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Geologic map of the northwest flank of Mauna Loa volcano, Island of Hawai‘i, Hawaii

Mauna Loa, the largest active volcano on Earth, has erupted 34 times since written descriptions became available in A.D. 1832. The most recent eruption of Mauna Loa occurred on November 27, 2022, after a 38 year hiatus; it lasted for 12 days. Some eruptions began with only brief seismic unrest, whereas others followed several months to a year of increased seismicity. Once underway, Mauna Loa’s eruptions can produce lava flows that may reach the sea in less than 24 hours, severing roads and utilities. For example, lava flows that erupted from the Southwest Rift Zone in 1950 advanced at an average rate of 9.3 kilometers per hour (5.8 miles per hour); all three lobes reached the ocean within ~24 hours. Near the eruptive vents, the flows likely traveled even faster. In terms of eruption frequency, pre-eruption warning, and rapid flow emplacement, Mauna Loa has great volcanic-hazard potential for the Island of Hawai‘i. Volcanic hazards on Mauna Loa can be anticipated, and risk substantially mitigated, by documenting its past activity to refine our knowledge of the hazards, and by alerting the public and local government officials of our findings and their implications for hazards assessments and risk. The map of the north and west flanks of Mauna Loa shows the distribution and relation of volcanic and surficial sedimentary deposits. It incorporates previously reported work published as generalized small-scale maps and a more detailed map. Within the mapped area, lava has flowed from three different source regions: the Northeast Rift Zone (22 percent), the summit (64 percent), and radial vents (14 percent). All three have different points of origin which, in turn, affect the flow characteristics and periodicity of activity. The map area includes the uppermost part of the NERZ and extends from the highest elevation––13,040 feet at the south end of the Kokoolau quadrangle, just below the summit caldera––to the sea northwest and west of the summit. Lava that erupts from the north and west flanks typically flows to the west, northwest, or north, depending on the vent location. Both morphologic lava flow types—‘a‘ā and pāhoehoe—are present. Pāhoehoe units tend to spread out or widen in low-slope regions, such as in the saddle regions between Mauna Loa and Mauna Kea or between Mauna Loa and Hualālai. In comparison, ʻaʻā flows generally produce narrower flow lobes that have higher relief. This map is the fifth in a series of five maps that will cover Mauna Loa volcano. NOTE: Map sheet 1 contains lines and type with overprint. This feature may be turned on or off in the Adobe Acrobat page display preferences.

Hawaii

Understanding market sensitivity: Estimation of supply and demand elasticities for non-fuel minerals

In today’s rapidly changing economic landscape, understanding market responsiveness to price changes and the factors influencing commodity prices has become increasingly relevant. Price elasticities serve as indicators of how variations in market conditions affect supply and demand, providing insights into the sensitivity of commodity markets to price fluctuations. This paper presents a comprehensive analysis of price elasticities of supply and demand for 74 non-fuel mineral commodities including precious metals, base metals, minor metals, and industrial minerals that are utilized across various industries. We employ various econometric techniques, including fixed effects models for panel data and two-stage dynamic ordinary least squares (2S-DOLS) alongside autoregressive distributed lag (ARDL) models for time series analysis, to derive robust estimates of price elasticities. Our findings reveal variability in elasticities among different commodities and indicate that all studied mineral commodities exhibit price inelastic supply and demand in the short run, which we define as one year for the purposes of our analysis, given that the data is all annual. This research provides original estimates of price responsiveness for a wide range of commodities that have not been previously addressed in the literature, thereby enhancing the understanding of market dynamics in the mineral sector. Given that price elasticities can be influenced by factors such as market structure, technological advancements, mining costs, and industry-specific demand drivers, we use variables that serve as proxies for these factors.

Mineral Economics

Connecting flood-related fluvial erosion and deposition with vulnerable downstream road-stream crossings

Fluvial erosion is increasingly responsible for infrastructure and building damages associated with floods as the intensity of extreme rainfalls hit rural and urban rivers in a variety of climate settings across the United States. Extreme floods in 2016 and 2018 caused widespread culvert blockages and road failures, including extensive damage along steep tributaries and ravines in the Marengo River, Wisconsin, watershed during 2016 and 2018. A study conducted by the U.S. Geological Survey (USGS), Wisconsin Wetlands Association (WWA), Ashland County, and the Northwest Wisconsin Regional Planning Commission (NWRPC) investigated the special concern of fluvial erosion hazards (FEHs) associated with gullying, streamside landslides, and the loss of wetland storage in headwaters. In 2019, a pilot study was begun to map and classify ephemeral and perennial streams and wetlands in terms of their sensitivity to FEHs. This study combined data from field-based rapid geomorphic assessments (RGAs) coupled with a stream network-wide geographic information system (GIS) approach for mapping stream segments, referred to as fluvial process zones (FPZ), sensitive to erosion, deposition, and channel change. The GIS approach used nationally available 10-meter (m) resolution topology and an extended stream network to map FPZs based on Strahler stream order, stream power, channel slope, presence of adjacent steep valley sides and headwater flats, and adjacent landform setting. Bankfull channel widths derived from RGA-based hydraulic geometry curves combined with drainage areas, an estimate of bankfull flow, and channel slope were used to calculate specific stream power for the FPZs. Lastly, the FPZs were characterized by their location within three major landform settings that affect erosion potential. The resulting vulnerability maps provided a screening framework to identify FPZs that are sensitive to incision, gullying and mass wasting along steep headwater ephemeral channels, as well as downstream perennial channels that have the potential for valley-side landslides, coarse sediment deposition, and channel change. Lastly, each FPZ was characterized in terms of hydrologic alteration associated with ditching. The vulnerability mapping products and rankings of sensitivity of FPZs will ultimately be used by Ashland County and their collaborators to prioritize natural flood management projects that mitigate FEHs, restore hydrology, and reconnect channels with adjacent wetlands and floodplains.

Wisconsin

A multidisciplinary approach that considers occurrence, geochemistry, bioavailability, and toxicity to prioritize critical minerals for environmental research

Critical minerals (or critical elements) are minerals or elements that are essential to global security and development and have supply chains vulnerable to disruption. In general, knowledge of the environmental behavior and health effects of critical elements is needed to support the development of safe and environmentally responsible supplies. This knowledge includes identifying potential consequences of increased critical element production and use, alternative critical element sources such as mine wastes, and adverse effects of critical elements on ecosystem condition and organismal health. Here we identify significant data gaps in the understanding of critical elements in surficial and aquatic environments, and the need, given the large number of commodities (50) identified on the 2022 critical minerals list for the United States, for an approach to prioritize them for study of their environmental fate and effects. We propose a multidisciplinary approach for this prioritization, considering measures of occurrence, geochemistry, bioavailability, and toxicity. We describe relatively easy-to-obtain metrics for each of these topic areas and demonstrate the utility of this integrated prioritization approach using indium and zinc as examples. This approach facilitates prioritizing research with a focus on those critical elements that are most mobile in the environment, bioavailable, toxic, or simply lacking data in these categories.

Environmental Science & Technology

Effect of land cover type on 3D deformation recovery from synthetically deformed high-resolution satellite optical imagery

The limits of detection for earthquake surface deformation in the spatial domain have improved with advances in remote sensing imagery data availability, resolution, and analysis. Sub-pixel correlation and digital elevation model (DEM) differencing from sub-meter, earthquake-spanning satellite optical imagery has enhanced surface rupture mapping and deformation measurements. However, knowledge of measurement accuracy and uncertainty is limited. To address this, we construct orthophotos and digital elevation models (DEMs) from repeat high resolution (∼0.5 m) satellite optical imagery along two sections of the Garlock fault, California with clear fault geomorphology and differing land cover. We deform later sets of DEMs and images with synthetic earthquakes containing both diffuse and discrete horizontal and vertical displacements. Sub-pixel image correlation and DEM differencing demonstrate how vegetation degrades recovered displacement accuracy. In barren land cover, horizontal displacements are detectable to an expected ∼1/10th-pixel size. With shrubs, trees, and grass, detectable displacements increase to >1/2-pixel size, and filtering results by correlation score and using elevation values as input rather than image values improves accuracy. Vertical displacement detection thresholds remain lower in vegetation, at >1-pixel size. Higher slope angles degrade displacement recovery, worsened by vegetation. Diminishing seasonal separation improves accuracy over vegetated regions, though not to the level achieved in barren environments. These results will inform research and operational efforts on the utility of high resolution satellite optical imagery for detecting deformation in varied land cover. Furthermore, they reveal where alternative measurements, such as from LiDAR or radar interferometry, are required to mitigate the effects of vegetation and capture fine-scale crustal deformation.

California

Key minerals in energy transmission

The electrical grid relies on minerals with unique properties to transform, transmit, and convert electricity. Transmission needs are growing—to support the expansion of data centers and link diverse energy resources into the grid. This expansion will require greater quantities of minerals. Although some minerals are produced in the United States, the United States relies on imports for others. This infographic shows the key minerals that support energy transmission, and how reliant the United States is on imports for these minerals.

General Information Product

Apatite (U-Th)/He thermochronology from Marsh Creek anticline reconciles Cenozoic and Holocene strain patterns and elucidates the Cenozoic canning displacement zone of Arctic Alaska

The northeastern Brooks Range is a vast fold-thrust belt that records the northernmost expression of Cenozoic deformation in Alaska, likely with complex dynamic linkages to distant tectonic elements. The principal focus of this manuscript is the Marsh Creek anticline (MCA), which is a large and recently active structure within the broader northeastern Brooks Range. The MCA is a complex, polyphase structure mostly buried beneath the Arctic coastal plain. We present apatite (U-Th)/He (AHe) dates from six outcrop samples, all near the structural crest of the anticline, as well as supporting detrital zircon U/Pb (ZUPb) age spectra from five outcrop samples. The AHe sample transect spans ~3 km of structural relief. The four shallowest AHe samples are not reset. However, the two deepest samples exhibit low intrasample variability among replicates and strong date versus grain radius correlations, suggesting post-depositional burial heating to within the AHe partial retention zone. Inverse thermal history modeling of these data resolves a protracted phase of exhumational cooling that began around 33–28 Ma. Detrital ZUPb age spectra from Paleogene strata support an interpretation of diverse inherited thermal histories recorded by the AHe data, and they are also consistent with extant reconstructions of Paleogene sediment dispersal. Placed into regional context, the results constrain a phase of increasing structural relief in the northeastern Brooks Range fold-thrust belt that began by the Eocene. The relief developed in a zone characterized by diminishing structural relief to the west called the Canning displacement zone. Although this zone was active since the Eocene, several structures including the studied part of the MCA were rapidly exhumed in the Oligocene. Lastly, we argue for kinematic compatibility between Cenozoic contraction and active strike-slip in the northeastern Brooks Range, with the temporal change in strain style likely reflecting the increase in structural relief and topography.

Alaska

Time varying crustal anisotropy at Whakaari/White Island volcano

Whakaari/White Island has been the most active New Zealand volcano in the 21st century, producing small phreatic and phreatomagmatic eruptions, which are hard to predict. The most recent eruption occurred in 2019, tragically claiming the lives of 22 individuals and causing numerous injuries. We employed shear-wave splitting analyses to investigate variations in anisotropy during quiescence, unrest, and an eruption between 2018 and 2020. We examined spatial and temporal variations in 7972 shear-wave splitting measurements and derived 1402 V p /IV s ratio measurements. Comparing shear-wave splitting parameters from similar earthquake paths across different times indicates that the observed temporal changes are unlikely to result from variations in earthquake paths through media with spatial variability. Instead, these changes may stem from variations in anisotropy over time, likely caused by changes in crack alignment due to stress or varying fluid content.

Whakaari/White Island volcano

Representation of surface-water flows using Gradient-Related Discharge in an Everglades Network

The Everglades Depth Estimation Network interpolates water-level gage data to produce daily water-level elevations for the Everglades in south Florida. These elevations were used to estimate flow vectors (gradients and directions) and volumetric flow rates using the Gradient-Related Discharge in an Everglades Network (GARDEN) application developed by the U.S. Geological Survey in cooperation with the U.S. Army Corps of Engineers. Flow rates in both the east-west and north-south directions were computed on a 400-meter square grid using modified parameters in the Manning’s equation. The frictional resistance parameter in the Manning’s equation was calibrated to measured flow rates at coastal creeks fed by Everglades Depth Estimation Network boundary flows. Levees and other features that act as barriers to flow were defined as “no-flow” grid cells where vectors were set to zero. The flow volume magnitudes were calibrated with 2020 daily values of coastal river flows, and verification was performed using 2021 data. Within a given day, the measured coastal river flows fluctuate more than the GARDEN boundary flows because of tidal and wind forcings. Because the GARDEN boundary flows were the upstream water source for the coastal rivers, calibration focused on matching average daily flow volumes rather than daily fluctuations. The Pearson’s correlation coefficient is 0.766 for the 2020 calibration period and 0.566 for the 2021 verification period. Applying GARDEN to periods with hydraulic-control-structure releases allows the propagation of structure flows to be seen in the daily flow-vector maps along with the multiday response of flows farther downgradient. Flow vectors may be overestimated near control structures because of difficulties in resolving the water gradient downstream from the structure. Flow vectors farther from the structure are more accurate than those near the structure.

Florida

Effects of drought and cloud-water interception on groundwater recharge and wildfire hazard for recent and future climate conditions, Kauaʻi, Oʻahu, Molokaʻi, Maui, and the Island of Hawaiʻi

The Water-budget Accounting for Tropical Regions Model (WATRMod) code was used for Kauaʻi, Oʻahu, Molokaʻi, Maui, and the Island of Hawaiʻi to estimate the spatial distribution of groundwater recharge, soil moisture, evapotranspiration, and climatic water deficit for a set of water-budget scenarios. The scenarios included historical and future drought conditions, and a land-cover condition where shrubland and forest within the cloud zone were converted to grassland. For the historical drought condition, island-wide mean annual recharge estimates range from a decrease of 30 percent (239 million gallons per day [Mgal/d]) for Kauaʻi to a decrease of 39 percent (2,706 Mgal/d) for the Island of Hawaiʻi, relative to the reference condition consisting of 1978–2007 rainfall and 2020 land cover. For the future drought condition, estimates of island-wide mean annual recharge range from a decrease of 40 percent (477 Mgal/d) on Maui to a decrease of 51 percent (116 Mgal/day) on Molokaʻi. Complete conversion of all shrubland and forest within the cloud zone to grassland for each drought condition produces estimated land-cover-related decreases in island-wide mean annual recharge (in addition to the drought-related decreases) of 11–12 Mgal/d on Oʻahu, 119–135 Mgal/day on Maui, and 689–849 Mgal/d on the Island of Hawaiʻi. The spatial distributions of increases in conditions indicative of moisture stress and potential wildfire hazard were quantified using the relative frequency of soil moisture less than a selected threshold value (monthly mean soil moisture less than 0.074, expressed as a fraction of available water capacity), evapotranspiration less than a selected threshold value (monthly evapotranspiration less than 0.96 inches), and climatic water deficit greater than a selected threshold value (monthly climatic water deficit greater than 0.77, expressed as fraction of potential evapotranspiration). For the historical drought condition, the greatest increases in the relative frequency for the moisture-stress indicators occur across parts of east and southwest Kauaʻi; central, east, and west Oʻahu; central Molokaʻi; central Maui and low- to mid-altitude parts of West Maui volcano; and the northwestern and southern parts of the Island of Hawaiʻi. For the future drought condition, the greatest increases in the relative frequency of the moisture-stress indicators occur across parts of west Kauaʻi; central and west Oʻahu and Molokaʻi; a band of mid-altitude area on the southern slope of West Maui volcano and across the southwestern slope of Haleakalā; and mid-altitude areas of the northwestern and southern parts of the Island of Hawaiʻi. Complete conversion of all shrubland and forest within the cloud zone to grassland for each drought condition results in land-cover-related increases in the relative frequency of moisture-stress indicators around Kaʻala in the Waiʻanae Range and the southeastern part of the Koʻolau Range on Oʻahu, the southern part of West Maui volcano and the southwestern slope of Haleakalā on Maui, and the upland regions of the western and southern parts of the Island of Hawaiʻi.

Hawaii

Testing rate‐and‐state predictions of aftershock decay with distance

We analyze aftershocks of the 2019 M 7.1 Ridgecrest mainshock and isolated M 5–6 mainshocks in southern California to test predictions made by the rate‐and‐state friction model of Dieterich (1994) . Rate‐and‐state friction predicts that the seismicity rate after a stress step follows Omori decay, where the Omori c ‐value, which is the saturation in aftershock rate observed at small times, is larger for smaller stress steps. Put in the context of an aftershock sequence, this predicts that the Omori c ‐value will be systematically larger at greater distances from the mainshock. To our knowledge, this predicted effect has not been observed. In part this may be because the Omori c ‐value is difficult to measure because it often reflects short‐term catalog incompleteness rather than a true saturation in aftershock rate. We explore the dependence of the Omori c ‐value on the distance to the mainshock by applying the “ a ‐positive” method ( van der Elst and Page, 2023 ). This method is insensitive to short‐term aftershock incompleteness and allows resolution of the true aftershock rate deep into the mainshock coda. For aftershocks of the Ridgecrest mainshock and stacked M 5–6 mainshocks, we observe systematic differences in early aftershock rates, relative to mainshock distance, consistent with the predictions of rate‐and‐state friction. Furthermore, for the larger Ridgecrest dataset, we observe that aftershocks nearer to the mainshock start earlier, and we resolve a flattening of the Omori curve consistent with a larger Omori c ‐value for the farthest aftershocks, as predicted by Dieterich (1994) .

Seismological Research Letters

A time-space model of graphite mineral systems

Increasing demand for graphite in energy storage systems warrants review of graphite ore genesis in a mineral systems framework. Orogenic graphite encompasses the metamorphic and orogenic mineral systems that produce flake graphite and hydrothermal vein (lump and chip) graphite deposits, respectively. A common feature of orogenic graphite deposits is an association with upper amphibolite- to granulite-facies metasedimentary rocks in continent-continent or continent-island arc collisional orogens. Orogenic flake graphite deposits form primarily through graphitization of organic carbon during regional metamorphism, but strain localization and partial melting of pelitic protoliths are likely important processes for graphite grade and quality enrichment. Orogenic vein graphite deposits precipitate from hydrothermal fluids, possibly derived from metamorphism or anatexis at depth. Decarbonation reactions in mixed calcareous-carbonaceous metasedimentary sequences are the most likely carbon sources for the veins. In contrast, intrusion-related graphite includes magmatic-hydrothermal and metamorphic mineral systems that form primarily in continental arc settings via the interaction of magmas with carbonaceous sedimentary packages. Magmatic-hydrothermal flake graphite deposits are hosted in plutonic and volcanic rocks, and result from the exsolution of CO 2 -CH 4 -rich fluids from melts contaminated by such packages. Contact metamorphism of carbonaceous sedimentary rocks by plutons produces some microcrystalline (amorphous) graphite deposits, including many in China. Compilation of geologic data from known graphite deposits globally suggests that pulses of carbon deposition in the Paleoproterozoic, Mesoproterozoic, and Neoproterozoic provided source carbon material. Subsequent supercontinent orogenesis at ca. 2,100 to 1,700 Ma (Columbia), ca. 1,300 to 1,000 Ma (Rodinia), and ca. 650 to 500 Ma (Gondwana) resulted in the genesis of orogenic flake and vein graphite deposits, where favorable geologic components overlapped with organic ± carbonate carbon-rich strata. Cryogenian deposition of graphite protoliths and Cryogenian – Cambrian metamorphic mineralization account for nearly 75% of all known resources globally and coincide with profound carbon isotope excursions and climate variability, implying a link with the global carbon budget. Comparatively few graphite deposits are associated with Pangea-forming orogens, attributed to less exhumation and/or denudation. High-temperature metasedimentary belts containing organic carbon-rich protoliths are most favorable for hosting orogenic flake graphite deposits, whereas sequences that also contain carbonate protoliths are favorable for orogenic graphite veins. Continent-scale orogenic belts may host both deposit types along with vanadium deposits. Use of a time-space mineral systems framework for graphite deposits can improve exploration models needed to ensure future supply of this critical mineral and provide insights into Earth’s long-term carbon cycle.

Mineralium Deposita

Effective site coefficients for the 2024 International Building Code (IBC)

The U.S. National Seismic Hazard Models (NSHMs), developed by the U.S. Geological Survey (USGS), have long been the scientific foundation of seismic design guidelines and have been used to compute design ground motions for construction of new buildings and retrofit of existing buildings in the United States and its territories. The 2018 NSHM is adopted by the 2024 International Building Code (IBC). Prior to the 2018 NSHM update, hazard calculations were required only at one reference site condition defined by V S30 =760 m/s (where V S30 is the time-averaged shear wave velocity from the surface to a depth of 30 m) and three periods (peak ground acceleration, PGA, and pseudo spectral accelerations at periods of 0.2 and 1 s, S s and S 1 ). Site coefficients, F PGA , F a , and F v , were then defined by the Building Seismic Safety Council (BSSC) Provisions Update Committee (PUC) in the site-specific procedures of National Earthquake Hazard Reduction Program (NEHRP) Recommended Seismic Provisions to calculate ground motions for other site classes with different V S30 values at the given periods. The design ground motions at other periods were then estimated using a generic spectral shape that was also defined by the BSSC PUC in NEHRP provisions. In recent years, the engineering community has realized there were deficiencies with the F a and F v site coefficients and the generic spectral shape. To avoid potentially dangerous underestimations of design ground motions for long period structures on soft site conditions in high seismicity regions, the BSSC PUC recommended the use of multi-period response spectra (MPRS) in 2017. As a result, the USGS produced multi-period and multi-V S30 response spectral values in the 2018 NSHM for calculations of design ground motions and the site coefficients F a and F v were eliminated from the 2020 NEHRP Provisions. As these site coefficients were widely used inside and outside of the United States, in this study we back-calculate the “effective” site coefficients F a,eff , and F v,eff by comparing MPRS for various site classes with the MPRS for the reference site condition, and discuss the changes that are observed in the 2024 IBC compared to its previous version in 2021. The effective site coefficients are presented for test site locations and their dependence on various factors including period, ground motion intensity, and regional models are discussed. Ratio maps between the new effective site coefficients and the old ones are then presented for soft site classes and for short and long periods. For soft site classes at short periods, the new effective site coefficients are lower than the old site coefficients for high seismicity regions and higher for low seismicity regions. As it was expected, for soft site classes at long periods and high seismicity regions, the new effective site coefficients are much larger than the old site coefficients without imposing the 50% increase as a penalty that was suggested in the 2021 IBC, whereas they could be much smaller if the 50% increase would have been imposed particularly around New Madrid and Charleston high seismicity regions. For low seismicity regions, the long period effective site coefficients can be smaller or larger by 20% compared to the 2021 IBC coefficients.

Conference Paper

Late Miocene Colorado River arrival in the Bidahochi basin supports spillover origin of Grand Canyon

The timing and mechanism of the integration of the Colorado River and incision of the Grand Canyon remain among geology’s enduring controversies. A key question is the configuration of the upper Colorado River watershed between 11 and 6 million years ago. In this study, we present new evidence from zircon uranium-lead geochronology for the arrival of distinctive Colorado–Green River sediment in the Bidahochi basin by 6.6 million years ago derived from the Browns Park Formation. This is coeval with an order-of-magnitude increase in depositional rate, an increase in carbonate strontium isotope ( 87 Sr/ 86 Sr) ratios, the appearance of large fish species characteristic of fast-flowing waters, and other sedimentological changes. This evidence is consistent with the Colorado River supplying water and sediment to the Bidahochi basin before spillover integration of the river through the Grand Canyon.

Arizona, Nevada, Utah

Top-down targeted network analysis of critical mineral commodities applied to international geochemistry database

The global demand for critical mineral commodities is rapidly increasing, making domestic production an important factor in supporting the economy and national security. Large scale, publicly available geochemical databases allow for the application of data informatics methods to interrogate critical mineral commodities data for correlations in deposit formation and distribution, particularly for identifying enrichment of multiple critical mineral commodities at the same deposit. In this study, we applied network analysis to the Critical Minerals Mapping Initiative (CMMI) ore geochemistry (Critical Minerals in Ores, CMiO) database to identify the high concentration (defined as 10× bulk crustal abundance) co-occurrence of different critical mineral commodities across a mineral system hierarchy from deposit environments to individual deposits. Identifying patterns or unique outliers in enrichment in network communities will allow for the location of secondary critical mineral commodity resources from under-utilized deposits. We find trends in the enrichment of critical mineral commodities in network-communities between the elements praseodymium (Pr), neodymium (Nd), terbium (Tb), and dysprosium (Dy) across multiple CMiO database deposit environments and groups down to specific deposit types and sites. A separate trend in network community deposition is observed as well between iridium (Ir) and platinum (Pt) in deposit environments, groups, types, and sites. Network analysis focused on critical minerals in magmatic-hydrothermal deposits identified multiple deposit sites from different deposit types within the CMiO database with concentrations of Dy, Nd, Tb, Pr, Ir, and Pt that are at least ten times greater than the crustal average. This approach can be applied to any target element(s) or deposit(s) of interest, allowing broad investigation of co-enriched critical mineral commodities.

Journal of Geochemical Exploration

Methods and guidelines for effective model calibration; with application to UCODE, a computer code for universal inverse modeling, and MODFLOWP, a computer code for inverse modeling with MODFLOW

This report documents methods and guidelines for model calibration using inverse modeling. The inverse modeling and statistical methods discussed are broadly applicable, but are presented as implemented in the computer programs UCODE, a universal inverse code that can be used with any application model, and MODFLOWP, an inverse code limited to one application model. UCODE and MODFLOWP perform inverse modeling, posed as a parameter-estimation problem, by calculating parameter values that minimize a weighted least-squares objective function using nonlinear regression. Minimization is accomplished using a modified Gauss-Newton method, and prior, or direct, information on estimated parameters can be included in the regression. Inverse modeling in many fields is plagued by problems of instability and nonuniqueness, and obtaining useful results depends on (1) defining a tractable inverse problem using simplifications appropriate to the system under investigation and (2) wise use of statistics generated using calculated sensitivities and the match between observed and simulated values, and associated graphical analyses. Fourteen guidelines presented in this work suggest ways of constructing and calibrating models of complex systems such that the resulting model is as accurate and useful as possible.

Water-Resources Investigations Report

Forecasting volcanic activity in Germany—A multi-criteria approach

Igneous activity, including shallow intrusions and volcanism, has the potential to disrupt underground critical infrastructure. Notably, future underground infrastructure projects like high-level radioactive waste repositories must be sited in areas of extremely low disruption probability by igneous activity. In Germany, according to the Repository Site Selection Act of 2017 (Standortauswahlgesetz, or StandAG), areas in which Quaternary volcanism is either present or future volcanic activity is expected within the next 1 million years (m.y.) must be excluded from the site selection process. Although the locations of regions with Quaternary volcanism are reasonably well known in Germany, forecasting potential igneous activity at intraplate volcanic fields is challenging, as many processes and their interactions control the spatial distribution of volcanic centers. Here, a semi-quantitative, multi-criteria approach is proposed for a regional evaluation of the relative potential of future igneous activity in Germany. A variety of geoscientific indicators are used, including seismic anomalies in Earth’s mantle, gravity data, tectonic activity, sutures, ground motion, earthquakes, mantle degassing centers, and geochronological data of volcanic rocks. The indicators describe the sequence of processes from potential melt generation in Earth’s mantle, through ascent and accumulation of melt within the lithosphere, to eruption at Earth’s surface. In total, 15 out of 30 proposed geoscientific indicators are selected and quantified using 20 total assigned parameters. Defined threshold values are used to spatially delimit relevant parameter properties to focus on areas with higher potential of future magmatic activity. To consider uncertainties of parameters and their underlying processes, which are usually more spatially extensive below ground, buffer zones are defined in which values of relevance decrease with increasing distance from the initial lateral shape of a parameter. Normalized parameters are combined into an index, whose spatial value distribution is used to differentiate the relative potential of future igneous activity (within the next 1 m.y.). The sensitivity of the results is shown by varying the weighting factors for the relevant parameters in country-wide index maps. Thereby, profiles illustrate the distribution of the resulting index values and respective index fractions of various parameters. Different index maps for the relative potential of future igneous activity are presented and can be used for hazard assessments.

Professional Paper

Nonpoint-source pollutant discharges of the three major tributaries to Reelfoot Lake, west Tennessee, October 1987-September 1989

An investigation of the concentration and loads of nitrogen, phosphorus, and suspended sediment in storm runoff to Reelfoot Lake, in western Tennessee, was conducted from October 1987 through September 1989. Concentrations of selected herbicides also were defined. Reelfoot Lake, with a surface area of about 15,500 acres, is the largest natural lake in Tennessee and an important recreation and fisheries resource. Previous studies showed that the lake is hypereutrophic, a condition caused by high concentrations of nutrients in water and sediments discharged from the three principal tributaries (South Reelfoot Creek, North Reelfoot Creek, and Running Slough) to the lake. Pesticides, including herbicides, have been detected in the lake's bottom sediments. Storm runoff contributed about 87percent of the total water discharge of the three main tributaries to Reelfoot Lake. South Reelfoot Creek contributed about 4.7 tons per acre per year of suspended sediment, while North Reelfoot Creek contributed about 1.9 tons per acre per year. Running Slough contributed only about 0.31 ton per acre per year of suspended sediment. Most of the suspended sediment was transported by storm runoff between October and March. About 80 percent of the annual streamflow of the three tributaries occurs during these months. The North Reelfoot Creek basin contributed 8.2 pounds per acre per year of total nitrogen and 2.4 pounds per acre per year of total phosphorus. South Reelfoot Creek basin contributed about 6.5 and 1.3 pounds per acre per year of total nitrogen and phosphorus, respectively, while Running Slough basin contributions were 3.4 and 0.86 pounds per acre per year, respectively. The differences in nutrient yields appear to result from more row-crop agriculture and the relatively steeply sloping agricultural land in the North Reelfoot Creek basin. Ninety-one percent of the total nitrogen load and 95 percent of the total phosphorus load in the three streams was transported by storm runoff. Significant differences in the mean concentrations of nutrients in runoff were defined between the active agricultural months (April through September) and the inactive months (October through March). Storm-runoff samples were analyzed for II selected triazine herbicides. Alachlor and atrazine were the most commonly detected herbicides. Thirty-two percent of the samples contained detectable levels of alachlor and 93 percent of the samples contained detectable levels of atrazine. Ninety percent of the samples collected during the active agricultural months contained detectable leveki of alachlor and all 29 samples contained detectable levels of atrazine. Sixteen samples exceeded lifetime health-advisory levels for atrazine in drinking water (3 micrograms per liter); two samples collected from the April IS, 1988, storm at North Reelfoot Creek and South Reelfoot Creek contained 42 and 57 micrograms per liter of atrazine, respectively. Concentrations of the other nine triazine herbicides were generally less than the level of detection (0.1 microgram per liter).

Tennessee