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At least 919 records · Page 51Linked to original sources
USGS1960

Wetland and water supply

The Geological Survey has received numerous inquiries about the effects of proposed changes in the wetland environment. The nature of the inquiries suggests a general confusion in the public mind as to wetland values and an increasing concern by the public with the need for facts as a basis for sound decisions when public action is required. Perhaps the largest gap in our knowledge is in regard to the role played by the wetland in the natural water scheme. Specialists in such fields as agriculture and conservation have studied the wetland in relation to its special uses and values for farming and as a habitat for fish and wildlife. However, except as studied incidentally by these specialists, the role of the wetland with respect to water has been largely neglected. This facet of the wetland problem is of direct concern to the Geological Survey. We commonly speak of water in terms of its place in the hydrologic environment---as, for example, surface water or ground water. These terms imply that water can be neatly pigeonholed. With respect to the wetland environment nothing can be further from the truth. In fact, one objective of this discussion is to demonstrate that for the wetland environment surface water, ground water, and soil water cannot be separated realistically, but are closely interrelated and must be studied together. It should be noted that this statement holds true for the hydrologic environment in general, and that the wetland environment is by no means unique in this respect. Our second and principal objective is to identify some of the problems that must be studied in order to clarify the role of the wetland in relation to water supply. We have chosen to approach these objectives by briefly describing one area for which we have some information, and by using this example to point out some of the problems that need study. First, however, let us define what we, as geohydrologists, mean by wetland and briefly consider wetland classifications. For our purpose wetlands are land areas that are covered with shallow water or subjected to intermittent flooding and subsequent slow drainage, and which generally are characterized by an accumulation of organic matter hereafter termed swamp deposits.' These wetlands may be classified in a number of different ways depending on the purpose of the classifier. For example, the Fish and Wildlife Service classifies wetlands into 20 different types based on water quality (fresh or salty), drainage, and vegetation. At the risk of some oversimplification we might consider 4 types of wetland from the standpoint of hydrology: (1) fresh-water swamps in which the swamp deposits are underlain by glacial till or bedrock; (2)fresh-water swamps in which the swamp deposits are underlain by marine or lacustrine clay and silt; (3) fresh-water swamps in which the swamp deposits are underlain by glacial outwash or alluvium consisting mostly of sand or sand and gravel; and (4) salt .marshes and salt meadows. The three fresh-water types of wetland are of interest with respect to water supply, and of these, the type in which swamp deposits are underlain by glacial outwash is of particular interest in New England. In the Ipswich River basin above the Geological Survey gaging station at South Middleton, Mass., is an area of 44 square miles which forms the headwaters section of the basin. The relief of the area is low. About half the area consists of hills mostly underlain by bedrock but mantled by a thin layer of glacial till. The other half consists Of lowlands---including swamps, low terraces and plains---underlain by glacial outwash, Swampland, used hereafter as a synonym for wetland, forms about a fourth of the area. Some of the swamps occupy depressions in the till blanket and are situated at somewhat higher levels than the lowlands. The largest swamps, however, border the Ipswich River and its tributaries. Here the swamp deposits, which consist of muck and peat mixed with s

Circular↗
USGS2009

Analysis of vertical flow during ambient and pumped conditions in four monitoring wells at the Pantex Plant, Carson County, Texas, July-September 2008

The Pantex Plant is a U.S. Department of Energy/National Nuclear Security Administration (USDOE/NNSA)-owned, contractor-operated facility managed by Babcock & Wilcox Technical Services Pantex, LLC (B&W Pantex) in Carson County, Texas, approximately 17 miles northeast of Amarillo. The U.S. Geological Survey, in cooperation with B&W Pantex through the USDOE/NNSA, made a series of flowmeter measurements and collected other borehole geophysical logs during July–September 2008 to analyze vertical flow in screened intervals of four selected monitoring wells (PTX01–1012, PTX06–1044, PTX06–1056, and PTX06–1068) at the Pantex Plant. Hydraulic properties (transmissivity values) of the section of High Plains (Ogallala) aquifer penetrated by the wells also were computed. Geophysical data were collected under ambient and pumped flow conditions in the four monitoring wells. Unusually large drawdowns occurred at two monitoring wells (PTX06–1044 and PTX06–1056) while the wells were pumped at relatively low rates. A decision was made to redevelop those wells, and logs were run again after redevelopment in the two monitoring wells. Logs collected in monitoring well PTX01–1012 during ambient conditions indicate a dynamic environment that probably was affected by pumping of nearby irrigation or public-supply wells. During pumping, downward vertical flow of 0.2 to 2.1 gallons per minute that occurred during ambient conditions was either reversed or reduced. During pumping, a gradual trend of more positive flowmeter values (upward flow) with distance up the well was observed. Estimated total transmissivity for four production zones identified from Flow–B numerical model results taken together was calculated to be about 3,100 feet squared per day. Logs collected in monitoring well PTX06–1044 during ambient conditions before redevelopment indicate a static environment with no flow. During pumping there was upward vertical flow at rates ranging from 0.1 to about 1.5 gallons per minute. During pumping, a gradual trend of more positive flowmeter values (upward flow) with distance up the well was observed. Estimated total transmissivity before redevelopment for five production zones identified from Flow–B numerical model results, and transmissivity values for each zone, are considered to be in error because of the lack of communication between the well and the aquifer before redevelopment. After redevelopment, logs for well PTX06–1044 during ambient conditions indicate a near-static environment with minimal downward flow. During pumping there was upward vertical flow at rates ranging from 0.5 to about 4.8 gallons per minute. During pumping, a gradual trend of more positive flowmeter values with distance up the well was observed. Estimated total transmissivity after redevelopment for the same five identified production zones taken together was calculated to be about 520 feet squared per day. Logs collected in monitoring well PTX06–1056 during ambient conditions before redevelopment indicate a static environment with no flow. During pumping there was upward vertical flow at rates ranging from 0.3 to about 1.5 gallons per minute. During pumping, a gradual trend of more positive flowmeter values (upward flow) with distance up the well was observed. Estimated total transmissivity before redevelopment for four production zones identified from Flow–B numerical model results taken together was calculated to be about 450 feet squared per day. After redevelopment, logs collected in monitoring well PTX06–1056 during ambient conditions indicate a near-static environment with no flow except for a very small amount of downward flow near the bottom of the well. During pumping there was upward vertical flow at rates ranging from 0.7 to about 2.9 gallons per minute. Estimated total transmissivity after redevelopment for five production zones identified from Flow–B numerical model results taken together was calculated to be about 330 feet squared per day. Logs collected in monitoring well PTX06–1068 during ambient conditions indicate a static environment with no flow. During pumping there was upward vertical flow at rates ranging from 0.4 to 4.8 gallons per minute. During pumping, a gradual trend of more positive flowmeter values (upward flow) with distance up the well was observed. Estimated total transmissivity for four production zones identified from Flow–B numerical model results taken together was calculated to be about 200 feet squared per day.

Open-File Report↗
USGS1977

Factors controlling localization of uranium deposits in the Dakota Sandstone, Gallup and Ambrosia Lake mining districts, McKinley County, New Mexico

Geologic studies were made at all of the uranium mines and prospects in the Dakota Sandstone of Early(?) and Late Cretaceous age in the Gallup mining district, McKinley County, New Mexico. Dakota mines in the adjacent Ambrosia Lake mining district were visited briefly for comparative purposes. Mines in the eastern part of the Gallup district, and in the Ambrosia Lake district, are on the Chaco slope of the southern San Juan Basin in strata which dip gently northward toward the central part of the basin. Mines in the western part of the Gallup district are along the Gallup hogback (Nutria monocline) in strata which dip steeply westward into the Gallup sag. Geologic factors which controlled formation of the uranium deposits in the Dakota Sandstone are: (1) a source of uranium, believed to be uranium deposits of the underlying Morrison Formation of Late Jurassic age; (2) the accessibility to the Dakota of uranium-bearing solutions from the Morrison; (3) the presence in the Dakota of permeable sandstone beds overlain by impermeable carbonaceous shale beds; and (4) the occurrence within the permeable Dakota sandstone beds of carbonaceous reducing material as bedding-plane laminae, or as pockets of carbonaceous trash. Most of the Dakota uranium deposits are found in the lower part of the formation in marginal-marine distributary-channel sandstones which were deposited in the backshore environment. However, the Hogback no. 4 (Hyde) Mine (Gallup district) occurs in sandy paludal shale of the backshore environment, and another deposit, the Silver Spur (Ambrosia Lake district), is found in what is interpreted to be a massive beach or barrier-bar sandstone of the foreshore environment in the upper part of the Dakota. The sedimentary depositional environment most favorable for the accumulation of uranium is that of backshore areas lateral to main distributary channels, where levee, splay, and some distributary-channel sandstones intertongue with gray carbonaceous shales and siltstones of the well-drained swamp environment. Deposits of black carbonaceous shale which were formed in the poorly drained swamp deposits of the interfluve area are not favorable host rocks for uranium. The depositional energy levels of the various environments in which the sandstone and shale beds of the Dakota were deposited govern the relative favorability of the strata as uranium host rocks. In the report area, uranium usually occurs in carbonaceous sandstone deposited under low- to medium-energy fluvial conditions within distributary channels. A prerequisite, however, is that such sandstone be overlain by impermeable carbonaceous shale beds. Low- to medium-energy fluvial conditions result in the deposition of sandstone beds having detrital carbonaceous material distributed in laminae or in trash pockets on bedding planes. The carbonaceous laminae and trash pockets provide the necessary reductant to cause precipitation of uranium from solution. High-energy fluvial conditions result in the deposition of sandstones having little or no carbonaceous material included to provide a reductant. Very low energy swampy conditions result in carbonaceous shale deposits, which are generally barren of uranium because of their relative impermeability to migrating uranium-bearing solutions.

Open-File Report↗
USGS1998

Mercury concentrations in estuarine sediments, Lavaca and Matagorda bays, Texas, 1992

A preliminary assessment of the distribution and variability of total mercury concentrations in five sediment environments—open water, ship channel, dredged spoil, oyster reef, and salt marsh—of the Lavaca-Matagorda Bays estuarine system along the central Texas Gulf Coast shows that the largest total mercury concentrations in the bays are in the 10- to 20-centimeter sample-depth zone in 2 of the 3 sample areas (1 open water and 1 salt marsh) closest to Point Comfort. The concentrations range from 137 to 1,270 micrograms per kilogram in the open-water environment and 73.8 to 1,900 micrograms per kilogram in the saltmarsh environment. In the surface-sample-depth zones among all sediment environments, total mercury concentrations typically are largest in the open-water environment and smallest in the dredged-spoil and salt-marsh environments. Open-water sample areas 1–01, 1–02 (middle Lavaca Bay), and 1–06 (upper Matagorda Bay) have median total mercury concentrations in all three sample-depth zones (0 to 2, 10 to 20, and 20 to 50 centimeters) greater than detection limits. Median concentrations for the different depth zones in the three sample areas range from 30.5 to 705 micrograms per kilogram. Statistical tests indicate that in all three sample-depth zones in open-water sediments, median total mercury concentrations in some sample areas are significantly different from median total mercury concentrations in other sample areas. Another statistical test indicates that the variance in concentrations of open-water samples collected within 10 meters of each other is the same as the variance in concentrations of samples collected randomly within each 1 square kilometer. However, the degree to which a probable lack of independence among the closely spaced data affects the test result is not known. Rank correlation coefficients between total mercury concentration and grain-size fractions (percentages of sand, silt, clay, and silt plus clay) and between total mercury concentration and total organic carbon concentration for open-water sample areas indicate that total mercury concentration has a significant positive correlation with clay percentage in 4 of the 8 open-water sample areas. In 6 of the 8 open-water sample areas, total mercury concentration has a significant positive correlation with silt-plus-clay percentage and total organic carbon concentration. The use of a technique known as kriging to estimate total mercury concentrations at unmeasured sites on the basis of sampling sites where mercury concentrations are measured in openwater sediments in the 0- to 2-centimeter sampledepth zone was explored. Kriging to estimate concentrations in the areas between clusters of sample data points is not a practical solution for obtaining a distribution of concentrations in the bays. U.S. Environmental Protection Agency Method 7471 (Cold Vapor Atomic Absorption) was an acceptable analytical method for determining the total mercury concentrations in the Lavaca-Matagorda Bays estuarine sediment samples. Measurement of additional trace metals would aid in the characterization of total mercury concentrations and in the identification of concentrator/collector relations that are principally responsible for the adsorption of mercurous compounds to particulates in the bottom sediments.

Texas↗
USGS2013

Managing the effects of endocrine disrupting chemicals in wastewater-impacted streams

A revolution in analytical instrumentation circa 1920 greatly improved the ability to characterize chemical substances. This analytical foundation resulted in an unprecedented explosion in the design and production of synthetic chemicals during and post-World War II. What is now often referred to as the 2nd Chemical Revolution has provided substantial societal benefits; with modern chemical design and manufacturing supporting dramatic advances in medicine, increased food production, and expanding gross domestic products at the national and global scales as well as improved health, longevity, and lifestyle convenience at the individual scale. Presently, the chemical industry is the largest manufacturing sector in the United States (U.S.) and the second largest in Europe and Japan, representing approximately 5% of the Gross Domestic Product (GDP) in each of these countries. At the turn of the 21st century, the chemical industry was estimated to be worth more than $1.6 trillion and to employ over 10 million people, globally. During the first half of the 20th century, the chemical sector expanded rapidly, the chemical industry enjoyed a generally positive status in society, and chemicals were widely appreciated as fundamental to individual and societal quality of life. Starting in the 1960s, however, the environmental costs associated with the chemical industry increasingly became the focus, due in part to the impact of books like “Silent Spring” and “Our Stolen Future” and to a number of highly publicized environmental disasters. Galvanizing chemical industry disasters included the 1976 dioxin leak north of Milan, Italy, the Love Canal evacuations in Niagara, New York beginning in 1978, and the Union Carbide leak in Bhopal, India in 1984. Understanding the environmental impact of synthetic compounds is essential to any informed assessment of net societal benefit, for the simple reason that any chemical substance that is in commercial production or use will eventually find its way to the environment. Not surprisingly given the direct link to profits, manufacturers intensely investigate and routinely document the potential benefits of new chemicals and chemical products. In contrast, the environmental risks associated with chemical production and uses are often investigated less intensely and are poorly communicated. An imbalance in the risk-benefit analysis of any synthetic chemical substance or naturally occurring chemical, which presence and concentration in the environment largely reflects human activities and management, is a particular concern owing to the fundamental link between chemistry and biology. Biological organisms are intrinsically a homeostatic balance of innumerable internal and external chemical interactions and, thus, inherently sensitive to changes in the external chemical environment.

Book chapter↗
USGS2019

The importance of natural versus human factors for ecological conditions of streams and rivers

Streams are influenced by watershed-scale factors, such as climate, geology, topography, hydrology, and soils, which mostly vary naturally among sites, as well as human factors, agriculture and urban development. Thus, natural factors could complicate assessment of human disturbance. In the present study, we use structural equation modeling and data from the 2008-2009 United States National Rivers and Streams Assessment to quantify the relative importance of watershed-scale natural and human factors for in-stream conditions. We hypothesized that biological condition, represented using a diatom multimetric index (MMI), is directly affected by in-stream physicochemical environment, which in turn is regulated by natural and human factors. We evaluated this hypothesis at both national and ecoregion scales to understand how influences vary among regions. We found that direct influences of in-stream environment on diatom MMIs were greater than natural and human factors at the national scale and in all but one ecoregion. Meanwhile, in-stream environments were jointly explained by natural variations in precipitation, base flow index, hydrological stability, % volcanic rock, soil water table depth, and soil depth and by human factors measured as % crops, % other agriculture, and % urban land use. The explained variance of in-stream environment by natural and human factors ranged from 0.30 to 0.75, for which natural factors independently accounted for the largest proportion of explained variance at the national scale and in seven ecoregions. Covariation between natural and human factors accounted for a higher proportion of explained variance of in-stream environment than unique effects of human factors in most ecoregions. Ecoregions with relatively weak effects by human factors had relatively high levels of covariance, high levels of human disturbance, or small ranges in human disturbance. We conclude that accounting for effects of natural factors and their covariation with human factors will be important for accurate ecological assessments.

Science of the Total Environment↗
USGS2021

Germination potential of baldcypress (Taxodium distichum) swamp soil seed bank along geographical gradients

Changing environments of temperature, precipitation and moisture availability can affect vegetation in ecosystems, by affecting regeneration from the seed bank. Our objective was to explore the responses of soil seed bank germination to climate-related environments along geographic gradients. We collected seed banks in baldcypress ( Taxodium distichum ) swamps along the Mississippi River and the Gulf of Mexico Coast in the United States, which have distinct temperature and/or precipitation gradients, and germinated them in a greenhouse. The frequency, richness and seed density of species germinated from the seed bank were compared between various geographic locations, experimental water regimes (saturated, flooded) and wetland types (tidal, non-tidal and inland swamps). We also analyzed the relationship of seed density to the environment by using a Non-metric Multi-dimensional Scaling (NMDS) model. Sixty-one species germinated from the seed bank, differing in pattern by geographic location, experimental water regime and wetland type. The foundation species (i.e., T. distichum and Cephalanthus occidentalis ) germinated with a niche affinity for the northern part of the latitudinal gradient (Tennessee and Illinois) and these species may shift northward with climate change. Some species had higher seed density in the locations that were subject to more persistent drought conditions (e.g., Texas) including Cyperus rotundus and Gratiola virginiana , indicating that these species may be better adapted to sites with high temperature and low precipitation. In contrast, certain species including Saururus cernuus and Ludwigia palustris were present throughout the range of these gradients, and so may be more resilient to any future climate shifts. We found that the regeneration potential of baldcypress swamps might be altered by changes in local and climate environment because of nuances of responses of seed banks to climates along latitudinal and longitudinal gradients. Our study can help predict vegetation regeneration potential to climate change environments depending on the ability of these species to disperse and maintain seed banks.

Science of the Total Environment↗
USGS2024

Effects of harmful algal blooms on amphibians and reptiles are under-reported and under-represented

Harmful algal blooms (HABs) are a persistent and increasing problem globally, yet we still have limited knowledge about how they affect wildlife. Although semi-aquatic and aquatic amphibians and reptiles have experienced large declines and occupy environments where HABs are increasingly problematic, their vulnerability to HABs remains unclear. To inform monitoring, management, and future research, we conducted a literature review, synthesized the studies, and report on the mortality events describing effects of cyanotoxins from HABs on freshwater herpetofauna. Our review identified 37 unique studies and 71 endpoints (no-observed-effect and lowest-observed-effect concentrations) involving 11 amphibian and 3 reptile species worldwide. Responses varied widely among studies, species, and exposure concentrations used in experiments. Concentrations causing lethal and sublethal effects in laboratory experiments were generally 1 to 100 µg/L, which contains the mean value of reported HAB events but is 70 times less than the maximum cyanotoxin concentrations reported in the environment. However, one species of amphibian was tolerant to concentrations of 10,000 µg/L, demonstrating potentially immense differences in sensitivities. Most studies focused on microcystin-LR (MC-LR), which can increase systemic inflammation and harm the digestive system, reproductive organs, liver, kidneys, and development. The few studies on other cyanotoxins illustrated that effects resembled those of MC-LR at similar concentrations, but more research is needed to describe effects of other cyanotoxins and mixtures of cyanotoxins that commonly occur in the environment. All experimental studies were on larval and adult amphibians; there were no such studies on reptiles. Experimental work with reptiles and adult amphibians is needed to clarify thresholds of tolerance. Only nine mortality events were reported, mostly for reptiles. Given that amphibians likely decay faster than reptiles, which have tissues that resist decomposition, mass amphibian mortality events from HABs have likely been under-reported. We propose that future efforts should be focused on seven major areas, to enhance our understanding of effects and monitoring of HABs on herpetofauna that fill important roles in freshwater and terrestrial environments. Environ Toxicol Chem 2024;00:1–14. Published 2024. This article is a U.S. Government work and is in the public domain in the USA. Environmental Toxicology and Chemistry published by Wiley Periodicals LLC on behalf of SETAC.

Environmental Toxicology and Chemistry↗
USGS2026

Structural evolution of iron coordination in proteins across Earth’s oxygenation history

Protein metal-binding sites support essential biological functions shaped by protein fold, subunit interactions, and cofactor chemistry. Because these sites encode both biochemical function and environmental constraint, they offer a route to connect protein evolution with changes in Earth’s surface environment through time. Of particular interest is iron (Fe), the most widely used metal in biology and a cofactor central to both anaerobic and aerobic metabolism. Here, we systematically compare the immediate chemical environments of functionally essential Fe-binding sites in three-dimensional protein structures to test whether Fe coordination spheres differ across oxygen contexts. Using a curated dataset of experimentally determined structures, we identify a clear shift in the local chemistry of Fe-binding environments from anaerobic to aerobic proteins. Aerobic Fe sites are significantly more hydrophilic than anaerobic ones, and amino-acid composition analyses show reduced cysteine use in aerobic Fe-binding neighborhoods. These patterns suggest that as Earth’s surface environments became more oxygenated, proteins retained Fe as a core redox metal while reconfiguring local coordination chemistry in ways less vulnerable to oxidative damage. More broadly, this study introduces and applies the Coordination Sphere Analysis and Comparison (CSAC) workflow, an open and archived Python workflow for extracting local metal-binding environments from structure datasets, providing a framework for linking metalloprotein structure to evolutionary and geobiological transitions across Earth history.

Discover Life↗
USGS2017

Status of correlation of Quaternary stratigraphic units in the western conterminous United States

Deposits of Quaternary age from the Rocky Mountains to the Pacific Coast in the western conterminous United States represent a great variety of environments. The deposits include those of continental and alpine glaciers, glacial meltwater streams, nonglacial streams, pluvial lakes, marine environments, eolian environments, and masswasting environments. On two charts we have attempted to correlate representative sequences of deposits of many of these environments, based on published sources and recent unpublished investigations. Evidence for correlation is based mainly on stratigraphic sequence, soil characteristics, the amount of subsequent erosion and interlayered volcanic ash beds identifiable as to source. Chronologic control is based on numerous radiocarbon dates, U-series dates on marine fossils, and K-Ar dates on volcanic rocks. The Bishop volcanic ash bed and one of the Pearlette-like volcanic ash beds appear to represent significant regional key horizons, respectively about 700,000 and 600,000 years old. Rock magnetism is shown to suggest the paleomagnetic polarity at the time of rock deposition. Assigned land-mammal ages of included fossils help to put limits on the age of some units.

Quaternary Research↗
USGS1991

Facies development in the Lower Freeport coal bed, west-central Pennsylvania, U.S.A.

The Lower Freeport coal bed in west-central Pennsylvania is interpreted to have formed within a lacustrine-mire environment. Conditions of peat formation, caused by the changing chemical and physical environments, produced five coal facies and two mineral-rich parting facies within the coal bed. The coal bed facies are compositionally unique, having developed under varying conditions, and are manifested by megascopic, petrographic, palynologic and quality characteristics. The initial environment of the Lower Freeport peat resulted in a coal facies that is relatively high in ash yield and contains large amounts of lycopod miospores and moderate abundances of cryptotelinite, crypto-gelocollinite, inertinite and tree fern miospores. This initial Lower Freeport peat is interpreted to have been a topogenous body that was low lying, relatively nutrient rich (mesotrophic to eutrophic), and susceptible to ground water and to sediment influx from surface water. The next facies to form was a ubiquitous, clay-rich durain parting which is attributed to a general rise in the water table accompanied by widespread flooding. Following formation of the parting, peat accumulation resumed within an environment that inhibited clastic input. Development of doming in this facies restricted deposition of the upper shale parting to the margins of the mire and allowed low-ash peat to form in the interior of the mire. Because this environment was conducive to preservation of cellular tissue, this coal facies also contains large amounts of crypto-telinite. This facies development is interpreted to have been a transitional phase from topogenous, planar peat formation to slightly domed, oligotrophic (nutrient-poor) peat formation. As domed peat formation continued, fluctuations in the water table enabled oxidation of the peat surface and produced high inertinite concentrations toward the top of the coal bed. Tree ferns became an increasingly important peat contributor in the e upper facies, based on the palynoflora. This floral change is interpreted to have resulted from the peat surface becoming less wet or better drained, a condition that inhibited proliferation of lycopod trees. Accumulation of the peat continued until rising water levels formed a freshwater lake within which clays and silts were deposited. The development of the Lower Freeport peat from a planar mire through transitional phases toward domed peat formation may be an example of the type of peat formation of other upper Middle and Upper Pennsylvanian coal beds.

International Journal of Coal Geology↗
USGS2007

Carbon isotopic compositions of organic matter across continental Cretaceous-Tertiary (K-T) boundary sections: Implications for paleoenvironment after the K-T impact event

To assess the environmental perturbation induced by the impact event that marks the Cretaceous-Tertiary (K-T) boundary, concentrations and isotopic compositions of bulk organic carbon were determined in sedimentary rocks that span the terrestrial K-T boundary at Dogie Creek, Montana, and Brownie Butte, Wyoming in the Western Interior of the United States. The boundary clays at both sites are not bounded by coals. Although coals consist mainly of organic matter derived from plant tissue, siliceous sedimentary rocks, such as shale and clay, may contain organic matter derived from microbiota as well as plants. Coals record ??13C values of plant-derived organic matter, reflecting the ??13C value of atmospheric CO2, whereas siliceous sedimentary rocks record the ??13C values of organic matter derived from plants and microbiota. The microbiota ??13C value reflects not only the ??13C value of atmospheric CO2, but also biological productivity. Therefore, the siliceous rocks from these sites yields information that differs from that obtained previously from coal beds. Across the freshwater K-T boundary at Brownie Butte, the ??13C values decrease by 2.6??? (from - 26.15??? below the boundary clay to - 28.78??? above the boundary clay), similar to the trend in carbonate at marine K-T sites. This means that the organic ??13C values reflect the variation of ??13C of atmospheric CO2, which is in equilibrium with carbon isotopes at the ocean surface. Although a decrease in ??13C values is observed across the K-T boundary at Dogie Creek (from - 25.32??? below the boundary clay to - 26.11??? above the boundary clay), the degree of ??13C-decrease at Dogie Creek is smaller than that at Brownie Butte and that for marine carbonate. About 2??? decrease in ??13C of atmospheric CO2 was expected from the ??13C variation of marine carbonate at the K-T boundary. This ??13C-decrease of atmospheric CO2 should affect the ??13C values of organic matter derived from plant tissue. As such a decrease in ??13C value was not observed at Dogie Creek, a process that compensates the ??13C-decrease of atmospheric CO2 should be involved. For example, the enhanced contribution of 13C-enriched organic matter derived from algae in a high-productivity environment could be responsible. The ??13C values of algal organic matter become higher than, and thus distinguishable from, those of plant organic matter in situations with high productivity, where dissolved HCO3- becomes an important carbon source, as well as dissolved CO2. As the ??13C-decrease of atmospheric CO2 reflected a reduction of marine productivity, the compensation of the ??13C decrease by the enhanced activity of the terrestrial microbiota means that the microbiota at freshwater environment recovered more rapidly than those in the marine environment. A distinct positive ??13C excursion of 2??? in the K-T boundary clays is superimposed on the overall decreasing trend at Dogie Creek; this coincides with an increase in the content of organic carbon. We conclude that the K-T boundary clays include 13C-enriched organic matter derived from highly productive algae. Such a high biological productivity was induced by phenomena resulting from the K-T impact, such as nitrogen fertilization and/or eutrophication induced by enhanced sulfide formation. The high productivity recorded in the K-T boundary clays means that the freshwater environments (in contrast to marine environments) recovered rapidly enough to almost immediately (within 10??yr) respond to the impact-related environmental perturbations. ?? 2006 Elsevier B.V. All rights reserved.

Earth and Planetary Science Letters↗
USGS2023

Triple oxygen isotope compositions of globally distributed soil carbonates record widespread evaporation of soil waters

The stable isotopic composition of pedogenic carbonates is central to many studies of past climate and topography, providing a basis for our understanding of Earth's terrestrial history. A core assumption of many applications of oxygen isotope values (δ18O) of pedogenic carbonate is that they reflect the δ18O value of precipitation (rain/snow). This assumption is violated if soil carbonates form in evaporated soil waters. In this work, we develop a means to identify evaporation in ancient soils using the triple oxygen isotope composition (16O-17O-18O) of pedogenic carbonates. Both theoretical predictions of isotope kinetics during evaporation and studies of triple oxygen isotopes in other geological materials show that the deviation in the relationship between δ17O and δ18O from a reference line, evaluated using the parameter Δ'17O, is sensitive to evaporation. As a first step in developing the use of Δ'17O in ancient pedogenic carbonates, we report Δ'17O values from 47 near-modern pedogenic carbonate samples from globally distributed environments that vary in aridity (hyper-arid to humid). The Δ'17O values of pedogenic carbonate range from -154 to -60 per meg (as CaCO3, measured via O2, VSMOW-SLAP), corresponding to calculated soil water values of -66 to +27 per meg (VSMOW-SLAP) (using a carbonate-water triple oxygen isotope fractionation exponent of 0.5250 and clumped isotope-derived carbonate growth temperatures). The Δ'17O values indicate that evaporative modification of soil water from which pedogenic carbonate forms is common, especially in arid environments. Arid environments host pedogenic carbonates formed from soil waters ranging from highly to minimally evaporated, while humid environments host pedogenic carbonates formed from waters that are only minimally evaporated. The variability in Δ'17O within environments classified by the same aridity may relate to the fact that pedogenic carbonates record soil conditions only during times of carbonate mineralization, which may deviate from annual conditions. Thus, Δ'17O may be useful in understanding the specific circumstances of pedogenic carbonate formation but may not provide incontrovertible evidence of the magnitude of environmental aridity. Evaporative modification of δ18O values of pedogenic carbonates can be detected with Δ'17O, thereby improving estimates of δ18O of unevaporated waters. Our data show that evaporation must be (re)considered for all paleoclimate inferences based on the δ18O of pedogenic carbonate. The addition of Δ'17O will re-energize paleoclimate studies that use (or have avoided using) δ18O of pedogenic carbonate.

Geochimica et Cosmochimica Acta↗
USGS2019

Tectono-magmatic evolution of porphyry belts in the central Tethys region of Turkey, the Caucasus, Iran, western Pakistan, and southern Afghanistan

Exploration in the central Tethys region of Turkey, Armenia, Azerbaijan, Georgia, Iran, and weste rn Pakistan has led to the identification of the giant Reko Diq (24 Mt Cu and 1300 t Au), Sar Cheshmeh (8.9 Mt Cu and 0.46 Mt Mo), Sungun (5.1 Mt Cu and 0.20 Mt Mo), and Kadjaran (4.6 Mt Cu, 0.94 Mt Mo, and 1100 t Au), and 10 other large (1–2 Mt Cu) porphyry deposits including Saindak, Cevizlidere, Teghout, Meiduk, and Halilağa. Continued exploration efforts have also resulted in the development of porphyry-related gold deposits such as Kişladağ (9.6 Moz Au), Çöpler (3.7 Moz Au), Aği Daği (1.7 Moz Au), and Sary Gunay (3.0 Moz Au), and in the generation of several other promising exploration projects. The distribution in space and time of porphyry deposits in the central Tethys region was shaped by complex pre- to post-mineral tectonic, igneous, collisional, uplift and burial events. These events are represented by a partially-overlapping and variably exhumed and covered collage of twenty-six Early Jurassic to Holocene magmatic belts permissive for the occurrence of porphyry deposits (porphyry tracts and sub-tracts). Twelve tracts or sub-tracts are characterized by compressional continental arcs that formed on drifting terranes or continental margins, 10 developed in compressional to extensional intra-oceanic arc and backarc-rift settings, and 4 formed in extensional post-collisional environments over amalgamated terranes. Eight of these belts were variably affected by coeval and younger metamorphic, fold-and-thrust, and extensional faulting events. Fifty-four porphyry Au-(Cu), Cu-Au, Cu-Mo, Mo-Cu deposits, 15 porphyry-related Au, Au-(Mo) and W-(Mo-Au) deposits, 239 porphyry prospects, and 68 other porphyry-related mineral sites were identified in the study region. Of the 376 porphyry and porphyry-related sites, about 11% formed in island arc, 42% in continental arc, 20% in backarc, and 27% in post-collisional settings. Of the 69 porphyry and porphyry-related deposits, 7% developed in intra-oceanic arc, 41% in continental arc, 27% in backarc, and 25% in post-collisional settings. The largest occur in either compressional continental arc (18 deposits including the Reko Diq and Sar Cheshmeh giants) or post-collisional (13 deposits including the Kadjaran and Sungun giants) environments. Ninety percent of the largest porphyry or porphyry-related deposits occur in only 9 of the 26 permissive porphyry tracts or sub-tracts. Moreover, 88, 90, and 77% of the identified Cu, Mo, and Au resources are contained in porphyry deposits that occur in only 4 of these 9 tracts. Of these 4 tracts, 3 outline arc settings, and one delimits a post-collisional environment. The compositional diversity of porphyry intrusions in these tectono-magmatic environments generally varies from island arc settings with the most restricted range (partly alkaline but mainly calc-alkaline dioritic to granodioritic-tonalitic), to continental arc (calc-alkaline dioritic-quartz dioritic, granodioritic, quartz monzonitic-granitic, and less commonly mildly alkaline), to backarc (mildly alkaline and calc-alkaline dioritic to granitic), to post-collisional settings with the most expansive range (alkaline and calc-alkaline mafic to felsic, and weakly peraluminous). Metal associations also vary broadly as a function of porphyry intrusion composition from weakly peraluminous to metaluminous felsic (Mo[±W ± Cu]; <2% of porphyry-related systems [i.e., Tyrnyauz]), to metaluminous felsic and intermediate (Cu-Mo[±Au]; 85% [i.e., Cevizlidere, Haft Cheshmeh, Kahang, Sar Cheshmeh, Sungun, Teghout, Reko Diq, Saindak]), to mildly alkaline felsic and intermediate (Cu-Au[±Mo] [i.e., Agarak, Kadjaran, Kale Kafi]) and mafic (Au-Cu; 12% [i.e., Çöpler]), and to alkaline felsic (Au-Mo; 1% of porphyry-related systems [i.e., Kişladağ). Tectonic changes were critical in triggering the formation of large porphyry deposits in the region. Large porphyry deposits were preferentially emplaced in continental arc settings shortly before major collisional events (Dar Alu, Kahang, Meiduk, Now Chun, and the giant Sar Cheshmeh and Reko Diq deposits), or in post-subduction environments shortly after collision (Bakirçay, Güzelyayla, Haft Cheshmeh, Masjed Daghi, and the giant Kadjaran and Sungun deposits) or during periods of prominent extension (Aği Daği, Halilağa, Kişladağ, Sari Gunay, and Zarshuran porphyry-related deposits). Collision-induced uplift, erosion, and removal of coeval volcanic rocks favorably exposed the hypabyssal level of subduction-related porphyry deposits. Extensional structures that developed parallel and orthogonal to the compressional principal stress component along transtensional or transpressional strike-slip faults or in pull-apart basins commonly controlled porphyry-related deposits in post-collisional settings. The latter deposits typically exhibit shallow epithermal levels of emplacement because of preservation by burial. Seventeen porphyry deposits and one porphyry-related deposit in the study region are reported to contain significant supergene resources. Relatively mature levels of secondary copper enrichment in dominantly granodioritic to granitic porphyry deposits occur in areas where large pyrite-rich quartz-sericite alteration zones have been preserved and exposed to surface oxidation (Güzelyayla and Ulutaş in northeastern Turkey; Agarak, Ankavan, Dastakert, Kadjaran, and Teghout in Armenia; Ali Javad in northern Iran; Kale Kafi in central Iran; Darreh Zar, Meiduk, Now Chun, and Sar Cheshmeh in southeastern Iran; and Tanjeel in southwestern Pakistan). Chalcocite blankets also developed over porphyry deposits in regions where significant post-mineral faulting has occurred (Muratdere and Sarıçayıryayla in western Turkey). Normal faulting also enhanced secondary enrichment of gold in the Halilağa porphyry and Sary Gunay porphyry-related deposits located respectively in western Turkey and northern Iran. Evaluation of provincial as well as local controls strongly suggests that continued exploration in the region will lead to the identification of additional porphyry and porphyry-related deposits. These deposits will likely be found under younger cover formations in porphyry belts that are already known, and in association with superjacent high- and intermediate-sulfidation epithermal deposits, or increasingly peripheral skarn, carbonate-replacement, and sediment-hosted deposits. Application of suitable exploration techniques to detect concealed and/or deformed deposits in porphyry belts that remain under-explored may also prove productive.

Tethys region↗
USGS2004

Probabilistic seismic hazard analysis for Sumatra, Indonesia and across the Southern Malaysian Peninsula

The ground motion hazard for Sumatra and the Malaysian peninsula is calculated in a probabilistic framework, using procedures developed for the US National Seismic Hazard Maps. We constructed regional earthquake source models and used standard published and modified attenuation equations to calculate peak ground acceleration at 2% and 10% probability of exceedance in 50 years for rock site conditions. We developed or modified earthquake catalogs and declustered these catalogs to include only independent earthquakes. The resulting catalogs were used to define four source zones that characterize earthquakes in four tectonic environments: subduction zone interface earthquakes, subduction zone deep intraslab earthquakes, strike-slip transform earthquakes, and intraplate earthquakes. The recurrence rates and sizes of historical earthquakes on known faults and across zones were also determined from this modified catalog. In addition to the source zones, our seismic source model considers two major faults that are known historically to generate large earthquakes: the Sumatran subduction zone and the Sumatran transform fault. Several published studies were used to describe earthquakes along these faults during historical and pre-historical time, as well as to identify segmentation models of faults. Peak horizontal ground accelerations were calculated using ground motion prediction relations that were developed from seismic data obtained from the crustal interplate environment, crustal intraplate environment, along the subduction zone interface, and from deep intraslab earthquakes. Most of these relations, however, have not been developed for large distances that are needed for calculating the hazard across the Malaysian peninsula, and none were developed for earthquake ground motions generated in an interplate tectonic environment that are propagated into an intraplate tectonic environment. For the interplate and intraplate crustal earthquakes, we have applied ground-motion prediction relations that are consistent with California (interplate) and India (intraplate) strong motion data that we collected for distances beyond 200 km. For the subduction zone equations, we recognized that the published relationships at large distances were not consistent with global earthquake data that we collected and modified the relations to be compatible with the global subduction zone ground motions. In this analysis, we have used alternative source and attenuation models and weighted them to account for our uncertainty in which model is most appropriate for Sumatra or for the Malaysian peninsula. The resulting peak horizontal ground accelerations for 2% probability of exceedance in 50 years range from over 100% g to about 10% g across Sumatra and generally less than 20% g across most of the Malaysian peninsula. The ground motions at 10% probability of exceedance in 50 years are typically about 60% of the ground motions derived for a hazard level at 2% probability of exceedance in 50 years. The largest contributors to hazard are from the Sumatran faults.

Tectonophysics↗
USGS2019

Local niche differences predict genotype associations in sister taxa of desert tortoise

Aims To investigate spatial congruence between ecological niches and genotype in two allopatric species of desert tortoise that are species of conservation concern. Location Mojave and Sonoran Desert ecoregions; California, Nevada, Arizona, Utah, USA. Methods We compare ecological niches of Gopherus agassizii and Gopherus morafkai using species distribution modelling (SDM) and then calibrate a pooled‐taxa distribution model to explore local differences in species–environment relationships based on the spatial residuals of the pooled‐taxa model. We use multiscale geographically weighted regression (MGWR) applied to those residuals to estimate local species–environment relationships that can vary across the landscape. We identify multivariate clusters in these local species–environment relationships and compare them against models of (a) a geographically based taxonomic designation for two sister species and (b) an environmental ecoregion designation, with respect to their ability to predict a genotype association index for these two species. Results We find non‐identical niches for these species, with differences that span physiographic and vegetation niche dimensions. We find evidence for two distinct clusters of local species–environment relationships that when mapped, predict an index of genotype association for the two sister taxa better than did either the geographically based taxonomic designation or an environmental ecoregion designation. Main conclusions Exploring local species–environment relationships by coupling SDM and MGWR can benefit studies of biogeography and conservation. We find that niche separation in habitat selection conforms to genotypic differences between sister taxa of tortoise in a recent secondary contact zone. This result may inform decision making by agencies with regulatory or land management authority for the two sister taxa addressed here.

Arizona, California, Nevada, Utah↗
USGS2022

Defining an epidemiological landscape that connects movement ecology to pathogen transmission and pace-of-life

Pathogen transmission depends on host density, mobility and contact. These components emerge from host and pathogen movements that themselves arise through interactions with the surrounding environment. The environment, the emergent host and pathogen movements, and the subsequent patterns of density, mobility and contact form an ‘epidemiological landscape’ connecting the environment to specific locations where transmissions occur. Conventionally, the epidemiological landscape has been described in terms of the geographical coordinates where hosts or pathogens are located. We advocate for an alternative approach that relates those locations to attributes of the local environment. Environmental descriptions can strengthen epidemiological forecasts by allowing for predictions even when local geographical data are not available. Environmental predictions are more accessible than ever thanks to new tools from movement ecology, and we introduce a ‘movement-pathogen pace of life’ heuristic to help identify aspects of movement that have the most influence on spatial epidemiology. By linking pathogen transmission directly to the environment, the epidemiological landscape offers an efficient path for using environmental information to inform models describing when and where transmission will occur.

Ecology Letters↗
USGS2006

Evolution of a trench-slope basin within the Cascadia subduction margin: The Neogene Humboldt Basin, California

The Neogene Humboldt (Eel River) Basin is located along the north-eastern margin of the Pacific Ocean within the Cascadia subduction zone. This sedimentary basin originated near the base of the accretionary prism in post-Eocene time. Subduction processes since that time have elevated strata in the south-eastern portion of the basin above sea level. High-resolution chronostratigraphic data from the onshore portion of the Humboldt Basin enable correlation of time-equivalent lithofacies across the palaeomargin, reconstruction of slope-basin evolution, and preliminary delineation of climatic and tectonic influence on lithological variation. Emergent basin fill is divided into five lithofacies which clearly document shoaling of the inner trench slope from deep-water environments in early Miocene time to paralic environments in Pleistocene time. The oldest strata consist of hemipelagic mudstones and minor debris-flow breccias deposited in a deep-water setting during elevated sea level. These strata are overlain by glauconite-rich, fine-grained turbidites which heralded an increasing influx of terrigenous detritus. Water depths shoaled earlier in the eastern basin area as the palaeoshoreline prograded seaward. Turbidite deposition ceased in the eastern basin area at about 2-2 Ma, whereas 22 km to the west, turbidite deposition continued until about 1-8 Ma. Lithofacies at the western study site change abruptly across a middle Pleistocene unconformity from outer shelf to paralic deposits. In the east, a more complete Pleistocene section records transition from outer to inner shelf, beach and fluvial environments. The Humboldt Basin lithofacies sequence is overprinted by eustatic control of sediment source. Comparison of sediment character with palaeoceanographic conditions indicates dominance of hemipelagic facies during periods of elevated sea level in the middle Miocene and early Pliocene when depocentres were isolated from terrigenous sediment. Glauconite-rich facies were mobilized from an upper slope setting following these periods of elevated sea level and redeposited in a deep-marine environment. Pleistocene shoreline lithofacies display glacio-esutatic control of depositional environment by recording several cycles of nearshore to fluvial progressions. General models of accretionary prism behaviour and trench-slope basin evolution are compatible with the overall coarsening-upward lithofacies sequence filling the Humboldt Basin. Early structural barriers precluded deposition of terrigenous material except from locally derived debris flows; subsequent shoaling and burial of deactivated thrust-folds enabled turbidity flows to reach the basin floor. However, late-stage tectonism apparently controlled the onset of coarse-grained deposition in this sequence. Significant sand-rich turbidite deposition began in the middle Pliocene, synchronous with tectonic uplift of the southern basin margin. Conversely, cessation of turbidite deposition in the eastern basin area in latest Pliocene time was synchronous with growth of anticlinal structures which again blocked widespread dispersal of turbidity flows. This middle Pliocene to Holocene period of crustal shortening is synchronous with continued reduction in spreading rate along the southern Juan de Fuca ridge, and probably reflects partial coupling between the subducting lithosphere and the overlying accretionary prism.

California↗