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At least 91 records · Page 5Linked to original sources

Experimental deformation of polycrystalline H2O ice at high pressure and low temperature: Preliminary results

Interest in the mechanical properties of water ice under the conditions in which it exists in the outer solar system has motivated the development and use of a new high‐pressure, low‐temperature triaxial deformation apparatus. Constant displacement rate tests on 70 samples of pure polycrystalline water ice have been performed at temperatures 77≤≤258 K, confining pressures 0.1≤≤350 MPa, and strain rates 3.5×10≤ ≤3.5×10 s. In most cases, the ice polymorph tested was ice . Both brittle and ductile behavior have been observed. Brittle behavior of ice, promoted by lower pressure, lower temperature, and higher strain rate, is analogous to that in rocks, with the important exception that brittle fracture strength becomes independent of confining pressure above 50 MPa pressure and the fracture angle is approximately 45° to the loading direction (i.e., the coefficient of internal friction is approximately zero). Ductile flow, the predominant behavior in our tests at ≥195 K, follows a law of form = σ exp (−*/) (σ is stress; is the gas constant; , * are material constants). Three sets of material constants are required to fit the data, with changes in sets (or mechanisms) occurring near 243 K and 195 K. The value of remains near 4 throughout the measured ductile field, but * drops from 91 to 61 to 31 /mole as temperature decreases. The maximum brittle strength measured was 171 MPa; the maximum ductile strength measured was 91 MPa. At confining pressures near the phase transition pressure of ice → ice II, the ductile strength is observed to drop dramatically. Some overlap with previous work occurs at higher temperatures and lower pressures. Agreement with present work is generally good, both quantitatively in the values of and *, and qualitatively in the mechanism of deformation. Although the ductile strengths measured here are somewhat higher than expected on the basis of extrapolations of previous work, the low value of * at <195 K indicates that the ice layer on icy bodies in the solar system is much weaker than has generally been predicted.

Journal of Geophysical Research B: Solid Earth

Temperature, pressure, and compositional effects on anomalous or "self" preservation of gas hydrates

We previously reported on a thermal regime where pure, polycrystalline methane hydrate is preserved metastably in bulk at up to 75 K above its nominal temperature stability limit of 193 K at 0.1 MPa, following rapid release of the sample pore pressure. Large fractions (>50 vol.%) of methane hydrate can be preserved for 2-3 weeks by this method, reflecting the greatly suppressed rates of dissociation that characterize this "anomalous preservation" regime. This behavior contrasts that exhibited by methane hydrate at both colder (193-240 K) and warmer (272-290 K) isothermal test conditions, where dissociation rates increase monotonically with increasing temperature. Here, we report on recent experiments that further investigate the effects of temperature, pressure, and composition on anomalous preservation behavior. All tests conducted on sI methane hydrate yielded self-consistent results that confirm the highly temperature-sensitive but reproducible nature of anomalous preservation behavior. Temperature-stepping experiments conducted between 250 and 268 K corroborate the relative rates measured previously in isothermal preservation tests, and elevated pore-pressure tests showed that, as expected, dissociation rates are further reduced with increasing pressure. Surprisingly, sII methane-ethane hydrate was found to exhibit no comparable preservation effect when rapidly depressurized at 268 K, even though it is thermodynamically stable at higher temperatures and lower pressures than sI methane hydrate. These results, coupled with SEM imaging of quenched sample material from a variety of dissociation tests, strongly support our earlier arguments that ice-"shielding" effects provided by partial dissociation along hydrate grain surfaces do not serve as the primary mechanism for anomalous preservation. The underlying physical-chemistry mechanism(s) of anomalous preservation remains elusive, but appears to be based more on textural or morphological changes within the hydrate material itself, rather than on compositional zoning or ice-rind development.

Canadian Journal of Physics

Recent surface movements in the Baldwin Hills, Los Angeles County, California

The Baldwin Hills are located in the northwest part of the densely populated Los Angeles basin. They comprise one of several groups of isolated hills that extend along the northwest-trending Newport-Inglewood zone of folds and faults, a structural lineament identified with a series of very productive oil fields. In addition to being the site of the Inglewood oil field, these hills are the site of surface deformation that has been monitored for over 35 years. This record of deformation, which includes differential subsidence, horizontal displacements, and surface rupturing, forms one of the best documented examples of oilfield-associated surface deformation yet recognized. The deformation is described in detail, analyzed as to cause(s), and finally attributed largely or essentially entirely to the exploitation of the spatially-associated Inglewood oil field. The Baldwin Hills are underlain by gently to moderately arched and conspicuously faulted Cenozoic sedimentary and volcanic rocks that overlie crystalline basement rocks at a depth of more than 10,000 feet. The Inglewood fault, a part of the northwest-trending Newport-Inglewood zone, diagonally transects the hills. Right-lateral displacements of 3,000-4,000 feet since middle or late Pliocene time and 1,500-2,000 feet during Quaternary time are indicated by offset structural and physio-graphic features; indications of vertical separations of up to about 200 feet during late Quaternary time occur locally. Evidence of continuing deformation includes recognized seismicity and regional elevation changes. The M5-5 1/2 Inglewood earthquake of 1920, the largest local earthquake of record, is believed to have originated immediately southeast of the Baldwin Hills; it was apparently unassociated with surficial fault displacements. Leveling in and around the west and central Los Angeles basin has shown that lowland stations have been consistently subsiding, whereas foothill stations commonly have been rising. Several seemingly persistent basins of differential subsidence and a zone of positive movement, roughly coincident with the Newport-Inglewood zone, have also been identified in the northwest part of the basin. A prominent, elliptically-shaped, northwest-trending subsidence bowl encompassing the northwest part of the Baldwin Hills, has been defined by repeated level circuits. Partial reconstruction of selected level circuits with respect to a common, relatively stable control point (Hollywood E-11), located on the edge of the subsidence bowl, has permitted evaluation of the subsidence since 1910 and 1911 at two points near the center of the bowl. Thus bench mark PBM 67 is estimated to have subsided approximately 4.324 feet between June 1910 and February 1963; and bench mark PBM 68 (the only bench mark within the subsidence bowl that was leveled prior to 1926 and has been repeatedly leveled since) subsided 3.846 feet between November 1911 and June 1962. Analysis of the available data indicates little if any elevation change at PBM 68 (or elsewhere throughout the Baldwin Hills-Inglewood area) associated with the Inglewood earthquake of 1920. Maximum subsidence of PBM 122 (which has remained very close to the center of subsidence since at . least 1950) between 1911 and 1963 is calculated to have been 5.67 feet. Horizontal displacements (with respect to a north-south base line about 3 miles east of the hills) of six triangulation points within the subsidence bowl have been measured for various periods between 1934 and 1963. Displacements have been generally toward the center of subsidence and almost precisely perpendicular to the immediately adjacent isobases of equal elevation change. Maximum movement has been recorded at triangulation point Baldwin Aux, which was displaced 2.21 feet between 1934 and 1961; horizontal displacements of three additional points ranged from 0.95 foot to 1.85 feet between 1936 and 1961. Displacements of 0.10-0.29 foot were recorded at all six monuments during the period 1961-1963. "Earth cracks" and surficial fault displacements were recognized in the Baldwin Hills at least as early as 1957. The cracks are relatively straight, generally continuous fractures confined to the structural block east of the Inglewood fault; they are concentrated in two areas centering on (1) the Baldwin Hills Reservoir and (2) the Stocker Street-LaBrea Avenue-Overhill Drive intersection. The cracks trend north to north-northeast and are nearly everywhere parallel to or coincident with minor faults and joints, and are generally orthogonal to radii emanating from the center of subsidence. Differential movement along the cracks has been almost entirely dip slip along steep to nearly vertical surfaces, and generally down-dropped toward the center of subsidence. Cumulative displacements have been as much as 6 or 7 inches. Rates of displacement have ranged widely, and the movement has generally occurred as creep or very small discrete jumps. A probable exception is the several inches of differential movement that is believed to have occurred along a crack through the floor of the Baldwin Hills Reservoir on or about December 14, 1963. The contemporary surface movements are attributable to one or more of the following phenomena: (1). exploitation of the Inglewood oil field; (2) changes in the ground-water regimen; (3) compaction of sedimentary materials in response to surface loading; (4) tectonic activity. The following considerations indicate that the differential subsidence is attributable largely or entirely to exploitation of the underlying Inglewood oil field: (1) the coincidence of the centers of the oil field, the producing structure, and the subsidence bowl; (2) the general correspondence between the pattern of subsidence and the outlines of the oil field; (3) the approximate coincidence between the initiation of production and the initiation of subsidence; (4) the generally linear relations between various measures of subsidence and liquid production from both the field as a whole and the exceptionally prolific Vickers zone in particular; (5) the sharp deceleration of subsidence in the eastern block of the field coincident with the initiation of full-scale water flooding there; (6) the many examples of oil fields In which both spatial and temporal associations between production and subsidence are recognized; (7) the many similarities of the subsidence-production relations in the Inglewood field to those in the Wilmington field, where the subsidence has been authoritatively attributed to oilfield operations; (8) the theoretical relation between subsidence or a tendency toward subsidence and increased effective pressure associated with underground fluid extraction. Consideration of six possible explanations for the increasing rather than decreasing or constant rate of subsidence with respect to reservoir fluid pressure decline suggests that measured or calculated down-hole reservoir fluid pressure decline is non-representative of average or real fluid pressure decline away from producing wells. The near-linear relations between net-liquid production and subsidence are explained through analogy with a tightly confined artesian system of infinite areal extent, where production must derive from liquid expansion and/or reservoir compaction. Test data from compaction studies in two other oil fields yield estimates of ultimate compaction of the Vickers zone resulting from a total loss of fluid pressure; these estimates range over an order of magnitude. The best estimate, based on these data and considerations of late Cenozoic history in the Baldwin Hills area, is about 10 feet. The centripetally-directed horizontal movements are considered attributable to exploitation of the Inglewood oil field on the basis of: (1) their well-defined symmetrical and geometrical association with the differential subsidence; (2) the similarities between these associations and those developed in and around other subsiding oil fields; and (3) the mechanical compatibility of these movements with subsidence induced by the extraction of subsurface materials. The earth cracks and surficial fault displacements are considered largely or entirely attributable to the exploitation of the Inglewood oil field on the basis of: (1) their spatial and temporal relations to both oil-field operations and the differential subsidence; (2) the similarities of these cracks and displacements to those generated in and around other oil fields and areas of subsurface materials extraction; and (3) surface strain patterns predicted from the measured vertical and horizontal surface movements. The cracks and displacements can i)e explained by an exploitation-based, elastic-rebound model which requires elastic compression of the sedimentary section in response to compaction-induced downdrag within those blocks around the periphery of the subsidence bowl. The measured displacements have been about one-quarter to one-half those predicted for a purely elastic system. Analysis of: (1) the history of ground-water extraction within and around the Baldwin Hills; and (2) subsidence associated with water-level declines in sediments comparable with those in the Baldwin Hills, indicate that the surface movements can be no more than incidentally attributed to changes in ground-water conditions. Similarly, analysis of the history of natural and artificial changes in surface loading indicate that these movements are generally unassociated with changes in surface loading conditions. Considerations of local geologic history and various tectonic associations indicate that it is very unlikely that the differential subsidence and horizontal movements are due to tectonic downwarping. There exists a far stronger prima facie argument for tectonic involvement in the earth cracking and associated fault displacements. This argument is disputed by; (1) the spatial and temporal relations of the earth cracks to, and their mechanical compatibility with, the nontectonic differential subsidence; (2) the absence of displacements on the Inglewood fault in conjunction with those along the conjugate earth cracks; (3) the probability that purely tectonic displaceMents would be characterized by oblique or strike slip; and (4) the absence of any clear temporal relation between crack growth and local seismicity, However, because as much as 10 percent of the local isobase gradient may be unexplained' by oil-field exploitation, a small fraction of this gradient, and thus the displacements among the southern group of cracks, may be attributable to tectonic activity. This fraction should have been insignificant in the presence of the strain pattern produced by nontectonic compaction of the underlying oil measures. Because nearly all of the observed and measured surface movements can be fully explained as the products of oil-field operations, yet can be no more than incidentally attributed to changes in ground-water conditions, surface loading, or tectonic activity, we conclude that these movements are attributable largely or essentially entirely to the exploitation of the Inglewood oil field.

California

Wildfire-related debris-flow initiation processes, Storm King Mountain, Colorado

A torrential rainstorm on September 1, 1994 at the recently burned hillslopes of Storm King Mountain, CO, resulted in the generation of debris flows from every burned drainage basin. Maps (1:5000 scale) of bedrock and surficial materials and of the debris-flow paths, coupled with a 10-m Digital Elevation Model (DEM) of topography, are used to evaluate the processes that generated fire-related debris flows in this setting. These evaluations form the basis for a descriptive model for fire-related debris-flow initiation. The prominent paths left by the debris flows originated in 0- and 1st-order hollows or channels. Discrete soil-slip scars do not occur at the heads of these paths. Although 58 soil-slip scars were mapped on hillslopes in the burned basins, material derived from these soil slips accounted for only about 7% of the total volume of material deposited at canyon mouths. This fact, combined with observations of significant erosion of hillslope materials, suggests that a runoff-dominated process of progressive sediment entrainment by surface runoff, rather than infiltration-triggered failure of discrete soil slips, was the primary mechanism of debris-flow initiation. A paucity of channel incision, along with observations of extensive hillslope erosion, indicates that a significant proportion of material in the debris flows was derived from the hillslopes, with a smaller contribution from the channels. Because of the importance of runoff-dominated rather than infiltration-dominated processes in the generation of these fire-related debris flows, the runoff-contributing area that extends upslope from the point of debris-flow initiation to the drainage divide, and its gradient, becomes a critical constraint in debris-flow initiation. Slope-area thresholds for fire-related debris-flow initiation from Storm King Mountain are defined by functions of the form Acr(tan ??)3 = S, where Acr is the critical area extending upslope from the initiation location to the drainage divide, and tan ?? is its gradient. The thresholds vary with different materials. ?? 2001 Elsevier Science B.V. All rights reserved.

Geomorphology

Three-dimensional flow structure and patterns of bed shear stress in an evolving compound meander bend

Compound meander bends with multiple lobes of maximum curvature are common in actively evolving lowland rivers. Interaction among spatial patterns of mean flow, turbulence, bed morphology, bank failures and channel migration in compound bends is poorly understood. In this paper, acoustic Doppler current profiler (ADCP) measurements of the three-dimensional (3D) flow velocities in a compound bend are examined to evaluate the influence of channel curvature and hydrologic variability on the structure of flow within the bend. Flow structure at various flow stages is related to changes in bed morphology over the study timeframe. Increases in local curvature within the upstream lobe of the bend reduce outer bank velocities at morphologically significant flows, creating a region that protects the bank from high momentum flow and high bed shear stresses. The dimensionless radius of curvature in the upstream lobe is one-third less than that of the downstream lobe, with average bank erosion rates less than half of the erosion rates for the downstream lobe. Higher bank erosion rates within the downstream lobe correspond to the shift in a core of high velocity and bed shear stresses toward the outer bank as flow moves through the two lobes. These erosion patterns provide a mechanism for continued migration of the downstream lobe in the near future. Bed material size distributions within the bend correspond to spatial patterns of bed shear stress magnitudes, indicating that bed material sorting within the bend is governed by bed shear stress. Results suggest that patterns of flow, sediment entrainment, and planform evolution in compound meander bends are more complex than in simple meander bends. Moreover, interactions among local influences on the flow, such as woody debris, local topographic steering, and locally high curvature, tend to cause compound bends to evolve toward increasing planform complexity over time rather than stable configurations.

Earth Surface Processes and Landforms

Directed blasts and blast-generated pyroclastic density currents: a comparison of the Bezymianny 1956, Mount St Helens 1980, and Soufrière Hills, Montserrat 1997 eruptions and deposits

We compare eruptive dynamics, effects and deposits of the Bezymianny 1956 (BZ), Mount St Helens 1980 (MSH), and Soufri&egrave;re Hills volcano, Montserrat 1997 (SHV) eruptions, the key events of which included powerful directed blasts. Each blast subsequently generated a high-energy stratified pyroclastic density current (PDC) with a high speed at onset. The blasts were triggered by rapid unloading of an extruding or intruding shallow magma body (lava dome and/or cryptodome) of andesitic or dacitic composition. The unloading was caused by sector failures of the volcanic edifices, with respective volumes for BZ, MSH, and SHV c. 0.5, 2.5, and 0.05 km 3 . The blasts devastated approximately elliptical areas, axial directions of which coincided with the directions of sector failures. We separate the transient directed blast phenomenon into three main parts, the burst phase, the collapse phase, and the PDC phase. In the burst phase the pressurized mixture is driven by initial kinetic energy and expands rapidly into the atmosphere, with much of the expansion having an initially lateral component. The erupted material fails to mix with sufficient air to form a buoyant column, but in the collapse phase, falls beyond the source as an inclined fountain, and thereafter generates a PDC moving parallel to the ground surface. It is possible for the burst phase to comprise an overpressured jet, which requires injection of momentum from an orifice; however some exploding sources may have different geometry and a jet is not necessarily formed. A major unresolved question is whether the preponderance of strong damage observed in the volcanic blasts should be attributed to shock waves within an overpressured jet, or alternatively to dynamic pressures and shocks within the energetic collapse and PDC phases. Internal shock structures related to unsteady flow and compressibility effects can occur in each phase. We withhold judgment about published shock models as a primary explanation for the damage sustained at MSH until modern 3D numerical modeling is accomplished, but argue that much of the damage observed in directed blasts can be reasonably interpreted to have been caused by high dynamic pressures and clast impact loading by an inclined collapsing fountain and stratified PDC. This view is reinforced by recent modeling cited for SHV. In distal and peripheral regions, solids concentration, maximum particle size, current speed, and dynamic pressure are diminished, resulting in lesser damage and enhanced influence by local topography on the PDC. Despite the different scales of the blasts (devastated areas were respectively 500, 600, and >10 km 2 for BZ, MSH, and SHV), and some complexity involving retrogressive slide blocks and clusters of explosions, their pyroclastic deposits demonstrate strong similarity. Juvenile material composes >50% of the deposits, implying for the blasts a dominantly magmatic mechanism although hydrothermal explosions also occurred. The character of the magma fragmented by explosions (highly viscous, phenocryst-rich, variable microlite content) determined the bimodal distributions of juvenile clast density and vesicularity. Thickness of the deposits fluctuates in proximal areas but in general decreases with distance from the crater, and laterally from the axial region. The proximal stratigraphy of the blast deposits comprises four layers named A, B, C, D from bottom to top. Layer A is represented by very poorly sorted debris with admixtures of vegetation and soil, with a strongly erosive ground contact; its appearance varies at different sites due to different ground conditions at the time of the blasts. The layer reflects intense turbulent boundary shear between the basal part of the energetic head of the PDC and the substrate. Layer B exhibits relatively well-sorted fines depleted debris with some charred plant fragments; its deposition occurred by rapid suspension sedimentation in rapidly waning, high-concentration conditions. Layer C is mainly a poorly sorted massive layer enriched by fines with its uppermost part laminated, created by rapid sedimentation under moderate-concentration, weakly tractive conditions, with the uppermost laminated part reflecting a dilute depositional regime with grain-by-grain traction deposition. By analogy to laboratory experiments, mixing at the flow head of the PDC created a turbulent dilute wake above the body of a gravity current, with layer B deposited by the flow body and layer C by the wake. The uppermost layer D of fines and accretionary lapilli is an ash fallout deposit of the finest particles from the high-rising buoyant thermal plume derived from the sediment-depleted pyroclastic density current. The strong similarity among these eruptions and their deposits suggests that these cases represent similar source, transport and depositional phenomena.

Bezymianny, Mount St Helens, Soufriere Hills

Formation of lunar basin rings

The origin of the multiple concentric rings that characterize lunar impact basins, and the probable depth and diameter of the transient crater have been widely debated. As an alternative to prevailing “megaterrace” hypotheses, we propose that the outer scarps or mountain rings that delineate the topographic rims of basins—the Cordilleran at Orientale, the Apennine at Imbrium, and the Altai at Nectaris—define the transient cavities, enlarged relatively little by slumping, and thus are analogous to the rim crests of craters like Copernicus; inner rings are uplifted rims of craters nested within the transient cavity. The magnitude of slumping that occurs on all scarps is insufficient to produce major inner rings from the outer. These conclusions are based largely on the observed gradational sequence in lunar central uplifts:. from simple peaks through somewhat annular clusters of peaks, peak and ring combinations and double ring basins, culminating in multiring structures that may also include peaks. In contrast, belts of slump terraces are not gradational with inner rings. Terrestrial analogs suggest two possible mechanisms for producing rings. In some cases, peaks may expand into rings as material is ejected from their cores, as apparently occurred at Gosses Bluff, Australia. A second process, differential excavation of lithologically diverse layers, has produced nested experimental craters and is, we suspect, instrumental in the formation of terrestrial ringed impact craters. Peak expansion could produce double-ring structures in homogeneous materials, but differential excavation is probably required to produce multiring and peak-in-ring configurations in large lunar impact structures. Our interpretation of the representative lunar multiring basin Orientale is consistent with formation of three rings in three layers detected seismically in part of the Moon—the Cordillera (basin-bounding) ring in the upper crust, the composite Montes Rook ring in the underlying, more coherent “heald” crust, and an innermost, 320-km ring at the crust-mantle interface. Depth-diameter ratios of 1 10 to 1 15 "> 110 to 115 are consistent with this interpretation and suggest that volumes of transient cavities and hence of basin ejecta may be considerably greater than commonly assumed.

Icarus

Bascom Laser Diffraction Sedimentology Laboratory, Reston, Virginia

Introduction At the Bascom Laser Diffraction Sedimentology Laboratory, which is located in the Florence Bascom Geoscience Center at U.S. Geological Survey (USGS) headquarters in Reston, Virginia, scientists use physical sedimentology and particle characterization techniques to conduct detailed sediment characterization. Scientists address research problems in collaboration with other USGS science centers, State geological surveys, commercial industry, universities, and other partners. Laboratory capabilities include laser diffractometry for quantitative particle-size analysis, portable x-ray fluorescence (XRF) analysis for determining elemental abundances in rock or sediment samples, petrographic analysis of geologic media, and mechanical sieve analysis. These methods are used to analyze soil and sediment core material from terrestrial, marine, and lacustrine environments, surface sediments from coastal regions, and calcareous materials. Work done by the laboratory supports geologic mapping, resource assessments, land change studies, and geohazard analyses.

Fact Sheet

Quantifying groundwater discharge through fringing wetlands to estuaries: Seasonal variability, methods comparison, and implications for wetland-estuary exchange

Because groundwater discharge along coastal shorelines is often concentrated in zones inhabited by fringing wetlands, accurately estimating discharge is essential for understanding its effect on the function and maintenance of these ecosystems. Most previous estimates of groundwater discharge to coastal wetlands have been temporally limited and have used only a single approach to estimate discharge. Furthermore, groundwater input has not been considered as a major mechanism controlling pore-water flushing. We estimated seasonally varying groundwater discharge into a fringing estuarine wetland using three independent methods (Darcy's Law, salt balance, and Br- tracer). Seasonal patterns of discharge predicted by both Darcy's Law and the salt balance yielded similar seasonal patterns with discharge maxima and minima in spring and early fall, respectively. They differed, however, in the estimated magnitude of discharge by two- to fourfold in spring and by 10-fold in fall. Darcy estimates of mean discharge ranged between -8.0 and 80 L m-2 d-1, whereas the salt balance predicted groundwater discharge of 0.6 to 22 L m-2 d-1. Results from the Br- tracer experiment estimated discharge at 16 L m-2 d-t, or nearly equal to the salt balance estimate at that time. Based upon the tracer test, pore-water conductivity profiles, and error estimates for the Darcy and salt balance approaches, we concluded that the salt balance provided a more certain estimate of groundwater discharge at high flow (spring). In contrast, the Darcy method provided a more reliable estimate during low flow (fall). Groundwater flushing of pore water in the spring exported solutes to the estuary at rates similar to tidally driven surface exchange seen in previous studies. Based on pore-water turnover times, the groundwater-driven flux of dissolved organic carbon (DOC), dissolved organic nitrogen (DON), and NH4+ to the estuary was 11.9, 1.6, and 1.3 g C or g N m-2 wetland for the 90 d encompassing peak spring discharge. Groundwater-induced flushing of the wetland subsurface therefore represents an important mechanism by which narrow fringing marshes may seasonally relieve salt stress and export material to adjacent water masses.

Limnology and Oceanography

Questa baseline and pre-mining ground-water quality investigation. 5. Well installation, water-level data, and surface- and ground-water geochemistry in the Straight Creek drainage basin, Red River Valley, New Mexico, 2001-03

The U.S. Geological Survey, in cooperation with the New Mexico Environment Department, is investigating the pre-mining ground-water chemistry at the Molycorp molybdenum mine in the Red River Valley, northern New Mexico. The primary approach is to determine the processes controlling ground-water chemistry at an unmined, off-site, proximal analog. The Straight Creek drainage basin, chosen for this purpose, consists of the same quartz-sericite-pyrite altered andesitic and rhyolitic volcanic rock of Tertiary age as the mine site. The weathered and rugged volcanic bedrock surface is overlain by heterogeneous debris-flow deposits that interfinger with alluvial deposits near the confluence of Straight Creek and the Red River. Pyritized rock in the upper part of the drainage basin is the source of acid rock drainage (pH 2.8-3.3) that infiltrates debris-flow deposits containing acidic ground water (pH 3.0-4.0) and bedrock containing water of circumneutral pH values (5.6-7.7). Eleven observation wells were installed in the Straight Creek drainage basin. The wells were completed in debris-flow deposits, bedrock, and interfingering debris-flow and Red River alluvial deposits. Chemical analyses of ground water from these wells, combined with chemical analyses of surface water, water-level data, and lithologic and geophysical logs, provided information used to develop an understanding of the processes contributing to the chemistry of ground water in the Straight Creek drainage basin. Surface- and ground-water samples were routinely collected for determination of total major cations and selected trace metals; dissolved major cations, selected trace metals, and rare-earth elements; anions and alkalinity; and dissolved-iron species. Rare-earth elements were determined on selected samples only. Samples were collected for determination of dissolved organic carbon, mercury, sulfur isotopic composition (34S and 18O of sulfate), and water isotopic composition (2H and 18O) during selected samplings. One set of ground-water samples was collected for helium-3/tritium and chlorofluorocarbon (CFC) age dating. Several lines of evidence indicate that surface water is the primary input to the Straight Creek ground-water system. Straight Creek streamflow and water levels in wells closest to the apex of the Straight Creek debris fan and closest to Straight Creek itself appear to respond to the same seasonal inputs. Oxygen and hydrogen isotopic compositions in Straight Creek surface water and ground water are similar, and concentrations of most dissolved constituents in most Straight Creek surface-water and shallow (debris-flow and alluvial) aquifer ground-water samples correlate strongly with sulfate (concentrations decrease linearly with sulfate in a downgradient direction). After infiltration of surface water, dilution along the flow path is the dominant mechanism controlling ground-water chemistry. However, concentrations of some constituents can be higher in ground water than can be accounted for by concentrations in Straight Creek surface water, and additional sources of these constituents must therefore be inferred. Constituents for which concentrations in ground water can be high relative to surface water include calcium, magnesium, strontium, silica, sodium, and potassium in ground water from debris-flow and alluvial aquifers and manganese, calcium, magnesium, strontium, sodium, and potassium in ground water from the bedrock aquifer. All ground water is a calcium sulfate type, often at or near gypsum saturation because of abundant gypsum in the aquifer material developed from co-existing calcite and pyrite mineralization. Calcite dissolution, the major buffering mechanism for bedrock aquifer ground water, also contributes to relatively higher calcium concentrations in some ground water. The main source of the second most abundant cation, magnesium, is probably dissolution of magnesium-rich carbonates or silicates.

New Mexico

Sorption of pure N 2 O to biochars and other organic and inorganic materials under anhydrous conditions

Suppression of nitrous oxide (N 2 O) emissions from soil is commonly observed after amendment with biochar. The mechanisms accounting for this suppression are not yet understood. One possible contributing mechanism is N 2 O sorption to biochar. The sorption of N 2 O and carbon dioxide (CO 2 ) to four biochars was measured in an anhydrous system with pure N 2 O. The biochar data were compared to those for two activated carbons and other components potentially present in soils—uncharred pine wood and peat—and five inorganic metal oxides with variable surface areas. Langmuir maximum sorption capacities ( Q max ) for N 2 O on the pine wood biochars (generated between 250 and 500 °C) and activated carbons were 17–73 cm 3 g –1 at 20 °C (median 51 cm 3 g –1 ), with Langmuir affinities ( b ) of 2–5 atm –1 (median 3.4 atm –1 ). Both Q max and b of the charred materials were substantially higher than those for peat, uncharred wood, and metal oxides [ Q max 1–34 cm 3 g –1 (median 7 cm 3 g –1 ); b 0.4–1.7 atm –1 (median 0.7 atm –1 )]. This indicates that biochar can bind N 2 O more strongly than both mineral and organic soil materials. Q max and b for CO 2 were comparable to those for N 2 O. Modeled sorption coefficients obtained with an independent polyparameter—linear free-energy relationship matched measured data within a factor 2 for mineral surfaces but underestimated by a factor of 5–24 for biochar and carbonaceous surfaces. Isosteric enthalpies of sorption of N 2 O were mostly between −20 and −30 kJ mol –1 , slightly more exothermic than enthalpies of condensation (−16.1 kJ mol –1 ). Q max of N 2 O on biochar (50000–130000 μg g –1 biochar at 20 °C) exceeded the N 2 O emission suppressions observed in the literature (range 0.5–960 μg g –1 biochar; median 16 μg g –1 ) by several orders of magnitude. Thus, the hypothesis could not be falsified that sorption of N 2 O to biochar is a mechanism of N 2 O emission suppression.

Environmental Science & Technology

The formation and failure of natural dams

Of the numerous kinds of dams that form by natural processes, dams formed from landslides, glacial ice, and late-neoglacial moraines present the greatest threat to people and property. Landslide dams form in a wide range of physiographic settings. The most common types of mass movements that form landslide dams are rock and debris avalanches; rock and soil slumps and slides; and mud, debris, and earth flows. The most common initiation mechanisms for dam-forming landslides are excessive rainfall and snowmelt and earthquakes. Landslide dams can be classified into six categories based on their relation with the valley floor. Type I dams (11% of 184 landslide dams from around the world that we were able to classify) do not reach from one valley side to the other. Type II dams (44%) span the entire valley floor, in some cases depositing material high on opposite valley sides. Type III dams (41%) move considerable distances both upstream and downstream from the landslide failure. Type IV dams (<1%) are rare and involve the contemporaneous failure of material from both sides of a valley. Type V dams (<1%) also are rare and are created when a single landslide sends multiple tongues of debris into a valley and forms two or more landslide dams in the same reach of river. Type VI dams (3%) involve one or more failure surfaces that extend under the stream or valley and emerge on the opposite valley side. Many landslide dams fail shortly after formation. In our sample of 73 documented landslide-dam failures, 27% of the landslide dams failed less than 1 day after formation, and about 50% failed within 10 days. Over-topping is by far the most common cause of failure. The timing of failure and the magnitude of the resulting floods are controlled by dam size and geometry; material characteristics of the blockage; rate of inflow to the impoundment; size and depth of the impoundment; bedrock control of flow; and engineering controls such as artificial spill-ways, diversions, tunnels, and planned breaching by blasting or conventional excavation. Glacial-ice dams can produce at least nine kinds of ice-dammed lakes. The most dangerous are lakes formed in main valleys dammed by tributary glaciers. Failure can occur by erosion of a drainage tunnel under or through the ice dam or by a channel over the ice dam. Cold polar-ice dams generally drain supraglacially or marginally by downmelting of an outlet channel. Warmer, temperate-ice dams tend to fail by sudden englacial or subglacial breaching and drainage. Late-neoglacial moraine-dammed lakes are located in steep mountain areas affected by the advances and retreats of valley glaciers in the last several centuries. These late-neoglacial dams pose hazards because (1) they are sufficiently young that vegetation has not stabilized their slopes, (2) many dam faces are steeper than the angle of repose, (3) these dams and lakes are immediately downslope from steep crevassed glaciers and near-vertical rock slopes, and (4) downstream from these dams are steep canyons with easily erodible materials that can be incorporated in the flow and increase flood peaks. The most common reported failure mechanism is overtopping and breaching by a wave or series of waves in the lake generated by icefalls, rockfalls, or snow or rock avalanches. Melting of ice cores or frozen ground and piping and seepage are other possible failure mechanisms. Natural dams may cause upstream flooding as the lake rises and downstream flooding as a result of failure of the dam. Although data are few, for the same potential energy at the dam site, ownstream flood peaks from the failure of glacier-ice dams are smaller than those from landslide, moraine, and structed earth-fill and rock-fill dam failures. Moraine-dam failures appear to produce some of the largest downstream flood peaks for potential energy at the dam site greater than 10 11 -10 12 joules. Differences in flood peaks natural-dam failures appear to be controlled by dam characteristics and failure mechanisms.

Geological Society of America Bulletin

Growth and erosion of volcanic islands since 1963 analyzed by multi-sensor satellite data and historical records

Most volcanic activity is taking place in the oceans. Depending on water depth, eruption recurrence times and volumes, a new island can form. The power of erosional forces, the type of erupted material and the efficiency of secondary processes determine the island’s lifetime. Since the famous eruption of Surtsey (Iceland) in 1963, at least another 23 volcanic islands have appeared. Some islands remained intact for years or decades, whereas others disappeared within just weeks or months. In this study, we analyzed satellite data to determine growth and erosion rates of the volcanic edifices related to these 24 islands. We combined multi-sensor (optical, thermal, radar) satellite data time series with information from literature and the Global Volcanism Program database. We developed a comprehensive dataset, including 19 parameters, on the islands’ lifetime, shape, area, volume, eruption style and duration, environmental conditions, development of sedimentary deposits, and the geomorphic evolution of the island over time. Our dataset is available in a database format. This database allows us to test eight hypotheses about factors influencing the islands’ lifetime. Our results show that instead of one single critical factor, a combination of different factors influences the life history of volcanic islands. For instance, we show that larger islands do not necessarily live longer. The mechanical properties of the eruption products affect the island’s structural integrity. Irrespective of the material, a minimum initial area of around 50,000 m 2 seems to be a reasonable threshold to give the island a chance to exist longer.

Bulletin of Volcanology

Stress, deformation, conservation, and rheology: a survey of key concepts in continuum mechanics

This chapter provides a brief survey of key concepts in continuum mechanics. It focuses on the fundamental physical concepts that underlie derivations of the mathematical formulations of stress, strain, hydraulic head, pore-fluid pressure, and conservation equations. It then shows how stresses are linked to strain and rates of distortion through some special cases of idealized material behaviors. The goal is to equip the reader with a physical understanding of key mathematical formulations that anchor continuum mechanics in order to better understand theoretical studies published in geomorphology.

Book chapter

Gravity-induced stresses in stratified rock masses

This paper presents closed-form solutions for the stress field induced by gravity in anisotropic and stratified rock masses. These rocks are assumed to be laterally restrained. The rock mass consists of finite mechanical units, each unit being modeled as a homogeneous, transversely isotropic or isotropic linearly elastic material. The following results are found. The nature of the gravity induced stress field in a stratified rock mass depends on the elastic properties of each rock unit and how these properties vary with depth. It is thermodynamically admissible for the induced horizontal stress component in a given stratified rock mass to exceed the vertical stress component in certain units and to be smaller in other units; this is not possible for the classical unstratified isotropic solution. Examples are presented to explore the nature of the gravity induced stress field in stratified rock masses. It is found that a decrease in rock mass anisotropy and a stiffening of rock masses with depth can generate stress distributions comparable to empirical hyperbolic distributions previously proposed in the literature. ?? 1988 Springer-Verlag.

Rock Mechanics and Rock Engineering

A high 87Sr 86Sr mantle source for low alkali tholeiite, northern Great Basin

Olivine tholeiites, the youngest Tertiary units (about 8–11 m.y. old) at five widely spaced localities in northeastern Nevada, are geologically related to the basalts of the Snake River Plain, Idaho, to the north and are similar in major element and alkali chemistry to mid-ocean ridge basalts (MORB) and island arc tholeiites. The measured K (1250–3350 ppm), Rb (1·9–6·2 ppm) and Sr (140–240 ppm) concentrations overlap the range reported for MORB. Three of the five samples have low, unfractionated rare earth element (REE) patterns, the other two show moderate light-REE enrichment. Barium concentration is high and variable (100–780 ppm) and does not correlate with the other LIL elements. The rocks have 87 Sr / 86 Sr = 0·7052–0·7076, considerably higher than MORB (~0·702–0·703). These samples are chemically distinct (i.e. less alkalic) from the olivine tholeiites from the adjacent Snake River Plain, but their Sr isotopic compositions are similar. They contain Sr that is distinctly more radiogenic than the basalts from the adjacent Great Basin. About 10 b.y. would be required for the mean measured Rb/Sr (~ 0·02) of these samples to generate, in a closed system, the radiogenic Sr they contain. The low alkali content of these basalts makes crustal contamination an unlikely mechanism. If the magma is uncontaminated, the time-averaged Rb/Sr of the source material must have been ~0·04. A significant decrease in Rb/Sr of the source material (a factor 2̆) thus most probably occurred in the relatively recent (1̌0 9 yr) past. Such a decrease of Rb/Sr in the mantle could accompany alkali depletion produced by an episode of partial melting and magma extraction. In contrast, low 87 Sr 86 Sr "> 87Sr86Sr ratios indicate that the source material of the mid-ocean ridge basalts may have been depleted early in the Earth's history.

Geochimica et Cosmochimica Acta

Crater clusters and light mantle at the Apollo 17 site: A result of secondary impact from Tycho

The morphologies of Tycho secondary craters and their ejecta deposits were studied using full-Moon, Lunar-Orbiter, and Apollo panoramic photographs. These data were compared with similar data for the secondary craters and light mantle of the Apollo 17 landing site. The results indicate that (1) the central crater cluster and the light mantle can be attributed to Tycho, (2) the dominant mechanism for emplacement of the light mantle was impact by secondary craters that threw material across the valley floor, and (3) level sheets of material may be emplaced locally by secondary impact. Analysis of returned samples confirms that secondary impacts rework mostly local material.

Icarus

Novel insights about petroleum systems from source and reservoir rock characterization, Cretaceous Deposits, Babouri-Figuil Basin, Northern Cameroon

The Babouri-Figuil Basin (BFB) is a frontier basin for petroleum in Cameroon. It belongs to the series of Cretaceous rift basins of the West and Central Rift System (WCARS), the origin of which is related to the opening of the South Atlantic. Within the same rift system, commercial hydrocarbon accumulations have been discovered in Chad, Sudan, Niger and, more recently, in Nigeria (Gongola Basin). The study of the geology of the BFB just recently received considerable attention, mainly because of its presumed hydrocarbon potential. In the pursuit of researching possible petroleum systems in the BFB, the current study provides a first look into the characterization of source and reservoir rock and its integration into a 2D lithostratigraphic model. The study was solely based on outcrop samples. Black shale and massive claystone are good to excellent hydrocarbon source rocks [e.g., up to 38 wt% total organic carbon (TOC), up to 943 mg/g hydrogen index, up to 85 m thickness, up to 20–30 km lateral extension], with moderate to high values of extractable organic matter (e.g., >10,000 ppm). Calcareous claystone, on the other hand, are poor source rocks [e.g., <0.20 wt% TOC]. The samples are thermally immature, except for those located close to volcanic intrusion at Golombe that have reached the threshold for oil generation (Tmax >435 °C, production index >0.1). The petrographic analysis of sandstone revealed that they are fine-grained to coarse-grained, poorly to moderately sorted, texturally and compositionally immature to submature, subarkosic to arkosic arenites. The main diagenetic processes that affected sandstones are as follows: moderate to intense compaction characterized by the development of long, concavo-convex, and sutured contacts between grains; cementation through calcite, iron oxide, and quartz cements; alteration of mica and feldspar grains; partial to complete dissolution of feldspar, mica, amphibole grains, and calcite cement; and the replacement of feldspar and mica grains by clay minerals. Alteration and dissolution increase the porosity of sandstone through the creation of secondary pores. However, mechanical compaction through the development of a pseudomatrix and cementation as pore-filling materials have significantly reduced the quality of sandstone beds as conventional petroleum reservoirs. Hence, the best reservoir-quality sandstones in the basin are generally located in the upper portion of the basin in terms of its lithostratigraphic model. They are the cleanest sandstones with the smallest amount of cement and the lowest ductile grain content (pseudomatrix), with a thickness that varies from 3 m to 120 m and a lateral extension of 20 km. The lithostratigraphic model of the basin is characterized by an extensive lacustrine environment that provided a thick sequence of organic-rich formations; sand deposited as extensive reservoirs sandwiched between shale/claystone beds; the development of stratigraphic traps through lateral facies change; and the widespread deposition of lacustrine and floodplain claystone that provide regional seals. The similarities between the Babouri-Figuil Basin and proven petroleum systems in other WCARS rift basins suggest that the basin may host at least one petroleum system where actively generating source rocks are present.

Babouri-Figuil Basin