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At least 883 records · Page 49Linked to original sources

USGS1983

Strata-bound, silver-bearing iron, lead, and zinc sulfide deposits in Silurian and Ordovician rocks of allochthonous terranes, Nevada and northern Mexico

Allochthonous terranes in northern Nevada contain strata-bound sulfide deposits at two horizons in Silurian and Ordovician siliceous sedimentary rocks. The most intensively mineralized horizon and most extensive deposit is at the base of the Silurian. Another less extensive deposit is in the lower Middle Ordovician. Spectrographic analyses of gossan from the basal Silurian horizon indicate anomalously high values of lead and zinc; and in about 40 percent of the samples, silver values are anomalously high. Suhsurface samples contain the primary minerals pyrite, galena, and sphalerite. The basal Silurian deposits are in thick-bedded chert that is overlain by micaceous siltstone. They are underlain by a thick-bedded black chert unit of Late Ordovician age. The basal Silurian gossan has been identified also in southwestern Nevada and in northern Mexico in stratigraphic sequences very similar to that of northern Nevada.

Open-File Report↗

USGS2015

Geologic map of the Bodie Hills, California and Nevada

The Bodie Hills covers about 1,200 km 2 straddling the California-Nevada state boundary just north of Mono Lake in the western part of the Basin and Range Province, about 20 km east of the central Sierra Nevada. The area is mostly underlain by the partly overlapping, middle to late Miocene Bodie Hills volcanic field and Pliocene to late Pleistocene Aurora volcanic field (John and others, 2012). Upper Miocene to Pliocene sedimentary deposits, mostly basin-filling sediments, gravel deposits, and fanglomerates, lap onto the west, north, and east sides of the Bodie Hills, where they cover older Miocene volcanic rocks. Quaternary surficial deposits, including extensive colluvial, fluvial, glacial, and lacustrine deposits, locally cover all older rocks. Miocene and younger rocks are tilted ≤30° in variable directions. These rocks are cut by several sets of high-angle faults that exhibit a temporal change from conjugate northeast-striking left-lateral and north-striking right-lateral oblique-slip faults in rocks older than about 9 Ma to north- and northwest-striking dip-slip faults in late Miocene rocks. The youngest faults are north-striking normal and northeast-striking left-lateral oblique-slip faults that cut Pliocene-Pleistocene rocks. Numerous hydrothermal systems were active during Miocene magmatism and formed extensive zones of hydrothermally altered rocks and several large mineral deposits, including gold- and silver-rich veins in the Bodie and Aurora mining districts (Vikre and others, in press).

California, Nevada↗

USGS2005

Potential for formation of disinfection by-products from storage of chlorinated surface water in the Basalt aquifer near Fallon, Nevada

Increased pumpage from a basalt aquifer near Fallon, Nevada, has caused its water levels to decline and has induced changes in the quality of water pumped from the basalt. The aquifer is the sole source of water for municipal supply to the city of Fallon, the Naval Air Station Fallon, and the Fallon Paiute-Shoshone Tribe. These changes may be mitigated by storage of surface water in the basalt for subsequent use. Because chlorination of the surface water may be required for storage, the U.S. Geological Survey, in cooperation with the Fallon Paiute-Shoshone Tribe, made laboratory tests using laboratory carbon-organic-free water, surface-water, ground-water, and basaltic-rock samples to determine the potential for formation of disinfection by-products. Experiments with water samples only (no rock and no chlorine) indicated no change in dissolved-organic-carbon (DOC) concentrations over a 20-day reaction period; whereas, all experiments using rock, water, and no chlorine indicated an increase in DOC concentrations. The greatest increase in DOC concentrations for all three water samples occurred in experiments with the rock samples from outcrops on Rattlesnake Hill. Experiments with water only and chlorine yielded a total trihalomethane (THM) concentration of 97.4 ?g/L for the ground-water sample and 347 ?g/L for the surface-water sample. Experiments with mixtures of water, rocks, and chlorine indicated that reactions with the rock consumed chlorine and released significant amounts of organic carbon from the rock, increasing the DOC concentration in the water. The organic carbon in the rocks likely is associated with the secondary clay minerals that line vesicles and fractures in the rocks. THM concentrations were greatest, from 335 to 909 ?g/L, for surface water equilibrated with rock samples from Rattlesnake Hill. However, the concentration of chlorine required to produce these high THM concentrations ranged from 18 to 84 mg/L. The results of the experiments suggest that the amount of organic carbon released from the rocks during successive cycles of recharge, storage, and recovery of chlorinated surface water may be relatively small. The chlorine demand of the rocks is so large that all of the free chlorine in the entire volume of recharged water likely would be consumed by only a very small volume of the aquifer surrounding an injection well, or beneath an infiltration bed. The majority of the volume of the aquifer filled by the stored water likely would never come in contact with free chlorine, and the increases in concentration of DOC observed in these experiments likely would occur in a very small volume of the stored water. For this reason, increases in concentration of THMs for the entire volume of water stored also likely would be considerably less than those measured in these experiments. To test this hypothesis, additional laboratory experiments using varying levels of chlorination, varying lengths of reaction periods, and repeated cycles of chlorination would be useful. A field experiment made at a small scale in an isolated part of the basalt aquifer would aid in the design of an operational system.

Scientific Investigations Report↗

USGS1957

Reconnaissance for uranium and thorium in Alaska, 1954

During 1954 reconnaissance investigations to locate minable deposits of uranium and thorium in Alaska were unsuccessful. Areas examined, from which prospectors had submitted radioactive samples, include Cap Yakataga, Kodiak Island, and Shirley Lake. Unconcentrated gravels from the beach at Cape Yakataga average about 0.001 percent equivalent uranium. Uranothorianite has been identified by X-ray diffraction data and is the principal source of radioactivity in the Cape Yakataga beach sands studied; but the zircon, monazite, and uranothorite are also radioactive. The black, opaque uranothorianite generally occurs as minute euhedral cubs, the majority of which will pass through a 100-mesh screen. The bedrock source of the radioactive samples from Kodiak Island was not found; the maximum radioactivity of samples from the Shirley Lake area was equivalent to about 0.02 percent uranium. Radiometric traverses of the 460-foot level of the Garnet shaft of the Nixon Fork mine in the Nixon Fork mining district indicated a maximum of 0.15 mr/hr. In the Hot Springs district, drill hole concentrates of gravels examined contained a maximum of 0.03 percent equivalent uranium. A radioactivity anomaly noted during the Survey's airborne reconnaissance of portions of the Territory during 1954 is located in the Fairhaven district. A ground check disclosed that the radioactivity was due to accessory minerals in the granitic rock.

Alaska↗

USGS1957

Summary of reconnaissance for uranium in Alaska, 1955

Reconnaissance for uranium in Alaska during 1955 included airborne radiometric traverses, examination of radioactivity anomalies found during the airborne traverses, examination of prospector leads, and examination of areas that seems geologically favorable for the occurrence of uranium. The airborne radiometric traverses in central Alaska revealed 33 anomalies considered worth examining. The ground examinations of a few of these anomalies indicated that they were due to radiation of from accessory minerals in intrusive granitic rocks. The examination of prospector leads revealed several radioactivity anomalies of interest and one, near Bokan Mountain on prince of Wales Island, of possible commercial importance.

Alaska↗

USGS1996

Mineral intergrowths replaced by "elbow-twinned" rutile in altered rocks

Some aggregates of rutile, classically considered to be "elbow" twinned, instead are topotactic replacements of ilmenite or other hexagonal titaniferous precursors. Twinned rutile can be differentiated from the reticulated rutile of topotactic replacements by the angle of prism intersections, junction morphology, and the overall form of the aggregate. In a special case of topotactic replacement of ilmenite, rutile forms pseudomorphs of "trellis"-textured ilmenite lamellae in {111} of precursor magnetite. We trace the progress of rutile formation through the alteration of fine-grained magnetite-bearing host rocks. The sequential two-step topotaxy from magnetite through ilmenite to rutile requires rutile prisms to parallel the intersections of {111} planes in precursor magnetite. Some coarse reticulated rutile may result from the same paragenetic sequence.

Canadian Mineralogist↗

USGS1992

Monitoring radionuclide and suspended-sediment transport in the Little Colorado River basin, Arizona and New Mexico, USA

From July 1988 through September 1991, radionuclide and suspended-sediment transport were monitored in ephemeral streams in the semiarid Little Colorado River basin of Arizona and New Mexico, USA, where in-stream gross-alpha plus gross-beta activities have exceeded Arizona's Maximum Allowable Limit through releases from natural weathering processes and from uranium-mining operations in the Church Rock Mining District, Grants Mineral Belt, New Mexico. Water samples were collected at a network of nine continuous-record streamgauges equipped with microprocessor-based satellite telemetry and automatic water-sampling systems, and six partial-record streamgauges equipped with passive water samplers. Analytical results from these samples were used to calculate transport of selected suspended and dissolved radionuclides in the uranium-238 and thorium-232 decay series.

Arizona;New Mexico↗

USGS2014

Mineral resource of the month: vermiculite

Vermiculite comprises a group of hydrated, laminar magnesium-aluminum-iron silicate minerals resembling mica. They are secondary minerals, typically altered biotite, iron-rich phlogopite or other micas or clay-like minerals that are themselves sometimes alteration products of amphibole, chlorite, olivine and pyroxene. Vermiculite deposits are associated with volcanic ultramafic rocks rich in magnesium silicate minerals, and flakes of the mineral range in color from black to shades of brown and yellow. The crystal structure of vermiculite contains water molecules, a property that is critical to its processing for common uses. Using a process called exfoliation-in which vermiculite flakes are heated to 900 degrees Celsius or higher, causing water within the flakes to flash to steam and expand-crude vermiculite ore is processed into particles that are eight to 20 times larger. The resulting lightweight material is chemically inert and fire resistant, with low density and low thermal conductivity. It is also odorless, has high liquid absorption capacity and catalytic properties. Because it is lightweight and thermally insulating, vermiculite is used in general building plasters and concrete products, alone or combined with other lightweight aggregates such as perlite. Special plasters, in which vermiculite is combined with binders like gypsum or portland cement, fillers or other additives, provide fire protection and soundproofing. As insulation, exfoliated vermiculite, sometimes treated with a water repellent, is used to fill pores and cavities in masonry construction and hollow blockwork to enhance acoustic properties, fire rating and insulation performance. Exfoliated vermiculite can also be used to produce refractory and insulation concretes and mortars, and to make high-temperature binders for construction materials, gaskets, specialty papers, textiles and vehicle brake linings. Finer grades of exfoliated vermiculite can be used to produce various shapes of insulation pellets, high-temperature insulation, as a primary component in cementitious coatings, and as a filler in inks, paints, plastics and other materials. Vermiculite can absorb liquids such as fertilizers, herbicides and insecticides, which can then be transported as free-flowing solids. It is used in the fertilizer and pesticide markets because of its ability to act as a bulking agent, carrier and extender. In horticulture, exfoliated vermiculite improves soil aeration and moisture retention, and when mixed with peat or other composted materials, such as pine bark, vermiculite produces a good growing medium for plants. As a soil conditioner, exfoliated vermiculite improves aeration in clay-rich soils and water retention in sandy soils, while reducing the likelihood of compaction, cracking and crusting of the soil. For more information on the commercial use of vermiculite, visit minerals.usgs.gov/minerals/ .

Earth↗

USGS2014

Mineral resource of the month: Vermiculite

Earth↗

USGS1988

Mg/Mn partitioning as a test for equilibrium between coexisting Fe-Ti oxides

Partitioning of Mg and Mn between titanomagnetite and ferrian ilmenite of volcanic rocks provides a test for equilibrium between coexisting phases. A plot of log(Mg/Mn)-, vs. log(Mg/Mn),, for 213 homogeneous oxide pairs from volcanic rocks yields a straight line over more than two orders of magnitude variation in Mg/Mn. Analyses that plot within reasonable limits of analytical precision of this line are consistent with preservation of equilibrium compositions. The test appears to be valid for fresh volcanic rocks but may not be applicable to oxides in metamorphic, plutonic, and altered volcanic rocks in which oxide minerals typicatly have oxidized or exsolved at subsolidus temperatures. It can be used to discriminate between multiple populations of an oxide phase or to evaluate equilibration of inclusions in silicate phenocrysts for Fe-Ti oxide geothermometry and oxygen barometry.

American Mineralogist↗

USGS2016

Geochemistry of host rocks in the Howards Pass district, Yukon-Northwest Territories, Canada: implications for sedimentary environments of Zn-Pb and phosphate mineralization

Detailed lithogeochemical data are reported here on early Paleozoic sedimentary rocks that host the large Howards Pass stratiform Zn-Pb deposits in Yukon-Northwest Territories. Redox-sensitive trace elements (Mo, Re, V, U) and Ce anomalies in members of the Duo Lake Formation record significant environmental changes. During the deposition of lower footwall units (Pyritic siliceous and Calcareous mudstone members), bottom waters were anoxic and sulphidic, respectively; these members formed in a marginal basin that may have become increasingly restricted with time. Relative to lower members, a major environmental change is proposed for deposition of the overlying Lower cherty mudstone member, which contains phosphorite beds up to ∼0.8 m thick in the upper part, near the base of the Zn-Pb deposits. The presence of these beds, together with models for modern phosphorite formation, suggests P input from an upwelling system and phosphorite deposition in an upper slope or outer shelf setting. The overlying Active mudstone member contains stratabound to stratiform Zn-Pb deposits within black mudstone and gray calcareous mudstone. Data for unmineralized black mudstone in this member indicate deposition under diverse redox conditions from suboxic to sulphidic. Especially distinctive in this member are uniformly low ratios of light to heavy rare earth elements that are unique within the Duo Lake Formation, attributed here to the dissolution of sedimentary apatite by downward-percolating acidic metalliferous brines. Strata that overlie the Active member (Upper siliceous mudstone member) consist mainly of black mudstone with thin (0.5–1.5 cm) laminae of fine-grained apatite, recording continued deposition on an upper slope or outer shelf under predominantly suboxic bottom waters. Results of this study suggest that exploration for similar stratiform sediment-hosted Zn-Pb deposits should include the outer parts of ancient continental margins, especially at and near stratigraphic transitions from marginal basin facies to overlying slope or shelf facies.

Mineralium Deposita↗

USGS2002

Dinosaurs that did not die: Evidence for Paleocene dinosaurs in the Ojo Alamo Sandstone, San Juan Basin, New Mexico

Palynologic and paleomagnetic data confirm a Paleocene age for the Ojo Alamo Sandstone (and its contained dinosaurs) throughout the San Juan Basin of New Mexico. The recently reported discovery of 34 skeletal elements from a single hadrosaur in the Ojo Alamo provides unequivocal evidence that these bones were not reworked from underlying Cretaceous strata. Geochemical studies of samples from several single-dinosaur-bone specimens from the Paleocene Ojo Alamo Sandstone and the underlying Late Cretaceous (Campanian) Kirtland Formation show that mineralized bones from these two rock units contain distinctly different abundances of uranium and rare-earth elements and demonstrate that Cretaceous and Paleocene bones were mineralized at different times when mineralizing fluids had distinctly different chemical compositions. These findings indicate that the dinosaur bone from the Paleocene Ojo Alamo is indigenous and not reworked. These data show that a relatively diverse assemblage of dinosaurs survived the end-Cretaceous asteroid-impact extinction event of 65.5 Ma. The San Juan Basin’s Paleocene dinosaur fauna is herein named the Alamoan fauna. Magnetic-polarity chronology shows that these survivors lived for about one million years into the Paleocene and then became extinct around 64.5 Ma. We suggest that a plausible survival mechanism for this Lazarus fauna may have been the large numbers of buried dinosaur eggs, laid just before the asteroid impact occurred. These buried eggs would have provided a safe haven for developing dinosaur embryos for the first one to two years after the impact, thereby making it possible for them to survive the worst of the impact’s early devastation.

Colorado, New Mexico↗

USGS2018

Compositional variation in the chevkinite group: new data from igneous and metamorphic rocks

Electron microprobe analyses are presented of chevkinite-group minerals from Canada, USA, Guatemala, Norway, Scotland, Italy and India. The host rocks are metacarbonates, alkaline and subalkaline granitoids, quartz-bearing pegmatites, carbonatite and an inferred K-rich tuff. The analyses extend slightly the range of compositions in the chevkinite group, e.g. the most MgO-rich phases yet recorded, and we report two further examples where La is the dominant cation in the A site. Patchily- zoned crystals from Virginia and Guatemala contain both perrierite and chevkinite compositions. The new and published analyses are used to review compositional variation in minerals of the perrierite subgroup, which can form in a wide range of host rock compositions and over a substantial pressure- temperature range. The dominant substitutions in the various cation sites and a generalized substitution scheme are described.

Mineralogical Magazine↗

USGS2025

Petrogenesis and mineralization potential of spinifex komatiitic basalts in the Bradley Peak greenstone terrane, Wyoming Province

Komatiitic volcanic rocks are important hosts of Ni sulfide mineralization and record early Earth evolution; however, those in the well-studied Archean Wyoming Province have received little attention. Here, we elucidate the timing and petrogenesis of the Bradley Peak komatiitic volcanic rocks using field and textural observations, geochronology, and geochemistry. Detrital and igneous zircon U-Pb ages for two samples from previously undated units support published age determinations, placing the eruption age at 2.72 Ga. Stratigraphy of the volcanic flows was mapped and 36 samples including cumulates, greenschists, and spinifex-textured rocks were collected. Whole-rock geochemistry was used to classify the spinifex-textured samples as Al-undepleted komatiitic basalts (11–17 wt% MgO). Platinum-group element concentrations (n = 25) are like those in global Al-undepleted komatiitic basalts, and PGE/Ti ratios do not indicate the volcanic flows likely host sulfide mineralization. Initial ε Nd values of −0.5 to +4.7 (n = 16), indicate that these lavas were derived from a depleted mantle source and have negligible evolved crust contamination. The primary magma to the komatiitic basalt flows is estimated to have had 19 wt% MgO and be derived from ∼15 to 25 % mantle partial melting at 3–4 GPa. Trace element chemistry and thermodynamic modeling suggest the primary melt assimilated local banded iron formation. Although the Bradley Peak komatiitic basalts do not contain positive evidence of magmatic sulfide deposits, depleted Au in the flows suggests they could be source rocks for nearby orogenic gold deposits.

Wyoming↗

USGS2023

A review of geology and mining in the Marble Mountains, southeastern California

Mining in the Marble Mountains of southeastern California was active in the earliest 1900s and gradually declined to very few active mines by 1959. Most mining consisted of hard-rock prospects and mines, with a few soft-rock prospects and one mine. The Marble Mountains are a 10 km by 30 km, gently NE-dipping dipping structural block composed of Proterozoic plutonic and metamorphic rocks, Paleozoic sedimentary rocks, and Jurassic granitoids exposed along the western anti-dip slopes, and Miocene volcanic and sedimentary rocks exposed along the crest of the range and eastern dip slopes. Mineralization occurred in metamorphic aureoles of intrusions, along dikes, as contact metasomatic replacement bodies in carbonate rocks, or adjacent to or along thrust faults. Mineralization locally formed gold, copper, malachite, azurite, bornite, chalcopyrite, magnetite, specularite, limonite, quartz, epidote, actinolite, and garnet. Hard-rock prospects and mines are clustered into five locations. The mines are small open pits, a few consist of a shaft or two with a few adits, most are just a single shaft or adit. There are a few small open-pit marble mines, and one is an open pit fossil mine. Eight prospects were developed in the Miocene tuffaceous deposits; three in the northwest and five prospects, and a single adit, in the south. Most of the Marble Mountains are now in the Trilobite Wilderness or adjacent Areas of Critical Environmental Concern, and the area of the Golden Cycle district (Castle Mine area) and prospect areas in the southern part of the range are in the Mojave Trails National Monument. The Iron Hat mine, several nearby areas, and the Trilobite mine area are privately owned. No rock or mineral mines are currently active, but the Trilobite mine in the south end of the range is still open to the public.

California↗

USGS2008

User's Guide to Handlens - A Computer Program that Calculates the Chemistry of Minerals in Mixtures

HandLens is a computer program, written in Excel macro language, that calculates the chemistry of minerals in mineral mixtures (for example, in rocks, soils and sediments) for related samples from inputs of quantitative mineralogy and chemistry. For best results, the related samples should contain minerals having the same chemical compositions; that is, the samples should differ only in the proportions of minerals present. This manual describes how to use the program, discusses the theory behind its operation, and presents test results of the program's accuracy. Required input for HandLens includes quantitative mineralogical data, obtained, for example, by RockJock analysis of X-ray diffraction (XRD) patterns, and quantitative chemical data, obtained, for example, by X-ray florescence (XRF) analysis of the same samples. Other quantitative data, such as sample depth, temperature, surface area, also can be entered. The minerals present in the samples are selected from a list, and the program is started. The results of the calculation include: (1) a table of linear coefficients of determination (r2's) which relate pairs of input data (for example, Si versus quartz weight percents); (2) a utility for plotting all input data, either as pairs of variables, or as sums of up to eight variables; (3) a table that presents the calculated chemical formulae for minerals in the samples; (4) a table that lists the calculated concentrations of major, minor, and trace elements in the various minerals; and (5) a table that presents chemical formulae for the minerals that have been corrected for possible systematic errors in the mineralogical and/or chemical analyses. In addition, the program contains a method for testing the assumption of constant chemistry of the minerals within a sample set.

Open-File Report↗

USGS1959

Geology and uranium-vanadium deposits of the slick rock district, San Miguel and Dolores counties, Colorado

Sedimentary rocks known in the Slick Rock district in southwestern Colorado range in age from Devonian (?) to Cretaceous, and aggregate about 13,000 feet in maximum thickness. Important uranium-vanadium production has come from deposits in the Salt Wash member of the Morrison formation of Late Jurassic age. The sedimentary rocks are gently folded in the Dolores and Glade anticlines and the Disappointment syncline, and are cut by the Dolores fault zone in the north part of the district and by the Glade fault zone in the south part of the district . Principal fracture sets are oriented approximately parallel to the major faults. Detrital hematite, magnetite, and ilmenite in rocks of the Morrison formation not affected by epigenetic alteration contain appreciable amounts of several of the elements found in the ore deposits . Epigenetic alteration processes have bleached large volumes of rock and largely destroyed these minerals. Such alteration is spatially associated with the Dolores fault zone. Most of the known ore deposits are in the north part of the Slick Rock district in a belt called the Dolores ore zone. The zone lies along the Dolores fault zone but is wider than the fault zone. All known deposits are associated with abundant carbonaceous plant material. Uranium-vanadium deposits in the district are chiefly tabular to lenticular and are roughly parallel to the sedimentary bedding. Some ore bodies, however, are narrow, elongate, and curve sharply across bedding; these bodies have been called "rolls" by the miners. Mineral zoning is evident in some roll bodies; carbonates, goethite (altered from pyrite), selenides, and sulfides are commonly found in concentric layers at the concave edge of rolls. This zoning, and the relationship of roll ore bodies to sedimentary structures and lithology, suggest that ore was deposited at an interface between two solutions, possibly cool connate water and a warmer ore solution. On a district scale, copper and lead are distinctly most abundant in the ore deposits within and immediately adjacent to the Dolores fault zone, and less abundant in deposits toward the edge of the zone. Uranium-vanadium deposits in the district occur only in sandstone that is considered to be epigenetically altered, and the most extensive epigenetic changes have occurred close to ore bodies. It is concluded that ground water, heated and set into circulation near the end of Cretaceous time by igneous intrusions in the La Sal and other centers on the Colorado Plateau, picked up elements from sedimentary rocks where they had been faulted and fractured, and deposited the elements at solution interfaces where accumulations of carbonaceous material provided favorable chemical conditions for precipitation.

Colorado, Utah↗

USGS2006

Geology and reconnaissance stable isotope study of the Oyu Tolgoi porphyry Cu-Au system, South Gobi, Mongolia

The Oyu Tolgoi porphyry Cu-Au system in the South Gobi desert, Mongolia, comprises five deposits that extend over 6 km in a north-northeast-oriented zone. They occur in a middle to late Paleozoic are terrane and are related to Late Devonian quartz monzodiorite intrusions. The Hugo Dummett deposits are the northernmost and deepest, with up to 1,000 m of premineral sedimentary and volcanic cover rock remaining. They are the largest deposits discovered to date and characterized by high-grade copper (>2.5% Cu) and gold (0.5-2 g/t) mineralization associated with intense quartz veining and several phases of quartz monzodiorite intruded into basaltic volcanic host rocks. Sulfide minerals in these deposits are zoned outward from a bornite-dominated core to chalcopyrite, upward to pyrite ?? enargite and covellite at shallower depth. The latter high-sulfidation-state sulfides are hosted by advanced argillic alteration mineral associations. This alteration is restricted mainly to dacitic ash-flow tuff that overlies the basaltic volcanic rock and includes ubiquitous quartz and pyrophyllite, kaolinite, plus late dickite veins, as well as K alunite, Al phosphate-sulfate minerals, zunyite, diaspore, topaz, corundum, and andalusite. A reconnaissance oxygen-hydrogen and sulfur isotope study was undertaken to investigate the origin of several characteristic alteration minerals in the Oyu Tolgoi system, with particular emphasis on the Hugo Dummett deposits. Based on the isotopic composition of O, H, and S (??18O(SO4) = 8.8-20.1???, ??D = -73 to -43???, ??34S = 9.8-17.9???), the alunite formed from condensation of magmatic vapor that ascended to the upper parts of the porphyry hydrothermal system, without involvement of significant amounts of meteoric water. The isotopic data indicate that pyrophyllite (??18O = 6.5-10.9???, ??D = -90 to -106???) formed from a magmatic fluid with a component of meteoric water. Muscovite associated with quartz monzodiorite intrusions occurs in the core of the Hugo Dummett deposits, and isotopic data (??18O = 3.0-9.0???, ??D = -101 to -116%o) show it formed from a magmatic fluid with water similar in composition to that which formed the pyrophyllite. Mg chlorite (??18O = 5.5???, ??D = -126???) is a widespread mineral retrograde after hydrothermal biotite and may have formed from fluids similar to those related to the muscovite during cooling of the porphyry system. By contrast, paragenetically later and postmineralization alteration fluid, which produced dickite (??18O = -4.1 to +3.3???, ??D = -130 to -140???), shows clear evidence for mixing with substantial amounts of meteoric water. Relatively low ??D values (-140???) for this meteoric water component may indicate that its source was at high elevations. The geologic structure, nature of alteration, styles of mineralization, and stable isotope data indicate that the Oyu Tolgoi deposits constitute a typical porphyry system formed in an island-arc setting. The outward zonation of sulfide minerals for the Hugo Dummett deposits, from a bornite-dominated core to chalcopyrite and pyrite-enargite, can be interpreted to be related to a cooling magmatic hydrothermal system which transgressed outward over enclosing advanced argillic alteration. This resulted in some unusual alteration and sulfide parageneses, such as topaz, or pyrite, enargite, and tennantite, entrained by high-grade bornite. ?? 2006 by Economic Geology.

Economic Geology↗