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Ground-truthing electrical resistivity methods in support of submarine groundwater discharge studies: Examples from Hawaii, Washington, and California

Submarine groundwater discharge (SGD) is an important conduit that links terrestrial and marine environments. SGD conveys both water and water-borne constituents into coastal waters, where these inflows may impact near-shore ecosystem health and sustainability. Multichannel electrical resistivity techniques have proven to be a powerful tool to examine scales and dynamics of SGD and SGD forcings. However, there are uncertainties both in data aquisition and data processing that must be addressed to maximize the effectiveness of this tool in estuarine or marine environments. These issues most often relate to discerning subtle nuances in the flow of electricity through variably saturated media that can also be highly conductive ( i.e., seawater). Three contrasting field sites were examined for this study to assess the effectiveness of electrical resistivity techniques in varying coastal settings by comparing resistivity data to direct salinity and resistivity observations, quantifying changes in lithology and beach geomorphology, and fine-tuning inversion protocols. The three study sites all have substantial (up to 85 cm day −1 ) submarine groundwater discharge rates, but the hydrologic, oceanographic, and geologic characteristics of the sites are all very different. At a site in Pelekane Bay on the Big Island of Hawaii, seasonal flooding introduces very high concentrations of fine to coarse sediment into the bay. Near-shore circulation is limited in Pelekane Bay, so this newly introduced sediment can become deposited in the bay where it accumulates over time. At a site in Hood Canal, a fjord within Puget Sound, Washington, SGD rates can be high because of the large tidal range, abundant recharge, and steep hydrologic gradients. At Younger Lagoon in northern California, the flow of groundwater towards the coast is much more parsimonious, but here marine processes, including recirculated seawater, are important in controlling the flow of material towards the coast. Rigorous ground-truthing at each field site showed that multi-channel electrcial resistivity techniques can reproduce the scales and dynamics of a seepage field when such data are correctly collected, and when the model inversions are tuned to field site characteristics. Such information can provide a unique perspective on the scales and dynamics of exchange processes within a coastal aquifer—information essential to scientists and resource managers alike.

California, Hawaii, Washington↗

Urban ecosystem services and decision making for a green Philadelphia

Traditional approaches to urban development often do not account for, or recognize, the role of ecosystem services and the benefits these services provide to the health and well-being of city residents. Without such accounting, urban ecosystem services are likely to be degraded over time, with negative consequences for the sustainability of cities and the well-being of their residents (Millennium Ecosystem Assessment, 2005; Hirsch, 2008). On May 23, 2013, the Spatial Integration Laboratory for Urban Systems (SILUS), a collaboration between the U.S. Geological Survey (USGS) Science and Decisions Center and the Wharton GIS Lab, convened a one-day symposium—Urban Ecosystem Services and Decision Making: A Green Philadelphia—at the University of Pennsylvania in Philadelphia, Pennsylvania, to examine the role of green infrastructure in the environmental, economic, and social well-being of cities. Cosponsored by the USGS and the Penn Institute for Urban Research (Penn IUR), the symposium brought together policymakers, practitioners, and researchers from a range of disciplines to advance a research agenda on the use of science in public decision making to inform investment in green infrastructure and ecosystem services in urban areas. The city of Philadelphia has recently implemented a program designed to sustain urban ecosystem services and advance the use of green infrastructure. In 2009, the Philadelphia Mayor’s Office of Sustainability launched its Greenworks plan, establishing a citywide sustainability strategy. Major contributions towards its goals are being implemented in coordination with the Philadelphia Water Department (PWD). The Green City, Clean Waters initiative, the city’s nationally recognized stormwater management plan, was signed into action with the U.S. Environmental Protection Agency (EPA) in April 2012. The plan outlines a 25-year strategy to use green infrastructure to protect and improve the city’s watershed. Widespread support for the plan marks a citywide effort to factor environmental quality concerns into the city’s strategic planning, choosing to replace expensive and aging grey infrastructure, with innovative and resilient green infrastructure. The symposium focused on these city of Philadelphia initiatives and also on two new Federal- local partnership programs: America’s Great Outdoors, initiated to promote conservation and recreation, and the Urban Waters Federal Partnership, a multiagency effort to reconnect urban communities to their waterways. A second goal of the symposium was to advance a research agenda on urban ecosystem services. While there has been considerable work on ecosystem services, the discussion of the benefits provided by urban ecosystems is not as developed. Benefits range from improved water and air quality to quality of life gains, including aesthetic and recreational considerations. There is also need for additional focused research toward furthering the understanding of the multiple indirect benefits provided by urban ecosystem services (Bolund and Hunhammar, 1999). Moreover, there is a need for a greater understanding of how best to inform local decision making in this area, as local decision makers in cities across the country are increasingly recognizing the importance of developing sustainability measures for their immediate and long-term planning (United States Conference of Mayors, 2005). Approaching these local and regional plans from a holistic perspective has become a guiding principle of sustainability and resiliency. Therefore, there is a need to better understand the gains that have been achieved and to advance a research agenda on ecosystem services going forward. The day’s program included presentations on greening initiatives from the Philadelphia’s Mayor’s Office of Sustainability, as well as discussion about using an urban ecosystem services framework to evaluate these initiatives. Panel sessions included discussion of the Green City, Clean Waters initiative; a dialogue about the management of urban trees and green space; and a conversation addressing the needs for future research.

Pennsylvania↗

Review and analysis of available streamflow and water-quality data for Park County, Colorado, 1962-98

Information on streamflow and surface-water and ground-water quality in Park County, Colorado, was compiled from several Federal, State, and local agencies. The data were reviewed and analyzed to provide a perspective of recent (1962-98) water-resource conditions and to help identify current and future water-quantity and water-quality concerns. Streamflow has been monitored at more than 40 sites in the county, and data for some sites date back to the early 1900's. Existing data indicate a need for increased archival of streamflow data for future use and analysis. In 1998, streamflow was continuously monitored at about 30 sites, but data were stored in a data base for only 10 sites. Water-quality data were compiled for 125 surface-water sites, 398 wells, and 30 springs. The amount of data varied considerably among sites; however, the available information provided a general indication of where water-quality constituent concentrations met or exceeded water-quality standards. Park County is primarily drained by streams in the South Platte River Basin and to a lesser extent by streams in the Arkansas River Basin. In the South Platte River Basin in Park County, more than one-half the annual streamflow occurs in May, June, and July in response to snowmelt in the mountainous headwaters. The annual snowpack is comparatively less in the Arkansas River Basin in Park County, and mean monthly streamflow is more consistent throughout the year. In some streams, the timing and magnitude of streamflow have been altered by main-stem reservoirs or by interbasin water transfers. Most values of surface-water temperature, dissolved oxygen, and pH were within recommended limits set by the Colorado Department of Public Health and Environment. Specific conductance (an indirect measure of the dissolved-solids concentration) generally was lowest in streams of the upper South Platte River Basin and higher in the southern one-half of the county in the Arkansas River Basin and in the South Platte River downstream from Antero Reservoir. Historical nitrogen concentrations in surface water were small. Nitrite was not detected, most un-ionized ammonia concentrations were less than 0.02 milligram per liter, and all nitrate concentrations were less than 1.2 milligrams per liter. Nitrate concentrations were higher in urban and built-up areas than in rangeland and forest areas. Most median concentrations of total phosphorus at individual sites were less than 0.05 milligram per liter, and concentrations were not significantly different among urban and built-up, rangeland, and forest areas. An upward trend in total phosphorus concentration was determined for flow from the East Portal of the Harold D. Roberts Tunnel, but the slope of the trend line was small and the concentrations were equal or nearly equal to the detection limit of 0.01 milligram per liter. Using median phosphorus loads for two South Platte River sites, the annual phosphorus load transported out of Park County in the South Platte River was calculated to be about 10,000 pounds. Median iron and manganese concentrations for most areas of Park County were less than in-stream water-quality standards, even though several individual concentrations were one to two orders of magnitude larger than the standards. The largest concentrations of aluminum, cadmium, chromium, copper, iron, manganese, nickel, and zinc were from the upper North Fork South Platte River Basin or the Mosquito Creek Basin. All ground-water concentrations of chloride and most ground-water concentrations of sulfate were less than the U.S. Environmental Protection Agency (USEPA) drinking-water standard of 250 milligrams per liter. Median dissolved-solids concentrations in ground water ranged from 160 milligrams per liter in the crystalline-rock aquifers to 257 milligrams per liter in the sedimentary-rock aquifers. Dissolved-solids concentrations greater than the USEPA drinking-water standard of 500 milligrams per liter were detected in about 10 percent of the wells and in all aquifer types sampled but were most common in samples from the sedimentary-rock aquifers between the towns of Jefferson and Hartsel. Nitrate concentrations in ground water greater than the USEPA drinking-water standard of 10 milligrams per liter were measured primarily in samples collected during the 1990's in wells located in subdivisions northeast of Bailey. Nitrate concentrations in these subdivision wells were significantly larger than concentrations measured in wells in the same area in the 1970's, indicating a possible increase in ground-water contamination. Most trace-element concentrations measured in Park County ground water were less than USEPA drinking-water standards; however, standards for iron, manganese, and zinc were exceeded in a small number of samples. Trace-element concentrations exceeding the standards occurred in each aquifer type, and median concentrations of iron, manganese, and zinc were similar among aquifer types. The physical and chemical characteristics of springwater in Park County varied greatly and were dependent on the type of rock in which the water originated. Specific conductance was lowest in springs originating in the crystalline-rock aquifers of Precambrian age and highest in a spring that may originate in evaporite beds in a sedimentary-rock aquifer that is composed of the Maroon Formation of Paleozoic age.

Colorado↗

The U.S. Geological Survey Ecosystem Science Strategy, 2012-2022 - Advancing discovery and application through collaboration

Ecosystem science is critical to making informed decisions about natural resources that can sustain our Nation’s economic and environmental well-being. Resource managers and policy-makers are faced with countless decisions each year at local, state, tribal, territorial, and national levels on issues as diverse as renewable and non-renewable energy development, agriculture, forestry, water supply, and resource allocations at the urban-rural interface. The urgency for sound decision-making is increasing dramatically as the world is being transformed at an unprecedented pace and in uncertain directions. Environmental changes are associated with natural hazards, greenhouse gas emissions, and increasing demands for water, land, food, energy, mineral, and living resources. At risk is the Nation’s environmental capital, the goods and services provided by resilient ecosystems that are vital to the health and well-being of human societies. Ecosystem science—the study of systems of organisms interacting with their environment and the consequences of natural and human-induced change on these systems—is necessary to inform decision-makers as they develop policies to adapt to these changes. This Ecosystems Science Strategy is built on a framework that includes basic and applied science. It highlights the critical roles that USGS scientists and partners can play in building scientific understanding and providing timely information to decision-makers. The strategy underscores the connection between scientific discoveries and the application of new knowledge. The strategy integrates ecosystem science and decision-making, producing new scientific outcomes to assist resource managers and providing public benefits. The USGS is uniquely positioned to play an important role in ecosystem science. With its wide range of expertise, the agency can bring holistic, cross-scale, interdisciplinary capabilities to the design and conduct of monitoring, research, and modeling and to new technologies for data collection, management, and visualization. Collectively, these capabilities can be used to reveal ecological patterns and processes, explain how and why ecosystems change, and forecast change over different spatial and temporal scales. USGS science can provide managers with options and decision-support tools to use resources sustainably. The USGS has long-standing, collaborative relationships with the DOI and other partners in the natural sciences, in both conducting science and its application. The USGS engages these partners in cooperative investigations that otherwise would lack the necessary support or be too expensive for a single bureau to conduct. The heart of this strategy is a framework and vision for USGS ecosystems science that focuses on five long-term goals, which are seen as interconnected and reinforcing components: • Improve understanding of ecosystem structure, function, and processes. The focus for this goal is an understanding of how ecosystems work, including the dynamics of species, their populations, interactions, and genetics, and how they change across spatial and temporal scales. • Advance understanding of how drivers influence ecosystem change. The challenges here are explaining the drivers of ecosystem change, their spatio-temporal patterns, their uncertainties and interactions, and their influence on ecosystem processes and dynamics. • Improve understanding of the services that ecosystems provide to society. Here the emphasis is on the measurement of environmental capital and ecosystem services, and the identification of sources and patterns of change in space and time. • Develop tools, technologies, and capacities to inform decision-making about ecosystems. This includes developing new technologies and approaches for conducting applications-oriented ecosystem science. A principal challenge will be how to quantify uncertainty and incorporate it in decision analysis. • Apply science to enhance strategies for management, conservation, and restoration of ecosystems. These challenges include development of novel approaches to monitoring, assessment, and restoration of ecosystems; new methods to address species of concern and communities at risk; and innovations in decision analysis and support to address imminent ecosystem changes or those that are underway. Closely integrated with the five goals are four strategic approaches that provide the path forward for the USGS Ecosystems Mission Area. These approaches cross-cut all of the goals and are seen as essential to the implementation of this strategy: • Assess information needs for ecosystem science through enhanced partnerships. Work with the DOI and other agencies and institutions to identify, design, and implement priority decision-driven ecological research. • Promote the use of interdisciplinary ecosystem science. Design and conduct interdisciplinary process-oriented research in ecosystem science. • Enhance modeling and forecasting. Build models to forecast ecosystem change, assess future management scenarios, and reduce uncertainties through an adaptive learning process. • Support decision-making. Use quantitative approaches to assess the vulnerabilities of ecosystems, habitats, and species, and evaluate strategies for adaptation, restoration, and sustainable management. Following the strategic approaches are a set of proposed actions that represent a sampling of specific activities that align with this strategy and that address the Nation’s most pressing environmental needs. The strategy emphasizes coordination of activities across the USGS mission areas pursuant to these goals. Ecosystem science is inherently interdisciplinary and requires a broad perspective that incorporates the biological and physical sciences, climate science, information technology, and scientific capacity in mission areas across the Bureau. With its emphasis on coordination, this strategy can provide a critical underpinning for integrated science efforts with scientists from multiple mission areas of the USGS working together. Of course, the USGS will continue to conduct both discipline-specific and interdisciplinary investigations, and both will continue to be vital parts of the ecosystem science portfolio. Finally, the strategy stresses the importance of coordination with other Federal agencies and organizations in the natural resources community. The USGS collaborates with resource agencies in the DOI and other organizations throughout the world to meet societal needs for species and ecosystem management. Working with these agencies and organizations, the USGS will play a key role over the next decade in advancing the scientific foundation for sustaining the natural resources that diverse, productive, resilient ecosystems provide.

Open-File Report↗

North American osprey populations and contaminants: Historic and contemporary perspectives

Osprey ( Pandion haliaetus ) populations were adversely affected by DDT and perhaps other contaminants in the United States and elsewhere. Reduced productivity, eggshell thinning, and high DDE concentrations in eggs were the signs associated with declining osprey populations in the 1950s, 1960s, and 1970s. The species was one of the first studied on a large scale to bring contaminant issues into focus. Although few quantitative population data were available prior to the 1960s, many osprey populations in North America were studied during the 1960s and 1970s with much learned about basic life history and biology. This article reviews the historical and current effects of contaminants on regional osprey populations. Breeding populations in many regions of North America showed post-DDT-era (1972) population increases of varying magnitudes, with many populations now appearing to stabilize at much higher numbers than initially reported in the 1970s and 1980s. However, the magnitude of regional population increases in the United States between 1981 (first Nationwide Survey, ∼8,000 pairs), when some recovery had already occurred, 1994 (second survey, ∼14,200), and 2001 (third survey, ∼16,000–19,000), or any other years, is likely not a simple response to the release from earlier contaminant effects, but a response to multi-factorial effects. This indirect “contaminant effects” measurement comparing changes (i.e., recovery) in post-DDT-era population numbers over time is probably confounded by changing human attitudes toward birds of prey (shooting, destroying nests, etc.), changing habitats, changing fish populations, and perhaps competition from other species. The species' adaptation to newly created reservoirs and its increasing use of artificial nesting structures (power poles, nesting platforms, cell towers, channel markers, offshore duck blinds, etc.) are two important factors. The timing of the initial use of artificial nesting structures, which replaced declining numbers of suitable trees at many locations, varied regionally (much later in the western United States and Mexico). Because of the increasing use of artificial nesting structures, there may be more ospreys nesting in North America now than ever before. Now, with the impact of most legacy organic contaminants (DDT, other organochlorine [OC] pesticides, polychlorinated biphenyls [PCB], polychlorinated dibenzo- p -dioxins [PCDD], polychlorinated dibenzofurans (PCDF]) greatly reduced or eliminated, and some osprey populations showing evidence of stabilizing, the species was proposed as a Worldwide Sentinel Species for evaluating emerging contaminants. Several emerging contaminants are already being studied, such as polybrominated diphenyl ethers (PBDE) and perfluorinated acids and sulfonate compounds (PFC). The many advantages for continued contaminant investigations using the osprey include a good understanding of its biology and ecology, its known distribution and abundance, and its ability to habituate to humans and their activities, which permits nesting in some of the potentially most contaminated environments. It is a top predator in most ecosystems, and its nests are relatively easy to locate and study with little researcher impact on reproductive success.

Journal of Toxicology and Environmental Health, Pa↗

U.S. Geological Survey ecosystems science strategy—Advancing discovery and application through collaboration

Executive Summary Ecosystem science is critical to making informed decisions about natural resources that can sustain our Nation’s economic and environmental well-being. Resource managers and policymakers are faced with countless decisions each year at local, regional, and national levels on issues as diverse as renewable and nonrenewable energy development, agriculture, forestry, water supply, and resource allocations at the urban-rural interface. The urgency for sound decisionmaking is increasing dramatically as the world is being transformed at an unprecedented pace and in uncertain directions. Environmental changes are associated with natural hazards, greenhouse gas emissions, and increasing demands for water, land, food, energy, mineral, and living resources. At risk is the Nation’s environmental capital, the goods and services provided by resilient ecosystems that are vital to the health and wellbeing of human societies. Ecosystem science—the study of systems of organisms interacting with their environment and the consequences of natural and human-induced change on these systems—is necessary to inform decisionmakers as they develop policies to adapt to these changes. This Ecosystems Science Strategy is built on a framework that includes basic and applied science. It highlights the critical roles that U.S. Geological Survey (USGS) scientists and partners can play in building scientific understanding and providing timely information to decisionmakers. The strategy underscores the connection between scientific discoveries and the application of new knowledge, and it integrates ecosystem science and decisionmaking, producing new scientific outcomes to assist resource managers and providing public benefits. We envision the USGS as a leader in integrating scientific information into decisionmaking processes that affect the Nation’s natural resources and human well-being. The USGS is uniquely positioned to play a pivotal role in ecosystem science. With its wide range of expertise, the Bureau can bring holistic, cross-scale, interdisciplinary capabilities to the design and conduct of monitoring, research, and modeling and to new technologies for data collection, management, and visualization. Collectively, these capabilities can be used to reveal ecological patterns and processes, explain how and why ecosystems change, and forecast change over different spatial and temporal scales. USGS science can provide managers with options and decision-support tools to use resources sustainably. The USGS has long-standing, collaborative relationships with the Department of the Interior (DOI) and other partners in the natural sciences, in both conducting science and applying the results. The USGS engages these partners in cooperative investigations that otherwise would lack the necessary support or be too expensive for a single bureau to conduct. The heart of this strategy is a framework for USGS ecosystems science that focuses on five long-term goals, which are seen as interconnected components that reinforce our vision of the USGS providing science that is at the forefront of decisionmaking: Improve understanding of ecosystem structure, function, and processes. The focus for this goal is an understanding of how ecosystems work, including the dynamics of species, their populations, interactions, and genetics, and how they change across spatial and temporal scales. Advance understanding of how drivers influence ecosystem change. The challenges here are explaining the drivers of ecosystem change, their spatio-temporal patterns, their uncertainties and interactions, and their influence on ecosystem processes and dynamics. Improve understanding of the services that ecosystems provide to society. Here the emphasis is on the measurement of environmental capital and ecosystem services, and the identification of sources and patterns of change in space and time. Develop tools, technologies, and capacities to inform decisionmaking about ecosystems. This includes developing new technologies and approaches for conducting applications-oriented ecosystem science. A principal challenge will be how to quantify uncertainty and incorporate it in decision analysis. Apply science to enhance strategies for management, conservation, and restoration of ecosystems. These challenges include development of novel approaches to monitoring, assessment, and restoration of ecosystems; new methods to address species of concern and communities at risk; and innovations in decision analysis and support to address imminent ecosystem changes or those that are underway. Closely integrated with the five goals are four strategic approaches that provide the path forward for the USGS Ecosystems Mission Area. These approaches cross-cut all of the goals and are seen as essential to the implementation of this strategy: Assess information needs for ecosystem science through enhanced partnerships. Work with the DOI and other agencies and institutions to identify, design, and implement priority decision-driven ecological research. Promote the use of interdisciplinary ecosystem science. Design and conduct interdisciplinary process-oriented research in ecosystem science. Enhance modeling and forecasting. Build models to forecast ecosystem change, assess future management scenarios, and reduce uncertainties through an adaptive learning process. Support decisionmaking. Use quantitative approaches to assess the vulnerabilities of ecosystems, habitats, and species, and evaluate strategies for adaptation, restoration, and sustainable management. Following the four strategic approaches are a set of proposed actions that represent a sampling of specific USGS activities that align with this strategy and that address the Nation’s most pressing environmental needs. The strategy emphasizes coordination of activities across the USGS mission areas pursuant to these goals. Ecosystem science is inherently interdisciplinary and requires a broad perspective that incorporates the biological and physical sciences, climate science, information technology, and scientific capacity in mission areas across the Bureau. With its emphasis on coordination, this strategy can provide a critical underpinning for integrated science efforts with scientists from multiple mission areas of the USGS working together. Of course, the USGS will continue to conduct discipline-specific and interdisciplinary investigations, and both will continue to be vital parts of the ecosystem science portfolio. Finally, the strategy stresses the importance of coordination with other Federal agencies and organizations in the natural resources community. The USGS collaborates with resource agencies in the DOI and other organizations throughout the world to meet societal needs for species and ecosystem management. Working with these agencies and organizations, the USGS will play a key role in guiding sound decisionmaking during the next decade by advancing the scientific foundation for sustaining the natural resources that diverse, productive, resilient ecosystems provide.

Circular↗

1993 Annual Report: San Francisco estuary regional monitoring program for trace substances

This first annual report of the San Francisco Estuary Regional Monitoring Program contains the results of monitoring measurements made in 1993. Measurements of conventional water quality parameters and trace contaminant concentrations were made at 16 stations throughout the Estuary three times during the year: the wet period (March), during declining Delta outflow (May), and during the dry period (September). Water toxicity tests were conducted at 8 of those stations. Measurements of sediment quality and contaminant concentrations were made at the same 16 stations during the wet and dry sampling periods. Sediment toxicity was measured at 8 of those stations. Transplanted, bagged bivalve bioaccumulation and condition was measured at 11 stations during the wet and dry sampling periods. Water Monitoring. Total or near-total (dissolved + particulate, see text) arsenic, cadmium, selenium, and dissolved (0.45 µm filtered) arsenic, cadmium, copper, nickel, silver, and zinc in water were highest in the South Bay. In general, dissolved metals in water were usually lowest in the Central Bay due to ocean influences. Near-total nickel and total mercury in water were highest in the northern estuary (San Pablo and Suisun Bays). Dissolved chromium and lead were highest at the Sacramento and San Joaquin River confluence stations. Six of the ten dissolved trace metals were highest in March during high runoff. Dissolved and total arsenic, selenium, and near-total cadmium were highest in September. Concentrations of trace organic contaminants are reported for the March sampling period. Total PAHs and PCBs were highest in the South Bay, but PCBs were also high in the Napa River. Dissolved PAHs were highest in the Central Bay, and dissolved PCBs were highest in the Napa River. Total and dissolved pesticides were highest in the Sacramento River and in the Extreme South Bay. Concentrations of trace elements in water (except selenium) were usually closely related with other environmental parameters. Total or near-total metals concentrations in water were most often associated with the amount of particulate material (TSS) in the water. Dissolved concentrations were usually associated with salinity or dissolved organic carbon (DOC) content. Dissolved PAHs were well correlated with TSS, but dissolved and total trace organic contaminants were poorly correlated with other water parameters. Based on deviations from conservative mixing of fresh and salt water, three different patterns of possible sources of metals were identified in 1993. For dissolved chromium and lead, rivers and local runoff appeared to be important sources. For dissolved arsenic, cadmium, copper, and nickel year-round inputs from the South Bay appeared to be important sources. Dissolved mercury, selenium, and zinc were associated with local runoff in the South Bay during the wet period. Dissolved silver did not fit any of these patterns. Although most contaminant concentrations were below water quality objectives, several trace contaminants were above the objectives at some stations. Comparisons to water quality objectives are used as a guide for evaluation of contaminant concentrations, but there are some differences in the way the RMP data are measured and that prescribed for regulatory purposes (see text). Concentrations of 5 metals in water were above EPA or Regional Basin Plan water quality objectives at six stations (see Table 30). Most of these elevated levels occurred at the northern estuary stations. Total PCB concentrations were above EPA human health objectives at all RMP stations. The pesticides chlordane, dieldrin, and DDTs were above the EPA objectives at several RMP stations, particularly at the northern-most, and river confluence stations. Although some of the contaminant concentrations were above water quality objectives, water toxicity tests (96 hour algal growth and 48 hour bivalve larval development tests) did not indicate toxicity (sometimes inconclusive) associated with the water samples collected at any of the RMP stations in 1993. Exposure to Bay San Francisco Estuary Regional Monitoring Program Regional Monitoring Program 1993 Report ii water actually enhanced algal growth at most stations. In addition to the Estuary-wide sampling, the Sacramento and San Joaquin Rivers were sampled upstream from their confluence. Stations in each river were sampled six times over a 6 week period of high flows. In the Sacramento River, seven of the ten dissolved metals measured had concentrations lower than those measured at the river confluence stations. Some metals concentrations in the San Joaquin River were higher, and some were lower than concentrations from the river confluence station. Metals concentrations in the Sacramento River were poorly related to river flow because the station at Rio Vista is under considerable tidal influence. In the San Joaquin River, flows were inversely related to 7 of 10 total metals concentrations. Sediment Monitoring. Concentrations of silver, mercury, and lead in sediment were highest in the South Bay. However, concentrations of most trace metals in sediments were highest in the northern estuary at stations with the finest (silt, clay) sediments. The northern estuary stations with the coarsest (sand, shell) sediments generally had the lowest metals concentrations. There were differences in concentrations of cadmium, lead, and selenium in sediments between the sampling periods, but no consistent trend as to which sampling period had higher values. In September, PAHs and PCBs in sediments were highest in the Central Bay, but pesticides in sediments were highest in the northern estuary and Extreme South Bay. NOAA’s Median Effects Ranges (ERM) for sediments were used as a guide for evaluation of sediment contaminant concentrations. Nickel was the only trace contaminant in sediment above the ERM guidelines, and it was high at all RMP stations. These high levels are probably due to natural, geologic sources. Although sediment contaminant concentrations were below ERMs, sediment toxicity tests (10 day amphipod mortality, and 48 hour bivalve larval development in elutriates) indicated toxicity at all stations tested. Sediment factors that could have caused the toxicity were not investigated. Bivalve Bioaccumulation. Mussels, oysters, and freshwater clams were transplanted to the RMP stations to evaluate bioaccumulation of trace substances. Trace metals were bioaccumulated at nearly all RMP stations. However, arsenic, lead, and mercury did not appear to bioaccumulate. There was generally more bioaccumulation during the dry season than during the wet season. In September, PAHs, PCBs, and pesticides accumulated in all samples. Bioaccumulation of PAHs and pesticides was generally highest at the river confluence stations, and the Napa River. PCBs accumulated most at Redwood Creek. There were substantial differences in the degree of bioaccumulation among the species. Oysters appeared to accumulate higher concentrations of trace metals than the other species, especially copper, which may be a natural phenomenon. There are no established tissue contaminant standards for trace metal and organic contaminants. Therefore, comparisons to Median International Standards (MIS) for human consumption, or U.S. Food and Drug Administration (USFDA) action levels for trace organics are used to evaluate the bioaccumulation results. Concentrations of selenium were higher than MIS guidelines at all stations during the wet season. Other trace metal concentrations were higher than MIS guidelines at various stations during one or the other sampling period. However, none of the bivalves contained concentrations above the USFDA or National Academy of Sciences (NAS) guidelines for trace organic contaminants. The transplanted bivalves survived well at all stations except in the Napa River where less than 35% survived during both sampling seasons. Measures of bivalve condition (dry weight, shell volume) indicated that bivalves deployed in the Central Bay grew significantly, but those at most other stations actually lost weight. Whether these differences were due to natural causes such as salinity or food supply, or to contamination, was not determined. Pilot Studies. Two pilot monitoring studies were conducted in 1993. A pilot study of Estuary hydrography and phytoplankton was conducted by scientists from the U.S. Summary Geological Survey in Menlo Park and U.C. Davis. Water column profiles at up to 37 stations were monitored along a transect of the Estuary run monthly between the South Bay and the Delta. The primary objective of this study was to define physical (salinity, temperature, suspended particulate matter, and light penetration), chemical (dissolved oxygen) and biological (chlorophyll a) characteristics of Estuary water that may influence other chemical and biological reactions. A second objective was to investigate planktonic indicators of ecosystem structure and function. The data collected in 1993 showed the extent and duration of the spring phytoplankton bloom in the South Bay, other localized blooms in the northern estuary, the stratification and mixing associated with the entrapment zone in the northern estuary, and mixing in the Estuary resulting from the high rainfall in 1993. Knowledge of the duration and extent of these natural features of the Estuary provide context for interpretation of the RMP contaminant data collected only 3 times per year. Another pilot study of suspended sediment transport processes was conducted by the USGS in Sacramento. This study used continuous recording sensors at Point San Pablo and the Bay Bridge to measure the amount of suspended sediment in the water at mid-depth and near the bottom, as well as tide height. The objectives of this study were to estimate which factors determine suspended solids concentrations in the Central Bay and to collect time series of suspended solids that are appropriate for continuous monitoring of suspended solids and for calibration and validation of numerical models. The investigators determined that spring tides accounted for most of the variation in suspended solids concentrations at the stations monitored, not runoff from the Sacramento or San Joaquin Rivers, or semidiurnal and diurnal tides. Comparisons were also made between measurements made by the continuous recordings and the RMP samples collected during the regular monitoring cruises. The different ways of measuring TSS were generally comparable, however only 3 measurements per year as made by the RMP could not provide the information of TSS variation actually occurring in the Estuary. This information is important because as shown by the RMP data, total contaminant concentrations in Estuary water is largely dependent on the TSS in the water. This implies that the RMP measurements alone cannot determine accurately the range of contaminant concentrations without better characterizing the dynamics of TSS. The RMP Pilot Studies are important to the developing RMP because they will help put RMP measurements into the perspective of Estuary processes and mechanisms at other time scales. The studies can relate those processes to the RMP measurements and will facilitate revision of sampling design and interpretation. Summaries of other monitoring activities pertinent to regional monitoring are also included in the Report: a description of the Regional Board’s Bay Protection Studies, the Sacramento Coordinated Monitoring Program, and a wetlands monitoring plan are included.

California↗