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At least 91 records · Page 5Linked to original sources
USGS2009

A new syringe pump apparatus for the retrieval and temporal analysis of helium in groundwaters and geothermal fluids

We present details of a newly designed syringe pump apparatus for the retrieval and temporal analysis of helium (SPARTAH). The device is composed of a commercially available syringe pump connected to coils of Cu tubing, which interface the syringe and the groundwater or geothermal wellhead. Through test deployments at geothermal wells in Iceland and California, we show that well fluids are drawn smoothly, accurately, and continuously into the Cu tubing and can be time‐stamped through user‐determined operating parameters. In the laboratory, the tubing is sectioned to reveal helium (He) characteristics of the fluids at times and for durations of interest. The device is capable of prolonged deployments, up to 6 months or more, with minimal maintenance. It can be used to produce detailed time series records of He, or any other geochemical parameter, in groundwaters and geothermal fluids. SPARTAH has application in monitoring projects assessing the relationship between external transient events (e.g., earthquakes) and geochemical signals in aqueous fluids.

Geochemistry, Geophysics, Geosystems↗
USGS2009

EMAG2: A 2-arc min resolution Earth Magnetic Anomaly Grid compiled from satellite, airborne, and marine magnetic measurements

A global Earth Magnetic Anomaly Grid (EMAG2) has been compiled from satellite, ship, and airborne magnetic measurements. EMAG2 is a significant update of our previous candidate grid for the World Digital Magnetic Anomaly Map. The resolution has been improved from 3 arc min to 2 arc min, and the altitude has been reduced from 5 km to 4 km above the geoid. Additional grid and track line data have been included, both over land and the oceans. Wherever available, the original shipborne and airborne data were used instead of precompiled oceanic magnetic grids. Interpolation between sparse track lines in the oceans was improved by directional gridding and extrapolation, based on an oceanic crustal age model. The longest wavelengths (>330 km) were replaced with the latest CHAMP satellite magnetic field model MF6. EMAG2 is available at http://geomag.org/models/EMAG2 and for permanent archive at http://earthref.org/ cgi-bin/er.cgi?s=erda.cgi?n=970. ?? 2009 by the American Geophysical Union.

Geochemistry, Geophysics, Geosystems↗
USGS2009

Advancing techniques to constrain the geometry of the seismic rupture plane on subduction interfaces a priori: Higher-order functional fits

Ongoing developments in earthquake source inversions incorporate nonplanar fault geometries as inputs to the inversion process, improving previous approaches that relied solely on planar fault surfaces. This evolution motivates advancing the existing framework for constraining fault geometry, particularly in subduction zones where plate boundary surfaces that host highly hazardous earthquakes are clearly nonplanar. Here, we improve upon the existing framework for the constraint of the seismic rupture plane of subduction interfaces by incorporating active seismic and seafloor sediment thickness data with existing independent data sets and inverting for the most probable nonplanar subduction geometry. Constraining the rupture interface a priori with independent geological and seismological information reduces the uncertainty in the derived earthquake source inversion parameters over models that rely on simpler assumptions, such as the moment tensor inferred fault plane. Examples are shown for a number of wellconstrained global locations. We expand the coverage of previous analyses to a more uniform global data set and show that even in areas of sparse data this approach is able to accurately constrain the approximate subduction geometry, particularly when aided with the addition of data from local active seismic surveys. In addition, we show an example of the integration of many two-dimensional profiles into a threedimensional surface for the Sunda subduction zone and introduce the development of a new global threedimensional subduction interface model: Slab1.0. ?? 2009 by the American Geophysical Union.

Geochemistry, Geophysics, Geosystems↗
USGS2010

Volume change associated with formation and dissociation of hydrate in sediment

Gas hydrate formation and dissociation in sediments are accompanied by changes in the bulk volume of the sediment and can lead to changes in sediment properties, loss of integrity for boreholes, and possibly regional subsidence of the ground surface over areas where methane might be produced from gas hydrate in the future. Experiments on sand, silts, and clay subject to different effective stress and containing different saturations of hydrate formed from dissolved phase tetrahydrofuran are used to systematically investigate the impact of gas hydrate formation and dissociation on bulk sediment volume. Volume changes in low specific surface sediments (i.e., having a rigid sediment skeleton like sand) are much lower than those measured in high specific surface sediments (e.g., clay). Early hydrate formation is accompanied by contraction for all soils and most stress states in part because growing gas hydrate crystals buckle skeletal force chains. Dilation can occur at high hydrate saturations. Hydrate dissociation under drained, zero lateral strain conditions is always associated with some contraction, regardless of soil type, effective stress level, or hydrate saturation. Changes in void ratio during formation-dissociation decrease at high effective stress levels. The volumetric strain during dissociation under zero lateral strain scales with hydrate saturation and sediment compressibility. The volumetric strain during dissociation under high shear is a function of the initial volume average void ratio and the stress-dependent critical state void ratio of the sediment. Other contributions to volume reduction upon hydrate dissociation are related to segregated hydrate in lenses and nodules. For natural gas hydrates, some conditions (e.g., gas production driven by depressurization) might contribute to additional volume reduction by increasing the effective stress.

Geochemistry, Geophysics, Geosystems↗
USGS2009

Joint inversion for Vp, Vs, and Vp/Vs at SAFOD, Parkfield, California

We refined the three-dimensional (3-D) Vp, Vs and Vp/Vs models around the San Andreas Fault Observatory at Depth (SAFOD) site using a new double-difference (DD) seismic tomography code (tomoDDPS) that simultaneously solves for earthquake locations and all three velocity models using both absolute and differential P, S, and S-P times. This new method is able to provide a more robust Vp/Vs model than that from the original DD tomography code (tomoDD), obtained simply by dividing Vp by Vs. For the new inversion, waveform cross-correlation times for earthquakes from 2001 to 2002 were also used, in addition to arrival times from earthquakes and explosions in the region. The Vp values extracted from the model along the SAFOD trajectory match well with the borehole log data, providing in situ confirmation of our results. Similar to previous tomographic studies, the 3-D structure around Parkfield is dominated by the velocity contrast across the San Andreas Fault (SAF). In both the Vp and Vs models, there is a clear low-velocity zone as deep as 7 km along the SAF trace, compatible with the findings from fault zone guided waves. There is a high Vp/Vs anomaly zone on the southwest side of the SAF trace that is about 1-2 km wide and extends as deep as 4 km, which is interpreted to be due to fluids and fractures in the package of sedimentary rocks abutting the Salinian basement rock to the southwest. The relocated earthquakes align beneath the northeast edge of this high Vp/Vs zone. We carried out a 2-D correlation analysis for an existing resistivity model and the corresponding profiles through our model, yielding a classification that distinguishes several major lithologies. ?? 2009 by the American Geophysical Union.

Geochemistry, Geophysics, Geosystems↗
USGS2009

Coral proxy record of decadal-scale reduction in base flow from Moloka'i, Hawaii

Groundwater is a major resource in Hawaii and is the principal source of water for municipal, agricultural, and industrial use. With a growing population, a long-term downward trend in rainfall, and the need for proper groundwater management, a better understanding of the hydroclimatological system is essential. Proxy records from corals can supplement long-term observational networks, offering an accessible source of hydrologic and climate information. To develop a qualitative proxy for historic groundwater discharge to coastal waters, a suite of rare earth elements and yttrium (REYs) were analyzed from coral cores collected along the south shore of Moloka'i, Hawaii. The coral REY to calcium (Ca) ratios were evaluated against hydrological parameters, yielding the strongest relationship to base flow. Dissolution of REYs from labradorite and olivine in the basaltic rock aquifers is likely the primary source of coastal ocean REYs. There was a statistically significant downward trend (−40%) in subannually resolved REY/Ca ratios over the last century. This is consistent with long-term records of stream discharge from Moloka'i, which imply a downward trend in base flow since 1913. A decrease in base flow is observed statewide, consistent with the long-term downward trend in annual rainfall over much of the state. With greater demands on freshwater resources, it is appropriate for withdrawal scenarios to consider long-term trends and short-term climate variability. It is possible that coral paleohydrological records can be used to conduct model-data comparisons in groundwater flow models used to simulate changes in groundwater level and coastal discharge.

Hawai'i↗
USGS2010

A snapshot of climate variability at Tahiti ~ 9 ka using a fossil coral from IODP Expedition 310

The Integrated Ocean Drilling Program (IODP) Expedition 310 recovered drill cores from the drowned reefs around the island of Tahiti (17°40′S, 149°30′W), many of which contained samples of massive corals from the genus Porites . Herein we report on one well-preserved fossil coral sample: a 13.6 cm long Porites sp. dated by uranium series techniques at 9523 ± 33 years. Monthly δ 18 O and Sr/Ca determinations reveal nine clear and robust annual cycles. Coral δ 18 O and Sr/Ca determinations estimate a mean temperature of ∼24.3°C (∼3.2°C colder than modern) for Tahiti at 9.5 ka; however, this estimate is viewed with caution since potential sources of cold bias in coral geochemistry remain to be resolved. The interannual variability in coral δ 18 O is similar between the 9.5 ka coral record and a modern record from nearby Moorea. The seasonal cycle in coral Sr/Ca is approximately the same or greater in the 9.5 ka coral record than in modern coral records from Tahiti. Paired analysis of coral δ 18 O and Sr/Ca indicates cold/wet (warm/dry) interannual anomalies, opposite from those observed in the modern instrumental record.

Geochemistry, Geophysics, Geosystems↗
USGS2010

Source materials for inception stage Hawaiian magmas: Pb‐He isotope variations for early Kilauea

New noble gas and radiogenic isotopic compositions are presented for tholeiitic, transitional, and alkalic rocks from the submarine Hilina region on the south flank of Kilauea, Hawaii. The 3 He/ 4 He ratios for undegassed glass and olivine separates (11–26 Ra) contrast with those of postshield and rejuvenated alkalic lavas, consistent with the alkalic and transitional basalts at Hilina corresponding to early Kilauea magmas. Most early Kilauea samples contain highly radiogenic Pb isotopes compared with other Hawaiian rocks and therefore derive from a Hawaiian plume end‐member source (here referred to as the Hilina component) distinctive in that respect. Besides radiogenic Pb isotopes, the Hilina component has relatively low 3 He/ 4 He (<12 Ra) among the Hawaiian magmas. Hawaiian inception stage magmas, including Hilina, Loihi, and deep Hana Ridge (east Maui), define a linear array in 206 Pb/ 204 Pb‐ 3 He/ 4 He isotope space, indicating that mixing between the Hilina and Loihi components (or their melts) dominates magmatism at the leading edge of the Hawaiian plume. The Hilina component's isotopic characteristics can be derived from young subduction‐recycled crust or metasomatised mantle. The isotopic differences between the geographically discriminated Kea and Loa trend volcanic chains, observed in shield stage lavas, are also seen in the inception stage magmas, suggesting that proportions of melts derived from the Hilina and Loihi components were different between the Kea and Loa trend volcanoes.

Hawaii↗
USGS2010

Upper mantle rheology from GRACE and GPS postseismic deformation after the 2004 Sumatra-Andaman earthquake

Mantle rheology is one of the essential, yet least understood, material properties of our planet, controlling the dynamic processes inside the Earth's mantle and the Earth's response to various forces. With the advent of GRACE satellite gravity, measurements of mass displacements associated with many processes are now available. In the case of mass displacements related to postseismic deformation, these data may provide new constraints on the mantle rheology. We consider the postseismic deformation due to the M w = 9.2 Sumatra 26 December 2004 and M w = 8.7 Nias 28 March 2005 earthquakes. Applying wavelet analyses to enhance those local signals in the GRACE time varying geoids up to September 2007, we detect a clear postseismic gravity signal. We supplement these gravity variations with GPS measurements of postseismic crustal displacements to constrain postseismic relaxation processes throughout the upper mantle. The observed GPS displacements and gravity variations are well explained by a model of viscoelastic relaxation plus a small amount of afterslip at the downdip extension of the coseismically ruptured fault planes. Our model uses a 60 km thick elastic layer above a viscoelastic asthenosphere with Burgers body rheology. The mantle below depth 220 km has a Maxwell rheology. Assuming a low transient viscosity in the 60–220 km depth range, the GRACE data are best explained by a constant steady state viscosity throughout the ductile portion of the upper mantle (e.g., 60–660 km). This suggests that the localization of relatively low viscosity in the asthenosphere is chiefly in the transient viscosity rather than the steady state viscosity. We find a 8.10 18 Pa s mantle viscosity in the 220–660 km depth range. This may indicate a transient response of the upper mantle to the high amount of stress released by the earthquakes. To fit the remaining misfit to the GRACE data, larger at the smaller spatial scales, cumulative afterslip of about 75 cm at depth should be added over the period spanned by the GRACE models. It produces only small crustal displacements. Our results confirm that satellite gravity data are an essential complement to ground geodetic and geophysical networks in order to understand the seismic cycle and the Earth's inner structure.

Andaman Sea, Sumatra↗
USGS2010

Archeomagnetic dating in western North America: An updated reference curve based on paleomagnetic and archeomagnetic data sets

[1] A robust database of paleomagnetic (PM) and archeomagnetic (AM) data for western North America covering the past 4 millennia is assembled from three data sets: (1) published PM data for dated lava flows, (2) recently published AM data generated by R. L. DuBois, and (3) published AM data generated by J. L. Eighmy. Chronologic information for the AM data sets has been reassessed, and the data points have been assigned to age ranges depending on their archeological contexts. We have selected the computer program ArcheoCourbe, available from M. Le Goff (http://www.ipgp.fr/∼legoff) or the auxiliary material (see also http://EarthRef.org), to construct AM reference curves and to quantitatively estimate AM dates for archeological and geological samples. The updated curve provides a more detailed record of prehistoric secular variation for western North America than was previously available and shows a short interval of rapid secular variation (SV) in the 10th or 11th centuries at near-excursional rates. Similar and coeval features in the Hawaiian and, to a lesser extent, Arkansan SV data sets possibly indicate a rapid amplitudinal shift in the regional nondipole field at that time.

Arizona, California, Colorado, Idaho, New Mexico, ↗
USGS2010

Ferromanganese crusts as archives of deep water Cd isotope compositions

The geochemistry of Cd in seawater has attracted significant attention owing to the nutrient-like properties of this element. Recent culturing studies have demonstrated that Cd is a biologically important trace metal that plays a role in the sequestration of inorganic carbon. This conclusion is supported by recent isotope data for Cd dissolved in seawater and incorporated in cultured phytoplankton. These results show that plankton features isotopically light Cd while Cd-depleted surface waters typically exhibit complimentary heavy Cd isotope compositions. Seawater samples from below 900 m depth display a uniform and intermediate isotope composition of ε 114/110 Cd = +3.3 ± 0.5. This study investigates whether ferromanganese (Fe-Mn) crusts are robust archives of deep water Cd isotope compositions. To this end, Cd isotope data were obtained for the recent growth surfaces of 15 Fe-Mn crusts from the Atlantic, Pacific, Indian, and Southern oceans and two USGS Fe-Mn reference nodules using double spike multiple collector inductively coupled plasma mass spectrometry. The Fe-Mn crusts yield a mean ε 114/110 Cd of +3.2 ± 0.4 (2 SE, n = 14). Data for all but one of the samples are identical, within the analytical uncertainty of ±1.1ε 114/110 Cd (2 SD), to the mean deep water Cd isotope value. This indicates that Fe-Mn crusts record seawater Cd isotope compositions without significant isotope fractionation. A single sample from the Southern Ocean exhibits a light Cd isotope composition of ε 114/110 Cd = 0.2 ± 1.1. The origin of this signature is unclear, but it may reflect variations in deep water Cd isotope compositions related to differences in surface water Cd utilization or long-term changes in seawater ε 114/110 Cd. The results suggest that time series analyses of Fe-Mn crusts may be utilized to study changes in marine Cd utilization.

Geochemistry, Geophysics, Geosystems↗
USGS2010

Contamination of basaltic lava by seawater: Evidence found in a lava pillar from Axial Seamount, Juan de Fuca Ridge

A lava pillar formed during the 1998 eruption at Axial Seamount exhibits compositional and textural evidence for contamination by seawater under magmatic conditions. Glass immediately adjacent to anastomosing microfractures within 1 cm of the inner pillar wall is oxidized and significantly enriched in Na and Cl and depleted in Fe and K with respect to that in glassy selvages from the unaffected outer pillar wall. The affected glass contains up to 1 wt % Cl and is enriched by ∼2 wt % Na 2 O relative to unaffected glass, consistent with a nearly 1:1 (molar) incorporation of NaCl. Glass bordering the Cl‐enriched glass in the inner pillar wall is depleted in Na but enriched in K. The presence of tiny (<10 μ m) grains of Cu‐Fe sulfides and Fe sulfides as well as elemental Ni, Ag, and Au in the Na‐depleted, K‐enriched glass of the inner pillar wall implies significant reduction of this glass, presumably by hydrogen generated during seawater contamination and oxidation of lava adjacent to microfractures. We interpret the compositional anomalies we see in the glass of the interior pillar wall as caused by rapid incorporation of seawater into the still‐molten lava during pillar growth, probably on the time scale of seconds to minutes. Only one of seven examined lava pillars shows this effect, and we interpret that seawater has to be trapped in contact with molten lava (inside the lava pillar, in this case) to produce the effects we see. Thus, under the right conditions, seawater contamination of lavas during submarine eruptions is one means by which the oceanic crust can sequester Cl during its global flux cycle. However, since very few recent lava flows have been examined in similar detail, the global significance of this process in effecting Earth's Cl budget remains uncertain.

Geochemistry, Geophysics, Geosystems↗
USGS2010

Clockwise rotation and implications for northward drift of the western Transverse Ranges from paleomagnetism of the Piuma Member, Sespe Formation, near Malibu, California

New paleomagnetic results from mid-Tertiary sedimentary beds in the Santa Monica Mountains reinforce the evidence for large-scale rotation of the western Transverse Ranges, and anisotropy measurements indicate that compaction-induced inclination flattening may resolve a long-standing controversy regarding the original paleolatitude of the rotated block. Previously published paleomagnetic data indicate that post-Oligocene rotation amounts to 70°–110° clockwise, affecting the Channel Islands, Santa Monica Mountains, and Santa Ynez Mountains. The Sespe Formation near Malibu consists of a lower member dominated by nonmarine sandstone and conglomerate and an upper section, the Piuma Member, which consists of gray-red sandstone and mudstone interbedded with minor tuff and limestone beds. The Piuma Member has a paleomagnetic pole at 36.6°N, 326.7°E (A 95min = 5.0°, A 95max = 9.6°), obtained by thermal demagnetization of 34 oriented cores from Oligocene and early Miocene beds. After correcting for plunge of the geologic structure, the data are consistent with significant clockwise rotation (77° ± 7°) of the region relative to stable North America. Rotation of the western Transverse Ranges is generally viewed as a consequence of Pacific–North American plate interactions after 28 Ma, when east–west subduction gave way to northwest transform motion in southern California. Inclinations from the Piuma study indicate a paleolatitude anomaly of 11° ± 7° and are consistent with a mean northward drift that exceeds generally accepted San Andreas fault displacement by a factor of 3. However, sedimentary inclination error may accentuate the anomaly. Anisotropy of isothermal remanent magnetization indicates inclination flattening of approximately 8°, and correction for the effect reduces the paleolatitude anomaly to 5.3° ± 5.8°. Compaction may explain the inclination flattening in these sedimentary rocks, but the process does not adequately explain lower-than-expected inclinations found in previous studies of Miocene volcanic rocks of the western Transverse Ranges.

Geochemistry, Geophysics, Geosystems↗
USGS2010

Time-averaged paleomagnetic field at the equator: Complete data and results from the Galapagos Islands, Ecuador

We present here the complete paleomagnetic laboratory results from a collection of approximately 1500 oriented cores from all 16 of the Galapagos Islands, Ecuador, collected by Allan Cox in 1964–1965 but nearly all previously unpublished. The islands are located in the eastern Pacific Ocean within 1.4° of latitude from the equator and range in age from historically erupted to 3 Ma, mostly determined by published K-Ar and 3He isotopic dating. The number of sites collected on each island ranges from 1 to 28, for a total of 186. After combining duplicate site mean directions, 149 are used for an overall mean direction and 8 represent excursions and one reversal path. Divided by geomagnetic polarity chron, 110 site means are Brunhes or Jaramillo (normal polarity), 27 are Matuyama (reversed polarity), and 12 are Gauss (both polarities). We have completed the magnetic cleaning that was commenced in the late 1960s. Secondary (mostly viscous) magnetizations were nearly all removed by alternating field demagnetization at 10 mT. We have used the so-called blanket cleaning method, generally at 10 mT. All sites were in basalt flows and gave good paleomagnetic results; none was rejected in toto, and only a few core specimens were magnetically unsatisfactory. Nearly all sites had eight independently oriented cores, and within-site angular standard deviations of directions range from 1° to 8°. We used both Fisher and Bingham statistics to analyze the data and found that many of the direction populations are strongly elongate along the paleomagnetic meridian, while the corresponding virtual pole (VGP) populations are essentially circularly distributed. The paleomagnetic poles, calculated as the means of VGPs, are as follows: Brunhes and Jaramillo, north latitude = 86.9°, east longitude = 245.1°, and 95% confidence radius A 95 = 1.9°; Matuyama, latitude = 87.2°, longitude = 158.2°, and A 95 = 3.8°; Gauss, latitude = 83.0°, longitude = 204.7°, and A 95 = 7.0°. These paleomagnetic poles do not differ significantly from one another, but the Brunhes and Jaramillo combined pole is significantly near-sided with respect to the Galapagos, as is the overall mean pole, which is at latitude = 87.1° and longitude = 227.6°, with A 95 = 1.7°. Omitting the excursion and reversal path data, the overall angular standard deviation of VGPs is 11.7° with lower and upper 95% confidence limits of 10.8° and 12.7°, respectively, in good agreement with previously published values for near-equatorial sampling latitudes.

Galapagos Islands↗
USGS2010

Atmospheric mineral dust in dryland ecosystems: Applications of environmental magnetism

Magnetic properties of shallow (<10‐cm depth), fine‐grained surficial sediments contrast greatly with those of immediately underlying bedrock across much of the dry American Southwest. At 26 study sites in fine‐grained (<63 μ m) surficial sediments isolated from alluvial inputs, isothermal remanent magnetization (IRM; mean of 67 samples = 6.72 × 10 −3 Am 2 kg −1 ) is more than two orders of magnitude greater than that for underlying Paleozoic and Mesozoic sedimentary rocks. This contrast is mainly caused by the presence of silt‐size, titanium‐bearing magnetite particles in the surficial deposits and their absence in bedrock. Because of their size, composition, and isolated location, the magnetite particles represent a component of atmospheric dust likely deposited over the past few centuries. The positive correlation of sediment‐IRM values with amounts of potential plant nutrients reveals the importance of atmospheric dust to soil fertility over much of the American Southwest. Subsequent disturbance of landscapes, by domestic livestock grazing as an example, commonly results in wind erosion, which then depletes exposed surfaces of original aeolian magnetite and associated fine‐grained sediment. Declines in soil fertility and water‐holding capacity in these settings can be estimated in some field settings via decreases in magnetic susceptibility, relative to nearby undisturbed areas. Along gentle hillslope gradients of the Colorado Plateau, field measures for aeolian magnetite demonstrate that the redistribution of deposited atmospheric dust influences landscape‐level patterns in the distribution of invasive exotic plant species. Our results indicate that environmental magnetism has high potential for assessing the development and degradation of dry landscapes elsewhere.

Geochemistry, Geophysics, Geosystems↗
USGS2010

Low‐productivity Hawaiian volcanism between Kaua‘i and O‘ahu

The longest distance between subaerial shield volcanoes in the Hawaiian Islands is between the islands of Kaua‘i and O‘ahu, where a field of submarine volcanic cones formed astride the axis of the Hawaiian chain during a period of low magma productivity. The submarine volcanoes lie ∼25–30 km west of Ka‘ena Ridge that extends ∼80 km from western O‘ahu. These volcanoes were sampled by three Jason2 dives. The cones are flat topped, <400 m high and 0.4–2 km in diameter at water depths between ∼2700 and 4300 m, and consist predominantly of pillowed flows. Ar‐Ar and K‐Ar ages of 11 tholeiitic lavas are between 4.9 and 3.6 Ma. These ages overlap with shield volcanism on Kaua‘i (5.1–4.0 Ma) and Wai‘anae shield basalts (3.9–3.1 Ma) on O‘ahu. Young alkalic lavas (circa 0.37 Ma) sampled southwest of Ka‘ena Ridge are a form of offshore secondary volcanism. Half of the volcanic cones contain high‐SiO 2 basalts (51.0–53.5 wt % SiO 2 ). The trends of isotopic compositions of West Ka‘ena tholeiitic lavas diverge from the main Ko‘olau‐Kea shield binary mixing trend in isotope diagrams and extend to lower 208 Pb/ 204 Pb and 206 Pb/ 204 Pb than any Hawaiian tholeiitic lava. West Ka‘ena tholeiitic lavas have geochemical and isotopic characteristics similar to volcanoes of the Loa trend. Hence, our results show that the Loa‐type volcanism has persisted for at least 4.9 Myr, beginning prior to the development of the dual, subparallel chain of volcanoes. Several West Ka‘ena samples are similar to higher SiO 2 , Loa trend lavas of Ko‘olau Makapu‘u stage, Lāna‘i, and Kaho‘olawe; these lavas may have been derived from a pyroxenite source in the mantle. The high Ni contents of olivines in West Ka‘ena lavas also indicate contribution from pyroxenite‐derived melting. Average compositions of Hawaiian shield volcanoes show a clear relation between 206 Pb/ 204 Pb and SiO 2 within Loa trend volcanoes, which supports a prominent but variable influence of pyroxenite in the Hawaiian plume source. In addition, both Pb isotopes and volcano volume show a steady increase with time starting from a minimum west of Ka‘ena Ridge. The entrained mafic component in the Hawaiian plume is probably not controlling the increasing magma productivity in the Hawaiian Islands.

Hawaii↗
USGS2010

A rapid method for the measurement of sulfur hexafluoride (SF6), trifluoromethyl sulfur pentafluoride (SF5CF3), and Halon 1211 (CF2ClBr) in hydrologic tracer studies

A rapid headspace method for the simultaneous laboratory determination of intentionally introduced hydrologic tracers, sulfur hexafluoride (SF6), trifluoromethyl sulfur pentafluoride (SF5CF3), Halon 1211 (CF2ClBr), and other halocarbons in water and gases is described. The high sensitivity of the procedure allows for introduction of minimal tracer mass (a few grams) into hydrologic systems with a large dynamic range of analytical detection (dilutions to 1:108). Analysis times by gas chromatography with electron capture detector are less than 1 min for SF6; about 2 min for SF6 and SF5CF3; and 4 min for SF6, SF5CF3, and Halon 1211. Many samples can be rapidly collected, preserved in stoppered septum bottles, and analyzed at a later time in the laboratory. Examples are provided showing the effectiveness of the gas tracer test studies in varied hydrogeological settings.

Geochemistry, Geophysics, Geosystems↗
USGS2011

A multitracer approach for characterizing interactions between shallow groundwater and the hydrothermal system in the Norris Geyser Basin area, Yellowstone National Park

Multiple environmental tracers are used to investigate age distribution, evolution, and mixing in local‐ to regional‐scale groundwater circulation around the Norris Geyser Basin area in Yellowstone National Park. Springs ranging in temperature from 3°C to 90°C in the Norris Geyser Basin area were sampled for stable isotopes of hydrogen and oxygen, major and minor element chemistry, dissolved chlorofluorocarbons, and tritium. Groundwater near Norris Geyser Basin is comprised of two distinct systems: a shallow, cool water system and a deep, high‐temperature hydrothermal system. These two end‐member systems mix to create springs with intermediate temperature and composition. Using multiple tracers from a large number of springs, it is possible constrain the distribution of possible flow paths and refine conceptual models of groundwater circulation in and around a large, complex hydrothermal system.

Wyoming↗