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USGS2004

Chester County ground-water atlas, Chester County, Pennsylvania

Chester County encompasses 760 square miles in southeastern Pennsylvania. Groundwater-quality studies have been conducted in the county over several decades to address specific hydrologic issues. This report compiles and describes water-quality data collected during studies conducted mostly after 1990 and summarizes the data in a county-wide perspective. In this report, water-quality constituents are described in regard to what they are, why the constituents are important, and where constituent concentrations vary relative to geology or land use. Water-quality constituents are grouped into logical units to aid presentation: water-quality constituents measured in the field (pH, alkalinity, specific conductance, and dissolved oxygen), common ions, metals, radionuclides, bacteria, nutrients, pesticides, and volatile organic compounds. Water-quality constituents measured in the field, common ions (except chloride), metals, and radionuclides are discussed relative to geology. Bacteria, nutrients, pesticides, and volatile organic compounds are discussed relative to land use. If the U.S. Environmental Protection Agency (USEPA) or Chester County Health Department has drinking water standards for a constituent, the standards are included. Tables and maps are included to assist Chester County residents in understanding the water-quality constituents and their distribution in the county. Ground water in Chester County generally is of good quality and is mostly acidic except in the carbonate rocks and serpentinite, where it is neutral to strongly basic. Calcium carbonate and magnesium carbonate are major constituents of these rocks. Both compounds have high solubility, and, as such, both are major contributors to elevated pH, alkalinity, specific conductance, and the common ions. Elevated pH and alkalinity in carbonate rocks and serpentinite can indicate a potential for scaling in water heaters and household plumbing. Low pH and low alkalinity in the schist, quartzite, and gneiss rocks can indicate a potential for corrosive water. The only constituent measured in the field that has a USEPA Secondary Maximum Contaminant Level (SMCL) is pH. The SMCL for pH is 6.5-8.5; 64 percent of samples analyzed for pH were acidic (below pH 6.5). Only 1 percent of samples were basic (above pH 8.5). Of the common ions, the USEPA has SMCLs for chloride, sulfate, and total dissolved solids. The USEPA has a SMCL and a Primary Maximum Contaminant Level (PMCL) for fluoride. Chloride is more closely related to land use than geology. In Chester County, chloride exceeded the SMCL (250 mg/L) only in 5 percent of the services (commercial services, community services, and military) land-use areas. No samples analyzed for sulfate exceeded the SMCL (250 mg/L). Only 3 percent of samples analyzed for total dissolved solids exceeded the SMCL (500 milligrams per liter) (mg/L). No samples analyzed for fluoride equaled or exceeded the SMCL (2.0 mg/L) or PMCL (4.0 mg/L). Iron concentrations exceeded the USEPA SMCL in 11 percent of samples and were highest in schist (14 percent) and gneiss (13 percent). Manganese concentrations exceeded the SMCL in 19 percent of samples and were highest in quartzite and schist (both 28 percent). Lead and arsenic were present in low concentrations: the highest concentrations of lead occurred in water from quartzite (8 percent exceeded the USEPA Action Level), and arsenic was detected mostly in Triassic sedimentary rocks (9 percent exceeded the USEPA PMCL). The highest concentrations of copper occurred more frequently in quartzite rocks, and to a lesser extent were evenly distributed between ground water in gneiss, schist, and Triassic sedimentary rocks. Elevated concentrations of radon-222 and the combined radium-226/radium-228 radionuclides were common in water from quartzite and schist. Gross alpha and gross beta particle activities were elevated in water from quartzite and carbonate rocks. In contrast, elevated concentrations of uranium primarily were measured in water from Triassic sedimentary and carbonate rocks. Despite a sampling bias towards agricultural land use, only two samples indicated the presence of fecal coliforms. Samples analyzed for nutrients generally exhibited low concentrations, but about 11 percent of samples collected for nitrate exceeded the USEPA PMCL. Only one nitrite sample (less than 1 percent) exceeded the respective USEPA PMCL. Approximately 190 samples were collected for each of the three pesticides in this report: lindane, dieldrin, and diazinon. Sampling was biased towards agricultural, low-medium density residential, and wooded land uses. Approximately 95 percent of samples for each pesticide were below minimum reporting levels (MRL). Only lindane has a USEPA PMCL, and only one sample exceeded the standard. Results for dieldrin and diazinon were similar, except results for two diazinon samples where concentrations were 57.0 and 490 micrograms per liter (μg/L). Volatile organic compounds in this report were analyzed in water from 198 samples. Sampling was biased towards agricultural, low-medium density residential, and wooded land uses. Two percent of samples analyzed for trichloroethylene and less than 1 percent of samples analyzed for tetrachloroethylene exceeded their respective USEPA PMCLs (each 5.0 μg/L). No samples analyzed for 1,1,1-trichloroethane exceeded the USEPA PMCL (200 μg/L). No samples analyzed for methyl tert-butyl ether exceeded the USEPA Drinking Water Advisory (20μg/L).

Open-File Report↗

USGS1979

Records of selected wells, springs, and test holes, in the Royal, upper Presumpscot, and upper Saco River basins in Maine

The area discussed in this report includes about 1200 square miles in southwestern Maine. Location of the area is shown on the cover, and a sketch map identifying the topographic quadrangles for the study area is given in figure 1. The northern boundary of the area is the divide between the Androscoggin River drainage basin on the north and the Saco, Presumpscot, and Royal River drainage basins on the south. The western boundary is the Maine-New Hampshire State line, and the southwestern boundary is the Little Ossipee River. The southeastern boundary is the mid-latitude of the Gray and Freeport 15-minute topographic quadrangles. The greatest part of the area is in Cumberland and Oxford Counties, a smaller area is in York County, and a small fraction is in Androscoggin County. Included are parts or all of 15 towns in Cumberland County, 15 towns in Oxford County, 5 towns in York County, and 2 towns in Androscoggin County. The report contains geologic and hydrologic data collected as part of an investigation of the surficial geology and ground-water resources made by the U.S. Geological Survey in cooperation with the Maine Public Utilities Commission. These data are made available for use in planning the development of natural resources. An interpretive report containing maps of surficial geology and ground-water availability and related geologic and hydrologic information will be published in the Survey's Water-Resources Investigations series.

Maine↗

USGS1994

Isotopic composition of Pb in ore deposits of the Betic Cordillera, Spain; origin and relationship to other European deposits

The Betic Cordillera in southern Spain is a complex Alpine fold belt that resulted from the Cretaceous through Cenozoic collision of Africa with Europe. The region is illustrative of one of the characteristics of the Alpine-Mediterranean orogen: the occurrence over a limited area of mineral deposits with a wide variety of host rocks, mineralization ages, and styles. The metamorphic basement in the Betic zone is characterized by a nappe structure of superimposed tectonostratigraphic units and consists of lower Paleozoic to Lower Triassic clastic metasedimentary rocks. This is overlain by Middle to Upper Triassic platform carbonate rocks with abundant strata-bound F-Pb-Zn-(Ba) deposits (e.g., Sierra de Gador, Sierra Alhamilla). Cretaceous to Paleogene subduction-related compression in southeastern Spain was followed by Miocene postcollisional extension and resulted in the formation of the Almeria-Cartagena volcanic belt and widespread hydrothermal activity and associated polymetallic mineralization. Typical Miocene hydrothermal deposits include volcanic-hosted Au (e.g., Rodalquilar) and Ag-rich base metal (e.g., Cabo de Gata, Mazarron) deposits as well as complex polymetallic veins, mantos, and irregular replacement bodies which are hosted by Paleozoic and Mesozoic metamorphic rocks and Neogene sedimentary and volcanic rocks (e.g., Cartagena, Sierra Almagrera, Sierra del Aguilon, Loma de Bas).Lead isotope compositions were measured on sulfide samples from nine ore districts and from representative fresh samples of volcanic and basement rock types of the region. The results have been used to evaluate ore-forming processes in southeastern Spain with emphasis on the sources of metals. During a Late Triassic mineralizing event, Pb was leached from Paleozoic clastic metasedimentary rocks and incorporated in galena in strata-bound F-Pb-Zn-(Ba) deposits ( 206 Pb/ 204 Pb = 18.332 + or - 12, 207 Pb/ 204 Pb = 15.672 + or - 12, 208 Pb/ 204 Pb = 38.523 + or - 46). The second episode of mineralization was essentially contemporaneous (late Miocene) throughout the region and did not involve remobilization of less radiogenic Triassic ore Pb. Lead isotope data indicate a dominantly Paleozoic metasedimentary source for polymetallic vein- and manto-type deposits that formed by hydrothermal circulation through the Betic basement, driven by Miocene intrusions ( 206 Pb/ 204 Pb = 18.747 + or - 20, 207 Pb/ 204 Pb = 15.685 + or - 9, 208 /Pb/ 204 Pb = 39.026 + or - 37). Lead in Au-(Cu-Te-Sn) ores is isotopically indistinguishable from that of the calc-alkalic volcanic host ( 206 Pb/ 204 Pb = 18.860 + or - 9, 207 Pb/ 204 Pb = 15.686 + or - 8, 208 Pb/ 204 Pb = 38.940 + or - 27). In contrast, the Pb in volcanic-hosted Pb-Zn-Cu-(Ag-Au) veins was derived from Paleozoic metamorphic and Miocene volcanic rocks ( 206 Pb/ 204 Pb = 18.786 + or - 5, 207 Pb/ 204 Pb = 15.686 + or - 2, 208 Pb/ 204 Pb = 38.967 + or - 9).A comparison of the Pb isotope data from southeastern Spain with published data from selected Pb-Zn deposits in southern Europe (including Les Malines, L'Argentiere, and the Alpine, Iglesiente-Sulcis, and Montagne Noire districts) indicates the importance of a metasedimentary basement as a common source of ore Pb.

Economic Geology↗

USGS2005

Variability of differences between two approaches for determining ground-water discharge and pumpage, including effects of time trends, Lower Arkansas River Basin, southeastern Colorado, 1998-2002

In the mid-1990s, the Colorado Division of Water Resources (CDWR) adopted rules governing measurement of tributary ground-water pumpage for the Arkansas River Basin. The rules allowed ground-water pumpage to be determined using one of two approaches?power conversion coefficient (PCC) or totalizing flowmeters (TFM). In addition, the rules allowed a PCC to be applied to the electrical power usage up to 4 years in the future to estimate ground-water pumpage. As a result of concerns about potential errors in applying the PCC approach forward in time, a study was done by the U.S. Geological Survey, in cooperation with CDWR and Colorado Water Conservation Board, to evaluate the variability in differences in pumpage between the two approaches, including the effects of time trends. This report compared measured ground-water pumpage using TFMs to computed ground-water pumpage using PCCs by developing statistical models of relations between explanatory variables, such as site, time, and pumping water level, and dependent variables, which are based on discharge, PCC, and pumpage. When differences in pumpage (diffP) were computed using PCC measurements and power consumption for the same year (1998-2002), the median diffP, depending on the year, ranged from +0.1 to -2.9 percent; the median diffP for the entire period was -1.5 percent. However, when diffP was computed using PCC measurements applied to the next year's power consumption, the median diffP was -0.3 percent; and when PCC measurements were applied 2, 3, or 4 years into the future, median diffPs were +1.8 percent for a 2-year forward lag and +5.3 percent for a 4-year forward lag, indicating that pumpage computed with the PCC approach, as generally applied under the ground-water pumpage measurement rules by CDWR, tended to overestimate pumpage as compared to pumpage using TFMs when PCC measurement was applied to future years of measured power consumption. Analyses were done to better understand the causes of the time trend; an estimate of the overall trend with time (uncorrected for pumping water-level changes) yielded a trend of about 2.2 percent per lag year for diffP. A separate analysis that incorporated a surface-water diversion term in the statistical model rendered the time-trend term insignificant, indicating that the time trend in the models served as a surrogate for other variables, some of which reflect underlying hydrologic conditions. A more precise explanation of the potential causes of the time trend was not obtained with the available data. However, the model results with the surface-water diversion term indicate that much of the trend of 2.2 percent per lag year in diffP resulted from applying a PCC to estimate pumpage under hydrologic conditions different from those under which the PCC was measured. Although there is no evidence to conclude that the upward time trend determined in the data for this 5-year period would hold in the future, historical static ground-water levels in the study area generally have exhibited small variations over multidecadal time scales. Therefore, the approximately 2 percent per lag year trend determined in these data is expected to be a reasonable guideline for estimating potential errors in the PCC approach resulting from temporally varying hydrologic conditions between time of PCC measurement and pumpage estimation. Comparisons also were made between total, or aggregated, pumpage for a network of wells as computed by the PCC approach and the TFM approach. For 100 wells and a lag of 4 years between PCC measurement and pumpage estimation, there was a 95-percent probability that the difference between total network pumpage measured by the PCC approach and that measured using a TFM would be between 5.2 and 14.4 percent. These estimates were based on a bias of 2.2 percent per lag year estimated for the period 1998-2002 during which hydrologic conditions were known to have changed. Using the same assumptions, the estimated d

Scientific Investigations Report↗

USGS2017

Riverine discharges to Chesapeake Bay: Analysis of long-term (1927–2014) records and implications for future flows in the Chesapeake Bay basin

The Chesapeake Bay (CB) basin is under a total maximum daily load (TMDL) mandate to reduce nitrogen, phosphorus, and sediment loads to the bay. Identifying shifts in the hydro-climatic regime may help explain observed trends in water quality. To identify potential shifts, hydrologic data (1927–2014) for 27 watersheds in the CB basin were analyzed to determine the relationships among long-term precipitation and stream discharge trends. The amount, frequency, and intensity of precipitation increased from 1910 to 1996 in the eastern U.S., with the observed increases greater in the northeastern U.S. than the southeastern U.S. The CB watershed spans the north-to-south gradient in precipitation increases, and hydrologic differences have been observed in watersheds north relative to watersheds south of the Pennsylvania—Maryland (PA-MD) border. Time series of monthly mean precipitation data specific to each of 27 watersheds were derived from the Precipitation-elevation Regression on Independent Slopes Model (PRISM) dataset, and monthly mean stream-discharge data were obtained from U.S. Geological Survey streamgage records. All annual precipitation trend slopes in the 18 watersheds north of the PA-MD border were greater than or equal to those of the nine south of that border. The magnitude of the trend slopes for 1927–2014 in both precipitation and discharge decreased in a north-to-south pattern. Distributions of the monthly precipitation and discharge datasets were assembled into percentiles for each year for each watershed. Multivariate correlation of precipitation and discharge within percentiles among the groups of northern and southern watersheds indicated only weak associations. Regional-scale average behaviors of trends in the distribution of precipitation and discharge annual percentiles differed between the northern and southern watersheds. In general, the linkage between precipitation and discharge was weak, with the linkage weaker in the northern watersheds compared to those in the south. On the basis of simple linear regression, 26 of the 27 watersheds are projected to have higher annual mean discharge in 2025, the target date for implementation of the TMDL for the CB basin.

Chesapeake Bay Basin↗

USGS2008

Flood of April 2007 in New Hampshire

During April 16-18, 2007, central and southeastern New Hampshire experienced severe flooding as a result of up to 7 inches of rainfall from a storm that stalled off the New England coast. As a result of the flooding, a Presidential Disaster Declaration was issued on April 27, 2007. On that day, disaster declarations were announced for Grafton, Hillsborough, Merrimack, Rockingham, and Strafford Counties. On May 10, 2007, Belknap County was added to the disaster declaration. Following the flooding, the U.S. Geological Survey, in a cooperative investigation with the Federal Emergency Management Agency, determined the peak stages, peak discharges, and recurrence-interval estimates of the April 2007 flood at 57 streamgages and 4 ungaged sites in and adjacent to the counties named in the disaster declaration. Data from flood-insurance studies published by the Federal Emergency Management Agency also were compiled for each streamgage site for comparison purposes. The peak discharges during the April 2007 flood were the highest ever recorded at five long-term (more than 10 years of record) streamgage sites on the New Hampshire-Salmon Falls River at Milton, Cocheco River near Rochester, Oyster River near Durham, Contoocook River at Peterborough, and South Branch Piscataquog River near Goffstown. In addition, peak discharges equaled or exceeded a 100-year recurrence interval at 10 streamgages and a 50-year recurrence interval at 16 streamgages. The most severe flooding occurred in Rockingham, Strafford, Merrimack, and Hillsborough Counties.

Scientific Investigations Report↗

USGS2021

Estimates of water use associated with continuous oil and gas development in the Permian Basin, Texas and New Mexico, 2010–19, with comparisons to the Williston Basin, North Dakota and Montana

The Permian Basin, in west Texas and southeastern New Mexico is one of the largest conventional oil and gas reservoirs in the United States and is becoming one of the world’s largest continuous oil and gas (COG) reservoirs. Advances in technology have enabled oil and gas to be extracted from reservoirs that historically were developed using conventional, or vertical, well drilling techniques. Conventional oil and gas reservoirs have discrete deposits that are well defined and are typically trapped by an overlying geologic formation or caprock, whereas COG reservoirs contain deposits that are distributed evenly throughout the geologic formation, typically have much lower permeability (the capacity of a porous rock to transmit a fluid) than the conventional deposits, and require specialized horizontal extraction techniques. The methods to extract the oil from the two different reservoirs require differing amounts of water, and the horizontal extraction methods typically require substantially more water. In 2015, the U.S. Geological Survey started a topical study to quantify water used during COG development. The Permian Basin, which contains both types of reservoirs (continuous and conventional), was the second basin in the United States in the U.S. Geological Survey’s topical study to quantify water used during COG development.

Montana, New Mexico, North Dakota, Texas↗

USGS1995

Physical characteristics of stream subbasins in the upper Minnesota River basin, west-central Minnesota, northeastern South Dakota and southeastern North Dakota

Data that describe the physical characteristics of stream subbasins upstream from selected points on streams in the Upper Minnesota River Basin, located in west-central Minnesota, north-eastern South Dakota, and southeastern North Dakota, are presented in this report. The physical characteristics are the drainage area of the subbasin, the percentage area of the subbasin covered only by lakes, the percentage area of the subbasin covered by both laker and wetlands, the main-channel length, and the main-channel slope. The points on the stream include outlets of subbasins of at least 5 square miles, outlets of sewage treatment plants, and locations of U.S. Geological Survey low-flow, highflow, and continuous-record gaging stations.

Minnesota, North Dakota, South Dakota↗

USGS1979

Geologic map of the Cebrenia quadrangle of Mars

Most of the Cebrenia quadrangle (lat 30˚ to 65˚ N., long 180˚ to 240˚ W.) is in the circumpolar plains of Mars. Craters from an early episode of intense bombardment have been largely obliterated by later volcanism, tectonism, erosion, and sedimentation by wind and water, and by circumpolar glacial and periglacial processes. South of 47˚ N. the plains are dissected by numerous channels, most of which drained off a broad volcanic upland near the southern border of the quadrangle. The impressive Elysium volcanoes cap the crest of this upland; their northernmost member, Hecates Tholus, lies within the Cebrenia quadrangle. The southeastern part of the Cebrenia quadrangle is dominated by the Phlegra Montes, which may be the only purely tectonic mountain range on Mars. It seems to have been formed by block faulting; there is no evidence that impact of volcanic processes played a role. An ancient pediment appears to have been uplifted by normal faults to form a north- to north-northeast-trending mountain range 1,400 km long, as much as 250 km wide, and more than 1 km high. Its foothills are partly covered by later volcanic and eolian deposits.

IMAP↗

USGS2016

Use of lidar point cloud data to support estimation of residual trace metals stored in mine chat piles in the Old Lead Belt of southeastern, Missouri

Historic lead and zinc (Pb-Zn) mining in southeast Missouri’s ―Old Lead Belt‖ has left large chat piles dominating the landscape where prior to 1972 mining was the major industry of the region. As a result of variable beneficiation methods over the history of mining activity, these piles remain with large quantities of unrecovered Pb and Zn and to a lesser extent cadmium (Cd). Quantifying the residual content of trace metals in chat piles is problematic because of the extensive field effort that must go into collecting elevation points for volumetric analysis. This investigation demonstrates that publicly available lidar point data from the U.S. Geological Survey 3D Elevation Program (3DEP) can be used to effectively calculate chat pile volumes as a method of more accurately estimating the total residual trace metal content in these mining wastes. Five chat piles located in St. Francois County, Missouri, were quantified for residual trace metal content. Utilizing lidar point cloud data collected in 2011 and existing trace metal concentration data obtained during remedial investigations, residual content of these chat piles ranged from 9247 to 88,579 metric tons Pb, 1925 to 52,306 metric tons Zn, and 51 to 1107 metric tons Cd. Development of new beneficiation methods for recovering these constituents from chat piles would need to achieve current Federal soil screening standards. To achieve this for the five chat piles investigated, 42 to 72% of residual Pb would require mitigation to the 1200 mg/kg Federal non-playground standard, 88 to 98% of residual Zn would require mitigation to the Ecological Soil Screening level (ESSL) for plant life, and 70% to 98% of Cd would require mitigation to achieve the ESSL. Achieving these goals through an existing or future beneficiation method(s) would remediate chat to a trace metal concentration level that would support its use as a safe agricultural soil amendment.

Missouri↗

USGS2001

Science Plan, U.S. Geological Survey Florida District

This Science Plan has been prepared by the Florida District of the U.S. Geological Survey (USGS) as a tool to provide direction for the scientific work to be accomplished in the District during the next 5-10 years. A Science Plan can serve as a guide to determine the optimum use of the limited financial resources of the USGS in Florida to address water resource issues. The Florida District has four primary operational centers geographically distributed across the State, in Tallahassee, Orlando, Tampa, and Miami, with a laboratory in Ocala and field offices in Jacksonville and Fort Myers. Other USGS discipline offices in Florida are located in Gainesville (biology), St. Petersburg (geology), and Miami (restoration ecology) (fig.1). Although some differences exist in programs among the four water-resource offices because of differing physiographic settings and information needs, many common elements are present and these common elements are the focus of this District Science Plan. Science Plan development was based on other planning documents including individual Science Plans prepared by personnel in each of the four primary Florida water resource offices, and strategic planning documents of the Southeastern Region, Water Resources Discipline (WRD), and the USGS. A broad cross-section of District staff, representing all primary offices, a number of different scientific disciplines, and different programs of the District (data collection, investigations, and research) collaborated on the development of this Science Plan. As part of the development process, input was solicited from staff in every office and considered for inclusion in the plan. The Science Plan will be evaluated on an ongoing basis to ensure its continued relevancy to recognized water resources needs in Florida, and to guide future program development and collaboration with our existing and potential partners and customers, both within and outside the USGS.

Florida↗

USGS2017

Field-trip guide to the vents, dikes, stratigraphy, and structure of the Columbia River Basalt Group, eastern Oregon and southeastern Washington

The Columbia River Basalt Group covers an area of more than 210,000 km 2 with an estimated volume of 210,000 km 3 . As the youngest continental flood-basalt province on Earth (16.7–5.5 Ma), it is well preserved, with a coherent and detailed stratigraphy exposed in the deep canyonlands of eastern Oregon and southeastern Washington. The Columbia River flood-basalt province is often cited as a model for the study of similar provinces worldwide. This field-trip guide explores the main source region of the Columbia River Basalt Group and is written for trip participants attending the 2017 International Association of Volcanology and Chemistry of the Earth’s Interior (IAVCEI) Scientific Assembly in Portland, Oregon, USA. The first part of the guide provides an overview of the geologic features common in the Columbia River flood-basalt province and the stratigraphic terminology used in the Columbia River Basalt Group. The accompanying road log examines the stratigraphic evolution, eruption history, and structure of the province through a field examination of the lavas, dikes, and pyroclastic rocks of the Columbia River Basalt Group.

Oregon, Washington↗

USGS1996

Geohydrology and evaluation of stream-aquifer relations in the Apalachicola-Chattahoochee-Flint River basin, southeastern Alabama, northwestern Florida, and southwestern Georgia

The lower Apalachicola-Chattahoochee-Flint River Basin is underlain by Coastal Plain sediments of pre-Cretaceous to Quaternary age consisting of alternating units of sand, clay, sandstone, dolomite, and limestone that gradually thicken and dip gently to the southeast. The stream-aquifer system consists of carbonate (limestone and dolomite) and elastic sediments, which define the Upper Floridan aquifer and Intermediate system, in hydraulic connection with the principal rivers of the basin and other surface-water features, natural and man made. Separate digital models of the Upper Floridan aquifer and Intermediate system were con structed by using the U.S. Geological Survey's MODular Finite-Element model of two dimensional ground-water flow, based on conceptualizations of the stream-aquifer system, and calibrated to drought conditions of October 1986. Sensitivity analyses performed on the models indicated that aquifer hydraulic conductivity, lateral and vertical boundary flows, and pumpage have a strong influence on ground-water levels. Simulated pumpage increases in the Upper Floridan aquifer, primarily in the Dougherty Plain physiographic district of Georgia, caused significant reductions in aquifer discharge to streams that eventually flow to Lake Seminole and the Apalachicola River and Bay. Simulated pumpage increases greater than 3 times the October 1986 rates caused drying of some stream reaches and parts of the Upper Floridan aquifer in Georgia. Water budgets prepared from simulation results indicate that ground-water discharge to streams and recharge by horizontal and vertical flow are the principal mechanisms for moving water through the flow system. The potential for changes in ground-water quality is high in areas where chemical constituents can be mobilized by these mechanisms. Less than 2 percent of ground-water discharge to streams comes from the Intermediate system; thus, it plays a minor role in the hydrodynamics of the stream aquifer system.

Alabama, Florida, Georgia↗

USGS2019

Hydrogeologic characterization of part of the Lower Floridan aquifer at the South District Wastewater Treatment Plant, Miami-Dade County, Florida

The South District Wastewater Treatment Plant in southeastern Miami-Dade County, Florida, includes a Class I treated wastewater injection well system. The detection of ammonia in monitoring zones above the injection zone in the Lower Floridan aquifer has elicited a need to understand the nature of confinement within the Lower Floridan aquifer as it pertains to the vertical migration of injectate out of the injection zone upward into the Underground Source of Drinking Water in the upper part of the Floridan aquifer system. Geologic and geophysical data, borehole video imagery, and aquifer performance data were used to refine and clarify the geologic and hydrogeologic frameworks of part of the Lower Floridan aquifer at the treatment plant. The data provide evidence for zones of enhanced dissolution permeability, extensive secondary porosity, fractures, karst collapse structures, and faults that could provide vertical cross-formational fluid pathways that transect the Lower Floridan aquifer.

Florida↗

USGS1997

Hydrogeology and water quality of the West Valley Creek Basin, Chester County, Pennsylvania

The West Valley Creek Basin drains 20.9 square miles in the Piedmont Physiographic Province of southeastern Pennsylvania and is partly underlain by carbonate rocks that are highly productive aquifers. The basin is undergoing rapid urbanization that includes changes in land use and increases in demand for public water supply and wastewater disposal. Ground water is the sole source of supply in the basin. West Valley Creek flows southwest in a 1.5-mile-wide valley that is underlain by folded and faulted carbonate rocks and trends east-northeast, parallel to regional geologic structures. The valley is flanked by hills underlain by quartzite and gneiss to the north and by phyllite and schist to the south. Surface water and ground water flow from the hills toward the center of the valley. Ground water in the valley flows west-southwest parallel to the course of the stream. Seepage investigations identified losing reaches in the headwaters area where streams are underlain by carbonate rocks and gaining reaches downstream. Tributaries contribute about 75 percent of streamflow. The ground-water and surface-water divides do not coincide in the carbonate valley. The ground-water divide is about 0.5 miles west of the surface-water divide at the eastern edge of the carbonate valley. Underflow to the east is about 1.1 inches per year. Quarry dewatering operations at the western edge of the valley may act partly as an artificial basin boundary, preventing underflow to the west. Water budgets for 1990, a year of normal precipitation (45.8 inches), and 1991, a year of sub-normal precipitation (41.5 inches), were calculated. Streamflow was 14.61 inches in 1990 and 12.08 inches in 1991. Evapotranspiration was estimated to range from 50 to 60 percent of precipitation. Base flow was about 62 percent of streamflow in both years. Exportation by sewer systems was about 3 inches from the basin and, at times, equaled base flow during the dry autumn of 1991. Recharge was estimated to be 18.5 inches in 1990 and 13.7 inches in 1991. Ground-water quality in the basin reflects differences in lithology and has been affected by human activities. Ground water in the carbonate rocks is naturally hard, has a near neutral pH, and contains more dissolved solids and less dissolved iron, manganese, and radon-222 than ground water in the noncarbonate rocks, which is soft, with moderately acidic to acidic pH. Regional contamination by chloride and nitrate and local contamination by organic compounds and metals was detected. Natural background concentrations are estimated to be about 1 milligram per liter for nitrate as nitrogen and less than 3 milligrams per liter for chloride. Ground water in unsewered areas and agricultural areas of the basin has median concentrations of nitrate that are greater than those in ground water from other areas; septic system effluent and fertilizer are probable sources of elevated nitrate. Water samples from wells in urbanized areas contain greater concentrations of chloride than samples from wells in residential areas; road salt is the probable source of elevated chloride. Organic solvents, especially trichloroethylene, were detected in 30 percent of the wells sampled in the urbanized carbonate valley. Most of the organic solvents and some of the metals in ground water were detected near old industrial sites. Base-flow stream quality of West Valley Creek was determined at 15 sites from monthly sampling for 1 year. Differences in stream quality reflect differences in lithology, land use, and point sources in tributary subbasins and mainstem reaches. The chemical composition of base flow in the mainstem is dominated by ground-water discharge from carbonate rocks. Elevated concentrations of nitrate (greater than 3 milligrams per liter as nitrogen) in base flow were measured in a tributary draining agricultural land and in a tributary draining an unsewered residential area. Elevated concentrations of phosphate (greater than 0.5 milligrams per liter as phosphorus) were measured in a stream that receives treated sewage effluent. Discharge of water containing elevated sulfate (about 250 milligrams per liter) from quarry dewatering operations contributes to die increase in sulfate concentration (of 10 to 40 milligrams per liter) in base flow downstream from the quarry. The chloride load at all stream sites is greater than the load contributed by precipitation and mineral weathering to the basin, indicating anthropogenic sources of chloride throughout the basin. The diversity index of the benthic invertebrate community has increased since 1973 at the longterm biological monitoring site on West Valley Creek, indicating an improvement in stream quality. The improvement probably is related to controls on discharges and banning of pesticides, such as DOT, in the 1970's. Concentrations of dissolved constituents, except for chloride, determined for base flow in the autumn do not appear to have changed since 1971. Application of the seasonal Kendall test for trend indicates that concentrations of chloride in base flow have increased since 1971; this increase may be related to the increase in urbanization in the basin. The benthic community structure at the West Valley Creek site in 1991 indicates slight nutrient enrichment. Lithium was detected in ground water and surface water downgradient from two lithiumprocessing facilities. Until 1991, lithium was discharged into a losing reach of West Valley Creek, thus introducing lithium into the ground-water system. The potential for cross-contamination between the ground-water and surface-water systems is great, as demonstrated by the detection of lithium in ground water and surface water downstream and downgradient from the two lithium-processing facilities. The lithium that was discharged into the creek acts as a conservative tracer in gaining reaches of West Valley Creek, maintaining a mass balance and characteristic isotopic signature. Lithium-7/lithium-6 ratios were greater in streams that are affected by sewage and by lithium-processing discharges and in ground water downgradient from the lithium-processing facilities than natural background lithium isotopic ratios.

Pennsylvania↗

USGS2020

Accounting for temporal variability of streamflow in estimates of travel time

Retention, processing, and transport of solutes and particulates in stream corridors are influenced by the travel time of streamflow through stream channels, which varies dynamically with discharge. The effects of streamflow variability across sites and over time cannot be addressed by time-averaged models if parameters are based solely on the characteristics of mean streamflow. We develop methods to account for the effects of streamflow variability on travel time and compare our estimates to flow-weighted (“effective”) travel time at 100 streams in the southeastern United States. Velocity time series were generated for each stream from multiple-year (median 15.5 years), high-frequency (15 min interval) records of instantaneous streamflow and field measurements of velocity and inverted to produce time series of specific travel time [T/L]. The effective travel times for streams are 60–90% of the specific travel time of mean streamflow because a large fraction of the total streamflow volume is discharged during higher flows with higher velocities. We find that adjusting the specific travel time of mean streamflow at a site by a factor of 0.81 generally accounts for the effect of a skewed streamflow distribution, but at-site estimates of the coefficient of variation of streamflow are necessary to resolve differences in streamflow variability between streams or changes in variability over time. For example, the effective travel time of urban streams is less than the effective travel of forested streams in the southeastern United States as a result of increased streamflow variability in urban streams. Effective travel time accounts for both the variation in velocity with streamflow and the large fraction of streamflow discharged during high flows in most streams and provides time-averaged models with limited capability to account for effects of streamflow variability that otherwise they lack. This capability is needed for continental-scale modeling where streamflow variability is not uniform because of heterogeneous surficial geology, hydro-climatology, and vegetation and for applications where streamflow variability is not stationary as a response to climate change or hydrologic alteration.

Alabama, Georgia, North Carolina, Virginia, South ↗

USGS2023

Spatial and temporal distribution of sinuous ridges in southeastern Terra Sabaea and the northern region of Hellas Planitia, Mars

Sinuous ridges are an important yet understudied component of Mars' hydrologic history. We have produced a map of sinuous ridges, valleys and channels, and tectonic ridges across southeastern Terra Sabaea and into northern Hellas Planitia (10°-45° S, 35°-80° E) using a CTX mosaic. Although we mapped different types of ridges and negative relief features, the focus of this paper are the sinuous ridges. We present here a new dataset of sinuous ridges that includes basic morphometry (e.g., length, width, sinuosity), morphology, and the types of terrains they are located on. We chose our region of interest because it includes surface ages spanning Mars' geologic history, with emphasis on Noachian and Hesperian terrains. The shift from either a warm and wet or a cold and icy environment to our modern cold and dry climate occurred towards the end of the Noachian and into the Hesperian, a critical temporal window to characterize fluvial landforms. Our CTX-based mapping significantly improved the documentation of fluvial landforms within the study region, with over an order of magnitude increase in the number of valley networks and channels, and nearly 1700 sinuous ridges. Sinuous ridges are found in concentrated settings, with the majority (∼80%) located within impact craters and relatively few (∼20%) on the intercrater plains. Fluvial features are prevalent on Early and Middle Noachian-aged terrain but are relatively rare in the Late Noachian, signifying a shift in fluvial activity that likely led to a decrease in channel incision and subsequent inversion of relief. A subset of sinuous ridges—radial ridges in high-elevation, degraded craters— are possible records of ancient proglacial lakes. The youngest sinuous ridges are associated with intracrater alluvial fans in a narrow zone (∼12°S to 30°S and ∼ 62°E to 77°E). These formed in the Late Hesperian into the Amazonian, reflecting a later epoch of punctuated fluvial events driven by pre-existing topography and solar insolation.

Icarus↗

USGS1963

Distribution of fluorine in unaltered silicic volcanic rocks of the western conterminous United States

An investigation of more than 170 samples of glass-rich volcanic rocks of rhyolitic or rhyodacitic composition shows marked regional variations in the fluorine content. The uniformity of the class of rocks was controlled by index of refraction determinations on fused beads and by chemical analyses of about one-seventh of the total number. The fluorine content ranges from 20 to 4,900 ppm. The frequency distribution closely approaches a log-normal one; the median value is 520 ppm, the 90 percentile 1,820 ppm. The mean for 167 samples is 820 ppm. These correspond fairly well with earlier averages for similar types of rocks . The highest values are predominantly from a belt in central Colorado and west-central New Mexico, from the Big Bend region of Texas, and from southeastern Idaho and western Utah and northeastern Nevada. The distribution of the fluorine in these rocks correlates well with the distribution of significant fluorspar deposits and somewhat less well with areas where volcanic rocks are prevalent and ground waters carry large amounts of fluorine .

Economic Geology↗