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At least 91 records · Page 5Linked to original sources
USGS1991

Quartz solubility in hydrothermal seawater: An experimental study and equation describing quartz solubility for up to 0.5 M NaCl solutions

Experimental investigations confirm an increase of quartz solubility in sea-water relative to distilled water. Combination of the experimental data with published data, most of which related to distilled water, permitted construction of a database for calculating an equation that fits all the data. Application of the equation indicates a shallower depth of circulation for sea- floor hydrothermal waters than has previously been calculated. Use of the equation as a quartz geothermometer-geobarometer has applications not only for hydrothermal sea-water systems, but also for other geothermal and geological systems.

American Journal of Science↗
USGS1991

Densities of liquids and vapors in boiling NaCl-H2O solutions: a PVTx summary from 300° to 500°C

Experimental data for densities of liquids and vapors on the two-phase surface of the system NaCl-H 2 O were compiled and evaluated to provide a complete summary between 300 ° and 500 ° C. The results are added to a previously published PTx summary compiled in the same manner to provide a PVTx summary of the present state of knowledge. Results are in table form of use to the understanding of two-phase behaviour in boiling hydrothermal systems and to theoretical modeling of this important system.

American Journal of Science↗
USGS1991

Brine evolution and mineral deposition in hydrologically open evaporite basins

A lumped-parameter, solute mass-balance model is developed to define the role of water outflow from a well-mixed basin. A mass-balance model is analyzed with a geochemical model designed for waters with high ionic strengths. Two typical waters, seawater and a Na-HCO3 ground water, are analyzed to illustrate the control that the leakage ratio (or hydrologic openness of the basin) has on brine evolution and the suite and thicknesses of evaporite minerals deposited. The analysis suggests that brines evolve differently under different leakage conditions. -from Authors

American Journal of Science↗
USGS1995

Abnormal pressures as hydrodynamic phenomena

So-called abnormal pressures, subsurface fluid pressures significantly higher or lower than hydrostatic, have excited speculation about their origin since subsurface exploration first encountered them. Two distinct conceptual models for abnormal pressures have gained currency among earth scientists. The static model sees abnormal pressures generally as relict features preserved by a virtual absence of fluid flow over geologic time. The hydrodynamic model instead envisions abnormal pressures as phenomena in which flow usually plays an important role. This paper develops the theoretical framework for abnormal pressures as hydrodynamic phenomena, shows that it explains the manifold occurrences of abnormal pressures, and examines the implications of this approach.

American Journal of Science↗
USGS1996

Raman spectroscopic characterization of gas mixtures. II. Quantitative composition and pressure determination of the CO2-CH4 system

Raman spectral parameters were determined for the v 1 band of CH4 and the v 1 and 2 v 2 bands (Fermi diad) of CO 2 in pure CO 2 and CO 2 -CH 4 mixtures at pressures up to 700 bars and room temperature. Peak position, area, height, and width were investigated as functions of pressure and composition. The peak positions of the CH 4 and CO 2 bands shift to lower relative wavenumbers as fluid pressure is increased. The peak position of the lower-wavenumber member of the Fermi diad for CO 2 is sensitive to fluid composition, whereas the peak positions of the CH 4 band and the upper Fermi diad member for CO 2 are relatively insensitive in the CO 2 -CH 4 system. The magnitude of the shifts in each of the three peak positions (as a function of pressure) is sufficient to be useful as a monitor of fluid pressure. The relative molar proportions in a CO 2 -CH 4 mixture may be determined from the peak areas: the ratio of the peak areas of the CH 4 band and the CO 2 upper Fermi diad member is very sensitive to composition, whereas above about 100 bars, it is insensitive to pressure. Likewise, the peak height ratio is very sensitive to composition but also to fluid pressure. The individual peak widths of CO 2 and CH 4 , as well as the ratios of the widths of the CH 4 peak to the CO 2 peaks are a sensitive function of pressure and, to a lesser extent, composition. Thus, upon determination of fluid composition, the peak width ratios may be used as a monitor of fluid pressure. The application of these spectral parameters to a suite of natural CO 2 -CH 4 inclusions has yielded internally-consistent, quantitative determinations of the fluid composition and density.

American Journal of Science↗
USGS1996

40Ar/39Ar whole-rock data constraints on Acadian diagenesis and Alleghanian cleavage in the Martinsburg formation, eastern Pennsylvania

A comparison of 40 Ar/ 39 Ar age spectra of whole-rock mudstone and slate samples from the Ordovician Martinsburg Formation at Lehigh Gap, Pennsylvania and stratigraphic and thermal constraints support Alleghanian age for regional slaty cleavage and a late Acadian age for diagenesis in these rocks. Age spectra from mud-stones have a sigmodal shape, with slopes that climb steeply from apparent Mesozoic ages to intermediate saddle regions with Devonian apparent ages, and then climb steeply again to Late Proterozoic apparent ages. The steps with these oldest apparent ages are interpreted to be dominated by late Proterzoic detrial muscovite. The saddle region of the mudstone samples gives very Late Silurian to earliest Devonian ages, which are maximum ages of diagenetic micas and which eliminate a Taconic age for the cleavage. The ages of saddle regions of the slate samples constraining cleavage-forming muscovite is <~375. This is the maximum age of this mica and requires an Alleghanian age for the cleavage. These age constraints are supported by ages of individual mica components calculated with knowledge of the total gas ages and mass fractions of the micas and by predictions from thermal modeling. We conclude that the Taconic orogeny in the Martinsburg Formation in eastern Pennsylvania was a very mild event. Not only is the cleavage in these rocks not Taconic in age, but even the mild (~100C) diagenetic growth of illite was Silurian of younger. Thus the Taconic event in these rocks in limited to loading of lass than about 3 km.

Connecticut, Delaware, Maryland, Pennsylvania, New↗
USGS1996

Pb and O isotopic constraints on the source of granitic rocks from Cape Breton Island, Nova Scotia, Canada

Pb isotopic compositions of leached feldspars from twenty-three plutons in Cape Breton Island can be divided into two groups: anorthosite, syenite, and granite in the Blair River Complex, which have the least radiogenic compositions on the Island, and granitic rocks from terranes (Aspy, Bras d'Or, and Mira) to the south. Pb isotopic data for the Blair River Complex ( 206 Pb/ 204 Pb = 17.399-18.107; 207 Pb/ 204 Pb = 15.505-15.560; 208 Pb/ 204 Pb = 36.689-37.733) are consistent with an old source region ultimately derived from the mantle and contaminated by sialic crust. Oxygen isotopic compositions of syenite in the Blair River Complex ( δ 18 O = +8.0 to +8.5 permil) are slightly higher than anorthosite (+7.0 to +8.3 permil); a Silurian granite in the Blair River Complex has δ 18 O = +7.5 permil. Cambrian to Devonian plutons in the Aspy, Bras d'Or, and Mira terranes are more radiogenic ( 206 Pb/ 204 Pb = 18.192-18.981; 207 Pb/ 204 Pb = 15.574-15.712; 208 Pb/ 204 Pb =37.815-38.936) than the Blair River Complex and were generated from source regions having a predominant crustal Pb signature (high μ ). The δ 18 O values of granites and granodiorites in the Aspy terrane (+7.5 to +9.2 permil; avg = +8.6 permil) and Bras d'Or (+3.7 to +11.3 permil; avg = +9.4 permil) are also consistent with involvement of sialic crust. Many Late Proterozoic granites from the Mira terrane have anomalously low δ 18 O values (+0.2 to +5.9 permil), perhaps produced from protoliths that had undergone hydrothermal alteration prior to melting. Paleozoic granitic rocks from the Aspy, Bras d'Or, and Mira terranes cannot be uniquely distinguished on the basis of their Pb and O isotopic compositions. The granitic rocks could have been generated during terrane amalgamation from combinations of unradiogenic (Grenville-like) and more radiogenic (Avalon-like) sources.

Nova Scotia↗
USGS1996

Petrology and U-PB geochronology of the Robertson River Igneous Suite, Blue Ridge province, Virginia - Evidence for multistage magmatism associated witn an early episode of Laurentian rifting

The Late Neoproterozoic (735-702 Ma) Robertson River Igneous Suite includes at least eight plutons ranging in composition from syenogranite to alkali feldspar granite to alkali feldspar syenite. These plutons intruded Mesoproterozoic (1.2-1.0 Ga) gneissic basement of the Blue Ridge anticlinorium in northern and central Virginia during an early episode of Laurentian rifting. Robertson River plutons range in composition from metaluminous to peralkaline and, relative to other granite types, exhibit compositional characteristics of A-type granitoids including (1) marked enrichment in Nb, Zr, Y, REE (except Eu), and Ga, (2) high Ga/Al and FeO (total) /MgO, and (3) depletion of Ba and Sr. High Ga/Al ratios are particularly diagnostic of the suite and serve as an effective discriminant between originally metaluminous and peralkaline bulk compositions, providing a useful proxy for widely used indicators based on major elements that are prone to remobilization. U-Pb isotopic analyses of zircons indicate that the suite was emplaced in two pulses, occurring at 735 to 722 and 706 to 702 Ma. Metaluminous magmas were emplaced during both pulses, formed most of the main batholith, and fractionated as independent, time-correlative groups. Peralkaline magmas were emplaced only during the final pulse, formed a volcanic center that erupted unknown quantities of rhyolite, and experienced a style of fractionation similar to the metaluminous types. Differences in Ce/Nb, Y/Nb, and Yb/Ta ratios suggest that the metaluminous and peralkaline magmas were derived from different sources. The Robertson River Igneous Suite is part of a regional group of Late Neoproterozoic (760-700 Ma) plutons including at least 20 other A-type granitoid bodies exposed throughout the Laurentian terrane of Virginia and northwestern North Carolina. Like the Robertson River, most of the other granitoids are metaluminous in composition, typically form multi-intrusive, elongate plutons, and are not geographically constrained to the vicinity of major Neoproterozoic volcanic centers. The Late Neoproterozoic plutons of the Laurentian Appalachians are similar in lithology, composition, and style of emplacement to Miocene granitoids that occur on the southern flanks of the present Red Sea rift and that are considered a younger analog of the Appalachian plutons. However, the Red Sea granitoids were emplaced within a few million years of the initial development of oceanic crust whereas the Appalachian plutons appear largely to have pre-dated development of the Iapetus Ocean by about 130 my.

Virginia↗
USGS1997

A geologic history of the north-central Appalachians. Part 1. Orogenesis from the Mesoproterozoic through the Taconic orogeny

The north-central Appalachians lie just southwest of the boundary between the central/southern and northern Appalachians, occupying a critical position within the 3000+ km-long Appalachian orogen. The history of tectonic activity in the north-central Appalachians spans more than one billion years, from the assembly and breakup of a Neoproterozoic supercontinent, through active orogenesis during Laurentia's Paleozoic northward journey off the western margin of West Gondwana, to the Mesozoic transformation of the active orogen into a passive margin during Pangea's disassembly. The major tectonic events include five compressional orogenies and two extensional episodes: 1. The late Mesoproterozoic Grenville orogeny assembled several continental masses into the Neoproterozoic supercontinent, Rodinia. It was the most widespread but now least exposed tectonism, and rocks involved in this event underlie as basement most of the exposed north-central Appalachians. Large fragments of Laurentian Grenville rock were subsequently broken off and incorporated in later Appalachian orogenesis. 2. Crustal extension and rifting late in the Neoproterozoic and into the earliest Cambrian separated Laurentia from West Gondwana, thereby forming the intervening Theic ocean and two continental rifts on Laurentia's eastern margin, the Catoctin rift and, later in the Middle? to Late Cambrian, the so-called "Rome" trough. The initial siliciclastic sedimentation on the margin migrated westward through time onto the craton, supplanted by a thick and increasingly wide carbonate shelf on Laurentia's eastern margin. Two microcontinents of Grenville-age, non-Laurentian(?) continental rock became positioned east of Laurentia, thereby creating the Octoraro sea as an arm of Theia. 3. In Theia, east of the two microcontinents, magmatic arcs developed over a subduction zone late in the Cambrian. Convergence within Theia caused the Potomac orogeny, which obduced the arcs (Wilmington Complex, Cecil Amalgamate) over the microcontinents and associated Theic deposits (including accretionary wedge sediments). 4. Continued westward convergence collapsed the Octoraro sea, producing the Middle to Late Ordovician Taconic orogeny in which the Potomac-deformed magmatic arcs and associated Theic elements were obduced onto the Laurentian continental margin. This obduction: drowned the carbonate shelf with siliciclastic sediments (Martinsburg Formation); drove continental rise and basinal deposits over the carbonate shelf on the Martic thrust; slid the Hamburg klippe onto the shelf; and accreted the Potomac package of microcontinent/arc/basinal-sediments onto the Laurentian margin. This orogeny transformed the broad Early Paleozoic carbonate shelf into the Appalachian basin that persisted throughout the Middle and Late Paleozoic. 5. The Middle Devonian Acadian orogeny ended the largely paralic environment that dominated the Appalachian basin during the Late Silurian. Active orogenesis in New England probably extended southward to the north-central Appalachians, because a vast amount of terrigenous sediment was introduced into the Appalachian basin to form the Catskill delta; however, evidence of actual Acadian deformation and metamorphism is lacking at this latitude. These presumed internal Acadides have yet to be found. 6. The convergence of West Gondwana and Laurentia during the Late Carboniferous and earliest Permian produced the Permian Alleghany orogeny in the north-central Appalachians. This widespread decollement tectonism directly affected a larger area of the presently exposed central and southern Appalachians than any earlier Paleozoic tectonic event. An early layer-parallel shortening phase gave way to a fold-thrust development above a basal decollement. This Alleghany fold-and-thrust tectonism created long, arcuate folds in the Appalachian basin. Late in the Alleghany orogeny, rock thrust northward over the Carboniferous rocks in the Anthracite region of northeastern Pennsylvania caused anthracitization of the underlying coals. The internal Alleghanides are not presently exposed. 7. Crustal extension in the Late Triassic and Early Jurassic produced numerous local, closed basins along eastern North America. Igneous intrusions and effusions marked the beginning of the Jurassic. By the end of the Early Jurassic, horizontal crustal rebound in response to opening of the Atlantic Ocean rotated the basins by crustal inversion, which folded some within-basin rocks and produced a prominent topographic ridge along the Piedmont, up-dip of the basins. Subsequent erosion of this Piedmont ridge and other parts of the Appalachian orogen fed large volumes of sediment to offshore basins during the remainder of the Mesozoic and throughout the Cenozoic. Each of these orogenies affected most of the Appalachian orogen. The tectonic expression of each orogeny varied along and across the orogen. The elements and structural bodies involved in each also varied along strike. However, many common elements persist from one part of the orogen to another; only a few features are singular in time and space. The tectonic boundary between the central and northern Appalachians is one of these singular features-it is solely an Alleghanian artifact.

American Journal of Science↗
USGS1997

A geologic history of the north-central Appalachians, part 2: The Appalachian basin from the Silurian through the Carboniferous

The north-central Appalachians occupy a critical position within the 3000+ km-long Appalachian orogen, lying southwest of the boundary between the central and northern Appalachians (CNAB). The one-billion-year-long history of tectonic activity in the north-central Appalachians includes the assembly and breakup of a late Proterozoic supercontinent, the creation and evolution of the Appalachian orogen during the Paleozoic, and the Mesozoic transformation of the active orogen into a passive margin during Pangea's disassembly. An important part of the Middle and Late Paleozoic history is the formation and growth of the Appalachian basin, an enormous, elongate continental basin lying cratonward of the active Appalachian internides along Laurentia's eastern margin. The Appalachian basin developed out of the Taconic orogeny, the second of the four orogenies that formed and modified the character of the Appalachian orogen. Prior to the Taconic orogeny, the eastern margin of Laurentia consisted of a broad carbonate shelf facing the Theic Ocean. The Taconic orogeny obduced various Theic components, including microcontinents, magmatic arcs, and accretionary prisms, onto the carbonate shelf. The resulting Taconic highlands formed a topographic barrier between Theia and the craton's interior. Because tectonic activity in the internides continued more or less throughout the remainder of the Paleozoic, the Appalachian basin never had a direct connection with Theia. The coarse-grained molasse from the newly uplifted Taconic highland spread westward over most of the basin during the Early Silurian. Carbonate deposition gradually encroached eastward over the basin as the siliciclastic input from the southeast waned. A resurgence in the earliest Late Silurian, perhaps related to orogenesis in Newfoundland and the Maritimes, expanded the clastic wedge somewhat. Before long, however, carbonate deposition once again dominated most of the north-central basin for the remainder of the Silurian and into the Early Devonian. The Early-to-Middle Devonian Acadian orogeny began introducing siliciclastic material into the eastern part of the Appalachian basin, thereby ending the largely paralic environment that persisted from the Late Silurian. A number of deltas formed around local sediment-input centers during the Middle Devonian. Continued uplift and/or orogenesis must have continued into the Late Devonian because a vast amount of terrigenous sediment was introduced into the Appalachian basin to form the vast Upper Devonian Catskill delta. Although the principal tectonic activity appears to have centered in New England, the large volume of sediment input suggests that orogenesis may have extended southward to the north-central Appalachians. However, direct evidence of actual Acadian deformation and metamorphism is lacking at this latitude. The north-central Appalachian basin underwent a significant change during the Carboniferous. Prior to this time, the shoreline shifted laterally through transgressions and regressions largely as a function of sediment input and regional subsidence. In the Carboniferous, vertical movements in the basin became more important. During the Early Carboniferous, much of the Mauch Chunk delta was eroded in the central and western parts of the basin. At the end of the Early Carboniferous, an unconformity truncated progressively older rocks to the north toward New York. New sediment transport patterns and depositional environments within the basin during the Late Carboniferous probably reflect significant topographic and tectonic changes, not only in the hinterland, but in the basin itself, perhaps in conjunction with climatic changes. Extensive interfluvial swamps on a lower delta plain accumulated thick organic deposits which would become coal. This delta plain graded southwestward into tidal and marine environments. The Alleghany orogeny in the Early Permian interrupted deposition in much of the north-central Appalachian basin and profoundly altered its structure.

American Journal of Science↗
USGS1998

Numerical analysis of seawater circulation in carbonate platforms: I. Geothermal convection

Differences in fluid density between cold ocean water and warm ground water can drive the circulation of seawater through carbonate platforms. The circulating water can be the major source of dissolved constituents for diagenetic reactions such as dolomitization. This study was undertaken to investigate the conditions under which such circulation can occur and to determine which factors control both the flux and the patterns of fluid circulation and temperature distribution, given the expected ranges of those factors in nature. Results indicate that the magnitude and distribution of permeability within a carbonate platform are the most important parameters. Depending on the values of horizontal and vertical permeability, heat transport within a platform can occur by one of three mechanisms: conduction, forced convection, or free convection. Depth-dependent relations for porosity and permeability in carbonate platforms suggest circulation may decrease rapidly with depth. The fluid properties of density and viscosity are controlled primarily by their dependency on temperature. The bulk thermal conductivity of the rocks within the platform affects the conductive regime to some extent, especially if evaporite minerals are present within the section. Platform geometry has only a second-order effect on circulation. The relative position of sealevel can create surface conditions that range from exposed (with a fresh-water lens present) to shallow water (with hypersaline conditions created by evaporation in constricted flow conditions) to submerged or drowned (with free surface water circulation), but these boundary conditions and associated ocean temperature profiles have only a second-order effect on fluid circulation. Deep, convective circulation can be caused by horizon tal temperature gradients and can occur even at depths below the ocean bottom. Temperature data from deep holes in the Florida and Bahama platforms suggest that geothermal circulation is actively occurring today to depths as great as several kilometers.

American Journal of Science↗