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At least 901 records · Page 50Linked to original sources
USGS2015

Marine geophysical data collected in a shallow back-barrier estuary, Barnegat Bay, New Jersey

In 2011, the U.S. Geological Survey, in cooperation with the New Jersey Department of Environmental Protection, began a multidisciplinary research project to better understand the water quality in Barnegat Bay, New Jersey. This back-barrier estuary is experiencing degraded water quality, algal blooms, loss of seagrass, and increases in oxygen stress, macroalgae, stinging nettles, and brown tide. The spatial scale of the estuary and the scope of challenges within it necessitate a multidisciplinary approach that includes establishing the regional geology and the estuary’s physical characteristics and modeling how the estuary’s morphology interacts to affect its water quality. This report presents the data collected during this project for use in understanding the morphology and the distribution of sea-floor and sub-sea-floor sediments within Barnegat Bay, describes the methods used to collect and process those data, and includes links to the final processed datasets. These data can be used by scientists to understand the links between geomorphology, geologic framework, sediment transport, and estuarine water quality and circulation.

New Jersey↗
USGS2010

Geologic Map of the House Rock Valley Area, Coconino County, Northern Arizona

This geologic map is a cooperative effort of the U.S. Geological Survey (USGS), the Bureau of Land Management, the National Park Service, and the U.S. Forest Service to provide a geologic database for resource management officials and visitor information services. This map was produced in response to information needs related to a proposed withdrawal of three segregated land areas near Grand Canyon National Park, Arizona, from new hard rock mining activity. House Rock Valley was designated as the east parcel of the segregated lands near the Grand Canyon. This map was needed to provide connectivity for the geologic framework of the Grand Canyon segregated land areas. This geologic map of the House Rock Valley area encompasses approximately 280 mi2 (85.4 km2) within Coconino County, northern Arizona, and is bounded by longitude 111 degrees 37'30' to 112 degrees 05' W. and latitude 36 degrees 30' to 36 degrees 50' N. The map area is in the eastern part of the Arizona Strip, which lies within the southern Colorado Plateaus geologic province (herein Colorado Plateau). The Arizona Strip is the part of Arizona lying north of the Colorado River. The map is bound on the east by the Colorado River in Marble Canyon within Grand Canyon National Park and Glen Canyon National Recreation Area, on the south and west by the Kaibab National Forest and Grand Canyon National Game Preserve, and on the north by the Vermilion Cliffs Natural Area, the Paria Canyon Vermilion Cliffs Wilderness Area, and the Vermilion Cliffs National Monument. House Rock State Buffalo Ranch also bounds the southern edge of the map area. The Bureau of Land Management Arizona Field Office in St. George, Utah, manages public lands of the Vermilion Cliffs Natural Area, Paria Canyon - Vermilion Cliffs Wilderness and Vermilion Cliffs National Monument. The North Kaibab Ranger District in Fredonia, Arizona, manages U.S. Forest Service land along the west edge of the map area and House Rock State Buffalo Ranch. Other lands include about 13 sections of Arizona State land, about ? of a section of private land along House Rock Wash, and about 1? sections of private land at Cliff Dwellers Lodge, Vermilion Cliffs Lodge, and Marble Canyon, Arizona. Landmark features within the map area include the Vermilion Cliffs, Paria Plateau, Marble Canyon, and House Rock Valley. Surface drainage in House Rock Valley is to the east toward the Colorado River in Marble Canyon. Large tributaries of Marble Canyon from north to south include Badger Canyon, Soap Creek, Rider Canyon, North Canyon, Bedrock Canyon, and South Canyon. Elevations range from about 2,875 ft (876 m) at the Colorado River in the southeast corner of the map to approximately 7,355 ft (2,224 m) on the east rim of Paria Plateau along the north-central edge of the map area. Three small settlements are in the map area along U.S. Highway 89A, Cliff Dwellers Lodge, Vermilion Cliffs Lodge, and Marble Canyon, Arizona. The community of Jacob Lake is about 9 mi (14.5 km) west of House Rock Valley on the Kaibab Plateau. Lees Ferry is 5 mi (8 km) north of Marble Canyon and marks the confluence of the Paria and Colorado Rivers and the beginning of Marble Canyon. U.S. Highway 89A provides access to the northern part of the map area. Dirt roads lead south into House Rock Valley from U.S. Highway 89A and are collectively maintained by the Bureau of Land Management, the U.S. National Forest Service, and the Grand Canyon Trust. House Rock Valley is one of the few remaining areas where uniform geologic mapping is needed for connectivity to the regional Grand Canyon geologic framework. This information is useful to Federal and State resource managers who direct environmental and land management programs that encompass such issues as range management, biological studies, flood control, water, and mineral-resource investigations. The geologic information will support future and ongoing geologic investigations and scientific studies

Scientific Investigations Map↗
USGS2007

Water quality in the upper Anacostia River, Maryland: Continuous and discrete monitoring with simulations to estimate concentrations and yields, 2003-05

From 2003 through 2005, continuous and discrete waterquality data were collected at two stations on the Anacostia River in Maryland: Northeast Branch at Riverdale, Maryland (U.S. Geological Survey Station 01649500) and Northwest Branch near Hyattsville, Maryland (Station 01651000). Both stations are above the heads of tide for the river, and measurements approximately represent contributions of chemicals from the nontidal watersheds in the Anacostia River. This study was a cooperative effort between the U.S. Geological Survey, the Prince George’s County Department of Environmental Resources, the Maryland Department of the Environment, the U.S. Environmental Protection Agency, and George Mason University. Samples were collected for suspended sediment, nutrients, and trace metals; data were used to calculate loads of selected chemical parameters, and to evaluate the sources and transport processes of contaminants. Enrichment factors were calculated for some trace metals and used to interpret patterns of occurrence over different flow regimes. Some metals, such as cadmium, lead, and zinc, were slightly enriched as compared to global averages for shales; overall, median values of enrichment factors for all metals were approximately 15 to 35. Stepwise linear regression models were developed on log-transformed concentrations to estimate the concentrations of suspended sediment, total nitrogen, and total phosphorus from continuous data of discharge and turbidity. The use of multiple explanatory variables improved the predictions over traditional rating curves that use only streamflow as the explanatory variable, because other variables such as turbidity measure the hysteretic effects of fine-grained suspended sediment over storm hydrographs. Estimates of the concentrations of suspended sediment from continuous discharge and turbidity showed coefficients of determination for the predictions (multiple R2) of 0.95 and biases of less than 4 percent. Models to estimate the concentrations of total phosphorus and total nitrogen had lower values of multiple R2 than suspended sediment, but the estimated bias for all the models was similar. The models for total nitrogen and total phosphorus tended to under-predict high concentrations and to over-predict low concentrations as compared to measured values. Annual yields (loads per square area in kilograms per year per square kilometer) were estimated for suspended sediment, total nitrogen, and total phosphorus using the U.S. Geological Survey models ESTIMATOR and LOADEST. The model LOADEST used hourly time steps and allowed the use of turbidity, which is strongly correlated to concentrations of suspended sediment, as a predictor variable. Annual yields for total nitrogen and total phosphorus were slightly higher but similar to previous estimates for other watersheds of the Chesapeake Bay, but annual yields for suspended sediment were higher by an order of magnitude for the two Anacostia River stations. Annual yields of suspended sediment at the two Anacostia River stations ranged from 131,000 to 248,000 kilograms per year per square kilometer for 2004 and 2005. LOADEST estimates were similar to those determined with ESTIMATOR, but had reduced errors associated with the estimates.

Maryland↗
USGS2016

Methods for estimating streamflow characteristics at ungaged sites in western Montana based on data through water year 2009: Chapter G in Montana StreamStats

The U.S. Geological Survey, in cooperation with the Montana Department of Environmental Quality and the Montana Department of Natural Resources and Conservation, developed regional regression equations based on basin and streamflow characteristics for streamflow-gaging stations through water year 2009 that can be used to estimate streamflow characteristics for ungaged sites in western Montana. The regression equations allow estimation of low-flow frequencies; mean annual and mean monthly streamflows; and the 20-, 50-, and 80-percent durations for annual and monthly duration streamflows for ungaged sites in western Montana that are unaffected by regulation. Regression equations were developed for 54 streamflow characteristics in each of the 4 hydrologic regions generally located in western Montana. Exploratory data analyses determined that of the 40 basin characteristics used as explanatory variables, only 3 were significant in the final equations. These three basin characteristics are contributing drainage area, mean annual precipitation of the drainage basin, and percentage of basin with slopes greater than 50 percent. Low-flow frequency data and daily mean streamflow data from 152 streamflow-gaging stations were used to develop the regression equations. These 152 streamflow-gaging stations were considered to be unregulated (or only the unregulated period of record for regulated streamflow-gaging stations were used). For this study, a streamflow-gaging station is considered to be unregulated if cumulative drainage area upstream from all upstream dams is less than 20 percent of the drainage basin for the streamflow-gaging station, and if no large diversion canals are upstream from the streamflow-gaging station. In addition to the regional regression equations, two methods for estimating streamflow characteristics based on drainage areas of a nearby streamflow-gaging station are provided. Also, spreadsheet tools are provided for calculating streamflow characteristics based on regression equations or the drainage-area ratio method. All of the data used to calculate basin characteristics were derived from publicly available data sources and are available through the U.S. Geological Survey Streamstats program ( http://water.usgs.gov/osw/streamstats/ ) for Montana. The primary purpose of the Montana StreamStats application is to provide estimates of basin characteristics and streamflow characteristics for user-selected ungaged sites on Montana streams. The regional regression equations presented in this report have been loaded to the Montana StreamStats application and can be used to derive streamflow characteristics for ungaged sites.

Montana↗
USGS2007

Simulation of Surface-Water Conditions in the Nontidal Passaic River Basin, New Jersey

The Passaic River Basin, the third largest drainage basin in New Jersey, encompasses 950 mi2 (square miles) in the highly urbanized area outside New York City, with a population of 2 million. Water quality in the basin is affected by many natural and anthropogenic factors. Nutrient loading to the Wanaque Reservoir in the northern part of the basin is of particular concern and is caused partly by the diversion of water at two downstream intakes that is transferred back upstream to refill the reservoir. The larger of these diversions, Wanaque South intake, is on the lower Pompton River near Two Bridges, New Jersey. To support the development of a Total Maximum Daily Load (TMDL) for nutrients in the nontidal part of the basin (805 mi2), a water-quality transport model was needed. The U.S. Geological Survey, in cooperation with the New Jersey Department of Environmental Protection and New Jersey EcoComplex, developed a flow-routing model to provide the hydraulic inputs to the water-quality model. The Diffusion Analogy Flow model (DAFLOW) described herein was designed for integration with the Water Quality Analysis Simulation Program (WASP) watershed water-quality model. The flow routing model was used to simulate flow in 108 miles of the Passaic River and major tributaries. Flow data from U.S. Geological Survey streamflow-gaging stations represent most of the model's upstream boundaries. Other model inputs include estimated flows for ungaged tributaries and unchanneled drainage along the mainstem, and reported flows for major point-source discharges and diversions. The former flows were calibrated using the drainage-area ratio method. The simulation extended over a 4+ year period representing a range in flow conditions. Simulated channel cross-sectional geometry in the DAFLOW model was calibrated using several different approaches by adjusting area and top width parameters. The model also was calibrated to observed flows for water year 2001 (low flow) at five mainstem gaging stations and one station at which flow was estimated. The model's target range was medium to low flows--the range of typical intake operations. Simulated flow mass balance, hydrographs (flood-wave speed, attenuation, and spread), flow-duration curves, and velocity and depth values were compared to observed counterparts. Mass balance and hydrograph fit were evaluated quantitatively. Simulation results generally were within the accuracy of the flow data at the measurement stations. The model was validated to observed flows for water years 2000 (average flow), 2002 (extreme low flow), and 2003 (high flow). Results for 19 of 20 comparisons indicate average mass-balance and model-fit errors of 6.6 and 15.7 percent, respectively, indicating that the model reasonably represents the time variation of streamflow in the nontidal Passaic River Basin. An algorithm (subroutine) also was developed for DAFLOW to simulate the hydraulic mixing that occurs near the Wanaque South intake upstream from the confluence of the Pompton and Passaic Rivers. The intake draws water from multiple sources, including effluent from a nearby wastewater-treatment plant, all of which have different phosphorus loads. The algorithm determines the proportion of flow from each source and operates within a narrow flow range. The equations used in the algorithm are based on the theory of diffusion and lateral mixing in rivers. Parameters used in the equations were estimated from limited available local flow and water-quality data. As expected, simulation results for water years 2000, 2001, and 2003 indicate that most of the water drawn to the intake comes from the Pompton River; however, during many short periods of low flow and high diversion, particularly in water year 2002, entrainment of the other flow sources compensated for the insufficient flow in the Pompton River. As additional verification of the flow model used in the water-quality model, a Branched Lagrangian Transport Model (B

Scientific Investigations Report↗
USGS2004

Herbicides and their transformation products in source-water aquifers tapped by public-supply wells in Illinois, 2001-02

During 2001-02, ground-water samples were collected from 117 public-supply wells distributed throughout Illinois to evaluate the occurrence of herbicides and their transformation products in the State?s source-water aquifers. Wells were selected using a stratified-random method to ensure representation of the major types of source-water aquifers in the State. Samples were analyzed for 18 herbicides and 18 transformation products, including 3 triazine and 14 chloroacetanilide products. Herbicide compounds (field-applied parent herbicides and their transformation products) were detected in 34 percent of samples. A subset of samples was collected unfiltered to determine if analytical results for herbicides in unfiltered samples are similar to those in paired filtered samples and, thus, can be considered equally representative of herbicide concentrations in ground water supplied to the public. The study by the U.S. Geological Survey was done in cooperation with the Illinois Environmental Protection Agency. Parent herbicides were detected in only 4 percent of all samples. The six most frequently detected herbicide compounds (from 5 to 28 percent of samples) were chloroacetanilide transformation products. The frequent occurrence of transformation products and their higher concentrations relative to those of most parent herbicides confirm the importance of obtaining information on transformation products to understand the mobility and fate of herbicides in ground-water systems. No sample concentrations determined during this study exceeded current (2003) Federal or State drinking-water standards; however, standards are established for only seven parent herbicides. Factors related to the occurrence of herbicide compounds in the State?s source-water aquifers include unconsolidated and unconfined conditions, various hydrogeologic characteristics and well-construction aspects at shallow depths, and proximity to streams. Generally, the closer an aquifer (or well location) is to a recharge area and (or) the stronger the hydraulic connection between an aquifer and a recharge area, the younger the ground water and the more vulnerable the aquifer will be to contamination by herbicide compounds. The weak relation between current (2001) statewide application rates of herbicides and current (2001-02) occurrence of herbicide compounds in source-water aquifers indicates that additional factors must be considered when relating herbicide-application rates to occurrence. These factors include historical application rates and the mobility and persistence of the various herbicide compounds in ground-water systems. Frequency of detection and concentrations of herbicides compounds in the State?s source-water aquifers are indicated to be highest during the spring, when crops are planted and herbicides primarily are applied. Excess nitrate (concentrations of nitrate, as nitrogen, higher than 3 milligrams per liter) in ground water strongly indicates the co-occurrence of herbicide compounds. However, nitrate concentrations are not a reliable indicator of herbicide-compound concentrations. The inverse relation found between current use of land for corn and soybean production and current occurrence of herbicide compounds in underlying aquifers indicates that various factors, along with current agricultural land use, contribute to herbicide occurrence. These factors include, among others, land-use history, ground-water age, ground-water-flow patterns, geology, soil microbiology, and chemistry and persistence of the herbicide compounds. Detection of agriculture-specific herbicide compounds in 71 percent of samples from urban areas with no current or recent agricultural land use near the sampled wells indicates that recharge to certain high-capacity supply wells may originate at considerable distances (up to about 10 miles) from the wells. Essentially no difference was found between the analytical results for herbicides in paired unfiltered and filtered samples,

Water-Resources Investigations Report↗
USGS2012

Stable isotope deltas: Tiny, yet robust signatures in nature

Although most of them are relatively small, stable isotope deltas of naturally occurring substances are robust and enable workers in anthropology, atmospheric sciences, biology, chemistry, environmental sciences, food and drug authentication, forensic science, geochemistry, geology, oceanography, and paleoclimatology to study a variety of topics. Two fundamental processes explain the stable isotope deltas measured in most terrestrial systems: isotopic fractionation and isotope mixing. Isotopic fractionation is the result of equilibrium or kinetic physicochemical processes that fractionate isotopes because of small differences in physical or chemical properties of molecular species having different isotopes. It is shown that the mixing of radioactive and stable isotope end members can be modelled to provide information on many natural processes, including 14C abundances in the modern atmosphere and the stable hydrogen and oxygen isotopic compositions of the oceans during glacial and interglacial times. The calculation of mixing fractions using isotope balance equations with isotope deltas can be substantially in error when substances with high concentrations of heavy isotopes (e.g. 13C, 2H, and 18O ) are mixed. In such cases, calculations using mole fractions are preferred as they produce accurate mixing fractions. Isotope deltas are dimensionless quantities. In the International System of Units (SI), these quantities have the unit 1 and the usual list of prefixes is not applicable. To overcome traditional limitations with expressing orders of magnitude differences in isotope deltas, we propose the term urey (symbol Ur), after Harold C. Urey, for the unit 1. In such a manner, an isotope delta value expressed traditionally as−25 per mil can be written as−25 mUr (or−2.5 cUr or−0.25 dUr; the use of any SI prefix is possible). Likewise, very small isotopic differences often expressed in per meg ‘units’ are easily included (e.g. either+0.015 ‰ or+15 per meg can be written as+15 μUr.

Isotopes in Environmental and Health Studies↗
USGS1998

Hydrology and geochemistry of a slag-affected aquifer and chemical characteristics of slag-affected ground water, northwestern Indiana and northeastern Illinois

Slag is a by-product of steel manufacturing and a ubiquitous fill material in northwestern Indiana. Ground water associated with slag deposits generally is characterized by high pH and elevated concentrations of many inorganic water-quality constituents. The U.S. Geological Survey, in cooperation with the Indiana Department of Environmental Management, conducted a study in northwestern Indiana from June 1995 to September 1996 to improve understanding of the effects of slag deposits on the water quality of a glacial-outwash aquifer. The Bairstow Landfill, a slag-fill deposit overlying the Calumet aquifer near Hammond, Indiana, was studied to represent conditions in slag-deposit settings that are common in northwestern Indiana. Ground water from 10 observation wells, located in four nests at the site, and surface water from the adjacent Lake George were analyzed for values of field-measured parameters and concentrations of major ions, nutrients, trace elements, and bulk properties. Solid-phase samples of slag and aquifer sediment collected during drilling were examined with X-ray diffraction and geochemical digestion and analysis. Concentrations of calcium, potassium, sodium, and sulfate were highest in wells screened partly or fully in slag. Potassium concentrations in ground water ranged from 2.9 to 120 milligrams per liter (mg/L), were highest in water from slag deposits, and decreased with depth. The highest concentrations for aluminum, barium, molybdenum, nickel, and selenium were in water from the slag. Silica concentrations were highest in wells screened directly beneath the slag-aquifer interface, and magnesium concentrations were highest in intermediate and deep aquifer wells. Silica concentrations in shallow and intermediate aquifer wells ranged from 27 to 41 mg/L and were about 10 times greater than those in water from slag deposits. The highest concentrations for chromium, lead, and zinc were in ground water from immediately below the slag-aquifer interface. The solid-phase analyses indicated that calcite, dolomite, and quartz generally were present throughout the slag-aquifer system; barian celestite, cristobalite, manganese-bearing calcite, and minrecordite were present in fewer samples. Trace elements that are liberated from the slag may be incorporated as impurities during precipitation of major minerals, sorbed onto clays and other grainsize fractions not analyzed as part of this study, or present in low-abundance minerals that were not detected by the X-ray analysis. Mass-balance and speciation programs were used to identify geochemical processes that may be occurring as water infiltrates through the slag, flows into the aquifer, and discharges into Lake George. The geochemical models indicate that precipitation of calcite may be occurring where slag-affected water enters the aquifer. Models also indicate that dolomite precipitation and clay-mineral dissolution may be occurring at the slag-aquifer interface; however, dolomite precipitation is generally believed to require geologically long time periods. Silica may be dissolving where slag-affected ground water enters the aquifer and may be precipitating where slag-affected ground water discharges to the lakebed of Lake George. In addition to the site-specific study, a statistical analysis of regional water quality was done to compare ground water in wells affected and unaffected by slag. When com-pared to wells in background locations in the Calumet aquifer, wells screened in slag across northwestern Indiana and northeastern Illinois generally had relatively higher pH and specific-conductance values and relatively higher concentrations of alkalinity, dissolved solids, suspended solids, total organic carbon, calcium, potassium, sodium, chloride, aluminum, barium, and possibly magnesium, sulfate, chromium, cobalt, copper, cyanide, manganese, mercury, nickel, and vanadium. When compared to wells in slag and wells in background locations, ground water from immediately beneath or immediately downgradient from slag had relatively high concentrations of arsenic and silica. Water-quality characteristics in ground water at the Bairstow Landfill were similar to water-quality characteristics in slag-contact and slag-affected wells throughout northwestern Indiana.

Illinois, Indiana↗
USGS1997

Recharge areas and quality of ground water for the Glen Canyon and valley-fill aquifers, Spanish Valley area, Grand and San Juan counties, Utah

The Spanish Valley area in southeastern Utah (fig. 1) is experiencing a rapid increase in development of residential and business property. In this report, the Spanish Valley area refers to the geographic area shown in figures 1, 3, and 4. This area includes Moab Valley, Spanish Valley, and the mesa area.-; to the northeast. Substantial development is taking place on the cast side of Spanish Valley, where the Navajo Sandstone, the Kaycnta Formation, and the Wingate Sandstone forn the Glen Canyon aquifer, wltich is the principal aquifer that supplies drinking water for the area. Additional business construction and subdivision development are occurring in Spanish Valley south of Moab, where valley-fill deposits make up a secondary aquifer that is used mostly for irrigation and stock watering but also for domestic drinking water. Because current (1995) sewage treatment facilities arc not adequate to accommodate the increase in development, county officials are concerned about protecting the ground-water resources from excess nitrate loading that might result if additional septic systems are used for the effluent disposal. Traditional land use in the Spanish Valley area has been agricultural, but more subdivisions and small farms with horse pastures are being developed. Sumsion (1971) reported that water from five wells in the valley-fill aquifer contained nitrate concentrations that ranged from 9 to 26 mg/Las NO 3 (2.0 to 5.87 mg/Las N). With the increased use of septic systems in the south end of the valley, nitrate plus nitrite concentrations might have increased in the valley-fill aquifer. Few data on nitrate plus nitrite concentration have been collected since 1968-69. Also, with the increased development, other types of contamination such as organic compounds might be infiltrating the valley-fill aquifer. Little or no sampling for organic compounds has been done in the valley-fill aquifer in Moab and Spanish Valleys. To protect ground-water resources in Grand County, Grand County Commissioners would like to classify the ground-water system according to the Ground Water Quality Protection Administrative Rule R317-6 of the Utah Administrative Code (table I. part A. located on the back of this report) (Utah Department of Environmental Quality, Division of Water Quality, 1995). The code states that when sufficient information is available, entire aquifers or parts thereof may be classified by the lJLah Water Quality Board according to the quality of ground water contained therein. After classification, groundwater protection levels are established and used to regulate existing and potential sources of contamination to ground water from new and existing facilities within the classified area. This investigation was done by the U.S. Geological Survey (USGS) in cooperation with the Utah Department of Environmental Quality, Division of Water Quality; Grand County; the city of Moab; and the U.S. Environmental Protection Agency.

Utah↗
USGS2000

Water-quality characteristics for selected streams in Lawrence County, South Dakota, 1988-92

During the 1980’s, significant economic development and population growth began to occur in Lawrence County in the northern part of the Black Hills of western South Dakota. Rising gold prices and heap-leach extraction methods allowed the economic recovery of marginal gold ore deposits, resulting in development of several large-scale, open-pit gold mines in Lawrence County. There was increasing local concern regarding potential impacts on the hydrologic system, especially relating to the quantity and quality of water in the numerous streams and springs of Lawrence County. In order to characterize the water quality of selected streams within Lawrence County, samples were collected from 1988 through 1992 at different times of the year and under variable hydrologic conditions. During the time of this study, the Black Hills area was experiencing a drought; thus, most samples were collected during low-flow conditions. Streamflow and water-quality characteristics in Lawrence County are affected by both geologic conditions and precipitation patterns. Most streams that cross outcrops of the Madison Limestone and Minnelusa Formation lose all or large part of their streamflow to aquifer recharge. Streams that are predominantly spring fed have relatively stable streamflow, varying slightly with dry and wet precipitation cycles. Most streams in Lawrence County generally have calcium magnesium bicarbonate type waters. The sites from the mineralized area of central Lawrence County vary slightly from other streams in Lawrence County by having higher concentrations of sodium, less bicarbonate, and more sulfate. False Bottom Creek near Central City has more sulfate than bicarbonate. Nitrogen, phosphorous, and cyanide concentrations were at or near the laboratory reporting limits for most sites and did not exceed any of the water-quality standards. Nitrite plus nitrate concentrations at Annie Creek near Lead, Whitetail Creek at Lead, Squaw Creek near Spearfish, and Spearfish Creek below Robison Gulch were somewhat higher than at other sites. Mining activity, agricultural activity, and domestic development are possible sources of nitrogen to the streams. Increased mining activities were identified as the probable cause of increased nitrogen concentrations in Annie Creek. In the mineralized area of the northern Black Hills, detectable concentrations of trace elements are common in stream water, occasionally exceeding beneficial-use and aquatic-life criteria. In addition, many basins have been disturbed by both historical and recent mining operations and cleanup activities. The maximum dissolved arsenic concentration at Annie Creek near Lead (48 micrograms per liter) approached the current arsenic drinking-water standard. Concentrations at or greater than 5 micrograms per liter were found in samples from Annie Creek near Lead, Spearfish Creek above Spearfish, Whitetail Creek at Lead, and False Bottom Creek near Spearfish. Bear Butte Creek near Deadwood had one sample with a dissolved copper concentration that exceeded acute and chronic aquatic-life criteria. Bear Butte Creek near Deadwood had several manganese concentrations that exceeded the secondary maximum contaminant level of 50 micrograms per liter. Bed-sediment and water-quality data from selected sites in small drainage basins were used to determine if factors such as pH, arsenic concentrations in bed sediments, and calcite saturation control dissolved arsenic concentrations. Arsenic solubility is controlled by adsorption, mainly on ferrihydrite. In addition, adsorption/desorption of arsenic is controlled by the pH of the stream, with high arsenic concentrations appearing only at higher pH conditions (above 8). There are significant arsenic sources available to almost all the small streams of the northern Black Hills mining area, but arsenic is less mobile in streams that are not influenced to the higher pH values by calcite. Streams where arsenic is more mobile have lower iron concentrations in their bed sediments, and they have relatively high concentrations of calcite Additional water-quality data have been collected as part of other studies or monitoring programs by the South Dakota Department of Environment and Natural Resources, U.S. Environmental Protection Agency, U.S. Forest Service, and the U.S. Geological Survey. Summaries of selected data from these other sources are included as additional information.

South Dakota↗
USGS2002

Analysis of nitrate (NO3-N) concentration trends in 25 ground-water-quality management areas, Idaho, 1961-2001

In Idaho, drinking-water supplies are pumped from relatively shallow ground-water zones where water quality has great potential for degradation by land- and water-use activities. One indicator of water quality, and one of the most widespread contaminants in Idaho ground water related to land and water uses, is dissolved nitrate. In December 2000, the U.S. Geological Survey, in cooperation with the Idaho Department of Environmental Quality, began a study to compile and assess nitrate data for ground water in 25 ground-water-quality management areas in Idaho. The primary objective of the study was to determine whether statistically significant trends in ground-water concentrations were discernible. Data included ground-water analyses but not analyses of water from springs, drains, or thermal water sources. A total of 8,465 nitrate analyses were compiled from 2,931 wells in the 25 priority areas; analyses dates ranged from June 1961 to February 2001. A time-period comparison was used to assess general trends in nitrate concentrations within individual priority areas. A time-series comparison was used to assess trends in nitrate concentrations from selected wells in each priority area. In time-period assessments, general trends in an area were evaluated by compiling nitrate data for selected time intervals to determine whether the population distributions were significantly different between one period and another. Data within each priority area were sorted into decades— 1970s, 1980s, and 1990s—for long-term trend assessment. The 1990s data also were divided into sets of selected years corresponding to Statewide Ambient Ground-Water Quality Program sampling cycles—1991 through 1994, 1995 through 1998, and a partial cycle, 1999 through 2000—for shortterm trend assessment. Data were analyzed by summary statistics, boxplots, and the Mann- Whitney statistical test. Long-term increasing trends in nitrate concentrations were evident for 6 of 25 priority areas, and long-term decreasing trends were evident for 4 of 25 areas. Short-term increasing trends were evident for 7 of 25 areas, and a short-term decreasing trend was evident for only 1 area. No long-term nitrate trends were evident for 7 of 25 areas, and no shortterm trends were evident for 15 of 25 areas. Data were insufficient for long-term trend assessment in 8 areas and for short-term assessment in 2 areas. Time-series trend analyses were conducted on data from wells with 7 or more nitrate analyses and longest periods of record, at least 10 years between oldest and most recent analyses. Because long-term records were available for so few wells and well construction data were not available for several of these wells, time-series analyses were not helpful to the nitrate trend assessment study. Trend results may be strongly affected by well construction, hydrogeologic environments, and changes in density and areal distribution of wells and analyses. The utility of nitrate trend assessments in priority areas would be improved by more consistent and specific well location descriptions between agencies; well construction and major water-yielding zone information to accompany the water-quality data for each well; and addition of historical nitrate data to data bases, particularly analyses prior to about 1990. Investigations of the possible effects of changing priority area boundaries and time periods on both long-term and short-term trend assessments are needed. Addition of these kinds of information would allow assessment of trends associated with hydrology and geology of each area and would provide a much stronger basis for trend assessment than currently possible.

Idaho↗
USGS1979

Summary report of the sediments, structural framework, petroleum potential, and environmental conditions of the United States Mid-Atlantic continental margin in area of proposed Oil & Gas Lease Sale No. 59

This report has been compiled to update and summarize the geological information concerning the area of the Atlantic continental margin off the U.S. Mid-Atlantic proposed for Oil and Gas Lease Sale No. 59 (fig. 1). The region of interest lies between 35° and 41° N and 70.5° and 76° W. The north-south dimension is about 660 km (356 nautical miles, 410 statute miles) and the maximum east-west dimension is approximately 250 km (135 nautical miles, 155 statute miles). The area is centered toward the outer Continental Shelf off Delaware and contains more than 154,000 km2 (38,000,000 acres) off the coasts of North Carolina, Virginia, Maryland, Delaware, New Jersey and New York. Water depths within the region range from 20 to slightly more than 4,000 m (fig. 1). This report begins with a discussion of the regional geology and geophysics, followed by a description of the oil and gas potential and potential environmental hazards.

Delaware, Maryland, New Jersey, New York, North Ca↗
USGS2012

Methods to characterize environmental settings of stream and groundwater sampling sites for National Water-Quality Assessment

Characterization of natural and anthropogenic features that define the environmental settings of sampling sites for streams and groundwater, including drainage basins and groundwater study areas, is an essential component of water-quality and ecological investigations being conducted as part of the U.S. Geological Survey's National Water-Quality Assessment program. Quantitative characterization of environmental settings, combined with physical, chemical, and biological data collected at sampling sites, contributes to understanding the status of, and influences on, water-quality and ecological conditions. To support studies for the National Water-Quality Assessment program, a geographic information system (GIS) was used to develop a standard set of methods to consistently characterize the sites, drainage basins, and groundwater study areas across the nation. This report describes three methods used for characterization-simple overlay, area-weighted areal interpolation, and land-cover-weighted areal interpolation-and their appropriate applications to geographic analyses that have different objectives and data constraints. In addition, this document records the GIS thematic datasets that are used for the Program's national design and data analyses.

Scientific Investigations Report↗
USGS2004

Overview--Development of a geodatabase and conceptual model of the hydrogeologic units beneath Air Force Plant 4 and Naval Air Station-Joint Reserve Base Carswell Field, Fort Worth, Texas

Air Force Plant 4 (AFP4) and adjacent Naval Air Station-Joint Reserve Base Carswell Field (NAS–JRB) at Fort Worth, Tex., constitute a contractor-owned, government-operated facility that has been in operation since 1942. Contaminants from the 3,600-acre facility, primarily volatile organic compounds (VOCs) and metals, have entered the ground-water-flow system through leakage from waste-disposal sites and from manufacturing processes. Environmental data collected at AFP4 and NAS–JRB during 1993–2002 created the need for consolidation of the data into a comprehensive temporal and spatial geodatabase. The U.S. Geological Survey (USGS), in cooperation with the U.S. Air Force Aeronautical Systems Center Environmental Management Directorate, developed a comprehensive geodatabase of temporal and spatial environmental data associated with the hydrogeologic units beneath the facility. A three-dimensional conceptual model of the hydrogeologic units integrally linked to the geodatabase was designed concurrently. Three hydrogeologic units—from land surface downward, the alluvial aquifer, the GoodlandWalnut confining unit, and the Paluxy aquifer—compose the subsurface of interest at AFP4 and NAS–JRB. The alluvial aquifer consists primarily of clay and silt with sand and gravel channel deposits that might be interconnected or interfingered. The Goodland-Walnut confining unit directly underlies the alluvial aquifer and consists of limestone, marl, shale, and clay. The Paluxy aquifer is composed of dense mudstone and fine- to coarse-grained sandstone

Texas↗
USGS2009

Description and evaluation of numerical groundwater flow models for the Edwards Aquifer, south-central Texas

A substantial number of public water system wells in south-central Texas withdraw groundwater from the karstic, highly productive Edwards aquifer. However, the use of numerical groundwater flow models to aid in the delineation of contributing areas for public water system wells in the Edwards aquifer is problematic because of the complex hydrogeologic framework and the presence of conduit-dominated flow paths in the aquifer. The U.S. Geological Survey, in cooperation with the Texas Commission on Environmental Quality, evaluated six published numerical groundwater flow models (all deterministic) that have been developed for the Edwards aquifer San Antonio segment or Barton Springs segment, or both. This report describes the models developed and evaluates each with respect to accessibility and ease of use, range of conditions simulated, accuracy of simulations, agreement with dye-tracer tests, and limitations of the models. These models are (1) GWSIM model of the San Antonio segment, a FORTRAN computer-model code that pre-dates the development of MODFLOW; (2) MODFLOW conduit-flow model of San Antonio and Barton Springs segments; (3) MODFLOW diffuse-flow model of San Antonio and Barton Springs segments; (4) MODFLOW Groundwater Availability Modeling [GAM] model of the Barton Springs segment; (5) MODFLOW recalibrated GAM model of the Barton Springs segment; and (6) MODFLOW–DCM (dual conductivity model) conduit model of the Barton Springs segment. The GWSIM model code is not commercially available, is limited in its application to the San Antonio segment of the Edwards aquifer, and lacks the ability of MODFLOW to easily incorporate newly developed processes and packages to better simulate hydrologic processes. MODFLOW is a widely used and tested code for numerical modeling of groundwater flow, is well documented, and is in the public domain. These attributes make MODFLOW a preferred code with regard to accessibility and ease of use. The MODFLOW conduit-flow model incorporates improvements over previous models by using (1) a user-friendly interface, (2) updated computer codes (MODFLOW–96 and MODFLOW–2000), (3) a finer grid resolution, (4) less-restrictive boundary conditions, (5) an improved discretization of hydraulic conductivity, (6) more accurate estimates of pumping stresses, (7) a long transient simulation period (54 years, 1947–2000), and (8) a refined representation of high-permeability zones or conduits. All of the models except the MODFLOW–DCM conduit model have limitations resulting from the use of Darcy’s law to simulate groundwater flow in a karst aquifer system where non-Darcian, turbulent flow might actually dominate. The MODFLOW–DCM conduit model is an improvement in the ability to simulate karst-like flow conditions in conjunction with porous-media-type matrix flow. However, the MODFLOW–DCM conduit model has had limited application and testing and currently (2008) lacks commercially available pre- and post-processors. The MODFLOW conduit-flow and diffuse-flow Edwards aquifer models are limited by the lack of calibration for the northern part of the Barton Springs segment (Travis County) and their reliance on the use of the calibrated hydraulic conductivity and storativity values from the calibrated Barton Springs segment GAM model. The major limitation of the Barton Springs segment GAM and recalibrated GAM models is that they were calibrated to match measured water levels and springflows for a restrictive range of hydrologic conditions, with each model having different hydraulic conductivity and storativity values appropriate to the hydrologic conditions that were simulated. The need for two different sets of hydraulic conductivity and storativity values increases the uncertainty associated with the accuracy of either set of values, illustrates the non-uniqueness of the model solution, and probably most importantly demonstrates the limitations of using a one-layer model to represent the heterogeneous hydrostratigraphic units composing the Edwards aquifer. In general, the best matches or agreement between groundwater flow directions inferred by numerical model simulation, and by dye-tracer tests, are observed where model outputs accurately reproduce the configuration of the potentiometric surface with regard to the positions of major and minor groundwater troughs and divides. None of the models, with the possible exception of the MODFLOW–DCM conduit model, has a documented capability to accurately simulate travel times for conduit-dominated velocities in the Edwards aquifer. Public water system assessments of wells in the Barton Springs segment of the Edwards aquifer, and elsewhere where conduit-flow conditions are thought to dominate aquifer hydraulic behavior, might be enhanced by use of either the MODFLOW–DCM model or the newly developed U.S. Geological Survey MODFLOW Conduit-Flow Process module for MODFLOW–2005, because each incorporates a type of dual or triple hydraulic conductivity approach and has the capability to explicitly simulate turbulent flow and conduit hydraulic characteristics.

Texas↗
USGS1998

Water-quality assessment of the lower Illinois River Basin: Environmental setting

The lower Illinois River Basin (LIRB) encompasses 18,000 square miles of central and western Illinois. Historical and recent information from Federal, State, and local agencies describing the physiography, population, land use, soils, climate, geology, streamflow, habitat, ground water, water use, and aquatic biology is summarized to describe the environmental setting of the LIRB. The LIRB is in the Till Plains Section of the Central Lowland physiographic province. The basin is characterized by flat topography, which is dissected by the Illinois River. The drainage pattern of the LIRB has been shaped by many bedrock and glacial geologic processes. Erosion prior to and during Pleistocene time created wide and deep bedrock valleys. The thickest deposits and most major aquifers are in buried bedrock valleys. The Wisconsinan glaciation, which bisects the northern half of the LIRB, affects the distribution and characteristics of glacial deposits in the basin. Agriculture is the largest land use and forested land is the second largest land use in the LIRB. The major urban areas are near Peoria, Springfield, Decatur, and Bloomington-Normal. Soil type and distribution affect the amount of soil erosion, which results in sedimentation of lakes and reservoirs in the basin. Rates of soil erosion of up to 2 percent per year of farmland soil have been measured. Many of the 300 reservoirs, lakes, and wetlands are disappearing because of sedimentation resulting from agriculture activities, levee building, and urbanization. Sedimentation and the destruction of habitat appreciably affect the ecosystem. The Illinois River is a large river-floodplain ecosystem where biological productivity is enhanced by annual flood pulses that advance and retreat over the flood plain and temporarily expand backwater and flood-plain lakes. Ground-water discharge to streams affects the flow and water quality of the streams. The water budget of several subbasins show variability in ground-water contribution from runoff and storage. More than half of the drinking water, including domestic and public-supply use, in the LIRB is from ground water. Fifty-two percent of the public-supply water is from surface water. Ground-water withdrawals mostly are from glacial sand and gravel aquifers. Structural features, such as monoclines, synclines, and anticlines, in the buried bedrock affect the water quality of the aquifers. There are five natural environmental divisions in the LIRB. The Grand Prairie covers most of the northeastern half of the basin, and the Western Forest-Prairie covers most of the southwestern half. Implications of environmental setting for water quality in the LIRB are related primarily to land use. The balanced fish community indicates that the lower Illinois River is affected less from urban and industrial waste than the upper Illinois River. A decrease in dissolved oxygen concentrations and turbidity in the lower reaches of the basin in 1993 have resulted from the recent influx of European zebra mussels to the LIRB. Many factors affect water quality in the LIRB. Bedrock and surface topography, type of glacial material, and land use most directly affect water quality in the basin.

Illinois↗
USGS2014

Geologic sources and concentrations of selenium in the West-Central Denver Basin, including the Toll Gate Creek watershed, Aurora, Colorado, 2003-2007

Toll Gate Creek, in the west-central part of the Denver Basin, is a perennial stream in which concentrations of dissolved selenium have consistently exceeded the Colorado aquatic-life standard of 4.6 micrograms per liter. Recent studies of selenium in Toll Gate Creek identified the Denver lignite zone of the non-marine Cretaceous to Tertiary-aged (Paleocene) Denver Formation underlying the watershed as the geologic source of dissolved selenium to shallow ground-water and surface water. Previous work led to this study by the U.S. Geological Survey, in cooperation with the City of Aurora Utilities Department, which investigated geologic sources of selenium and selenium concentrations in the watershed. This report documents the occurrence of selenium-bearing rocks and groundwater within the Cretaceous- to Tertiary-aged Denver Formation in the west-central part of the Denver Basin, including the Toll Gate Creek watershed. The report presents background information on geochemical processes controlling selenium concentrations in the aquatic environment and possible geologic sources of selenium; the hydrogeologic setting of the watershed; selenium results from groundwater-sampling programs; and chemical analyses of solids samples as evidence that weathering of the Denver Formation is a geologic source of selenium to groundwater and surface water in the west-central part of the Denver Basin, including Toll Gate Creek. Analyses of water samples collected from 61 water-table wells in 2003 and from 19 water-table wells in 2007 indicate dissolved selenium concentrations in groundwater in the west-central Denver Basin frequently exceeded the Colorado aquatic-life standard and in some locations exceeded the primary drinking-water standard of 50 micrograms per liter. The greatest selenium concentrations were associated with oxidized groundwater samples from wells completed in bedrock materials. Selenium analysis of geologic core samples indicates that total selenium concentrations were greatest in samples containing indications of reducing conditions and organic matter (dark gray to black claystones and lignite horizons). The Toll Gate Creek watershed is situated in a unique hydrogeologic setting in the west-central part of the Denver Basin such that weathering of Cretaceous- to Tertiary-aged, non-marine, selenium-bearing rocks releases selenium to groundwater and surface water under present-day semi-arid environmental conditions. The Denver Formation contains several known and suspected geologic sources of selenium including: (1) lignite deposits; (2) tonstein partings; (3) organic-rich bentonite claystones; (4) salts formed as secondary weathering products; and possibly (5) the Cretaceous-Tertiary boundary. Organically complexed selenium and/or selenium-bearing pyrite in the enclosing claystones are likely the primary mineral sources of selenium in the Denver Formation, and correlations between concentration of dissolved selenium and dissolved organic carbon in groundwater indicate weathering and dissolution of organically complexed selenium from organic-rich claystone is a primary process mobilizing selenium. Secondary salts accumulated along fractures and bedding planes in the weathered zone are another potential geologic source of selenium, although their composition was not specifically addressed by the solids analyses. Results from this and previous work indicate that shallow groundwater and streams similarly positioned over Denver Formation claystone units at other locations in the Denver Basin also may contain concentrations of dissolved selenium greater than the Colorado aquatic-life standard or the drinking- water standard.

Colorado↗
USGS2018

Surface-water quality in the Lycoming Creek watershed, north-central Pennsylvania, August 1–3, 2011

This report presents the methodology and results for a study of surface-water quality of the Lycoming Creek watershed in north-central Pennsylvania during August 1–3, 2011. The study was done in cooperation with the Williamsport Municipal Water Authority and the Pennsylvania Department of Environmental Protection. Samples of stream water were collected from 31 sites in an area of exploration and production of natural gas from the Marcellus Shale – 5 sites on the main stem of Lycoming Creek and 26 sites on tributary streams. The samples provide a snapshot of the base-flow water-quality conditions, which helps document the spatial variability in water-quality and could be useful for assessing future changes. The 272-square mile Lycoming Creek watershed is located within Lycoming, Tioga, and Sullivan Counties in north-central Pennsylvania. Lycoming Creek flows 37.5 miles to its confluence with the West Branch Susquehanna River in the city of Williamsport. A well field that supplies water for Williamsport captures some water that has infiltrated the streambed of Lycoming Creek. Because the stream provides a source of water to the well field, this study focused on the stream-water quality as it relates to drinking-water standards as opposed to aquatic life. Surface-water samples collected at 20 sites by the U.S. Geological Survey and 11 sites by the Pennsylvania Department of Environmental Protection were analyzed by each agency for a suite of constituents that included major ions, trace metals, nutrients, and radiochemicals. None of the analytical results failed to meet standards set by the U.S. Environmental Protection Agency as maximum contaminant levels for drinking water. Results of the sampling show the substantial spatial variability in base-flow water quality within the Lycoming Creek watershed caused by the interrelated effects of physiography, geology and land use. Dissolved-solids concentrations ranged from less than the laboratory reporting level of 12 milligrams per liter (mg/L) in Wolf Run, a pristine forested watershed, to 202 mg/L in Bottle Run, a watershed with more development near Williamsport. Concentrations of the major ions ranged over at least one order of magnitude; chloride had the largest range from 0.3 to 45.4 mg/L, with nine samples exceeding the natural background level of about 5 mg/L, most likely because of the application of deicing salt to roads. Trace constituents were even more variable, with concentrations for aluminum, cobalt, and manganese ranging over almost four orders of magnitude. Samples from Red Run and Dutchman Run, watersheds that experienced past coal mining activity, had concentrations of 11 metals that were significantly greater than in samples collected from other streams. Samples from Bottle Run, the tributary of Lycoming Creek nearest to Williamsport, contained elevated levels of chloride and boron, constituents associated with urban development.

Pennsylvania↗