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Concentration data for anthropogenic organic compounds in ground water, surface water, and finished water of selected community water systems in the United States, 2002-05

The National Water-Quality Assessment Program of the U.S. Geological Survey began implementing Source Water-Quality Assessments (SWQAs) in 2001 that focus on characterizing the quality of source water and finished water of aquifers and major rivers used by some of the larger community water systems (CWSs) in the United States. As used for SWQA studies, source water is the raw (ambient) water collected at the supply well prior to water treatment (for ground water) or the raw (ambient) water collected from the river near the intake (for surface water), and finished water is the water that is treated and ready to be delivered to consumers. Finished water is collected before entering the distribution system. SWQA studies are conducted in two phases, and the objectives of SWQA studies are twofold: (1) to determine the occurrence and, for rivers, seasonal changes in concentrations of a broad list of anthropogenic organic compounds (AOCs) in aquifers and rivers that have some of the largest withdrawals for drinking-water supply (phase 1), and (2) for those AOCs found to occur most frequently in source water, characterize the extent to which these compounds are present in finished water (phase 2). These objectives were met for SWQA studies by collecting ground-water and surface-water (source) samples and analyzing these samples for 258 AOCs during phase 1. Samples from a subset of wells and surface-water sites located in areas with substantial agricultural production in the watershed were analyzed for 19 additional AOCs, for a total of 277 compounds analyzed for SWQA studies. The 277 compounds were classified according to the following 13 primary use or source groups: (1) disinfection by-products; (2) fumigant-related compounds; (3) fungicides; (4) gasoline hydrocarbons, oxygenates, and oxygenate degradates; (5) herbicides and herbicide degradates; (6) insecticides and insecticide degradates; (7) manufacturing additives; (8) organic synthesis compounds; (9) pavement- and combustion-derived compounds; (10) personal care and domestic use products; (11) plant- or animal-derived biochemicals; (12) refrigerants and propellants; and (13) solvents. Source and finished water samples were collected during phase 2 and analyzed for constituents that were detected frequently during phase 1. This report presents concentration data for AOCs in ground water, surface water, and finished water of CWSs sampled for SWQA studies during 2002-05. Specifically, this report presents the analytical results of samples collected during phase 1 including (1) samples from 221 wells that were analyzed for 258 AOCs; (2) monthly samples from 9 surface-water sites that were analyzed for 258 AOCs during phase 1; and (3) samples from a subset of the wells and surface-water sites located in areas with substantial agricultural production that were analyzed for 3 additional pesticides and 16 pesticide degradates. Samples collected during phase 2 were analyzed for selected AOCs that were detected most frequently in source water during phase 1 sampling; analytical results for phase 2 are presented for (1) samples of source water and finished water from 94 wells; and (2) samples of source water and finished water samples that were collected monthly and during selected flow conditions at 8 surface-water sites. Results of quality-assurance/quality-control samples collected for SWQA studies during 2002-05 also are presented.

Data Series↗

Selenium and other elements in water and adjacent rock and sediment of Toll Gate Creek, Aurora, Arapahoe County, Colorado, December 2003 through March 2004

Streamwater and solid samples (rock, unconsolidated sediment, stream sediment, and efflorescent material) in the Toll Gate Creek watershed, Colorado, were collected and analyzed for major and trace elements to determine trace-element concentrations and stream loads from December 2003 through March 2004, a period of seasonally low flow. Special emphasis was given to selenium (Se) concentrations because historic Se concentrations exceeded current (2004) stream standards. The goal of the project was to assess the distribution of Se concentration and loads in Toll Gate Creek and to determine the potential for rock and unconsolidated sediment in the basin to be sources of Se to the streamwater. Streamwater samples and discharge measurements were collected during December 2003 and March 2004 along Toll Gate Creek and its two primary tributaries - West Toll Gate Creek and East Toll Gate Creek. During both sampling periods, discharge ranged from 2.5 liters per second to 138 liters per second in the watershed. Discharge was greater in March 2004 than December 2003, but both periods represent low flow in Toll Gate Creek, and results of this study should not be extended to periods of higher flow. Discharge decreased moving downstream in East Toll Gate Creek but increased moving downstream along West Toll Gate Creek and the main stem of Toll Gate Creek, indicating that these two streams gain flow from ground water. Se concentrations in streamwater samples ranged from 7 to 70 micrograms per liter, were elevated in the upstream-most samples, and were greater than the State stream standard of 4.6 micrograms per liter. Se loads ranged from 6 grams per day to 250 grams per day, decreased in a downstream direction along East Toll Gate Creek, and increased in a downstream direction along West Toll Gate Creek and Toll Gate Creek. The largest Se-load increases occurred between two sampling locations on West Toll Gate Creek during both sampling periods and between the two sampling locations on the main stem of Toll Gate Creek during the December 2003 sampling. These load increases may indicate that sources of Se exist between these two locations; however, Se loading along West Toll Gate Creek and Toll Gate Creek primarily was characterized by gradual downstream increases in load. Linear regressions between Se load and discharge for both sampling periods had large, significant values of r2 (r2 > 0.96, p < 0.0001) because increases in Se load (per unit of flow increase) were generally constant. This relation is evidence for a constant addition of water having a relatively constant Se concentration over much of the length of Toll Gate Creek, a result which is consistent with a ground-water source for the Se loads. Rock outcroppings along the stream were highly weathered, and Se concentrations in rock and other solid samples ranged from below detection (1 part per million) to 25 parts per million. One sample of efflorescence (a surface encrustation produced by evaporation) had the greatest selenium concentration of all solid samples, was composed of thenardite (sodium sulfate), gypsum (calcium sulfate) and minor halite (sodium chloride), and released all of its Se during a 30-minute water-leaching procedure. Calculations indicate there was an insufficient amount of this material present throughout the watershed to account for the observed Se load in the stream. However, this material likely indicates zones of ground-water discharge that contain Se. This report did not identify an unequivocal source of Se in Toll Gate Creek. However, multiple lines of evidence indicate that ground-water discharge supplies Se to Toll Gate Creek: (1) the occurrence of elevated Se concentrations in the stream throughout the watershed and in the headwater regions, upstream from industrial sources; (2) the progressive increase in Se loads moving downstream, which indicates a continuous input of Se along the stream rather than input from point sources; (3) the occurr

Colorado↗

Water-quality assessment within a drainage control district in southeastern Florida

The U.S. Geological Survey (USGS) began an extensive ground- and surface-water quality study in July 1989 to define the baseline water quality within a southeastern Florida drainage district and to develop a data base for future water-resource planning and management. Results were published in a USGS report (Lietz, 1996), comparing ground- and surface-water quality data (1989-94) to the Florida Department of Environmental Regulation Class I drinking-water standards. This Fact Sheet presents an additional 4 years of water-quality data and summarizes water-quality trends over the entire 10-year sampling period (1989-98) for selected sites and constituents.

Fact Sheet↗

Sources and migration pathways of natural gas in near-surface ground water beneath the Animas River valley, Colorado and New Mexico

In July 1990, the U.S. Geological Survey began a study of the occurrence of natural gas in near-surface ground water in the Animas River valley in the San Juan Basin between Durango, Colorado, and Aztec, New Mexico. The general purpose of the study was to identify the sources and migration pathways of natural gas in nearsurface ground water in the study area. The purpose of this report is to present interpretive conclusions for the study, primarily based on data collected by the U.S. Geological Survey from August 1990 to May 1991. Seventy of the 205 (34 percent) groundwater samples collected during August-November 1990 had methane concentrations that exceeded the reporting limit of 0.005 milligram per liter. The maximum concentration was 39 milligrams per liter, and the mean concentration was 1.3 milligrams per liter. Samples from wells completed in bedrock have greater mean concentrations of methane than samples from wells completed in alluvium. Correlations indicate weak or nonexistent associations between dissolved-methane concentrations and concentrations of dissolved solids, major ions, bromide, silica, iron, manganese, and carbon dioxide. Dissolved methane was associated with hydrogen sulfide. Soil-gas-methane concentrations were measurable at few of 192 ground-water sites, even at sites at which ground water contained large concentrations of dissolved methane, which indicates that soil-gas surveys are not useful to delineate areas of gas-affected ground water. The reporting limit of 0.005 milligram per liter of gas was equaled or exceeded by 40 percent of soil-gas measurements adjacent to 352 gas-well casings. Concentrations of at least 100 milligrams per liter of gas were measured at 25 (7 percent) of the sites. Potential sources of gases in water, soil, gas-well surface casings, and cathodic-protection wells were determined on the basis of their isotopic and molecular compositions and available information about gas-well construction or leaks. Biogenic and thermogenic sources of gas exist in the near-surface environment of the study area. Biogenic gas is present locally in the near-surface Animas and Nacimiento formations, and biogenic gas has been detected in water wells completed in those rocks. Most gas probably is thermogenic gas from deep reservoirs, including the Dakota Sandstone, Mesaverde Group, Lewis Shale, Pictured Cliffs Sandstone, and coals in the Fruitland Formation. Less important sources include sandstones in the upper Fruitland Formation and the Kirtland Shale. Although migration of gas by diffusion or through natural fractures is possible, manmade conduits probably account for most of the upward migration of gas to the near-surface environment of the study area. Primary migration pathways largely consist of 1) leaking, conventional gas wells and 2) uncemented annuli of conventional gas wells along coals in the Fruitland Formation. Secondary migration pathways are gas-well annuli, cathodic-protection wells, seismic-test holes, and bedrock water wells.

Colorado, New Mexico↗

Questa baseline and premining ground-water quality investigation 18. Characterization of brittle structures in the Questa Caldera and their potential influence on bedrock ground-water flow, Red River Valley, New Mexico

This report presents a field-based characterization of fractured and faulted crystalline bedrock in the southern portion of the Questa caldera and its margin. The focus is (1) the identification and description of brittle geological structures and (2) speculation on the potential effects and controls that these structures might have on the potential fluxes of paleo to present-day ground water in relation to natural or mining-related metal and acid loads to surface and ground water. The entire study area is pervasively jointed with a few distinctive patterns such as orthogonal, oblique orthogonal, and conjugate joint sets. Joint intensity, the number of joints measured per unit line length, is high to extreme. Three types of fault zones are present that include partially silicified, low- and high-angle faults with well-developed damage zones and clay-rich cores and high-angle, unsilicified open faults. Conceptually, the joint networks can be thought of as providing the background porosity and permeability structure of the bedrock aquifer system. This background is cut by discrete entities such as the faults with clay-rich cores and open faults that may act as important hydrologic heterogeneities. The southern caldera margin runs parallel to the course of the Red River Valley, whose incision has left an extreme topographic gradient at high angles to the river. Many of the faults and fault intersections run parallel to this assumed hydraulic gradient; thus, these structures have great potential to provide paleo and present-day, discrete and anisotropic pathways for solute transport within the otherwise relatively low porosity and permeability bedrock background aquifer system. Although brittle fracture networks and faults are pervasive and complex, simple Darcy calculations are used to estimate the hydraulic conductivity and potential ground-water discharges of the bedrock aquifer, caldera margin, and other faults in order to gain insight into the potential contributions of these features to the ground-water and surface-water flow systems. These calculations show that, because all of these features are found along the Red River in the Cabin Springs-Columbine Park-Goat Hill fan area, their combined effect increases the probability that the bedrock aquifer ground-water flow system provides discharge to the Red River along this reach.

New Mexico↗

Evaluation of agricultural best-management practices in the Conestoga River headwaters, Pennsylvania: Characterization of surface-runoff and ground-water quantity and quality in a small carbonate basin near Churchtown, Pennsylvania, prior to terracing and implementation of nutrient management: Water-quality study of the Conestoga River headwaters, Pennsylvania

The U.S. Geological Survey, in cooperation with the Pennsylvania Department of Environmental Protection1 , conducted a study as part of the U.S. Department of Agriculture's Rural Clean Water Program to determine the effects of agricultural best-management practices on surface-water and ground-water quality in the Conestoga River headwaters basin. This report describes Field-Site 1 and characterizes the surface-runoff and ground-water quantity and quality at the site from January 1983 through September 1984, before the implementation of terracing and nutrient-management best-management practices. The 22.1-acre site, part of two dairy farms, was cropland used primarily for the production of corn and alfalfa, and is underlain by carbonate rock. During the 21-month study period, 91.2 inches of precipitation fell, of which 66 percent occurred during the 1984 water year. Of the 169 storms of 0.10 inch or larger, 97 produced measurable runoff. The average annual application of nutrients to the 14.4 acres of cornfields was 410 pounds per acre of nitrogen and 110 pounds per acre of phosphorus. About three times more nutrients were applied during 1984 water year than during the 1983 water year. The approximate soil-nitrate concentration as nitrogen for the study period was 8.2 milligrams per kilogram in the top 8 inches of soil. Runoff for the study period totalled 714,000 cubic feet, or 9.8 percent of total precipitation. Eighty-eight percent of the runoff occurred during the 1984 water year. Regression analyses indicate that total runoff was controlled primarily by total precipitation amounts during storms and by antecedent moisture conditions; mean event and maximum instantaneous discharges are controlled by precipitation intensity and by antecedent moisture conditions. Regression analyses also suggest that crop cover on the corn acreage affected runoff amounts and rates. Mean concentrations in runoff ranged from 24 to 73,000 milligrams per liter for suspended sediment, 0.45 to 24 milligrams per liter for total phosphorus, and 1.5 to 55 milligrams per liter for total nitrogen. Of the total nitrogen in instantaneous runoff samples, a median of 72 percent was total organic nitrogen. Results of multiple regression analyses suggest that mean nitrogen concentrations in runoff (1) increased with increased surface-nitrogen applications made prior to runoff, and (2) were diluted with increased precipitation duration. Runoff from storms on frozen ground produced the highest loads of nitrogen in runoff. Over the 21-month study period, an estimated 258 tons of suspended sediment, 314 pounds of nitrogen, and 176 pounds of phosphorus were transported with runoff from the site. Of this, 88 percent of the nitrogen and phosphorus loads and 94 percent of the suspended-sediment load were discharged during the wet 1984 water year. The loads for the study period represent 2.5 percent of the total nitrogen and 5.5 percent of the total phosphorus applied to the site as manure and commercial fertilizer. The ground-water basin at the site is slightly larger than the surface-water basin. Ground-water levels, except at one well, responded quickly to recharge; water levels peaked several hours to a day after precipitation. Surface-applied materials moved rapidly to the water table through macropores and slowly by transport through micropores in the unsaturated zone. Median concentrations of dissolved nitrate ranged from 9.2 to 13 milligrams per liter as nitrogen for ground-water samples collected monthly from five wells and a spring. Dissolved nitrate comprised 93 percent (median percentage) of the total nitrogen in ground-water samples. The effect of recharge on ground-water nitrate concentrations was affected by variations in nutrient availability at the land surface and in the unsaturated zone. A lag time of 1 to 3 months was observed between the time that nitrogen was applied to the land surface and local maximums in nitrate concentrations were detected in ground water unaffected by recharge events. Approximately 3,187,000 cubic feet of ground water and an associated 2,200 pounds of nitrate-nitrogen discharged from the site during the study period. For the study period, 42 percent of the precipitation recharged to ground water, 10 percent became runoff, and 48 percent evapotranspired. Inputs of nitrogen to the study area were estimated to be 93 percent from manure, 5 percent from commercial fertilizer, and 2 percent from precipitation. Nitrogen outputs from the system were estimated to be 38 percent to crop uptake, 39 percent to volatilization, 20 percent to ground-water discharge, and 3 percent to surface runoff.

Pennsylvania↗

Hydrologic data for the Usquepaug-Queen River basin, Rhode Island

The Usquepaug-Queen River ground-water reservoir in Rhode Island is part of the stratified-drift aquifer along the Usquepaug-Queen River and its tributaries. The thickest, most permeable parts of the aquifer form the Usquepaug-Queen River ground-water reservoir. The 36.1-square mile study area comprises parts of Washington and Kent counties, and includes parts of the towns of Exeter, North Kingstown, Richmond, South Kingstown, and West Greenwich. The report presents geologic and hydrologic information needed for the prediction and management of hydrologic effects of proposed ground-water development. The report describes aquifer lithology, provides historical data on water-level and aquifer-storage changes, provides information on ground-water quality, and presents natural flow characteristics and water quality of streams in the Usquepaug-Queen River area. The data includes 275 ground-water sites; lithologic logs of 66 ground-water sites; water levels for 43 ground- water sites; chemical analyses of 36 ground-water sites; stream discharge measurements from the continuous-record gaging station on the Usquepaug- Queen River; discharge measurements at 10 partial- record stations in the area; chemical analyses of 17 stream sites; and the data from 14 slug tests conducted at ground-water sites.

Open-File Report↗

A digital model for simulation of ground-water hydrology in the Houston area, Texas

This report documents the construction and calibration of a digital model for the simulation of hydrologic conditions in the Chicot and Evangeline aquifers in the Houston area of southeastern Texas. The model is a five-layer finite-difference model, with a grid pattern of 63 x 67 nodes representing an area of 27,000 square miles, for simulation of three- dimensional ground-water flow. The hydrologic properties and processes modeled were ground-water withdrawals, transmissivities, storage coefficients of the aquifers and clays, quantity of water derived from storage in the clays, and vertical hydraulic conductivity and vertical leakage. The model, which simulates water-level declines, changes in storage in the clay layers, and land-surface subsidence, was calibrated by use of historical records from 1890 to 1975. It is very sensitive to variations in transmissivities and to variations in water-table and artesian storage. It is less sensitive to variations in clay storage.

Texas↗

Numerical simulation of ground-water flow in La Crosse County, Wisconsin, and into nearby pools of the Mississippi River

This report describes a two-dimensional regional screening model and two associated three-dimensional ground-water flow models that were developed to simulate the ground-water flow systems in La Crosse County, Wisconsin, and Pool 8 of the Mississippi River. Although the geographic extents of the three-dimensional models were slightly different, both were derived from the same geologic interpretation and regional screening model, and their calibrations were performed concurrently. The objectives of the La Crosse County (LCC) model were to assess the effects of recent (1990s) and potential future ground-water withdrawals and to provide a tool suitable to evaluate the effects of proposed water-management programs. The Pool 8 model objectives were to quantify the magnitude and distribution of ground-water flow into the Pool. The Wisconsin Geological and Natural History Survey and the U.S. Geological Survey developed the models cooperatively. The report describes: 1) the conceptual hydrogeologic model; 2) the methods used in simulating flow; 3) model calibration and sensitivity analysis; and 4) model results, such as simulation of predevelopment conditions and location and magnitude of ground-water discharge into Pool 8 of the Mississippi. Three aquifer units underlie the model area: 1) a shallow unconsolidated sand and gravel aquifer; 2) an upper bedrock aquifer, composed of Cambrian and Ordovician sandstone and dolomite; and 3) a lower bedrock aquifer composed of Cambrian sandstone of the Eau Claire Formation and the Mount Simon Formation. A shale layer that is part of the Eau Claire Formation forms a confining unit separating the upper and lower bedrock aquifers. This confining unit is absent in the Black River and parts of the La Crosse and Mississippi River valleys. Precambrian crystalline basement rock forms the lower base of the ground-water flow system. The U.S. Geological Survey ground-water flow model code, MODFLOW, was used to develop the La Crosse County (LCC) and Pool 8 ground-water flow models. Boundary conditions for the MODFLOW model were extracted from an analytic element screening model of the regional flow system surrounding La Crosse County. Model input was obtained from previously published and unpublished geologic and hydrologic data. Pumpages from municipal and high-capacity wells were also simulated. Model calibration included a comparison of modeled and field-measured water levels and field-measured base flows to simulated stream flows. At calibration, most measured water levels compared favorably to model-calculated water levels. Simulated streamflows at two targets were within 3 percent of estimated measured base flows. Mass balance results from the LCC and Pool 8 models indicated that 63 to 74 percent of ground water was from recharge and 19 to 26 percent was from surface-water sources. Ground-water flow out of the model was to rivers and streams (85 to 87 percent) and pumping wells (11 and 13 percent). The model demonstrates the effects of development on ground water in the study area. The maximum simulated water-level decline in the city of La Crosse metropolitan area is 9.3 feet. Simulated stream losses are similar to the amount of ground water pumped by wells. This indicates that ground water withdrawn by La Crosse County wells is water that under predevelopment conditions discharged to streams and lakes. The models provide estimates of the locations and amount of ground-water flow into Pool 8 and the southern portion of Pool 7 of the Mississippi River. Ground-water discharges into all areas of the pools, except along the eastern shore in the vicinity of the city of La Crosse and immediately downgradient from lock and dam 7 and 8. Ground-water flow into the pools is generally greatest around the perimeter with decreasing amounts away from the perimeter. An area of relatively high ground-water discharge extends out towards the center of Pool 7 from the upper reaches of the pool and may

Wisconsin↗

Water-resources data for the Fort Berthold Indian Reservation, west-central North Dakota

A study of the water resources of the Fort Berthold Indian Reservation was undertaken to characterize the quality and quantity of ground-water and surface-water resources. The purpose of this report is to document the data-collection procedures used during the study and to present the data collected in tabular and graphical form. Ground-water data were collected during May 1990 through November 1992. The data presented in this report include records of 1,325 wells, test holes, and springs; water-levels fcr 40 observation wells; drillers' logs for 211 wells and test holes; gamma-ray and resistivity logs for 21 test holes drilled in June 1992; water-quality data for 293 water samples from wells ani springs; and trace-element data for 225 water samples from wells. Surface-water data were collected on Bear Den Creek, East Fork Shell Creek, Deepwater Creek, Moccasin Creek, and Squaw Creek from April 1990 through September 1992. Initial!}', five miscellaneous measurement sites were established so that discharge data, selected physical properties of water, and water samples for water-quality analysis could be collected. Gravity data were collected over parts of the Fort Berthold Indian Reservation. As part of the gravity survey, positional data were acquired using global positioning satellite technology.

Open-File Report↗

An investigation of ground-water recharge by injection in the Palo Alto Baylands, California: Hydraulic and chemical interactions — Final report

The U.S. Geological Survey, in cooperation with the Santa Clara Valley Water District, has completed a study of ground-water recharge by injection in the Palo Alto baylands along San Francisco Bay, California. Selected wells within the Water District 's injection-extraction network were monitored to determine hydraulic and chemical interactions affecting well-field operation. The well field was installed to prevent and eliminate saline contamination in the local shallow aquifer system. The primary focus of this study is on factors that affect injection efficiency, specifically well and aquifer clogging. Mixing and break-through curves for major chemical constituents indicate ion exchange, adsorption, and dissolution reactions. Freshwater breakthrough was detected in water-level data, which reflected fluid-density change as well as head buildup. Dissolution of calcium carbonate caused by dilution of saline ground water probably accounts for an apparent increase in specific capacity possibly related to improved aquifer permeability. Adsorption evidently removed trace elements during passage of injected water through the aquifer. In terms of hydraulic and chemical compatibility, the well field is a viable system for ground-water recharge. Aquifer heterogeneity and operational constraints reduce the efficiency of the system. Efficiency may be maximized by careful attention to extraction distribution and quantity and to injection distribution, quantity, and water quality. (USGS)

California↗

Late Pleistocene paleohydrology near the boundary of the Sonoran and Chihuahuan Deserts, southeastern Arizona, USA

Ground-water discharge (GWD) deposits form in arid environments as water tables rise and approach or breach the ground surface during periods of enhanced effective precipitation. Where preserved, these deposits contain information on the timing and elevation of past ground-water fluctuations. Here we report on the investigation of a series of GWD deposits that are exposed in discontinuous outcrops along a ???150-km stretch of the San Pedro Valley in southeastern Arizona, near the boundary of the Sonoran and Chihuahuan Deserts. Chronologic, isotopic, geochemical, faunal assemblage (ostracodes and gastropods), and sedimentological evidence collectively suggest that the elevation of the regional water table in the valley rose in response to a change in climate ???50 ka ago and remained relatively high for the next ???35 ka before falling during the B??lling-Aller??d warm period, rebounding briefly during the Younger Dryas cold event, and falling again at the onset of the Holocene. The timing of these hydrologic changes coincides closely with variations in ??18O values of calcite from a nearby speleothem to the west and changes in lake levels at pluvial Lake Cochise to the east. Thus, in southeastern Arizona, the assumption that changes in climate are reflected in all aspects of the hydrologic cycle of a region simultaneously is validated. The timing of these changes also broadly coincides with variations in the GISP2 ??18O record, which supports the hypothesis that atmospheric teleconnections existed between the North Atlantic and the deserts of the American Southwest during the late Pleistocene.

Arizona↗

Development of a comprehensive watershed model applied to study stream yield under drought conditions

We developed a model code to simulate a watershed's hydrology and the hydraulic response of an interconnected stream-aquifer system, and applied the model code to the Lower Republican River Basin in Kansas. The model code links two well-known computer programs: MODFLOW (modular 3-D flow model), which simulates ground water flow and stream-aquifer interaction; and SWAT (soil water assessment tool), a soil water budget simulator for an agricultural watershed. SWAT represents a basin as a collection of subbasins in terms of soil, land use, and weather data, and simulates each subbasin on a daily basis to determine runoff, percolation, evaporation, irrigation, pond seepage, and crop growth. Because SWAT applies a lumped hydrologic model to each sub-basin, spatial heterogeneities with respect to factors such as soil type and land use are not resolved geographically, but can instead be represented statistically. For the Republican River Basin model, each combination of six soil types and three land uses, referred to as a hydrologic response unit (HRU), was simulated with a separate execution of SWAT. A spatially weighted average was then taken over these results for each hydrologic flux and time step by a separate program, SWBAVG. We wrote a package for MODFLOW to associate each subbasin with a subset of aquifer grid cells and stream reaches, and to distribute the hydrologic fluxes given for each subbasin by SWAT and SWBAVG over MODFLOW's stream-aquifer grid to represent tributary flow, surface and ground water diversions, ground water recharge, and evapotranspiration from ground water. The Lower Republican River Basin model was calibrated with respect to measured ground water levels, streamflow, and reported irrigation water use. The model was used to examine the relative contributions of stream yield components and the impact on stream yield and base flow of administrative measures to restrict irrigation water use during droughts. Model results indicate that tributary flow is the dominant component of stream yield and that reduction of irrigation water use produces a corresponding increase in base flow and stream yield. However, the increase in stream yield resulting from reduced water use does not appear to be of sufficient magnitude to restore minimum desirable streamflows.

Groundwater↗

Geologic, hydrologic, and water-quality data from multiple-well monitoring sites in the Central and West Coast basins, Los Angeles County, California, 1995-2000

In 1995, the U.S. Geological Survey (USGS), in cooperation with the Water Replenishment District of Southern California (WRDSC) , began a study to examine ground-water resources in the Central and West Coast Basins in Los Angeles County, California. The study characterizes the geohydrology and geochemistry of the regional ground-water flow system and provides extensive data for evaluating ground-water management issues. This report is a compilation of geologic, hydrologic, and water-quality data collected from 24 recently constructed multiple-well monitoring sites for the period 1995–2000. Descriptions of the collected drill cuttings were compiled into lithologic logs, which are summarized along with geophysical logs—including gamma-ray, spontaneous potential, resistivity, electromagnetic induction, and temperature tool logs—for each monitoring site. At selected sites, cores were analyzed for magnetic orientation, physical and thermal properties, and mineralogy. Field and laboratory estimates of hydraulic conductivity are presented for most multiple-well monitoring sites. Periodic water-level measurements are also reported. Water-quality information for major ions, nutrients, trace elements, deuterium and oxygen-18, and tritium is presented for the multiple-well monitoring locations, and for selected existing production and observation wells. In addition, boron-11, carbon-13, carbon-14, sulfur-34, and strontium-87/86 data are presented for selected wells.

Open-File Report↗

Water-quality data from ground- and surface-water sites near concentrated animal feeding operations (CAFOs) and non-CAFOs in the Shenandoah Valley and eastern shore of Virginia, January-February, 2004

Concentrated animal feeding operations (CAFOs) result from the consolidation of small farms with animals into larger operations, leading to a higher density of animals per unit of land on CAFOs than on small farms. The density of animals and subsequent concentration of animal wastes potentially can cause contamination of nearby ground and surface waters. This report summarizes water-quality data collected from agricultural sites in the Shenandoah Valley and Eastern Shore of Virginia. Five sites, three non-CAFO and two dairy-operation CAFO sites, were sampled in the Shenandoah Valley. Four sites, one non-CAFO and three poultry-operation CAFO sites were sampled on the Eastern Shore. All samples were collected during January and February 2004. Water samples were analyzed for the following parameters and constituents: temperature, specific conductance, pH, and dissolved oxygen; concentrations of the indicator organisms Escherichia coli ( E. coli ) and enterococci; bacterial isolates of E. coli , enterococci, Salmonella spp., and Campylobacter spp.; sensitivity to antibiotics of E. coli , enterococci, and Salmonella spp.; arsenic, cadmium, chromium 3+ , copper, nickel, and mercury; hardness, biological oxygen demand, nitrate, nitrite, ammonia, ortho-phosphate, total Kjeldahl nitrogen, chemical oxygen demand, total organic carbon, and dissolved organic carbon; and 45 dissolved organic compounds, which included a suite of antibiotic compounds. Data are presented in tables 5-21 and results of analyses of replicate samples are presented in tables 22-28. A summary of the data in tables 5-8 and 18-21 is included in the report.

Virginia↗

A plan to study the aquifer system of the Central Valley of California

Unconsolidated Quaternary alluvial deposits comprise a large complex aquifer system in the Central Valley of California. Millions of acre-feet of water is pumped from the system annually to support a large and expanding agribusiness industry. Since the 1950's, water levels have been steadily declining in many areas of the valley and concern has been expressed about the ability of the entire ground-water system to support agribusiness at current levels, not to mention its ability to function at projected expansion levels. At current levels of ground-water use, an estimated 1.5 to 2 million acre-feet is withdrawn from storage each year; that is, 1.5 to 2 million acre-feet of water is pumped annually in excess of annual replenishment. The U.S. Geological Survey has initiated a 4-year study to develop geologic, hydrologic, and hydraulic information and to establish a valleywide ground-water data base that will be used to build computer models of the ground-water flow system. Subsequently, these models may be used to evaluate the system response to various ground-water management alternatives. This report describes current problems, objectives of the study, and outlines the general work to be accomplished in the study area. A bibliography of about 600 references is included. (Kosco-USGS)

California↗

Lithostratigraphy, petrography, biostratigraphy, and strontium-isotope stratigraphy of the surficial aquifer system of western Collier County, Florida

In 1996, seven cores were recovered in western Collier County, southwestern Florida, to acquire subsurface geologic and hydrologic data to support ground-water modeling efforts. This report presents the lithostratigraphy, X-ray diffraction analyses, petrography, biostratigraphy, and strontium-isotope stratigraphy of these cores. The oldest unit encountered in the study cores is an unnamed formation that is late Miocene. At least four depositional sequences are present within this formation. Calculated age of the formation, based on strontium-isotope stratigraphy, ranges from 9.5 to 5.7 Ma (million years ago). An unconformity within this formation that represents a hiatus of at least 2 million years is indicated in the Old Pump Road core. In two cores, Collier-Seminole and Old Pump Road, the uppermost sediments of the unnamed formation are not dated by strontium isotopes, and, based on the fossils present, these sediments could be as young as Pliocene. In another core (Fakahatchee Strand-Ranger Station), the upper part of the unnamed formation is dated by mollusks as Pliocene. The Tamiami Formation overlies the unnamed formation throughout the study area and is represented by the Ochopee Limestone Member. The unit is Pliocene and probably includes the interval of time near the early/late Pliocene boundary. Strontium-isotope analysis indicates an early Pliocene age (calculated ages range from 5.1 to 3.5 Ma), but the margin of error includes the latest Miocene and the late Pliocene. The dinocyst assemblages in the Ochopee typically are not age-diagnostic, but, near the base of the unit in the Collier-Seminole, Jones Grade, and Fakahatchee Strand State Forest cores, they indicate an age of late Miocene or Pliocene. The molluscan assemblages indicate a Pliocene age for the Ochopee, and a distinctive assemblage of Carditimera arata and Chione cortinaria in several of the cores specifically indicates an age near the early/late Pliocene boundary. Undifferentiated sands overlie the Pliocene limestones in two cores in the southern part of the study area. Artificial fill occurs at the top of most of the cores. The hydrologic confining units penetrated by these cores are different in different parts of the study area. To the west, a hard tightly cemented dolostone forms the first major confining unit below the water table. In the eastern part of the study area, confinement is more difficult to determine. A tightly cemented sandstone, much younger than the dolostones to the west and probably not laterally connected to them, forms a slight confining unit in one core. Thick zones of poorly sorted muddy unconsolidated sands form a slight confining unit in other cores; these probably are not correlative to either the sandstone or the dolostones to the west. The age and sedimentologic observations suggest a complex compartmentalization of the surficial aquifer system in southwestern Florida. The calibrations of dinocyst and molluscan occurrences with strontium-isotope stratigraphy allows us to expand and document the reported ranges of many taxa. This report is preliminary and has not been reviewed for conformity with U.S. Geological Survey editorial standards or with the North American Stratigraphic Code. Any use of trade, product, or firm names is for descriptive purposes only and does not imply endorsement by the U.S. Government.

Florida↗

Water-Level Changes in the High Plains Aquifer, Predevelopment to 2007, 2005-06, and 2006-07

The High Plains aquifer underlies 111.6 million acres (174,000 square miles) in parts of eight States - Colorado, Kansas, Nebraska, New Mexico, Oklahoma, South Dakota, Texas, and Wyoming. Water-level declines began in parts of the High Plains aquifer soon after the beginning of substantial irrigation with ground water in the aquifer area. This report presents water-level changes in the High Plains aquifer from the time before substantial ground-water irrigation development had occurred (about 1950 and termed 'predevelopment' in this report) to 2007, from 2005-06, and from 2006-07. The report also presents the percentage change in saturated thickness of the aquifer, from predevelopment to 2007. Measured water-level changes from predevelopment to 2007 ranged from a rise of 84 feet in Nebraska to a decline of 234 feet in Texas. The area-weighted, average water-level changes in the aquifer were a decline of 14.0 feet from predevelopment to 2007, a decline of 0.4 foot during 2005-06, and a decline of 0.6 foot during 2006-07. Total water in storage in the aquifer in 2007 was about 2.9 billion acre-feet, which was a decline of about 270 million acre-feet since predevelopment.

Scientific Investigations Report↗