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Concentrations, distribution, and sources of selenium from irrigated lands in western United States

Concentrations, distribution, and sources of selenium from irrigated lands were studied between 1986 and 1990 at 20 reconnaissance project areas in 17 western states under the Department of Interior's National Irrigation Water Quality Program. Samples of water, bottom sediment, whole‐body fish, and bird livers for analysis of selenium concentrations were collected before, during, and after irrigation season from streams, canals, lakes, and ground water in each project area. Selenium concentrations in water ranged from less than the detection limit of 1 μg/L in 42% of the 586 samples collected to 4,800 μg/L from a well in the Pine River Area, in southern Colorado. Selenium concentrations in 223 samples of bottom sediment ranged from less than the detection limit of 0.1 μg/g to 85 μg/g in a sample from the Middle Green River Basin, in Utah. Selenium concentrations in whole‐body fish (all species) ranged from 0.1 μg to 50 μg per gram dry weight, with the maximum concentration observed in a carp from the Gunnison River Basin, in western Colorado. Selenium concentrations in bird livers (all species) ranged from less than 0.32 μg to 170 μg per gram dry weight with the maximum concentration observed in the liver of an avocet from the Kendrick Reclamation Project, in Wyoming. Cretaceous‐age marine shales probably are the original sources for selenium in 16 of the 20 areas studied. In several areas, evaporative concentration of applied irrigation water and drainage of this water to wetlands, canals, streams, and lakes appears to be responsible for elevated concentrations of selenium.

Colorado, Utah, Wyoming

Groundwater residence time estimates obscured by anthropogenic carbonate

Groundwater is an important source of drinking and irrigation water. Dating groundwater informs its vulnerability to contamination and aids in calibrating flow models. Here, we report measurements of multiple age tracers ( 14 C, 3 H, 39 Ar, and 85 Kr) and parameters relevant to dissolved inorganic carbon (DIC) from 17 wells in California’s San Joaquin Valley (SJV), an agricultural region that is heavily reliant on groundwater. We find evidence for a major mid-20th century shift in groundwater DIC input from mostly closed- to mostly open-system carbonate dissolution, which we suggest is driven by input of anthropogenic carbonate soil amendments. Crucially, enhanced open-system dissolution, in which DIC equilibrates with soil CO 2 , fundamentally affects the initial 14 C activity of recently recharged groundwater. Conventional 14 C dating of deeper SJV groundwater, assuming an open system, substantially overestimates residence time and thereby underestimates susceptibility to modern contamination. Because carbonate soil amendments are ubiquitous, other groundwater-reliant agricultural regions may be similarly affected.

California

Selective annotated bibliography of geology and ground-water resources for the Montana part of the Northern Great Plains regional aquifer-system analysis

Increasing demand for water to meet needs for energy, industry, irrigation, domestic, and municipal uses has resulted in a study of the geology and hydrology of rocks of Mesozoic and Cenozoic age. This report presents the results of a literature search for the part of the study area in Montana. It consists of an annotated listing of pertinent published reports, a partial subject and area index of the reports, and a correlation chart of geologic and aquifer units listed in the annotations. (USGS)

Open-File Report

Hydrologic conditions in the Wheatland Flats area, Platte County, Wyoming

The area includes about 260 square miles in central Platte County that consists of Wheatland Flats and a border region. Wheatland Flats is an area of about 100 square miles that is bounded by Chugwater Creek on the east, the Laramie River on the north, and Sybille Creek on the west. The southern boundary is approximately the southernmost limit of alluvial terrace deposits. Surface water diverted from the Laramie River along with ground water from wells is used to irrigate about 57,000 acres most of which are on and adjacent to Wheatland Flats. More than 200 wells are used for irrigation, industrial, and municipal supplies. The wells are completed in an upper aquifer consisting primarily of shallow alluvial deposits of Quaternary age and a lower aquifer, the Arikaree Formation of early Miocene age. Net water-level decline after approximately 20 years (1958-60 to 1979) generally is less than 10 feet in each aquifer , although declines of as much as 13 feet have occurred in the Airkaree Formation at specific locations. A digital model was used to simulate hydrologic conditions in the Wheatland Flats area. The model indicated that ground-water discharge to streams decreased by 10 percent from 1971 to 1978. Stream-discharge measurements are not available to verify the loss. However, it is reasonable to assume, on the basis of hydraulic-head decline in the aquifers, that there has been some ground-water contribution to the stream. (USGS)

Water-Resources Investigations Report

Hydrologic conditions near Glendo, Platte County, Wyoming

The Glendo area of Platte and Carbon Counties, Wyo., about 250 square miles in extent, is in the Great Plains physiographic province. It is bordered on the west by the Laramie Range and on the east by the Hartville uplift. The North Platte River and Horseshoe and Middle Bear Creeks are the principal streams that drain the area. Gentle to steep hills, which lie between 4,450 and 6,360 feet above sea level, characterize the topography. Approximately 7,600 acres of land is cultivated in the Horseshoe Creek valley and 1,000 or more acres in the Cassa Flats of the North Platte River and Middle Bear Creek valleys. The average annual precipitation of 13.15 inches and the streamflow diverted for irrigation from Horseshoe Creek and the North Platte River are usually inadequate to sustain crops during the entire growing season. Sedimentary rocks, which underlie about 99 percent of the Glendo area, range in age from Cambrian(?) to Recent and in thickness from about 3,000 to 4,700 feet. Beds of Paleozoic and Mesozoic age dip steeply away from the Laramie Range and the Hartville uplift to form a large syncline, which is interrupted by the Elkhorn anticline in the central part of the area. Beds of Tertiary and Quaternary age that were deposited over the older structural features and later were partly removed by erosion have dips of less than 6 ? . The 'Converse sand' of local usage at the top of the Hartville Formation of Mississippian(7), Pennsylvanian, and Permian age, the White River Formation of Oligocene age, and the flood-plain deposits of Recent .age are the most important aquifers in the Glendo area. The Hartville Formation consists predominantly of hard limestone and dolomite and of lesser amounts of sandstone and shale ; its thickness ranges from 850 to 1,050 feet throughout most of the area. The 'Converse sand' is an artesian aquifer consisting of fine- to medium-grained porous sandstone having an average thickness of about 80 feet. Recharge to the Hartville Formation is mainly from seepage of surface water from Glendo Reservoir and Spring Creek; ground water is discharged from the formation to the overlying White River Formation and the alluvium in the North Platte River valley near Cassa and to four wells in the Horseshoe Creek valley. Flowing wells yielding from a few gallons per minute to 175 gpm (gallons per minute) or more from the 'Converse sand' can probably be located in an area from ? mile to 1? miles wide and about 4? miles long in the lower Horseshoe Creek valley. The depth to the 'Converse sand' in this area depends upon the topographic relief and distance from the outcrop and ranges from 250 to about 1,000 feet. The discharge induced by pumping a well in the aquifer in the 'Converse sand' would probably amount to about 2 gpm per foot of drawdown. Values of 2,000, 2,100, and 10,300 gpd (gallons per day) per ft for the coefficient of transmissibility of the 'Converse sand' were obtained from aquifer tests at three wells. The chemical analyses of samples from the Hartville Formation ('Converse. sand' included) indicate that the water in the formation is of fairly good quality and adequate for domestic, stock, and irrigation uses, although the fluoride content is low and the water is hard. The White River Formation is composed of as much as 575 feet of fractured siltstone and claystone, and the flood-plain deposits include up to 65 feet of silt, sand, and gravel. Precipitation is the main type of recharge to the rocks of Tertiary age. Recharge to the alluvium in the valleys of Horseshoe Creek and the North Platte River occurs mainly by seepage of ground water from. underlying beds, by infiltration of irrigation water, and by infiltration of streamflow as bank storage. Ground water is discharged naturally from the area by seepage to streams, by underflow, and by evapotranspiration and artificially by wells. In 1961, the total discharge from 38 wells in the White River and Arikaree Formations and 2

Water Supply Paper

Ground-water reconnaissance in the Burnt River valley, Baker County, Oregon

The Burnt River valley in southern Baker County, Oreg., is underlain by rocks that range in age from pre-Tertiary to Quaternary. The pre-Tertiary rocks consist mainly of argillites, schists, limestones, and intrusive igneous rocks, while the Tertiary rocks consist mainly of felsic and mafic volcanic tuffs, lava flows and breccias, and fluviolacustrine deposits. Quaternary rocks include terrace gravels of Pleistocene and Recent age, and stream-valley alluvium of Recent age. The rock units most widely exposed along the valley are the fluviolacustrine deposits of Miocene and Pliocene(?) age, which extend to depths of as much as a thousand feet below the valley floor, and the pre-Tertiary rocks. Most of the rocks that underlie the valley are of relatively low permeability and yield only small to moderate quantities of water (generally less than 50 gpm) to wells. The fluviolacustrine deposits contain scattered lenses of relatively permeable sand and gravel, hut the unit as a whole is mainly silt and clay of low permeability. Two prospective irrigation wells in the area penetrated these deposits but were abandoned because of insufficient yield. Perhaps the most permeable rock unit in the area is the Columbia River Basalt of Miocene and Pliocene(?) age. It is exposed extensively west of the main valley, but apparently occurs only' as discontinuous lenses beneath the valley floor. Chemical analyses of water from seven wells in the area indicate that the ground waters have relatively large concentrations of dis-. solved mineral constituents. Water from two of the wells had excessive concentrations of boron and high sodium and salinity hazards with respect to use for irrigation. Perhaps the most favorable site for a test irrigation well is about 8 to 10 miles east of Hereford, where the Columbia River Basalt apparently extends beneath, and is intercalated with, the fluviolacustrine deposits.

Oregon

Geology and ground-water resources of the lower Little Bighorn River Valley, Big Horn County, Montana, with special reference to the drainage of waterlogged lands

The lower Little Bighorn River valley, Montana, is in the unglaciated part of the Missouri Plateau section of the Great Plains physiographic province. The river and its principal tributaries rise in the Bighorn Mountains, and the confluence of this northward-flowing stream with the Bighorn River is near the east edge of Hardin, Mont. The normal annual precipitation ranges from about 12 inches in the northern part of the area to 15 inches in the southern part. The economy of the area is founded principally on farming, much of the low-lying land adjacent to the river being irrigated. The irrigated land is within the Crow Indian Reservation, although a part is privately owned. The bedrock formations exposed in the area are of Cretaceous age and include the Parkman sandstone, Claggett shale, Eagle sandstone, Telegraph Creek shale, and Cody shale. The Cloverly formation, Tensleep sandstone, and Madison limestone, which underlie but are not exposed in the area, and the Parkman sandstone in the southern half of the area appear to be the principal bedrock aquifers. All except the Parkman lie at depths ranging from a few feet to several thousand feet, and all appear to be capable of yielding water in commercial quantities. Some of the other formations arc capable of yielding enough water for domestic and stock needs. The river alluvium of Recent age and the Pleistocene terrace deposits are the principal unconsolidated formations in the area with respect to water supply and drainage. Wells yielding as much as 100 gallons per minute may be developed in favorable areas. Pumping tests reveal that the transmissibility of the coarser unconsolidated materials probably ranges from about 15,000 to 30,000 gallons per day per foot. Two tests of the Parkman sandstone showed transmissibilities of 6,000 and 20,000 gallons per day per foot. Although a test of the Cloverly formation showed a transmissibility of only 3,000 gallons per day per foot, the high artesian pressure--80 pounds per square inch at the land surface--in the Cloverly caused the tested well to yield about 200 gallons per minute by natural flow; this is greater than the yield of any other single well in the area. Textural properties were compared with the hydraulic properties determined by laboratory tests to show the relation between different types of waterbearing materials. Materials classified as heavy soils-normally somewhat dense and impervious-had an average permeability of 7.2 gallons per day per square foot, which was more than expected. One sample of very coarse alluvial material had a permeability of 6,000 gallons per day per square foot. The depth to water beneath irrigation units was mapped, thus showing the waterlogged areas. Waterlogging is not a serious problem where the water table is more than 6 feet below the land surface. For the drainage studies the unconsolidated deposits are classified in two zones-coarse-grained sediments resting on the relatively impermeable bedrock floor and overlying fine-grained sediments which extend to the land surface. The transmissibility of the coarse-sediment zone generally is many times greater than that of the fine-sediment zone. Because in many places drains could not be economically dug deep enough to enter the coarse zone, the study of the effectiveness of drainage completed in the fine zone received much attention. The studies showed that, despite a considerable thickness of fine-grained sediments between the bottom of the drain and the top of the coarse zone, drainage ditches frequently were effective in relieving waterlogging of fields nearby. Pilot relief wells installed in existing drains showed that the effectiveness of some drains could be increased appreciably by installing a series of relief wells. Records of fluctuations of water levels in 196 observation wells and water-level contour maps were studied to show the principal areas of recharge and discharge in the irrigable areas.

Montana

A partial exponential lumped parameter model to evaluate groundwater age distributions and nitrate trends in long-screened wells

A partial exponential lumped parameter model (PEM) was derived to determine age distributions and nitrate trends in long-screened production wells. The PEM can simulate age distributions for wells screened over any finite interval of an aquifer that has an exponential distribution of age with depth. The PEM has 3 parameters – the ratio of saturated thickness to the top and bottom of the screen and mean age, but these can be reduced to 1 parameter (mean age) by using well construction information and estimates of the saturated thickness. The PEM was tested with data from 30 production wells in a heterogeneous alluvial fan aquifer in California, USA. Well construction data were used to guide parameterization of a PEM for each well and mean age was calibrated to measured environmental tracer data ( 3 H, 3 He, CFC-113, and 14 C). Results were compared to age distributions generated for individual wells using advective particle tracking models (PTMs). Age distributions from PTMs were more complex than PEM distributions, but PEMs provided better fits to tracer data, partly because the PTMs did not simulate 14 C accurately in wells that captured varying amounts of old groundwater recharged at lower rates prior to groundwater development and irrigation. Nitrate trends were simulated independently of the calibration process and the PEM provided good fits for at least 11 of 24 wells. This work shows that the PEM, and lumped parameter models (LPMs) in general, can often identify critical features of the age distributions in wells that are needed to explain observed tracer data and nonpoint source contaminant trends, even in systems where aquifer heterogeneity and water-use complicate distributions of age. While accurate PTMs are preferable for understanding and predicting aquifer-scale responses to water use and contaminant transport, LPMs can be sensitive to local conditions near individual wells that may be inaccurately represented or missing in an aquifer-scale flow model.

California

Hydrogeologic and water-quality characteristics of glacial-drift aquifers in Minnesota

Water in Minnesota 's glacial drift aquifers generally is of acceptable quality for most uses, including household supply, industrial use, and irrigation. The aquifers generally contain calcium magnesium bicarbonate-type waters, but other types are present also. Calcium magnesium sulfate-type waters are common in the confined drift aquifers in the southwestern and northwestern parts of the State. The elevated concentrations of sulfate, which exceed limits recommended for drinking water by the EPA, results mainly from solution of sulfate bearing minerals in rocks of Cretaceous age that have been reworked in deep glacial drift. Sodium and chloride-type waters are common in drift aquifers in northwestern Minnesota owing to the inflow of saline water from bedrock aquifers of Paleozoic age North Dakota. Cation exchange with clay minerals in the drift also is a source of sodium to these waters, particularly in the confined drift aquifers. Some of the water from these aquifers are unsuitable for irrigation because of elevated concentrations of sodium, and some are unsuitable for drinking because of elevated concentrations of chloride. Concentrations of nitrite plus nitrate (as N) locally exceed the EPA recommended limits for drinking water in central and northwestern Minnesota. Shallow, unconfined drift aquifers are particularly susceptible to nitrate contamination from land surface. Confined drift aquifers are much less susceptible because overlying till deposits retard downward movement of contaminants to the deeper aquifers. Nitrate contamination, which may cause methemoglobinemia in infants, is one of the more serious water quality concerns in Minnesota. Iron and manganese concentrations commonly exceed EPA 's recommendations for drinking water throughout the State, but these constituents affect aesthetic properties of water rather than health.

Minnesota

Environmental factors regulating the recruitment of walleye Sander vitreus and white bass Morone chrysops in irrigation reservoirs

Understanding the environmental factors that regulate fish recruitment is essential for effective management of fisheries. Generally, first-year survival, and therefore recruitment, is inherently less consistent in systems with high intra- and interannual variability. Irrigation reservoirs display sporadic patterns of annual drawdown, which can pose a substantial challenge to recruitment of fishes. We developed species-specific models using an 18-year data set compiled from state and federal agencies to investigate variables that regulate the recruitment of walleye Sander vitreus and white bass Morone chrysops in irrigation reservoirs in south-west Nebraska, USA. The candidate model set for walleye included only abiotic variables (water-level elevation, minimum daily air temperature during winter prior to hatching, annual precipitation, spring warming rate and May reservoir discharge), and the candidate model set for white bass included primarily biotic variables (catch per unit effort (CPUE) of black crappie Pomoxis nigromaculatus , CPUE of age-0 walleye, CPUE of bluegill Lepomis macrochirus and CPUE of age-3 and older white bass), each of which had a greater relative importance than the single abiotic variable (minimum daily air temperature during winter after hatching). Our findings improve the understanding of the recruitment of fishes in irrigation reservoirs and the relative roles of abiotic and biotic factors.

Nebraska

Hydrosalinity studies of the Virgin River, Dixie Hot Springs, and Littlefield Springs, Utah, Arizona, and Nevada

The Virgin River contributes a substantial amount of dissolved solids (salt) to the Colorado River at Lake Mead in the lower Colorado River Basin. Degradation of Colorado River water by the addition of dissolved solids from the Virgin River affects the suitability of the water for municipal, industrial, and agricultural use within the basin. Dixie Hot Springs in Utah are a major localized source of dissolved solids discharging to the Virgin River. The average measured discharge from Dixie Hot Springs during 2009–10 was 11.0 cubic feet per second (ft 3 /s), and the average dissolved-solids concentration was 9,220 milligrams per liter (mg/L). The average dissolved-solids load—a measurement that describes the mass of salt that is transported per unit of time—from Dixie Hot Springs during this period was 96,200 tons per year (ton/yr). Annual dissolved-solids loads were estimated at 13 monitoring sites in the Virgin River Basin from streamflow data and discrete measurements of dissolved-solids concentrations and (or) specific conductance. Eight of the sites had the data needed to estimate annual dissolved-solids loads for water years (WYs) 1999 through 2010. During 1999–2010, the smallest dissolved-solids loads in the Virgin River were upstream of Dixie Hot Springs (59,900 ton/yr, on average) and the largest loads were downstream of Littlefield Springs (298,200 ton/yr, on average). Annual dissolved-solids loads were smallest during 2002–03, which was a period of below normal precipitation. Annual dissolved-solids loads were largest during 2005—a year that included a winter rain storm that resulted in flooding throughout much of the Virgin River Basin. An average seepage loss of 26.7 ft 3 /s was calculated from analysis of monthly average streamflow from July 1998 to September 2010 in the Virgin River for the reach that extends from just upstream of the Utah/Arizona State line to just above the Virgin River Gorge Narrows. Seepage losses from three river reaches in the Virgin River Gorge containing known fault zones accounted for about 48 percent of this total seepage loss. An additional seepage loss of 6.7 ft 3 /s was calculated for the reach of the Virgin River between Bloomington, Utah, and the Utah/Arizona State line. This loss in flow is small compared to total flow in the river and is comparable to the rated error in streamflow measurements in this reach; consequently, it should be used with caution. Littlefield Springs were studied to determine the fraction of its discharge that originates as upstream seepage from the Virgin River and residence time of this water in the subsurface. Geochemical and environmental tracer data from groundwater and surface-water sites in the Virgin River Gorge area suggest that discharge from Littlefield Springs is a mixture of modern (post-1950s) seepage from the Virgin River upstream of the springs and older groundwater from a regional carbonate aquifer. Concentrations of the chlorofluorocarbons (CFCs) CFC-12 and CFC-113, chloride/fluoride and chloride/bromide ratios, and the stable isotope deuterium indicate that water discharging from Littlefield Springs is about 60 percent seepage from the Virgin River and about 40 percent discharge from the regional carbonate aquifer. The river seepage component was determined to have an average subsurface traveltime of about 26 ±1.6 years before discharging at Littlefield Springs. Radiocarbon data for Littlefield Springs suggest groundwater ages from 1,000 to 9,000 years. Because these are mixed waters, the component of discharge from the carbonate aquifer is likely much older than the groundwater ages suggested by the Littlefield Springs samples. If the dissolved-solids load from Dixie Hot Springs to the Virgin River were reduced, the irrigation water subsequently applied to agricultural fields in the St. George and Washington areas, which originates as water from the Virgin River downstream of Dixie Hot Springs, would have a lower dissolved-solids concentration. Dissolved-solids concentrations in excess irrigation water draining from the agricultural fields are about 1,700 mg/L higher than the concentrations in the Virgin River water that is currently (2014) used for irrigation that contains inflow from Dixie Hot Springs; this increase results from evaporative concentration and dissolution of mineral salts in the irrigated agricultural fields. The water samples collected from drains downgradient from the irrigated areas are assumed to include the dissolution of all available minerals precipitated in the soil during the previous irrigation season. Based on this assumption, a change to more dilute irrigation water will not dissolve additional minerals and increase the dissolved-solids load in the drain discharge. Following the hypothetical reduction of salts from Dixie Hot Springs, which would result in more dilute Virgin River irrigation water than is currently used, the dissolution of minerals left in the soil from the previous irrigation season would result in a net increase in dissolved-solids concentrations in the drain discharge, but this increase should only last one irrigation season. After one (or several) seasons of irrigating with more dilute irrigation water, mineral precipitation and subsequent re-dissolution beneath the agricultural fields should be greatly reduced, leading to a reduction in dissolved-solids load to the Virgin River below the agricultural drains. A mass-balance model was used to predict changes in the dissolved-solids load in the Virgin River if the salt discharging from Dixie Hot Springs were reduced or removed. Assuming that 33.4 or 26.7 ft 3 /s of water seeps from the Virgin River to the groundwater system upstream of the Virgin River Gorge Narrows, the immediate hypothetical reduction in dissolved-solids load in the Virgin River at Littlefield, Arizona is estimated to be 67,700 or 71,500 ton/yr, respectively. The decrease in dissolved-solids load in seepage from the Virgin River to the groundwater system is expected to reduce the load discharging from Littlefield Springs in approximately 26 years, the estimated time lag between seepage from the river and discharge of the seepage water, after subsurface transport, from Littlefield Springs. At that time, the entire reduction in dissolved solids seeping from the Virgin River is expected to be realized as a reduction in dissolved solids discharging from Littlefield Springs, resulting in an additional reduction of 24,700 ton/yr (based on 33.4 ft 3 /s of seepage loss) or 21,000 ton/yr (based on 26.7 ft 3 /s of seepage loss) in the river’s dissolved-solids load at Littlefield.

Arizona, Nevada, Utah

Hydrology of the shallow aquifer and uppermost semiconfined aquifer near El Paso, Texas

The availability of fresh ground water in El Paso and adjacent areas that is needed to meet increased demand for water supply concerns local, State, and Federal agencies. The Hueco bolson is the principal aquifer in the El Paso area. Starting in the early 1900s and continuing to the 1950s, most of the municipal and industrial water supply in El Paso was pumped from the Hueco bolson aquifer from wells in and near the Rio Grande Valley and the international border. The Rio Grande is the principal surface-water feature in the El Paso area, and a major source of recharge to the shallow aquifer (Rio Grande alluvium) within the study area is leakage of flow from the Rio Grande. The shallow aquifer and the underlying Hueco bolson aquifer are in general hydrologic connection, but wells that penetrate these aquifers have different water levels and water quality. The configuration (slope) of the predevelopment (pre- 1903) water table indicates that ground water in the Hueco bolson flowed south from the Texas-New Mexico State line toward the El Paso Valley and the Rio Grande. There the water moved upward from the Hueco bolson fill through the alluvium and discharged as seepage at the land surface or through evapotranspiration on the river flood plain. Subsequent (post-January 1903) development of the Hueco bolson has caused water levels to decline in both the bolson aquifer and the shallow aquifer, and these declines have reversed the original vertical hydraulic gradient and now cause vertical leak- 1 Hydrologist, U.S. Geological Survey. 2 Geologist, El Paso Water Utilities-Public Service Board. age downward. Water-level declines in the shallow aquifer have in turn induced increasing amounts of leakage from the Rio Grande and from irrigation canals. The reversal from upward to downward in vertical hydraulic gradient between the Rio Grande alluvium and the underlying Hueco bolson aquifer has induced shallow water in the alluvium to move downward into the deeper aquifer. The introduction of water from the alluvium probably has led to a gradual water-quality deterioration of ground water in the Hueco bolson aquifer. The extent of any deterioration is a major concern because the dissolved solids concentration in water from some wells is approaching 1,000 milligrams per liter and already has exceeded this limit in other wells.

Texas

Water resources of Fremont County, Wyoming

Average annual runoff (inches per year) ranged from 0.90 to 22 in the Mountainous Region of Fremont County and from 0.06 to 0.72 in the Plains Region. The Wind River Formation of Tertiary age has the most well development. Quaternary alluvium and colluvium is the second-most developed. Some wells and springs discharge more than 300 gallons per minute from older selected geologic units. Geologic units are recharged by infiltration of precipi- tation, surface water, or irrigation water, or by leakage from another unit. The general direction of ground-water movement in the two major basins in the county is toward the Sweetwater and Wind Rivers. Ground water is discharged by wells, springs and seeps, evapotranspiration, and discharge to streams, lakes, drains, and other geologic units. Ground- water levels near Riverton's municipal supply were typically deepest in August when ground water was the sole supply. After 1981, ground water only supplemented the supply and water levels appeared to recover. Surface water supplies about 99 percent of total offstream use in Fremont County; irrigation is the largest use. The largest use of ground water is public supply. Twenty-five samples were collected from the Sweetwater River and tributaries in September 1991. Dissolved-solids concentrations ranged from 39 to 271 milligrams per liter, increasing downstream. All six water samples collected from the Cody Shale (Cretaceous age) exceeded 500 milligrams per liter dissolved solids-all samples from Miocene rocks and the White River Formation (Oligocene age) had dissolved solids less than 500 milligrams per liter.

Wyoming

Population biology of bluegills, Lepomis macrochirus, in lotic habitats on the irrigated San Joaquin Valley floor

Rapid expansion of irrigated agriculture in the western United States has prompted concerns for aquatic resources. Although the impacts of irrigation activities on quality and quantity of river water are well documented (e.g., high turbidity from soil erosion, eutrophication from nutrient runoff, pesticide contamination, reduced dis- charge), their effects on fish populations are still poorly understood. We studied the food, growth, and relative weight (a measure of body condition) of bluegills, Lepo- mis macrochirus, in relation to environmental factors in reaches of the San Joaquin and Merced rivers that have been affected to varying degrees by irrigation return flows. Fry of bluegills ate mostly cladocerans and copepods; fingerlings and larger fish ate immature aquatic insects, terrestrial insects, amphipods, and mollusks. Bluegill stomachs were fuller and contained a higher diversity of forage taxa in habitats with low turbidity and conductivity, weak buffering capacity, and low nutrient levels; bluegills also ate a more diverse diet where the potential forage supply (benthic macroinvertebrates) was most diverse. Bluegills attained mean total lengths of about 42 mm at age I, 86 mm at age 11, 116 mm at age III, 153 mm at age IV, and 166 mm at age V. Mean relative weight ranged from 96-111. Growth rate and relative weight were not significantly correlated with environmental or dietary variables. On the basis of our study, we concluded that environmental degradation from irrigation activities affected the diet of bluegills primarily by modifying the food supply, but growth rate and body condition were not affected.

California

Time of travel and dye dosage for an irrigation canal system near Duchesne, Utah

Fracturing and subsidence of the land surface in the Milford area oil Utah have resulted from the decline of water levels due to pumping in unconsolidated deposits of Quaternary age. To the writers’ knowledge, these are the first such effects of ground-water withdrawal reported in Utah. The fracturing is in an area about 1 mile (1.6 km) wide and 11 miles (18 km) long near Milford, in an unsaturated clay-silt zone (locally peaty at top) in the upper part of the principal ground-water reservoir. The fractures range in length from several feet to more than 100 feet (30 m), and their maximum measured depth in 1972 was 4 feet (1.2 m). Land subsidence in the Milford area is demonstrated by three lines of evidence: (1) collapse structures, (2) well casings that protrude higher above the land surface than when first placed in the borehole, and (3) lower elevations at National Ocean Survey (formerly U.S. Coast and Geodetic Survey) bench marks in 1970 than in 1908. This evidence shows that land subsidence in the Milford area is of two types, each having a different origin. One type has a near-surface origin in the clay-silt zone in the upper part of the principal groundwater reservoir, and the other is in the lower artesian aquifers of the principal ground-water reservoir. The amount of observed subsidence ranges from 0.05 foot (0.015 m) at the bench mark at Read to about 6 feet (1.8 m) at collapse structures in the Hay Springs area.

Utah

Ground-water age and quality in the High Plains Aquifer near Seward, Nebraska, 2003-04

The U.S. Geological Survey, in cooperation with the City of Seward, Nebraska, conducted a study of ground-water age and quality to improve understanding of: (1) traveltimes from recharge areas to public-supply wells, (2) the effects of geochemical reactions in the aquifer on water quality, and (3) how water quality has changed historically in response to land-use practices. Samples were collected from four supply wells in the Seward west well field and from nine monitoring wells along two approximate ground-water flow paths leading to the well field. Concentrations of three different chlorofluorocarbons (CFC-12, CFC-11, and CFC-113), sulfur hexafluoride (SF 6 ), and ratios of tritium ( 3 H) to helium-3 ( 3 He) isotope derived from radioactive decay of 3H were used to determine the apparent recharge age of ground-water samples. Age interpretations were based primarily on 3 H/ 3 He and CFC-12 data. Estimates of apparent ground-water age from tracer data were complicated by mixing of water of different ages in 10 of the 13 ground-water samples collected. Apparent recharge dates of unmixed ground-water samples or mean recharge dates of young fractions of mixed water in samples collected from monitoring wells ranged from 1985 to 2002. For monitoring-well samples containing mixed water, the fraction of the sample composed of young water ranged from 26 to 77 percent of the sample. Apparent mean recharge dates of young fractions in samples collected from four supply wells in the Seward west well field ranged from about 1980 to 1990. Estimated fractions of the samples composed of young water ranged from 39 to 54 percent. It is implicit in the mixing calculations that the remainder of the sample that is not young water is composed of water that is more than 60 years old and contains no detectable quantities of modern atmospheric tracers. Estimated fractions of the mixed samples composed of "old" water ranged from 23 to 74 percent. Although alternative mixing models can be used to interpret the results, the mean age and mixing fractions from the primary mixing models used were fairly similar. Relations of ground-water age and nitrate concentrations to depth were not consistent across the study area. In some well nests, more young water and nitrate were present near the bottom than in the middle of the aquifer. These results probably reflect pumping from irrigation and supply wells, which are screened primarily in the lower part of the aquifer, and draw younger water downward in the aquifer. Substantial mixing probably occurs because the aquifer is relatively thin (50 feet) and has a relatively high density of wells (about five pumping wells per square mile). The most reliable estimate of horizontal traveltimes based on differences in ground-water ages between a shallow monitoring well at the upgradient end of the northwest well transect and the deep well at the downgradient end of the well transect was 9 years to travel a distance of about 2 miles. The general similarity of ages at similar depths between different well nests is consistent with the fact that horizontal flow in the aquifer is relatively rapid. Concentrations of nitrate (as nitrogen) in untreated ground-water samples from supply wells in the well field were larger than the U.S. Environmental Protection Agency Maximum Contaminant Level for drinking water of 10 mg/L (milligrams per liter), ranging from 11.3 to 13.5 mg/L. It is unlikely that nitrate concentrations in the aquifer near the Seward west well field are decreased by denitrification in the aquifer due to oxic geochemical conditions that preclude this reaction. Nitrate concentrations coupled with water recharge dates were compared to historical estimated fertilizer application in an attempt to reconstruct historical trends in ground-water nitrate concentrations and their relation to land-use practices. Nitrate concentrations in young-water fractions, after adjustment for mixing, may be decreasing over apparent recharge dates of 1980 to 2002, corresponding to a period of generally decreasing nitrogen fertilizer applications.

Nebraska

Groundwater quality and hydrology with emphasis on selenium mobilization and transport in the Lower Gunnison River Basin, Colorado, 2012–16

Dissolved selenium is a contaminant of concern in the lower Gunnison River Basin, Colorado. Selenium is naturally present in the Cretaceous Mancos Shale and is leached to groundwater and surface water by irrigation. The groundwater on the east side of the Uncompahgre River in Delta and Montrose Counties is one of the primary sources of selenium concentration and load to surface water in the lower Gunnison River Basin. Although little information about the contribution of groundwater to surface water has been historically available, groundwater has often been implicated as an appreciable source of selenium to surface water. From 2012 to 2016, the U.S. Geological Survey, in cooperation with the Bureau of Reclamation, the Colorado Water Conservation Board, and the Gunnison Basin Selenium Management Program, established a 30-well groundwater-monitoring network on irrigated land to characterize the hydrology and groundwater quality of the shallow groundwater system on the east side of the Uncompahgre River in the lower Gunnison River Basin. The installation of the 30-well network and the data collected allowed for the development of a conceptual model of selenium mobilization and transport in the shallow groundwater system. Monitoring wells were completed in surficial deposits and in weathered Mancos Shale, which generally exhibited unconfined and confined conditions, respectively. Groundwater-quality monitoring provides information on the distribution of selenium and the geochemical processes controlling selenium concentrations in shallow groundwater. Monitoring wells were sampled between August 2013 and March 2015 to understand groundwater quality, seasonality, sources of recharge, and groundwater age. Concentrations of dissolved selenium ranged from below the limit of detection to 4,100 micrograms per liter (µg/L), with a median concentration of 14 µg/L. Concentrations showed a high degree of spatial variability and no seasonal difference. Similarly, no seasonal pattern was observed in specific conductance values of groundwater despite the considerably lower specific conductance value of irrigation water. Reduction-oxidation processes are important controls on selenium mobility. Nitrate derived from geologic material was a primary control on reduction-oxidation conditions in groundwater and inhibited selenium reduction to less mobile forms. Nitrate was reduced by denitrification in groundwater, but it was not reduced to the extent necessary to allow for selenium reduction. Groundwater ages were determined for groundwater samples from eight wells and ranged from 6 to 20 years old. Isotopic data indicate groundwater was recharged by irrigation water; no information collected supported an older, deeper source of recharge to the shallow groundwater system. Data on water level in all wells showed response to irrigation practices, but the response was delayed in some wells, which may be an indication of distance from recharge source.

Colorado

Effect of agricultural practices on hydrology and water chemistry in a small irrigated catchment, Yakima River Basin, Washington

The role of irrigation and artificial drainage in the hydrologic cycle and the transport of solutes in a small agricultural catchment in central Washington's Yakima Valley were explored using hydrologic, chemical, isotopic, age-dating, and mineralogical data from several environmental compartments, including stream water, ground water, overland flow, and streambed pore water. A conceptual understanding of catchment hydrology and solute transport was developed and an inverse end-member mixing analysis was used to further explore the effects of agriculture in this small catchment. The median concentrations of major solutes and nitrates were similar for the single field site and for the catchment outflow site, indicating that the net effects of transport processes for these constituents were similar at both scales. However, concentrations of nutrients were different at the two sites, suggesting that field-scale variations in agricultural practices as well as nearstream and instream biochemical processes are important components of agricultural chemical transformation and transport in this catchment. This work indicates that irrigation coupled with artificial drainage networks may exacerbate the ecological effects of agricultural runoff by increasing direct connectivity between fields and streams and minimizing potentially mitigating effects (denitrification and dilution, for example) of longer subsurface pathways.

Washington