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At least 91 records · Page 5Linked to original sources

Energy development and production in the Great Plains: Implications and restoration opportunities

Energy is an integral part of society. The major US energy sources of fossil fuels (coal, oil, natural gas); biofuels (ethanol); and wind are concentrated in grassland ecosystems of the Great Plains. As energy demand continues to increase, mounting pressures will be placed on North American grassland systems. In this review, we present the ecological effects of energy development and production on grassland systems. We then identify opportunities to mitigate these effects during the planning, construction, and production phases by using informed methodology and improved technology. Primary effects during energy development include small- and large-scale soil disturbance and vegetation removal as small patches of grasslands are used to host oil or gas wells, wind turbine pads, associated roadways, and pipelines or through the conversion of large grassland areas to biofuel croplands. Direct habitat loss or habitat fragmentation can affect wildlife directly through increased mortality or indirectly through reduction in habitat quantity and quality. During energy production, air and water quality can be affected through regular emissions or unplanned spills. Energy development can also affect the economy and health of local communities. During planning, energy development and production effects can be reduced by carefully considering effects on grasslands during siting and even by selecting different energy source types. During construction, effects on soil and plant systems can be minimized by eliminating weed populations before disturbance, salvaging and stockpiling topsoil for future revegetation, and harvesting native local seed for postsite restoration. During energy production operations, noise and road traffic reduction plans and atmospheric monitoring will enable more informed mitigation measures. Continued research on energy development effects and mitigation measures is necessary to establish best management practices beneficial to grassland health while providing needed energy for the United States.

Colorado, Illinois, Indiana, Iowa, Kansas, Minneso↗

Screening of polar components of petroleum products by electrospray ionization mass spectrometry

The polar components of fuels may enable differentiation between fuel types or commercial fuel sources. Screening for these components in the hydrocarbon product is difficult due to their very low concentrations in such a complex matrix. Various commercial fuels from several sources were analyzed by flow injection analysis/electrospray ionization/mass spectrometry without extensive sample preparation, separation, or chromatography. This technique enabled screening for unique polar components at very low concentrations in commercial hydrocarbon products. This analysis was then applied to hydrocarbon samples collected from the subsurface with a different extent of biodegradation or weathering. Although the alkane and isoprenoid portion had begun to biodegrade or weather, the polar components had changed little over time. Because these polar compounds are unique in different fuels, this screening technique can provide source information on hydrocarbons released into the environment.

Energy and Fuels↗

The geographic extent of bird populations affected by renewable-energy development

Bird populations are declining globally. Wind and solar energy can reduce emissions of fossil fuels that drive anthropogenic climate change, yet renewable-energy production represents a potential threat to bird species. Surveys to assess potential effects at renewable-energy facilities are exclusively local, and the geographic extent encompassed by birds killed at these facilities is largely unknown, which creates challenges for minimizing and mitigating the population-level and cumulative effects of these fatalities. We performed geospatial analyses of stable hydrogen isotope data obtained from feathers of 871 individuals of 24 bird species found dead at solar- and wind-energy facilities in California (USA). Most species had individuals with a mix of origins, ranging from 23% to 98% nonlocal. Mean minimum distances to areas of likely origin for nonlocal individuals were as close as 97 to >1250 km, and these minimum distances were larger for species found at solar-energy facilities in deserts than at wind-energy facilities in grasslands (Cohen's d = 6.5). Fatalities were drawn from an estimated 30–100% of species’ desingated ranges, and this percentage was significantly smaller for species with large ranges found at wind facilities (Pearson's r = −0.67). Temporal patterns in the geographic origin of fatalities suggested that migratory movements and nonmigratory movements, such as dispersal and nomadism, influence exposure to fatality risk for these birds. Our results illustrate the power of using stable isotope data to assess the geographic extent of renewable-energy fatalities on birds. As the buildout of renewable-energy facilities continues, accurate assessment of the geographic footprint of wildlife fatalities can be used to inform compensatory mitigation for their population-level and cumulative effects.

Conservation Biology↗

Aligning renewable energy expansion with climate-driven range shifts

Fossil fuel dependence can be reduced, in part, by renewable energy expansion. Increasingly, renewable energy siting seeks to avoid significant impacts on biodiversity but rarely considers how species ranges will shift under climate change. Here we undertake a systematic literature review on the topic and overlay future renewable energy siting maps with the ranges of two threatened species under future climate scenarios to highlight this potential conflict.

Nature Climate Change↗

Water demands for expanding energy development

Water is used in producing energy for mining and reclamation of mined lands, onsite processing, transportation, refining, and conversion of fuels to other forms of energy. In the East, South, Midwest, and along the seacoasts, most water problems are related to pollution rather than to water supply. West of about the 100th meridian, however, runoff is generally less than potential diversions, and energy industries must compete with other water users. Water demands for extraction of coal, oil shale, uranium, and oil and gas are modest, although large quantities of water are used in secondary recovery operations for oil. The only significant use of water for energy transportation, aside from in-stream navigation use, is for slurry lines. Substantial quantities of water are required in the retorting and the disposal of spent oil shale. The conversion of coal to synthetic gas or oil or to electric power and the generation of electric power with nuclear energy require large quantities of water, mostly for cooling. Withdrawals for cooling of thermal-electric plants is by far the largest category of water use in energy industry, totaling about 170 billion gallons (644 million m3) per day in 1970. Water availability will dictate the location and design of energy-conversion facilities, especially in water deficient areas of the West.

Circular↗

An approach toward a combined scheme for the petrographic classification of fly ash: Revision and clarification

Hower and Mastalerz's classification scheme for fly ash is modified to make more widely acceptable. First, proper consideration is given to the potential role of anthracite in the development of isotropic and anisotropic chars. Second, the role of low-reflectance inertinite in producing vesicular chars is noted. It is shown that noncoal chars in the fuel can potentially produce chars that have the potential to stretch the limits of the classification. With care, it is possible to classify certain biomass chars as being distinct from coal-derived chars.

Energy and Fuels↗

Reprocessing and reuse of waste tire rubber to solve air-quality related problems

There is a potential for using waste tire rubber to make activated-carbon adsorbents for air-quality control applications. Such an approach provides a recycling path for waste tires and the production of new adsorbents from a low-cost waste material. Tire-derived activated carbons (TDACs) were prepared from waste tires. The resulting products are generally mesoporous, with N2-BET specific surface areas ranging from 239 to 1031 m2/g. TDACs were tested for their ability to store natural gas and remove organic compounds and mercury species from gas streams. TDACs are able to achieve 36% of the recommended adsorbed natural gas (methane) storage capacity for natural-gas-fueled vehicles. Equilibrium adsorption capacities for CH4 achieved by TDACs are comparable to Calgon BPL, a commercially available activated-carbon adsorbent. The acetone adsorption capacity for a TDAC is 67% of the adsorption capacity achieved by BPL at 1 vol % acetone. Adsorption capacities of mercury in simulated flue-gas streams are, in general, larger than adsorption capacities achieved by coal-derived activated carbons (CDACs) and BPL. Although TDACs may not perform as well as commercial adsorbents in some air pollution control applications, the potential lower cost of TDACS should be considered when evaluating economics.

Energy and Fuels↗

Geologic energy storage

Introduction As the United States transitions away from fossil fuels, its economy will rely on more renewable energy. Because current renewable energy sources sometimes produce variable power supplies, it is important to store energy for use when power supply drops below power demand. Battery storage is one method to store power. However, geologic (underground) energy storage may be able to retain vastly greater quantities of energy over much longer durations compared to typical battery storage. Geologic energy storage also has high flexibility; many different types of materials can be used to store chemical, thermal, or mechanical energy in a variety of underground settings. The U.S. Geological Survey (USGS) has the capability to research and assess possible domestic geologic energy storage resources to help prepare the United States for the future of renewable energy.

Fact Sheet↗

Intra- and inter-unit variation in fly ash petrography and mercury adsorption: Examples from a western Kentucky power station

Fly ash was collected from eight mechanical and 10 baghouse hoppers at each of the twin 150-MW wall-fired units in a western Kentucky power station. The fuel burned at that time was a blend of many low-sulfur, high-volatile bituminous Central Appalachian coals. The baghouse ash showed less variation between units than the mechanical hoppers. The mechanical fly ash, coarser than the baghouse ash, showed significant differences in the amount of total carbon and in the ratio of isotropic coke to both total carbon and total coke - the latter excluding inertinite and other unburned, uncoked coal. There was no significant variation in proportions of inorganic fly ash constituents. The inter-unit differences in the amount and forms of mechanical fly ash carbon appear to be related to differences in pulverizer efficiency, leading to greater amounts of coarse coal, therefore unburned carbon, in one of the units. Mercury capture is a function of both the total carbon content and the gas temperature at the point of fly ash separation, mercury content increasing with an increase in carbon for a specific collection system. Mercury adsorption on fly ash carbon increases at lower flue-gas temperatures. Baghouse fly ash, collected at a lower temperature than the higher-carbon mechanically separated fly ash, contains a significantly greater amount of Hg.

Energy and Fuels↗

Nanoscale molecular composition of solid bitumen from the Eagle Ford Group across a natural thermal maturity gradient

Microscopic solid bitumen is a petrographically defined secondary organic matter residue produced during petroleum generation and subsequent oil transformation. The presence of solid bitumen impacts many reservoir properties including porosity, permeability, and hydrocarbon generation and storage, among others. Furthermore, solid bitumen reflectance is an important parameter for assessing the thermal maturity of formations with little to no vitrinite. While the molecular composition of solid bitumen will strongly impact associated parameters such as the development of organic matter porosity, hydrocarbon generation, and optical reflectance, assessing the molecular composition of solid bitumen in situ within shale reservoirs can be challenging due to the small grain sizes (often ≤1 μm in diameter) and the inherent heterogeneity of shale formations. Here we employ the recently developed atomic force microscopy based infrared spectroscopy (AFM-IR) technique to investigate solid bitumen molecular composition in situ within shale samples from the Late Cretaceous Eagle Ford Group. These samples possess sulfur-rich type II kerogens that span a natural thermal maturity gradient from early oil generation to the dry gas window. The application of AFM-IR allows for the rapid collection of thousands of compositional measurements from solid bitumen with ∼50 nm resolution. Our results indicate that (i) solid bitumen from the lower Eagle Ford displays both intra- and intergranular variation in the relative abundance of CH 2 , C═C, and C═O moieties present; (ii) this molecular variation tends to, but does not always, decrease with an increase in thermal maturity; and (iii) the solid bitumen composition between samples, from an atomic ratio perspective, is more similar than analysis of bulk kerogen isolates would indicate. These findings are discussed with perspective toward understanding the impact of thermal stress on the composition of secondary organic matter within the Eagle Ford Shale and highlight the growing awareness that organic matter heterogeneity within petroliferous mudrocks extends down to the nanoscale regime.

Energy and Fuels↗

Permeability measurement and prediction with nuclear magnetic resonance analysis of gas hydrate-bearing sediments recovered from Alaska North Slope 2018 Hydrate-01 Stratigraphic Test Well

Permeability of porous media, such as oil and gas reservoirs, is the crucial material parameter for predicting their hydraulic behavior. A nuclear magnetic resonance (NMR) analyzer is widely used as a powerful tool to predict permeability of various media. NMR T 2 (transverse or spin–spin) relaxation time distribution, which is related to pore size distribution, gives the information to allow calculation of effective (initial) permeability. In this study, we investigate effective, intrinsic (absolute), and relative water and gas permeabilities of hydrate-bearing pressure core samples. These samples were recovered from the Alaska North Slope 2018 Hydrate-01 Stratigraphic Test Well by sidewall pressure coring and then analyzed in a laboratory using both fluid flow test and NMR analyzer. The peak of the NMR T 2 distribution was measured at 10–20 ms using a laboratory NMR analyzer, which compares well with in situ measurements obtained via logging while drilling NMR data for two samples with high gas hydrate saturations ( S h = 76% and 74%). Further, comparison of laboratory NMR T 2 distribution after hydrate dissociation revealed that the hydrate existed in large pore spaces. Effective permeabilities predicted by the Timur-Coates (TC) model and the Schlumberger-Doll-Research (SDR) model, with T 2 cutoff 33 ms, were about an order of magnitude less than the laboratory measured values. Alternative TC model-based calculations with the T 2 cutoff reduced to 10 ms and a newly developed hydraulic radius model better matched the laboratory data. For the analysis of the intrinsic permeabilities, the TC model with a T 2 cutoff of 33 ms and SDR model were greater than the laboratory derived values, while the hydraulic radius model more closely matched the laboratory-derived values. In addition, permeability measurements were also made relative to gas and water under constant three-phase flow (water–gas–hydrate) conditions. After hydrate dissociation, a relative permeability curve was developed for each of the analyzed core samples based on the Corey petrophysical model. The results indicate that the gas permeability changed rapidly at high water saturation around 90%. Thus, we infer that the selection of relative reservoir parameters should focus on the higher water saturation conditions.

Alaska↗

Planning and operations of the Hydrate 01 Stratigraphic Test Well, Prudhoe Bay Unit, Alaska North Slope

The National Energy Technology Laboratory, the Japan Oil, Gas and Metals National Corporation, and the U.S. Geological Survey are leading an effort to conduct an extended gas hydrate production test in northern Alaska. The proposed production test required the drilling of an initial stratigraphic test well (STW) to confirm the geologic conditions of the proposed test site. This well was completed in January 2019 in cooperation with the Prudhoe Bay Unit Working Interest Owners. The Prudhoe Bay Unit Hydrate-01 STW was spudded on 10-December-2018. Downhole data acquisition was completed on 25-December-2018, and the rig was released on 01-January-2019. The Hydrate-01 STW was drilled in two sections, including the surface hole that was drilled to a depth of 2248 ft measured depth (MD) (685 m MD) and cased, and the production hole section that was drilled to a depth of 3558 ft MD (1084 m MD) and also cased. A thermally chilled mineral-oil-based mud was used in the main (production) hole section of the well to maintain wellbore stability and quality of the wellbore acquired data. The primary wellbore data were acquired using logging-while-drilling tools. A sidewall pressure core system was also deployed to gather grain size and other data needed for the design of the future production test wells. In addition to confirming the geologic conditions at the test site, the Hydrate-01 STW was designed to serve as a monitoring well during future field operations. Therefore, two sets of fiber-optic cables, each including a bundled distributed acoustic sensor (DAS) and a distributed temperature sensor (DTS), were clamped to the outside of the production casing and cemented in place. In March 2019, the project team acquired three-dimensional (3D) DAS vertical seismic profiling data in the Hydrate-01 STW. Temperature surveys were also acquired with the DTS as deployed in the Hydrate-01 STW during the completion of the well and nearly continuously since March-2019.

Alaska↗

Gas hydrate saturation estimates, gas hydrate occurrence, and reservoir characteristics based on well log data from the hydrate-01 stratigraphic test well, Alaska North Slope

The Hydrate-01 Stratigraphic Test Well was drilled at the Kuparuk 7-11-12 site on the Alaska North Slope in December 2018. Sonic log data provide compressional (P) and shear (S) slowness from which we determine gas hydrate saturation ( S gh ) estimates using effective medium theory. The sonic S gh estimates compare favorably with S gh estimated from resistivity and nuclear magnetic resonance (NMR) logs, showing that gas hydrate occupies up to approximately 90% of the pore space in the target reservoir sands. The informally named B1 sand (2294 feet below mean sea level) shows lower V P / V S ratios than the D1 sand (2770 feet below mean sea level), with the lower part of the B1 sand showing lower V P / V S ratios than the upper part of the B1 sand. This corresponds to a stiffer, or more “cemented”, behavior for the lower B1 sand and less cemented behavior for the D1 sand. This trend could be due to differences in the reservoirs themselves or in the gas hydrate morphology or to both factors. We observe that the presence of gas hydrate in the upper B1 sand has greater impact on hydraulic permeability (measurements suggest a greater difference between intrinsic and effective permeability) than in the D1 sand, possibly related to gas hydrate morphology but more likely due simply to higher gas hydrate saturations in the upper B1 sand. Analyses of S gh relative to porosity, shale fraction, and intrinsic permeability show that reservoir quality (as represented by these three metrics) exerts control on gas hydrate saturation. Grain size and mineralogy data show somewhat smaller grains and better sorting in the D1 reservoir relative to the upper B1 reservoir and smaller grains and greater clay fraction in the lower B1 reservoir relative to the other two reservoir zones. Together, these data suggest that reservoir characteristics play a role in the observed V P / V S patterns, but gas hydrate morphology (possibly varying with saturation) must also be considered.

Alaska↗

New insights into the occurrence and implications of mobile water in gas hydrate systems

Gas hydrate production technologies commonly feature reservoir depressurization. Depressurization occurs when a pressure gradient is established in a well, drawing mobile water from the reservoir and reducing reservoir pressure. As such, the occurrence of mobile water is a necessary condition for effective gas production from gas hydrate reservoirs using common borehole-based methods. However, recent field programs have revealed that mobile water exists widely within the overall gas hydrate reservoir system, including within overlying and underlying units once thought of as virtually impermeable seals. Further, excess free water may also be commonly found in hydrate-free or hydrate-poor permeable strata interbedded within the larger gas hydrate reservoir system. Such internal sources of water are complex to characterize, difficult to explain, potentially highly heterogeneous, and may pose significant challenges to depressurization-based production. This report summarizes the general occurrence of water in gas hydrate systems and select technical implications.

Journal of Energy and Fuels↗

Advanced distributed acoustic sensing vertical seismic profile imaging of an Alaska North Slope gas hydrate field

Gas hydrates are found in significant quantities on the North Slope of Alaska in subpermafrost sand units and intermixed in lower portions of permafrost within the hydrate stability window. While conventional surface seismic data and established imaging methods can indicate the presence of gas hydrate reservoirs, producing high-resolution images of (seismically) thin layers remains challenging due to the preferential attenuation of the higher-frequency data components. An alternative strategy is to use distributed acoustic sensing (DAS) involving cementing optical fibers into boreholes to measure seismic wavefield energy closer to the strata of interest using vertical seismic profiling (VSP). DAS VSP imaging takes advantage of the shorter travel paths and reduced attenuation to generate higher-resolution near-well images. We illustrate these benefits on a DAS VSP data set acquired at the Hydrate-01 stratigraphic test well located in the Prudhoe Bay Unit of Alaska where significant gas hydrate deposits have been detected in two subpermafrost sand layers that are intended for long-duration production testing. Our DAS data preprocessing workflow effectively isolates the upgoing compressional-wave (P-wave) reflections required for subsurface acoustic imaging. After applying three-dimensional (3-D) tomography to improve the quality of the 3-D migration velocity model, we use 3-D reverse-time migration (RTM) to develop high-quality images of the two target sands and minor near-well faulting. We validate our RTM images through highly accurate well-ties with previously acquired petrophysical log data. This study demonstrates that combining 3-D RTM imaging with DAS VSP data provides significant value to gas hydrate and similar projects, and it suggests that more advanced inversion approaches such as (elastic) least-squares RTM could recover higher-resolution and more quantitative estimates of subsurface reflectivity, which would be valuable for refining the understanding of gas hydrate systems.

Alaska↗

Review of past gas Production attempts from subsurface gas hydrate deposits and necessity of long-term production testing

This paper summarizes the conditions, applied techniques, results, and lessons of major field gas production attempts from gas hydrates in the past and the necessity of longer term production testing with the scale of years to fulfill the gap between the currently available information and the knowledge required for commercial development. The temporal and spatial scales of field production test projects employing depressurization have expanded since 2002. The results from the projects have proved the applicability of these techniques in both onshore and offshore conditions. However, many technical and reservoir condition-related issues have emerged in gas production, and the gap between current status and industrial requirements is still large. Sand control, artificial lift, and related flow assurance issues are common technical issues that impact onshore and offshore production testing operations. Different reservoir responses were observed well by well, and discrepancy between model predictions and actual field measurements were seen, although reasonable matches were made for short-term behaviors. Those observations suggest that temporal change of the wellbore and near-wellbore conditions and reservoir heterogeneity that cannot be fully modeled have caused complex short-term responses to the depressurization operations. To ensure the long-term operational stability and reliability of the prediction technologies for production behaviors that are essential for commercialization of gas hydrate resources, gas hydrate production testing with comparable duration with commercial operations are necessary. Due to the locality of geological conditions in gas hydrate reservoirs, numerous gas production tests will be required to understand the factors controlling gas production.

Journal of Energy and Fuels↗

Scientific results of the Hydrate-01 Stratigraphic Test Well Program, Western Prudhoe Bay Unit, Alaska North Slope

The United States Department of Energy, the MH21-S Research Consortium of Japan, and the United States Geological Survey are collaborating to enable gas hydrate scientific drilling and extended-duration reservoir response testing on the Alaska North Slope. To feasibly execute such a test, a location is required that is accessible from existing roads and gravel pads and that can be occupied without disrupting ongoing industry operations. A review of potential locations meeting these criteria determined the likely occurrence of gas hydrate in two fine-grained marginal-marine sands of Tertiary age in the vicinity of the inactive “Kuparuk State 7-11-12” exploration pad in the western Prudhoe Bay Unit (PBU). Existing well and seismic data for that site were insufficient to preclude the potential for free gas occurrence within the deeper (and most prospective) target sand. Therefore, with support from the PBU Working Interest Owners, Alaska Department of Natural Resources, and Petrotechnical Resources Alaska, the Hydrate-01 Stratigraphic Test Well (STW) was drilled in December 2018 to confirm the suitability of the site for future gas hydrate scientific testing. The Hydrate-01 well was successfully drilled to −3290 ft (1003 m) subsea vertical depth at a bottom hole location of approximately 900 ft (∼275 m) east of the surface location. The drilling program featured acquisition of a full suite of logging while drilling data, the collection of side-wall pressure cores, and the installation of distributed temperature and distributed acoustic sensor fiber-optic cables. The log data acquired confirmed the occurrence of gas hydrate at high saturation in two target sands. Integrated evaluation of log and sidewall core data provide petrophysical and geomechanical property information that allow for potential reservoir response to depressurization to be simulated. The deeper “B1 sand” is deemed to be most favorable for reservoir response testing as a result of confirmed gas hydrate occurrence in sediments of high intrinsic permeability, location within 100 ft (30 m) of the base of gas hydrate stability, and minimal risk for direct communication with permeable water-bearing (hydrate-free) zones. The shallower “D1 sand” provides a secondary target that is differentiated by colder in situ temperatures and the interpreted direct hydraulic communication to a lower section of non-hydrate-bearing, water-saturated sand. The Hydrate-01 log data also confirm the occurrence of at least one sub-seismic fault in close proximity to the B1 sand reservoir. To better image the distribution of the gas-hydrate-bearing reservoir sections and associated faults, a three-dimensional (3D) vertical seismic profile was conducted in early 2019 using the distributed acoustic sensors installed as part of the Hydrate-01 STW completion. Detailed two-dimensional (2D) and 3D geologic models have been constructed to enable numerical simulations to inform the planning for potential future scientific tests of reservoir response to depressurization at the site.

Alaska↗