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Test of airborne fluorometer over land surfaces and geologic materials

Response of an experimental Fraunhofer line discriminator(FLD) to a wide range of surficial deposits common in deserts and semideserts was tested in the laboratory and from an 1-1-19 helicopter. By design the instrument sensed radiation from the ground specifically at the sodium D2 Fraunhofer line (5890 angstroms). It is capable of detecting a fluorescence component emanating from ground targets irradiated by sunlight along the line of flight, provided the aircraft is nearly level. However, no signals attributable to fluorescence were recorded during 540 miles of aerial traverses over southeastern California and west-central Arizona. It is concluded that exposed surfaces of target materials throughout the traverses were either non-luminescent at 5890 A or not sufficiently so to be detectable. It cannot be ruled out that the lack of fluorescence is partly attributable to surficial coatings of non-luminescent weathered material. The principal route surveyed from the air was from Needles, California to Furnace Creek Ranch, Death Valley and return via the Amargosa River valley, Silurian Lake (dry), Silver Lake (dry), and Soda Lake (dry). Principal targets traversed were unconsolidated elastic sediments ranging from silty clay to cobbles, and a wide range of evaporite deposits. Evaporite minerals thought to have been viewed in high concentrations are halite (sodium chloride), gypsum (hydrous calcium sulfate), probably other sulfate minerals, borax and probably ulexite (hydrous sodium borates), possibly colemanite (hydrous calcium borate), and probably some carbonate minerals. Extensive manganese-rich outcrops midway between Needles and Prescott had to be by-passed because of low sun-angles, cloudiness, and a heavy load in relation to altitude (above 5,000 feet). Several of the more common evaporite minerals were tested under the FLD on the ground, while being irradiated by bright sunlight. Minerals tested were chiefly from salt fiats (salars) in the Atacama Desert of northern Chile, and included halite, gypsum, ulexite, thenardite (sodium sulfate), aragonite (calcium carbonate) and nitrate ore containing soda niter (sodium nitrate). Crude oil from the Santa Barbara leak was tested in its natural state and in solutions of methyl-isobutyl-ketone (MIBK). Petroliferous sandstone samples containing both high and moderate concentrations of oil were tested on both fresh and weathered surfaces. No response definitely attributable to fluorescence at 5890 A was noted from any of the foregoing geologic materials, although a possible very weak response to one oil sample in MBK solution appears on the record. Although no fluorescence was detected, the mechanical operation of the FLD was satisfactory throughout 8 hours of flight, with attendant vibrations, and during a wide range of sun angles, from 13° to 33°. In accord with design, the FLD showed no appreciable response to moderate contrasts in reflectivity among targets, although there was a marked response to strong contrasts in reflectivity. Airborne tests also established that a minimum instrumental warm-up time of seven minutes is required, and that response is not entirely independent of either the vertical angle (tilt) or horizontal angle (flight direction) of the aircraft.

Open-File Report

Ostracods and facies of the Early and Middle Frasnian at Devils Gate in Nevada: Relationship to the Alamo Event

In order to document the Alamo Event and to investigate its influence on shallow-marine environments, we undertook a study of ostracods, conodonts, and analysis of the sedimentology of the lower member of the type Devils Gate Limestone, Six major carbonate microfacies (MF1-MF6) ranging from open-marine environments below storm wave base to pre-evaporitic supratidal lagoons were recognized. The sedimentological study detected no important sedimentological changes during the Alamo Event; only an influx of detrital material and lithoclasts indicate that an unusual event had occurred. Ostracods are generally rare or absent in the lower member of the Devils Gate Limestone, and only 2,000 carapaces, valves and fragments were extracted; from these some 26 taxa were identified. Two new species, Voronina? eureka and Serenida dorsoplicata are proposed. The ostracods belong to the Eifelian Mega-Assemblage and their distribution was influenced by strong salinity variations. Because of the rarity and low diversity of ostracods and conodonts in samples collected from the lower part of the lower member of the Devils Gate Limestone it is not adequate to demonstrate conclusively an extinction event close to the Alamo Event Bed. Nevertheless the greater abundance and diversity of ostracods above this bed seems to indicate that the Alamo Event did not result in significant extinction of ostracod taxa in this shallow water setting. The ostracod fauna present in the lower member of the Devils Gate Limestone suggests faunal exchanges between Nevada and the Russian Platform via the Western Canadian platform.

Nevada

Geology and genesis of the Shalipayco evaporite-related Mississippi Valley-type Zn–Pb deposit, Central Peru: 3D geological modeling and C–O–S–Sr isotope constraints

The Shalipayco Zn–Pb deposit, in central Peru, is composed of several stratabound orebodies, the largest of which are the Resurgidora and Intermedios, contained in carbonate rocks of the Upper Triassic Chambará Formation, Pucará group. Petrography suggests that a single ore-forming episode formed sphalerite and galena within vugs, open spaces, and fractures. Three-dimensional (3D) geological modeling has allowed division of the Chambará Formation into four members (Chambará I, II, III, and IV) that better define lithological controls on sulfide formation. Diagenetic replacement of evaporite minerals with the organic matter (OM) presence likely generated secondary porosity and H 2 S accumulation by bacterial sulfate reduction (BSR), providing ground preparation for the later Zn–Pb mineralizing event. The least-altered host rocks have C–O isotope compositions of 1.8 ± 0.1‰ (VPDB) and 29.9 ± 2.1‰ (VSMOW), respectively, within the Triassic marine carbonate ranges. Early dolomite contains lighter C–O composition (1.1 ± 0.9 and 23.8 ± 2.9‰, respectively) consistent with OM decomposition during burial diagenesis. Post-mineralization calcite has still lighter C–O composition (− 5.1 and 13.3‰, respectively), suggesting meteoric water that had migrated through organic-rich strata. The strontium isotopes of Mitu group basalts (0.709654–0.719669) indicate it as a possible, but not the unique source of strontium and probably of other metals. Highly negative sulfide sulfur isotope values (− 23.3 to − 6.2‰ (VCDT)) indicate a major component of the ore sulfur derived ultimately from BSR. However, multiple lines of evidence suggest that preexisting H 2 S underwent thermochemical redox cycling prior to ore formation. The influx of hot metalliferous brines to dolomitized zones containing trapped H 2 S is the preferred model for ore deposition at Shalipayco.

Mineralium Deposita

Genesis of the Assif El Mal Zn-Pb (Cu, Ag) vein deposit. An extension-related Mesozoic vein system in the High Atlas of Morocco. Structural, mineralogical, and geochemical evidence

The Assif El Mal Zn-Pb (Cu-Ag) vein system, located in the northern flank of the High Atlas of Marrakech (Morocco), is hosted in a Cambro-Ordovician volcaniclastic and metasedimentary sequence composed of graywacke, siltstone, pelite, and shale interlayered with minor tuff and mudstone. Intrusion of synorogenic to postorogenic Late Hercynian peraluminous granitoids has contact metamorphosed the host rocks giving rise to a metamorphic assemblage of quartz, plagioclase, biotite, muscovite, chlorite, amphibole, chloritoid, and garnet. The Assif El Mal Zn-Pb (Cu-Ag) mineralization forms subvertical veins with ribbon, fault breccia, cockade, comb, and crack and seal textures. Two-phase liquid-vapor fluid inclusions that were trapped during several stages occur in quartz and sphalerite. Primary inclusion fluids exhibit T h mean values ranging from 104??C to 198??C. Final ice-melting temperatures range from -8.1??C to -12.8??C, corresponding to salinities of ???15 wt.% NaCl equiv. Halogen data suggest that the salinity of the ore fluids was largely due to evaporation of seawater. Late secondary fluid inclusions have either Ca-rich, saline (26 wt.% NaCl equiv.), or very dilute (3.5 wt.% NaCl equiv.) compositions and homogenization temperatures ranging from 75??C to 150??C. The ?? 18 O and ??D fluid values suggest an isotopically heterogeneous fluid source involving mixing between connate seawater and black-shale-derived organic waters. Low ?? 13 C VPDB values ranging from -7.5??? to -7.7??? indicate a homogeneous carbon source, possibly organic matter disseminated in black shale hosting the Zn-Pb (Cu-Ag) veins. The calculated ?? 34 S H2S values for reduced sulfur (22.5??? to 24.3???) are most likely from reduction of SO 4 2- in trapped seawater sulfate or evaporite in the host rocks. Reduction of sulfate probably occurred through thermochemical sulfate reduction in which organic matter was oxidized to produce CO 2 which ultimately led to precipitation of saddle dolomite with isotopically light carbon. Lead isotope compositions are consistent with fluid-rock interaction that leached metals from the immediate Cambro-Ordovician volcaniclastic and metasedimentary sequence or from the underlying Paleo-Neoproterozoic crustal basement. Geological constraints suggest that the vein system of Assif El Mal formed during the Jurassic opening of the central Atlantic Ocean. ?? Springer-Verlag 2009.

Mineralium Deposita

Ground-water quality in the eastern part of the Silurian-Devonian and upper Carbonate aquifers in the eastern Iowa basins, Iowa and Minnesota, 1996

Ground-water samples were collected from 33 domestic wells to assess the water quality of the eastern part of the Silurian-Devonian and Upper Carbonate aquifers in the Eastern Iowa Basins National Water-Quality Assessment Program study unit. Samples were collected during June and July 1996 and analyzed for major ions, nutrients, pesticides and pesticide metabolites, volatile organic compounds, tritium, radon222, and environmental isotopes. Calcium, magnesium, and bicarbonate were the dominant ions in most samples and were likely derived from the solution of carbonate minerals (calcite and dolomite) present in the aquifer materials. The dominance of sulfate in samples from several wells suggests the dissolution of evaporite minerals. Ammonia and orthophosphorus were the most commonly detected nutrients. Nitrate was detected in about half of the samples and exceeded the U.S. Environmental Protection Agency maximum contaminant level (10 milligrams per liter) in 6 percent of samples. Atrazine and metolachlor were the only pesticides detected and were present in 18 percent and 12 percent of samples, respectively. Alachlor ethanesulfonic acid and deethylatrazine were the most commonly detected pesticide metabolites and were present in 16 percent and 9 percent of samples, respectively. Radon-222 was detected in all samples, and 47 percent had concentrations in excess of the U.S. Environmental Protection Agency previously proposed maximum contaminant level (300 picocuries per liter). Radon-222 concentrations were significantly higher in samples from wells that produced recently recharged water. This relation suggests that uranium-bearing glacial deposits (Schumann, 1993) may be a source of radon-222 in the underlying aquifers. The presence of regional confining units and thick overlying Quaternary-age deposits have an effect on water quality in the Silurian-Devonian and Upper Carbonate aquifers in the study area. Tritium-based ground-water ages were significantly older, and dissolved-solids concentrations were significantly higher in relatively well protected areas (where the aquifers are overlain by a bedrock confining unit or more than 100 feet of Quaternary-age deposits). Ammonia concentrations were significantly higher in relatively well protected areas and in samples from wells that produced older water. Higher ammonia concentrations also were observed in ground water with dissolved-oxygen concentrations of 0.5 milligram per liter or less, allowing for the anaerobic reduction of nitrate to ammonia. Nitrate concentrations were significantly higher in relatively poorly protected areas (where the aquifers are not overlain by a bedrock confining unit or are overlain by less than 100 feet of Quaternaryage deposits) and in samples from wells that produced recently recharged water. Pesticide and metabolite concentrations were significantly higher in samples from wells that produced recently recharged water. Atrazine, metolachlor, and deethylatrazine were not detected in any samples from relatively well protected areas of the aquifers.

Iowa, Minnesota

Hydrostratigraphic subdivisions and fault barriers of the Edwards aquifer, south-central Texas, U.S.A.

The karstic Edwards Limestone within the Balcones Fault Zone of south-central Texas forms a productive confined aquifer that consists predominately of dense carbonate rocks and contains several layers of highly permeable and porous honeycombed rocks that have been produced by the leaching of evaporitic, tidal flat or reefal deposits. Fractures have hydraulically interconnected these layers at some places. Faults, however, commonly place rocks of very high-permeability opposite rocks of very low permeability, thus creating a lateral discontinuity and a flow barrier. At places, fault barriers probably cause partial to almost complete blockage of groundwater flow normal to the fault.

Texas

Isotopic studies of epigenetic features in metalliferous sediment, Atlantis II Deep, Red Sea

The unique depositional environment of the Atlantis II Deep brine pool in the Red Sea produces a stratiform metalliferous deposit of greater areal extent than deposits formed by buoyant-plume systems typical of the midocean ridges because of much more efficient metal entrapment. Isotopic analyses of strontium, sulfur, carbon, and oxygen from the metalliferous sediments indicate that three major sources contribute dissolved components to the hydrothermal system: seawater, Miocene evaporites, and rift-zone basalt. An areally restricted magnetite-hematite-pyroxene assemblage formed at high temperatures, possibly in response to hydrothermal convection initiated by intrusion of basalt into the metalliferous sediment. A correlation between smectite Fe/(Fe+Mg) ratios and oxygen isotope temperatures suggests that smectite is a potentially important chemical geothermometer, and confirms geochemical calculations indicating that Mg-rich smectite is more stable than Fe-rich smectite at elevated temperatures.

Canadian Mineralogist

Hard mineral resources around the U.S continental margin

The territorial waters surrounding the United States contain vast quantities of hard mineral resources. Some, such as sand and gravel in the New York Bight, Beaufort Sea, portions of southern California, and submerged lands near Hawaii are relatively well known and characterized by local need and immediate mining potential with available technology. Commoditie of interest to industry and having nearterm economic potential that might require new or innovative technology, inlcude phosphorites such as those in the south eastern Atlantic margin, and manganese nodules on the Blake Plateau (which have potential for catalyst material, manganese, cobalt, nickel, and platinum). Commodities having significant potential, but which are poorly known and which may require innovative recovery technology, include chrome, gold, platinum, and tin placer deposits, with special emphasis on the continental margins of northern California, Oregon, Washington, and Alaska; rock salt and evaporite minerals in the Gulf of Mexico and Atlantic; titanium and other heavy minerals in the Atlantic continental margin, and calcium carbonate. A. U.S. Department of the Interior moratorium on offshore leasing in federal waters has existed since 1968. Leasing and regulatory systems will be required to begin commercial mining or intensive exploration of the above resources

Conference Paper

Tectonic framework and Late Cenozoic tectonic history of the northern part of Cyprus: Implications for earthquake hazards and regional tectonics

Located near the triple junction of the African, Arabia, and Eurasian Plate, Cyprus has had an active and complex neotectonic history, which includes devastating historical earthquakes. Investigations into the tectonic framework of the northern part of Cyprus provide important insights into regional tectonism of the Eastern Mediterranean and Middle East. The northern part of Cyprus is divided into two tectono-stratigraphic terranes, the boundary of which is the Ovgos fault zone. In the Middle Miocene, the Ovgos fault zone was a marine platform margin, which separated open-marine platform carbonates from deep-marine turbidites. Transpressive movement along easterly and northeasterly trending structures dominated the Late Miocene; deposition and preservation of Messinian evaporites occurred in grabens at intersections of these trends. N–S compression began in the Early Pliocene and produced contractional tectonism along east–west trends, including major thrusting of allochthonous rocks in the Kyrenia Range. Quaternary deformation has been dominated by strike-slip faults along northeast and northwest trends; movement during the Pleistocene occurred on several of these faults; Holocene movement is documented on one of these faults. A seismic hazard is implied for the Nicosia area because its proximity to the Quaternary faults. Since the Miocene, Cyprus has been continuously uplifted, but the tectonic setting is controversial, as some researchers invoke a subduction zone setting and others ascribe to a regime of strike-slip tectonics. Our neotectonic framework is consistent with a restraining bend model for Cyprus in a regional strike-slip regime.

Journal of Asian Earth Sciences

Petroleum geology and resources of the Volga-Ural province, U.S.S.R.

The Volga-Ural petroleum province is, in general, coincident with the Volga-Ural regional high, a broad upwarp of the east-central part of the Russian (East European) Platform. The central part of the province is occupied by the Tatar arch, which contains the major share of the oilfields of the province. The Komi-Perm arch forms the northeastern part of the regional high, and the Zhigulevsko-Pugachev and Orenburg arches make up the southern part. These arches are separated from one another by elongate downwarps. The platform cover overlies an Archean crystalline basement and consists of seven main sedimentation cycles. (1) Riphean (lower Bavly) continental sandstone, shale, and conglomerate beds, from 500 to 5,000 m thick, were deposited in aulacogens. (2) Vendian (upper Bavly) continental and marine shale and sandstone are up to 3,000 m thick. (3) Middle Devonian-Tournaisian transgressive deposits, which are sandstone, siltstone, and shale in the lower part and carbonates and abundant reefs in the upper part, range from 300 to 1,000 m in thickness. The upper carbonate part includes the Kamsko-Kinel trough system, which consists of narrow, interconnected, deepwater troughs. (4) The Visean-Namurian-Bashkirian cycle began with deposition of Visean clastic deposits, which draped over reefs of the previous cycle and filled in an erosional relief that had formed in some places on the sediments of the previous cycle. The Visean clastic deposits are overlain by marine carbonate beds. The cycle is from 50 to 800 m thick. (5) The lower Moscovian-Lower Permian cycle consists of 1,000 to 3,000 m of terrigenous clastic deposits and marine carbonate beds. (6) The upper Lower Permian-Upper Permian cycle reflects the maximum growth of the Ural Mountains and the associated Ural foredeep. Evaporite deposits were first laid down, followed by marine limestones and dolomites, which intertongue eastward with clastic sediments from the Ural Mountains. (7) Continental red beds of Triassic age and mixed continental and marine clastic beds of Jurassic and Cretaceous age were deposited on the western, southwestern, and northern margins of the Russian Platform; they are generally absent in the Volga-Ural province, however. Approximately 600 oilfields and gasfields and 2,000 pools have been found in the Volga-Ural province. Nine productive sequences are recognized; these are, in general, the same as the sedimentation cycles, although some subdivisions have been added. The clastic section of Middle and early Late Devonian age contains the major recoverable oil accumulations, including the supergiant Romashkino field. Cumulative production to 1980 is estimated at 30 to 35 billion barrels of oil equivalent, identified reserves at about 10 billion barrels of oil equivalent, and undiscovered resources at about 7 billion barrels of oil equivalent. Identified reserves of natural gas are estimated at 100 trillion cubic feet and undiscovered resources at 63 trillion cubic feet.

Circular

Dolomitization model for Upper Cambrian and Lower Ordovician carbonate rocks in the eastern United States

Existing models for dolomitization emphasize that penecontemporaneous dolomitization can occur in both subtidal and supratidal environments if the necessary chemical and physical factors favorable for the development of magnesium-rich hypersaline waters exist. Holocene shallow-water hypersaline environments that have the potential to produce dolomite without deposition of more soluble evaporite minerals are found in Shark Bay, Australia, and on the Great Bahama Bank. These hypersalinity systems are characterized by near-vertical isosalinity layers of increasing concentration landward from the open ocean and show little or no relationship to bottom topography. I suggest that a similar but larger scale epicontinentalsalinity system covering the Late Cambrian and Early Ordovician carbonate continental shelf produced a broad wedge of subtidally deposited dolomite in the eastern half of the United States from Mexico to Canada. The distribution of limestone and dolomite in this region is closely keyed to the salinity gradient and accounts for the natural progression from a normal marine limestone facies through a transition zone to a highly saline dolomite facies phase. Algal stromatolite mats and domes occupied low-energy niches in both the limestone and dolomite facies, whereas stratiform algal stromatolites were confined to the areas of moderate energy within the dolomite facies.

Journal of Research of the U.S. Geological Survey

Salt deposits in Los Medanos area, Eddy and Lea Counties, New Mexico

The salt deposits of Los Medanos area, in Eddy and Lea Counties, southeastern New Mexico, are being considered for possible use as a receptacle for radioactive wastes in a pilot-plant repository. The salt deposits of the area. are in three evaporite formations: the Castile, Salado, and Rustler Formations, in ascending order. The three formations are dominantly anhydrite and rock salt, but some gypsum, potassium ores, carbonate rock, and fine-grained clastic rocks are present. They have combined thicknesses of slightly more than 4,000 feet, of which roughly one-half belongs to the Salado. Both the Castile and the Rustler are-richer in anhydrite-and poorer in rock salt-than the Salado, and they provide this salt-rich formation with considerable Protection from any fluids which might be present in underlying or overlying rocks. The Salado Formation contains many thick seams of rock salt at moderate depths below the surface. The rock salt has a substantial cover of well-consolidated rocks, and it is very little deformed structurally. Certain geological details essential for Waste-storage purposes are unknown or poorly known, and additional study involving drilling is required to identify seams of rock salt suitable for storage purposes and to establish critical details of their chemistry, stratigraphy, and structure.

New Mexico

History of the Redwall Limestone of northern Arizona

Throughout most of northern Arizona the Redwall Limestone of Mississippian age is readily divisible into four lithologic units, designated in ascending order as the Whitmore Wash, Thunder Springs, Mooney Falls, and Horseshoe Mesa Members. The first and third members are thick-bedded to massive carbonate rock. The Horseshoe Mesa Member is relatively thin-bedded limestone, and the Thunder Springs Member is distinctive because it consists of chert beds alternating with thin beds of carbonate rock. Trends in thickness of the various members indicate that the sediment that formed the Redwall was deposited on an even, gently sloping shelf that extended westward from the Defiance positive element, a low landmass located near the present eastern border of northern Arizona. The Peach Springs and Payson ridges projected west and southwest, respectively, from the positive element. These ridges, which were partly submerged and partly above sea level during Mississippian time, are indicated by the patterns of isopach lines and, in part, by the distribution of faunas. The ridges divided the Arizona section of the shelf into three segments: the northern-most, which slopes northwest toward the Cordilleran geosyncline, and the other two, which slope toward the south and southwest. Two transgressions and two regressions of the western and southern seaways are believed to be represented by the Redwall. The first transgression, which is recorded by thick beds of clastic sediment of the Whitmore Wash Member, was less extensive than the second, which is recorded by massive beds of the Mooney Falls Member, for on the western margins of the Defiance positive element the Mooney Falls Member overlaps the two lower members. Furthermore, south of Grand Canyon the Whitmore Wash and Thunder Springs Members lap against the Payson ridge without covering it, whereas the Mooney Falls Member, although relatively thin, extends across it. Regression is believed to be represented by thin beds of the Thunder Springs and Horseshoe Mesa Members, which are interpreted to be the result of low base level caused by silting up with clastic material and consequent retreat of the sea. Cycles in sedimentation are well developed in some parts of the Redwall, especially in the upper two members in which differences in grain size represent five major cycles recognized throughout the extent of the Grand Canyon. These textural differences, ranging from aphanitic to coarse grained, are considered to be not measures of the amount of transportation, as with terrigenous sediments, but reflections of the degree of turbulence or the lack of turbulence during deposition. They are interpreted as indicators of cyclic fluctuations in environment, probably related to changes in wave base. Several clearly defined facies within the Redwall indicate environments of deposition. The clastic limestone that forms a major part of the formation, especially in the offshore areas to the west and south, is believed to represent normal marine conditions where circulation was good and turbulence moderate to strong. Uniform finely crystalline dolomite probably developed through early diagenetic processes on the sea floor. On the basis of its distribution pattern the dolomite seems to have formed under shoal conditions, especially where it borders the shore of the Defiance positive element and along Peach Springs ridge. Oölitic limestone at the top of both major transgressive units is interpreted as reflecting the oscillatory conditions of sea level that provided wave and current agitation at times of maximum sea advance in shoal areas bordering the ridges. Aphanitic limestone, representing accumulations of lime mud, seems to be developed best in the uppermost, or Horseshoe Mesa, member, where, as the seas regressed, nearshore waters may have been isolated and certainly were very calm. Original textures and some structures are preserved in most limestones of the Redwall, and they give much evidence concerning oceanographic factors of the time. Generalizations have been developed concerning the character of the bottom, degrees of energy represented, depth, salinity, and other factors for various parts of the formation. Although these factors differed greatly with time and space, the general conclusions reached are that (1) depths were very shallow to moderate, (2) the sea floor was composed nearly entirely of lime mud and lime sand, which contained no terrigeneous material but with great crinoidal accumulations locally, (3) turbulence ranged from considerable to none, and (4) the sea was clear and warm and nowhere contained saline concentrations sufficient to form evaporites. Chert forming thin irregular beds, locally lenticular and nodular, occurs at two prinicpal positions in the stratigraphic section, and in each it alternates with thin beds of carbonate rock. Chert is prominent throughout the Thunder Springs Member and forms thin but definite zones near the top of the Mooney Falls Member. This chert is believed to have formed on the sea floor during early diagenesis, as evidenced by petrography, paleogeography, and faunal relations. Regional differences in the abundance and type of associated fossils, recorded on a series of 4-foot-square sample plots made throughout the Grand Canyon, suggest a probable relation between fossil distribution and genesis of the chert. The fauna of the Redwall is abundant and varied, but preservation in many places is poor, and numerous specimens can be collected only locally. The most common fossils are brachiopods, corals, foraminifers, and crinoids, but blastoids, gastropods, cephalopods, and pelecypods are not rare. Bryozoans are abundant in the chert of the Thunder Springs Member but uncommon elsewhere. Other organisms locally distributed but not common are algae, trilobites, fish, holothurians, and ostracodes. These groups have been studied by specialists and are the subject of Chapters V through XIII. Certain of the faunal groups, notably the corals and foraminifers, show some degree of vertical zoning and so have furnished important data on age and correlation. Among the corals, the zones of Dorlodotia inconstans and Michelinia expansa are especially significant because of their persistence from section to section across broad areas. The foraminiferal zones are broader and less sharply defined, but they represent a series of major changes in species from bottom to top of the formation. Age determination made on the basis of foraminifers and brachiopods indicate that the base of the Redwall is progressively younger as it passes from areas that were offshore eastward or northward toward the Defiance positive element; the top of the Redwall, in contrast, is shown to be progressively younger away from the positive element. Thus basal beds of Kinderhook age are recognized at Grand Wash, Quartermaster, and Meriwitica Canyons to the northwest, but the lowest strata are of Osage age at Bridge Canyon, Grandview, and other sections closer to the landmass. Likewise, units with fossils of middle Meramec age occur in western Grand Canyon, but, except in the one place discussed in the following paragraph, topmost beds farther east in Grand Canyon are of Osage age. South of Grand Canyon the youngest member of the Redwall (Horseshoe Mesa) has been removed by pre-Supai Formation erosion. Rocks still younger than the Horseshoe Mesa once may have covered the entire region, possibly representing a third sequence of transgression and regression. At Bright Angel trail in eastern Grand Canyon, for example, a unique unit at the top of the Redwall section contains fossils of Chester age and apparently represents a remnant of Late Mississippian rocks that survived as an inlier there.

Arizona

Salt deposits of the paradox basin, southeast Utah and southwest Colorado

Thick salt deposits are present in the Middle Pennsylvanian Paradox Member of the Hermosa Formation in the Paradox Basin of southeast Utah and southwest Colorado . Data suggest that the original thickness of these deposits was from 5000-6000 feet. Locally, however, these deposits have been subjected to intense deformation and flow, resulting in thicknesses as great as 14,000 feet. Each salt bed is part of a series of partial and complete evaporite cycles which show a lateral and vertical change in facies. Varve counts in the salt beds give an indication of deposition rates of time-equivalent carbonate beds. Black sapropelic shales are interbedded with the salt beds. It appears that the euxinic environment in which the shales were deposited persisted during the deposition of salt . An understanding of the stratigraphy of the salt deposits has made possible a more complete depiction of early tectonic events involving the salt basin . These studies indicate that many of the salt anticlines in the basin were formed along trends of originally thick salt beds, and that upward growth of these anticlines possibly began during the late stages of salt deposition.

Utah, Colorado

Fluorine

Fluorine compounds are essential in numerous chemical and manufacturing processes. Fluorspar is the commercial name for fluorite (isometric CaF 2 ), which is the only fluorine mineral that is mined on a large scale. Fluorspar is used directly as a fluxing material and as an additive in different manufacturing processes. It is the source of fluorine in the production of hydrogen fluoride or hydrofluoric acid, which is used as the feedstock for numerous organic and inorganic chemical compounds. The United States was the world’s leading producer of fluorspar until the mid-1950s. In the mid-1970s, the U.S. fluorspar mining industry began to decline because of foreign competition. By 1982, there was essentially only a single U.S. producer left, and that company ceased mining in 1996. Consumption of fluorspar in the United States peaked in the early 1970s, which was also the peak period of U.S. steel production. Since then, U.S. fluorspar consumption has decreased substantially; the United States has nonetheless increased its imports of downstream fluorine compounds, such as, in order of tonnage imported, hydrofluoric acid, aluminum fluoride, and cryolite. This combination of no U.S. production (until recently) and high levels of consumption has made the United States the world’s leading fluorspar-importing country, in all its various forms. The number of fluorspar-exporting countries has decreased substantially in recent decades, and, as a result, the United States has become dependent on just a few countries to supply its needs. In 2013, the United States imported the majority of its fluorspar from three countries, which were, in descending order of the amount imported, Mexico, China, and South Africa. Geologically, in igneous systems, fluorine is one of a number of elements that are “incompatible.” These incompatible elements become concentrated in the residual magma while the common silicates crystallize upon magma ascent and cooling, leading to relatively high fluorine concentrations in the more evolved or differentiated igneous rocks and in hydrothermal deposits associated with those evolved igneous rocks. In sedimentary rocks, fluorine’s highest concentrations are found in phosphorites because fluorine substitutes for hydroxyl ions in apatite, which leads to fluorine concentrations of, typically, from 2 to 4 weight percent in phosphorites. Because of the presence of fluorine, phosphate fertilizer manufacturers can produce a fluorosilicic acid byproduct. Most deposits mined for fluorine are hydrothermal, however, and consist of fluorine minerals that precipitated from hot water. Magmatic brines and brines from deep within sedimentary basins that have high concentrations of dissolved fluoride are the mineralizing fluids for various types of hydrothermal fluorspar deposits. Relatively dilute hydrothermal fluids that formed in some volcanic rocks can also transport sufficient fluoride to form a high-grade fluorspar deposit. Fluorite has low solubility in a common range of hydrothermal temperatures, particularly from about 160 degrees Celsius (°C) down to 60 °C. The increasing fluorite solubility below 60 °C partly explains why some water with exceptionally high levels of dissolved fluorine are found even at ambient temperatures in evaporitic lake basins in some East African Rift valleys in Kenya and Tanzania. The geologic conditions that led to the high concentrations there are known to exist in a number of other places in the world as well, including, perhaps, places in the Basin and Range province of the United States. Eight minerals or mineral groups have sufficient fluorine in their structures to be considered as possible ores of the element; they are bastnaesite (also spelled bastnäsite; and other fluorocarbonates), cryolite, sellaite, villiaumite, fluorite, fluorapatite (in phosphorites), various phyllosilicates, and topaz. Fluorite is currently the only mineral that is mined for fluorine, and nomineral except fluorite is likely to become a source of commercially produced fluorine as a primary product as long as supplies from relatively thick and high-grade fluorite deposits continue to be available. At least seven classes (which include one subclass) of hydrothermal fluorite deposits are recognized; they are classified according to their tectonic and (or) magmatic settings, as follows: (1) carbonatite-related fluorspar deposits; (2) alkaline-intrusion-related fluorspar deposits; (3) alkaline-volcanic-related epithermal fluorspar deposits; (4) Mississippi Valley-type fluorspar deposits (and a subclass of salt-related carbonate-hosted fluorspar deposits); (5) fluorspar deposits related to strongly differentiated granites; (6) subalkaline-volcanic-related epithermal fluospar deposits; and (7) fluorspar deposits that appear to be conformable within tuffaceous limy lacustrine sediments. An eighth class (not hydrothermal) is that of fluorspar deposits concentrated in soils and weathered zones; that is, residual fluorspar deposits. Generally, fluorspar deposits related to strongly differentiated granites have larger tonnages and lower grades than carbonatite-related fluorspar deposits, which, in turn, have larger tonnages and lower grades than fluorspar vein deposits from various other classes. The United States has a few identified resources of fluorspar, most notably the Klondike II property in the Illinois- Kentucky fluorspar district located about 8 kilometers southwest of Salem, Kentucky, which has a large vein that contains at least 1.6 million metric tons at a grade of 60 percent CaF 2 (Feytis, 2009). Additional fluorspar resources of lower grade but larger tonnage have been identified at Hicks Dome in the Illinois-Kentucky fluorspar district and at Lost River near the western tip of the Seward Peninsula in Alaska, along with a couple of dozen smaller, higher grade resources. Internationally, new mines that either opened before the beginning of 2013 or were scheduled to open soon after that time include the Nui Phao tungsten-fluorspar-bismuth-copper-gold deposit in northern Vietnam; the St. Lawrence project in Newfoundland, Canada, which is located in a well-known fluorspar district; the Bamianshan deposit, which is related to a strongly differentiated granite in northwestern Zhejiang Province, China, near some of that Province’s large, subalkaline-volcanic-related epithermal veins; and the Nokeng project in South Africa, which is also related to a strongly differentiated granite. Other deposits in northwestern Australia, Nevada (United States), Norway, South Africa, and Sweden have been identified and could be put into production within just a few years. Among undiscovered resources, an interesting possibility might be to produce a fluorine product from evaporitic, high-fluorine, high-pH sodium-carbonate brines like Lake Magadi (Kenya) and Lake Natron (Tanzania) in Africa’s Eastern Rift Valley. In addition, apparently conformable fluorspar deposits in tuffaceous limy lacustrine sediments, such as those in Italy, are likely to occur in similar young alkalic volcanic settings elsewhere in the world. Modern geophysical and geochemical exploration techniques have typically not been brought to bear in exploration for new fluorspar deposits, although such techniques are likely to be used in future exploration. The tendency for fluorine to dissolve in significant concentrations in water at low temperature allows both surface water and groundwater to be used as sampling media in geochemical exploration. Evolved granite-related fluorspar deposits may be particularly susceptible to geophysical exploration methods because crystalline rocks that form a basement to sedimentary sections can be approximately defined with gravity and magnetic methods, and magnetite-bearing skarns can be directly detected with magnetic surveys. Environmental considerations of fluorine mining focus especially on drinking water, where high fluorine concentrations can lead to tooth decay; dental and skeletal fluorosis; and bone and cartilage conditions, including genu valgum, which is the crippling bone deformity more commonly known as knock knee. Trace amounts of other elements in fluorspar ores are a concern at some deposits; for example, high beryllium concentrations in alkaline-volcanic-related epithermal deposits or high cadmium concentrations associated with Mississippi Valley-type and salt-related carbonate-hosted fluorspar deposits. Future research might include testing whether fluorine can be extracted economically from high-pH, sodium-carbonate brines and exploring for new occurrences of apparently conformable fluorspar deposits in tuffaceous limy lacustrine sediments outside of the Latium Region of Italy. Other promising new areas of research could be studies of fluorspar deposit fluid inclusion compositions by quadrupole mass spectrometry, by noble gas mass spectrometry on irradiated fluid inclusions, or by chlorine isotopes, while also measuring the chemistry of the same fluid inclusions either by bulk crush-and-leach methods or by laser ablation-inductively coupled plasma mass spectrometry. Advanced studies of fluid inclusion chemistry could be applied beneficially to some of the enigmatic large epithermal fluorspar veins at various places in the world, where they might determine those deposits’ possible relationships to igneous intrusions, or to dissolved salt, or to heated meteoric water in volcanic sections, or perhaps to all three. This knowledge could help focus new exploration.

Professional Paper

Hydrogeology and water-quality characteristics of the Lower Floridan aquifer in east-central Florida

The hydrogeology and water-quality characteristics of the Lower Floridan aquifer and the relation of the Lower Floridan aquifer to the framework of the Floridan aquifer system were evaluated during a 6-year (1995-2001) study. The study area, a 7,500 square-mile area of east-central Florida, is underlain by three principal hydrogeologic units: the surficial aquifer system, the intermediate confining unit, and the Floridan aquifer system. The Floridan aquifer system, a carbonate-rock aquifer system composed of the Upper Floridan aquifer, a middle semiconfining unit, a middle confining unit, and the Lower Floridan aquifer, is the major source of water supply to east-central Florida. The Upper Floridan aquifer provides much of the water required to meet the current (2002) demand; however, the Lower Floridan aquifer is being used increasingly as a source of freshwater, particularly for municipal needs. For this reason, a better understanding of the aquifer is needed. The Lower Floridan aquifer is present throughout east-central Florida. The aquifer is composed of alternating beds of limestone and dolomite, and is characterized by abundant fractured dolomite zones and solution cavities. The altitude of the top of the Lower Floridan aquifer ranges from less than 600 feet below sea level in the northern part of the study area to more than 1,600 feet below sea level in the southwestern part. Thickness of the unit ranges from about 910 to 1,180 feet. The top of the Lower Floridan aquifer generally is marked by an increase in formation resistivity and by an increase in the occurrence of fractures and solution cavities within the carbonates. Also, a noticeable increase in borehole flow often marks the top of the unit. The bottom of the Lower Floridan aquifer is based on the first occurrence of evaporites. Ground-water in the Lower Floridan aquifer generally moves in a southwest-to-northeast direction across the study area. In September 1998, the altitude of the potentiometric surface of the Lower Floridan aquifer ranged from about 16 to 113 feet above sea level, and altitudes in May 1999 were about 2 to 7 feet lower than those measured in September 1998. The potentiometric surface of the Floridan aquifer system is constantly fluctuating, mainly in response to seasonal variations in rainfall and ground-water withdrawals. Seasonal fluctuations in the Lower Floridan aquifer typically range from about 2 to 10 feet. Water samples from 50 Lower Floridan aquifer wells were collected during this study. Most samples were analyzed in the field for temperature, pH, and specific conductance, and in the laboratory for major cations and anions. Specific conductance ranged from 147 to 6,710 microsiemens per centimeter. Chloride concentrations ranged from 3.0 to 2,188 milligrams per liter; sulfate concentrations ranged from 0.2 to 750 milli-grams per liter; and hardness ranged from 69 to 940 milligrams per liter. Water was least mineralized in the recharge areas of the Lower Floridan aquifer in the western part of the study area. The most mineralized water in the Lower Floridan aquifer occurred along parts of the Wekiva and St. Johns Rivers and in much of the eastern and southern parts of the study area. The altitude of the base of freshwater in the Floridan aquifer system (where chloride concentrations are equal to 250 milligrams per liter) is variable throughout the study area. The estimated position of the 250 milligram per liter isochlor surface is less than 200 feet below sea level in much of the eastern part of the study area, including the areas along the St. Johns River in Lake, Seminole, and Volusia Counties and near the Wekiva River in western Seminole County. The altitude of the 250 milligram per liter isochlor exceeds 3,000 feet below sea level in the extreme southwestern part of the study area.

Water-Resources Investigations Report

Geology of Paleozoic Rocks in the Upper Colorado River Basin in Arizona, Colorado, New Mexico, Utah, and Wyoming, Excluding the San Juan Basin

The geology of the Paleozoic rocks in the Upper Colorado River Basin in Arizona, Colorado, New Mexico, Utah, and Wyoming, was studied as part of the U.S. Geological Survey's Regional Aquifer-System Analysis Program to provide support for hydrogeological interpretations. The study area is segmented by numerous uplifts and basins caused by folding and faulting that have recurred repeatedly from Precambrian to Cenozoic time. Paleozoic rocks in the study area are 0-18,000 feet thick. They are underlain by Precambrian igneous, metamorphic, and sedimentary rocks and are overlain in most of the area by Triassic formations composed mostly of shale. The overlying Mesozoic and Tertiary rocks are 0-27,000 feet thick. All Paleozoic systems except the Silurian are represented in the region. The Paleozoic rocks are divisible into 11 hydrogeologic units. The basal hydrogeologic unit consisting of Paleozoic rocks, the Flathead aquifer, predominantly is composed of Lower to Upper Cambrian sandstone and quartzite. The aquifer is 0-800 feet thick and is overlain gradationally to unconformably by formations of Cambrian to Mississippian age. The Gros Ventre confining unit consists of Middle to Upper Cambrian shale with subordinate carbonate rocks and sandstone. The confining unit is 0-1,100 feet thick and is overlain gradationally to unconformably by formations of Cambrian to Mississippian age. The Bighom aquifer consists of Middle Cambrian to Upper Ordovician limestone and dolomite with subordinate shale and sandstone. The aquifer is 0-3,000 feet thick and is overlain unconformably by Devonian and Mississipplan rocks. The Elbert-Parting confining unit consists of Lower Devonian to Lower Mississippian limestone, dolomite, sandstone, quartzite, shale, and anhydrite. It is 0-700 feet thick and is overlain conformably to unconformably by Upper Devonian and Mississippian rocks. The Madison aquifer consists of two zones of distinctly different lithology. The lower (Redwall-Leadville) zone is 0-2,500 feet thick and is composed almost entirely of Upper Devonian to Upper Mississippian limestone, dolomite, and chert. The overlying (Darwin-Humbug) zone is 0-800 feet thick and consists of Upper Mississippian limestone, dolomite, sandstone, shale, gypsum, and solution breccia. The Madison aquifer is overlain conformably by Upper Mississippian and Pennsylvanian rocks. The Madison aquifer in most areas is overlain by Upper Mississippian to Middle Pennsylvanian rocks of the Four Comers confining unit. The lower part of this confining unit, the Belden-Molas subunit, consists of as much as 4,300 feet of shale with subordinate carbonate rocks, sandstone, and minor gypsum. The upper part of the confining unit, the Paradox-Eagle Valley subunit, in most places consists of as much as 9,700 feet of interbedded limestone, dolomite, shale, sandstone, gypsum, anhydrite, and halite. Locally, the evaporitic rocks are deformed into diapirs as much as 15,000 feet thick. The Four Corners confining unit is overlain gradationally to disconformably by Pennsylvanian rocks. The uppermost Paleozoic rocks comprise the Canyonlands aquifer, which is composed of three zones with distinctly different lithologies. The basal (Cutler-Maroon) zone consists of as much as 16,500 feet of Lower Pennsylvanian to Lower Permian sandstone, conglomerate, shale, limestone, dolomite, and gypsum. The middle (Weber-De Chelly) zone consists of as much as 4,000 feet of Middle Pennsylvanian to Lower Permian quartz sandstone with minor carbonate rocks and shale. The upper (Park City-State Bridge) zone consists of as much as 800 feet of Lower to Upper Permian limestone, dolomite, shale, sandstone, phosphorite, chert, and gypsum. The Canyonlands aquifer is overlain disconformably to unconformably by formations of Triassic and Jurassic age.

Professional Paper

HELIOTHERMAL LAKE MODEL OF BORATE DEPOSITION IN THE MIOCENE FURNACE CREEK FORMATION, DEATH VALLEY REGION, CALIFORNIA.

Heliothermal lakes are density-stratified with shallow submerged margins surrounding areally restricted deep pool(s) containing a dense brine overlain by a much less dense brine. The reflective brine interface allows solar energy to be trapped in the dense brine which may warm to over 90 degree C. Carbonate precipitated from the dense brine is the typical sediment produced in warm deep pool. Miocene borate deposits of the Death Valley region are typically contained within areally limited carbonate-rich pods that interfinger with a finely interlaminated (varve-like) mudstone and limestone. Primary borates there are predominately either Na-Ca borates or Ca-borates. This bimodal evaporite assemblage suggests that brine chemistries and (or) crystallization paths varied significantly in temporally and spatially related portions of this apparently continuous lacustrine deposit.

Conference Paper