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Insights on the characteristics and sources of gas from an underground coal mine using compositional data analysis

Coal mine gas originates from the gas emission zone (GEZ) of the mine, as well as the longwall face and pillars. Gas emissions are controlled directly at the sources using horizontal or vertical boreholes drilled from surface or from the entries in advance of mining, or it is captured from the fractured and caved zones (gob) using ventholes during mining. The rest of the gas, especially that gas that originates from the longwall face and caved zone, mixes with the ventilation air and travels through bleeder and return entries before being exhausted to atmosphere from air shafts. Although the gas associated with mining mostly focuses on methane, the gas is not pure methane but is a mixture (where both the components and their quantities vary depending on the sampling location). Understanding the evolution of the composition of the gas from source to different sampling and evaluation points in mines using proper statistical analysis and interpretation methods can lead to better designed degasification and ventilation systems and the selection of the most adequate utilization method for generating energy from the gas. In this work, we present the results of compositional data analysis (CoDa) of gases sampled at different locations in a longwall mine operating in Pennsylvanian coal-bearing strata in the Northern Appalachian coal basin. Sampling locations were from accessible parts of the bleeder entries, returns, bleeder evaluation points and shafts within the mine, and also from gob gas ventholes (GGV) and coal degasification boreholes drilled in the panel areas. In addition, desorbed gas samples from seams that are important for the mine were included in the analyses for comparison. The compositional data analysis showed that the gas composition shifts based on the sampling location, putting in-mine and pure coalbed gases on the opposite ends. Removal of air from the samples did not change this observation suggesting that oxygen is depleted especially for in-mine samples, which is due to oxidation. Results also suggested that desorbed gas samples may not represent the composition of the coal seam gas.

International Journal of Coal Geology↗

Deformation in the White Mountain seismic gap, California-Nevada, 1972-1982

A 100×40 km trilateration network extending from Bishop, California, to near Hawthorne, Nevada, crosses the east end of the Long Valley caldera, site of renewed magma inflation in the 1979–1980 interval, and spans most of the White Mountain seismic gap. The network was surveyed in 1972, 1973, 1976, 1979, 1980, and 1982. The 1980 survey may be contaminated by a scale error. In addition, leveling surveys across the caldera have been run in 1932, 1957, 1975, 1980, 1982, and 1983. Interpretation of the deformation is complicated by the occurrence of the May 1980 Mammoth Lakes earthquake sequence (four earthquakes M L ≥6) at the south edge of the caldera as well as other moderate earthquakes within the White Mountain seismic gap. The vertical deformation is largely accounted for by 0.10‐ to 0.15‐km 3 expansion of a spherical magma chamber 8–10 km beneath the resurgent dome within the Long Valley caldera sometime between July 1979 and September 1980 with an additional expansion of perhaps 0.05 km 3 between September 1980 and July 1982. Some additional sources of deformation within the aftershock zone of the Mammoth Lakes earthquakes seem to be required to explain the horizontal deformation. We show that right‐lateral slip on vertical faults extending WNW from each of the three largest earthquakes in the Mammoth Lakes sequence provides the required additional deformation, but this solution is by no means unique. There are simply too few data to define the rather complex deformation that apparently occurred within the aftershock zone. There is little doubt, however, that inflation of a magma chamber beneath the resurgent dome within the Long Valley caldera was involved in the deformation.

California↗

Isotopic evidence for the sources of Cretaceous and tertiary granitic rocks, east-central Alaska: Implications for the tectonic evolution of the Yukon-Tanana terrane

Magnetotelluric traverses across the southern Yukon-Tanana terrane (YTT) reveal the presence of a thick conductive layer (or layers) beneath Paleozoic crystalline rocks. These rocks have been interpreted to be flysch of probable Mesozoic age, on the basis of the occurrence of Jurassic-Cretaceous flysch in the Kahiltna assemblage and Gravina-Nutzotin belt flanking the YTT to the southwest and southeast, respectively. The Pb, Nd, Sr, and O isotopes in Cretaceous and Tertiary granitic rocks that crop out throughout the YTT were measured to determine if these rocks do in fact contain a component of flysch. Previous limited analyses indicated that the Pb isotopes of the granitic rocks could be a mixture of radiogenic Pb derived from Paleozoic crystalline rocks of the YTT with an increasing component of relatively nonradiogenic Pb with decreasing age. Our Nd, Sr, and O data, along with additional Pb isotope data, eliminate flysch as a likely source and strongly suggest that the nonradiogenic end-member was derived from mafic rocks, either directly from mantle magma or by melting of mafic crust. The lack of a sedimentary component in the granitic plutons suggests either that the plutons did not incorporate significant amounts of flysch during intrusion or that the conductive layer beneath the YTT crystalline rocks is not flysch.

Alaska↗

The high-pressure electronic structure of magnesiowustite (Mg, Fe)O: applications to the physics and chemistry of the lower mantle

The electronic structure of magnesiowustite is investigated using self-consistent field X α scattered wave (SCF- X α-SW) molecular orbital calculations on (FeO 6 ) 10− and (FeMg 12 O 14 ) 2− clusters. Calculated one-electron transition energies are used to interpret the optical spectrum of (Mg, Fe)O. The results are applied to the electrical and thermal conductivity of the lower mantle. The spin pairing of Fe 2+ and the effect of pressure on bonding in magnesiowustite, with some inferences regarding the incorporation of oxygen in the outer core, is also addressed. The approach used here appears to give a reliable description of the energy and pressure dependence of the spin-allowed 5 T 2 g → 5 E g ligand field transition and the spin-pairing transition of Fe 2+ in (Mg, Fe)O. However, the oxygen to metal charge transfer transitions in (Mg, Fe)O are not as reliably determined insofar as the p - d band gap varies with cluster size and the energies of the charge transfer states cannot be found without including configurational interaction. Nevertheless, it is argued that the charge transfer transitions that are intrinsic to (Fe, Mg)O are of a sufficiently high energy to be irrelevant to the electrical and thermal conductivity of the lower mantle. This is especially true if Fe 2+ adopts the low-spin configuration. The geophysically significant properties of (Fe, Mg)O probably result from defect Fe 3+ .

Journal of Geophysical Research↗

Radio-transmitters do not affect seasonal productivity of female Golden-winged Warblers

Investigating the potential effects of handling and marking techniques on study animals is important for correct interpretation of research results and to effect progress in data-collection methods. Few investigators have compared the reproductive output of radio-tagged and non-radio-tagged songbirds, and no one to date has examined the possible effect of radio-tagging adult songbirds on the survival of their fledglings. In 2011 and 2012, we compared several parameters of reproductive output of two groups of female Golden-winged Warblers ( Vermivora chrysoptera ) breeding in Minnesota, including 45 females with radio-transmitters and 73 females we did not capture, handle, or mark. We found no difference between groups in clutch sizes, hatching success, brood sizes, length of incubation and nestling stages, fledging success, number of fledglings, or survival of fledglings to independence. Thus, radio-tags had no measurable impact on the productivity of female Golden-winged Warblers. Our results build upon previous studies where investigators have reported no effects of radio-tagging on the breeding parameters of songbirds by also demonstrating no effect of radio-tagging through the post-fledging period and, therefore, the entire breeding season.

Journal of Field Ornithology↗

Pyrite formation in the Lower Cretaceous Mowry Shale: Effect of organic matter type and reactive iron content

Geochemical analysis of the Lower Cretaceous Mowry Shale in Wyoming and Montana shows that organic matter type and reactive iron content limited pyrite formation during early diagenesis. Consequently, direct interpretation of paleosalinity cannot be made from a carbon/sulfur plot. Mowry Shale samples with hydrogen index (HI) less than 150 (mg hydrocarbon/ organic carbon) contain low amounts of sulfur. In these samples, bacterial reduction of sulfate may have been inhabited by low nutritive content of the organic matter. For Mowry samples with HI greater than 150 there is a range of sulfur values and a positive correlation between iron and sulfur. The iron sulfur regression is approximately parallel to the stoichiometric pyrite line and intersects the iron axis at 0.5 percent. On average, 60 percent of the iron present was nonreactive; the remaining iron reacted with sulfide to form pyrite. For samples with HI greater than 150, pyrite formation was limited by sulfide or organic carbon content but by reactive iron content. In one modern setting, where salinity is greater than one-half normal seawater, sulfate content does not limit pyrite formation (Berner and Raiswell, 1984). From this analysis then, it can be estimated that the Mowry Sea was not a fresh water body but was either of normal marine salinity or contained brackish water with greater than one-half normal salinity.

Wyoming↗

Organic petrology of Paleocene Marcelina Formation coals, Paso Diablo mine, western Venezuela: Tectonic controls on coal type

About 7??Mt of high volatile bituminous coal are produced annually from the four coal zones of the Upper Paleocene Marcelina Formation at the Paso Diablo open-pit mine of western Venezuela. As part of an ongoing coal quality study, we have characterized twenty-two coal channel samples from the mine using organic petrology techniques. Samples also were analyzed for proximate-ultimate parameters, forms of sulfur, free swelling index, ash fusion temperatures, and calorific value. Six of the samples represent incremental benches across the 12-13??m thick No. 4 bed, the stratigraphically lowest mined coal, which is also mined at the 10??km distant Mina Norte open-pit. Organic content of the No. 4 bed indicates an upward increase of woody vegetation and/or greater preservation of organic material throughout the life of the original mire(s). An upward increase in telovitrinite and corresponding decrease in detrovitrinite and inertinite illustrate this trend. In contrast, stratigraphically higher coal groups generally exhibit a 'dulling upward' trend. The generally high inertinite content, and low ash yield and sulfur content, suggest that the Paso Diablo coals were deposited in rain-fed raised mires, protected from clastic input and subjected to frequent oxidation and/or moisture stress. However, the two thinnest coal beds (both 0.7??m thick) are each characterized by lower inertinite and higher telovitrinite content relative to the rest of Paso Diablo coal beds, indicative of less well-established raised mire environments prior to drowning. Foreland basin Paleocene coals of western Venezuela, including the Paso Diablo deposit and time-correlative coal deposits of the Ta??chira and Me??rida Andes, are characterized by high inertinite and consistently lower ash and sulfur relative to Eocene and younger coals of the area. We interpret these age-delimited coal quality characteristics to be due to water availability as a function of the tectonic control of subsidence rate. It is postulated that slower subsidence rates dominated during the Paleocene while greater foreland basin subsidence rates during the Eocene-Miocene resulted from the loading of nappe thrust sheets as part of the main construction phases of the Andean orogen. South-southeastward advance and emplacement of the Lara nappes during the oblique transpressive collision of the Caribbean and South American tectonic plates in the Paleocene was further removed from the sites of peat deposition, resulting in slower subsidence rates. Slower subsidence in the Paleocene may have favored the growth of raised mires, generating higher inertinite concentrations through more frequent moisture stress. Consistently low ash yield and sulfur content would be due to the protection from clastic input in raised mires, in addition to the leaching of mineral matter by rainfall and the development of acidic conditions preventing fixation of sulfur. In contrast, peat mires of Eocene-Miocene age encountered rapid subsidence due to the proximity of nappe emplacement, resulting in lower inertinite content, higher and more variable sulfur content, and higher ash yield.

International Journal of Coal Geology↗

Elucidating the magma plumbing system of Ol Doinyo Lengai (Natron Rift, Tanzania) Using satellite geodesy and numerical modeling

Ol Doinyo Lengai, located in the southern Eastern Branch of the East African Rift had several eruptive episodes with ash falls and lava flows (VEI 3) that caused damage to the nearby communities between 2007 and 2010. The volcano is remote and access is difficult. Although this volcano has been studied for decades, its plumbing system is still poorly understood, in part, because of the lack of precise observations of surface deformation during periods of quiet and unrest. This study investigates the volcanic plumbing system of Ol Doinyo Lengai and its surroundings using data from the network of permanent Global Navigation Satellite System (GNSS) sites monitoring the volcano (the TZVOLCANO network) around the flanks of the volcano and Interferometric Synthetic Aperture Radar (InSAR) observations. We constrain surface motions using 6 GNSS sites distributed around Ol Doinyo Lengai, operating between 2016 and 2021, and InSAR data covering nearly the same time period. Because of the complex local tectonics, the interpretation of the deformation pattern is not straightforward. We first invert the GNSS deformation and InSAR observations independently to infer potential deformation sources. Then we perform a joint inversion of both GNSS and InSAR datasets to verify our findings. We compare the results from the joint inversion with the results from inverting each dataset independently. The GNSS, InSAR, and joint inversion results point to a deflating source, located east of Ol Doinyo Lengai and southwest of the dormant volcano Gelai at a depth of 3.49 ± 0.03 km (GNSS inversion), 5.2 ± 1.2 km (InSAR inversion) and 3.49 ± 0.06 km (joint inversion) relative to the summit (vent) and with a volume change ∆V of −0.04 ± 0.05 × 10 6 m 3 (GNSS inversion), −0.39 ± 0.29 × 10 6 m 3 (InSAR inversion), and − 0.04 ± 0.01 × 10 6 m 3 (joint inversion). Although this is non-unique modeling of geodetic datasets with small signals, the inversion results suggest that Ol Doinyo Lengai could be fed by an offset multi-reservoir system that includes a shallow magma reservoir (<5 km) east of Ol Doinyo Lengai, possibly connected to a deeper magma reservoir.

Natron Rift, Ol Doinyo Lengai↗

The geology and distribution of impact craters on Venus: What are they telling us?

Magellan has revealed an ensemble of impact craters on Venus that is unique in many important ways. We have compiled a data base describing the 842 craters on 89% of Venus' surface mapped through orbit 2578. (The craters range in diameter from 1.5 to 280 km.) We have studied the distribution, size‐density, morphology, geology, and associated surface properties of these craters both in the aggregate and, for some craters, in greater detail. We find that (1) the spatial distribution of craters is highly uniform; (2) the size‐density distribution of large craters (diameters ≥35 km) is similar to the young crater populations on other terrestrial planets but at a much lower density that indicates an average age of only about 0.5 Ga (based on the estimated population of Venus‐crossing asteroids); (3) unlike the case on other planets, the density of small craters (diameters ≤35 km) declines rapidly with decreasing diameters because of atmospheric filtering; (4) the spectrum of crater modification differs greatly from that on other planets: 62% of all craters are pristine, only 4% are embayed by lavas, and the remainder are affected by tectonism, but none are severely and progressively depleted (as extrapolated from the size‐density distribution of larger craters); (5) large craters have a progression of morphologies generally similar to those on other planets, but small craters are typically irregular or multiple rather than bowl shaped; (6) diffuse radar‐bright or ‐dark features surround some craters, and 367 similar diffuse “splotches” with no central crater are observed; and (7) other crater features unique to Venus include radar‐bright or ‐dark parabolic arcs opening westward and extensive outflows originating in crater ejecta. The first three of these observations are entirely unexpected. We interpret them as indicating that the planet's cratering record was erased by a global resurfacing event or events, the latest ending about 0.5 Ga, after which volcanic activity declined (but did not cease entirely). Since the last resurfacing event, a maximum of 10% of the planet has been resurfaced and only about 4% of the craters have been obliterated. Convective thermal evolution models support this interpretation (Arkani‐Hamed and Toksoz, 1984). Observations 3–7 confirm quantitatively the expectation that the dense atmosphere of Venus has strongly affected the production of craters. Large impactors have been relatively unaffected, intermediate‐sized ones have been fragmented and have produced overlapping or multiple craters, a narrow size range has produced shock‐induced “splotches” but no craters, and the smallest bodies have had no observable effect on the surface. The number of craters eliminated by the “atmospheric filter” is enormous, about 98% of the craters between 2 and 35 km in diameter that Magellan might have observed on a hypothetical airless Venus. Unique crater‐related features such as parabolas and outflow deposits demonstrate the roles of Venus' high atmospheric density and temperature in modifying the crater formation process. Finally, heavily fractured craters and lava‐embayed craters are found to have higher than average densities along the major fracture belts and rifted uplands connecting Aphrodite Terra and Atla, Beta, Themis, and Phoebe regiones. These craters thus provide physical evidence for recent volcanic and tectonic activity at a low level.

Journal of Geophysical Research E: Planets↗

What lies beneath: geophysical mapping of a concealed Precambrian intrusive complex along the Iowa–Minnesota border

Large-amplitude gravity and magnetic highs over northeast Iowa are interpreted to reflect a buried intrusive complex composed of mafic–ultramafic rocks, the northeast Iowa intrusive complex (NEIIC), intruding Yavapai province (1.8–1.72 Ga) rocks. The age of the complex is unproven, although it has been considered to be Keweenawan (∼1.1 Ga). Because only four boreholes reach the complex, which is covered by 200–700 m of Paleozoic sedimentary rocks, geophysical methods are critical to developing a better understanding of the nature and mineral resource potential of the NEIIC. Lithologic and cross-cutting relations interpreted from high-resolution aeromagnetic and airborne gravity gradient data are presented in the form of a preliminary geologic map of the basement Precambrian rocks. Numerous magnetic anomalies are coincident with airborne gravity gradient (AGG) highs, indicating widespread strongly magnetized and dense rocks of likely mafic–ultramafic composition. A Yavapai-age metagabbro unit is interpreted to be part of a layered intrusion with subvertical dip. Another presumed Yavapai unit has low density and weak magnetization, observations consistent with felsic plutons. Northeast-trending, linear magnetic lows are interpreted to reflect reversely magnetized diabase dikes and have properties consistent with Keweenawan rocks. The interpreted dikes are cut in places by normally magnetized mafic–ultramafic rocks, suggesting that the latter represent younger Keweenawan rocks. Distinctive horseshoe-shaped magnetic and AGG highs correspond with a known gabbro, and surround rocks with weaker magnetization and lower density. Here, informally called the Decorah complex, the source body has notable geophysical similarities to Keweenawan alkaline ring complexes, such as the Coldwell and Killala Lake complexes, and Mesoproterozoic anorogenic complexes, such as the Kiglapait, Hettasch, and Voisey’s Bay intrusions in Labrador. Results presented here suggest that much of the NEIIC is composed of such complexes, and broadly speaking, may be a discontinuous group of several intrusive bodies. Most units are cut by suspected northwest-trending faults imaged as magnetic lineaments, and one produces apparent sinistral fault separation of a dike in the eastern part of the survey area. The location, trend, and apparent sinistral sense of motion are consistent with the suspected faults being part of the Belle Plaine fault zone, a complex transform fault zone within the Midcontinent rift system that is here proposed to correspond with a major structural discontinuity.

Iowa, Minnesota↗

Geographical patterns of human diet derived from stable-isotope analysis of fingernails

Carbon and nitrogen isotope ratios of human fingernails were measured in 490 individuals in the western US and 273 individuals in southeastern Brazil living in urban areas, and 53 individuals living in a moderately isolated area in the central Amazon region of Brazil and consuming mostly locally grown foods. In addition, we measured the carbon and nitrogen isotope ratios of common food items to assess the extent to which these isotopic signatures remain distinct for people eating both omnivorous and vegetarian diets and living in different parts of the world, and the extent to which dietary information can be interpreted from these analyses. Fingernail ??13C values (mean ?? standard deviation) were -15.4 ?? 1.0 and -18.8 ?? 0.8??? and ??15N values were 10.4 ?? 0.7 and 9.4 ?? 0.6??? for southeastern Brazil and western US populations, respectively. Despite opportunities for a "global supermarket" effect to swamp out carbon and nitrogen isotope ratios in these two urbanized regions of the world, differences in the fingernail isotope ratios between southeastern Brazil and western US populations persisted, and appeared to be more associated with regional agricultural and animal production practices. Omnivores and vegetarians from Brazil and the US were isotopically distinct, both within and between regions. In a comparison of fingernails of individuals from an urban city and isolated communities in the Amazonian region, the urban region was similar to southeastern Brazil, whereas individuals from isolated nonurban communities showed distinctive isotopic values consistent with their diets and with the isotopic values of local foods. Although there is a tendency for a "global supermarket" diet, carbon and nitrogen isotopes of human fingernails hold dietary information directly related to both food sources and dietary practices in a region. ?? 2006 Wiley-Liss, Inc.

American Journal of Physical Anthropology↗

Relocated aftershocks and background seismicity in eastern Indonesia shed light on the 2018 Lombok and Palu earthquake sequences

High seismicity rates in eastern Indonesia occur due to the complex interaction of several tectonic plates which resulted in two deadly, destructive earthquake sequences that occurred in Lombok Island and the city of Palu, Sulawesi in 2018. The first sequence began in July with an M w 6.4 event near Lombok, culminating in an M w 7.0 event 8 d later. This was then followed by a nearby M w 6.9 event 12 d later. Approximately 1000 km to the northeast, a separate sequence began several weeks later near Palu where an M w 7.5 event occurred that triggered a tsunami. In this study, we present hypocentre relocations for both earthquake sequences as well as all other regional earthquakes in eastern Indonesia. The relocations were performed using a teleseismic double-difference relocation method and arrival times for P and S waves from stations at local, regional, and teleseismic distances. The catalogue and phase data were taken from the Agency for Meteorology, Climatology and Geophysics (BMKG) of Indonesia and the International Seismological Centre (ISC) for the period of April 2009 through November 2018. The relocated catalogue provides an improved view of seismicity in eastern Indonesia over the study period, sharpening locations and interpretations of seismogenic features throughout the region. In the Lombok area, the relocated earthquakes clearly show a backarc thrust to the north of the Sunda-Banda Arc transition zone. The relocated aftershocks show that the destructive M w 7.0 and M w 6.9 earthquakes of the Lombok sequence ruptured two different regions: The M w 7.0 earthquake propagated westward, whereas the M w 6.9 earthquake propagated eastward. The entire sequence of Lombok earthquakes was most likely started by the M w 6.4 event as the initial event or foreshock, which then triggered backarc thrusts on both sides. Several weeks later and far to the northeast, the M w 7.5 Palu earthquake occurred along the Palu-Koro Fault, filling a seismic gap that had not ruptured in an M w 6.0 event or larger since at least 1900. The distribution of aftershocks indicates that the northern part of the Palu-Koro Fault has lower relative seismicity rates than the southern part at shallow depths, and that off fault aftershocks are mostly located to the east of the Palu-Koro Fault.

Lombok, Palu↗

Snow effects on alpine vegetation in the Qinghai-Tibetan Plateau

Understanding the relationships between snow and vegetation is important for interpretation of the responses of alpine ecosystems to climate changes. The Qinghai-Tibetan Plateau is regarded as an ideal area due to its undisturbed features with low population and relatively high snow cover. We used 500 m Moderate Resolution Imaging Spectroradiometer (MODIS) datasets during 2001&ndash;2010 to examine the snow&ndash;vegetation relationships, specifically, (1) the influence of snow melting date on vegetation green-up date and (2) the effects of snow cover duration on vegetation greenness. The results showed that the alpine vegetation responded strongly to snow phenology (i.e., snow melting date and snow cover duration) over large areas of the Qinghai-Tibetan Plateau. Snow melting date and vegetation green-up date were significantly correlated (p < 0.1) in 39.9% of meadow areas (accounting for 26.2% of vegetated areas) and 36.7% of steppe areas (28.1% of vegetated areas). Vegetation growth was influenced by different seasonal snow cover durations (SCDs) in different regions. Generally, the December&ndash;February and March&ndash;May SCDs played a significantly role in vegetation growth, both positively and negatively, depending on different water source regions. Snow's positive impact on vegetation was larger than the negative impact.

Qinghai-Tibetan Plateau↗

Coastal change analysis program implemented in Louisiana

Landsat Thematic Mapper images from 1990 to 1996 and collateral data sources were used to classify the land cover of the Mermentau River Basin (MRB) within the Chenier Plain of coastal Louisiana. Landcover classes followed the definition of the National Oceanic and Atmospheric Administration's Coastal Change Analysis Program; however, classification methods had to be developed as part of this study for attainment of these national classification standards. Classification method developments were especially important when classes were spectrally inseparable, when classes were part of spatial and spectral continuums, when the spatial resolution of the sensor included more than one landcover type, and when human activities caused abnormal transitions in the landscape. Most classification problems were overcome by using one or a combination of techniques, such as separating the MRB into subregions of commonality, applying masks to specific land mixtures, and highlighting class transitions between years that were highly unlikely. Overall, 1990, 1993, and 1996 classification accuracy percentages (associated kappa statistics) were 80% (0.79), 78% (0.76), and 86% (0.84), respectively. Most classification errors were associated with confusion between managed (cultivated land) and unmanaged grassland classes; scrub shrub, grasslands and forest classes; water, unconsolidated shore and bare land classes; and especially in 1993, between water and floating vegetation classes. Combining cultivated land and grassland classes and water and floating vegetation classes into single classes accuracies for 1990, 1993, and 1996 increased to 82%, 83%, and 90%, respectively. To improve the interpretation of landcover change, three indicators of landcover class stability were formulated. Location stability was defined as the percentage of a landcover class that remained as the same class in the same location at the beginning and the end of the monitoring period. Residence stability was defined as the percent change in each class within the entire MRB during the monitoring period. Turnover was defined as the addition of other landcover classes to the target landcover class during the defined monitoring period. These indicators allowed quick assessment of the dynamic nature of landcover classes, both in reference to a spatial location and to retaining their presence throughout the MRB. Examining the landcover changes between 1990 to 1993 and 1993 to 1996, led us to five principal findings: (1) Landcover turnover is maintaining a near stable logging cycle, although the locations of grassland, scrub shrub, and forest areas involved in the cycle appeared to change. (2) Planting of seedlings is critical to maintaining cycle stability. (3) Logging activities tend to replace woody land mixed forests with woody land evergreen forests. (4) Wetland estuarine marshes are expanding slightly. (5) Wetland palustrine marshes and mature forested wetlands in the MRB are relatively stable.

Louisiana↗

Effects of exploitation and emigration on apparent survival of Walleye in Lake Sharpe, South Dakota

Objective In 2017, we began a 5-year mark–recapture study to estimate apparent survival of Walleye Sander vitreus and angler exploitation in Lake Sharpe, South Dakota, and inform management strategies for this fishery. The study revealed substantial downstream emigration of Walleye; therefore, we also examined the influence of emigration on apparent mortality. Methods We estimated Walleye apparent survival using the Seber parameterization of the dead recovery model. In our models, we included factors influencing voluntary fish release, as well as harvest restrictions, tagging location, and year. We used a multistate Markov model to estimate emigration in relation to Walleye total length, sex, and tagging location, as well as annual reservoir discharge. The exploitation and emigration estimates informed our interpretations of annual Walleye apparent survival. Result Apparent survival patterns were explained by an interaction between Walleye length and a minimum harvest length restriction. Apparent survival was lower during July and August, when the minimum harvest length limit was suspended, and results suggest that anglers were willing to release preferred sizes (≥508 mm) when able to harvest smaller (<381 mm) Walleye. Annual apparent survival, exploitation, and emigration estimates ranged between 15% and 47%, 8% and 25%, and 11% and 28%, respectively. Emigration was influenced by tagging location and annual discharge: increasing with proximity to Big Bend dam and during high annual flows. Although years with high exploitation or emigration corresponded to years with low apparent survival, estimates did not explain the magnitude of mortality or emigration indicated by survival models. Conclusion Our results revealed that harvest–release decisions by Walleye anglers in Lake Sharpe are primarily influenced by regulations, although exploitation was not a significant source of mortality. Annual patterns in apparent survival indicate high mortality or emigration. Continued investigations into immigration and emigration and sources of mortality of Lake Sharpe Walleye are warranted to better inform management strategies for the fishery.

South Dakota↗

Hyperspectral (VNIR-SWIR) analysis of roll front uranium host rocks and industrial minerals from Karnes and Live Oak Counties, Texas Coastal Plain

VNIR-SWIR (400–2500 nm) reflectance measurements were made on the surfaces of various cores, cuttings and sample splits of sedimentary rocks from the Tertiary Jackson Group, and Catahoula, Oakville and Goliad Formations. These rocks vary in composition and texture from mudstone and claystone to sandstone and are known host rocks for roll front uranium occurrences in Karnes and Live Oak Counties, Texas. Spectral reflectance profiles, 569 in total, were reduced to 125 representative spectral signatures, which were analyzed using the U.S. Geological Survey's (USGS) Material Identification and Characterization Algorithm (MICA). MICA uses an automated continuum-removal procedure together with a least-squares linear regression to determine the fit of observed sample spectral absorption features to those of reference mineral standards in a spectral library. The reference minerals include various clay, mica, carbonate, ferric and ferrous iron minerals and their mixtures. In addition, absorption feature band-depth analysis was done to identify rock surfaces exhibiting absorption features related to uranium and zeolite minerals, which were not included in the command files used to execute MICA. Rocks from each of the four geologic units produced broadly similar spectral signatures as a result of comparable mineral compositions, but there were some notable differences. For example, Ca- and Na-montmorillonite was matched most frequently to the spectral absorption features in 2-μm (∼2000–2500 nm) wavelengths, while goethite occurred often at 1-μm (∼400–1000 nm) wavelengths. The latter is related to limonitic iron-staining in and around oxidized zones of the uranium roll front as described in previous papers. Rocks of the Jackson Group differed from those of the Catahoula, Oakville and Goliad units in that the former exhibited spectral features we interpret as being due to the presence of lignite-bearing mudstone layers. Goliad rocks exhibit spectral features related to dolomite, gypsum, anhydrite, and an unidentified green clay mineral that is possibly glauconite . Jackson Group rocks also exhibit weak but well-resolved absorption features at 964 and 1157 nm related to either or both zeolite minerals clinoptilolite and heulandite. These zeolite minerals and a few spectra exhibiting hydrous silica absorption features are indicative of alteration of volcanic glass in tuffaceous mudstone and claystone layers. A few sample spectra exhibited strong absorption features at around 1135 nm related to the uranium mineral coffinite. Both the 1135 nm coffinite and 1157 nm zeolite absorption features overlap somewhat, potentially making them difficult to distinguish without additional hyperspectral field, laboratory or remote sensing data. The results of this study were compared to mixtures of minerals described for ore, gangue and alteration minerals in deposit models for sandstone-hosted uranium, sedimentary bentonite and sedimentary zeolite. Use of these spectra can help facilitate mapping of both waste materials from the legacy mining of the above commodities, as well as future exploration and resource assessment activities.

Texas↗

Sampling efficiency of the Moore egg collector

Quantitative studies focusing on the collection of semibuoyant fish eggs, which are associated with a pelagic broadcast-spawning reproductive strategy, are often conducted to evaluate reproductive success. Many of the fishes in this reproductive guild have suffered significant reductions in range and abundance. However, the efficiency of the sampling gear used to evaluate reproduction is often unknown and renders interpretation of the data from these studies difficult. Our objective was to assess the efficiency of a modified Moore egg collector (MEC) using field and laboratory trials. Gear efficiency was assessed by releasing a known quantity of gellan beads with a specific gravity similar to that of eggs from representatives of this reproductive guild (e.g., the Arkansas River Shiner Notropis girardi) into an outdoor flume and recording recaptures. We also used field trials to determine how discharge and release location influenced gear efficiency given current methodological approaches. The flume trials indicated that gear efficiency ranged between 0.0% and 9.5% (n = 57) in a simple 1.83-m-wide channel and was positively related to discharge. Efficiency in the field trials was lower, ranging between 0.0% and 3.6%, and was negatively related to bead release distance from the MEC and discharge. The flume trials indicated that the gellan beads were not distributed uniformly across the channel, although aggregation was reduced at higher discharges. This clustering of passively drifting particles should be considered when selecting placement sites for an MEC; further, the use of multiple devices may be warranted in channels with multiple areas of concentrated flow.

North American Journal of Fisheries Management↗

Automated calibration of a stream solute transport model: Implications for interpretation of biogeochemical parameters

The hydrologic processes of advection, dispersion, and transient storage are the primary physical mechanisms affecting solute transport in streams. The estimation of parameters for a conservative solute transport model is an essential step to characterize transient storage and other physical features that cannot be directly measured, and often is a preliminary step in the study of reactive solutes. Our study used inverse modeling to estimate parameters of the transient storage model OTIS (One dimensional Transport with Inflow and Storage). Observations from a tracer injection experiment performed on Uvas Creek, California, USA, are used to illustrate the application of automated solute transport model calibration to conservative and nonconservative stream solute transport. A computer code for universal inverse modeling (UCODE) is used for the calibrations. Results of this procedure are compared with a previous study that used a trial-and-error parameter estimation approach. The results demonstrated 1) importance of the proper estimation of discharge and lateral inflow within the stream system; 2) that although the fit of the observations is not much better when transient storage is invoked, a more randomly distributed set of residuals resulted (suggesting non-systematic error), indicating that transient storage is occurring; 3) that inclusion of transient storage for a reactive solute (Sr2+) provided a better fit to the observations, highlighting the importance of robust model parameterization; and 4) that applying an automated calibration inverse modeling estimation approach resulted in a comprehensive understanding of the model results and the limitation of input data.

Journal of the North American Benthological Societ↗