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USGS1940

Phosphate deposits of the United States

Different types of phosphate deposits and different sources of phosphate in the United States are briefly discussed. In Florida two types of phosphate are now mined, land pebble and hard rock. The principal characteristics of these types of rock are stated and methods of prospecting, mining and recovery briefly outlined. Testimony given before the Congressional Committee to Investigate the Adequacy and Use of Phosphate Resources of the United States, November 28, 1938, at Lakeland, Fla., showed Florida's reserves to be far greater than previously supposed. Similarly at corresponding hearings in Tennessee a few days earlier the reserves of brown phosphate, the only type now mined in that State, were shown to exceed earlier official estimates. Reserves of the Western fields have been raised a little to bring them abreast of current information but no attempt has been made, as in the other States named, to include lower grades of rock than those formerly considered in the estimates. Professor J. Stewart Williams has shown for Utah that such a procedure would tremendously increase these figures . Reserves of the United States as a whole are now considered to exceed ten billion tons, not counting those classed as possible or certain phosphatic limestones mentioned at the hearings of the Congressional Committee. As nearly 2,000,000 acres of public land in the Western States and 66,000 acres in Florida remain to be examined for their phosphate content the stated figure will ultimately be greatly increased. At the present rate of consumption, 3,000,000 tons annually, ten billion tons would last more than 3,000 years.

Colorado, Florida, Idaho, Montana, South Carolina,↗
USGS1944

The fluorspar deposits of Saint Lawrence, Newfoundland

Fluorspar from Newfoundland, eighth ranking producer of the world, comes entirely from the St. Lawrence district. Here pre-Cambrian lavas and pyroclastics, Cambrian sedimentary rocks, Ordovician (?) volcanic and sedimentary rocks, and a Paleozoic alaskite-granite comprise the bedrock.Epithermal fluorite veins occupy steeply dipping fault fissures in granite, rhyolite porphyry, and lamprophyre. Eleven veins show walls bearing nearly horizontal striations; one vein bears only vertical striations; and the walls of three veins show both horizontal and vertical striations. The strikes of nearly all veins are within 45 degrees of the normal to the walls of the elongated granite mass. Some veins are more than a mile long and contain numerous workable lenses. Veins are of two types: high-grade containing over 95 per cent CaF 2 and averaging about 5 feet thick, and lower grade containing about 75 per cent CaF 2 and averaging between 15 and 20 feet thick.Sulphides, present in small quantities, include pyrite, chalcopyrite, sphalerite, and argentiferous galena. Non-metallic gangue minerals are quartz, calcite, and rarely barite. "Blastonite," a local name for material composed of microcrystalline quartz and brecciated fluorite, in some places forms as much as 10 per cent of a vein. A nodular type of fluorspar probably formed by alternate rotation of fragments of breccia and deposition of fluorite.Regional zoning is shown by the distribution of barite and green fluorite. Barite shows a distinct zone of localization, and green fluorite predominates in veins both near the granite margins and farther from the granite body.This district will undoubtedly occupy a still more prominent position among producers of fluorspar.

Newfoundland↗
USGS1944

"Ribbon rock", an unusual beryllium-bearing tactite

The beryllium deposits at Iron Mountain, near the northern end of the Sierra Cuchillo in Sierra and Socorro Counties, New Mexico, are unusual products of contact metamorphism. They occur in irregular bodies of tactile formed by replacement of Paleozoic limestone, generally at or near contacts with small intrusive masses of rhyolite, aplite, and fine-grained granite. The metamorphism took place in mid-Tertiary time. Beryllium is present chiefly in the complex silicate minerals helvite and danalite, and is a minor constituent of the garnet grossularite, a boron-bearing idocrase, and chlorite. These minerals are known to occur in noteworthy concentrations in only one type of rock, a peculiar rhythmically layered variety of tactile to which the name "ribbon rock" is given. The structure of such tactite is very conspicuous, and appears in section as thin, finely crenulated bands of magnetite alternating with similar bands of silicate minerals and finely crystalline fluorite. Concentric banding about fluorite-rich pod-like masses is common. Bodies of "ribbon rock" range in size from inch-thick lenses to large masses amounting to thousands of tons; most appear to have been formed along contacts between re-crystallized limestone and massive magnetite-andradite tactite, chiefly by replacing fluids penetrating the limestone from fractures. The layered structure is interpreted as a diffusion effect.The formation of massive and "ribbon rock" tactites can be traced through a range of falling temperature from a stage characterized by deposition from iron-rich vapors to a stage in which hydrothermal solutions were dominant. Both vapors and liquids appear to have been acid. Reducing conditions undoubtedly existed during the latter part of the hydrothermal stage. The occurrence of beryllium in "ribbon rock," but not in typical massive tactite, may signify that its compounds in deposits at or near intrusive contacts are confined to rocks of hydrothermal origin. The occurrence of "ribbon rock" is suggested as a potentially useful clue for recognition of beryllium-bearing contact deposits elsewhere; at least two other occurrences of what apparently is "ribbon rock" have been described in the literature.

New Mexico↗
USGS1954

Sedimentary facies of iron-formation

The sedimentary iron -formations of Precambrian age in the Lake Superior region can be divided on the basis of the dominant original iron mineral into four principal facies : sulfide, carbonate, oxide, and silicate. As chemical sediments, these rocks reflect certain aspects of the chemistry of the depositional environments. The major control, at least for the sulfide, carbonate, and oxide types, probably was the oxidation potential. The evidence indicates that deposition took place in restricted basins, which were separated from the open sea by thresholds that inhibited free circulation and permitted development of abnormalities in oxidation potential and water composition. The sporadic distribution of metamorphism and of later oxidation permits description of the primary facies on the basis of unoxidized, essentially unmetamorphosed material. The sulfide facies is represented by black slates in which pyrite may make up as much as 40 percent of the rock. The free-carbon content of these rocks typically ranges from 5 to 15 percent, indicating that ultra-stagnant conditions prevailed during deposition. Locally, the pyritic rocks contain layers of iron -rich carbonate. The carbonate facies consists, in its purer form, of interbedded iron -rich carbonate and chert. It is a product of an environment in which oxygen concentration was sufficiently high to destroy most of the organic material but not high enough to permit formation of ferric compounds. The oxide facies is found as two principal types, one characterized by magnetite and the other by hematite. Both minerals appear to be of primary origin. The magnetite-banded rock is one of the dominant lithologies in the region; it consists typically of magnetite interlayered with chert, carbonate, or iron silicate, or combinations of the three. Its mineralogy and association suggest origin under weakly oxidizing to moderately reducing conditions, but the mode of precipitation of magnetite is not clearly understood. The hematite-banded rocks consist of finely crystalline hematite interlayered with chert or jasper. Oolitic structure is common. This facies doubtless accumulated in a strongly oxidizing, probably near-shore, environment similar to that in which younger hema-titic ironstones such as the Clinton oolite were deposited. The silicate facies contains one or more of the hydrous ferrous silicates (greenalite, minnesotaite, stilpnomelane, chlorite) as a major constituent. Granule structure, similar to that of glauconite, is typical of some varieties; others are nongranular and finely laminated. The most common association of the silicate rocks is with either carbonate- or magnetite-bearing rocks, which suggests that the optimum conditions for deposition ranged from slightly oxidizing to slightly reducing. The relationship between the iron -rich rocks and volcanism, stressed by many authors, is considered by the writer to be structural, not chemical: in the Lake Superior region both iron -deposition and volcanism are believed to be related to geosynclinal development during Huronian time. In Michigan, the lower Huronian rocks are iron -poor quartzite and dolomite-typical "stable-shelf" deposits; much of the upper Huronian consists of iron -poor graywacke and slate with associated volcanic rocks -a typical "geosynclinal" assemblage. Thus the iron -rich beds of the middle Huronian and lower part of the upper Huronian were deposited during a transitional stage in structural history. The major environmental requirement for deposition of iron - formation is the closed or restricted basin; this requirement coincides in time with what would be a normal stage in evolution of the geosyncline: namely, structural development of offshore buckles or swells that subsequently develop into island arcs characterized by volcanism.

Lake Superior↗
USGS1958

Minerals of the cassiterite-bearing veins at Irish Creek, Virginia, and their paragenetic relations

Major rock types of the Irish Creek district are gneisses and schists, intruded by granodiorite. All these rocks are believed to be Precambrian. The ore deposits are fissure veins consisting largely of quartz veins bordered by greisen, and enriched by recurrent deposition. From field and microscopic evidence six stages of mineral formation have been deduced: 1. Crystallization of the granodiorite with the formation of hypersthene, augite, hornblende, andesine, orthoclase, microcline, and quartz; and accessory apatite, rutile, ilmenite, titanomagnetite, and zircon. 2. Metamorphism of the granodiorite and gneiss with formation of uralitic actinolite, epidote, and sphene. 3. A period of fracturing and formation of quartz veins. 4. Greisenization of the host rock producing first: coarse muscovite, brown biotite, cassiterite, beryl, wolframite, and quartz; then producing a second group of minerals-fluorite, green biotite, chlorite, phenakite, siderite, ankerite, parisite, sphalerite, sulfides, including aikinite and galeno-bismutite, leucoxene, fine muscovite, and quartz. 5. Formation of late vein minerals, clinozoisite, calcite, nontronite, and montmorillonite. 6. Formation of surficial alteration products, kaolinite, vermiculite, hematite, limonite, and scorodite. The italicized mineral names indicate the minerals heretofore unreported from Irish Creek; parisite, aikinite, and galenobismutite are new minerals for Virginia. Included in the detailed descriptions of all the minerals is a chemical analysis of beryl.

Virginia↗
USGS1959

Peneconcordant uranium deposit: A proposed term

The term peneconcordant is proposed to describe the form of the numerous and highly productive U deposits in sedimentary rocks of the Colorado Plateau, Wyoming, the Dakotas, and Texas. Peneconcordant U deposits are tabular, lenticular, or irregularly-shaped masses of widely differing size that are, in general, concordant to the gross sedimentary structures of the enclosing rock but that in detail cut across sedimentary structures. They differ from vein deposits in that they do not occupy or follow fractures or shear zones in the sedimentary rocks. Furthermore, they are not coextensive with a specific lithologic unit, such as U-bearing marine black shale. The many terms now used to describe these U deposits are based variously on petrographic, mineralogic, geographic, and genetic considerations; none is satisfactory for describing all these deposits having a common and distinctive form. Furthermore, some of the terms are ambiguous and have been commonly used to group together deposits having distinctly different forms. The term peneconcordant U deposit clearly sets apart a widespread and important type of U deposit that has a common and distinctive form, namely, nearly concordant to the bedding of the host rock. The meaning of the term is self-evident, and the term is readily applicable to field usage.

Economic Geology↗
USGS1962

The origin of jasperoid in limestone

The name jasperoid has been applied to rocks that consist mainly of silica and that have formed by replacement. This paper considers only those jasperoids formed by replacement of limestone . Major problems involved in the origin of such jasperoid include: source of the silica; nature of solutions that dissolve, transport, and precipitate silica; and the mechanism of replacement of limestone by silica. The answers to these problems are of practical as well as scientific interest because many jasperoid bodies are closely related to mineralization. Silica may be derived from: juvenile silica of magmatic origin ; silica leached from underlying rocks by hydrothermal solutions; silica locally derived from enclosing rocks by circulating solutions; and silica carried downward in ground water from the weathering of overlying rocks. The nature and the concentration of other substances in solutions influence, in a complex manner, the ability of these solutions to dissolve, transport, and precipitate silica. Nevertheless, the following generalizations can be made. The solubility and rate of solution of silica in water at moderate pressure increase slowly with temperature up to 200 degrees C.; from 200 degrees to 360 degrees C. they increase rapidly; above 360 degrees C. solubility is pressure dependent, increasing steadily at high pressure and decreasing slightly at moderate pressure due to the formation of a vapor phase. The pH has slight effect on the ionic solubility of silica in the range from pH 1 to ph 9 at low temperature. The effect of other components on the solubility of silica is probably subordinate to that of temperature above 200 degrees C., but becomes increasingly important as the temperature falls below that point. Most jasperoid bodies form by both replacement and silica deposition in voids, with replacement dominant during the early phase, and precipitation dominant during later phases. Replacement of limestone by silica is favored by relatively low temperature acid solutions, and the presence of CO 2 . As limestone dissolves, Ca ions are released to promote the precipitation of colloidal silica. Acid solutions then diffuse through this gelatinous film to continue dissolving limestone behind it; the Ca ions diffusing outward cause the precipitation of more colloidal silica at the solution-gel interface. As the gel mass ages, it shrinks, hardens, and ruptures. More silica is then deposited in the fractures. Eventually the gel crystallizes to a dense mass of aphanitic quartz and chalcedony, with shrinkage cracks and vugs filled or coated with younger coarse-grained quartz and other minerals that have been deposited directly from solution. The theory that relatively low temperature favors the formation of jasperoid replacement bodies in carbonate rocks, and high temperature inhibits their formation, offers an explanation for the gap that is observed in some districts between contact metasomatic lime silicates and siliceous replacement of limestone . This gap is characterized by the lack of any reaction between limestone and silica-bearing solutions moving through it.

Economic Geology↗
USGS1967

Aurorite, argentian todorokite, and hydrous silver-bearing lead manganese oxide

During a study of hypogene manganese minerals, three silver-bearing manganese oxides were identified in "black calcite" associated with silver ores at the Aurora mine (Treasure Hill), Hamilton, Nevada. Specifically these are: (1) argentian chalcophanite (aurorite) (Ag 2 Ba,Ca,Pb,-K 2 ,Cu,Mn (super +2) )Mn 3 (super +4) O 7 . 3H 2 O; (2) argentian todorokite (Ag 2 ,K 2 ,Ca,Ba,-Na 2 ,Cu,Pb)Mn 4 (super +4) O 9 . 5H 2 O; and (3) hydrous silver-bearing lead manganese oxide (Pb,Cu,Ba,Sb,Ag 2 ,Ca,K 2 )Mn 5 (super +4) O 11 . 5H 2 O. Based on the large concentration of silver in argentian chalcophanite (7.50% Ag 2 O) and the low zinc content (0.25% ZnO) this mineral is recognized as a new species and named "aurorite."Physical and optical properties, and chemical analyses of the three minerals are presented together with X-ray powder diffraction data for aurorite and argentian todorokite. All chemical analyses were done with the electron microprobe analyzer. Due to extremely small particle size and textural relations, no X-ray powder data were obtained for the hydrous silver-bearing lead manganese oxide. Associated minerals include cryptomelane, pyrolusite, birnessite(?), cerargyrite, native silver, quartz, and manganoan calcite. Although the general uniform dark color of the "black calcite" and apparent uniform distribution of the inclusions suggests contemporaneous formation, examination of polished sections at high magnifications shows a definite paragenetic sequence. Manganoan calcite is replaced by fine-grained intergrowths of cryptomelane, pyrolusite, birnessite(?), and cerargyrite. Native silver formed early and the silver-bearing manganese oxides formed late in the sequence; aurorite fills microfractures that cut through all other minerals.These three silver-bearing manganese oxides were recognized only at the Aurora mine, Hamilton, Nevada, although black calcite veins were studied from numerous areas in the western United States. The geologic features of silver-bearing black calcites are described by Hewett and Radtke in the preceding paper.

Nevada↗
USGS1985

Regional setting and new information on some critical geologic features of the West Shasta district, California

The West Shasta massive sulfide district is in the easternmost of a series of accreted island-arc and oceanic crust terranes that comprise the Klamath Mountains. A sequence of submarine volcanic rocks of predominantly Early Devonian age is the principal component of the island-arc terrane in which the sulfide deposits are hosted. The Copley Greenstone, consisting mainly of andesitic and basaltic pillow lavas and breccias totaling at least 1,800 m in thickness, is the oldest rock unit in the sequence. It is overlain and also intruded by dikes of the Balaklala Rhyolite. Northeast of the West Shasta district, greenstone also overlies the Balaklala Rhyolite, suggesting that a major greenstone unit may overlie potentially mineralized rhyolite east of the district. However, recent studies have shown that the complex relations in that area can be explained by folding.The Balaklala sequence consists of silicic flows, breccias, and tuffs having a maximum thickness somewhat in excess of 1,000 m. The Balaklala has been divided by Kinkel et al. (1956) into three units: a lower nonporphyritic to slightly porphyritic unit containing large amounts of breccia and tuff; a middle unit characterized by rhyolite containing quartz phenocrysts 1 to 4 mm in diameter but also containing a complex assortment of tuff, breccia, and pyritic massive sulfide bodies in its upper part; and an upper unit typically containing dark quartz phenocrysts in excess of 4 mm in diameter. Much of the lower part of the upper unit is pyroclastic material, whereas most of the upper part of the unit appears to be a massive volcanic-flow rock. At least half a dozen eruptive centers for the Balaklala Rhyolite are identified, three of them within an area measuring 17 X 3 km that constitutes the limits of the former mining district.The youngest unit in the arc sequence is the Kennett Formation consisting of black shale and chert containing radiolarians, which indicate fairly deep-water deposition in its lower part, and limestone containing a shallow water fauna of probable Middle Devonian age in the upper part. A 400-m.y.-old trondhjemite stock, named the Mule Mountain stock, intrudes the Copley Greenstone and Balaklala Rhyolite and is considered to be essentially coeval with these volcanic units.The pyritic massive sulfide deposits occur in clusters of individual bodies owing in large part to disruption by postmineral faults. The deposits are stratigraphically confined to the upper part of the subhorizontal middle unit of the Balaklala, and their horizontal distribution is here interpreted to have been controlled by an extensional tectonic regime that prevailed during Early Devonian time. The major geologic evidence for such a regime is the marked preferred elongations exhibited by the distribution of the afore-mentioned eruptive centers, the eight or nine massive sulfide clusters in the district, and the geometrically similar distribution of the clusters in relation to each other. The preferred directions of elongation in both the detailed and broader senses may be generalized to N 20 degrees to 25 degrees E, N 37 degrees E, N 60 degrees to 80 degrees E, and N 40 degrees to 60 degrees W. The three northeast trends dominate throughout the district, whereas the northwest trend is evident mainly in the northern part and is more speculative. The major deposit clusters fall at intersections of the major trends, some of which may have been grabens. Trend intersections having no known deposits may be good exploration targets in localities where the stratigraphically favorable middle unit of the Balaklala is still present.

Economic Geology↗
USGS1986

Genesis of the Spar Lake strata-bound copper-silver deposit, Montana: Part I. Controls inherited from sedimentation and preore diagenesis

Mineable zones of the Spar Lake deposit occur where argentiferous copper sulfides and native silver formed cements and replaced certain earlier cements and clasts in the gently dipping middle quartzite beds of the upper member of the Revett Formation, middle Proterozoic Belt Supergroup. The copper sulfides and native silver are part of a large, zoned system of authigenic ore and gangue minerals at Spar Lake. Mineral zone boundaries of ore and gangue phases cross all five stratigraphic units of the upper member.Deduced depositional environments for the host sedimentary rocks include beach and near-shore slope environments for the lower quartzite beds and subtidal(?) channels for the middle quartzite beds. The deposit must be epigenetic because mineral zone boundaries cross every facies in the sequence of beach and nearshore slope sediments.Mineral zonation has been mapped, and seven major associations, each named for its most abundant sulfide and/or most characteristic gangue cement, are recognized. Zones that appear to be developed on a regional scale include, in spatial order, pyrite-calcite, chalcopyrite-ankerite, and the lavender (hematitic) zone. Minor concentrations of base and precious metals occur along boundaries between the hematite and chalcopyrite-ankerite zones, and between the chalcopyrite-ankerite and pyrite-calcite zones; however, at the major concentrations of metals in the Revett Formation, including the Spar Lake deposit, additional mineral zones are developed between the chalcopyrite-ankerite and pyrite-calcite regional zones. Mineral zones at the deposit are, from northwest to southeast: pyrite-calcite, galena-calcite, chalcopyrite-calcite, bornite-calcite, chalcocite-chlorite, and chalcopyrite-ankerite. Gangue minerals, including carbonates, Fe-Ti oxides, chlorite, barite, authigenic feldspars, and apatite, are zonally distributed with boundaries parallel to the sulfide-mineral zone boundaries. Bornite-calcite and chalcocite-chlorite zones form ore grades in certain, but not all, quartzite intervals.As observed at unmetamorphosed deposits where sulfide-mineral zonation is similar, some pyrite-calcite-zone minerals were probably replaced by galena-calcite-zone minerals, which were probably succeeded, in sequence, by minerals of the chalcopyrite-calcite, bornite-calcite, and chalcocite-chlorite zones. This inferred paragenesis suggests that the chalcocite-chlorite zone is more proximal to the source of ore solutions than the galena-calcite or pyrite-calcite zones. The subeconomic chalcopyrite-ankerite zone, found farthest to the southeast at the Spar Lake deposit, was apparently even more proximal to the source than ore. Ore deposition took place during diagenesis from solutions that migrated upward and laterally through the sediments from a southeasterly source.The distributions of mineral zones and ore grades were controlled by two factors, one inherited from sedimentation and the other from preore diagenesis. All mineral zones spread out within coarser grained portions of quartzite units, suggesting that lateral migration of ore solutions was controlled by primary permeability of the sediments. However, high grades of copper and silver are found only in certain of the coarser grained beds. The distributions of higher grades suggest that ore mineral abundances reflect the abundances of preore diagenetic phases which were involved in the ore precipitation reactions. Preore reactant phases were evidently more abundant in sandstones deposited in subtidal(?) channels (the ore-grade middle quartzite beds) than in sandstones deposited in beach and nearshore slope environments (the lower quartzite beds). The identity of the reactant phases and the processes that resulted in their concentration at the site of later ore deposition remain unknown, although a preore sulfide- and hydrocarbon-bearing pore fluid appears to be the best hypothesis as to the identity of the reactants.

Economic Geology↗
USGS1987

Source of lead and mineralizing brines for rossie-type Pb-Zn veins in the Frontenac axis area, New York ( USA).

Veins composed mainly of calcite and some galena, sphalerite, fluorite, and other minerals are widespread in the Frontenac axis area of New York and Ontario. In New York, the veins (Fig. 1) occur mainly west and northwest of Gouverneur (Brown, 1983). The veins, mined in the 1800s for lead, were first described by Emmons (1838). Smyth (1903) called these the "Rossie lead veins," a name now used locally for all veins of this type. Similar veins in southeastern Ontario were described by Uglow (1916) and Sangster (1970). The steeply dipping veins are aligned along extensional fractures in metamorphic rocks of the Grenville Complex and in Paleozoic sedimentary rocks, including the Potsdam Sandstone of Late Cambrian age, and limestones as young as Middle Ordovician. However, the age of emplacement of Rossie veins is unknown. The veins are mineralogically simple, consisting of calcite (~95%) with minor and approximately equal amounts of sphalerite and galena, and sparse fluorite, barite, celestite, and chalcopyrite (Brown, 1983). Paragenetically early minerals are crushed and granulated; later undeformed minerals fill open spaces (Fig. 2). Sandstone dikes that originated from either the overlying Potsdam Sandstone or stratigraphically higher arenaceous rocks cut into the Rossie veins and occupy all available space. Their unstratified nature suggests that sand was intruded under high hydraulic pressure during tectonic events that reopened the veins. Most veins are vertical and narrow (1-3 cm wide) and those that were mined are as much as 1.7 m wide. The veins trend mainly northwest-southeast but have a local east-west orientation. The fractures and veins show evidence of strike-slip faulting with a right-lateral offset due to late reactivation of north-east-trending faults that originally formed during the Proterozoic Grenville orogeny. Relatively rare inclined veins, termed gash veins (Brown, 1983), occur in proximity to some of the regional northeast-trending faults. These veins contain open spaces lined with large, undeformed crystals of calcite (~90%) and green fluorite (~5%). The minerals of the northeast-trending gash veins, which dip to the northwest, are believed to be paragenetically late results of the same mineralization and tectonic event that produced the Rossie veins. For example, the green fluorite in the gash veins is similar in color and occurrence to small fluorite crystals in vugs in the vertical Rossie veins. Associated with the fluorite in both occurrences is coarse crystalline calcite containing tiny tetrahedra of chalcopyrite aligned along crystallographic planes. The present study of fluid inclusions and lead isotopes was done to understand better the nature and possible source of the mineralizing solutions for both vertical and gash veins and the possible origin of the lead and zinc mineralization. Large deposits of essentially syngenetic sphalerite with minor to trace galena occur in the Proterozoic rocks of this region (e.g., Balmat-Edwards, New York). Although none of these deposits are known in the immediate vicinity of Rossie veins, the possibility that Rossie veins contain remobilized metals from these older deposits was considered.

New York↗
USGS1993

Optimization of an extraction procedure for the accurate determination of total tin in eighteen Geological Survey of Japan rock reference materials

A fusion-extraction procedure for the determination of total tin in rocks and sediments by graphite furnace atomic absorption spectrometry (GFAAS) was reexamined and modified to obtain the optimum accuracy and precision. Several variations based on increases in the sample weight or extraction ratio were compared based on the determination of tin in 18 Geological Survey of Japan (GSJ) reference materials. The most accurate and precise procedure was found to be an 8:1 extraction of a 0.5 g rock sample fused with lithium metaborate and dissolved in 7.5% hydrochloric acid, using a 4% solution of trioctylphosphine oxide in methyl isobutyl ketone (TOPO-MIBK). Rocks containing <I ug/g total tin require a 0.5 g sample size for the utmost accuracy. Utilizing these modifications, tin concentrations were found to be within 0.1 ug/g for all of the GSJ reference standards with the exception of the rhyolites. Values are reported for the total tin content of three new GSJ reference materials, namely, JLk-1, JLs-1, and JDo-1.

Analytical Sciences↗
USGS2013

Selenium in irrigated agricultural areas of the western United States

Selenium was recognized as an important aquatic contaminant following the identification of widespread deformities in waterfowl at the agricultural drainage evaporation ponds of the Kesterson Reservoir (California) in 1983. Since then, California has been the focal point for global research and management of Se contamination. We analyzed the history and current developments in science, policy, and management of irrigation-induced Se contamination in California. In terms of management, we evaluated the effects of improvements in the design of local attenuation methods (drainage reuse and evaporation ponds) in conjunction with the development of programs for Se load reductions at the regional scale (namely the Grassland Bypass Project). In terms of policy, the USEPA is currently working on site-specific water quality criteria for the San Francisco Bay Delta that may be a landmark for future legislation on Se in natural water bodies. We provide a critical analysis of this approach and discuss challenges and opportunities in expanding it to other locations such as the Salton Sea. Management lessons learned in California and the novel policy approach may help prevent future events of Se contamination.

Journal of Environmental Quality↗
USGS2009

Comment on "Evaluating interactions between groundwater and vadose zone using the HYDRUS-based flow package for MODFLOW" by Navin Kumar C. Twarakavi, Jirka Šimůnek and Sophia Seo

Twarakavi et al (2008) compared four packages that can be used to estimate recharge for regional-scale groundwater flow simulations using MODFLOW (Harbaugh, 2005). This comment is focused on the comparisons made between two of these packages, namely, UZF1 (Niswonger et al., 2006) and a derivative of HYDRUS referred to herein as HYDRUS (Seo et al., 2007). In their paper, Twarakavi et al. (2008) stated that HYDRUS more accurately simulates unsaturated flow processes and groundwater recharge as compared to UZF1. However, Twarakavi et al. (2008) did not address several important differences between these models that undermine the advantages of HYDRUS as compared to UZF1 for simulating recharge. These differences were not revealed by the comparisons presented by Twarakavi et al. because the test simulations used to compare the models were too simple

Vadose Zone Journal↗
USGS2025

Wangyanite, PdNi8S8, a new Pd end-member mineral of the pentlandite group from the J-M reef, Stillwater Complex, Montana, USA

Wangyanite (IMA2024-008a), ideally PdNi 8 S 8 , is a Pd end-member mineral of the pentlandite group that was discovered in the J-M reef of the Stillwater Complex, Montana, USA. Wangyanite occurs as anhedral-subhedral granular crystals 200–400 µm in size, associated with isoferroplatinum, braggite, pentlandite, and chalcopyrite interstitial to plagioclase grains within anorthosite. Wangyanite exhibits a yellowish brown color with a black streak and a metallic luster. It is brittle with uneven fractures, and has a calculated density of 5.14 g/cm 3 . The mineral does not show discernible pleochroism, bireflectance, or anisotropy. It has an average composition of 9.95 wt.% Pd, 31.95 wt.% Ni, 25.02 wt.% Fe, 0.57 wt.% Co, 31.74 wt.% S, totaling 99.23 wt.%. The empirical formula, based on eight sulfur atoms per formula unit, is (Pd 0.76 Co 0.08 ) Σ0.84 (Ni 4.39 Fe 3.60 ) Σ7.99 S 8 . Wangyanite has a cubic cell with a space group of Fm -3 m (#225), having lattice parameters of a = 10.1167(12) Å, V = 1035.4(4) Å 3 , and Z = 4. Its crystal structure has been solved by single-crystal three-dimensional electron diffraction study. The strongest X-ray diffraction lines of wangyanite are claculated at [ d in Å ( I %)( hkl )]: 5.841(14.03)(111), 3.050(100)(311), 1.947(29.16)(115,333), 1.264(11.66)(800), 3.577(8.79)(220), 2.920(20.82)(222), and 2.321(9.34)(331). Wangyanite shares the same crystal structure as pentlandite, but the octahedrally coordinated site is mainly occupied by Pd in wangyanite. Based on the textural features and previous experimental Pd-Fe-Ni-S phase system, wangyanite could form by peritectic reaction between braggite, pentlandite and sulfide liquid. These mineral associations are stable in a Ni-Pd-rich sulfide melt system at about 550 °C or even lower temperature. Therefore, wangyanite can potentially serve as an indicator of the presence of Pd-rich residual melts. The mineral is named in honor of Prof. Christina Yan Wang, a well-known researcher on platinum-group element (PGE) occurrences and enrichment mechanisms in mafic-ultramafic intrusions, notably those deposits related to the Emeishan large igneous province in China.

Montana↗
USGS2000

Metal-sulfate salts from sulfide mineral oxidation

The observation of “efflorescences,” or the flowering of salts, associated with periods of dryness in soils, in closed-basin lakes, in rock outcrops, and in mines and mine wastes has been noted since early antiquity. The formation of metal-sulfate salts, in connection with the mining of metals, was a phenomenon well known to the early Greek and Roman civilizations. Alum, most commonly potash alum KAl(SO 4 ) 2 · 12H 2 O, which is from the Latin alumen , was extensively mined and used by goldsmiths, dyers, paper manufacturers, and physicians in ancient civilizations. It forms from the oxidation of pyrite in shales and slates and from oxidation of sulfurous gases in geothermal areas. The Greeks and the Romans described stalactites of atramentum (soluble metal-sulfate salts) that formed within mines and along rock faces (Agricola 1546, 1556). Furthermore, the toxic effects of these salts on animals were also noted. For example, in De Natura Fossilium , Agricola (1546) stated “….I mention the congealed acid juice which usually produces cadmia . It is white, hard, and so acrid that it can eat away walls, grills and even destroy all living matter.” Cadmia is thought to be derived from the oxidation of zinc, cobalt, and arsenic sulfides, such as cobaltite. He goes on to say that “Pyrite, unless it contains sulphates, is either a golden or silver color, rarely any other, while cadmia is black, yellow brown, or gray. The former will cure gatherings while the latter is a deadly poison and will destroy any living substance. It is used to kill grasshoppers, mice and flies.” These descriptions suggest the presence of arsenic compounds. The range of colors from white to black commonly is caused by different amounts of admixed pyrite with sulfate minerals. From the days of the Greek philosopher Theophrastus ( ca 325 BCE) and the Greek physician Dioscorides (first century CE), the efflorescent salts atramentum sutorium virida or melanterite (also called melanteria ) and atramentum sutorium caeruleum or chalcanthite were well known to form from the corrosion of pyrite and chalcopyrite by moisture (Agricola 1546, footnotes on p. 47–51). By the time of Pliny the Second (Caius Plinius Secundus, 23–79 CE), the names “green vitriol” for melanterite and “blue vitriol” for chalcanthite were in common use and continued to be used from the Middle Ages to the 20th century.

Reviews in Mineralogy and Geochemistry↗
USGS2014

The environmental geochemistry of Arsenic – An overview

Arsenic is one of the most prevalent toxic elements in the environment. The toxicity, mobility, and fate of arsenic in the environment are determined by a complex series of controls dependent on mineralogy, chemical speciation, and biological processes. The element was first described by Theophrastus in 300 B.C. and named arsenikon (also arrhenicon; Caley and Richards 1956 ) referring to its “potent” nature, although it was originally considered an alternative form of sulfur ( Boyle and Jonasson 1973 ). Arsenikon is believed to be derived from the earlier Persian, zarnik (online etymology dictionary, http://www.etymonline.com/index.php?term=arsenic ). It was not until the thirteenth century that an alchemist, Albertus Magnus, was able to isolate the element from orpiment, an arsenic sulfide (As 2 S 3 ). The complex chemistry required to do this led to arsenic being considered a “bastard metal” or what we now call a “metalloid,” having properties of both metals and non-metals. As a chemical element, arsenic is widely distributed in nature and can be concentrated in many different ways. In the Earth’s crust, arsenic is concentrated by magmatic and hydrothermal processes and has been used as a “pathfinder” for metallic ore deposits, particularly gold, tin, copper, and tungsten ( Boyle and Jonasson 1973 ; Cohen and Bowell 2014 ). It has for centuries been considered a potent toxin, is a common poison in actual and fictional crimes, and has led to significant impacts on human health in many areas of the world ( Cullen 2008 ; Wharton 2010 ).

Reviews in Mineralogy and Geochemistry↗
USGS2007

Minimising visitor impacts to protected areas: The efficacy of low impact education programmes

Protected area managers, tourism providers, and other organisations commonly employ education programmes to address visitation-related impairment of natural and cultural resources, social conditions, and neighbouring communities. These programmes have different names (Leave No Trace, Codes of Conduct, Environmental Guidelines for Tourists) but share common objectives: to sustain opportunities for high quality visitor experiences while avoiding or minimising associated negative impacts to protected area resources, visitor experiences, and park neighbours. Theoretical and empirical research studies in the United States are reviewed to evaluate the efficacy of educational efforts that seek to encourage adoption of low impact behaviours. Findings reveal that most of the visitor education efforts evaluated did effectively alter visitor knowledge, behaviour and/or resource and social conditions in the intended direction. These findings, including discussions of message content, delivery, audience characteristics and theoretical grounding, provide insights for improving the efficacy of future educational efforts.

Journal of Sustainable Tourism↗