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At least 919 records · Page 51Linked to original sources

USGS2015

Frac sand in the United States: a geological and industry overview

A new mineral rush is underway in the upper Midwest of the United States, especially in Wisconsin and Minnesota, for deposits of high-quality frac sand that the mining industry calls “Northern White” sand or “Ottawa” sand. Frac sand is a specialized type of sand that is added to fracking fluids that are injected into unconventional oil and gas wells during hydraulic fracturing (fracking or hydrofracking), a process that enhances petroleum extraction from tight (low permeability) reservoirs. Frac sand consists of natural sand grains with strict mineralogical and textural specifications that act as a proppant (keeping induced fractures open), extending the time of release and the flow rate of hydrocarbons from fractured rock surfaces in contact with the wellbore. The current sand mining surge has been driven by the boom in unconventional oil and gas production that has been largely spurred by advancements in technology promoting the expansion of hydraulic fracturing and horizontal drilling over the past decade. Because of its superior quality, the sand of the upper Midwest not only supports the majority of domestic oil and gas production, but it also supplies frac sand to some of Canada’s western shale basins. The principal sources of “Northern White” or “Ottawa” sand in the upper Midwest are the Middle and Upper Ordovician St. Peter Sandstone and the Lower Ordovician and Upper Cambrian Jordan Formation, with the Upper Cambrian Wonewoc and Mount Simon Formations gaining in importance. Additional frac sand sources to the south include the Upper Cambrian Hickory Sandstone Member of the Riley Formation in Texas, which is referred to informally as “Brown” or “Brady” sand, and the Middle Ordovician Oil Creek Formation in Oklahoma. More than 40 United States industry operators are involved in the mining, processing, transportation, and distribution of frac sand to a robust market that is fast-growing in the United States and throughout the world. In addition to the abrupt rise in frac sand mining and distribution, a new industry has emerged from the production of alternative proppants, such as coated sand and synthetic beads. Alternative proppants, developed through new technologies, are competing with supplies of natural frac sand. In the long term, the vitality of both industries will be tied to the future of hydraulic fracturing of tight oil and gas reservoirs, which will be driven by the anticipated increases in global energy consumption.

Open-File Report↗

USGS2010

Fate and transport of petroleum hydrocarbons in the subsurface near Cass Lake, Minnesota

The U.S. Geological Survey (USGS) investigated the natural attenuation of subsurface petroleum hydrocarbons leaked over an unknown number of years from an oil pipeline under the Enbridge Energy Limited Partnership South Cass Lake Pumping Station, in Cass Lake, Minnesota. Three weeks of field work conducted between May 2007 and July 2008 delineated a dissolved plume of aromatic hydrocarbons and characterized the biodegradation processes of the petroleum. Field activities included installing monitoring wells, collecting sediment cores, sampling water from wells, and measuring water-table elevations. Geochemical measurements included concentrations of constituents in both spilled and pipeline oil, dissolved alkylbenzenes and redox constituents, sediment bioavailable iron, and aquifer microbial populations. Groundwater in this area flows east-southeast at approximately 26 meters per year. Results from the oil analyses indicate a high degree of biodegradation, characterized by nearly complete absence of n-alkanes. Cass Lake oil samples were more degraded than two oil samples collected in 2008 from the similarly contaminated USGS Bemidji, Minnesota, research site 40 kilometers away. Based on 19 ratios developed for comparing oil sources, the conclusion is that the oils at the two sites appear to be from the same hydrocarbon source. In the Cass Lake groundwater plume, benzene concentrations decrease by three orders of magnitude within 150 meters (m) downgradient from the oil body floating on the water table (between well MW-10 and USGS-4 well nest). The depths of the highest benzene concentrations increase with distance downgradient from the oil, a condition typical of plumes in shallow, unconfined aquifers. Background groundwater, which is nearly saturated with oxygen, becomes almost entirely anaerobic in the plume. As at the Bemidji site, the most important biodegradation processes are anaerobic and dominated by iron reduction. The similarity between the Cass Lake and Bemidji benzene degradation rates, redox conditions, and aquifer material all support a hypothesis that the Cass Lake plume, like the Bemidji plume, is decades old. As concentrations of alkylbenzenes in the oil decrease over time, the benzene concentrations in the groundwater plume will also decrease and the plume is expected to shrink. The Fox Creek wetland, about 250 m south of the Cass Lake site, is the nearest receptor to the south.

Scientific Investigations Report↗

USGS2022

Advancing geophysical techniques to image a stratigraphic hydrothermal resource

Sedimentary-hosted geothermal energy systems are permeable structural, structural-stratigraphic, and/or stratigraphic horizons with sufficient temperature for direct use and/or electricity generation. Sedimentary-hosted (i.e., stratigraphic) geothermal reservoirs may be present in multiple locations across the central and eastern Great Basin of the USA, thereby constituting a potentially large base of untapped, economically accessible energy resources. Sandia National Laboratories has partnered with a multi-disciplinary group of collaborators to evaluate a stratigraphic system in Steptoe Valley, Nevada using both established and novel geophysical imaging techniques. The goal of this study is to inform an optimized strategy for subsequent exploration and development of this and analogous resources. Building from prior Nevada Play Fairway Analysis (PFA), this team is primarily 1) collecting additional geophysical data, 2) employing novel joint geophysical inversion/modeling techniques to update existing 3D geologic models, and 3) integrating the geophysical results to produce a working, geologically constrained thermo-hydrological reservoir model. Prior PFA work highlights Steptoe Valley as a favorable resource basin that likely has both sedimentary and hydrothermal characteristics. However, there remains significant uncertainty on the nature and architecture of the resource(s) at depth, which increases the risk in exploratory drilling. Newly acquired gravity, magnetic, magnetotelluric, and controlled-source electromagnetic data, in conjunction with new and preceding geoscientific measurements and observations, are being integrated and evaluated in this study for efficacy in understanding stratigraphic geothermal resources and mitigating exploration risk. Furthermore, the influence of hydrothermal activity on sedimentary-hosted reservoirs in favorable structural settings (i.e., whether fault-controlled systems may locally enhance temperature and permeability in some deep stratigraphic reservoirs) will also be evaluated. This paper provides details and current updates on the course of this study in-progress.

Geothermal Resources Council Transactions↗

USGS2024

Phosphates in some Missouri refractory clays

This paper describes in detail phosphate minerals occurring in refractory clays of Missouri and their effect on the refractory degree of the clays. The minerals identified include carbonate-fluorapatite (francolite), crandallite, goyazite, wavellite, variscite and strengite. It is emphasized that these phosphates occur only in local isolated concentrations, and not generally in Missouri refractory clays. The Missouri fireclay region comprises 2 districts, northern and southern, separated by the Missouri River. In this region, clay constitutes a major part of the Lower Pennsylvanian Cheltenham Formation. The original Cheltenham mud was an argillic residue derived from leaching and dissolution of pre-Pennsylvanian carbonates. The mud accumulated on a karstic erosion surface truncating the pre-Cheltenham rocks. Fireclays of the northern district consist mainly of poorly ordered kaolinite, with variable but minor amounts of illite, chlorite and fine-grained detrital quartz. Clays of the southern district were subjected to extreme leaching that produced well-ordered kaolinite flint clays. Local desilication formed pockets of diaspore, or more commonly, kaolinite, with oolite-like nubs or burls of diaspore (“burley”" clay). The phosphate-bearing materials have been studied by X-ray diffraction (XRD), scanning electron microscopy-energy dispersive spectral analysis (SEM-EDS) and chemical analysis. Calcian goyazite was identified in a sample of diaspore, and francolite in a sample of flint clay. A veinlet of wavellite occurs in flint clay at one locality, and a veinlet of variscite-strengite at another locality. The Missouri flint-clay-hosted francolite could not have formed in the same manner as marine francolite. The evidence suggests that the Cheltenham francolite precipitated from ion complexes in pore water, nearly simultaneously with crystallization of kaolinite flint clay from an alumina-silica gel. Calcian goyazite is an early diagenetic addition to its diaspore host. The wavellite and variscite-strengite veinlets are secondary, precipitated from ion complexes in ground water percolating along cracks in the flint clay. The flint clay host of the variscite-strengite veinlet contains strontian crandallite. All of the phosphates contain significant amounts of strontium. The source of P, Ca and Sr was the marine carbonates. Dissolution of these carbonates produced the argillic residue that became the primordial Cheltenham paludal mud, which ultimately altered to fireclay. Preliminary firing tests show that the presence of phosphates lowers fusion temperature. However, it is not clear whether poor refractoriness is due to the presence of phosphates, per se, or to Ca, Sr and other alkaline elements present in the phosphates.

Clays and Clay Minerals↗

USGS1984

Map showing outcrops of granitic rocks, Basin and Range Province, Nevada

This map report is one of a series of geologic and hydrologic maps covering all or parts of States within the Basin and Range province of the western United States. The map reports contain information on subjects that characterize the geohydrology of the province, including the ground-water hydrology, ground-water quality, surface distribution of selected rock types, tectonic conditions, areal geophysics, Pleistocene lakes and marshes, and mineral and energy resources. This work is a part of the U.S. Geological Survey's program for geologic and hydrologic evaluation of the Basin and Range province to identify potentially suitable regions for further study relative to isolation of high-level nuclear waste (Bedinger, Sargent, and Reed, 1984). Data for this report were taken largely from Spengler and others (1979), supplemented by data from individual geologic maps and reports, following the project guidelines as defined in Sargent and Bedinger (1984). As used in this report, granitic rocks include granodiorite, quartz monzonite, and granite, and locally associated mafic rocks such as diorite and gabbro. In the Snake Range and Ruby Mountains, Stewart (1980) has recognized large areas as metamorphic core complexes, and in these complexes some plutonic masses may not extend to great depth because of lateral displacement along low-angle faults subsequent to intrusion. The Description of Map Units includes the sources of data, the geologic, and if available, the radiometric age, lithologic character, type of intrusive body and relation to rock units, where known, for the granitic rocks within outlined and numbered areas in each county of the study area. The radiometric ages of the rock units are only those which are available and do not necessarily represent the entire age range of the geologic units.

Nevada↗

USGS2006

The allometric relationship between resting metabolic rate and body mass in wild waterfowl (Anatidae) and an application to estimation of winter habitat requirements

We examined the allometric relationship between resting metabolic rate (RMR; kJ day-1) and body mass (kg) in wild waterfowl (Anatidae) by regressing RMR on body mass using species means from data obtained from published literature (18 sources, 54 measurements, 24 species; all data from captive birds). There was no significant difference among measurements from the rest (night; n = 37), active (day; n = 14), and unspecified (n = 3) phases of the daily cycle (P > 0.10), and we pooled these measurements for analysis. The resulting power function (aMassb) for all waterfowl (swans, geese, and ducks) had an exponent (b; slope of the regression) of 0.74, indistinguishable from that determined with commonly used general equations for nonpasserine birds (0.72-0.73). In contrast, the mass proportionality coefficient (b; y-intercept at mass = 1 kg) of 422 exceeded that obtained from the nonpasserine equations by 29%-37%. Analyses using independent contrasts correcting for phylogeny did not substantially alter the equation. Our results suggest the waterfowl equation provides a more appropriate estimate of RMR for bioenergetics analyses of waterfowl than do the general nonpasserine equations. When adjusted with a multiple to account for energy costs of free living, the waterfowl equation better estimates daily energy expenditure. Using this equation, we estimated that the extent of wetland habitat required to support wintering waterfowl populations could be 37%-50% higher than previously predicted using general nonpasserine equations. ?? The Cooper Ornithological Society 2006.

Condor↗

USGS2025

Relative abundance, seasonal occurrence, and distribution of marine birds in the northern Gulf of Mexico

Marine birds in the U.S. Gulf of Mexico have long been poorly studied. Given statutory obligations to protect migratory birds and endangered species, three broad-scale vessel and aerial programs initiated since 2010 have now surveyed the entire northern Gulf. Vessel coverage alone exceeds 700 d and 74,000 km of observer effort using 300-m strip transects. We supplemented these survey data with earlier, smaller-scale studies, eBird checklists, literature reviews, and other less accessible sources to create snapshot summaries of relative abundance, seasonal occurrence, and regional distribution for 117 taxa of marine and water birds reported from the northern Gulf (113 of which were substantiated with physical evidence). Using taxonomic and functional criteria, we identified 56 taxa characteristic of open shelf, slope, and pelagic waters (federal jurisdiction), 41 taxa with primarily coastal affinities (state and federal jurisdiction), and 20 taxa of sea and diving ducks. High species richness of marine birds in the northern Gulf is attributed to (1) a temperate-to-tropical gradient facilitating diverse marine environments year-round; (2) varied geographic origins of marine bird species using the Gulf; and (3) a mostly enclosed sea basin acting as a vagrant trap for wide-ranging species. Our taxonomic list and status updates seek to bridge information gaps for marine birds now subject to accelerated commercial uses of this region's continental shelf, including newly proposed offshore wind energy development. Other applications include guiding risk and vulnerability assessments of Gulf marine birds, providing core content for seabird observer training, and prioritizing environmental impact reviews and monitoring programs in offshore energy construction and operations plans.

Marine Ornithology: Journal of Seabird Research an↗

USGS1996

Quantitative investigations of the Missouri gravity low: A possible expression of a large, Late Precambrian batholith intersecting the New Madrid seismic zone

Analysis of gravity and magnetic anomaly data helps characterize the geometry and physical properties of the source of the Missouri gravity low, an important cratonic feature of substantial width (about 125 km) and length (> 600 km). Filtered anomaly maps show that this prominent feature extends NW from the Reelfoot rift to the Midcontinent Rift System. Geologic reasoning and the simultaneous inversion of the gravity and magnetic data lead to an interpretation that the gravity anomaly reflects an upper crustal, 11-km-thick batholith with either near vertical or outward dipping boundaries. Considering the modeled characteristics of the batholith, structural fabric of Missouri, and relations of the batholith with plutons and regions of alteration, a tectonic model for the formation of the batholith is proposed. The model includes a mantle plume that heated the crust during Late Precambrian and melted portions of lower and middle crust, from which the low-density granitic rocks forming the batholith were partly derived. The batholith, called the Missouri batholith, may be currently related to the release of seismic energy in the New Madrid seismic zone (earthquake concentrations occur at the intersection of the Missouri batholith and the New Madrid seismic zone). Three qualitative mechanical models are suggested to explain this relationship with seismicity. Copyright 1996 by the American Geophysical Union.

Journal of Geophysical Research B: Solid Earth↗

USGS2012

Hydrological information products for the Off-Project Water Program of the Klamath Basin Restoration Agreement

The Klamath Basin Restoration Agreement (KBRA) was developed by a diverse group of stakeholders, Federal and State resource management agencies, Tribal representatives, and interest groups to provide a comprehensive solution to ecological and water-supply issues in the Klamath Basin. The Off-Project Water Program (OPWP), one component of the KBRA, has as one of its purposes to permanently provide an additional 30,000 acre-feet of water per year on an average annual basis to Upper Klamath Lake through "voluntary retirement of water rights or water uses or other means as agreed to by the Klamath Tribes, to improve fisheries habitat and also provide for stability of irrigation water deliveries." The geographic area where the water rights could be retired encompasses approximately 1,900 square miles. The OPWP area is defined as including the Sprague River drainage, the Sycan River drainage downstream of Sycan Marsh, the Wood River drainage, and the Williamson River drainage from Kirk Reef at the southern end of Klamath Marsh downstream to the confluence with the Sprague River. Extensive, broad, flat, poorly drained uplands, valleys, and wetlands characterize much of the study area. Irrigation is almost entirely used for pasture. To assist parties involved with decisionmaking and implementation of the OPWP, the U.S. Geological Survey (USGS), in cooperation with the Klamath Tribes and other stakeholders, created five hydrological information products. These products include GIS digital maps and datasets containing spatial information on evapotranspiration, subirrigation indicators, water rights, subbasin streamflow statistics, and return-flow indicators. The evapotranspiration (ET) datasets were created under contract for this study by Evapotranspiration, Plus, LLC, of Twin Falls, Idaho. A high-resolution remote sensing technique known as Mapping Evapotranspiration at High Resolution and Internalized Calibration (METRIC) was used to create estimates of the spatial distribution of ET. The METRIC technique uses thermal infrared Landsat imagery to quantify actual evapotranspiration at a 30-meter resolution that can be related to individual irrigated fields. Because evaporation uses heat energy, ground surfaces with large ET rates are left cooler as a result of ET than ground surfaces that have less ET. As a consequence, irrigated fields appear in the Landsat images as cooler than nonirrigated fields. Products produced from this study include total seasonal and total monthly (April-October) actual evapotranspiration maps for 2004 (a dry year) and 2006 (a wet year). Maps showing indicators of natural subirrigation were also provided by this study. "Subirrigation" as used here is the evapotranspiration of shallow groundwater by plants with roots that penetrate to or near the water table. Subirrigation often occurs at locations where the water table is at or above the plant rooting depth. Natural consumptive use by plants diminishes the benefit of retiring water rights in subirrigated areas. Some agricultural production may be possible, however, on subirrigated lands for which water rights are retired. Because of the difficulty in precisely mapping and quantifying subirrigation, this study presents several sources of spatially mapped data that can be used as indicators of higher subirrigation probability. These include the floodplain boundaries defined by stream geomorphology, water-table depth defined in Natural Resources Conservation Service (NRCS) soil surveys, and soil rooting depth defined in NRCS soil surveys. The two water-rights mapping products created in the study were "points of diversion" (POD) and "place of use" (POU) for surface-water irrigation rights. To create these maps, all surface-water rights data, decrees, certificates, permits, and unadjudicated claims within the entire 1,900 square mile study area were aggregated into a common GIS geodatabase. Surface-water irrigation rights within a 5-mile buffer of the study area were then selected and identified. The POU area was then totaled by water right for primary and supplemental water rights. The maximum annual volume (acre-feet) allowed under each water right also was calculated using the POU area and duty (allowable annual irrigation application in feet). In cases where a water right has more than one designated POD, the total volume for the water right was equally distributed to each POD listed for the water right. Because of this, mapped distribution of diversion rates for some rights may differ from actual practice. Water-right information in the map products was from digital datasets obtained from the Oregon Water Resources Department and was, at the time acquired, the best available compilation of water-right information available. Because the completeness and accuracy of the water-right data could not be verified, users are encouraged to check directly with the Oregon Water Resources Department where specific information on individual rights or locations is essential. A dataset containing streamflow statistics for 72 subbasins in the study area was created for the study area. The statistics include annual flow durations (5-, 10-, 25-, 50-, and 95-percent exceedances) and 7-day, 10-year (7Q10) and 7-day, 2-year (7Q2) low flows, and were computed using regional regression equations based on measured streamflow records in the region. Daily streamflow records used were adjusted as needed for crop consumptive use; therefore the statistics represent streamflow under more natural conditions as though irrigation diversions did not exist. Statistics are provided for flow rates resulting from streamflow originating from within the entire drainage area upstream of the subbasin pour point (referring to the outlet of the contributing drainage basin). The statistics were computed for the purpose of providing decision makers with the ability to estimate streamflow that would be expected after water conservation techniques have been implemented or a water right has been retired. A final product from the study are datasets of indicators of the potential for subsurface return flow of irrigation water from agricultural areas to nearby streams. The datasets contain information on factors such as proximity to surface-water features, geomorphic floodplain characteristics, and depth to water. The digital data, metadata, and example illustrations for the datasets described in this report are available on-line from the USGS Water Resources National Spatial Data Infrastructure (NSDI) Node Website http://water.usgs.gov/lookup/getgislist or from the U.S. Government website DATA.gov at http://www.data.gov with links provided in a Microsoft® Excel® workbook in appendix A.

California;Oregon↗

USGS1996

Evapotranspiration from successional vegetation in a deforested area of the Lake Wales Ridge, Florida

The suitability of three evapotranspiration models (Penman-Monteith, Penman, and a modified Priestley-Taylor) was evaluated at a site of successional vegetation in a deforested area of the Lake Wales Ridge, Florida. Eddy correlation measurements of evapotranspiration made during 22 approximately 1-day periods at a temporal resolution of 20 minutes from September 1993 to August 1994 were used to calibrate the evapotranspiration models. Three variants of the eddy correlation method that ascribe measurement error to three different sources were considered in the analysis. The Penman-Monteith and modified Priestley- Taylor models were successful in approximating measured 20-minute values of evapotranspiration (r 2 ≥0.918). The most successful approaches were the modified Priestley-Taylor model (r 2 =0.972) and a nontraditional and simplified form of the Penman-Monteith model (r 2 =0.967). The Penman approach was unsuccessful as a predictor of evapotranspiration. The evapotranspiration models were used to estimate evapotranspiration between measurements. When evapotranspiration values measured with a Bowen ratio variant of the eddy correlation method were used for model calibration, estimated daily evapotranspiration rates varied seasonally ranging from 0.2 millimeters per day (0.008 inch per day) in late December 1993 to 5 millimeter per day (0.2 inch per day) in mid-July 1994. Annual evapotranspiration (September 15, 1993, to September 15, 1994) was estimated to be about 680 millimeters (27 inches). Evapotranspiration models calibrated to the standard eddy correlation method and to an energy-balance residual variant provided estimates of annual evapotranspiration that were about 10 per cent lower and higher, respectively. These data indicate that of the 1,320 millimeters (52 inches) of precipitation during the 1-year period, about 570 to 700 millimeters (22 to 28 inches) recharged the surficial aquifer. Evapotranspiration at this study site probably defines the lower limit of evapotranspiration from vegetated surfaces in central Florida because of the shallow-rooted plants, rapidly-drained soils, and relatively deepwater table.

Florida↗

USGS2022

Tracking heat in the Willamette River system, Oregon

The Willamette River Basin in northwestern Oregon is home to several cold-water fish species whose habitat has been altered by the Willamette Valley Project, a system of 13 dams and reservoirs operated by the U.S. Army Corps of Engineers. Water-resource managers use a variety of flow- and temperature-management strategies to ameliorate the effects of upstream Willamette Valley Project dams on the habitat and viability of these anadromous and native fish. In this study, new capabilities were added to the CE-QUAL-W2 two-dimensional flow and water-quality model to inform those flow- and temperature-management strategies by tracking the quantities and ages of water and heat from individual upstream sources to downstream locations in the Willamette River system. Specifically, the fraction of water and heat attributable to upstream dam releases or other water inputs, and the fraction of heat sourced from environmental heat fluxes across the water and sediment surfaces, were tracked and quantified in the river at all locations and times simulated by the model. Applying the updated CE-QUAL-W2 models to the Willamette River system for the months of March through October in the years 2011 (cool and wet), 2015 (hot and dry), and 2016 (warm and somewhat dry) demonstrated that the influence of upstream dam releases on downstream water temperature diminished within a few days as water moved downstream. At sites that are roughly two or more days of travel from upstream dams (Albany and downstream), the July–August fraction of riverine heat content that could be tracked back to upstream dam releases typically diminished to less than 20 percent, despite the fact that roughly 50 percent of July–August streamflow could be attributed to upstream dam releases at the same sites. In contrast, the fraction of riverine heat content that could be attributed to environmental energy fluxes continued to increase with downstream distance, from about 59 to 67 percent at Albany during July–August to 62 to 73 percent at Keizer and 68 to 79 percent at Newberg. At locations sufficiently far downstream, upstream dam releases affect water temperature mainly through a decrease in travel time (less time for environmental heat fluxes to warm the river during summer) and an increase in thermal mass (more water to dilute and buffer incoming heat fluxes) rather than through the simple transport of heat content (water temperature) released from the dams. This concept was explored not only for the baseline conditions that occurred in March–October of 2011, 2015, and 2016, but also for a hypothetical high-flow release during August 2016 and an actual high-flow release during August 2017. In these high-flow releases, an extra 2,500 cubic feet per second (roughly) was released from Dexter Dam on the Middle Fork Willamette River, and downstream effects were measured (2017, actual) and simulated (2016, hypothetical). Results of the simulations were consistent with insights gained from the baseline conditions, such that temperature changes caused by flow augmentation were substantial in upstream reaches (measured cooling of about 1.5 °C near Harrisburg [43 miles downstream] and Albany [84 miles downstream] in 2017, and cooling of about 0.5 °C near Albany in 2016) and diminished farther downstream, but still measurable (more than a few tenths of a degree Celsius) even at Newberg, which is about 154 miles downstream. The direct downstream effects of dam releases on the river heat content attributable to those releases were increased by the hypothetical flow augmentation, with increases of 20 percent at Harrisburg and 12 percent at Keizer. Even with a decreased influence of environmental energy fluxes on river heat content, however, the fraction of heat content attributable to such fluxes was still more than 50 percent at and downstream of Albany and more than 70 percent at Newberg, where the river temperature was less affected by upstream dam-release temperatures and instead was affected primarily by a decreased travel time and increased thermal mass.

Oregon↗

USGS2021

Patterns of bubble bursting and weak explosive activity in an active lava lake—Halema‘uma‘u, Kīlauea, 2015

The rise of the Halemaʻumaʻu lava lake in 2013–2018 to depths commonly 40 meters or less below the rim of the vent was an excellent opportunity to study outgassing and the link to associated eruptive activity. We use videography to investigate the rise and bursting of bubbles through the free surface of the lake in 2015. We focus on low-energy explosive activity (spattering) in which the ascent and bursting of meter-sized, mechanically decoupled bubbles trigger the ejection of fluidal bombs to tens of meters above the free surface. A decay in initial pyroclast velocity with time follows the same functional form as that observed for ejecta at Stromboli (Italy), suggesting a similar bubble-burst mechanism. We also find that the upward velocity of the bubble crust as it bursts is around 2.5 times higher than the velocity of the bubble as it rises through the lake surface, indicating that the bubbles are over-pressurized. Prior to bursting, bubbles emerge at velocities of 4 to 14 meters per second, suggesting rise from depths of at least tens of meters but unaffected by the deeper circulation of the lava lake. We identify three styles of bubble bursting: (1) isolated, widely spaced, single bursts, (2) recurring clusters of discrete bubbles, and (3) prolonged episodes of overlapping bubble bursts along elongate narrow sources typically parallel to the margins of the lava lake. We call these styles of bursting isolated events, clusters, and prolonged episodes, respectively. The frequency of bubble bursting and the mass fluxes of gas and pyroclasts increase from styles 1 to 3. The intensity (mass eruption rate) for single bubble bursts ranges from 280 to 3,500 kilograms per second. The total erupted mass of pyroclasts for a single burst is <4,000 kilograms (kg) and for a single well-constrained prolonged episode is about 10 7 kg. These numbers place the observed spattering at the lowest end of basaltic explosivity in terms of erupted mass (that is, magnitude). Most ejecta fell back into the crater; only strands of Pele’s hair rose to heights where they could be advected downwind from the vent. Collectively, the explosive activity accompanying the three styles of bubble bursting spans from impulsive, transient eruptive behaviors to sustained discharge; this shift represents progressively higher frequency and intensity of bubble bursting.

Hawaii↗

USGS2015

Effects of elevated water temperature on physiological responses in adult freshwater mussels

Freshwater mussels (order Unionoida) face multiple environmental stressors, which pose serious conservation challenges to this diverse assemblage of aquatic invertebrates. Of these stressors, elevated water temperature from global climate change and other anthropogenic sources may be the most ubiquitous and could be placing many mussel populations dangerously close to their thermal maxima. We tested the hypothesis that elevated water temperatures (20, 25, 30 and 35 °C) adversely affected physiological responses in adults of four North American species of mussels ( Amblema plicata , Elliptio complanata, Fusconaia flava and Lampsilis cardium) in 21-d laboratory tests. Oxygen consumption rates were directly affected by temperature in E. complanata and L. cardium , and indirectly affected by temperature in A. plicata and F. flava . Rates of O 2 consumption were generally positively correlated with water temperature. Ammonium excretion rates varied significantly with temperature in E. complanata and generally increased with temperature. The amount of O 2 consumed relative to nitrogen excreted (O : N ratio), varied significantly with temperature in A. plicata , E. complanata and F. flava . The tissue condition index varied among temperatures and species. These data suggest that elevated temperatures can alter metabolic rates in native mussels and may decrease the amount of energy that is available for key biological processes, such as survival, growth and reproduction.

Freshwater Biology↗

USGS2019

Encylopedia of Caves

For many people, a visit to a cave is a wondrous event directing our minds to ponder the mysteries presented by these unique places and inspiring questions: How old is the cave? What was the role of water in forming the cave and where did the water come from? How is the cave connected to the surface environment? These are intriguing questions to ask, and karst scientists use isotope geochemistry to help solve these mysteries. Isotopes are atoms of the same chemical element that have the same number of protons but vary in their number of neutrons. As a result of their atomic mass difference, isotopes of a single element may exhibit slightly different chemical behavior. Radioisotopes are unstable and the nucleus of a parent isotope will spontaneously break apart (decay), releasing energy and changing into another element (daughter product) by loss or gain of protons, neutrons, or electrons. Stable isotopes, as implied by the name, are stable and do not spontaneously decay. These two types of isotopes are used widely by scientists to understand ancient and modern karst systems. Generally, radioisotopes are used for absolute dating karst water, cave sediments, cave formations (speleothems), and other material preserved in caves (such as bones). Stable isotopes can provide information about relative ages of cave water and speleothems. An absolute age provides a numeric date—such as 100,000 years old—whereas a relative age provides information that something is older or younger than something else—such as cave art is younger than a speleothem found in the same cave. Stable isotopes are used to study ancient karst systems because isotopic signals of past climate (paleoclimate) and environmental conditions (paleoenvironment) are preserved in speleothems and sediments. Stable isotopes are also used to understand modern systems, primarily through studies that distinguish sources of karst water, cave air, or contaminants, mixing of those sources, and biologic or chemical reactions that process compounds, such as breakdown of contaminants or organic matter. The variation in mass among isotopes is small, and isotope abundances are measured as a ratio of a common isotope to its less common isotopic counterparts (stable isotopes) or the abundance of a parent compared to daughter isotope (radioisotopes). As an example, hydrogen (H) has three naturally occurring isotopes. Most H comprises one proton (1H), but the rarer stable isotope (called deuterium) comprises one proton and one neutron (2H), and the radioisotope (called tritium) comprises one proton and two neutrons (3H). Because scientists use the minute differences in isotopes to test hypotheses, a scientist must understand the accuracy, precision, and error of the available methods, the assumptions about the chemical conditions of interest, and the limitations of the isotopic method being used. Many isotopic studies employ multiple isotopic tracers to better leverage the strengths and offset the limitations of using a single isotope. This article focuses on isotopes used to study the geology and hydrology of caves, but much additional isotopic work has been used to characterize the biology of caves.

Book chapter↗

USGS2017

Trophic structure of mesopelagic fishes in the Gulf of Mexico revealed by gut content and stable isotope analyses

Mesopelagic fishes represent an important component of the marine food web due to their global distributions, high abundances and ability to transport organic material throughout a large part of the water column. This study combined stable isotope (SIAs) and gut content analyses (GCAs) to characterize the trophic structure of mesopelagic fishes in the North-Central Gulf of Mexico. Additionally, this study examined whether mesopelagic fishes utilized chemosynthetic energy from cold seeps. Specimens were collected (9–25 August 2007) over three deep (>1,000 m) cold seeps at discrete depths (surface to 1,503 m) over the diurnal cycle. GCA classified 31 species (five families) of mesopelagic fishes into five feeding guilds: piscivores, large crustacean consumers, copepod consumers, generalists and mixed zooplanktivores. However, these guilds were less clearly defined based on stable isotope mixing model (MixSIAR) results, suggesting diets may be more mixed over longer time periods (weeks–months) and across co-occurring species. Copepods were likely important for the majority of mesopelagic fishes, consistent with GCA (this study) and previous literature. MixSIAR results also identified non-crustacean prey items, including salps and pteropods, as potentially important prey items for mesopelagic fishes, including those fishes not analysed in GCA ( Sternoptyx spp. and Melamphaidae). Salps and other soft-bodied species are often missed in GCAs. Mesopelagic fishes had δ 13 C results consistent with particulate organic matter serving as the baseline organic carbon source, fueling up to three trophic levels. Fishes that undergo diel vertical migration were depleted in 15 N relative to weak migrators, consistent with depth-specific isotope trends in sources and consumers, and assimilation of 15 N-depleted organic matter in surface waters. Linear correlations between fish size and δ 15 N values suggested ontogenetic changes in fish diets for several species. While there was no direct measure of mesopelagic fishes assimilating chemosynthetic material, detection of infrequent consumption of this food resource may be hindered by the assimilation of isotopically enriched photosynthetic organic matter. By utilizing multiple dietary metrics ( e.g . GCA, δ 13 C, δ 15 N, MixSIAR), this study better defined the trophic structure of mesopelagic fishes and allowed for insights on feeding, ultimately providing useful baseline information from which to track mesopelagic trophodynamics over time and space.

Marine Ecology↗

USGS2008

Metabolizable energy in Chinese tallow fruit for Yellow-rumped Warblers, Northern Cardinals, and American Robins

The invasive exotic Chinese tallow tree (Triadica sebifera) produces an abundant fruit crop, which is primarily bird-dispersed. The fruit pulp of tallow is lipid-rich, high in saturated fatty acids, and consumed by many bird species. Long-chained fatty acids can be difficult for many birds to digest and we investigated the ability of tallow consumers to assimilate energy in the pulp. We used the total collection method and compared apparent metabolizable energy (AME) of tallow fruit for three species of birds with differing fruit composition in their natural diets. All birds exhibited nitrogen deficits and lost body mass during the trials. Northern Cardinals (Cardinalis cardinalis) lost more mass (8.73%/day) than Yellow-rumped Warblers (Dendroica coronata) (5.29%/day) and American Robins (Turdus migratorius) (5.48%/day), and had larger nitrogen deficits (-120.1 mg N/g diet) than both species as well (-36.4 mg N/g diet and -68.9 mg N/g diet, respectively). Food intake relative to metabolic body mass was highest in Yellow-rumped Warblers (0.70 g-dry/g 0.75??day). Northern Cardinal and American Robin food intake was lower and did not differ from each other (both species: 0.13 g-dry/g 0.75??day). Nitrogen corrected values of AME were used to make species comparisons. Yellow-rumped-Warblers exhibited the highest values of AME (30.00 kJ/g), followed by American Robins (23.90 kJ/g), and Northern Cardinals (14.34 kJ/g). We suggest tallow may be an important winter food source for Yellow-rumped Warblers where their ranges overlap.

Wilson Journal of Ornithology↗

USGS2015

Non-linear resonant coupling of tsunami edge waves using stochastic earthquake source models

Non-linear resonant coupling of edge waves can occur with tsunamis generated by large-magnitude subduction zone earthquakes. Earthquake rupture zones that straddle beneath the coastline of continental margins are particularly efficient at generating tsunami edge waves. Using a stochastic model for earthquake slip, it is shown that a wide range of edge-wave modes and wavenumbers can be excited, depending on the variability of slip. If two modes are present that satisfy resonance conditions, then a third mode can gradually increase in amplitude over time, even if the earthquake did not originally excite that edge-wave mode. These three edge waves form a resonant triad that can cause unexpected variations in tsunami amplitude long after the first arrival. An M &sim; 9, 1100 km-long continental subduction zone earthquake is considered as a test case. For the least-variable slip examined involving a Gaussian random variable, the dominant resonant triad includes a high-amplitude fundamental mode wave with wavenumber associated with the along-strike dimension of rupture. The two other waves that make up this triad include subharmonic waves, one of fundamental mode and the other of mode 2 or 3. For the most variable slip examined involving a Cauchy-distributed random variable, the dominant triads involve higher wavenumbers and modes because subevents, rather than the overall rupture dimension, control the excitation of edge waves. Calculation of the resonant period for energy transfer determines which cases resonant coupling may be instrumentally observed. For low-mode triads, the maximum transfer of energy occurs approximately 20–30 wave periods after the first arrival and thus may be observed prior to the tsunami coda being completely attenuated. Therefore, under certain circumstances the necessary ingredients for resonant coupling of tsunami edge waves exist, indicating that resonant triads may be observable and implicated in late, large-amplitude tsunami arrivals.

Geophysical Journal International↗

USGS2019

Rare earth element mineral deposits in the United States

Because of their unique special chemical properties, many of the metals in the group of rare earth elements (REEs) have essential applications in 21st century technologies. Examples of products that use REEs are cell phones, computers, fluorescent and light-emitting-diode lights, flat-screen television and computer monitors, and in high-strength magnets used by clean energy technologies such as the generators of wind turbines and batteries of hybrid and electric vehicles. REEs are used in many defense applications, such as in components of jet engines, missile guidance systems, antimissile defense systems, satellites, and communication systems. The rare earth elements have become vital to manufacturing numerous high-tech products, which has been accompanied by a large increase in their demand. At the same time, there has been concern by the United States and many other Nations about the near-monopoly of mining, processing, and supply of REEs from one Nation, China. Between 2011 and 2017, China produced approximately 84 percent of the world’s REEs, and during this time the United States only produced REEs between 2012 and 2015. The U.S. production came entirely from the Mountain Pass mine in California, providing only about 4 percent of the world REE supply. Because REEs are essential for technological applications and are primarily supplied by one Nation, there has been an increased concern in identifying new sources of REEs, including economic REE deposits. In response to these concerns, since 2009, the U.S. Geological Survey (USGS) has conducted numerous studies focused on the distribution, geology, and potential resources for the REE-bearing mineral deposits in the United States. The basic characteristics of mineral deposit types that host REE enrichments in the United Sates are summarized in this report, with selected examples. Several types of REE-enriched mineral deposits are reviewed, including deposits in carbonatites, alkaline igneous rocks, sedimentary phosphate-rich rocks (phosphorite), regions containing REE-rich veins, iron oxide deposits containing REE-bearing apatite, monazite-xenotime-bearing placer deposits (heavy-mineral sands), and ion-adsorption clay deposits (REE in granite-derived regolith). A better understanding of these mineral deposits will assist in identifying domestic resources to help alleviate the dependence on imported REEs. The economic development of REE mineral deposits is affected by many factors beyond mining, such as commodity prices and mineral processing costs. Most of the REEs are hosted by minerals that have complex chemical formulas; this presents more challenges to process and extract the REEs. Continued advancements and refinements in mineral processing techniques may allow REE deposits with complex mineralogy to be economically developed in the future.

Circular↗