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88 records · Page 5Linked to original sources
USGS2014

Identifying sources of aeolian mineral dust: Present and past

Aeolian mineral dust is an important component of the Earth’s environmental systems, playing roles in the planetary radiation balance, as a source of fertilizer for biota in both terrestrial and marine realms and as an archive for understanding atmospheric circulation and paleoclimate in the geologic past. Crucial to understanding all of these roles of dust is the identification of dust sources. Here we review the methods used to identify dust sources active at present and in the past. Contemporary dust sources, produced by both glaciogenic and non-glaciogenic processes, can be readily identified by the use of Earth-orbiting satellites. These data show that present dust sources are concentrated in a global dust belt that encompasses large topographic basins in low-latitude arid and semiarid regions. Geomorphic studies indicate that specific point sources for dust in this zone include dry or ephemeral lakes, intermittent stream courses, dune fields, and some bedrock surfaces. Back-trajectory analyses are also used to identify dust sources, through modeling of wind fields and the movement of air parcels over periods of several days. Identification of dust sources from the past requires novel approaches that are part of the geologic toolbox of provenance studies. Identification of most dust sources of the past requires the use of physical, mineralogical, geochemical, and isotopic analyses of dust deposits. Physical properties include systematic spatial changes in dust deposit thickness and particle size away from a source. Mineralogy and geochemistry can pinpoint dust sources by clay mineral ratios and Sc-Th-La abundances, respectively. The most commonly used isotopic methods utilize isotopes of Nd, Sr, and Pb and have been applied extensively in dust archives of deep-sea cores, ice cores, and loess. All these methods have shown that dust sources have changed over time, with far more abundant dust supplies existing during glacial periods. Greater dust supplies in glacial periods are likely due to greater production of glaciogenic dust particles from expanded ice sheets and mountain glaciers, but could also include dust inputs from exposed continental and insular shelves now submerged. Future dust sources are difficult to assess, but will likely differ from those of the present because of global warming. Global warming could bring about shifts in dust sources by changes in degree or type of vegetation cover, changes in wind strength, and increases or decreases in the size of water bodies. A major uncertainty in assessing dust sources of the future is related to changes inhuman land use, which could affect land surface cover, particularly due to increased agricultural endeavors and water usage.

Book chapter↗
USGS2001

Dynamics of carbon dioxide emission at Mammoth Mountain, California

Mammoth Mountain, a dormant volcano in the eastern Sierra Nevada, California, has been passively degassing large quantities of cold magmatic CO2 since 1990 following a 6-month-long earthquake swarm associated with a shallow magmatic intrussion in 1989. A search for any link between gas discharge and volcanic hazard at this popular recreation area led us to initiate a detailed study of the degassing process in 1997. Our continuous monitoring results elucidate some of the physical controls that influence dynamics in flank CO2 degassing at this volcano. High coherence between variations in CO2 efflux and variations in atmospheric pressure and wind speed imply that meteorological parameters account for much, if not all of the variability in CO2 efflux rates. Our results help explain differences among previously published estimates of CO2 efflux at Mammoth Mountain and indicate that the long-term (annual) CO2 degassing rate has in fact remained constant since ~ 1997. Discounting the possibility of large meteorologically driven temporal variations in gas efflux at other volcanoes may result in spurious interpretations of transients do not reflect actual geologic processes. ?? 2001 Elsevier Science B.V. All rights reserved.

Earth and Planetary Science Letters↗
USGS2023

Deep root activity overprints weathering of petrogenic organic carbon in shale

The oxidation of organic carbon in sedimentary bedrock (petrogenic OC, OC p e t r o "> petro ) is increasingly recognized as a potential source of CO 2 to the atmosphere. Recent studies provide evidence for the mobilization and oxidation of OC p e t r o "> petro in sedimentary bedrock during rock weathering. However, the mechanisms and rates remain uncertain, particularly where overlying soils and vegetation drive contemporaneous oxidation of recently fixed organic carbon. Here, we quantify OC p e t r o "> petro weathering across a 16 m shale depth profile in a steep, rapidly eroding forested hillslope in the Northern California Coast Ranges. We report solid and gas phase radiocarbon and stable isotope analyses of samples extracted from specialized in-situ samplers, and a supporting laboratory incubation experiment of the shale regolith. OC p e t r o "> petro is removed from the weathered bedrock at a rate of approximately 0.12 gC/m 3 yr, which is orders of magnitude lower than the rate of OC p e t r o "> petro oxidation we achieved in the laboratory with crushed samples (557.1 gC/m 3 /yr). This disparity occurs despite high O 2 ( g ) "> 2(g) content across the depth profile, indicating that physical accessibility of OC p e t r o "> petro can regulate oxidative weathering. There is no direct radiocarbon evidence of OC p e t r o "> petro oxidation in CO 2 ( g ) "> 2(g) across the upper 13 m of the weathering profile during both wet and dry seasons. Instead, vadose zone CO 2 ( g ) "> 2(g) production at the site is dominated by respiration of recently fixed carbon associated with deep rooting. OC p e t r o "> petro is clearly mobilized across the vadose zone during weathering in this rapidly eroding, oxygen-rich, biologically dynamic hillslope, but at rates far below what can be measured given the contribution of root-derived CO 2 ( g ) "> 2(g) .

California↗
USGS1977

Voyager imaging experiment

The overall objective of this experiment is exploratory reconnaissance of Jupiter, Saturn, their satellites, and Saturn's rings. Such reconnaissance, at resolutions and phase angles unobtainable from Earth, can be expected to provide much new data relevant to the atmospheric and/or surface properties of these bodies. The experiment also has the following specific objectives: Observe and characterize the global circulation of the atmospheres of Jupiter and Saturn; Determine the horizontal and vertical structure of the visible clouds and establish their relationship to the belted appearance and dynamical properties of the planetary atmospheres; Determine the vertical structure of high, optically-thin, scattering layers on Jupiter and Saturn; Determine the nature of anomalous features such as the Great Red Spot, South Equatorial Belt disturbances, etc.; Characterize the nature of the colored material in the clouds of Jupiter and Saturn, and identify the nature and sources of chromophores on Io and Titan; Perform comparative geologic studies of many satellites at less than 15-km resolution; Map and characterize the geologic structure of several satellites at high resolution (???1 km); Investigate the existence and nature of atmospheres on the satellites; Determine the mass, size, and shape of many of the satellites by direct measurement; Determine the direction of the spin axes and periods of rotation of several satellites, and establish coordinate systems for the larger satellites; Map the radial distribution of material in Saturn's rings at high resolution; Determine the optical scattering properties of the primaries, rings, and satellites at several wavelengths and phase angles; Search for novel physical phenomena, e.g., phenomena associated with the Io flux tube, meteors, aurorae, lightning, or satellite shadows. ?? 1977 D. Reidel Publishing Company.

Space Science Reviews↗
USGS2015

Tectonic activity as a significant source of crustal tetrafluoromethane emissions to the atmosphere: observations in groundwaters along the San Andreas Fault

Tetrafluoromethane (CF4) concentrations were measured in 14 groundwater samples from the Cuyama Valley, Mil Potrero and Cuddy Valley aquifers along the Big Bend section of the San Andreas Fault System (SAFS) in California to assess whether tectonic activity in this region is a significant source of crustal CF4 to the atmosphere. Dissolved CF4 concentrations in all groundwater samples but one were elevated with respect to estimated recharge concentrations including entrainment of excess air during recharge (CreCre; ∼30 fmol kg−1 H2O), indicating subsurface addition of CF4 to these groundwaters. Groundwaters in the Cuyama Valley contain small CF4 excesses (0.1–9 times CreCre), which may be attributed to an in situ release from weathering and a minor addition of deep crustal CF4 introduced to the shallow groundwater through nearby faults. CF4 excesses in groundwaters within 200 m of the SAFS are larger (10–980 times CreCre) and indicate the presence of a deep crustal flux of CF4 that is likely associated with the physical alteration of silicate minerals in the shear zone of the SAFS. Extrapolating CF4 flux rates observed in this study to the full extent of the SAFS (1300 km × 20–100 km) suggests that the SAFS potentially emits (0.3–1)×10−1 kg(0.3–1)×10−1 kg CF4 yr−1 to the Earth's surface. For comparison, the chemical weathering of ∼7.5×104 km2∼7.5×104 km2 of granitic rock in California is estimated to release (0.019–3.2)×10−1 kg(0.019–3.2)×10−1 kg CF4 yr−1. Tectonic activity is likely an important, and potentially the dominant, driver of natural emissions of CF4 to the atmosphere. Variations in preindustrial atmospheric CF4 as observed in paleo-archives such as ice cores may therefore represent changes in both continental weathering and tectonic activity, including changes driven by variations in continental ice cover during glacial–interglacial transitions.

California↗
USGS2024

Global variability of the composition and temperature at the 410-km discontinuity from receiver function analysis of dense arrays

Seismic boundaries caused by phase transitions between olivine polymorphs in Earth's mantle provide thermal and compositional markers that inform mantle dynamics. Seismic studies of the mantle transition zone often use either global averaging with sparse arrays or regional sampling from a single dense array. The intermediate approach of this study utilizes many densely spaced seismic arrays distributed around the globe. We systematically compute teleseismic P-to-S receiver functions for each seismic array and invert for the 1-D seismic velocity structure of the mantle transition zone beneath each array to facilitate a comparison between densely sampled regions. We stack 3,600 receiver functions on average at 67 arrays in total. The stack is used in a probabilistic inversion to estimate the mantle transition zone interface depths and velocities beneath each array. We focus on the 410-km discontinuity (410) because it is a prominent seismic interface that is clearly linked to a single mineral phase transition between olivine and wadsleyite. The depths and velocity contrasts of the 410 are mapped to temperatures and compositions using mineral physics constraints. The depth of the 410 ranges from ∼405–440 km, which is consistent with a ∼360 K temperature range in a dry mantle and a ∼260 K temperature range in a wet mantle (2 wt. % water). The Vs contrast across the 410 ranges from ∼2.5–8 %, which is consistent with ∼20–70 vol. % olivine composition in a dry mantle and ∼25–80 vol. % in a wet mantle. The bulk composition of the upper mantle near the 410-km discontinuity is typically considered to be well-mixed because there is no thermodynamic impediment to convection at the olivine to wadsleyite phase transition. However, the wide range of inferred olivine content from our study suggests that there are large lateral variations in the bulk composition of the upper mantle near the 410-km discontinuity.

Earth and Planetary Science Letters↗
USGS2003

Comment on “Isotopic fractionation between Fe(III) and Fe(II) in aqueous solutions” by Clark Johnson et al., [Earth Planet. Sci. Lett. 195 (2002) 141–153]

In a recent contribution [1] , Johnson et al. reported the equilibrium isotope fractionation factor between dissolved Fe(II) and Fe(III) in aqueous solutions at pH=2.5 and 5.5. They suggest that because the iron isotope fractionation observed in their experiments spans virtually the entire range observed in sedimentary rocks, Fe(II)–Fe(III) aqueous speciation may play a major role in determining iron isotope variations in nature where Fe(II) and Fe(III) can become physically separated. They discounted earlier conclusions by us and others [2] ; [3] that significant equilibrium fractionation between specific coexisting Fe(II)- or Fe(III)-aqueous complexes (e.g., between aqueous Fe(II)(OH) x(aq) and Fe(II) (aq) ion) is capable of producing iron isotope contrasts that can be preserved in nature. This is an important contribution not only because the authors recognize the importance of abiotic equilibrium iron isotope fractionation in nature in contrast to previous assertions [4] , but also because it will help to focus discussion on the development and evaluation of experimental approaches that can reveal abiotic fractionation mechanisms. However, in this Comment we propose that the experiments presented in this paper cannot be interpreted as straightforwardly as Johnson et al. contend. In particular, we show that in one of their critical experiments attainment of either isotope mass balance or equilibrium was not demonstrated, and thus the results of that experiment cannot be used to calculate an Fe(II)–Fe(III) equilibrium fractionation factor.

Earth and Planetary Science Letters↗
USGS2011

Strong climate and tectonic control on plagioclase weathering in granitic terrain

Investigations to understand linkages among climate, erosion and weathering are central to quantifying landscape evolution. We approach these linkages through synthesis of regolith data for granitic terrain compiled with respect to climate, geochemistry, and denudation rates for low sloping upland profiles. Focusing on Na as a proxy for plagioclase weathering, we quantified regolith Na depletion, Na mass loss, and the relative partitioning of denudation to physical and chemical contributions. The depth and magnitude of regolith Na depletion increased continuously with increasing water availability, except for locations with mean annual temperature < 5 °C that exhibited little Na depletion, and locations with physical erosion rates < 20 g m − 2 yr − 1 that exhibited deep and complete regolith Na depletion. Surface Na depletion also tended to decrease with increasing physical erosion. Depth-integrated Na mass loss and regolith depth were both three orders of magnitude greater in the fully depleted, low erosion rate sites relative to other locations. These locations exhibited strong erosion-limitation of Na chemical weathering rates based on correlation of Na chemical weathering rate to total Na denudation. Sodium weathering rates in cool locations with positive annual water balance were strongly correlated to total Na denudation and precipitation, and exhibited an average apparent activation energy ( Ea ) of 69 kJ mol − 1 Na. The remaining water-limited locations exhibited kinetic limitation of Na weathering rates with an Ea of 136 kJ mol − 1 Na, roughly equivalent to the sum of laboratory measures of Ea and dissolution reaction enthalpy for albite. Water availability is suggested as the dominant factor limiting rate kinetics in the water-limited systems. Together, these data demonstrate marked transitions and nonlinearity in how climate and tectonics correlate to plagioclase chemical weathering and Na mass loss.

Earth and Planetary Science Letters↗
USGS2015

The effect of pressurized magma chamber growth on melt migration and pre-caldera vent locations through time at Mount Mazama, Crater Lake, Oregon

The pattern of eruptions at long-lived volcanic centers provides a window into the co-evolution of crustal magma transport, tectonic stresses, and unsteady magma generation at depth. Mount Mazama in the Oregon Cascades has seen variable activity over the last 400 ky, including the 50 km 3 climactic eruption at ca. 7.7 ka that produced Crater Lake caldera. The physical mechanisms responsible for the assembly of silicic magma reservoirs that are the precursors to caldera-forming eruptions are poorly understood. Here we argue that the spatial and temporal distribution of geographically clustered volcanic vents near Mazama reflects the development of a centralized magma chamber that fed the climactic eruption. Time-averaged eruption rates at Mount Mazama imply an order of magnitude increase in deep magma influx prior to the caldera-forming event, suggesting that unsteady mantle melting triggered a chamber growth episode that culminated in caldera formation. We model magma chamber&ndash;dike interactions over &sim;50 ky preceding the climactic eruption to fit the observed distribution of surface eruptive vents in space and time, as well as petrologically estimated deep influx rates. Best fitting models predict an expanding zone of dike capture caused by a growing, oblate spheroidal magma chamber with 10&ndash;30 MPa of overpressure. This growing zone of chamber influence causes closest approaching regional mafic vent locations as well as more compositionally evolved Mazama eruptions to migrate away from the climactic eruptive center, returning as observed to the center after the chamber drains during the caldera-forming eruption.

Oregon↗
USGS2002

A bibliography of terrain modeling (geomorphometry), the quantitative representation of topography: Supplement 4.0

Terrain modeling, the practice of ground-surface quantification, is an amalgam of Earth science, mathematics, engineering, and computer science. The discipline is known variously as geomorphometry (or simply morphometry), terrain analysis, and quantitative geomorphology. It continues to grow through myriad applications to hydrology, geohazards mapping, tectonics, sea-floor and planetary exploration, and other fields. Dating nominally to the co-founders of academic geography, Alexander von Humboldt (1808, 1817) and Carl Ritter (1826, 1828), the field was revolutionized late in the 20th Century by the computer manipulation of spatial arrays of terrain heights, or digital elevation models (DEMs), which can quantify and portray ground-surface form over large areas (Maune, 2001). Morphometric procedures are implemented routinely by commercial geographic information systems (GIS) as well as specialized software (Harvey and Eash, 1996; Köthe and others, 1996; ESRI, 1997; Drzewiecki et al., 1999; Dikau and Saurer, 1999; Djokic and Maidment, 2000; Wilson and Gallant, 2000; Breuer, 2001; Guth, 2001; Eastman, 2002). The new Earth Surface edition of the Journal of Geophysical Research, specializing in surficial processes, is the latest of many publication venues for terrain modeling. This is the fourth update of a bibliography and introduction to terrain modeling (Pike, 1993, 1995, 1996, 1999) designed to collect the diverse, scattered literature on surface measurement as a resource for the research community. The use of DEMs in science and technology continues to accelerate and diversify (Pike, 2000a). New work appears so frequently that a sampling must suffice to represent the vast literature. This report adds 1636 entries to the 4374 in the four earlier publications1. Forty-eight additional entries correct dead Internet links and other errors found in the prior listings. Chronicling the history of terrain modeling, many entries in this report predate the 1999 supplement. Coverage is representative from about 1800 through early–mid 2002. Papers increasingly are published exclusively or in duplicate on the Internet's World Wide Web; the dates given here for Web addresses (URLs) that lack a print publication indicate a Web site's last update or my last access of it. The bibliography is arranged alphabetically and thus is not readily summarized. This introduction cites about 500 entries, a third of them grouped under 24 morphometric topics, as a guide to the listing's contents. Continuing the practice of previous bibliographies in the series to provide more information on a few applications (see summary of past topics in Pike, 2000a), this report elaborates further on topographic data, putative new parameters, tectonic geomorphology/neo-orometry, biogeography, ice-cap morphometry, results from the Mars Global DEM, landslide-hazard mapping, terrain modeling as physics, Hack's law, and broad-scale computer visualization. The literature of some of these subjects is large, and none of the summaries is intended to more than introduce the topic and comment on some of the current contributions of terrain modeling. Closing the essay is a discussion of pre-1900 papers that trace the evolution of ridge-line and watercourse quantification by descriptive geometry, as well as comments on some new books and an on-line bulletin board.

Open-File Report↗
USGS2000

Using submarine lava pillars to record mid-ocean ridge eruption dynamics

Submarine lava pillars are hollow, glass-lined, basaltic cylinders that occur at the axis of the mid-ocean ridge, and within the summit calderas of some seamounts. Typically, pillars are ~1-20 m tall and 0.25-2.0 m in diameter, with subhorizontal to horizontal glassy selvages on their exterior walls. Lava pillars form gradually during a single eruption, and are composed of lava emplaced at the eruption onset as well as the last lava remaining after the lava pond has drained. On the deep sea floor, the surface of a basaltic lava flow quenches to glass within 1 s, thereby preserving information about eruption dynamics, as well as chemical and physical properties of lava within a single eruption. Investigation of different lava pillars collected from a single eruption allows us to distinguish surficial lava-pond or lava-lake geochemical processes from those operating in the magma chamber. Morphologic, major-element, petrographic and helium analyses were performed on portions of three lava pillars formed during the April 1991 eruption near 9°50'N at the axis of the East Pacific Rise. Modeling results indicate that the collected portions of pillars formed in ~2-5 h, suggesting a total eruption duration of ~8-20 h. These values are consistent with observed homogeneity in the glass helium concentrations and helium diffusion rates. Major-element compositions of most pillar glasses are homogeneous and identical to the 1991 flow, but slight chemical variations measured in the outermost portions of some pillars may reflect post-eruptive processes rather than those occurring in subaxial magma bodies. Because lava pillars are common at mid-ocean ridges (MORs), the concepts and techniques we present here may have important application to the study of MOR eruptions, thereby providing a basis for quantitative comparisons of volcanic eruptions in geographically and tectonically diverse settings. More research is needed to thoroughly test the hypotheses presented here. (C) 2000 Published by Elsevier Science B.V. All rights reserved.

Earth and Planetary Science Letters↗
USGS2003

Extraordinary phase separation and segregation in vent fluids from the southern East Pacific Rise

The discovery of Brandon vent on the southern East Pacific Rise is providing new insights into the controls on midocean ridge hydrothermal vent fluid chemistry. The physical conditions at the time ofsampling (287 bar and 405??C) place the Brandon fluids very close to the critical point of seawater (298 bar and 407??C). This permits in situ study of the effects of near criticalphenomena, which are interpreted to be the primary cause of enhanced transition metal transport in these fluids. Of the five orifices on Brandon sampled, three were venting fluids with less than seawater chlorinity, and two were venting fluids with greater than seawater chlorinity. The liquid phase orifices contain 1.6-1.9 times the chloride content of the vapors. Most other elements, excluding the gases, have this same ratio demonstrating the conservative nature of phase separation and the lack of subsequent water-rock interaction. The vapor and liquid phases vent at the same time from orifices within meters of each other on the Brandon structure. Variations in fluid compositions occur on a time scale of minutes. Our interpretation is that phase separation and segregation must be occurring 'real time' within the sulfide structure itself. Fluids from Brandon therefore provide an unique opportunity to understand in situ phase separation without the overprinting of continued water-rock interaction with the oceanic crust, as well as critical phenomena. ?? 2002 Elsevier Science B.V. All rights reserved.

Earth and Planetary Science Letters↗
USGS2021

Onset and evolution of Kilauea’s 2018 flank eruption and summit collapse from continuous gravity

Prior to the 2018 lower East Rift Zone (ERZ) eruption and summit collapse of Kīlauea Volcano, Hawai‘i, continuous gravimeters operated on the vent rims of ongoing eruptions at both the summit and Pu‘u ‘Ō‘ō. These instruments captured the onset of the 2018 lower ERZ eruption and the effects of lava withdrawal from both locales, providing constraints on the timing and style of activity and the physical properties of the lava lakes at both locations. At the summit, combining gravity, lava level, and a three-dimensional model of the vent indicates that the upper ∼200 m of the lava lake had a density of about 1700 kg m −3 , slightly greater than estimates from 2011–2015 and possibly indicating a gradual densification over time. At Pu‘u ‘Ō‘ō, gravity and vent geometry were used to model both the density and the rate of crater collapse, which was unknown owing to a lack of visual observations. Results suggest the withdrawal of at least 11×106 m 3 of lava over the course of two hours, and a material density of 1800–1900 kg m −3 . In addition, gravity data at Pu‘u ‘Ō‘ō captured a transient decrease and increase about an hour prior to crater collapse and that was probably related to a small, short-lived fissure eruption on the west flank of the cone and possibly to dike intrusion beneath Pu‘u ‘Ō‘ō. The fissure was the first event in the subsequent cascade that ultimately led to the extrusion of over 1 km 3 of lava from lower ERZ vents, collapse of the summit caldera floor by more than 500 m, and the destruction of over 700 homes and other structures. These results emphasize the importance of continuous gravity in operational monitoring of active volcanoes.

Hawaii↗
USGS2023

Summary of the history and research of the U.S. Geological Survey gas hydrate properties laboratory in Menlo Park, California, active from 1993 to 2022

The U.S. Geological Survey (USGS) Clathrate Hydrate Properties Project, active from 1993 to 2022 in Menlo Park, California, stemmed from an earlier project on the properties of planetary ices supported by the National Aeronautics and Space Administration’s (NASA’s) Planetary Geology and Geophysics Program. We took a material science approach in both projects, emphasizing chemical purity of samples, having controlled grain size and grain texture, and having verified crystal structures and phase relations. A foundational contribution from our USGS Gas Hydrate Properties Laboratory (GHPL) was in demonstrating the ability to reproducibly create such pure clathrate hydrate samples for study. Clathrate sample synthesis was achieved by heating sieved and weighed pure granular water ice in the presence of cold clathrate-forming gas or liquid. During heating, the ice melts at the grain scale and reacts with the gas to form clathrate. The resulting material has the desired uniformity and purity, with known intergranular porosity; our subsequent measurements showed that these clathrates exhibited the established clathrate structures and phase relations. This novel synthesis method was successful in creating clathrates of pure methane, ethane, propane, carbon dioxide, and multi-component gases. By mixing sand or silt with granular ice, we were also able to make clathrate-sediment aggregates with controlled grain textures. This simple method, adopted by many others in the community, permitted us to measure the physical and chemical properties of well-characterized and well-crystallized clathrates and clathrate/sediment aggregates. At about the same time, we adapted conventional scanning electron microscopy to cryogenic conditions for analysis of grain-scale characteristics of clathrates made in the GHPL as well as those collected from nature by drill core. The uniformity and reproducibility of our samples also allowed us to investigate how clathrates respond to environmental changes in chemistry, temperature, and pressure: we measured chemical exchange rates with dissolved gas species—such as noble gases and chlorofluorocarbons—as well as rates of clathrate dissolution and decomposition. These advances include the first accurate mapping of the conditions that promote the remarkable process of “anomalous preservation” at room pressure, a metastability that offers potential application for low-cost and safe transportation of natural gas from gas fields far from pipelines. Another advancement stemming from the GHPL was the compaction of as-synthesized porous clathrates to nearly full density by applying external pressure using three different techniques. Compaction allows for high-accuracy measurements of many fundamental physical and chemical properties of these materials, such as elastic wavespeeds and moduli, complete thermal properties, decomposition rates, thermal expansion, and clathrate equations of state. These properties and others, in turn, have helped USGS scientists to interpret geophysical well logs and active geophysical surveys, as well as model the rates of gas production from hydrate deposits in nature. Studying this class of icy minerals that occur in abundance on Earth and in the outer solar system has been a fascinating laboratory journey. Here, we summarize the history and major findings of the USGS GHPL in Menlo Park, including both in-house research as well as findings from the synergistic collaborations with other agencies and institutes that were key to the success of our laboratory. The Menlo Park GHPL was more formally incorporated within the USGS Gas Hydrates Project, a collaboration among multiple USGS Science Centers, in the early 2000s under the leadership of Deborah Hutchinson, and now under the leadership of Carolyn Ruppel and Timothy Collett.

Open-File Report↗
USGS2023

Porosity, strength, and alteration – Towards a new volcano stability assessment tool using VNIR-SWIR reflectance spectroscopy

Volcano slope stability analysis is a critical component of volcanic hazard assessments and monitoring. However, traditional methods for assessing rock strength require physical samples of rock which may be difficult to obtain or characterize in bulk. Here, visible to shortwave infrared (350–2500 nm; VNIR–SWIR) reflected light spectroscopy on laboratory-tested rock samples from Ruapehu, Ohakuri, Whakaari, and Banks Peninsula (New Zealand), Merapi (Indonesia), Chaos Crags (USA), Styrian Basin (Austria) and La Soufrière de Guadeloupe (Eastern Caribbean) volcanoes was used to design a novel rapid chemometric-based method to estimate uniaxial compressive strength (UCS) and porosity. Our Partial Least Squares Regression models return moderate accuracies for both UCS and porosity, with R 2 of 0.43–0.49 and Mean Absolute Percentage Error (MAPE) of 0.2–0.4. When laboratory-measured porosity is included with spectral data, UCS prediction reaches an R 2 of 0.82 and MAPE of 0.11. Our models highlight that the observed changes in the UCS are coupled with subtle mineralogical changes due to hydrothermal alteration at wavelengths of 360–438, 532–597, 1405–1455, 2179–2272, 2332–2386, and 2460–2490 nm. These mineralogical changes include mineral replacement, precipitation hydrothermal alteration processes which impact the strength of volcanic rocks, such as mineral replacement, precipitation, and/or silicification. Our approach highlights that spectroscopy can provide a first order assessment of rock strength and/or porosity or be used to complement laboratory porosity-based predictive models. VNIR-SWIR spectroscopy therefore provides an accurate non-destructive way of assessing rock strength and alteration mineralogy, even from remote sensing platforms.

Earth and Planetary Science Letters↗
USGS1991

Numerical simulations of hydrothermal circulation resulting from basalt intrusions in a buried spreading center

A two-dimensional, one by two-kilometer section through the seafloor was simulated with a numerical model to investigate coupled fluid and heat flow resulting from basalt intrusions in a buried spreading center. Boundary and initial conditions and physical properties of both sediments and basalt were constrained by field surveys and drilling in the Guaymas Basin, central Gulf of California. Parametric variations in these studies included sediment and basalt permeability, anisotropy in sediment permeability, and the size of heat sources. Faults were introduced through new intrusions both before and after cooling. Background heat input caused fluid convection at velocities ≤ 3 cm a −1 through shallow sediments. Eighty to ninety percent of the heat introduced at the base of the simulations exited through the upper, horizontal surface, even when the vertical boundaries were made permeable to fluid flow. The simulated injection of a 25–50 m thick basalt intrusion at a depth of 250 m resulted in about 10 yr of pore-fluid expulsion through the sea-floor in all cases, leaving the sediments above the intrusions strongly underpressured. A longer period of fluid recharge followed, sometimes accompanied by reductions in total seafloor heat output of 10% in comparison to pre-intrusion values. Additional discharge-recharge events were dispersed chaotically through the duration of the cooling period. These cycles in heat and fluid flow resulted from the response of the simulated system to a thermodynamic shock, the sudden emplacement of a large heat source, and not from mechanical displacement of sediments and pore fluids, which was not simulated. Water/rock mass ratios calculated from numerical simulations are in good agreement with geochemical estimates from materials recovered from the Guaymas Basin, assuming a bulk basalt permeability value of at least 10 −17 m 2 /(10 −2 mD). The addition of faults through intrusions and sediments in these simulations did not facilitate continuous, rapid venting. Increased heat input at the base of the faults resulted in temporarily greater fluid discharge, but the flow could not be sustained because the modeled system could not recharge cold fluid quickly enough to remove sufficient heat through the vents.

Earth and Planetary Science Letters↗