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Revisiting the utility of regional-scale, high-quality geophysical data in mineral exploration - A case study featuring the Mammoth Magnetic Anomaly, Pinal County, Arizona

Regional aeromagnetic surveys passively measure the total magnetic intensity (TMI) and are a foundational tool used in mineral exploration (Airo, 2015). With the increased global demand and the number of critical mineral resources required for manufacturing high-tech devices, developing high-quality, regional-scale geophysical surveys could aid critical mineral exploration efforts and geologic mapping. In 2019, the U. S. Geological Survey launched the Earth Mapping Resources Initiative (Earth MRI) to modernize the geologic and geophysical mapping of regions that have the potential to contain critical mineral resources within the United States. In support of planning Earth MRI geophysical surveys, Drenth and Grauch (2019) defined five aeromagnetic data quality rankings (rank 1 through rank 5) applying them to the airborne geophysical survey inventory of the United States (Johnson et al., 2021). Rank 1 aeromagnetic surveys are of the highest quality, meeting modern standards and allowing best practices for qualitative and quantitative interpretation; whereas rank 5 aeromagnetic surveys are of the lowest quality, being useful only for qualitative interpretation of broad features. Through the Earth MRI effort, 48 high-quality, regional-scale rank 1 and 2 airborne magnetic and radiometric geophysical surveys have been planned, collected, or publicly release through May 2025 (U. S. Geological Survey, 2025). Here, a portion of a rank 1 Earth MRI aeromagnetic survey in southeast Arizona is presented and compared to a legacy rank 5 aeromagnetic survey over the Mammoth Magnetic Anomaly (MMA), demonstrating how modern, high-quality aeromagnetic data improves our view of crustal geology, aiding mineral exploration.

Arizona

Sedimentological and geochemical characterization of lacustrine deposits of the Babouri-Figuil basin, northern Cameroon: Implications for source rocks distribution and petroleum exploration

The West and Central African Rift System (WCARS) refers to the series of Cretaceous rift basins where commercial hydrocarbon accumulations have been discovered. Some of the WCARS frontier basins are currently being investigated to increase our understanding of these basins in light of new commercial discoveries. The present study was performed in the Babouri-Figuil Basin (BFB), which is genetically related to the WCARS and constitutes an area of interest in terms of petroleum prospecting, where the distribution of petroleum source rocks and potential targets for petroleum exploration across the entire basin is poorly understood. For the current study, an integrated facies analysis along with organic and inorganic geochemical techniques were applied to the basin's Cretaceous deposits with the aim of reconstructing the paleodepositional environment, assessing factors that triggered the input of organic matter, and providing a spatial overview of the organic matter accumulation in the basin based on outcrop samples. An alluvial fan-lacustrine-braided river system is inferred from the facies analysis of the stratigraphic sequence consisting of conglomerate, sandstone, siltstone, limestone, marlstone, and claystone. Bulk analysis of organic matter reveals that black shale and massive claystone are the main prospective petroleum source rocks in the basin. Inorganic geochemical analyses reveal the influence of anoxic conditions, moderate to high primary productivity, and low terrigenous inputs in organic matter enrichment. The formations rich in organic matter are predominantly concentrated in the western and eastern parts of the basin which may represent areas with depressions, characterized by high accommodation space. In terms of the regional context of the WCARS rift basins, typical hydrocarbon exploration in the BFB may target basal-conglomerate, sandstone beds situated directly above or/and interbedded with the Lower Cretaceous source rocks, and the Upper Cretaceous sandstone beds. Basement rocks (granite, granodiorite, and gneisses) and oil shale deposits may represent potential unconventional hydrocarbon exploration. The current integrated study provides an insight that should guide future hydrocarbon exploration campaigns in the basin.

Babouri-Figuil basin

USGS 2025 critical minerals review

The United States Geological Survey (USGS) provides scientific information for the Department of Interior and the nation, consistent with its original mission expressed in the Organic Act of 1879 (43 U.S.C. 31): “the classification of the public lands and examination of the geological structure, mineral resources, and products within and outside the national domain.” Legislation such as the Energy Act of 2020 and the 2022 Infrastructure Investment and Jobs Act (43 USC 31l) and recent executive actions (Executive Orders 14154 , 14153, 14241 Secretary’s Orders 3417, 3418, 3422, 3436) underscore the importance of mineral resources and focus USGS activities on mapping and assessing mineral resources, with a particular focus on those presently identified as critical, both in ground and above ground in mine wastes. This article reviews selected activities and accomplishments by the USGS Mineral Resources Program related to critical minerals in 2025. Highlights include a new List of Critical Minerals, a first-ever national mine waste inventory, international minerals partnerships, mineral resource assessment advancements, and national data collection activities and outcomes of the Earth Mapping Resources Initiative (Earth MRI). The selected contributions are not comprehensive but are intended to demonstrate USGS leadership in critical mineral mapping and assessment, the importance of domestic and global partnerships, and the breadth of research activities that are responsive to national needs and priorities.

Mining Engineering

An orbital comparison of a late mantling unit on Aeolis Mons with other erosion-resistant strata explored by MSL in Gale crater, Mars

Previous investigations along Curiosity 's traverse in Gale crater have explored the relationship between orbital and in situ observations. This work aims to better understand the geologic environment of units only observable from orbit and compare them to the properties of units examined by Curiosity . Here, we map an erosion-resistant dark-toned mantling unit that overlies the modern topography of Aeolis Mons (informally known as Mt. Sharp) and compare this unit to two other previously mapped dark-toned resistant units, the marker band and the mound skirting unit (MSU), that have been inferred to represent different geologic environments (lacustrine and aeolian, respectively). Visible to short wave infrared spectra from the Compact Reconnaissance Imaging Spectrometer for Mars and visual images from the High Resolution Imaging Science Experiment and Context Cameras aboard the Mars Reconnaissance Orbiter are used for this comparison. Spectral data suggest a mafic composition with minor alteration, although the composition varies more with location around Mt. Sharp rather than between units. Morphologically, the mantling unit has strong similarities to the marker band based on their consistent low-albedo, erosion-resistance, and smooth appearance, contrasting with the highly variable surface texture of the MSU. We hypothesize that all three units had a similar sediment source but experienced aqueous alteration at different times: early ubiquitous cementation in a surface aqueous environment in the mantling unit and marker band versus patchy late diagenesis in the MSU. If true, these results suggest that water activity continued within the Gale crater long after the erosion of Mt. Sharp.

JGR Planets

An exploration of the relative influence of physical models for Omori’s law

Omori’s law states that the rate of aftershocks decays as a function of inverse time. There are multiple physical explanations that we reduce into a nonlinear mixed effects relation of three terms: (1) a Rate/State expression that can account for static/dynamic and viscoelastic triggering caused directly by the mainshock, (2) a fluid diffusion triggering term, and (3) a randomized secondary triggering (cascade) term. We fit free physical-model parameters to an observed aftershock sequence through two nonlinear regression methods to find the relative contributions of physics-based models in an observed aftershock sequence. Results from both methods show that Rate/State models overpredict aftershock rates by ∼0–30%. Secondary aftershocks cause a net negative contribution (seismicity rate reduction that corrects overprediction by other terms) ranging between ∼0 and 30%. All regression solutions yield negative secondary triggering contributions without being guided to do so. A physical explanation for this is that aftershock occurrence relieves stress from the crust, ultimately causing the sequence to extinguish itself. Fluid diffusion triggering contributions range from ∼0 to 20%. Diffusion processes are observed to be shorter in time than the full duration of an aftershock sequence and they are also spatially limited, diminishing their influence. Our results apply to an aftershock decay curve from the 2016 Central Apennines earthquake sequence, meaning that our specific results may not be general. Our primary conclusion is that any one physical model cannot alone fit the observed sequence as well as the combination of three we investigated.

Frontiers in Earth Science

Exploration for blind geothermal systems in the eastern Great Basin of Utah: An update on the “Lund North” INGENIOUS detailed study site

Existing geothermal production in Utah is commonly collocated with surficial expressions of geothermal heat including active hot springs and hot spring deposits. However, geothermal potential across the Great Basin region is thought to be much higher for hidden or blind geothermal systems. Accordingly, exploration techniques that can locate geothermal resources that lack surface thermal features could support future development of these systems. The goal of the INGENIOUS project is to reduce exploration risk and discover new, economically viable hidden geothermal systems in the Great Basin region. This paper summarizes the efforts and preliminary results of blind geothermal resource prospecting in Utah as part of the larger INGENIOUS project. The Lund North site in the Basin and Range province of southwest Utah was designated as the fourth detailed study site for the project. The site was initially identified from the preliminary Play Fairway Analysis (PFA) geothermal favorability map, which is based on various data elements, and the identification of favorable structural settings across Utah. This site contains existing legacy data including a thermal gradient borehole with a heat-flow value exceeding 220 mW/m 2 . New data collected at this site include terrestrial gravity, magnetotellurics, transient electromagnetics, fluid geochemistry, geologic mapping, UAV-based lidar, paleomagnetism, aeromagnetic surveys, and a shallow temperature survey. Preliminary data and model interpretations corroborate the presence of a large, east-dipping, northeast-southwest-trending normal fault on the edge of a typical Basin and Range graben. Quaternary fault mapping refined by high-resolution lidar surveys suggests a complex step over fault geometry. Utilizing multi-disciplinary datasets for further site assessment at Lund North will facilitate the development of a local-scale PFA and geothermal conceptual model. This new data will be used to site successive thermal gradient drilling to verify heat flow with temperatures at depth at the Lund North site and further investigate the existence of a local geothermal system.

Utah

Using public participatory geographic information systems (PPGIS) to explore uses and values for Mojave Trails National Monument, California

Many people ascribe a variety of values to public lands and waters, but some values are more difficult to assess and quantify than others. Public participatory geographic information systems (PPGIS) are tools that have been used to help quantify and map the public’s diverse values for a landscape. This work describes the first known Office of Management and Budget–approved use of PPGIS by a Department of the Interior bureau. The U.S. Geological Survey developed an internet-based application to aid in gathering PPGIS data, called Values Mapping for Planning in Regional Ecosystems (VaMPIRE). Further, this work describes the first pilot of the VaMPIRE application in coordination with the Bureau of Land Management to collect spatial data and other survey data regarding the public’s uses of and values for locations within Mojave Trails National Monument. We emailed the link to the VaMPIRE application to an interested party email list in 2024 with 207 valid emails and received 74 responses; we also received 47 responses from members of an off-roading social media group. Of the list of 16 value options, recreation was the most popular value for the monument, followed by wilderness and inspirational. Over 1,000 points were placed throughout the monument, indicating locations people use or value, with the locations spread throughout the entire monument. Additionally, most survey respondents stated their ability to receive benefits in locations they mapped would not change in response to a hypothetical scenario related to recreational facility development. This report describes exploratory results from the first use of the VaMPIRE tool in Mojave Trails National Monument and includes reflections on how the process went and considerations for future use of VaMPIRE.

California

Alteration mapping in granitic gneiss using handheld geophysical and geochemical instruments: Implications for iron oxide-apatite and rare earth elements exploration

The Adirondack Mountains of New York, U.S.A. contain iron oxide-apatite (IOA) mineral deposits with variable concentrations of rare earth elements (REE). The IOA mineral deposits are typically hosted in the Lyon Mountain Granite Gneiss and are spatially correlated with extensive Na metasomatism (albitization) of the surrounding country rocks, although some mineral deposits also occur in metagabbro, paragneiss, and anorthosite hosts. The location of albitization zones is key to finding new IOA mineral deposits and better understanding the mineralization processes associated with their genesis. However, the Na alteration zones are generally not visibly identifiable in outcrop or hand specimens because the color and textural changes are subtle and are thus difficult to map. Here, we discuss the results from testing two spectroscopic techniques (handheld, field gamma-ray spectroscopy, and portable X-ray fluorescence (pXRF)) to characterize albitization zones surrounding IOA mineral deposits. The gamma-ray and pXRF spectrometers successfully distinguished the relative intensity of alteration in the Lyon Mountain Granite Gneiss based on the K abundance. The measured K content decreases towards the IOA mineral deposits, and the magnitude and width of the gradient are similar along the strike of each mineral deposit. Elevated Th and U values are present in host rocks adjacent to REE-bearing IOA mineral deposits. The pXRF and gamma-ray spectrometer K values are remarkably consistent with laboratory-based, whole-rock XRF compositional data and, therefore, useful for semi-quantitative analysis. Notably, albitization aureoles are consistent around REE-rich and REE-poor mineral deposits, suggesting that saline fluids are essential for the petrogenesis of IOA mineral deposits but may not be critical to REE mineralization. Ultimately, this study demonstrates the utility of handheld gamma-ray and pXRF spectrometry for identifying otherwise cryptic albitization gradients associated with IOA mineral deposits in granitic gneiss.

New York

Formation of the Mount Weld rare earth element deposit, Western Australia: A carbonatite-derived laterite

Carbonatite-hosted rare earth element (REE) deposits are the primary source of the world’s light REEs. The Mount Weld REE deposit in Western Australia is hosted in a lateritic sequence that reflects supergene enrichment of the underlying carbonatite. Water-rock interaction is a key to the formation of this world-class deposit. REE enrichment in the laterite is controlled by the breakdown of primary minerals, the release and transport of REEs, and the formation of secondary minerals. Secondary REE-bearing phosphate minerals are the primary REE-host phases in the laterite ore with monazite as the dominant phase; other REE-bearing phases include rhabdophane, cerianite, churchite, florencite, and crandallite subgroup minerals. Profiles through the laterite show that in the REE-rich zone, apatite and primary calcite and dolomite have broken down such that the loss of Ca and Mg, as well as Si and K, leads to a relative increase in the REEs. Sequestering of REEs in secondary mineral phases formed by groundwater further enhances the REE concentration.

Mount Weld Mine

Evaluation of stream capture related to groundwater pumping, middle Humboldt River Basin, Nevada

Historical, future, and potential stream capture from groundwater pumping in the middle Humboldt River Basin (MHRB), Nevada, is estimated using a calibrated numerical groundwater flow model. The model was developed to estimate (1) stream capture, which is the change in flux between the groundwater system and the Humboldt River and tributaries, and (2) change in streamflow, which is the change in streamflow estimated for the Imlay gage on the Humboldt River (U.S. Geological Survey streamgage 10333000). Historical stream capture for water years (WYs) 1961–2015 is estimated using recorded and estimated groundwater pumping during that period. Future (predictive) stream capture was based on historical stresses (WYs 1961–2015) using a scenario that simulated non-mine pumping from WY 2015 at a uniform rate for 100 years into the future. Potential stream capture throughout the middle Humboldt River Basin from groundwater pumping during varying durations of time are presented in a series of capture maps. Maps also are presented that show the potential to capture from groundwater evapotranspiration, as well as the storage changes for pumping duration of 100 years. Estimates of historical stream capture from the mainstem Humboldt River during the early 1960s are less than 400 acre-feet per year (acre-ft/yr) when groundwater withdrawals and pumping rates were relatively small compared to more recent times. In the late 1980s and early 1990s, groundwater withdrawals increased and estimated historical stream capture also increased from about 4,000 acre-ft/yr in the late 1980s and early 1990s to as much as 18,800 acre-feet (acre-ft) in WY 1998. In WY 2015, estimated historical stream capture declined to about 13,000 acre-ft because of decreasing groundwater withdrawals and lower streamflow during the drought of WYs 2012–15, resulting in less stream water available for capture. Stream capture was estimated for 100 years into the future based on WY 2015 non-mine pumping rates and mine-dewatering activity through WY 2015. Stream capture is forecast to increase to about 23,000 acre-ft/yr, and streamflow in the Humboldt River could decrease by as much as 19,000 acre-ft/yr. Pumping for mine-dewatering and the associated discharge of that water affects streamflow in the Humboldt River at Imlay, Nevada (U.S. Geological Survey streamgage 10333000). Historically, from WYs 1991 to 2015, streamflow was greater at Imlay gage during active mine-dewatering from mine-water discharge operations and increased by as much as 105,000 acre-ft in WY 1998. The increase was attributed mostly to the discharge of groundwater from mine-related dewatering operations directly into the mainstem Humboldt River or its tributaries, with some of this increase associated with return flows from discharge to rapid infiltration basins. Results indicate that streamflow at Imlay gage is expected to decrease by as much as 1,600 acre-ft/yr 30 years after mine-related pumping and discharge are discontinued. The streamflow reductions at the Imlay gage are expected to then decrease to around 500 acre-ft/yr, 100 years after mine-related pumping and discharge are discontinued. Potential capture maps were produced for pumping durations of 10, 25, 50, and 100 years. Capture map results indicate that areas of greater potential stream capture occur adjacent to the Humboldt River and for upstream tributaries areas north of the Humboldt River.

Nevada

Global maps of critical mineral production in 2023

Introduction The global production of many mineral commodities, especially critical minerals, is concentrated in a few countries that have mineral resources and the infrastructure necessary to mine and process those resources. For this reason, the type and amount of mineral production differ by country. For example, many countries produce such metallic ores as gold and silver, whereas only a few countries produce magnesium, niobium, platinum-group metals, and rare earths. The concentration of mining and processing in certain countries necessitates the existence of a global supply chain. A mineral supply chain is the sequence of mining and processing of minerals and manufacturing of products. Mineral supply chains are global in scale, complex, and dynamic. Supply chain data can be used to understand how a country’s mineral resources and various economic, technical, and environmental factors affect the complexity of global supply chains. This fact sheet summarizes the world’s leading countries (those accounting for 5 percent or more of a commodity’s global production in 2023) for production of select mineral commodities (mainly critical minerals) in the mining and processing stages. These countries and the minerals they produce are synthesized on global maps to communicate the status of, and potential risk to, mineral commodity supply chains from geographic production concentration. Trade data from United Nations Statistics Division (2025) is used to support assessments of the observed production data.

Fact Sheet

Seamless Geologic Map Database for the Intermountain West, United States: A foundational dataset for mineral systems analysis

The Intermountain West has a complex geologic history, resulting in the formation of a diverse array of mineral deposits. Effective mineral exploration requires understanding the spatial and temporal relationships among geologic processes and events, a key focus of the mineral systems approach to exploration. This paper presents the Intermountain West Seamless Geologic Map Database, a unified dataset designed to support mineral exploration. Integrating geologic provinces, structural settings, and hydrothermal alteration, the database leverages the Seamless Integrated Geologic Mapping (SIGMa) extension to the USGS Geologic Map Schema (GeMS) to standardize geologic data from varied sources. SIGMa's hierarchical stratigraphic organization and feature-level metadata enhance data interoperability and reusability, enabling seamless query, analysis, and visualization of lithology, structural features, mineral deposits, geochronology, hydrothermal alteration. volcanic activity, and By providing a regionally consistent and dynamically evolving geologic map, this database provides a foundational framework for mineral exploration and geologic research. It also allows for an efficient workflow that expedites the publication of integrated geologic map databases.

Conference Paper

Evidence for organic and igneous carbon sources in the Mesoproterozoic Adirondack Highlands graphite district, New York

This study examined the origin of graphite mineralization in the Mesoproterozoic Adirondack Highlands. Flake graphite was mined from the historic mining district around Ticonderoga, New York, USA, from the 1850s to the 1920s. Most of the production and reserves from the district are disseminated graphite from feldspathic quartz schists (e.g., Dixon-American Graphite Co. mine, Faxon property, Flake Graphite Company). Protolith sediments of the schists were deposited in the Trans-Adirondack backarc basin at ca. 1.25 Ga and were metamorphosed to high grade at 1.18–1.15 Ga during the accretionary Shawinigan orogeny and at 1.09–1.02 Ga during the Ottawan phase of the Grenvillian orogeny. Major elements and carbon isotopes of graphite from schists (δ 13 C = −28.1‰ to −5.4‰ relative to Vienna Peedee belemnite) are consistent with derivation from organic carbon in protolith sandstones that devolatilized during metamorphism. Some small mines and prospects in the district mined graphitic calcite marbles and clinopyroxene ± scapolite skarns associated with a pegmatite suite dated by U-Pb in zircon to 1.04–1.01 Ga (e.g., Lead Hill and Crown Point deposits), and rare graphite veins are observed at several deposits. Hydrothermal flake graphite from pegmatites, skarns, and veins are distinct from graphite in schist-hosted deposits and have δ 13 C values that cluster around −7‰ to −5‰, consistent with deposition from igneous CO 2 . Covariation of carbon and oxygen stable isotopes and U-Pb zircon geochronology are not compatible with precipitation from fluids derived from country rock metapelites or marbles. Some graphite districts elsewhere show compelling evidence for remobilization and redeposition of sedimentary-derived carbon as hydrothermal graphite, sometimes as thick veins producing world-class, high-grade deposits. In the Adirondacks, there is evidence for two generations of graphite mineralization with distinct carbon sources: syngenetic graphite with an organic origin in Shawinigan quartz schists and epigenetic graphite with an igneous origin in Ottawan skarns and pegmatites.

New York

Trace elements in streambed sediment and fish liver at selected sites in the Upper Colorado River Basin, Colorado 1995-96

Trace elements were analyzed in streambed-sediment samples collected from 16 sites and in fish-liver samples collected from 14 sites in the Upper Colorado River Basin in Colorado as part of the National Water-Quality Assessment program. Sites sampled represented agricultural, mining, mixed, and urban/recreation land uses and background conditions. The results for 15 trace elements in streambed-sediment and in fish-liver samples are presented in this report. Fourteen of the selected trace elements were detected in streambed-sediment samples collected at all sites. Twelve of the selected trace elements were detected in fish liver at more than 50 percent of the sites. Cadmium, copper, selenium, and zinc were selected for a more detailed analysis. Cadmium, copper, and zinc concentrations in streambed sediment were highest at mining land-use sites in the Southern Rocky Mountains physiographic province. Selenium concentrations in streambed sediment were highest at an agricultural land-use site in the Colorado Plateau physiographic province. The concentration of trace elements in streambed sediment generally increased as particle size decreased. Concentrations of trace elements in fish liver generally did not follow the same relation to land use as concentrations in streambed sediment; however, cadmium concentrations in fish liver were highest at a mining land-use site in the Southern Rocky Mountains physiographic province, and selenium concentrations in fish liver were highest at an agricultural land-use site in the Colorado Plateau physiographic province. Copper and zinc concentrations in fish liver were highest at mixed land-use sites. Comparison of streambed-sediment and fish-liver concentrations to two other similar NAWQA studies in the Rocky Mountain region generally indicated similar patterns in relation to land use for streambed sediment, but not for fish liver. Cadmium, copper, and zinc concentrations in streambed sediment were highest at sites affected by mining in all three study units. Selenium concentrations in streambed sediment did not indicate relations among the three study units when compared to land use. Cadmium in fish liver was highest at sites affected by mining in all three study units. Copper, selenium, and zinc in fish liver did not indicate relations among the three study units when compared to land use.

Colorado

Modeling interconnected minerals markets with multicommodity supply curves: Examining the copper-cobalt-nickel system

Demand for many of the metals used in the energy transition is expected to grow rapidly. Many of these are by-products, often considered critical because their production responds weakly to prices and is instead tied to the economics of the host mineral. We present a model of prices and production for jointly produced commodities that accounts for interconnectivity between host and by-product markets at the mine level. We demonstrate this method using the copper–cobalt–nickel system, in which approximately 99% of cobalt is a by-product of copper or nickel mining. Our results show that the model more accurately captures the economic benefits of diversified mine outputs than previous approaches. Furthermore, changes in demand drivers for any two commodities produce non-linear effects on production and price. We challenge the prior best-practice assumption that cobalt cannot impact the copper or nickel markets. Recognizing the importance of both copper and cobalt for future electrification, we emphasize that incentivizing the copper industry to reduce cobalt supply risks could inadvertently undermine copper supply.

Nature Communications

Critical minerals in zinc ore—An update on Earth Mapping Resources Initiative Research in the Boulder Batholith region, Montana

Plain Language Summary U.S. Geological Survey research, in collaboration with Montana Technical University and Montana Bureau of Geology and Mines, is providing key critical mineral information that may have potential for critical mineral production of several mining districts in the Boulder Batholith region, to better understand the abundance and distribution of natural resources within this region. Continued research can be used to show the potential for previously undiscovered critical mineral resources in southwestern Montana and in other parts of the United States.

Montana

Top-down targeted network analysis of critical mineral commodities applied to international geochemistry database

The global demand for critical mineral commodities is rapidly increasing, making domestic production an important factor in supporting the economy and national security. Large scale, publicly available geochemical databases allow for the application of data informatics methods to interrogate critical mineral commodities data for correlations in deposit formation and distribution, particularly for identifying enrichment of multiple critical mineral commodities at the same deposit. In this study, we applied network analysis to the Critical Minerals Mapping Initiative (CMMI) ore geochemistry (Critical Minerals in Ores, CMiO) database to identify the high concentration (defined as 10× bulk crustal abundance) co-occurrence of different critical mineral commodities across a mineral system hierarchy from deposit environments to individual deposits. Identifying patterns or unique outliers in enrichment in network communities will allow for the location of secondary critical mineral commodity resources from under-utilized deposits. We find trends in the enrichment of critical mineral commodities in network-communities between the elements praseodymium (Pr), neodymium (Nd), terbium (Tb), and dysprosium (Dy) across multiple CMiO database deposit environments and groups down to specific deposit types and sites. A separate trend in network community deposition is observed as well between iridium (Ir) and platinum (Pt) in deposit environments, groups, types, and sites. Network analysis focused on critical minerals in magmatic-hydrothermal deposits identified multiple deposit sites from different deposit types within the CMiO database with concentrations of Dy, Nd, Tb, Pr, Ir, and Pt that are at least ten times greater than the crustal average. This approach can be applied to any target element(s) or deposit(s) of interest, allowing broad investigation of co-enriched critical mineral commodities.

Journal of Geochemical Exploration

Evolution of arsenic speciation during thermal treatment simulating wildfire heating in arsenic-rich sediments

Understanding arsenic transformations during wildfires can help better constrain the environmental impacts of increased wildfire intensity, frequency, and burned area. Previous studies have monitored the evolution of metal(loid) speciation at specific time/temperature endpoints, hampering the comprehension of the dynamic transformations of metal(loid)s during wildfires. Here, a novel approach, namely in situ time-resolved X-ray absorption near edge structure (TR-XANES) spectroscopy, was used for the first time to monitor the heat-induced redox transformations of arsenic (As) in two As-rich sediments with different characteristics. No arsenic transformations were observed in either sediment at room temperature or when the sediments were heated to a maximum temperature of 400 ºC. When heated to a maximum temperature of 600 or 700 ºC, As underwent complex, dynamic, and partially reversible redox transformations, the extent of which varied with sediment properties, initial As speciation, and heating temperature and duration. In the case of sediments initially containing As(V) and a low sulfide/sulfate ratio, the As(V) was reduced to As(III) over a short period of time, followed by immediate reoxidation of As(III) to As(V). The extent of the transient As reduction increased with increasing maximum temperature. The final As speciation at the end of the heating experiment was not substantially different from that at the beginning of the experiment. In contrast, in sediments that were best described by a more complex combination of reference compounds (As(V) coprecipitated with or adsorbed on iron oxide, arseniosiderite, arsenopyrite) with a high sulfide/sulfate ratio, As(V) phases were reduced to As(III) and As(III) was further reduced to As(-I) (at 700 ºC, only), followed by delayed reoxidation of As(-I) to As(III) (at 700 ºC, only) and reoxidation of As(III) to As(V). Approximately 9% and 26% of all As remained as As(III) ( i.e., was not reoxidized to As(V)) at the end of the experiment when heated to a maximum temperature of 600 and 700 ºC, respectively, which is higher than the relative abundance of As(III) in the native sediment. These fire-induced As transformations can potentially enhance As mobilization to surface water and groundwater, posing risks to environmental and human health.

California