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Detection of pesticides and pesticide metabolites using the cross reactivity of enzyme immunoassays

Enzyme immunoassay is an important environmental analysis method that may be used to identify many pesticide analytes in water samples. Because of similarities in chemical structure between various members of a pesticide class, there often may be an unwanted response that is characterized by a percentage of cross reactivity. Also, there may be cross reactivity caused by degradation products of the target analyte that may be present in the sample. In this paper, the concept of cross reactivity caused by degradation products or by nontarget analytes is explored as a tool for identification of metabolites or structurally similar compounds not previously known to be present in water samples. Two examples are examined in this paper from various water quality studies. They are alachlor and its metabolite, alachlor ethane sulfonic acid, and atrazine and its class members, prometryn and propazine. A method for using cross reactivity for the detection of these compounds is explained in this paper.

Journal of AOAC International↗

Controlled photomosaic map of Callisto JC 15M CMN

This sheet is one in a series of maps of the Galilean satellites of Jupiter at a nominal scale of 1:15,000,000. This series is based on data from the Galileo Orbiter Solid-State Imaging (SSI) camera and the cameras of the Voyager 1 and 2 spacecraft. Mercator and Polar Stereographic projections used for this map of Callisto are based on a sphere having a radius of 2,409.3 km. The scale is 1:8,388,000 at ±56° latitude for both projections. Longitude increases to the west in accordance with the International Astronomical Union (1971) (Seidelmann and others, 2002). The geometric control network was computed at the RAND Corporation using RAND's most recent solution as of April 1999 (Davies and Katayama, 1981; Davies and others, 1998). This process involved selecting control points on the individual images, making pixel measurements of their locations, using reseau locations to correct for geometric distortions, and converting the measurements to millimeters in the focal plane. These data are combined with the camera focal lengths and navigation solutions as input to photogrammetric triangulation software that solves for the best-fit sphere, the coordinates of the control points, the three orientation angles of the camera at each exposure (right ascension, declination, and twist), and an angle (W0) which defines the orientation of Callisto in space. W0-in this solution 259.51°-is the angle along the equator to the east, between the 0° meridian and the equator's intersection with the celestial equator at the standard epoch J2000.0. This solution places the crater Saga at its defined longitude of 326° west (Seidelmann and others, 2002). This global map base uses the best image quality and moderate resolution coverage supplied by Galileo SSI and Voyager 1 and 2 (Batson, 1987; Becker and others, 1998; Becker and others, 1999; Becker and others, 2001). The digital map was produced using Integrated Software for Imagers and Spectrometers (ISIS) (Eliason, 1997; Gaddis and others, 1997; Torson and Becker, 1997). The individual images were radiometrically calibrated and photometrically normalized using a Lunar-Lambert function with empirically derived values (McEwen, 1991; Kirk and others, 2000). A linear correction based on the statistics of all overlapping areas was then applied to minimize image brightness variations. The image data were selected on the basis of overall image quality, reasonable original input resolution (from 20 km/pixel for gap fill to as much as 150 m/pixel), and availability of moderate emission/incidence angles for topography. Although consistency was achieved where possible, different filters were included for global image coverage as necessary: clear for Voyager 1 and 2; clear and green (559 nm) for Galileo SSI. Individual images were projected to a Sinusoidal Equal-Area projection at an image resolution of 1.0 kilometer/pixel. The final constructed Sinusoidal projection mosaic was then reprojected to the Mercator and Polar Stereographic projections included on this sheet. The final mosaic was enhanced using commercial software. Names on this sheet are approved by the International Astronomical Union. Names have been applied for features clearly visible at the scale of this map; for a complete list of nomenclature for Callisto, please see the Gazeteer of Planetary Nomenclature. Font color was chosen only for readability.

IMAP↗

Quality-assurance plan for the analysis of fluvial sediment by the U.S. Geological Survey New Mexico Water Science Center Sediment Laboratory

This report describes laboratory procedures used by the U.S. Geological Survey New Mexico Water Science Center Sediment Laboratory for the processing and analysis of fluvial-sediment samples for concentration of sand and finer material. The report details the processing of a sediment sample through the laboratory from receiving the sediment sample, through the analytical process, to compiling results of the requested analysis. Procedures for preserving sample integrity, calibrating and maintaining of laboratory and field instruments and equipment used to analyze samples, internal quality assurance and quality control, and validity of the sediment-analysis results also are described. The report includes a list of references cited and a glossary of sediment and quality-assurance terms.

Open-File Report↗

Construction of shipping channels in the Detroit River: History and environmental consequences

The Detroit River is one of the most biologically diverse areas in the Great Lakes basin. It has been an important international shipping route since the 1820s and is one of the busiest navigation centers in the United States. Historically, it supported one of the most profitable Lake Whitefish (Coregonus clupeaformis) commercial fisheries in the Great Lakes. Since 1874, the lower Detroit River has been systematically and extensively modified, by construction of deepwater channels, to facilitate commercial shipping. Large-scale dredging, disposal of dredge spoils, and construction of water-level compensating works has greatly altered channel morphology and flow dynamics of the river, disrupting ecological function and fishery productivity of the river and influencing Great Lakes water levels. From 1874 to 1968, major construction projects created 96.5 kilometers (60 miles) of shipping channels, removed over 46,200,000 m 3 of material, covered 4,050 hectares (40.5 square kilometers) of river bottom with dredge spoils, and built 85 hectares of above-waterline compensating works at a total cost of US$283 million. Interest by industries and government agencies to develop the river further for shipping is high and increasing. Historically, as environmental protection agencies were created, construction impacts on natural resources were increasingly addressed during the planning process and, in some cases, assessments of these impacts greatly altered or halted proposed construction projects. Careful planning of future shipping-channel construction and maintenance projects, including a thorough analysis of the expected environmental impacts, could greatly reduce financial costs and ecological damages as compared to past shipping-channel construction projects.

Michigan↗

A refined index of model performance: a rejoinder

Willmott et al. [Willmott CJ, Robeson SM, Matsuura K. 2012. A refined index of model performance. International Journal of Climatology , forthcoming. DOI:10.1002/joc.2419.] recently suggest a refined index of model performance ( d r ) that they purport to be superior to other methods. Their refined index ranges from − 1.0 to 1.0 to resemble a correlation coefficient, but it is merely a linear rescaling of our modified coefficient of efficiency ( E 1 ) over the positive portion of the domain of d r . We disagree with Willmott et al. ( 2012 ) that d r provides a better interpretation; rather, E 1 is more easily interpreted such that a value of E 1 = 1.0 indicates a perfect model (no errors) while E 1 = 0.0 indicates a model that is no better than the baseline comparison (usually the observed mean). Negative values of E 1 (and, for that matter, d r < 0.5) indicate a substantially flawed model as they simply describe a ‘level of inefficacy’ for a model that is worse than the comparison baseline. Moreover, while d r is piecewise continuous, it is not continuous through the second and higher derivatives. We explain why the coefficient of efficiency ( E or E 2 ) and its modified form ( E 1 ) are superior and preferable to many other statistics, including d r , because of intuitive interpretability and because these indices have a fundamental meaning at zero. We also expand on the discussion begun by Garrick et al. [Garrick M, Cunnane C, Nash JE. 1978. A criterion of efficiency for rainfall-runoff models. Journal of Hydrology 36 : 375-381.] and continued by Legates and McCabe [Legates DR, McCabe GJ. 1999. Evaluating the use of “goodness-of-fit” measures in hydrologic and hydroclimatic model validation. Water Resources Research 35 (1): 233-241.] and Schaefli and Gupta [Schaefli B, Gupta HV. 2007. Do Nash values have value? Hydrological Processes 21 : 2075-2080. DOI: 10.1002/hyp.6825.]. This important discussion focuses on the appropriate baseline comparison to use, and why the observed mean often may be an inadequate choice for model evaluation and development.

International Journal of Climatology↗

Landsat-8: Science and product vision for terrestrial global change research

Landsat 8, a NASA and USGS collaboration, acquires global moderate-resolution measurements of the Earth's terrestrial and polar regions in the visible, near-infrared, short wave, and thermal infrared. Landsat 8 extends the remarkable 40 year Landsat record and has enhanced capabilities including new spectral bands in the blue and cirrus cloud-detection portion of the spectrum, two thermal bands, improved sensor signal-to-noise performance and associated improvements in radiometric resolution, and an improved duty cycle that allows collection of a significantly greater number of images per day. This paper introduces the current (2012–2017) Landsat Science Team's efforts to establish an initial understanding of Landsat 8 capabilities and the steps ahead in support of priorities identified by the team. Preliminary evaluation of Landsat 8 capabilities and identification of new science and applications opportunities are described with respect to calibration and radiometric characterization; surface reflectance; surface albedo; surface temperature, evapotranspiration and drought; agriculture; land cover, condition, disturbance and change; fresh and coastal water; and snow and ice. Insights into the development of derived ‘higher-level’ Landsat products are provided in recognition of the growing need for consistently processed, moderate spatial resolution, large area, long-term terrestrial data records for resource management and for climate and global change studies. The paper concludes with future prospects, emphasizing the opportunities for land imaging constellations by combining Landsat data with data collected from other international sensing systems, and consideration of successor Landsat mission requirements.

Remote Sensing of Environment↗

Committee on glaciers, 1939–40

The Committee on Glaciers is now composed of the following members: Harry Fielding Reid, Professor Emeritus of Geology, Johns Hopkins University, 608 Cathedral Street, Baltimore, Maryland; William H. Hobbs, Professor Emeritus of Geology, University of Michigan, Ann Arbor, Michigan; Lawrence Martin, Chief of the Division of Maps, Library of Congress, Washington, D.C.; J. E. Church, Professor of Meteorology, Agricultural Experiment Station, University of Nevada, Reno, Nevada; Wm. Osgood Field, Jr., Explorer, 18 West Twelfth Street, New York, N.Y.; Earl A. Trager, Chief of the Naturalist Division, National Park Service, Washington, D.C.; Oliver Kehrlein, Chairman, Committee on Glacier Studies, 1050 Mills Tower, 220 Bush Street, San Francisco, California; Kenneth N. Phillips, Associate Hydraulic Engineer, Water Resources Branch, United States Geological Survey, Chairman, Research Committee of the Mazamas, 606 Post‐Office Building, Portland, Oregon; William S. Cooper, Professor of Botany, University of Minnesota, Minneapolis, Minnesota; Gerald FitzGerald, Senior Topographic Engineer, Alaska Branch, United States Geological Survey, Washington, D.C.; Lawrence M. Gould, Professor of Geology, Carleton College, Northfield, Minnesota; François E. Matthes (Chairman), Senior Geologist, Section of Glacial Geology, United States Geological Survey, Washington, D.C. The international relations of the Committee have changed somewhat during the past year as a result of the consolidation of the International Commission of Glaciers with the International Commission of Snow. That consolidation was effected by the International Association of Scientific Hydrology (to which both commissions belonged) at the triennial meeting in Washington, in September, 1939. Inasmuch as the membership of the new International Commission of Snow and Glaciers comprises the personnel of the two former commissions, our Committee on Glaciers now automatically is represented on the new International Commission by four men—Church, Hobbs, Gould, and Matthes. Moreover, Church is acting President, and it is understood that he will become President as soon as the political situation in Europe permits the holding of a formal election of officers at which all nations interested can exercise their right of voting

Eos, Transactions, American Geophysical Union↗

Landsat Image Mosaic of Antarctica (LIMA)

For most of us, Antarctica was at best a distant acquaintance. Now, with the Landsat Image Mosaic of Antarctica (LIMA), we are on intimate terms. In stunning, up-close and personal detail, LIMA brings Antarctica to life. Explore this virtually cloudless, seamless, most geometrically accurate, and highest resolution satellite mosaic of Antarctica. A team of scientists from the U.S. Geological Survey, the British Antarctic Survey, and the National Aeronautics and Space Administration, with funding from the National Science Foundation, created LIMA in support of the International Polar Year (IPY; 2007?08). As the first major scientific outcome of the IPY, LIMA truly fulfills the IPY goals. LIMA is an international effort, supports current scientific polar research, encourages new projects, and helps the general public visualize Antarctica and changes happening in this southernmost environment. Researchers and the general public can download LIMA and all component Landsat scenes at no charge.

Fact Sheet↗

Limnology of Big Lake, south-central Alaska, 1983-84

The limnological characteristics and trophic state of Big Lake in south-central Alaska were determined from the results of an intensive study during 1983-84. The study was begun in response to concern over the potential for eutrophication of Big Lake, which has experienced substantial residential development and recreational use because of its proximity to Anchorage. The east and west basins of the 1,213 square-hectometer lake were each visited 36 times during the 2-year study to obtain a wide variety of physical, chemical, and biological data. During 1984, an estimate was made of the lake's annual primary production. Big Lake was classified as oligotrophic on the basis of its annual mean values for total phosphorus (9.5 micrograms per liter), total nitrogen (209 micrograms per liter), chlorophyll-a (2.5 micrograms per liter), secchi-disc transparency (6.3 meters), and its mean daily integral primary production of 81.1 milligrams of carbon fixed per square meter. The lake was, however, uncharacteristic of oligotrophic lakes in that a severe dissolved-oxygen deficit developed within the hypolimnion during summer stratification and under winter ice cover. The summer dissolved-oxygen deficit resulted from the combination of strong and persistent thermal stratification, which developed within 1 week of the melting of the lake's ice cover in May, and the failure of the spring circulation to fully reaerate the hypolimnion. The autumn circulation did reaerate the entire water column, but the ensuing 6 months of ice and snow cover prevented atmospheric reaeration of the water column and led to development of the winter dissolved-oxygen deficit. The anoxic conditions that eventually developed near the lake bottom allowed the release of nutrients from the bottom sediments and facilitated ammonification reactions. These processes yielded hypolimnetic concentrations of nitrogen and phosphorus compounds, which were much larger than the oligotrophic concentrations measured within the epilimnion. An analysis of nitrogen-to-phosphorus ratios showed that nitrogen was the nutrient most likely to limit phytoplankton growth during the summer. Although mean chlorophyll-a concentrations were at oligotrophic levels, concentrations did peak at 46.5 micrograms per liter in the east basin. During each year and in both basins, the peak chlorophyll-a concentrations were measured within the hypolimnion because the euphotic zone commonly was deeper than the epilimnion during the summer. The annual integral primary production of Big Lake in 1984 was 29.6 grams of carbon fixed per square meter with about 90 percent of that produced during May through October. During this time period, the lake received 76 percent of its annual input of solar irradiance. Monthly integral primary production, in milligrams of carbon fixed per square meter, ranged from 1.5 in January to 7,050 in July. When compared with the range of annual integral primary production measured in 50 International Biological Program lakes throughout the world, Big Lake had a low value of annual integral primary production. The results of this study lend credence to the concerns about the potential eutrophication of Big Lake. Increases in the supply of oxygen-demanding materials to Big Lake could worsen the hypolimnetic dissolved-oxygen deficit and possibly shift the lake's trophic state toward mesotrophy or eutrophy.

Water Supply Paper↗

Comparison of accuracy and completeness of data obtained from three types of automatic water-quality monitors

A comparison of data (specific conductance, dissolved-oxygen concentration, temperature, and pH) collected by the U.S. Geological Survey flowthrough monitor, the U.S. Geological Survey minimonitor, and a self-contained commercial 'packaged-sensor' system indicates that the data obtained by means of the most complete of the three systems. The U.S. Geological Survey flowthrough monitor is powered by 120-volt alternating current and in a heated weather-proof shelter. A pumping system brings water from the stream to sensors clustered in a sample clustered in a sample chamber located in the shelter. This instrument measures output from the senors; data are recorded in binary-coded decimal form on a 16-channel punched-paper tape recorder tape recorder housed in the shelter. The U.S. Geological Survey's minimonitor is powered by an external battery and is housed in a weatherproof shelter. This instrument measures output of instream sensors with extension cables having underwater connectors; data are recorded in binary-coded decimal form on a 16-channel punched-paper tape recorder housed in the shelter. The packaged-sensor system also measures output of senors housed in a packages that is submerged in the stream. It has internal power supply, no moving parts, and does not requires a weatherproof shelter; data are stored are stored in solid-state memory. Minimonitors were installed at four sites in Ohio where U.S. Geological survey flowthrough were in operation. Two package-sensor systems also were assigned to each site and were alternated every two weeks. Detailed records were kept of (1) field measurements, for comparison with monitor-system data from each instrument, and (2) equipment problems that resulted in loss of data. Results of the comparisons shows that the flow-through monitor gave the most accurate and the most complete data.

Water-Resources Investigations Report↗

Profiling lunar dust dissolution in aqueous environments: The design concept

Published studies and internal NASA reports indicate that when native lunar dust is suspended in an aqueous solution a variety of metal and other ions are released. This release has implications for future lunar missions, ranging from effects on mission hardware, effects on life support systems, possible direct effects on human health, and effects on research experiments such as plant growth experiments, space biology experiments and any activities that may involve the use of water sourced from the lunar poles. Furthermore, such contaminants could become concentrated or chemically altered to a more hazardous form during a variety of lunar mission activities, including everything from space suit cleaning to lunar industrial materials extraction. The exact profile of the release of ions from lunar dust and the nature of the partially dissolved particles has not been explored. Any model of this dissolution must be based on an understanding of the unique micromorphology of lunar dust, including its glassy nature, agglutinate features, high surface area and the presence of small deposits of elemental iron (nanophase iron) located near the surface of the grain particles. Dust has a very high surface area available for interaction with water. For this reason, on first exposure to water, an immediate pulsed release of ions could occur, with more prolonged release taking place over months or years. The few studies that have been conducted previously have been limited in both the time scales examined and in the selection of ions that were measured. The proposed investigation is a comprehensive materials science investigation, using the most modern analytical tools to catalogue all metals given off from lunar dust in various aqueous solutions and their time profiles of release from the very short term to the very long term. The product of the proposed study will be a comprehensive database determined from NASA curated samples collected from the Apollo landing sites that can be applied to research in both living systems and non-living systems on the moon. The methods developed in the proposed study will also establish standards for analysis of lunar dust samples returned from future manned missions (Artemis and others) and future robotic missions. The knowledge gained from this basic materials science investigation will have broad impact on the design of engineered human safety and health systems.

Acta Astronautica↗

Carbon assimilation characteristics of the aquatic CAM plant Isoetes howellii

The relationship between malic acid production and carbon assimilation was examined in the submerged aquatic Crassulacean acid metabolism (CAM) plant, Isoetes howellii Engelmann. Under natural conditions free-CO 2 level in the water was highest at 0600 hours and 14 CO 2 assimilation rates in I. howellii were also highest at this time. After 0900 hours there was a similar pattern in (a) rate of free-CO 2 depletion from the water, (b) reduction of carbon assimilation rates, and (c) rate of deacidification in leaves. Rates of daytime deacidification increased under CO 2 -free conditions and as irradiance intensity increased. Nighttime CO 2 uptake was estimated to contribute one-third to one-half of the total daily gross carbon assimilation. CO 2 uptake, however, accounted for only one-third to one-half of the overnight malic acid accumulation. Internal respiratory CO 2 may be a substrate for a large portion of overnight acid accumulation as leaves incubated overnight without CO 2 accumulated substantial levels of malic acid. Loss of CAM occurred in emergent leaf tips even though submerged bases continued CAM. Associated with loss of CAM in aerial leaves was an increase in total chlorophyll, a/b ratio, and carotenoids, and a decrease in leaf succulence. δ 13 C values of I. howellii were not clearly distinguishable from those for associated non-CAM submerged macrophytes.

Plant Physiology↗

Summary of reconnaissance for radioactive deposits in Alaska, 1945-1954, and an appraisal of Alaskan uranium possibilities

In the period 1945-1954 over 100 investigations for radioactive source materials were made in Alaska. The nature of these investigations ranged from field examinations of individual prospects or the laboratory analysis of significantly radioactive samples submitted by prospectors to reconnaissance studies of large districts. In this period no deposits of uranium or thorium that would warrant commercial exploitation were discovered. The investigations, however, disclosed that radioactive materials occur in widely scattered areas of Alaska and in widely diverse environments. Many igneous rocks throughout Alaska are weakly radioactive because of uranium- and thorium-bearing accessory minerals, such as allanite, apatite, monazite, sphene, xenotime, and zircon; more rarely the radioactivity of these rocks is due to thorianite or thorite and their uranoan varieties. The felsic rocks, for example, granites and syenites, are generally more radioactive than the mafic igneous rocks. Pegmatites, locally, have also proved to be radioactive, but they have little commercial significance. No primary uranium oxide minerals have been found yet in Alaskan vein deposits, except, perhaps, for a mineral tentatively identified as pitchblende in the Hyder district of southeastern Alaska. However, certain occurrences of secondary uranium minerals, chiefly those of the uranite group, on the Seward Peninsula, in the Russian Mountains, and in the vicinity of Kodiak suggest that pitchblende-type ores may occur at depth beneath zones of alteration. Thorite-bearing veins have been discovered on Prince of Wales Island in southeastern Alaska. Although no deposits or carnotite-type minerals have been found in Alaska, several samples containing such minerals have been submitted by Alaskan prospectors. Efforts to locate the deposits from which these minerals were obtained have been unsuccessful, but review of available geologic data suggests that several Alaskan areas are potentially favorable for carnotite-type deposits. The chief of these areas is the Alaska Peninsula-Cook Inlet area which encompasses most of the reported occurrences of the prospectors' carnotite-type samples. Alaska is also potentially favorable for the occurrence of large bodies of the very low-grade uraniferous sedimentary rocks, such as phosphorites and black shales. This type of deposit, however, has not received much study because of the emphasis on the search for bonanza-type high-grade ores. Uraniferous phosphorites similar to those of Idaho, Montana, and Wyoming occur in northern Alaska on the north flank of the Brooks Range; black shales comparable to the uraniferous shales of the Chattanooga formation of southeastern United States have been noted along the Yukon River near the international boundary. Placer deposits in Alaska have some small potential for the production of the radioactive elements as byproducts of gold- and tin-placer mining. the placer area believed to have the relatively greatest potential in Alaska lies in the Kahiltna River valley where concentrates are known to contain such commercial minerals as ilmenite, cassiterite, platinum, and gold in addition to uranothorianite and monazite. The possibilities of the natural fluids--water and petroleum--have not yet been tested in Alaska to any great extent. Studies of fluids are in progress to determine whether they may be used to discover and define areas potentially favorable for the occurrence of uraniferous lodes.

Alaska↗

Developing and optimizing shrub parameters representing sagebrush (Artemisia spp.) ecosystems in the Northern Great Basin using the Ecosystem Demography (EDv2.2) model

Ecosystem dynamic models are useful for understanding ecosystem characteristics over time and space because of their efficiency over direct field measurements and applicability to broad spatial extents. Their application, however, is challenging due to internal model uncertainties and complexities arising from distinct qualities of the ecosystems being analyzed. The sagebrush-steppe in western North America, for example, has substantial spatial and temporal heterogeneity as well as variability due to anthropogenic disturbance, invasive species, climate change, and altered fire regimes, which collectively make modelling dynamic ecosystem processes difficult. Ecosystem Demography (EDv2.2) is a robust ecosystem dynamic model, initially developed for tropical forests, that simulates energy, water, and carbon fluxes at fine scales. Although EDv2.2 has since been tested on different ecosystems via development of different Plant Function Types (PFT), it still lacks a shrub PFT. In this study, we developed and parameterized a shrub PFT representative of sagebrush (Artemisia spp.) ecosystems in order to initialize and test it within EDv2.2, and to promote future broad-scale analysis of restoration activities, climate change, and fire regimes in the sagebrush-steppe. Specifically, we parameterized the sagebrush PFT within EDv2.2 to estimate gross primary production (GPP), using data from two sagebrush study sites in the northern Great Basin. To accomplish this, we employed a three-tier approach: 1) To initially parameterize the sagebrush PFT, we fitted allometric relationships for sagebrush using field-collected data, information from existing sagebrush literature, and parameters from other land models. 2) To determine influential parameters in GPP prediction, we used a sensitivity analysis to identify the five most sensitive parameters. 3) To improve model performance and validate results, we optimized these five parameters using an exhaustive search method to estimate GPP, and compared results with observations from two Eddy Covariance (EC) sites in the study area. Our modeled results were encouraging, with reasonable fidelity to observed values, although some negative biases (i.e., seasonal underestimates of GPP) were apparent.

Great Basin↗

Geologic map of the Butte City 7.5' Quadrangle, Butte County, Idaho

The geologic map of the Butte City 7.5’ quadrangle is based on mapping summarized in the 1:100,000 scale map of the Idaho National Laboratory, U.S. Geological Survey Miscellaneous Investigations Map I-2330, by Kuntz and others, 1994. New surficial geologic mapping was completed by National Association of Geoscience Teachers (NAGT) interns, Evan Martin (2015) and Samuel Helmuth (2017). Previously published maps and associated data, by various authors, including Kuntz, M.A., Betty Skipp, M.A. Lanphere, W.E. Scott, K.L. Pierce, G.B. Dalrymple, L.A. Morgan, D.E. Champion, G.F. Embree, W.R. Page, R.P. Smith, W.R. Hackett, and D.W. Rodgers from 1994 to 2017, were incorporated into this project. The U. S. Geological Survey (USGS) Idaho National Laboratory Project Office, a field office of the Idaho Water Science Center, conducts subsurface investigations to study the Snake River aquifer at the Idaho National Laboratory. Many subsurface basalts erupted from vents exposed at the surface. Tracing the flows from the surface to the subsurface provides data for numerical models of groundwater flow and contaminant transport.

Idaho↗

Depositional and diagenetic history and petroleum geology of the Jurassic Norphlet Formation of the Alabama coastal waters area and adjacent federal waters area

The discovery of deep (>20,000 ft) gas reservoirs in eolian sandstone of the Upper Jurassic Norphlet Formation in Mobile Bay and offshore Alabama in the late 1970s represents one of the most significant hydrocarbon discoveries in the nation during the past several decades. Estimated original proved gas from Norphlet reservoirs in the Alabama coastal waters and adjacent federal waters is 7.462 trillion ft3 (Tcf) (75% recovery factor). Fifteen fields have been established in the offshore Alabama area. Norphlet sediment was deposited in an arid environment in alluvial fans, alluvial plains, and wadis in updip areas. In downdip areas, the Norphlet was deposited in a broad desert plain, with erg development in some areas. Marine transgression, near the end of Norphlet deposition, resulted in reworking of the upper part of the Norphlet Formation. Norphlet reservoir sandstone is arkose and subarkose, consisting of a simple assemblage of three minerals, quartz, albite, and K-feldspar. The present framework grain assemblage of the Norphlet is dominantly diagenetic, owing to albitization and dissolution of feldspar. Despite the simple framework composition, the diagenetic character of the Norphlet is complex. Important authigenic minerals include carbonate phases (calcite, dolomite, Fe-dolomite, and breunnerite), feldspar (albite and K-feldspar), evaporite minerals (anhydrite and halite), clay minerals (illite and chlorite), quartz, and pyrobitumen. The abundance and distribution of these minerals varies significantly between onshore and offshore regions of Norphlet production. The lack of sufficient internal sources of components for authigenic minerals, combined with unusual chemical compositions of chloride (Mg-rich), breunnerite, and some minor authigenic minerals, suggests that Louann-derived fluids influenced Norphlet diagenesis. In offshore Alabama reservoirs, porosity is dominantly modified primary porosity. Preservation of porosity in deep Norphlet reservoirs is due to a combination of factors, including a lack of sources of cement components and lack of pervasive early cement, so that fluid-flow pathways remained open during burial. Below the dominantly quartz-cemented tight zone near the top of the Norphlet, pyrobitumen is a major contributor to reduction in reservoir quality in offshore Alabama. The highest reservoir quality occurs in those wells where the present gas-water contact is below the paleohydrocarbon-water contact. Thiz zone of highest reservoir quality is between the lowermost occurrence of pyrobitumen and the present gas-water contact.The Upper Jurassic Norphlet Formation sediment was deposited in an arid environment in alluvial fans, alluvial plains, and wadis in undip areas. In downdip areas, the Norphlet was deposited in a broad desert plain, with erg development in some areas. Marine transgression, near the end of Norphlet deposition resulted in reworking of the upper part of the formation. he present framework grain assemblage of the Norphlet is dominantly diagenetic, owing to albitization and dissolution of feldspar. Despite the simple framework composition, the diagenetic character of the Norphlet is complex.

Marine Georesources and Geotechnology↗

Remote sensing and GIS technology in the Global Land Ice Measurements from Space (GLIMS) Project

Global Land Ice Measurements from Space (GLIMS) is an international consortium established to acquire satellite images of the world's glaciers, analyze them for glacier extent and changes, and to assess these change data in terms of forcings. The consortium is organized into a system of Regional Centers, each of which is responsible for glaciers in their region of expertise. Specialized needs for mapping glaciers in a distributed analysis environment require considerable work developing software tools: terrain classification emphasizing snow, ice, water, and admixtures of ice with rock debris; change detection and analysis; visualization of images and derived data; interpretation and archival of derived data; and analysis to ensure consistency of results from different Regional Centers. A global glacier database has been designed and implemented at the National Snow and Ice Data Center (Boulder, CO); parameters have been expanded from those of the World Glacier Inventory (WGI), and the database has been structured to be compatible with (and to incorporate) WGI data. The project as a whole was originated, and has been coordinated by, the US Geological Survey (Flagstaff, AZ), which has also led the development of an interactive tool for automated analysis and manual editing of glacier images and derived data (GLIMSView). This article addresses remote sensing and Geographic Information Science techniques developed within the framework of GLIMS in order to fulfill the goals of this distributed project. Sample applications illustrating the developed techniques are also shown. ?? 2006 Elsevier Ltd. All rights reserved.

Computers & Geosciences↗

Trace element geochemistry and surface water chemistry of the Bon Air coal, Franklin County, Cumberland Plateau, southeast Tennessee

Mean contents of trace elements and ash in channel, bench-column, and dump samples of the abandoned Bon Air coal (Lower Pennsylvanian) in Franklin County, Tennessee are similar to Appalachian COALQUAL mean values, but are slightly lower for As, Fe, Hg, Mn, Na, Th, and U, and slightly higher for ash, Be, Cd, Co, Cr, REEs, Sr, and V, at the 95% confidence level. Compared to channel samples, dump sample means are slightly lower in chalcophile elements (As, Cu, Fe, Ni, Pb, S, Sb, and V) and slightly higher in clay or heavy-mineral elements (Al, K, Mn, REEs, Th, Ti, U, and Y), but at the 95% confidence level, only As and Fe are different. Consistent abundances of clay or heavy-mineral elements in low-Br, high-S, high-ash benches that are relatively enriched in quartz and mire-to-levee species like Paralycopodites suggest trace elements are largely fluvial in origin. Factor analysis loadings and correlation coefficients between elements suggest that clays host most Al, Cr, K, Ti, and Th, significant Mn and V, and some Sc, U, Ba, and Ni. Heavy accessory minerals likely house most REEs and Y, lesser Sc, U, and Th, and minor Cr, Ni, and Ti. Pyrite appears to host As, some V and Ni, and perhaps some Cu, but Cu probably exists largely as chalcopyrite. Data suggest that organic debris houses most Be and some Ni and U, and that Pb and Sb occur as Pb-Sb sulfosalt(s) within organic matrix. Most Hg, and some Mn and Y, appear to be hosted by calcite, suggesting potential Hg remobilization from original pyrite, and Hg sorption by calcite, which may be important processes in abandoned coals. Most Co, Zn, Mo, and Cd, significant V and Ni, and some Mn probably occur in non-pyritic sulfides; Ba, Sr, and P are largely in crandallite-group phosphates. Selenium does not show organic or "clausthalite" affinities, but Se occurrence is otherwise unclear. Barium, Mn, Ni, Sc, U, and V, with strongly divided statistical affinities, likely occur subequally in multiple modes. For study area surface waters, highest levels of most trace elements occur in mine-adit or mine-dump drainage. Effluent flow rates strongly affect both acidity and trace element levels. Adit drainages where flow is only a trickle have the most acidic waters (pH 3.78-4.80) and highest trace element levels (up to two orders of magnitude higher than in non-mine site waters). Nonetheless, nearly all surface waters have low absolute concentrations of trace elements of environmental concern, and all waters sampled meet U.S. EPA primary drinking water standards and aquatic life criteria for all elements analyzed. Secondary drinking water standards are also met for all parameters except Al, pH, Fe, and Mn, but even in extreme cases (mine waters with pH as low as 3.78 and up to 1243 ppb Al, 6280 ppb Fe, and 721 ppb Mn, and non-mine dam-outflow waters with up to 18,400 ppb Fe and 1540 ppb Mn) downslope attenuation is apparently rapid, as down-drainage plateau-base streams show background levels for all these parameters. ?? 2005 Elsevier B.V. All rights reserved.

International Journal of Coal Geology↗