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At least 901 records · Page 50Linked to original sources

The 2008 phreatomagmatic eruption of Okmok volcano, Aleutian Islands, Alaska: Chronology, deposits, and landform changes

Okmok volcano, Aleutian Islands, Alaska, explosively erupted over a five-week period between July 12 and August 23, 2008. The eruption was predominantly phreatomagmatic, producing fine-grained tephra that covered most of northeastern Umnak Island. The eruption had a maximum Volcanic Explosivity Index (VEI) of 4, with eruption column heights up to 16 km during the opening phase. Several craters and a master tuff cone formed in the caldera as a result of phreatomagmatic explosions and accumulated tephra-fall and surge deposits. Ascending magma continuously interacted with an extensive shallow groundwater table in the caldera, resulting in the phreatomagmatic character of the eruption. Syneruptive explosion and collapse processes enlarged a pre-existing lake, created a second, entirely new lake, and formed new, deep craters. A field of ephemeral collapse pits and collapse escarpments formed where rapid groundwater withdrawal removed material from beneath capping lava flows. This was the first significant phreatomagmatic event in the U.S. since the Ukinrek Maars eruption in 1977.

Alaska↗

Geological interpretation of combined Seabeam, Gloria and seismic data from Anegada Passage (Virgin Islands, north Caribbean)

The Anegada Passage (sensu lato) includes several basins and ridges from Southeast of Puerto Rico to the corner of the Virgin Islands Platform. Seabeam (Seacarib I) and Gloria long-range sidescan sonar surveys were carried out in this area. These new data allow us to propose an interpretation of the Anegada Passage. Most of the features described are related to wrench faulting: (a) St Croix and Virgin Islands Basins are pull-apart basins created in a right-lateral strike-slip environment based on their rhomboidal shape and seismic data (e.g. the flower structure). These two pull-aparts are divided into two sub-basins by a curvilinear normal fault in the Virgin Islands Basin and a right-lateral strike-slip fault in the St Croix Basin. (b) Tortola Ridge and a 'dog's leg' shaped structure are inferred to be restraining bends between two right-lateral strike-slip faults. (c) We identified two ENE-WSW volcanic lineaments in the eastern area and one volcano lying between Virgin Islands and St Croix Basins. (d) As shown by the seismic activity main wrench motion occurs along the north slope of Virgin Islands Basin and through Anegada Passage. A branching of this main fault transmits the transtensional motion to St Croix Basin. A two-stage story is proposed for the creation of the basins. A first extensional event during Eocene(?)-Oligocene-lower Miocene time created Virgin Islands, St Croix Basins and the tilted blocks of St Croix Ridge. A second transtensional event from Pliocene to Recent gave the present day pattern to this area. However, the displacement along the strike-slip faults is no more than 15 km long. The proposed geodynamic model is based on the separation of the northeastern Caribbean boundary into two blocks. In the West, the indenter of Beata Ridge gives a northeastern motion to Hispaniola Block. In the East, as a result of Hispaniola Block's motion, the Puerto Rico-Virgin Islands Block could escape in an east-northeast direction.

Anegada Passage↗

Characterization of a complex sand-rich gas hydrate reservoir system in the Indian marine continental margin with downhole log and seismic data

Logging-while-drilling (LWD) and coring data were acquired in Areas A, B, C and E during the National Gas Hydrate Program Expedition 02 (NGHP-02). At Sites NGHP-02-16, −17, −20, −23 and −24 of Area B in the Indian Krishna-Godavari Basin, the gas hydrate-bearing sand-rich reservoirs directly in contact with an underlying water-saturated sediment were revealed near the seismic-inferred bottom simulating reflector (BSR) along a large anticlinal structure. Lithofacies analysis of cores show that the lower gas hydrate-bearing reservoir section at these sites is an interbedded unit with thin fine-sand layers alternating with clay-rich layers. We reanalyzed the LWD data including resistivity, compressional-wave and shear-wave acoustic velocities to assess and compare the spatial variation of sand-hosted gas hydrate and possible related free-gas accumulations. The presence of free gas-bearing sediments in direct contact with gas hydrate-bearing sediments was confirmed at Sites NGHP-02-20 and −24 along the northeastern flank of the anticline. The sand-rich reservoirs associated with the Area B anticlinal feature reveal different pore-filling constituents and variable boundary conditions, including gas hydrate/water contacts and gas hydrate/free gas contacts. We infer that the sedimentary depositional history at Sites NGHP-02-20 and −24, may have resulted in an upward shift of the base of gas hydrate stability zone, that could have led to in situ gas hydrate dissociation and the accumulation of free gas and coexistence interval below the log-inferred gas hydrate-bearing reservoir sections. This study demonstrates that reservoir heterogeneity and fluid migration were major factors affecting the distribution of gas hydrate and free gas in the identified sand-rich reservoirs.

Journal of Marine and Petroleum Geology↗

Dating of Archean basement in northeastern Wyoming and southern Montana.

Rb-Sr whole-rock and U-Pb zircon ages of granite and gneiss cores from three deep drill holes extend known occurrences of Archean rocks in the subsurface of NE Wyoming and S Montanta. Rb-Sr and K- Ar mineral ages are discordant and reflect early or middle Proterozoic disturbance. Highly altered rocks occur in a thin zone immediately below the sub-Cambrian unconformity. Samples from a few metres deeper in the basement are much fresher but show the effects of this alteration in filled fractures and thin adjacent alteration haloes. Whole-rock Rb-Sr systems have retaioned a fair degree of integrity in spite of increased susceptibility to modification because of the disturbed mineral systems. Interaction of the rocks with water a few metres below the sub-Cambrian unconformity probably occurred for only a relatively short time. Fractures filled rapidly with secondary minerals such as chlorite, anhydrite, and carbonate to maintain a relatively impermeable crystalline basement in which the silicates and their contained isotopic systems were preserved.- Author

Geological Society of America Bulletin↗

Phosphatic zone in the lower part of the Maquoketa Shale in northeastern Iowa

The basal beds of the Maquoketa Shale in northeastern Iowa include a basal silty phosphorite layer that is thickest near Dubuque. In Clayton County, Iowa, the bed averages about 1 foot thick (30 centimeters) and contains 22.5 percent P 2 0 5 . Phosphatic dolomite that is 8 10 feet (2.4 3 meters) thick and occurs higher in the Maquoketa was observed only in Dubuque County. The thickest and most phosphatic rock in the Maquoketa appears to be coextensive with dark-brown shale, which also occurs mainly in Dubuque County. Rare-earth content of the phosphatic rock decreases southeastward across the area, ranging from 2,000 to about 120 parts per million. The thin low-grade phosphorite is typical of the platform-type phosphorite facies and may be' genetically related to the emergence of the Ozark uplift as an island late in the Ordovician period.

Iowa↗

Ordovician and middle Silurian rocks of the Wildhorse window, northeastern Pioneer Mountains, central Idaho

Along Wildhorse Creek in the northeastern Pioneer Mountains, autochthonous Ordovician and Silurian rocks of an eastern carbonate assemblage are exposed in a structural window through allochthonous flysch deposits of the Mississippian Copper Basin Group. Graptolite-bearing Middle and Upper Ordovician dolomite and cherty dolomite 210 ft (64 m) thick are lithologically and faunally similar to the Hanson Creek Formation of central Nevada and the Saturday Mountain Formation of central Idaho. Monograptus -bearing Middle Silurian platy limestone at least 130 ft (40 m) thick resembles the Roberts Mountains Formation of central Nevada and rocks improperly designated Trail Creek Formation in the Bayhorse region of central Idaho. Allochthonous age-equivalent units of a more western transitional assemblage (the type Phi Kappa and Trail Creek Formations) occur 5 mi (8 km) west of the Wildhorse window, along the crest of the Pioneer Mountains.

Idaho↗

Spatial variation in total element concentration in soil within the Northern Great Plains coal region and Regional soil chemistry in Bighorn and Wind River basins, Wyoming and Montana

PART A: To objectively determine the changes in chemical character of an area subjected to mining and reclamation, prior information is needed. This study represents a broadscale inventory of total chemical composition of the surficial materials of the Northern Great Plains coal region (western North and South Dakota, eastern Montana, and northeastern Wyoming); data are given for 41 elements in A and C soil horizons. An unbalanced, nested, analysis-of-variance design was used to quantify variation in total content of elements between glaciated and unglaciated terrains, for four increasingly smaller geographic scales, and to quantify variation due to sample preparation and analysis. From this statistical study, reliable maps on a regional basis (>100 km) were prepared for C, K, and Rb in A and C soil horizons; for N a, Si, Th, D, and Zn in A-horizon soil; and for As, Ca, Ge, and Mg in C-horizon soil. The distribution of variance components for the remaining 29 elements did not permit the construction of reliable maps. Therefore, a baseline value for each of these elements is given as a measure of the total element concentration in the soils of the Northern Great Plains coal region. The baseline is expressed as the 95-percent range in concentration to be expected in samples of natural soils. PART B: A reconnaissance study of total concentrations of 38 elements in samples of soils (0-40 cm deep, composite) from the Bighorn and Wind River Basins of Montana and Wyoming indicates that the geographic variation for most elements occurs locally (5 km or less). However, in the Bighorn Basin, Zn exhibits significant regional variation (between geologic units); and in the Wind River Basin, AI, Cr, K, Mn, Mo, Ni, U, and V exhibit similar variation. For the remaining elements, the lack of regional variation suggests that a single summary statistic can be used to estimate a baseline value that reflects the range in concentration to be expected in samples of soils in each basin. The concentrations of most of these elements in both basins are not much different from those measured independently in the Powder River Basin of Wyoming or in the Western United States. In addition, data from an analysis of variance provide an estimate of the number of random samples within an area of specified size (10 km square, approximately a township) that are needed to prepare a reliable map of total element concentration in soils for each of the elements in each of the basins.

Montana, North Dakota, Saskatchewan, South Dakota,↗

Use of dye tracing in water-resources investigations in Wyoming, 1967-94

During 1967-94, the U.S. Geological Survey made numerous applications of dye tracing for water-resources investigations in Wyoming. Many of the dye tests were done in cooperation with other agencies. Results of all applications, including some previously unpublished, are described. A chronology of past applications in Wyoming and a discussion of potential future applications are included. Time-of-travel and dispersion measurements were made in a 113-mile reach of the Wind/Bighorn River below Boysen Dam; a 117-mile reach of the Green River upstream from Fontenelle Reservoir and a 70-mile reach downstream; parts of four tributaries to the Green (East Fork River, 39 miles; Big Sandy River, 112 miles; Horse Creek, 14 miles; and Blacks Fork, 14 miles); a 75-mile reach of the Little Snake River along the Wyoming-Colorado State line; and a 95-mile reach of the North Platte River downstream from Casper. Reaeration measurements were made during one of the time-of-travel measurements in the North Platte River. Sixty-eight dye-dilution measurements of stream discharge were made at 22 different sites. These included 17 measurements for verifying the stage-discharge relations for streamflow-gaging stations on North and South Brush Creeks near Saratoga, and total of 29 discharge measurements at 12 new stations at remote sites on steep, rough mountain streams crossing limestone outcrops in northeastern Wyoming. The largest discharge measured by dye tracing was 2,300 cubic feet per second. In karst terrane, four losing streams-North Fork Powder River, North Fork Crazy Woman Creek, Little Tongue River, and Smith Creek-were dye-tested. In the Middle Popo Agie River, a sinking stream in Sinks Canyon State Park, a dye test verified the connection of the sink (Sinks of Lander Cave) to the rise, where flow in the stream resumes.

Water-Resources Investigations Report↗

Tectonic significance of the Kodiak-Bowie seamount chain, northeastern Pacific

The hypothesis of a fixed melting spot reference frame (M) for relative plate motion is tested in the northeastern Pacific Ocean, where the Kodiak-Bowie seamount chain intersects the northern triple junction between the Pacific, American, and Juan de Fuca plates. Available age determinations on Kodiak and Giacomini Seamounts provide an estimated average rate of volcanic propagation along the chain of 6.5 cm per yr and allow estimates of plate movements relative to the melting spot. The inferred motion of the American plate relative to M is close to that observed along the Yellowstone-Snake River Plain volcanic trend and broadly supports the concept of a fixed melting spot reference frame. However, the convex northward curvature of the Kodiak-Bowie chain and of several chains to the south does not support the hypothesis. The lack of parallelism between these seamounts and the Hawaiian chain suggests slow relative movement between the Kodiak-Bowie and Hawaiian melting spots.

Geology↗

Quaternary sediment thickness and bedrock topography of the glaciated United States east of the Rocky Mountains

Beginning roughly 2.6 million years ago, global climate entered a cooling phase known as the Pleistocene Epoch. As snow in northern latitudes compacted into ice several kilometers thick, it flowed as glaciers southward across the North American continent. These glaciers extended across the northern United States, dramatically altering the landscape they covered. East of the Rocky Mountains, the ice coalesced into continental glaciers (called the Laurentide Ice Sheet) that at times blanketed much of the north-central and northeastern United States. To the west of the Laurentide Ice Sheet, glaciers formed in the mountains of western Canada and the United States and coalesced into the Cordilleran ice sheet; this relatively smaller ice mass extended into the conterminous United States in the northernmost areas of western Montana, Idaho, and Washington. Throughout the Pleistocene, landscape alteration occurred by (1) glacial erosion of the rocks and sediments; (2) redeposition of the eroded earth materials in a form substantially different from their source rocks, in terms of texture and overall character; and (3) disruption of preexisting drainage patterns by the newly deposited sediments. In many cases, pre-glacial drainage systems (including, for example, the Mississippi River) were rerouted because their older drainage courses became blocked with glacial sediment. The continental glaciers advanced and retreated many times across those areas. During each ice advance, or glaciation, erosion and deposition occurred, and the landscape was again altered. Through successive glaciations, the landscape and the bedrock surface gradually came to resemble their present configurations. As continental ice sheets receded and the Pleistocene ended, erosion and deposition of sediment (for example in stream valleys) continued to shape the landscape up to the present day (albeit to a lesser extent than during glaciation). The interval of time since the last recession of the glaciers is called the Holocene and, together with the Pleistocene, constitutes the Quaternary Period of geologic time; this publication characterizes the three-dimensional geometry of the Quaternary sediments and the bedrock surface that lies beneath. The pre-glacial landscape was underlain mostly by weathered bedrock generally similar in nature to that found in many areas of the non-glaciated United States. Glacial erosion and redeposition of earth materials produced a young, mineral-rich soil that formed the basis for the highly productive agricultural economy in the U.S. midcontinent. Extensive buried sands and gravels within the glacial deposits also provided a stimulus to other economic sectors by serving as high-quality aquifers supplying groundwater to the region’s industry and cities. An understanding of the three-dimensional distribution of these glacial sediments has direct utility for addressing various societal issues including groundwater quality and supply, and landscape and soil response to earthquake-induced shaking. The Quaternary sediment thickness map and bedrock topographic map shown here provide a regional overview and are intended to supplement the more detailed work on which they are based. Detailed mapping is particularly useful in populated areas for site-specific planning. In contrast, regional maps such as these serve to place local, detailed mapping in context; to permit the extrapolation of data into unmapped areas; and to depict large-scale regional geologic features and patterns that are beyond the scope of local, detailed mapping. They also can enhance the reader’s general understanding of the region’s landscape and geologic history and provide a source of information for regional decision making that could benefit by improved predictability of bedrock depth beneath the unconsolidated Quaternary sediments. To enable these maps to be analyzed in conjunction with other types of information, this publication also includes the map data in GIS compatible format.

Scientific Investigations Map↗

Reconnaissance geology of the Precambrian rocks in the Bi'r Ghamrah quadrangle, Kingdom of Saudi Arabia

Three sequences of volcanic and sedimentary rocks are identified in the Precambrian rocks of the Bi'r Ghamrah quadrangle at the eastern edge of the Precambrian Shield in central Saudi Arabia. The oldest sequence is called the Bi'r Khountina Group. It consists of conglomerate marble, andesite, and graywacke. Unconformably overlying this group is a sequence of graywacke with minor lava called the Murdama Group. In a small area in the southern part of the quadrangle, these rocks are unconformably overlain by rhyolitic tuff and rhyolite tentatively correlated with the Shammar Rhyolite. The older of these sedimentary and volcanic rocks were intruded by diorite and gabbro and by a large pluton of alkalic granite. A contact metamorphic aureole was formed in the Bi'r Khountina and Murdama Groups adjacent to the granite, and feeder dikes of the Sbmmmar Rhyolite(?) intrude the granite. The Bi'r Khountina Group is folded into a south-plunging asymmetrical anticlinorium, the west limb of which is repeated across northwest-trending faults. The Murdama Group appears to have been folded along the same axes, but the contact aureole against the alkalic granite and the imprint of the west-northwest striking Najd fault zone cause the rocks of the Murdama Group to appear to trend westward. Results of spectrographic and chemical analyses of wadi sand, heavy-mineral concentrates, and detrital magnetite show small anomalies. The ultramafic rocks intruded prior to the deposition of the Murdama Group are the source of anomalous chromium and lanthanum and of threshold nickel, scandium, and vanadium. The intrusive rocks younger than the Murdama Group are sources for anomalous lead and threshold silver, boron, barium, beryllium, zirconium, lanthanum, and tin. One small ancient working, probably opened for gold, is present, and at least four places in the Precambrian part of the quadrangle ere potentially favorable for gold, silver, and lead. Chromite is a potential resource in the northeastern part of the quadrangle.

Open-File Report↗

Interpretation of a high-grade Precambrian terrane in northern Idaho

A terrane of high-grade metamorphic rocks in northern Idaho and northeastern Washington is almost completely surrounded by low-grade rocks of the Precambrian Belt Supergroup. The high-grade terrane includes both Belt and pre-Belt rocks. Four events of folding and metamorphism occurred in the high-grade terrane. The first three events may have been associated with the Late Cretaceous emplacement of quartz monzonite of the Kaniksu batholith; the fourth may have been associated with a slightly later emplacement of granodiorite or with a Tertiary plutonic and volcanic episode. A much older event of plutonism in the high-grade terrane is recorded by zircon, which was dated by the Pb-U method at 1,500 m.y. from pre-Belt meta-igneous augen gneiss. Evidence of regional events intermediate in age between 1,500 and 100 m.y. has been found in the surrounding low-grade rocks but not in the high-grade terrane.

Idaho↗

Catastrophic meltwater discharge down the Hudson Valley: A potential trigger for the Intra-Allerød cold period

Glacial freshwater discharge to the Atlantic Ocean during deglaciation may have inhibited oceanic thermohaline circulation, and is often postulated to have driven climatic fluctuations. Yet attributing meltwater-discharge events to particular climate oscillations is problematic, because the location, timing, and amount of meltwater discharge are often poorly constrained. We present evidence from the Hudson Valley and the northeastern U.S. continental margin that establishes the timing of the catastrophic draining of Glacial Lake Iroquois, which breached the moraine dam at the Narrows in New York City, eroded glacial lake sediments in the Hudson Valley, and deposited large sediment lobes on the New York and New Jersey continental shelf ca. 13,350 yr B.P. Excess 14 C in Cariaco Basin sediments indicates a slowing in thermohaline circulation and heat transport to the North Atlantic at that time, and both marine and terrestrial paleoclimate proxy records around the North Atlantic show a short-lived (<400 yr) cold event (Intra-Allerød cold period) that began ca. 13,350 yr B.P. The meltwater discharge out the Hudson Valley may have played an important role in triggering the Intra-Allerød cold period by diminishing thermohaline circulation.

Geology↗

Evaluation of factors affecting ice forces at selected bridges in South Dakota

During 1998-2002, the U.S. Geological Survey, in cooperation with the South Dakota Department of Transportation (SDDOT), conducted a study to evaluate factors affecting ice forces at selected bridges in South Dakota. The focus of this ice-force evaluation was on maximum ice thickness and ice-crushing strength, which are the most important variables in the SDDOT bridge-design equations for ice forces in South Dakota. Six sites, the James River at Huron, the James River near Scotland, the White River near Oacoma/Presho, the Grand River at Little Eagle, the Oahe Reservoir near Mobridge, and the Lake Francis Case at the Platte-Winner Bridge, were selected for collection of ice-thickness and ice-crushing-strength data. Ice thickness was measured at the six sites from February 1999 until April 2001. This period is representative of the climate extremes of record in South Dakota because it included both one of the warmest and one of the coldest winters on record. The 2000 and 2001 winters were the 8th warmest and 11th coldest winters, respectively, on record at Sioux Falls, South Dakota, which was used to represent the climate at all bridges in South Dakota. Ice thickness measured at the James River sites at Huron and Scotland during 1999-2001 ranged from 0.7 to 2.3 feet and 0 to 1.7 feet, respectively, and ice thickness measured at the White River near Oacoma/Presho site during 2000-01 ranged from 0.1 to 1.5 feet. At the Grand River at Little Eagle site, ice thickness was measured at 1.2 feet in 1999, ranged from 0.5 to 1.2 feet in 2000, and ranged from 0.2 to 1.4 feet in 2001. Ice thickness measured at the Oahe Reservoir near Mobridge site ranged from 1.7 to 1.8 feet in 1999, 0.9 to 1.2 feet in 2000, and 0 to 2.2 feet in 2001. At the Lake Francis Case at the Platte-Winner Bridge site, ice thickness ranged from 1.2 to 1.8 feet in 2001. Historical ice-thickness data measured by the U.S. Geological Survey (USGS) at eight selected streamflow-gaging stations in South Dakota were compiled for 1970-97. The gaging stations included the Grand River at Little Eagle, the White River near Oacoma, the James River near Scotland, the James River near Yankton, the Vermillion River near Wakonda, the Vermillion River near Vermillion, the Big Sioux River near Brookings, and the Big Sioux River near Dell Rapids. Three ice-thickness-estimation equations that potentially could be used for bridge design in South Dakota were selected and included the Accumulative Freezing Degree Day (AFDD), Incremental Accumulative Freezing Degree Day (IAFDD), and Simplified Energy Budget (SEB) equations. These three equations were evaluated by comparing study-collected and historical ice-thickness measurements to equation-estimated ice thicknesses. Input data required by the equations either were collected or compiled for the study or were obtained from the National Weather Service (NWS). An analysis of the data indicated that the AFDD equation best estimated ice thickness in South Dakota using available data sources with an average variation about the measured value of about 0.4 foot. Maximum potential ice thickness was estimated using the AFDD equation at 19 NWS stations located throughout South Dakota. The 1979 winter (the coldest winter on record at Sioux Falls) was the winter used to estimate the maximum potential ice thickness. The estimated maximum potential ice thicknesses generally are largest in northeastern South Dakota at about 3 feet and are smallest in southwestern and south-central South Dakota at about 2 feet. From 1999 to 2001, ice-crushing strength was measured at the same six sites where ice thickness was measured. Ice-crushing-strength measurements were done both in the middle of the winter and near spring breakup. The maximum ice-crushing strengths were measured in the mid- to late winter before the spring thaw. Measured ice-crushing strengths were much smaller near spring breakup. Ice-crushing strength measured at the six sites

Water-Resources Investigations Report↗

Trends in groundwater quality in principal aquifers of the United States, 1988-2012

The U.S. Geological Survey (USGS) National Water-Quality Assessment (NAWQA) Program analyzed trends in groundwater quality throughout the nation for the sampling period of 1988-2012. Trends were determined for networks (sets of wells routinely monitored by the USGS) for a subset of constituents by statistical analysis of paired water-quality measurements collected on a near-decadal time scale. The data set for chloride, dissolved solids, and nitrate consisted of 1,511 wells in 67 networks, whereas the data set for methyl tert -butyl ether (MTBE) consisted of 1, 013 wells in 46 networks. The 25 principal aquifers represented by these networks account for about 75 percent of withdrawals of groundwater used for drinking-water supply for the nation. Statistically significant changes in chloride, dissolved-solids, or nitrate concentrations were found in many well networks over a decadal period. Concentrations increased significantly in 48 percent of networks for chloride, 42 percent of networks for dissolved solids, and 21 percent of networks for nitrate. Chloride, dissolved solids, and nitrate concentrations decreased significantly in 3, 3, and 10 percent of the networks, respectively. The magnitude of change in concentrations was typically small in most networks; however, the magnitude of change in networks with statistically significant increases was typically much larger than the magnitude of change in networks with statistically significant decreases. The largest increases of chloride concentrations were in urban areas in the northeastern and north central United States. The largest increases of nitrate concentrations were in networks in agricultural areas. Statistical analysis showed 42 or the 46 networks had no statistically significant changes in MTBE concentrations. The four networks with statistically significant changes in MTBE concentrations were in the northeastern United States, where MTBE was widely used. Two networks had increasing concentrations, and two networks had decreasing concentrations. Production and use of MTBE peaked in about 2000 and has been effectively banned in many areas since about 2006. The two networks that had increasing concentrations were sampled for the second time close to the peak of MTBE production, whereas the two networks that had decreasing concentrations were sampled for the second time 10 years after the peak of MTBE production.

Book↗

Karstification without carbonic acid: Bedrock dissolution by gypsum- driven dedolomitization

Aggressive karstification can take place where dolomite and gypsum are in contact with the same aquifer. Gypsum dissolution drives the precipitation of calcite, thus consuming carbonate ions released by dolomite. Lake Banyoles, in northeastern Spain, is a karst lake supplied by sublacustrine springs, and karstic collapse is occurring in the immediate vicinity of the lake. Lake water is dominated by Mg-Ca and SO 4 -HCO 3 , and is supersaturated with calcite that is actively accumulating in lake sediments. Water chemistry, sulfur isotope composition, local stratigraphy, and mass-balance modelling suggest that the primary karst-forming process at at Lake Banyoles is dedolomitization of basement rocks driven by gypsum dissolution. Karstification takes place along the subsurface contact between the gypsiferous Beuda Formation and the dolomitic Perafita Formation. This process is here recognized for the first time to cause karstification on a large scale; this is significant because it proceeds without the addition of soil-generated carbonic acid. Gypsum-driven dedolomitization may be responsible for other karstic systems heretofore attributed to soil-generated carbonic acid.

Geology↗

Computation of bromide concentrations at the Kansas River at De Soto, Kansas, January 2021 through October 2023

The Kansas River is an essential water resource that provides drinking water to more than 950,000 people in northeastern Kansas. Water suppliers that rely on the Kansas River as a water-supply source use physical and chemical water-treatment strategies to remove contaminants before distribution. Water District No. 1 of Johnson County, Kansas (WaterOne), is the largest water supplier in the State and uses the Kansas and Missouri Rivers as water-supply sources to provide drinking water to the Kansas City metropolitan area. WaterOne has been using ozone disinfection as a primary water-treatment strategy since the summer of 2020. Water suppliers that rely on ozone disinfection have become increasingly concerned with the presence of elevated dissolved bromide (the negatively charged form of bromine; hereafter referred to as “bromide”) concentrations in their water-supply source. Ozone disinfection of source water containing elevated concentrations of bromide can lead to the formation of bromate, a regulated disinfection byproduct and probable carcinogen. Real-time computations of bromide concentrations upstream from the WaterOne source-water intake in the Kansas River can be used to assist WaterOne with proactive adjustment of water-treatment strategies. These computations can also be used to advance understanding of hydrologic processes affecting ozone disinfection and formation of bromate. This report documents the development of the surrogate-regression model that computes bromide concentrations in real time at De Soto, Kansas, and characterizes daily and monthly bromide concentrations at this location during the study period. The U.S. Geological Survey (USGS), in cooperation with WaterOne, collected specific conductance and discrete bromide sample data at the USGS streamgage Kansas River at De Soto, Kans. (06892350; hereafter referred to as “De Soto”), during January 2021 through October 2023 to develop a surrogate-regression model using ordinary least-squares regression that computes bromide concentrations at De Soto, which is about 15 miles upstream from the WaterOne source-water intake in the Kansas River. Specific conductance explained about 85 percent of the variance in bromide concentrations at De Soto during the study period. The surrogate-regression model documented in this report estimated that bromide concentrations at De Soto were likely to exceed the WaterOne water-treatment level of concern (150 micrograms per liter [μg/L]) when specific conductance was greater than or equal to about 930 microsiemens per centimeter at 25 degrees Celsius. Surrogate-regression model computations of bromide concentrations documented in this report are available at the USGS National Real-Time Water-Quality website ( https://nrtwq.usgs.gov/ ). Bromide concentrations in discrete samples ranged from 31.9 to 251 μg/L and exceeded the water-treatment level of concern in about 34 percent of the 41 samples collected at De Soto during January 2021 through October 2023. Computed daily bromide concentrations ranged from 38.2 to 277 μg/L and exceeded the water-treatment level of concern about 46 percent of the time during January 2021 through October 2023. Generally, an inverse relation was observed between bromide and streamflow during the study period. Higher bromide concentrations were observed during September through February, and lower bromide concentrations were observed during March through August. Seasonal median bromide concentrations were significantly different in all pairwise seasonal combinations, except for summer versus spring. Computed median bromide concentrations were highest during winter, followed by fall, then spring and summer.

Kansas↗

Evidence on the age mineralization in the of east of barite, zinc, and iron lower paleozoic rocks Tennessee

Based on a study of minor occurrences of zinc, barite, and iron in East Tennessee, certain deposits are interpreted to have formed during early Middle Ordovician time. Principal lines of evidence supporting this age are: (1) the occurrence of barite, sphalerite, and pyrite associated with synsedimentary collapse breccias which span the pre-Middle Ordovician unconformity at the Lost Creek barite mine in Union County; (2) barite in basal Middle Ordovician beds (Athens Shale and Lenoir Limestone) in northeastern Tennessee and southwestern Virginia; (3) sphalerite and pyrite in dolomite filling paleocaves in the uppermost part of the Lower Ordovician Mascot Dolomite at the Trotter prospect near Douglas Dam in Sevier County; and (4) oolitic hematite and pyritiferous beds near the base of the Athens Shale and subjacent pyritiferous collapse breccias in the Mascot and Kingsport Formations at several localities along the eastern side of the Appalachian Valley. Thus, it is concluded that ascending solutions formed epigenetic deposits in pre-Middle Ordovician carbonate strata nearly contemporaneously with syngenetic deposits in early Middle Ordovician sediments. These findings are in general accord with those of recent workers in the Mascot-Jefferson City and Copper Ridge districts who have proposed that mineralization in these areas occurred during the time interval of pre-Middle Ordovician erosion. The long-held theory which associates mineralization with late Paleozoic diastrophism is not supported.

Tennessee↗