Geology ReportsSearch

SEARCH · Geology Reports

Results for “Environmental Health Perspectives”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

289 records · Page 5Linked to original sources

Near-surface geophysics: Environmental applications

The field of geophysics encompasses a broad and diverse compilation of methodologies that employs principles of physics to characterize properties of earth materials within the subsurface. While geophysical methods have a long history in resource exploration and studies of Earth’s interior, the subdiscipline of “near-surface geophysics” has evolved in recent decades for examination of the shallow, near-surface environment for a range of purposes ranging from archaeological or forensic investigations to assessment of geologic, hydrologic, biologic, and geochemical properties and processes. “Environmental geophysics” are near-surface geophysical studies and methods that focus on understanding natural systems (e.g., watershed hydrology, groundwater–surface water connections, biophysical processes) as well as research pertaining to anthropogenic impacts and land management, (e.g., contamination and remediation, saltwater intrusion, agricultural practices). This field can be further subdivided into subdisciplines focused on specific topics and applications, such as water resources and hydrology (hydrogeophysics) or biologic and microbial processes (biogeophysics). Studies in environmental geophysics span a range of scales, from pore-scale laboratory tests to watershed-scale or regional field experiments. Methods vary by the nature of physics employed, the specific measurement acquired, and how that data is ultimately processed and analyzed to produce interpretable results. There exists further diversity in the acquisition logistics, geometry, and timing of data collection. Geophysical data can be collected in boreholes (one-dimensional, 1-D, vertical profiles), along survey lines (two-dimensional, 2-D, cross-sections), or in dense sensor arrays or gridded profiles (three-dimensional, 3-D, models). Regarding the temporal aspect, studies can conduct one-time geophysical surveys to obtain detailed imaging of subsurface structure or use timelapse and continuous monitoring to investigate variations in subsurface properties over time. The cumulation of all possible permutations of these factors (method, acquisition geometry, survey design, and target application) results in an immense diversity among environmental geophysical studies. Nevertheless, this field remains unified in the pursuit of understanding natural and human-impacted near-surface environments through geophysical investigations. Here we highlight some key references within environmental geophysics. Resources on geophysical theory, acquisition logistics, processing and inversion workflows, and example case studies are categorized into the most common geophysical classes within Geophysical Methods. Lastly, example references for the dominant types of applications in environmental geophysical studies are catalogued in Environmental Applications.

Book chapter

Hydrologic variability drives environmental and geospatial relationships in Smallmouth Bass (Micropterus dolomieu) distribution

Hydrologic variation is a primary driver of stream ecosystems. Changing hydrology can lead to assemblage shifts and alterations in suitable habitat for freshwater species. As climate change is predicted to alter flow patterns in addition to increasing water temperatures, insight into relationships between species occupancy, hydrology, and temperature is critical for understanding current and future distributions. We examined how hydrologic variability, temperature, and other environmental variables interact to influence Micropterus dolomieu (Smallmouth Bass) occurrence. We used Spatial Stream Network models, allowing for the incorporation of spatial autocorrelation along streams' unique dendritic network, to examine Smallmouth Bass occupancy across a range of hydrologic variation in the Ozark-Ouachita Interior Highlands, USA. Hydrologic variation was the main driver of Smallmouth Bass occurrence, with occurrence more likely in groundwater streams with low hydrologic variation and high flow permanence. For groundwater streams, occurrence was positively associated with summer stream temperature and negatively associated with annual stream temperature. As variation increased, more variables showed significant relationships with occurrence. Distance metrics were important for all models, however as hydrologic disturbance increased, flow connected distance played a lesser role and stream distance played a greater role. Hydrologic variability was the overarching determinant of Smallmouth Bass occurrence and strongly influenced the predictive importance of environmental variables and geospatial relationships. Greater hydrologic variability resulted in stronger statistical relationships between occurrence and environmental variables and an increased importance of system connectivity. As climate change alters hydrologic processes and streams become more variable, understanding and accounting for these shifting relationships is essential.

Arkansas, Kansas, Missouri, Oklahoma

An environmental assessment of impacts of coal development on the water resources of the Yampa River basin, Colorado and Wyoming; Phase I work plan

Coal resources of the western United States are being developed at ever-increasing rates, causing concerns of the effects of mining and associated activities on the environment. The Yampa River basin in northwestern Colorado and south-central Wyoming is undergoing economic development of its coal, oil and gas, and uranium resources. The Yampa River basin assessment is a 21-year program of the U.S. Geological Survey. It is designed primarily to assess the availability and quality of the basin's water resources. The basin assessment also will evaluate potential environmental and selected socioeconomic impacts of energy-resource development plans proposed by mining and power companies. This report serves as a project work plan for the basin assessment's first-phase work activities. Economic development in the Yampa River basin will result in higher levels of residuals (noneconomic byproducts) being discharged into the environment. Residuals-management encompasses the technological and economic interrelationships that should be considered in order to comply with Federal and State environmental-control regulations regarding air quality, water quality, and disposal of solid wastes. The basin assessment, the first phase that is described by this report, is designed to provide Federal, State, and local decision-makers with the basic environmental information needed to formulate and to evaluate policies for the development of energy resources. The techniques applied and conclusions reached in the Yampa River basin assessment should aid similar studies of other energy-rich basins in the western United States.

Colorado, Wyoming

VIPER site analysis

We needed to evaluate available orbital data of NASA’s Volatiles Investigating Polar Exploration Rover (VIPER) mission area in order to derive a variety of maps to help the science team identify scientifically interesting places for the rover to visit and to provide scientific context for our mission. Some of these maps also fulfilled engineering and mission design needs to enable safe and efficient landing and roving. We incorporated data from the Lunar Reconnaissance Orbiter Camera, the Lunar Orbital Laser Altimeter, the Mini-RF instrument, the Chandrayaan-2 Orbital High Resolution Camera, the Korean Pathfinder Lunar Orbiter’s Shadowcam, the Kaguya Spectral Profiler and Multiband Imager, and the Chandrayaan-1 Moon Mineralogy Mapper. We used a variety of techniques to build these maps, including stereogrammetry, shape-from-shading, ice stability depth and surface temperature calculations, and the horizon method for solar illumination and direct-to-Earth communications maps. Altogether, these maps allowed us to survey for boulders, evaluate features in permanently shadowed regions that VIPER might explore, provide mineralogic context for what VIPER’s instruments may learn, estimate the ages and radar properties of craters in the VIPER mission area, and evaluate the potential for gravity traverses with the rover. These data and techniques provided a rich set of information from which both the VIPER science team and engineering teams were able to draw in order to plan a safe landing and to plan a VIPER surface mission that will be both scientifically valuable and robust from an operational perspective.

The Planetary Science Journal

Groundwater hydrology, groundwater and surface-water interactions, water quality, and groundwater-flow simulations for the Wet Mountain Valley alluvial aquifer, Custer and Fremont Counties, Colorado, 2017–19

In 2017, the U.S. Geological Survey, in cooperation with the Upper Arkansas Water Conservancy District, began a study to provide a comprehensive analysis of the Wet Mountain Valley alluvial aquifer, Custer and Fremont Counties, Colorado. The study included collection of data pertaining to groundwater hydrology, groundwater and surface-water interactions, and water quality in the alluvial aquifer. In addition to providing foundational information on the hydrology of the alluvial aquifer, a numerical groundwater-flow model was developed to estimate the potential effects of additional storage of groundwater in the alluvial aquifer. Groundwater-level elevation data from 30 wells were used to estimate groundwater-flow directions in the alluvial aquifer, which were generally from the southwest to northeast, away from the Sangre de Cristo Mountains and towards perennial streams in the center of the valley. Although some seasonal variation was apparent in groundwater-level elevation records, no statistically significant seasonal trends were indicated. Statistically significant long-term trends were indicated in groundwater-level elevation records for 8 of the 30 wells, and of these wells with statistically significant trends, all but 1 indicated a negative trend of groundwater-level elevations. Spatial evaluation of wells with statistically significant negative groundwater-level elevation trends showed many are in areas of denser well drilling for domestic or other uses, indicating increasing groundwater use could potentially be causing groundwater-level elevation declines. There were instances of wells with no statistically significant groundwater-level elevation trends also located in areas of greater density of well completions. Additional investigations may be necessary to more fully characterize the processes responsible for negative groundwater-level elevation trends. Streamflow gain or loss calculations were completed for low flow in 2017–19 and for high flow in 2018 in nine reaches of streams within the study area. Stream reaches of the upper Texas Creek, upper Grape Creek, upper-middle Grape Creek, and Taylor Creek displayed consistent streamflow loss in each period from 2017 to 2019. These stream reaches represent long-term sources of recharge to the alluvial aquifer. Streamflow gain or loss varies through time in other stream reaches (lower Texas Creek, lower-middle Grape Creek, lower Grape Creek below Westcliffe, and lower Grape Creek above DeWeese Reservoir). The temporally variable behavior indicates these stream reaches may be sources of groundwater recharge or areas of groundwater discharge, likely depending on temporal dynamics between the elevation of the water table and the stream. Water-quality samples were collected from 10 groundwater wells and 10 stream sites during September through November 2019. All groundwater and stream samples were analyzed for major and trace elements and stable isotopes of water. A subset of groundwater samples was also analyzed for the environmental tracers sulfur hexafluoride, tritium, and noble gases. Comparison of water-quality results to U.S. Environmental Protection Agency drinking water-quality standards indicated no constituents exceeded primary standards for human health. Spatial evaluation of water quality indicated the concentrations of various constituents are likely controlled by groundwater and surface-water interactions and by spatial variability in bedrock geology underlying the alluvial aquifer. Specifically, streams shown to gain from groundwater had water chemistry constituent compositions similar to groundwater, whereas streams exiting the Sangre de Cristo Mountains tended to have compositions consistent with snowmelt. Groundwater geochemistry appeared to be partially controlled by oxidation-reduction processes and by proximity to igneous rocks in the Wet Mountains. Environmental tracers used to estimate groundwater age indicated all sampled groundwater contained tracers representing modern recharge (approximately less than 65 years old) but mixing of premodern recharge (approximately more than 65 years old) also occurs. Spatial evaluation of environmental tracers indicated large faults may be conduits for upwelling of older groundwater. No trends were observed in groundwater age with well depth, indicating all sampled wells are located within the zone of active groundwater flow. The presence of modern groundwater in wells with statistically significant negative groundwater-level elevation trends indicates groundwater storage depletions may be partially offset by capture of modern recharge. Repeated sampling of groundwater age would be necessary, however, to determine if any trends in groundwater age exist, which may indicate changing groundwater recharge, storage, or discharge. Additional investigations could also consider quantifying groundwater age in deeper wells to more fully define the depth of active groundwater flow. A numerical groundwater-flow model was developed to estimate components of the water budget, simulate groundwater and surface-water interactions, and evaluate the potential effects of aquifer storage and recovery. Simulated groundwater-level elevations from the calibrated groundwater-flow model are similar to the observed pattern of groundwater-level elevations with higher elevations in the western part of the study area along the Sangre de Cristo Mountains. Simulated water-budget components indicate most of the recharge to the alluvial aquifer is derived from streamflow losses, which is consistent with observations of losing streams along the mountain front. The largest groundwater discharge component of the alluvial aquifer was to streams in the center of the valley, where observations of stream gain or loss indicated the predominance of gaining conditions. Comparison of groundwater and surface-water interactions between the calibrated groundwater-flow model for 2000-19 (the base-case model) and a simulation including additional recharge, representing potential aquifer storage and recovery operations, indicated the additional recharge distributed throughout the area had minimal effects on streamflow in the nearby Grape Creek. An analysis of subregional groundwater budgets showed approximately 54 percent of the additional recharge flowed back to nearby Grape Creek, and the other 46 percent was distributed laterally into adjacent cells in the alluvial aquifer. The comparison of simulations and subregional water budget show the additional recharge did not substantially alter groundwater-level elevations or basin wide groundwater storage. Although the analysis of additional recharge provided in the numerical groundwater-flow model considers only one of many possible recharge scenarios, the model provides a useful tool that could be modified for various scenarios to understand potential effects of managed aquifer recharge.

Colorado

Trends and environmental impacts of virtual water trade

Virtual water describes water embedded in the production of goods and offers meaningful insights about the complex interplay between water, trade and sustainability. In this Review, we examine the trends, major players, traded products and key drivers of virtual water trade (VWT). Roughly 20% of water used in global food production is traded virtually rather than domestically consumed. As such, agriculture dominates VWT, with livestock products, wheat, maize, soybean, oil palm, coffee and cocoa contributing over 70% of total VWT. These products are also driving VWT growth, the volume of which has increased 2.9 times from 1986 to 2022. However, the countries leading VWT contributions (with China, the United States, the Netherlands, Germany and India accounting for 34% of the global VWT in 2022) have remained relatively stable over time, albeit with China becoming an increasingly important importer. VWT can mitigate the effects of water scarcity and food insecurity, although there are concerns about the disconnect between consumers and the environmental impacts of their choices, and unsustainable resource exploitation. Indeed, approximately 16% of unsustainable water use and 11% of global groundwater depletion are virtually traded. Future VWT analyses must consider factors such as water renewability, water quality, climate change impacts and socioeconomic implications.

Nature Reviews Earth & Environment

Groundwater surveillance of swine pathogens from private wells supplying swine farms in Iowa

Biosecurity practices are essential for maintaining pig health and productivity. Despite these measures, pathogen spread still occurs. Water is one of the largest daily inputs on swine farms by volume and is not routinely tested or disinfected before it is consumed by the animals [1-3], making it a poorly understood biosecurity risk. Groundwater from privately-owned wells is a common water source for swine farms. Pathogens in the landscape, such as bacteria, viruses, and protozoa, can reach groundwater more rapidly through soil macropores, maintaining viability and facilitating transmission of pathogens into aquifers [3-13].

Iowa

High-resolution magnetic survey using an unoccupied aerial vehicle to constrain buried lava flow geometry, volume, and eruptive history of Little Cones, Crater Flat, Nevada

Magnetic surveys are an important tool used to augment geologic mapping in distributed volcanic fields. Using magnetic anomalies, it is possible to model the geometry of shallowly buried volcanic features, such as conduits, sills, and lava flows. This subsurface mapping is important for understanding eruption dynamics and emplacement of lava flows, and it sometimes reveals buried volcanoes no longer visible at the surface. These data are critical to better interpret the numbers, styles, and magnitudes of eruptions in distributed volcanic fields and their associated volcanic hazards. New advances in unoccupied aerial vehicles (UAVs) offer an attractive middle range of resolution and aerial coverage between ground-based magnetic surveys and aeromagnetic surveys. Here, we present the results of a UAV fluxgate magnetic survey of the Little Cones, Nevada, scoria cones, which have been the target of previous ground and aeromagnetic surveys. The magnetic anomalies at Little Cones are of interest because the surrounding alluvium conceals lava flows that erupted from Little Cones, making it very difficult to understand the volume and morphology of lava flows from geologic mapping alone. Nonlinear inversion of UAV-collected magnetic data were used to model the thickness and morphology of buried Little Cones’ lava flows with higher precision than achieved previously. The sequence of events and calculated flow characteristics are then interpreted. The total volume of Little Cones, including concealed lava flows, is approximately 0.016 cubic kilometer, and the initial sheet flow erupted in less than 24 hours. The findings presented herein demonstrate that UAV-based magnetic surveys are a reliable method of data collection and an efficient alternative to other survey methods, facilitating development of a three-dimensional perspective of distributed volcanic fields.

Nevada

Environmental monitoring of groundwater, surface water, and soil at the Ammonium Perchlorate Rocket Motor Destruction Facility at the Letterkenny Army Depot, Chambersburg, Pennsylvania, 2021

Letterkenny Army Depot in Chambersburg, Pennsylvania, built an Ammonium Perchlorate Rocket Motor Destruction (ARMD) Facility in 2016 to centralize rocket motor destruction and contain all waste during the destruction process. The U.S. Geological Survey has collected environmental samples from groundwater, surface water, and soils at ARMD since 2016. During 2021, samples were collected from four groundwater wells in September, one surface-water site in October, and five soil sites in November near the facility. Samples were analyzed for nutrients, trace metals, major ions, total volatile organic compounds, and perchlorate. Perchlorate was not detected in any 2021 samples. Groundwater results showed no constituents exceeded any U.S. Environmental Protection Agency (EPA) maximum contaminant level (MCL). Dissolved arsenic (As) was detected in one well above the reporting detection level (RDL) of 3 micrograms per liter (μg/L) at 5.4 μg/L but below its MCL of 10 μg/L. Dissolved iron (Fe) was the only inorganic constituent measured above an EPA secondary maximum contaminant level (SMCL). All groundwater samples collected in 2021 exceeded the Fe SMCL of 300 μg/L, with concentrations ranging from 390 μg/L to 3,500 μg/L. Surface-water data collected during 2021 showed no measured constituents in the surface-water sample that exceeded any EPA MCL or SMCL. Soil samples collected from 2016 through 2021 showed all concentrations of As exceeded the EPA soil screening levels of 3 milligrams per kilogram (mg/kg) but did not exceed the Pennsylvania medium-specific concentrations for As of 61 mg/kg. Arsenic concentrations in 2021 ranged from 9.1 mg/kg to 12.9 mg/kg. The 2021 results for the ARMD Facility indicate no increases in concentrations of reported compounds compared to data from 2016 to 2020. The contained burn treatment facility for demilitarization of rocket motors during 2021 appears to have operated without elevating concentrations of target compounds compared to previous years.

Pennsylvania

Water-quality assessment of the New England coastal basins in Maine, Massachusetts, New Hampshire, and Rhode Island: Environmental settings and implications for water quality and aquatic biota

The New England Coastal Basins in Maine, Massachusetts, New Hampshire, and Rhode Island constitute one of 59 study units selected for water-quality assessment as part of the U.S. Geological Survey's National Water-Quality Assessment (NAWQA) program. England Coastal Basins study unit encompasses the fresh surface waters and ground waters in a 23,000 square-mile area that drains to the Atlantic Ocean. Major basins include those of the Kennebec, Androscoggin, Saco, Merrimack, Charles, Blackstone, Taunton, and Pawcatuck Rivers. Defining the environmental setting of the study unit is the first step in designing and conducting a multi-disciplinary regional water-quality assessment. The report describes the natural and human factors that affect water quality in the basins and includes descriptions of the physiography, climate, geology, soils, surface- and ground-water hydrology, land use, and the aquatic ecosystem. Although surface-water quality has greatly improved over the past 30 years as a result of improved wastewater treatment at municipal and industrial wastewater facilities, a number of water-quality problems remain. Industrial and municipal wastewater discharges, combined sewer overflows, hydrologic modifications from dams and water diversions, and runoff from urban land use are the major causes of water-quality degradation in 1998. The most frequently detected contaminants in ground water in the study area are volatile organic compounds, petroleum-related products, nitrates, and chloride and sodium. Sources of these contaminants include leaking storage tanks, accidental spills, landfills, road salting, and septic systems and lagoons. Elevated concentrations of mercury are found in fish tissue from streams and lakes throughout the study area.

Maine, Massachusetts, New Hampshire, Rhode Island

Site response models based on geometric parameters for southern California sedimentary basins

Site response in sedimentary basins is influenced by complex three-dimensional (3D) features, including trapping of seismic waves, focusing of seismic energy and basin resonance. Current ground motion models (GMMs) incorporate basin effects using one-dimensional parameters like V S30 and shear wave velocity isosurface depths, which are limited in capturing lateral and 3D effects. To address these limitations, we develop seismic site response models based on novel parameters that represent multi-dimensional properties of the Los Angeles Basin (LAB) geometry and shear wave velocity. We define a basin shape for the LAB using depth to subsurface geologic interfaces associated with the oldest sedimentary deposits (depth to a particular shear wave velocity horizon, i.e., 1.5 km/s - z 1.5 ) and the depth to the crystalline basement ( z cb ) which are determined using geologic cross sections and community seismic velocity model profiles. We explore a suite of geometric descriptors computed for the LAB and southern California, from which three parameters with the greatest predictive potential are selected and evaluated using empirical ground motion residual analyses in combination with the Boore et al. GMM. The results demonstrate that the zonal heterogeneity index ( ), standard deviation of the absolute difference between z 1.5 and z cb ( ) and standard deviation of z cb ( ) each provide a reduction in site-to-site variability ( ϕ S2S ) of empirical GMMs. The reduction in ϕ S2S is period-dependent, with average decreases of 3%, 26% and 6% for , , and , respectively. Although these reductions are modest from an engineering application perspective, they are statistically significant, underscoring the inherent difficulty in fully characterising complex basin effects. Collectively, these findings indicate that the inclusion of basin-specific geometric parameters yields measurable, albeit incremental, improvements in site response prediction and establishes a framework for the progressive refinement of seismic hazard characterisation within sedimentary basins.

California

Polystyrene microplastics alter the accumulation and elimination dynamics of silver nanoparticles in Daphnia magna

Rationale Microplastics (MPs) can interact with engineered nanomaterials and alter their environmental fate and bioavailability. However, their influence on the bioaccumulation dynamics of silver nanoparticles (AgNPs) in aquatic filter feeders under environmentally relevant conditions remains poorly understood. We hypothesized that polystyrene microplastics (PS-MPs) alter the uptake, elimination and overall bioaccumulation dynamics of AgNPs in Daphnia magna . Methodology Adult D. magna were exposed to isotopically labeled citrate-coated 109 AgNPs in the presence and absence of PS-MPs. Waterborne uptake, dietary uptake, assimilation efficiency, food ingestion and elimination were quantified experimentally and incorporated into a biodynamic model to predict steady-state silver (Ag) concentrations under environmentally relevant exposure scenarios. Results PS-MPs increased waterborne Ag accumulation by approximately eightfold compared with AgNPs exposure alone. However, Ag elimination was substantially faster, with 98% of accumulated Ag eliminated after five days of depuration compared with 66% without PS-MPs. PS-MPs also reduced food ingestion rates (IRs), while assimilation efficiency remained largely unchanged. Biodynamic modeling predicted that steady-state Ag accumulation was approximately fivefold greater in the presence of PS-MPs, with waterborne exposure becoming the dominant accumulation pathway. Discussion These findings suggest that PS-MPs alter bioaccumulation dynamics of AgNPs in filter-feeding organisms by enhancing organism-associated Ag during waterborne exposure while accelerating Ag elimination, likely through particle-associated transport and gut egestion. Collectively, these results underscore the complexity of Ag bioaccumulation processes when MPs and AgNPs interact and highlight the importance of studies conducted under environmentally relevant conditions.

Environmental Chemistry

Dissolved arsenic concentrations in surface waters within the upper portions of the Klamath River Basin, Oregon and California

Arsenic toxicity is an environmental health problem. Levels of arsenic in surface waters at some locations in the Klamath River Basin in southern Oregon and northern California can exceed the U.S. Environmental Protection Agency (EPA) standard for drinking water. There are both anthropogenic and natural sources of arsenic. The Klamath River Basin consists primarily of volcanic deposits and contains an underground geothermal system with hot springs and warm water wells, all known natural sources of arsenic. Anthropogenic sources of arsenic are related to the agricultural use of herbicides, fungicides, and insecticides. Surface water arsenic levels can also be affected by fertilizer amendments, evaporative concentration, oxygen-level depletion, and various geochemical transformations that can increase arsenic mobilization. In this study by the U.S. Geological Survey and the Bureau of Reclamation, dissolved concentrations of arsenic, copper, and lead were measured in surface waters at 39 unique sites within the upper portions of the Klamath River Basin between 2018 and 2022. In every year, except 2022, sites were sampled four times between April and November. Surface-water arsenic concentrations varied up to four-orders of magnitude among sites. Median arsenic concentration was lowest at Cherry Creek (0.03 micrograms per liter [μg/L]) and highest at Wood Kimball Spring (36.7 μg/L), two sites located north of Upper Klamath Lake. The highest arsenic concentrations (17.4±4.9 μg/L, n =3) were found in drain sites (defined here as a waterbody returning used irrigation water) while the lowest arsenic concentrations were found in an artesian well (0.8 μg/L, n =1). The elevated arsenic concentrations of the drain sites suggest that arsenic might be concentrated or mobilized by agricultural activities, water re-use practices, and (or) by geochemical processes occurring around water stored in drains (that is, in the water column and across sediment water boundaries). A source of arsenic in drain water in the Klamath Strait Drain area includes water used for irrigation originating from Ady Canal. Other potential sources include groundwater, geothermal water, and local soils and sediments. Seasonal differences in surface-water arsenic concentrations were detected at 13 sites, 10 of which had higher arsenic concentrations in summer than in either spring or fall. The sites sampled around Upper Klamath Lake, the impounded rivers, one of the two canal sites, and 5 of the 14 river sites had higher surface-water arsenic concentrations in the summer than in either spring or fall. Surface-water arsenic concentrations from groundwater sources (that is, springs and in the artesian well) did not vary significantly among seasons (p-values greater than 0.1). Median surface-water concentrations of copper and lead ranged from 0.03 to 3.7 μg/L, and from 0.013 to 0.175 μg/L ( n =2–18), respectively. Dissolved concentrations of both metals were below acute toxicity endpoints reported by the EPA for freshwater animals. Surface-water arsenic concentrations varied independently from corresponding changes in surface-water lead or copper concentrations. However, arsenic concentrations measured in bed-sediment samples collected from a subset of sites located north of Upper Klamath Lake correlated strongly and significantly with the corresponding sedimentary lead concentrations ( p =0.015). Aqueous arsenic speciation measured in a subset of sites in 2019 and 2022 showed that all the arsenic existed as arsenic (V), the most oxidized arsenic species, and presumably, the least toxic. The highest proportions of arsenite (As(III)), the presumably most toxic arsenic species, relative to total arsenic concentrations were found at drain sites. Our assessment of dissolved arsenic concentrations in various surface-water bodies in the Upper Klamath River Basin reveals geographical areas of consistently low (below 2.1 μg/L), moderate (below 10 μg/L) and high (above 10 μg/L) surface-water arsenic concentrations. South of Upper Klamath Lake, surface-water arsenic concentrations were consistently higher than 20 μg/L at two drain sites located in an area of predominant agricultural land use with extensive water re-use practices. North of Upper Klamath Lake, surface-water arsenic concentrations greater than 20 μg/L were consistently measured at sites with limited nearby agricultural activities, suggesting a geogenic source. The consistently high arsenic levels from the Wood River at Jackson F. Kimball State Park, Fort Creek, and Crooked Creek, which are sites located at or near headwater spring sources, suggest a natural background source of arsenic. Water flowing downstream from this area could be a potential source of arsenic to Upper Klamath Lake and the Upper Klamath River.

California, Oregon

Integration of rupture directivity models for the US National Seismic Hazard Model

Several rupture directivity models (DMs) have been developed in recent years to describe the near-source spatial variations in ground motion amplitudes related to propagation of rupture along the fault. We recently organized an effort towards incorporating these directivity effects into the USGS National Seismic Hazard Model (NSHM), by first evaluating the community's work and potential methods to implement directivity adjustments into probabilistic seismic hazard analysis (PSHA). Guided by this evaluation and comparison among the considered DMs, we selected an approach that can be readily implemented into the USGS hazard software, that provides an azimuthally varying adjustment to the median ground motion and its aleatory variability. This method allows assessment of the impact on hazard levels and provides a platform to test the DM amplification predictions using a generalized coordinate system, necessary for consistent calculation of source-to-site distance terms for complex ruptures. We give examples of the directivity-related impact on hazard, progressing from a simple, hypothetical rupture, to more complex fault systems, composed of multiple rupture segments and sources. The directivity adjustments were constrained to strike-slip faulting, where DMs have good agreement. We find that rupture directivity adjustments using a simple median and aleatory adjustment approach can impact hazard both from a site perspective and on a regional scale, increasing shaking off the end of the fault trace up to 30--40\% and potentially reducing it for sites along strike. Statewide hazard maps of California show that the change in shaking along major faults can be a factor to consider for assessing long-period (>ls) near-source effects within the USGS NSHM going forward, reaching up to 10--20\%. Finally, we suggest consideration of minimum parameter ranges and baseline requirements as future DMs are developed to minimize single approach adaptations, to enable more consistent application within both ground motion and hazard studies.

Earthquake Spectra

Predictions of groundwater PFAS occurrence at drinking water supply depths in the United States

Per- and polyfluoroalkyl substances (PFAS), known colloquially as “forever chemicals”, have been associated with adverse human health effects and have contaminated drinking water supplies across the United States owing to their long-term and widespread use. People in the United States may unknowingly be drinking water that contains PFAS because of a lack of systematic analysis, particularly in domestic water supplies. We present an extreme gradient boosting model for predicting the occurrence of PFAS in groundwater at the depths of drinking water supply for the conterminous United States. Our model results indicate that 71 to 95 million people in the conterminous United States potentially rely on groundwater with detectable concentrations of PFAS for their drinking-water supplies prior to any treatment.

conterminous United States

The role of bedrock circulation depth and porosity in mountain streamflow response to prolonged drought

Quantitative understanding is lacking on how the depth of active groundwater circulation in bedrock affects mountain streamflow response to a multi‐year drought. We use an integrated hydrological model to explore the sensitivity of a variety of streamflow metrics to bedrock circulation depth and porosity under a plausible extreme drought scenario lasting up to 5 years. Endmember depth versus hydraulic conductivity relationships and porosity values for fractured crystalline rock are simulated. With drought, a deeper circulation system with higher drainable porosity more effectively buffers minimum flow and significantly limits perennial stream loss in comparison to a shallow circulation system. Streamflow buffering is accomplished through extensive groundwater storage loss. However, deeper circulation systems experience prolonged recovery from drought in comparison to storage‐limited shallow systems. Research highlights the importance of characterizing the deeper bedrock hydrogeology in mountainous watersheds to better understand and predict drought impacts on stream ecosystem health and water resource sustainability.

Colorado

Microplastics undergo fragmentation during pressurized membrane filtration

Low-micrometer microplastics (<10 μm) have been detected in drinking water, driving growing interest in using pressure-driven membrane filtration to remove these particles and ensure drinking water safety. However, little attention is paid to the fate of microplastics concentrated in the filtration byproduct. In this study, using well-defined polystyrene (PS) and poly(methyl methacrylate) microspheres as model particles, we observed microplastic fragmentation during nanofiltration and the subsequent release of smaller fragments. After operating for 3 h at 20 bar, 67.9 ± 8.0% of the PS spheres in the concentrate, based on particles counted in selected fields of view, were transformed into fractured particles. The characteristic Raman band signals of microplastics were significantly weakened after fragmentation, leading to detection challenges. To address this, a data processing algorithm was developed to identify PS fragments as small as 1 μm. Preliminary statistical analysis reveals that within the tested pressure range, operation time has a stronger influence on fragmentation than pressure magnitude alone and that fragmentation is further governed by the intrinsic mechanical properties of the tested model polymers. This work provides direct evidence that pressure-driven membrane processes induce microplastic fragmentation and highlights the environmental risks associated with the discharge of fragmented microplastics into the concentrate.

Environmental Science & Technology Letters

Tracing mercury from land to river: Global sources, retention, and implications for sustainability

Mercury (Hg) pollution in river systems is a global sustainability challenge. Yet the transport, transformation, and retention of Hg within global rivers remain poorly quantified, particularly in regions with sparse observations such as Southeast Asia and Africa, hindering effective pollution mitigation and reinforcing geographic inequities in scientific knowledge and environmental governance. Here, we present the first global, high-resolution simulation of riverine Hg dynamics using a process-based model that traces Hg from land-based sources through river networks to the ocean. Under a realistic scenario, we estimate that ∼1900 megagrams per year (Mg/yr) of Hg enters global rivers, including 1500 Mg/yr from human-induced sources and 400 Mg/yr from soil erosion. Nearly half of this flux (∼1000 Mg/yr) is retained in reservoirs and dams, which act as major sinks. While such retention limits downstream delivery to the oceans, it also heightens in-reservoir Hg methylation risks. By bridging the gap between Hg releases and observed riverine exports, our framework offers a scalable tool for data-limited regions, promotes data access, and supports global freshwater and pollution-management strategies.

Environmental Science & Technology