Ridge Mountains is classified as a subdivision of the dolomite hydrogeologic terrane that may produce yields of water in excess of 1,000 gallons per minute (gal/min) to public and industrial supply wells. Specific-capacity data for homogeneous data sets, which consist of all wells that have the same characteristics in regard to casing diameter, primary use of the water, and topographic setting, revealed significant differences in water-yielding properties among the five hydrogeologic terranes. According to results of Tukey statistical tests at a probability (alpha level) of 0.05, 8 out of 10 pairs of hydrogeologic terranes (for example, alluvium/limestone) had significantly different median specific-capacity values. The median value for public and industrial supply wells in the western toe is three times greater than the value for comparable wells in the dolomite hydrogeologic terrane elsewhere. Estimates of potential yields to public and industrial supply wells were calculated from specific-capacity data for most-productive wells, which have casing diameter of 7 in. or more, discharge water primarily for public or industrial supply, and are in a valley. Median constant drawdowns, calculated from reported drawdowns, were assumed to be between 10 and 90 ft for wells completed in each of the five hydrogeologic terranes, and well-entrance losses were assumed to be negligible. Estimated interquartile ranges in potential yields to 412 mostproductive wells in the five hydrogeologic terranes were 170 to 580 gal/min, alluvium; 210 to 1,400 gal/min, dolomite; 80 to 720 gal/min, limestone; 65 to 850 gal/min, argillaceous carbonate rock; and 70 to 280 gal/min, siliciclastic rock.

Alabama, Georgia, Maryland, New Jersey, Pennsylvan↗

Applications of research from the U.S. Geological Survey program, assessment of regional earthquake hazards and risk along the Wasatch Front, Utah

INTERACTIVE WORKSHOPS: ESSENTIAL ELEMENTS OF THE EARTHQUAKE HAZARDS RESEARCH AND REDUCTION PROGRAM IN THE WASATCH FRONT, UTAH: Interactive workshops provided the forum and stimulus necessary to foster collaboration among the participants in the multidisciplinary, 5-yr program of earthquake hazards reduction in the Wasatch Front, Utah. The workshop process validated well-documented social science theories on the importance of interpersonal interaction, including interaction between researchers and users of research to increase the probability that research will be relevant to the user's needs and, therefore, more readily used. REDUCING EARTHQUAKE HAZARDS IN UTAH: THE CRUCIAL CONNECTION BETWEEN RESEARCHERS AND PRACTITIONERS: Complex scientific and engineering studies must be translated for and transferred to nontechnical personnel for use in reducing earthquake hazards in Utah. The three elements needed for effective translation, likelihood of occurrence, location, and severity of potential hazards, and the three elements needed for effective transfer, delivery, assistance, and encouragement, are described and illustrated for Utah. The importance of evaluating and revising earthquake hazard reduction programs and their components is emphasized. More than 30 evaluations of various natural hazard reduction programs and techniques are introduced. This report was prepared for research managers, funding sources, and evaluators of the Utah earthquake hazard reduction program who are concerned about effectiveness. An overview of the Utah program is provided for those researchers, engineers, planners, and decisionmakers, both public and private, who are committed to reducing human casualties, property damage, and interruptions of socioeconomic systems. PUBLIC PERCEPTIONS OF THE IMPLEMENTATION OF EARTHQUAKE MITIGATION POLICIES ALONG THE WASATCH FRONT IN UTAH: The earthquake hazard potential along the Wasatch Front in Utah has been well defined by a number of scientific and engineering studies. Translated earthquake hazard maps have also been developed to identify areas that are particularly vulnerable to various causes of damage such as ground shaking, surface rupturing, and liquefaction. The implementation of earthquake hazard reduction plans are now under way in various communities in Utah. The results of a survey presented in this paper indicate that technical public officials (planners and building officials) have an understanding of the earthquake hazards and how to mitigate the risks. Although the survey shows that the general public has a slightly lower concern about the potential for economic losses, they recognize the potential problems and can support a number of earthquake mitigation measures. The study suggests that many community groups along the Wasatch Front, including volunteer groups, business groups, and elected and appointed officials, are ready for action-oriented educational programs. These programs could lead to a significant reduction in the risks associated with earthquake hazards. A DATA BASE DESIGNED FOR URBAN SEISMIC HAZARDS STUDIES: A computerized data base has been designed for use in urban seismic hazards studies conducted by the U.S. Geological Survey. The design includes file structures for 16 linked data sets, which contain geological, geophysical, and seismological data used in preparing relative ground response maps of large urban areas. The data base is organized along relational data base principles. A prototype urban hazards data base has been created for evaluation in two urban areas currently under investigation: the Wasatch Front region of Utah and the Puget Sound area of Washington. The initial implementation of the urban hazards data base was accomplished on a microcomputer using dBASE III Plus software and transferred to minicomputers and a work station. A MAPPING OF GROUND-SHAKING INTENSITIES FOR SALT LAKE COUNTY, UTAH: This paper documents the development of maps showing a

Professional Paper↗

Stratigraphic Notes

Welcome to the resurrected series of U.S. Geological Survey (USGS) reports on stratigraphy entitled “Stratigraphic Notes.” For several decades, until the mid-1990s, the USGS published volumes of short papers that highlighted stratigraphic studies, changes in stratigraphic nomenclature, and explanations of stratigraphic names and concepts used on published geologic maps. The purpose was to encourage formal documentation on these topics. Today (2023) the need for such documentation has become especially important because of the increasing number of informal reports that use new or updated stratigraphic nomenclature. Because the North American Stratigraphic Code does not recognize informal reports as proper publications to formalize stratigraphic studies, a report series such as “Stratigraphic Notes” is needed to bridge this gap. “Stratigraphic Notes” is a long-term (multiyear), multivolume publication containing articles that address updates or revisions to stratigraphic nomenclature (and whose content ultimately will be incorporated into Geolex, https://ngmdb.usgs.gov/Geolex/ ). The papers in “Stratigraphic Notes” are meant to be an outlet to communicate changes in stratigraphic nomenclature, to support geologic map publications, and to facilitate compilation of new geologic maps and their databases. The goal is to publish a new volume each year, each of which will contain papers that present results of stratigraphic studies drawn from scientific interpretations of stratigraphic and biostratigraphic changes related to changes in environments of deposition and facies, as well as interpretations of igneous and metamorphic units. We welcome papers for the “Stratigraphic Notes” series from geoscientists of the USGS, of State Geological Surveys, and from academicians. Papers can be submitted for publication in “Stratigraphic Notes” by contacting the USGS Geologic Names Committee ( gnc@usgs.gov ). As new “Stratigraphic Notes” volumes are published, links to the volumes will be posted here at https://doi.org/10.3133/pp1879 .

Professional Paper↗

Aquifer properties, stream base flow, water use, and water levels in the Pohatcong Valley, Warren County, New Jersey

A study was conducted to define the hydrogeology and describe the ground-water flow in the Pohatcong Valley in Warren County, N.J. near the Pohatcong Valley Ground Water Contamination Site. The area is underlain by glacial till and alluvial sediments and weathered and competent carbonate bedrock. The northwest and southeast valley boundaries are regional-scale thrust faults and ridges underlain by crystalline rocks. The unconsolidated sediments and weathered bedrock form a minor surficial aquifer. The carbonate rocks form a highly transmissive fractured-rock aquifer with well yields commonly as high as 500 gallons per minute. Ground-water recharge and flow in the crystalline-rock aquifer bordering the valley is minor compared to flow in the carbonate-rock aquifer, and little ground water flows into the carbonate-rock aquifer directly from the crystalline-rock aquifer. The thrust faults separating the carbonate and crystalline rocks may further impede flow between the two rock types. Interpretations of water-level and transmissivity data collected during 2000 to 2003 indicate that the carbonate formations generally can be considered to be one aquifer. The transmissivity of the carbonate-rock aquifer was estimated from the results of four aquifer tests conducted with two public supply wells. The transmissivity estimated from aquifer tests at a well located in Washington Borough is about 8,600 square feet per day. An aquifer test at a well located near the southwest border of Washington Borough was conducted to estimate transmissivity and the direction and magnitude of anisotropy. The estimated direction of maximum horizontal transmissivity near the second well is about 58? east of north and the magnitude is 7,600 square feet per day. The minimum horizontal transmissivity is 3,500 square feet per day and the ratio of anisotropy (maximum transmissivity to minimum transmissivity) is 2.2 to 1. Stream base-flow data indicate that Pohatcong Creek steadily gains flow, but most of the gain is from tributaries originating in the crystalline rock areas (valley walls). Therefore, it is concluded there are no major heterogeneities (such as karst springs) in ground-water discharge to surface water. During periods of low ground-water levels, it is likely that, within the study area, Pohatcong Creek gains no flow from the carbonate-rock aquifer and may even lose flow to the surficial aquifer (which then recharges the carbonate-rock aquifer). There are few sites in the Pohatcong Valley with large-scale (greater than 10 million gallons per year) ground- or surface-water withdrawals. The only substantial withdrawals in the valley are from two public supply wells and from two industrial facilities. Average annual withdrawals during 1997-2002 at these four locations totaled 298 million gallons per year. About 95 percent of the water withdrawn by the large industrial user (108 million gallons per year) is re-injected into the aquifer. In some locations throughout the valley, water levels in the shallow surficial deposits were substantially higher than those in underlying carbonate-rock aquifer. Water levels in the deep part of the surficial aquifer and underlying carbonate-rock aquifer were similar, although the gradients were often (but not always) downward. Furthermore, data collected during aquifer tests at a public supply well in Washington Borough and a public-supply well west of Washington Borough show that the deep part of the surficial aquifer is hydraulically well connected to the underlying carbonate-rock aquifer at these two locations. The shallow surficial deposits, however, are not well connected to the deep surficial deposits and carbonate rock at these two locations. The overall ground-water-flow pattern in the valley appears to be that precipitation recharges the surficial aquifer and is discharged from the surficial aquifer to the underlying bedrock aquifer and the Pohatcong Creek and its tri

Scientific Investigations Report↗

Application of health-based screening levels to ground-water quality data in a state-scale pilot effort

A state-scale pilot effort was conducted to evaluate a Health-Based Screening Level (HBSL) approach developed for communicating findings from the U.S. Geological Survey (USGS) National Water-Quality Assessment Program in a human-health context. Many aquifers sampled by USGS are used as drinking-water sources, and water-quality conditions historically have been assessed by comparing measured contaminant concentrations to established drinking-water standards and guidelines. Because drinking-water standards and guidelines do not exist for many analyzed contaminants, HBSL values were developed collaboratively by the USGS, U.S. Environmental Protection Agency (USEPA), New Jersey Department of Environmental Protection, and Oregon Health & Science University, using USEPA toxicity values and USEPA Office of Water methodologies. The main objective of this report is to demonstrate the use of HBSL approach as a tool for communicating water-quality data in a human-health context by conducting a retrospective analysis of ground-water quality data from New Jersey. Another important objective is to provide guidance on the use and interpretation of HBSL values and other human-health benchmarks in the analyses of water-quality data in a human-health context. Ground-water samples collected during 1996-98 from 30 public-supply, 82 domestic, and 108 monitoring wells were analyzed for 97 pesticides and 85 volatile organic compounds (VOCs). The occurrence of individual pesticides and VOCs was evaluated in a human-health context by calculating Benchmark Quotients (BQs), defined as ratios of measured concentrations of regulated compounds (that is, compounds with Federal or state drinking-water standards) to Maximum Contaminant Level (MCL) values and ratios of measured concentrations of unregulated compounds to HBSL values. Contaminants were identified as being of potential human-health concern if maximum detected concentrations were within a factor of 10 of the associated MCL or HBSL (that is, maximum BQ value (BQmax) greater than or equal to 0.1) in any well type (public supply, domestic, monitoring). Most (57 of 77) pesticides and VOCs with human-health benchmarks were detected at concentrations well below these levels (BQmax less than 0.1) for all three well types; however, BQmax values ranged from 0.1 to 3,000 for 6 pesticides and 14 VOCs. Of these 20 contaminants, one pesticide (dieldrin) and three VOCs (1,2-dibromoethane, tetrachloroethylene, and trichloroethylene) both (1) were measured at concentrations that met or exceeded MCL or HBSL values, and (2) were detected in more than 10 percent of samples collected from raw ground water used as sources of drinking water (public-supply and (or) domestic wells) and, therefore, are particularly relevant to human health. The occurrence of multiple pesticides and VOCs in individual wells also was evaluated in a human-health context because at least 53 different contaminants were detected in each of the three well types. To assess the relative human-health importance of the occurrence of multiple contaminants in different wells, the BQ values for all contaminants in a given well were summed. The median ratio of the maximum BQ to the sum of all BQ values for each well ranged from 0.83 to 0.93 for all well types, indicating that the maximum BQ makes up the majority of the sum for most wells. Maximum and summed BQ values were statistically greater for individual public-supply wells than for individual domestic and monitoring wells. The HBSL approach is an effective tool for placing water-quality data in a human-health context. For 79 of the 182 compounds analyzed in this study, no USEPA drinking-water standards or guidelines exist, but new HBSL values were calculated for 39 of these 79 compounds. The new HBSL values increased the number of detected pesticides and VOCs with human-health benchmarks from 65 to 77 (of 97 detected compounds), thereby expanding the basis for interpreting contaminant-occu

Scientific Investigations Report↗

The Amphibian Research and Monitoring Initiative (ARMI): 5-year report

The Amphibian Research and Monitoring Initiative (ARMI) is an innovative, multidisciplinary program that began in 2000 in response to a congressional directive for the Department of the Interior to address the issue of amphibian declines in the United States. ARMI’s formulation was cross-disciplinary, integrating U.S. Geological Survey scientists from Biology, Water, and Geography to develop a course of action (Corn and others, 2005a). The result has been an effective program with diverse, yet complementary, expertise. ARMI’s approach to research and monitoring is multiscale. Detailed investigations focus on a few species at selected local sites throughout the country; monitoring addresses a larger number of species over broader areas (typically, National Parks and National Wildlife Refuges); and inventories to document species occurrence are conducted more extensively across the landscape. Where monitoring is conducted, the emphasis is on an ability to draw statistically defensible conclusions about the status of amphibians. To achieve this objective, ARMI has instituted a monitoring response variable that has nationwide applicability. At research sites, ARMI focuses on studying species/environment interactions, determining causes of observed declines, and developing new techniques to sample populations and analyze data. Results from activities at all scales are provided to scientists, land managers, and policymakers, as appropriate. The ARMI program and the scientists involved contribute significantly to understanding amphibian declines at local, regional, national, and international levels. Within National Parks and National Wildlife Refuges, findings help land managers make decisions applicable to amphibian conservation. For example, the National Park Service (NPS) selected amphibians as a vital sign for several of their monitoring networks, and ARMI scientists provide information and assistance in developing monitoring methods for this NPS effort. At the national level, ARMI has had major exposure at a variety of meetings, including a dedicated symposium at the 2004 joint meetings of the Herpetologists’ League, the American Society of Ichthyologists and Herpetologists, and the Society for the Study of Amphibians and Reptiles. Several principal investigators have brought international exposure to ARMI through venues such as the World Congress of Herpetology in South Africa in 2005 (invited presentation by Dr. Gary Fellers), the Global Amphibian Summit, sponsored by the International Union for Conservation of Nature (IUCN) and Wildlife Conservation International, in Washington, D.C., 2005 (invited participation by Dr. P.S. Corn), and a special issue of the international herpetological journal Alytes focused on ARMI in 2004 (edited by Dr. C.K. Dodd, Jr.). ARMI research and monitoring efforts have addressed at least 7 of the 21 Threatened and Endangered Species listed by the U.S. Fish and Wildlife Service (California red-legged frog [Rana draytonii], Chiricahua leopard frog [R. chiricahuensis], arroyo toad [Bufo californicus], dusky gopher frog [Rana sevosa], mountain yellow-legged frog [R. muscosa], flatwoods salamander [Ambystoma cingulatum], and the golden coqui [Eleutherodactylus jasperi]), and 9 additional species of concern recognized by the IUCN. ARMI investigations have addressed time-sensitive research, such as emerging infectious diseases and effects on amphibians related to natural disasters like wildfire, hurricanes, and debris flows, and the effects of more constant, environmental change, like urban expansion, road development, and the use of pesticides. Over the last 5 years, ARMI has partnered with an extensive list of government, academic, and private entities. These partnerships have been fruitful and have assisted ARMI in developing new field protocols and analytic tools, in using and refining emerging technologies to improve accuracy and efficiency of data handling, in conducting amphibian disease, malformation, and environmental effects research, and in implementing a network of monitoring and research sites. Accomplishments from these endeavors include more than 40 publications on amphibian status and trends, nearly 100 publications on amphibian ecology and causes of declines, and over 30 methodological publications. Several databases have emerged as a result of ARMI and its partnerships; one, a digital atlas of ranges for all U.S. amphibian species, was used by the IUCN to display amphibian distribution maps in the Global Amphibian Assessment Project. Given the scope of ARMI and the panoply of projects, findings have had implications for policy. Investigations that demonstrate amphibian declines or illuminate causes of declines provide valuable information about habitat management, environmental effects, mechanisms for the spread of disease, and human/amphibian interfaces. This information has been made available to land managers, scientists, educators, Congress and other policymakers, and the public. The support afforded ARMI by Congress has been influential in the program’s development and success. The value of ARMI’s efforts will continue to increase as we are able to extend our studies spatially and temporally to answer critical questions with more confidence. We are using ARMI’s resources efficiently and continuing to develop innovative mechanisms for leveraging resources for maximum effectiveness during challenging financial times. This report is a 5-year retrospective of the structure, methodology, progress, and contributions to the broader scientific community that have resulted from this national USGS program. We evaluate ARMI’s success to date, with regard to the challenges faced by the program and the strengths that have emerged. We chart objectives for the next 5 years that build on current accomplishments, highlight areas meriting further research, and direct efforts to overcome existing weaknesses.

Scientific Investigations Report↗

Processes Affecting Phosphorus and Copper Concentrations and Their Relation to Algal Growth in Two Supply Reservoirs in the Lower Coastal Plain of Virginia, 2002-2003, and Implications for Alternative Management Strategies

Elevated phosphorus concentrations commonly promote excessive growth of algae in waters nationwide. When such waters are used for public supply, the algae can plug filters during treatment and impart tastes and odors to the finished water. This increases treatment costs and results in finished water that may not be of the quality desired for public supply. Consequently, copper sulfate is routinely applied to many reservoirs to control algal growth but only is a 'temporary fix' and must be reapplied at intervals that can range from more than 30 days in the winter to less than 7 days in the summer. Because copper has a maximum allowable concentration in public drinking water and can be toxic to aquatic life, water suppliers commonly seek to develop alternative, long-term strategies for managing reservoirs. Because these are nationwide issues and part of the mission of the U.S. Geological Survey (USGS) is to define and protect the quality of the Nation's water resources and better understand the physical, chemical, and biological processes in wetlands, lakes, reservoirs, and estuaries, investigations into these issues are important to the fulfillment of the mission of the USGS. The City of Newport News, Virginia, provides 50 million gallons per day of treated water for public supply from Lee Hall and Harwoods Mill Reservoirs (terminal reservoirs) to communities on the lower York-James Peninsula. About 3,500 pounds of copper sulfate are applied to each reservoir at 3- to 99-day intervals to control algal growth. Consequently, the USGS, in cooperation with the City of Newport News, investigated the effects of management practices and natural processes on phosphorus (the apparent growth-limiting nutrient), copper, and algal concentrations in the terminal reservoirs to provide information that can be used to develop alternative management strategies for the terminal reservoirs. Initial parts of the research evaluated circulation and stratification in the reservoirs because these factors affect phosphorus availability to algae. Results indicate that (1) water flows through both reservoirs in a 'plug-flow' manner; (2) little water in the lower part of Lee Hall Reservoir, into which pumped water enters, flows into the upper part of the reservoir and mixes with that water; (3) Lee Hall Reservoir generally does not stratify; and (4) Harwoods Mill Reservoir stratifies from April to June through September or October into an upper epilimnion that does not mix with water in the lower hypolimnion. The ratio of dissolved nitrogen to phosphorus concentrations (N:P) for sites in both reservoirs generally was greater than 20:1, indicating that phosphorus likely is the growth-limiting nutrient in both reservoirs. Phosphorus was present predominantly as suspended, rather than dissolved, species except in the hypolimnion of Harwoods Mill Reservoir and the natural inflow represented by Baptist Run. Because Harwoods Mill Reservoir stratified, field-measured physical and chemical characteristics and concentrations of nitrogen and phosphorus species changed sharply over short depth intervals in this reservoir. Dissolved phosphorus concentration increased from 0.015 to 0.057 milligrams per liter between a depth of 15 feet (ft) and the bottom (depth of 18 ft), indicating the release of phosphorus by the decomposition of organic material and(or) the reduction of iron oxides in bed sediment and the lower water column. Because the mixing boundary between the epilimnion and the hypolimnion likely was between depths of 6 and 10 ft, such sources in the hypolimnion would not contribute phosphorus to the growth of algae in the epilimnion from which water is withdrawn for supply until the breakdown of stratification in the fall. Furthermore, laboratory studies of samples from both reservoirs indicated that dissolved phosphorus was released from suspended particles at rates of 0.0007 to 0.0019 milligrams per liter per day. At these rates of release, particl

Scientific Investigations Report↗

Water use in Georgia by county for 2005; and water-use trends, 1980-2005

Water use for 2005 for each county in Georgia was estimated using data obtained from various Federal and State agencies and local sources. Total consumptive water use also was estimated for each county in Georgia for 2005. Estimates of offstream water use include the categories of public supply, domestic, commercial, industrial, mining, irrigation, livestock, and thermoelectric power. The only category of instream use estimated was hydroelectric-power generation. Total offstream water use from ground- and surface-water sources was about 5,471 million gallons per day (Mgal/d) in 2005. Surface water used in the process of thermoelectric-power generation was the largest volume of water withdrawn with withdrawals of 2,717 Mgal/d in 2005. Estimated instream water use for hydroelectric-power generation was 54,096 Mgal/d. Withdrawals for irrigation totaled 752 Mgal/d with 65 percent supplied by ground-water sources. Surface water provided 78 percent of the 1,180 Mgal/d withdrawn for public supply. Many counties in the northern Piedmont physiographic province of Georgia, an area of dense population, had a large percentage of withdrawals from surface-water sources. In contrast, in the southern Coastal Plain physiographic province part of the State, many counties had more withdrawals from ground-water sources. As part of the Georgia Water-Use Program, statewide water-use estimates have been compiled every 5 years since 1980. During this period, water use was greatest in 1980 at 6,725 Mgal/d. Water use decreased by 31 percent to 5,353 Mgal/d in 1990 then increased to 6,487 Mgal/d in 2000. By 2005, water withdrawals had decreased to an estimated 5,471 Mgal/d primarily because of a decline in withdrawals for thermoelectric-power generation and a decline in demands as 2005 was a normal year for precipitation compared to 2000, which was in drought. Throughout the period 1980–2005, water withdrawn for thermoelectric-power generation made up the largest volume of offstream water use in Georgia. Total withdrawals for thermoelectric-power generation decreased about 24 percent in 2005 compared to 2000, due to the decommissioning of three power plants in the State. In addition, several plants operated by Georgia Power Company were retooled during this period to increase water conservation. Public-supply use steadily increased from 1980 to 2000, concurrent with increasing population in the State; however, in 2005, there was a slight decrease in public-supply use. Conversely, industrial water use decreased during the period 1980–2005. Water withdrawals for irrigation during 1980–2005 followed changing hydrologic conditions, increasing during drier years (1980 and 2000) and decreasing during normal or wetter years. Withdrawals for the categories of domestic and commercial use remained about the same during 1980–2005. Livestock and mining use increased in 2005 compared to the 2000 estimates because of changes in estimation techniques. Consumptive water use was determined for each category of use and compiled for each county. Estimation techniques vary for each water-use category. While consumptive use varied for each county in 2005, from about 1 percent to nearly 100 percent of total withdrawals, consumptive-use estimates for the entire State totaled 1,310 Mgal/d, about 24 percent of total withdrawals.

Georgia↗

Variations in Withdrawal, Return Flow, and Consumptive Use of Water in Ohio and Indiana, with Selected Data from Wisconsin, 1999-2004

This report contains an analysis of water withdrawal and return-flow data for Ohio and withdrawal data for Indiana and Wisconsin to compute consumptive-use coefficients and to describe monthly variability of withdrawals and consumptive use. Concurrent data were available for most water-use categories from 1999 through 2004. Average monthly water withdrawals are discussed for a variety of water-use categories, and average water use per month is depicted graphically for Ohio, Indiana, and Wisconsin (public supply only). For most water-use categories, the summer months were those of highest withdrawal and highest consumptive use. For public supply, average monthly withdrawals ranged from 1,380 million gallons per day (Mgal/d) (November) to 1,620 Mgal/d (July) in Ohio, 621 Mgal/d (December) to 816 Mgal/d (July) in Indiana, and 515 Mgal/d (December) to 694 Mgal/d (July) in Wisconsin. Ohio and Indiana thermoelectric facilities had large increases in average monthly withdrawals in the summer months (5,520 Mgal/d in March to 7,510 Mgal/d in August for Indiana; 7,380 Mgal/d in February to 10,040 Mgal/d in July for Ohio), possibly because of increased electricity production in the summer, a need for additional cooling-water withdrawals when intake-water temperature is high, or use of different types of cooling methods during different times of the year. Average industrial withdrawals ranged from 2,220 Mgal/d (December) to 2,620 Mgal/d (August) in Indiana and from 707 Mgal/d (January) to 787 Mgal/d (August) in Ohio. The Ohio and Indiana irrigation data showed that most withdrawals were in May through October for golf courses, nurseries, and crop irrigation. Commercial water withdrawals ranged from 30.4 Mgal/d (January) to 65.0 Mgal/d (September) in Indiana and from 23.2 Mgal/d (November) to 49.5 Mgal/d (August) in Ohio; commercial facilities that have high water demand in Ohio and Indiana are medical facilities, schools, amusement facilities, wildlife facilities, large stores, colleges, correctional institutions, and national security facilities. Monthly livestock withdrawals were constant for Ohio but were more variable in Indiana and depended on whether the livestock facility operated on a seasonal schedule. Aquaculture withdrawals appeared to correlate with growing seasons and with aeration of ponds during the winter months. Mining withdrawals - specifically, those for nonmetallic mining - tended to be highest in April and may be related to dewatering. Consumptive use and consumptive-use coefficients were computed by two principal methods in this study: the return-flow and withdrawal method (RW; Ohio only) and the winter-base-rate method (WBR; Ohio, Indiana and Wisconsin). The WBR method was not suitable for the thermoelectric, industrial, irrigation, livestock, aquaculture, and mining water-use categories. The RW method was not used for public-supply facilities. A third method, the Standard Industrial Classification code method (SIC), was used only for certain industrial facilities. The public-supply annual average consumptive-use coefficient derived by use of the WBR methods ranged from 6 to 8 percent among Ohio, Indiana, and Wisconsin; the summer average consumptive-use coefficient was considerably higher, ranging from 16 to 20 percent. The commercial annual consumptive-use coefficient for both Ohio and Indiana was 30 percent by the WBR method, which fell within the Ohio annual median (17 percent) and annual average (42 percent) by the RW method. Thermoelectric consumptive use differs greatly by the type of cooling the facility uses; the Ohio annual median consumptive-use coefficient (RW method) was 2 percent for all thermoelectric facilities and facilities with multiple types of cooling, but exclusively once-through-cooling facilities had a median of 0 percent and exclusively closed-loop-cooling facilities had a median of 25 percent. Industrial consumptive-use coefficients varied by type of industry, as reflected by SIC code

Scientific Investigations Report↗

Description and evaluation of numerical groundwater flow models for the Edwards Aquifer, south-central Texas

A substantial number of public water system wells in south-central Texas withdraw groundwater from the karstic, highly productive Edwards aquifer. However, the use of numerical groundwater flow models to aid in the delineation of contributing areas for public water system wells in the Edwards aquifer is problematic because of the complex hydrogeologic framework and the presence of conduit-dominated flow paths in the aquifer. The U.S. Geological Survey, in cooperation with the Texas Commission on Environmental Quality, evaluated six published numerical groundwater flow models (all deterministic) that have been developed for the Edwards aquifer San Antonio segment or Barton Springs segment, or both. This report describes the models developed and evaluates each with respect to accessibility and ease of use, range of conditions simulated, accuracy of simulations, agreement with dye-tracer tests, and limitations of the models. These models are (1) GWSIM model of the San Antonio segment, a FORTRAN computer-model code that pre-dates the development of MODFLOW; (2) MODFLOW conduit-flow model of San Antonio and Barton Springs segments; (3) MODFLOW diffuse-flow model of San Antonio and Barton Springs segments; (4) MODFLOW Groundwater Availability Modeling [GAM] model of the Barton Springs segment; (5) MODFLOW recalibrated GAM model of the Barton Springs segment; and (6) MODFLOW–DCM (dual conductivity model) conduit model of the Barton Springs segment. The GWSIM model code is not commercially available, is limited in its application to the San Antonio segment of the Edwards aquifer, and lacks the ability of MODFLOW to easily incorporate newly developed processes and packages to better simulate hydrologic processes. MODFLOW is a widely used and tested code for numerical modeling of groundwater flow, is well documented, and is in the public domain. These attributes make MODFLOW a preferred code with regard to accessibility and ease of use. The MODFLOW conduit-flow model incorporates improvements over previous models by using (1) a user-friendly interface, (2) updated computer codes (MODFLOW–96 and MODFLOW–2000), (3) a finer grid resolution, (4) less-restrictive boundary conditions, (5) an improved discretization of hydraulic conductivity, (6) more accurate estimates of pumping stresses, (7) a long transient simulation period (54 years, 1947–2000), and (8) a refined representation of high-permeability zones or conduits. All of the models except the MODFLOW–DCM conduit model have limitations resulting from the use of Darcy’s law to simulate groundwater flow in a karst aquifer system where non-Darcian, turbulent flow might actually dominate. The MODFLOW–DCM conduit model is an improvement in the ability to simulate karst-like flow conditions in conjunction with porous-media-type matrix flow. However, the MODFLOW–DCM conduit model has had limited application and testing and currently (2008) lacks commercially available pre- and post-processors. The MODFLOW conduit-flow and diffuse-flow Edwards aquifer models are limited by the lack of calibration for the northern part of the Barton Springs segment (Travis County) and their reliance on the use of the calibrated hydraulic conductivity and storativity values from the calibrated Barton Springs segment GAM model. The major limitation of the Barton Springs segment GAM and recalibrated GAM models is that they were calibrated to match measured water levels and springflows for a restrictive range of hydrologic conditions, with each model having different hydraulic conductivity and storativity values appropriate to the hydrologic conditions that were simulated. The need for two different sets of hydraulic conductivity and storativity values increases the uncertainty associated with the accuracy of either set of values, illustrates the non-uniqueness of the model solution, and probably most importantly demonstrates the limitations of using a one-layer model to represent the heterogeneous hydrostratigraphic units composing the Edwards aquifer. In general, the best matches or agreement between groundwater flow directions inferred by numerical model simulation, and by dye-tracer tests, are observed where model outputs accurately reproduce the configuration of the potentiometric surface with regard to the positions of major and minor groundwater troughs and divides. None of the models, with the possible exception of the MODFLOW–DCM conduit model, has a documented capability to accurately simulate travel times for conduit-dominated velocities in the Edwards aquifer. Public water system assessments of wells in the Barton Springs segment of the Edwards aquifer, and elsewhere where conduit-flow conditions are thought to dominate aquifer hydraulic behavior, might be enhanced by use of either the MODFLOW–DCM model or the newly developed U.S. Geological Survey MODFLOW Conduit-Flow Process module for MODFLOW–2005, because each incorporates a type of dual or triple hydraulic conductivity approach and has the capability to explicitly simulate turbulent flow and conduit hydraulic characteristics.

Texas↗

Quality of volatile organic compound data from groundwater and surface water for the National Water-Quality Assessment Program, October 1996–December 2008

This report describes the quality of volatile organic compound (VOC) data collected from October 1996 to December 2008 from groundwater and surface-water sites for the U.S. Geological Survey's National Water-Quality Assessment (NAWQA) Program. The VOC data described were collected for three NAWQA site types: (1) domestic and public-supply wells, (2) monitoring wells, and (3) surface-water sites. Contamination bias, based on the 90-percent upper confidence limit (UCL) for the 90th percentile of concentrations in field blanks, was determined for VOC samples from the three site types. A way to express this bias is that there is 90-percent confidence that this amount of contamination would be exceeded in no more than 10 percent of all samples (including environmental samples) that were collected, processed, shipped, and analyzed in the same manner as the blank samples. This report also describes how important native water rinsing may be in decreasing carryover contamination, which could be affecting field blanks. The VOCs can be classified into four contamination categories on the basis of the 90-percent upper confidence limit (90-percent UCL) concentration distribution in field blanks. Contamination category 1 includes compounds that were not detected in any field blanks. Contamination category 2 includes VOCs that have a 90-percent UCL concentration distribution in field blanks that is about an order of magnitude lower than the concentration distribution of the environmental samples. Contamination category 3 includes VOCs that have a 90-percent UCL concentration distribution in field blanks that is within an order of magnitude of the distribution in environmental samples. Contamination category 4 includes VOCs that have a 90-percent UCL concentration distribution in field blanks that is at least an order of magnitude larger than the concentration distribution of the environmental samples. Fifty-four of the 87 VOCs analyzed in samples from domestic and public-supply wells were not detected in field blanks (contamination category 1), and 33 VOC were detected in field blanks. Ten of the 33 VOCs had a 90-percent UCL concentration distribution in field blanks that was at least an order of magnitude lower than the concentration distribution in environmental samples (contamination category 2). These 10 VOCs may have had some contamination bias associated with the environmental samples, but the potential contamination bias was negligible in comparison to the environmental data; therefore, the field blanks were assumed to be representative of the sources of contamination bias affecting the environmental samples for these 10 VOCs. Seven VOCs had a 90-percent UCL concentration distribution of the field blanks that was within an order of magnitude of the concentration distribution of the environmental samples (contamination category 3). Sixteen VOCs had a 90-percent UCL concentration distribution in the field blanks that was at least an order of magnitude greater than the concentration distribution of the environmental samples (contamination category 4). Field blanks for these 16 VOCs appear to be nonrepresentative of the sources of contamination bias affecting the environmental samples because of the larger concentration distributions (and sometimes higher frequency of detection) in field blanks than in environmental samples. Forty-three of the 87 VOCs analyzed in samples from monitoring wells were not detected in field blanks (contamination category 1), and 44 VOCs were detected in field blanks. Eight of the 44 VOCs had a 90-percent UCL concentration distribution in field blanks that was at least an order of magnitude lower than concentrations in environmental samples (contamination category 2). These eight VOCs may have had some contamination bias associated with the environmental samples, but the potential contamination bias was negligible in comparison to the environmental data; therefore, the field blanks were assumed to be representative. Seven VOCs had a 90-percent UCL concentration distribution in field blanks that was of the same order of magnitude as the concentration distribution of the environmental samples (contamination category 3). Twenty-nine VOCs had a 90-percent UCL concentration distribution in the field blanks that was an order of magnitude greater than the distribution of the environmental samples (contamination category 4). Field blanks for these 29 VOCs appear to be nonrepresentative of the sources of contamination bias to the environmental samples. Fifty-four of the 87 VOCs analyzed in surface-water samples were not detected in field blanks (category 1), and 33 VOC were detected in field blanks. Sixteen of the 33 VOCs had a 90-percent UCL concentration distribution in field blanks that was at least an order of magnitude lower than the concentration distribution in environmental samples (contamination category 2). These 16 VOCs may have had some contamination bias associated with the environmental samples, but the potential contamination bias was negligible in comparison to the environmental data; therefore, the field blanks were assumed to be representative. Ten VOCs had a 90-percent UCL concentration distribution in field blanks that was similar to the concentration distribution of environmental samples (contamination category 3). Seven VOCs had a 90-percent UCL concentration distribution in the field blanks that was greater than the concentration distribution in environmental samples (contamination category 4). Field-blank samples for these seven VOCs appear to be nonrepresentative of the sources of contamination bias to the environmental samples. The relation between the detection of a compound in field blanks and the detection in subsequent environmental samples appears to be minimal. The median minimum percent effectiveness of native water rinsing is about 79 percent for the 19 VOCs detected in more than 5 percent of field blanks from all three site types. The minimum percent effectiveness of native water rinsing (10 percent) was for toluene in surface-water samples, likely because of the large detection frequency of toluene in surface-water samples (about 79 percent) and in the associated field-blank samples (46.5 percent). The VOCs that were not detected in field blanks (contamination category 1) from the three site types can be considered free of contamination bias, and various interpretations for environmental samples, such as VOC detection frequency at multiple assessment levels and comparisons of concentrations to benchmarks, are not limited for these VOCs. A censoring level for making comparisons at different assessment levels among environmental samples could be applied to concentrations of 9 VOCs in samples from domestic and public-supply wells, 16 VOCs in samples from monitoring wells, and 9 VOCs in surface-water samples to account for potential low-level contamination bias associated with these selected VOCs. Bracketing the potential contamination by comparing the detection and concentration statistics with no censoring applied to the potential for contamination bias on the basis of the 90-percent UCL for the 90th-percentile concentrations in field blanks may be useful when comparisons to benchmarks are done in a study. The VOCs that were not detected in field blanks (contamination category 1) from the three site types can be considered free of contamination bias, and various interpretations for environmental samples, such as VOC detection frequency at multiple assessment levels and comparisons of concentrations to benchmarks, are not limited for these VOCs. A censoring level for making comparisons at different assessment levels among environmental samples could be applied to concentrations of 9 VOCs in samples from domestic and public-supply wells, 16 VOCs in samples from monitoring wells, and 9 VOCs in surface-water samples to account for potential low-level contamination bias associated with these selected VOCs. Bracketing the potential contamination by comparing the detection and concentration statistics with no censoring applied to the potential for contamination bias on the basis of the 90-percent UCL for the 90th-percentile concentrations in field blanks may be useful when comparisons to benchmarks are done in a study.

Scientific Investigations Report↗

Metal prices in the United States through 2010

This report, which updates and revises the U.S. Geological Survey (USGS) (1999) publication, “Metal Prices in the United States Through 1998,” presents an extended price history for a wide range of metals available in a single document. Such information can be useful for the analysis of mineral commodity issues, as well as for other purposes. The chapter for each mineral commodity includes a graph of annual current and constant dollar prices for 1970 through 2010, where available; a list of significant events that affected prices; a brief discussion of the metal and its history; and one or more tables that list current dollar prices. In some cases, the metal prices presented herein are for some alternative form of an element or, instead of a price, a value, such as the value for an import as appraised by the U.S. Customs Service. Also included are the prices for steel, steel scrap, and iron ore—steel because of its importance to the elements used to alloy with it, and steel scrap and iron ore because of their use in steelmaking. A few minor metals, such as calcium, potassium, sodium, strontium, and thorium, for which price histories were insufficient, were excluded. The annual prices given may be averages for the year, yearend prices, or some other price as appropriate for a particular commodity. Certain trade journals have been the source of much of this price information—American Metal Market, ICIS Chemical Business, Engineering and Mining Journal, Industrial Minerals, Metal Bulletin, Mining Journal, Platts Metals Week, Roskill Information Services Ltd. commodity reports, and Ryan’s Notes. Price information also is available in minerals information publications of the USGS (1880–1925, 1996–present) and the U.S. Bureau of Mines (1926–95), such as Mineral Commodity Summaries, Mineral Facts and Problems, Mineral Industry Surveys, and Minerals Yearbook. In addition to prices themselves, these journals and publications contain information relevant to prices, which has been helpful in the preparation of this publication. Prices in this report have been graphed in 1992 constant dollars to show the effects of inflation as measured by the U.S. Bureau of Labor Statistics Consumer Price Index for All Urban Consumers, a widely used measure of overall inflation in the United States. These prices are not tabulated, but a table of the deflators used is given in an appendix. Constant dollar prices can be used to show how prices that producers receive would have less purchasing power.

Scientific Investigations Report↗

Lithology, hydrologic characteristics, and water quality of the Arkansas River Valley alluvial aquifer in the vicinity of Van Buren, Arkansas

A study to assess the potential of the Arkansas River Valley alluvial aquifer in the vicinity of Van Buren, Arkansas, as a viable source of public-supply water was conducted by the U.S. Geological Survey in cooperation with the Little Rock, District, U.S. Army Corps of Engineers. An important study component was to identify possible changes in hydrologic conditions following installation of James W. Trimble Lock and Dam 13 (December 1969) on the Arkansas River near the study area. Data were gathered for the study in regard to the lithology, hydrologic characteristics, and water quality of the aquifer. Lithologic information was obtained from drillers’ logs of wells drilled from 1957 through 1959. Water-quality samples were collected from 10 irrigation wells and analyzed for inorganic constituents and pesticides. To evaluate the potential viability of the alluvial aquifer in the Van Buren area, these data were compared to similar stratigraphic, lithologic, and groundwater-quality data from the Arkansas River Valley alluvial aquifer at Dardanelle, Ark., where the aquifer provides a proven, productive, sole-source of public-supply water. Drillers’ logs for 59 wells in the Van Buren study area revealed well depths ranging from 25 to 52 feet (ft), with a mean depth of 42 ft. The thickness of the lower sand/gravel interval serving as the water-producing zone ranged from 5 to 47 ft, with a mean thickness of 29 ft. The presence of gravel was noted in only 4 of 59 well logs available for review from the study area. Percent sand was calculated from well logs in the study area, and these sand percentages were overlain onto an orthophotograph map to examine the areal distribution of sand percentage in relation to geomorphologic features of the flood plain in the study area. The logs denoting the greatest percent sand tend to occur in areas near to the river and on the concave (point bar) side of abandoned channels, while the lower percent sand tends to occur on the convex (channel fill and backswamp deposits) side of the abandoned channels. Comparison of hydrographs from water levels collected between 1957 and 1972 to cumulative departure from mean monthly and mean annual precipitation showed overall good fit and explained the long-term decreasing water levels from the earliest period of record through October 1967, followed by a sharp rise in water levels concurrent with rises in cumulative departure from mean monthly and mean annual precipitation. Hydrographs for four wells ranging from 0.8 to 4.5 miles upstream from the dam and potentially affected by rising river stage were compared to graphs of river stage and cumulative departure from mean monthly precipitation. Water levels for these wells showed minimal discernible effect by rising river stage following dam completion. Periods of increased precipitation compared closely to increases in water level for all hydrographs, regardless of river stage, and periods of no precipitation resulted in declining water levels, although river stage continued to slowly rise during these same periods. The Arkansas River has greater salinity than local groundwater, providing a quantitative tracer for any groundwater recharge originating from the river. Comparison of predam and postdam groundwater-chloride concentrations showed no increase in chloride concentrations after dam installation, which is consistent with hydrologic data. These data suggest that the dominant source of groundwater recharge in the Arkansas River Valley alluvial aquifer is infiltration of precipitation through proximal, coarse channel deposits, with minimal influx of river water. Groundwater-quality data collected from 10 wells in the study area indicated a calcium-bicarbonate water type. No primary drinking-water standards were exceeded for any constituents, and iron and manganese were the only constituents exceeding secondary drinking-water regulations. Six of the 10 well-water samples were analyzed for the presence of pesticides, as row-crop agriculture is the dominant land use in the study area. Six herbicide compounds and one herbicide metabolite were detected at concentrations substantially below those of the Federal primary drinking-water standards and health advisories. The hydrologic and geochemical data gathered for this study provide a qualitative assessment of the potential of the Arkansas River Valley alluvial aquifer as a source of public water supply in the Van Buren area. Results indicate minimal influx of water from the Arkansas River, and recharge to the aquifer appears to be dominantly by infiltration of precipitation through overlying alluvium. If vertical wells are used as a source of public water supply, then several wells will have to be used in combination at relatively low pumping rates and placed in areas with a greater percent sand. Use of a horizontal well configuration near the river to increase production may depend on infiltration of river water to supplement water removed from storage, especially where areas of lower permeability sediments might be encountered within the surrounding alluvium. If a poor hydraulic connection exists between the river and the alluvium, as indicated by this study, then production will depend on ample precipitation and recharge throughout the year and groundwater storage sufficient to prevent declining water levels where pumping rates exceed recharge.

Arkansas↗

Proceedings of the 12th Biennial Conference of research on the Colorado Plateau

Introduction The Colorado Plateau is a physiographic region that encompasses 330,000 square kilometers in parts of four states in the southwestern United States (Colorado, Utah, New Mexico, and Arizona). Known for its high deserts, the Colorado Plateau also includes isolated mountains, high plateaus, and rugged canyons. Not only is the region topographically diverse, but geologically, biologically, and culturally diverse as well. The landscape is managed by Federal entities including the Bureau of Land Management, the National Park Service, and the U.S. Forest Service; Tribal nations including the Navajo Nation, Kaibab Paiute, Mountain Ute, Southern Ute, Hopi, Zuni, Hualapai, Havasupai, and White Mountain Apache Tribes; State land and wildlife management agencies; and privately owned holdings, creating complex interactions and management challenges. Population growth, increased tourism to Federal and State lands, and energy development have increased water demands and altered land-use patterns, and these changes have emerged as management challenges facing the people working and living in the region. Climate change, particularly the ongoing drought, has exacerbated the effects of population growth, land-use change, and other stressors such as invasive species. As managers seek solutions to the challenges facing the region’s natural and cultural resources, the Biennial Conference of Science and Management of the Colorado Plateau has become an important venue for exchanging information about emerging management concerns and recent scientific research. Each biennial conference has sought to promote discussion, information sharing, and productive communication among the managers, scientists, students, administrators, tribal representatives, and others who attend the conference with the goal of enhancing the use of the best available science to manage the region’s incomparable natural and cultural resources. The publication and dissemination of a conference proceedings series expands the reach of the conference beyond those people in attendance and creates a record on the research presented. The idea of producing a conference proceedings, and its subsequent publication, first occurred in 1993 following the first biennial conference in 1991. A published volume of contributed papers has followed each subsequent biennial conference, including this volume. The venue for publishing proceedings has changed over the years and has included the National Park Service, the Government Printing Office, the U.S. Geological Survey, and University of Arizona Press. Recently, van Riper and others (2015) published a compilation of the abstracts from the 11 previous conference proceedings. Collectively, the proceedings highlight approximately 25 years of natural- and cultural-resources research, promoting the integration of research with resource management across the Colorado Plateau. This volume is freely downloadable by the public, thereby further expanding the influence of this conference beyond the Colorado Plateau. The 12th Biennial Conference held in Flagstaff, Arizona, from September 16 to 19, 2013, covered a range of topics in the physical, biological, and socio-cultural sciences. The conference was organized and hosted by Northern Arizona University’s ( NAU) Merriam-Powell Center for Environmental Research, the Colorado Plateau Cooperative Ecosystem Studies Unit, and the U.S. Geological Survey Southwest Biological Science Center. Financial and in-kind support was provided by a wide range of organizations including the U.S. Forest Service, National Park Service, Bureau of Land Management, Grand Canyon Trust, Colorado Plateau Research Station, and various NAU entities. NAU sponsors include the Landscape Conservation Initiative, School of Forestry, School of Earth Science and Environmental Sustainability, Office of the Provost, and Office of the Vice President of Research. Contributors to these proceedings include researchers and managers from Federal, State, and Tribal governments, universities, private entities, and non-profit organizations. In this regard, this conference has wide-ranging support and participation among private and public entities involved in the science and management of natural resources on the Colorado Plateau.

Arizona, Colorado, New Mexico, Utah↗

Status and understanding of groundwater quality in the North San Francisco Bay Shallow Aquifer study unit, 2012; California GAMA Priority Basin Project (ver. 1.1, February 2018)

Groundwater quality in the North San Francisco Bay Shallow Aquifer study unit (NSF-SA) was investigated as part of the Priority Basin Project of the California Groundwater Ambient Monitoring and Assessment (GAMA) Program. The study unit is in Marin, Mendocino, Napa, Solano, and Sonoma Counties and included two physiographic study areas: the Valleys and Plains area and the surrounding Highlands area. The NSF-SA focused on groundwater resources used for domestic drinking water supply, which generally correspond to shallower parts of aquifer systems than that of groundwater resources used for public drinking water supply in the same area. The assessments characterized the quality of untreated groundwater, not the quality of drinking water. This study included three components: (1) a status assessment , which characterized the status of the quality of the groundwater resources used for domestic supply for 2012; (2) an understanding assessment , which evaluated the natural and human factors potentially affecting water quality in those resources; and (3) a comparison between the groundwater resources used for domestic supply and those used for public supply. The status assessment was based on data collected from 71 sites sampled by the U.S. Geological Survey for the GAMA Priority Basin Project in 2012. To provide context, concentrations of constituents measured in groundwater were compared to U.S. Environmental Protection Agency (EPA) and California State Water Resources Control Board Division of Drinking Water regulatory and non-regulatory benchmarks for drinking-water quality. The status assessment used a grid-based method to estimate the proportion of the groundwater resources that has concentrations of water-quality constituents approaching or above benchmark concentrations. This method provides statistically unbiased results at the study-area scale and permits comparisons to other GAMA Priority Basin Project study areas. In the NSF-SA study unit as a whole, inorganic constituents with human-health benchmarks were detected at high relative concentrations (RCs) in 27 percent of the shallow aquifer system, and inorganic constituents with secondary maximum contaminant levels (SMCL) were detected at high RCs in 24 percent of the system. The inorganic constituents detected at high RCs were arsenic, boron, fluoride, manganese, nitrate, iron, sulfate, and total dissolved solids (TDS). Organic constituents with human-health benchmarks were detected at high RCs in 1 percent of the shallow aquifer system. Of the 148 organic constituents analyzed, 30 constituents were detected, although only 1, chloroform, had a detection frequency greater than 10 percent. Natural and anthropogenic factors that could affect the groundwater quality were evaluated by using results from statistical testing of associations between constituent concentrations and values of potential explanatory factors. Groundwater age class (modern, mixed, or pre-modern), redox class (oxic or anoxic), aquifer lithology class (metamorphic, sedimentary, or volcanic), and dissolved oxygen concentrations were the explanatory factors that explained distribution patterns of most of the inorganic constituents best. Groundwater classified primarily as pre-modern or mixed in age was associated with higher concentrations of arsenic and fluoride than waters classified as modern. Anoxic or mixed redox conditions were associated with higher concentrations of boron, fluoride, and manganese. Similar patterns of association with explanatory variables were seen for inorganic constituents with aesthetic-based benchmarks detected at high concentrations. Nitrate and perchlorate had higher concentrations in oxic than in the anoxic redox class and were positively correlated with urban land use. The NSF-SA water-quality results were compared to those of the GAMA North San Francisco Bay Public-Supply Aquifer study unit (NSF-PA). The NSF-PA was sampled in 2004 and covers much of the same area as the NSF-SA, but focused on the deeper public-supply aquifer system. The comparison of the NSF-PA to the NSF-SA showed that there were more differences between the Valleys and Plains study areas of the two study units than between the Highlands study areas of the two study units. As expected from the shallower depth of wells, the NSF-SA Valleys and Plains study area had a lesser proportion of pre-modern age groundwater and greater proportion of modern age groundwater than the NSF-PA Valleys and Plains study area. In contrast, well depths and groundwater ages were not significantly different between the two Highlands study areas. Arsenic, manganese, and nitrate were present at high RCs, and perchlorate was detected in greater proportions of the NSF-SA Valleys and Plains study area than the NSF-PA Valleys and Plains study area.

California↗

Comparison of the results of enzyme-linked immunosorbent assay (ELISA) to mass-spectrometry based analytical methods for six unregulated contaminants in source water and finished drinking-water samples

Regulatory entities, such as the Minnesota Department of Health, monitor public water systems for conformance with Federal and State monitoring requirements and water-quality standards. Although some contaminants have Federal and (or) State regulations and guidance values, many contaminants, such as pesticides and pharmaceuticals, are unregulated in that only non-enforceable health-based guidance values have been assigned to them. Furthermore, because these contaminants are not regulated, commonly only limited resources are available to public water systems or regulatory entities to monitor them in drinking water. Focused screening efforts on contaminants that are frequently detected in the environment can provide information to help monitoring entities prioritize their sampling efforts. Here we assess the use of enzyme-linked immunosorbent assay (ELISA) method, a rapid, inexpensive screening method, as an alternative to more expensive methods to analyze source and finished drinking-water samples collected from public water systems throughout Minnesota for three commonly detected pesticides (atrazine, imidacloprid, and pyrethroids) and three commonly detected pharmaceuticals (caffeine, carbamazepine, and sulfamethoxazole). The ELISA results were compared to results provided by more advanced mass-spectrometry analytical methods at the U.S. Geological Survey National Water Quality Laboratory (NWQL) and SGS AXYS Analytical Services Ltd. (AXYS). Overall, these datasets are highly censored (>80 percent) and contain multiple reporting limits within and between laboratories. To discern agreement between paired contaminant group results (target contaminant plus immunologically similar contaminants) by ELISA and the advanced analytical methods at NWQL and AXYS, presence-absence agreement analysis was coupled with false negative and false positive analysis. Analysis of presence-absence agreement shows that ELISA has generally good agreement (77.9 to 100 percent) with both NWQL and AXYS for all unregulated contaminant groups. Imidicloprid, pyrethroids, and caffeine contaminant groups have relatively low false positivity rates (16, 6, and 5 percent, respectively) when analyzed by ELISA, which indicates the ELISA method, for these contaminant groups, could be experiencing low-level interference attributed to the detection of immunologically similar contaminants. Similarly, sulfamethoxazole has a low false positivity rate (0.8 percent), which indicates ELISA is likely not overestimating results for this contaminant group. Analyses for carbamazepine and sulfamethoxazole by ELISA resulted in low false negativity rates (1.6 and 0.8 percent, respectively), which indicates the ELISA method is likely not underestimating the results for this contaminant group. Conversely, the atrazine contaminant group has a high false negativity rate (84 percent), which indicates the method has a strong negative bias and that ELISA underestimates results for this contaminant. These qualitative results indicate that the ELISA method could potentially serve as a reliable and cost-effective screening method to help drinking water monitoring entities prioritize sampling efforts for analyzing carbamazepine and sulfamethoxazole in source and finished drinking-water samples collected from public water systems. At the same time, although ELISA did not prove to be a good screening method for atrazine, evaluation of ELISA results indicated that its use for screening imidacloprid, pyrethroids, and caffeine could be beneficial for water testing.

Minnesota↗

Hydrogeologic framework and extent of saltwater intrusion in Kings, Queens, and Nassau Counties, Long Island, New York

In 2016, the U.S. Geological Survey began a multiyear cooperative study with the New York State Department of Environmental Conservation to evaluate the sustainability of Long Island’s sole-source aquifer system through hydrogeologic mapping, compilation of groundwater chloride concentrations, and groundwater flow modeling. In the initial phase of the islandwide study, the hydrogeologic framework and extent of saltwater intrusion in aquifers in Kings, Queens, and Nassau Counties on western Long Island, N.Y., were investigated. The aquifer system underlying western Long Island has been under stress from pumping of public, irrigation (golf course), and industrial supply wells. Saltwater intrusion has occurred from surrounding embayments (East River, Long Island Sound, Jamaica Bay, and the Atlantic Ocean) due to pumping. Eighteen boreholes were drilled and cores taken during 2019–21 to collect hydrogeologic, geochemical, and geophysical data to delineate the complex subsurface hydrogeology and extent of saltwater intrusion within the study area. Evaluation of the new cores, reexamination of legacy core descriptions, and analysis of borehole geophysical logs was used to refine the previously published hydrogeologic framework of Pleistocene and Cretaceous unconsolidated sediments in the area, including delineation of a previously undefined hydrogeologic unit between the Magothy aquifer and the Raritan confining unit, herein named the “upper Raritan aquifer.” The upper Raritan aquifer was first recognized in southeastern Nassau County from an analysis of about 50 closely spaced boreholes with high-resolution core descriptions and gamma-ray (gamma) logs. Further analysis of borehole logs across the study area indicated that the upper Raritan aquifer was also present in Kings and Queens Counties. Nuclear magnetic resonance (NMR) logging was used for the first time on Long Island to provide estimates of the hydraulic properties of the major aquifer and confining units. Unlike other geophysical logs that record responses to the rock matrix and fluid properties and are strongly dependent on mineralogy, NMR logs record responses to the presence of hydrogen protons in the formation fluid to determine water fraction and pore-size distribution. NMR log analysis provided estimates of the clay-bound, capillary-bound, and mobile water fractions and hydraulic conductivity of aquifers and confining units penetrated by five wells in Nassau County. Pumpage for public-supply and industrial wells on Long Island began in the 1870s with small, localized suppliers of populated areas in Kings and Queens Counties. By 1904–16, pumpage for public water supply in Kings County averaged 21 million gallons per day, and averaged 37 million gallons per day in Queens County, mostly from the upper glacial aquifer. Saltwater intrusion was reported as early as the beginning of the 20th century and included the upper glacial-Jameco-Magothy and Lloyd-North Shore aquifer systems. By 1936, pumping in central Kings County created a major cone of depression in the water table extending to the south shore of much of Kings County and into southwestern Queens County. Saltwater intrusion has caused the shutdown of public-supply wells in Kings, Queens, and Nassau Counties. A large saltwater intrusion wedge in the Lloyd aquifer was indicated in southern Queens County in the early part of the 20th century, and the saltwater interface may have been onshore predevelopment. Most of Kings and Queens Counties are intruded with saltwater in both the upper glacial-Jameco-Magothy and Lloyd-North Shore aquifers systems. Saltwater increased during the 20th century and continues to increase to the present (2023) in the Lloyd-North Shore aquifer system in Great Neck and Manhasset Neck in northern Nassau County. A major wedge of saltwater intrusion in the upper glacial-Jameco-Magothy aquifer in southwestern Nassau County appears to be increasing.

New York↗