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Summary of available state ambient stream-water-quality data, 1990-98, and limitations for national assessment

The investigation described in this report summarized data from State ambient stream-water-quality monitoring sites for 10 water-quality constituents or measurements (suspended solids, fecal coliform bacteria, ammonia as nitrogen, nitrite plus nitrate as nitrogen, total phosphorus, total arsenic, dissolved solids, chloride, sulfate, and pH). These 10 water-quality constituents or measurements commonly are listed nationally as major contributors to degradation of surface water. Water-quality data were limited to that electronically accessible from the U.S. Environmental Protection Agency Storage and Retrieval System (STORET), the U.S. Geological Survey National Water Information System (NWIS), or individual State databases. Forty-two States had ambient stream-water-quality data electronically accessible for some or all of the constituents or measurements summarized during this investigation. Ambient in this report refers to data collected for the purpose of evaluating stream ecosystems in relation to human health, environmental and ecological conditions, and designated uses. Generally, data were from monitoring sites assessed for State 305(b) reports. Comparisons of monitoring data among States are problematic for several reasons, including differences in the basic spatial design of monitoring networks; water-quality constituents for which samples are analyzed; water-quality criteria to which constituent concentrations are compared; quantity and comprehensiveness of water-quality data; sample collection, processing, and handling; analytical methods; temporal variability in sample collection; and quality-assurance practices. Large differences among the States in number of monitoring sites precluded a general assumption that statewide water-quality conditions were represented by data from these sites. Furthermore, data from individual monitoring sites may not represent water-quality conditions at the sites because sampling conditions and protocols are unknown. Because of these factors, a high level of uncertainty exists in a national assessment of water quality. The purpose of this report is to present a summary of electronically available State ambient stream-water-quality data for 10 selected constituents and measurements from monitoring sites with nine or more analyses for 199098 and to discuss limitations for use of the data for national assessment. These analyses were statistiscally summarized by monitoring site and State, and the results presented in tabular format. Most of the selected constituents or measurements have U.S. Environmental Protection Agency criteria or guidelines for aquatic-life or drinking-water purposes. A significant finding of this investigation is that for a large percentage of monitoring sites in the Nation, there are insufficient data to meet U.S. Environmental Protection Agency recommendations for determining if water-quality conditions are degraded and for making informed decisions regarding total maximum daily loads.

Water-Resources Investigations Report↗

Review of the transport of selected radionuclides in the interim risk assessment for the Radioactive Waste Management Complex, Waste Area Group 7 Operable Unit 7-13/14, Idaho National Engineering and Environmental Laboratory, Idaho

The U.S. Department of Energy (DOE) requested that the U.S. Geological Survey conduct an independent technical review of the Interim Risk Assessment (IRA) and Contaminant Screening for the Waste Area Group 7 (WAG-7) Remedial Investigation, the draft Addendum to the Work Plan for Operable Unit 7-13/14 WAG-7 comprehensive Remedial Investigation and Feasibility Study (RI/FS), and supporting documents that were prepared by Lockheed Martin Idaho Technologies, Inc. The purpose of the technical review was to assess the data and geotechnical approaches that were used to estimate future risks associated with the release of the actinides americium, uranium, neptunium, and plutonium to the Snake River Plain aquifer from wastes buried in pits and trenches at the Subsurface Disposal Area (SDA). The SDA is located at the Radioactive Waste Management Complex in southeastern Idaho within the boundaries of the Idaho National Engineering and Environmental Laboratory. Radionuclides have been buried in pits and trenches at the SDA since 1957 and 1952, respectively. Burial of transuranic wastes was discontinued in 1982. The five specific tasks associated with this review were defined in a ?Proposed Scope of Work? prepared by the DOE, and a follow-up workshop held in June 1998. The specific tasks were (1) to review the radionuclide sampling data to determine how reliable and significant are the reported radionuclide detections and how reliable is the ongoing sampling program, (2) to assess the physical and chemical processes that logically can be invoked to explain true detections, (3) to determine if distribution coefficients that were used in the IRA are reliable and if they have been applied properly, (4) to determine if transport model predictions are technically sound, and (5) to identify issues needing resolution to determine technical adequacy of the risk assessment analysis, and what additional work is required to resolve those issues.

Idaho↗

Laboratory evaluation of the Sea-Bird Scientific HydroCycle-PO4 phosphate sensor

Sea-Bird Scientific’s HydroCycle-PO 4 phosphate sensor is a single-analyte wet-chemistry sensor designed for in situ environmental monitoring. The unit was evaluated at the U.S. Geological Survey Hydrologic Instrumentation Facility to assess the accuracy of the sensor in solutions with known phosphorous concentration and to test the effects of chromophoric (colored) dissolved organic matter (CDOM) and natural water matrixes on sensor accuracy. Accuracy was tested with three standards: 0.110, 0.174, and 0.260 milligram per liter, as phosphorous (mg/L as P). The 0.110- and 0.260-mg/L standards were made from a dilution of a National Institute of Standards and Technology-traceable phosphate-phosphorous standard with Type I deionized water (DIW). Average measured phosphate concentrations of the tested standards (0.110, 0.174, and 0.260 mg/L as P) in DIW were 0.132, 0.181, and 0.310 mg/L as P, for differences of 20, 4, and 19 percent, respectively. Measured phosphate concentration of a tested standard was biased by the addition of tea water filtered through a 0.45-micrometer pore size filter (filtered tea water [FTW]) simulating the effect of CDOM. An aliquot of the filtered tea solution was sent to a certified environmental laboratory, which reported a less than reporting level (<0.004 mg/L as P) phosphate concentration. True color of the FTW was measured at 380 platinum-cobalt units by using Standard Methods 8025. For this FTW test, the measured phosphate concentration for the clear 0.260 mg/L as P standard averaged 0.366 mg/L as P. This concentration increased to an average of 0.653 mg/L as P with the addition of 10 percent FTW, and to an average of 0.859 mg/L as P with the addition of 20 percent FTW. These test results indicate a positive bias of up to 40 percent of the concentrations of the measured phosphate concentrations when CDOM is present and indicate a proportional increase in an apparent concentration of phosphorus instrument response as CDOM concentration increases.

Open-File Report↗

Natural gases in ground water near Tioga Junction, Tioga County, north-central Pennsylvania: Occurrence and use of isotopes to determine origins, 2005

In January 2001, State oil and gas inspectors noted bubbles of natural gas in well water during a complaint investigation near Tioga Junction, Tioga County, north-central Pa. By 2004, the gas occurrence in ground water and accumulation in homes was a safety concern; inspectors were taking action to plug abandoned gas wells and collect gas samples. The origins of the natural-gas problems in ground water were investigated by the U.S. Geological Survey, in cooperation with the Pennsylvania Department of Environmental Protection, in wells throughout an area of about 50 mi2, using compositional and isotopic characteristics of methane and ethane in gas and water wells. This report presents the results for gas-well and water-well samples collected from October 2004 to September 2005. Ground water for rural-domestic supply and other uses near Tioga Junction is from two aquifer systems in and adjacent to the Tioga River valley. An unconsolidated aquifer of outwash sand and gravel of Quaternary age underlies the main river valley and extends into the valleys of tributaries. Fine-grained lacustrine sediments separate shallow and deep water-bearing zones of the outwash. Outwash-aquifer wells are seldom deeper than 100 ft. The river-valley sediments and uplands adjacent to the valley are underlain by a fractured-bedrock aquifer in siliciclastic rocks of Paleozoic age. Most bedrock-aquifer wells produce water from the Lock Haven Formation at depths of 250 ft or less. A review of previous geologic investigations was used to establish the structural framework and identify four plausible origins for natural gas. The Sabinsville Anticline, trending southwest to northeast, is the major structural feature in the Devonian bedrock. The anticline, a structural trap for a reservoir of deep native gas in the Oriskany Sandstone (Devonian) (origin 1) at depths of about 3,900 ft, was explored and tapped by numerous wells from 1930-60. The gas reservoir in the vicinity of Tioga Junction, depleted of native gas, was converted to the Tioga gas-storage field for injection and withdrawal of non-native gases (origin 2). Devonian shale gas (shallow native gas) also has been reported in the area (origin 3). Gas might also originate from microbial degradation of buried organic material in the outwash deposits (origin 4). An inventory of combustible-gas concentrations in headspaces of water samples from 91 wells showed 49 wells had water containing combustible gases at volume fractions of 0.1 percent or more. Well depth was a factor in the observed occurrence of combustible gas for the 62 bedrock wells inventoried. As well-depth range increased from less than 50 ft to 51-150 ft to greater than 151 ft, the percentage of bedrock-aquifer wells with combustible gas increased. Wells with high concentrations of combustible gas occurred in clusters; the largest cluster was near the eastern boundary of the gas-storage field. A subsequent detailed gas-sampling effort focused on 39 water wells with the highest concentrations of combustible gas (12 representing the outwash aquifer and 27 from the bedrock aquifer) and 8 selected gas wells. Three wells producing native gas from the Oriskany Sandstone and five wells (two observation wells and three injection/withdrawal wells) with non-native gas from the gas-storage field were sampled twice. Chemical composition, stable carbon and hydrogen isotopes of methane (13CCH4 and DCH4), and stable carbon isotopes of ethane (13CC2H6) were analyzed. No samples could be collected to document the composition of microbial gas originating in the outwash deposits (outwash or 'drift' gas) or of native natural gas originating solely in Devonian shale at depths shallower than the Oriskany Sandstone, although two of the storage-field observation wells sampled reportedly yielded some Devonian shale gas. Literature values for outwash or 'drift' gas and Devonian shale gases were used to supplement the data collection. Non-native gases fr

Pennsylvania↗

Records of wells and chemical analyses of ground water in Charles Mix and Douglas counties, South Dakota

The U.S. Geological Survey, in cooperation with the South Dakota Department of Environmental and Natural Resources, maintains a data base of information on water resources in the State of South Dakota. The ground-water site data for Charles Mix and Douglas Counties are presented in two tables, with the data organized by county and location. The chemical data for ground-water sites also are located in a table organized by geologic unit and location.

Open-File Report↗

Water-quality assessment of the Albemarle-Pamlico drainage basin, North Carolina and Virginia environmental setting and water-quality issues

The Albemarle-Pamlico drainage study unit is one of 60 units of the U.S. Geological Survey's National Water-Quality Assessment Program, and includes the large river basins which drain into the Albemarle and Pamlico Sounds-the Chowan, Roanoke, Tar-Pamlico, and Neuse River Basins. The study unit includes about 28,000 square miles and has an interrelated set of environmental characteristics which strongly influence water quality. The chemical and physical nature of these characteristics are the dominant controls on baseline water quality in the study area. About 50 percent of the study area is forested, slightly more than 30 percent is agricultural, about 15 percent is wetlands, and less than 5 percent is developed. Three million people live in the study area, and activities related to agriculture and development have caused increased concentrations of constituents such as nutrients, pesticides, and suspended sediment. About two-thirds of the 36 to 52 inches of precipitation in the area reenters the atmosphere by evapotranspiration. About one-third of the remaining precipitation reaches streams by overland runoff; the remainder recharges the water table aquifer, where much of the water eventually discharges to streams as ground water. Thus, ground-water quality has a substantial influence on surface-water quality, particularly during dry weather. In 1990, about 152,900 tons of elemental nitrogen and 10,500 tons of elemental phosphorus either were applied to crops as fertilizer or fixed by biological processes, and in 1987, about 43,500 tons of nitrogen and 12,200 tons of phosphorus were produced as animal wastes. In addition, about 1,300 tons of selected herbicides and 400 tons of selected insecticides were applied to crops in 1990. Some 249 permitted point sources discharged 410 million gallons per day, containing an annual load of 5,800 tons of nitrogen and 1,800 tons of phosphorus, to the study area in 1990. Data from 1970-79 indicate that mean annual suspended-sediment yields for selected forested, agricultural, and developed urban basins in North Carolina are 50, 250, and 550 tons per square mile, respectively. In order to facilitate comparisons, much of the data were compiled by hydrologic unit. Homogeneous areas, or strata, representing the most prevalent combinations of environmental factors, such as land use, soils, and geology, were defined. Future data collection and analyses will be designed to answer objective-related concerns about the relations between important water-quality conditions and these study-unit strata.

North Carolina, Virginia↗

Watershed Boundary Dataset for Mississippi

The U.S. Geological Survey, in cooperation with the Mississippi Department of Environmental Quality, U.S. Department of Agriculture-Natural Resources Conservation Service, Mississippi Department of Transportation, U.S. Department of Agriculture-Forest Service, and the Mississippi Automated Resource Information System developed a 1:24,000-scale Watershed Boundary Dataset for Mississippi including watershed and subwatershed boundaries, codes, names, and areas. The Watershed Boundary Dataset for Mississippi provides a standard geographical framework for water-resources and selected land-resources planning. The original 8-digit subbasins (Hydrologic Unit Codes) were further subdivided into 10-digit watersheds (62.5 to 391 square miles (mi2)) and 12-digit subwatersheds (15.6 to 62.5 mi2) - the exceptions being the Delta part of Mississippi and the Mississippi River inside levees, which were subdivided into 10-digit watersheds only. Also, large water bodies in the Mississippi Sound along the coast were not delineated as small as a typical 12-digit subwatershed. All of the data - including watershed and subwatershed boundaries, subdivision codes and names, and drainage-area data - are stored in a Geographic Information System database, which are available at: http://ms.water.usgs.gov/. This map shows information on drainage and hydrography in the form of U.S. Geological Survey hydrologic unit boundaries for water-resource 2-digit regions, 4-digit subregions, 6-digit basins (formerly called accounting units), 8-digit subbasins (formerly called cataloging units), 10-digit watershed, and 12-digit subwatersheds in Mississippi. A description of the project study area, methods used in the development of watershed and subwatershed boundaries for Mississippi, and results are presented in Wilson and others (2008). The data presented in this map and by Wilson and others (2008) supersede the data presented for Mississippi by Seaber and others (1987) and U.S. Geological Survey (1977).

Scientific Investigations Map↗

Development of a geodatabase and conceptual model of the hydrogeologic units beneath air force plant 4 and Naval Air Station-Joint Reserve Base Carswell Field, Fort Worth, Texas

Air Force Plant 4 and adjacent Naval Air Station-Joint Reserve Base Carswell Field at Fort Worth, Texas, constitute a government-owned, contractor-operated facility that has been in operation since 1942. Contaminants from AFP4, primarily volatile organic compounds and metals, have entered the ground-water-flow system through leakage from waste-disposal sites and from manufacturing processes. The U.S. Geological Survey developed a comprehensive geodatabase of temporal and spatial environmental information associated with the hydrogeologic units (alluvial aquifer, Goodland-Walnut confining unit, and Paluxy aquifer) beneath the facility and a three-dimensional conceptual model of the hydrogeologic units integrally linked to the geodatabase. The geodatabase design uses a thematic layer approach to create layers of feature data using a geographic information system. The various features are separated into relational tables in the geodatabase on the basis of how they interact and correspond to one another. Using the geodatabase, geographic data at the site are manipulated to produce maps, allow interactive queries, and perform spatial analyses. The conceptual model for the study area comprises computer-generated, three-dimensional block diagrams of the hydrogeologic units. The conceptual model provides a platform for visualization of hydrogeologic-unit sections and surfaces and for subsurface environmental analyses. The conceptual model is based on three structural surfaces and two thickness configurations of the study area. The three structural surfaces depict the altitudes of the tops of the three hydrogeologic units. The two thickness configurations are those of the alluvial aquifer and the Goodland-Walnut confining unit. The surface of the alluvial aquifer was created using a U.S. Geological Survey 10-meter digital elevation model. The 2,130 point altitudes of the top of the Goodland-Walnut unit were compiled from lithologic logs from existing wells, available soil-boring logs, and previous studies. Data from 120 wells, primarily from existing reports, were used to create a map of the approximate altitude of the Paluxy aquifer.

Texas↗

Geology and mineral resources of the Lake Valley area, Sierra County, New Mexico

At the request of the Bureau of Land Management, the U.S. Geological Survey assessed the Lake Valley Area of Critical Environmental Concern (ACEC), which includes the historic Lake Valley townsite and silver-manganese mining district, for undiscovered mineral resources. The Lake Valley ACEC is along the southeastern margin of the Black Range of western Sierra County, New Mexico. The Black Range contains eleven mining districts from which silver, lead, zinc, manganese, copper, gold, and tin have been recovered. As part of the study, an area of over 75 square mi (195 square km) in the area of the Lake Valley ACEC was mapped to understand ore controls and to assess mineral-resource potential. Lake Valley mining district is in Mississippian Lake Valley Formation carbonate rocks, but much of the surrounding terrane consists of volcanic rocks on the southeastern edge of the Emory cauldron which formed about 34.9 Ma. Volcanic rocks are part of the Mogollon-Datil volcanic province which include flows, breccias, ash-flow tuffs, and intrusive rhyolites. The Lake Valley mining district is located about 20 mi (32 km) south of the Late Cretaceous Laramide copper-gold porphyry intrusion at Hillsboro. It is also located at the western boundary of the Rio Grande rift basin.The Lake Valey fault is the major structural feature of the study area. Geological and geophysical data suggest the fault is composed of two segments: a southern, northwest-striking segment that may have a pre-Tertiary history and a northerly-striking segment that is part of the Emory cauldron ring fracture. The mining district is bounded by the southern, northwest-striking segment of the fault which may have up to 800 ft (240m) of normal offset. Deposit types identified in the Black Range, and for which we assess mineral potential, are Laramide porphyry, Laramide skarns, Laramide veins, gold placer, carbonate-hosted, volcanic-epithermal, and rhyolite tin; no Rio Grande Rift baritefluorite-galena deposits are known, but they are included in the assessment. The most likely deposits to be discovered in the Lake Valley district are carbonate-hosted silver-manganese deposits. These deposits could be deposited by hydrothermal fluids or be related to intrusion of Oligocene rhyolite or Laramide porphyry. An aeromagnetic high south of the district probably reflects a small felsic intrusion of unknown age. We assess the Lake Valley ACEC as having low to moderate potential for undiscovered carbonate-hosted deposits associated with volcanic rocks or Laramide porphyry plutons, and low potential for gold placer and rhyolite tin deposits.

New Mexico↗

Methods of analysis by the U.S. Geological Survey National Water Quality Laboratory-Determination of ammonium plus organic nitrogen by a Kjeldahl digestion method and an automated photometric finish that includes digest cleanup by gas diffusion

The National Water Quality Laboratory (NWQL) determined ammonium plus organic nitrogen (Kjeldahl nitrogen) by using semiautomated, block digester methods for filtered and whole-water samples from 1986 until October 1, 1991. During that time, phosphorus was determined by a persulfate digestion method. In 1991, projected increases in demand for both tests by the U.S. Geological Survey?s National Water-Quality Assessment Program led the NWQL to develop and validate methods for determining both analytes in a common digest. This report describes a rapid and accurate method to determine Kjeldahl nitrogen. The batch, high-temperature (block digester), Hg (II)-catalyzed digestion step used in the new methods I-2515-91/4515-91 is similar to U.S. Geological Survey methods I-2552-85/4552-85 and U.S. Environmental Protection Agency method 351.2 except that sample and reagent volumes are halved. Prepared digests are desolvated at 220 degrees Celsius (oC) and digested at 370oC in separate block digesters set at these temperatures, rather than in a single, temperatureprogrammed block digester. This approach permits 40 calibrants, reference materials, and samples to be digested and resolvated in about an hour. Ammonium ions originally present in samples, along with those released during the digestion step, are determined photometrically by an automated, salicylatehypochlorite Berthelot reaction procedure at a rate of 90 tests per hour. About 100 microliters of digest are required per determination. The upper concentration level is 10 milligrams per liter (mg/L) with a method detection level of 0.05 mg/L. Repeatability for a sample containing about 4.1 mg/L of Kjeldahl nitrogen in a high suspended-solids matrix is 3.1 percent. Between-day precision for the same sample is 4.8 percent. A gas diffusion cell in the air-segmented continuous flow analyzer eliminates particulates and ions that otherwise would interfere in the photometric finish. A singlechannel analyzer can process the resolvated digests from two pairs of block digesters each hour. Statistical analysis of paired data for about 1,500 samples determined by U.S. Geological Survey methods I-2552-85/4552- 85 and I-2515-91/4515-91 during method validation revealed a median concentration difference between the former and the latter methods of about 0.1 mg-N/L. This result was expected because digestion blank concentrations (nearly equal to 0.1 mg/L) were not subtracted from concentrations reported by methods I-2552-85/4552-85. A 10-year record of National Water Quality Laboratory Kjeldahl nitrogen blind blank concentration data also supports a step-change decrease in Kjeldahl nitrogen concentrations of about 0.1 mg/L after methods I-2552-85/4552-85 were replaced by methods I-2515-91/4515-91 on October 1, 1991. Somewhat larger concentration differences between the two methods were observed for a subset of about 350 samples with nitrate plus nitrite concentrations greater than 1 mg-N/L.

Open-File Report↗

Water-Quality Characteristics for Sites in the Tongue, Powder, Cheyenne, and Belle Fourche River Drainage Basins, Wyoming and Montana, Water Years 2001-05, with Temporal Patterns of Selected Long-Term Water-Quality Data

Water-quality sampling was conducted regularly at stream sites within or near the Powder River structural basin in northeastern Wyoming and southeastern Montana during water years 2001-05 (October 1, 2000, to September 30, 2005) to characterize water quality in an area of coalbed natural gas development. The U.S. Geological Survey, in cooperation with the Wyoming Department of Environmental Quality, characterized the water quality at 22 sampling sites in the Tongue, Powder, Cheyenne, and Belle Fourche River drainage basins. Data for general hydrology, field measurements, major-ion chemistry, and selected trace elements were summarized, and specific conductance and sodium-adsorption ratios were evaluated for relations with streamflow and seasonal variability. Trend analysis for water years 1991-2005 was conducted for selected sites and constituents to assess change through time. Average annual runoff was highly variable among the stream sites. Generally, streams that have headwaters in the Bighorn Mountains had more runoff as a result of higher average annual precipitation than streams that have headwaters in the plains. The Powder River at Moorhead, Mont., had the largest average annual runoff (319,000 acre-feet) of all the sites; however, streams in the Tongue River drainage basin had the highest runoff per unit area of the four major drainage basins. Annual runoff in all major drainage basins was less than average during 2001-05 because of drought conditions. Consequently, water-quality samples collected during the study period may not represent long-term water-quality con-ditions for all sites. Water-quality characteristics were highly variable generally because of streamflow variability, geologic controls, and potential land-use effects. The range of median specific-conductance values among sites was smallest in the Tongue River drainage basin. Median values in that basin ranged from 643 microsiemens per centimeter at 25 degrees Celsius (?S/cm at 25?C) on the Tongue River to 1,460 ?S/cm at 25?C on Prairie Dog Creek. The Tongue River drainage basin has the largest percentage of area underlain by Mesozoic-age and older rocks and by more resistant rocks. In addition, the higher annual precipitation and a steeper gradient in this basin compared to basins in the plains produce relatively fast stream velocities, which result in a short contact time between stream waters and basin materials. The Powder River drainage basin, which has the largest drainage area and most diverse site conditions, had the largest range of median specific-conductance values among the four major drainage basins. Median values in that basin ranged from 680 ?S/cm at 25?C on Clear Creek to 5,950 ?S/cm at 25?C on Salt Creek. Median specific-conductance values among sites in the Cheyenne River drainage basin ranged from 1,850 ?S/cm at 25?C on Black Thunder Creek to 4,680 ?S/cm at 25?C on the Cheyenne River. The entire Cheyenne River drainage basin is in the plains, which have low precipitation, soluble geologic materials, and relatively low gradients that produce slow stream velocities and long contact times. Median specific-conductance values among sites in the Belle Fourche River drainage basin ranged from 1,740 ?S/cm at 25?C on Caballo Creek to 2,800 ?S/cm at 25?C on Donkey Creek. Water in the study area ranged from a magnesium-calcium-bicarbonate type for some sites in the Tongue River drainage basin to a sodium-sulfate type at many sites in the Powder, Cheyenne, and Belle Fourche River drainage basins. Little Goose Creek, Goose Creek, and the Tongue River in the Tongue River drainage basin, and Clear Creek in the Powder River drainage basin, which have headwaters in the Bighorn Mountains, consistently had the smallest median dissolved-sodium concentrations, sodium-adsorption ratios, dissolved-sulfate concentrations, and dissolved-solids concentrations. Salt Creek, Wild Horse Creek, Little Powder River, and the Cheyenne River, which have headwat

Scientific Investigations Report↗

Development of a global land cover characteristics database and IGBP DISCover from 1 km AVHRR data

Researchers from the U.S. Geological Survey, University of Nebraska-Lincoln and the European Commission's Joint Research Centre, Ispra, Italy produced a 1 km resolution global land cover characteristics database for use in a wide range of continental-to global-scale environmental studies. This database provides a unique view of the broad patterns of the biogeographical and ecoclimatic diversity of the global land surface, and presents a detailed interpretation of the extent of human development. The project was carried out as an International Geosphere-Biosphere Programme, Data and Information Systems (IGBP-DIS) initiative. The IGBP DISCover global land cover product is an integral component of the global land cover database. DISCover includes 17 general land cover classes defined to meet the needs of IGBP core science projects. A formal accuracy assessment of the DISCover data layer will be completed in 1998. The 1 km global land cover database was developed through a continent-by-continent unsupervised classification of 1 km monthly Advanced Very High Resolution Radiometer (AVHRR) Normalized Difference Vegetation Index (NDVI) composites covering 1992-1993. Extensive post-classification stratification was necessary to resolve spectral/temporal confusion between disparate land cover types. The complete global database consists of 961 seasonal land cover regions that capture patterns of land cover, seasonality and relative primary productivity. The seasonal land cover regions were aggregated to produce seven separate land cover data sets used for global environmental modelling and assessment. The data sets include IGBP DISCover, U.S. Geological Survey Anderson System, Simple Biosphere Model, Simple Biosphere Model 2, Biosphere-Atmosphere Transfer Scheme, Olson Ecosystems and Running Global Remote Sensing Land Cover. The database also includes all digital sources that were used in the classification. The complete database can be sourced from the website: http://edcwww.cr.usgs.gov/landdaac/glcc/glcc.html.

International Journal of Remote Sensing↗

The Connecticut Streamflow and Sustainable Water Use Estimator—A decision-support tool to estimate water availability at ungaged stream locations in Connecticut

Freshwater streams in Connecticut are subject to many competing demands, including public water supply; agricultural, commercial, and industrial water use; and ecosystem and habitat needs. In recent years, drought has further stressed Connecticut’s water resources. To sustainably allocate and manage water resources among these competing uses, Federal, State, and local water-resource managers require data and modeling tools to estimate the water availability at a variety of temporal and spatial scales for planning purposes. The Connecticut Streamflow and Sustainable Water Use Estimator (CT SSWUE), developed by the U.S. Geological Survey in cooperation with the Connecticut Department of Energy and Environmental Protection, is a decision-support tool for estimating daily unaltered streamflow and sustainable water use at ungaged sites in Connecticut. The CT SSWUE estimates unaltered daily mean streamflow and water-use-adjusted streamflow for the period from October 1, 1960, to September 30, 2015, and the monthly sustainable net withdrawal at ungaged sites in Connecticut. Unaltered streamflow is the estimated daily mean streamflow in a drainage basin in the absence of any water withdrawals or wastewater discharges and with minimal human development. Sustainable net withdrawal is the maximum net withdrawal (withdrawal minus wastewater discharges) that can be drawn from a basin without critically depleting the water available through natural streamflow patterns. Sustainable net withdrawal is defined for this study as the difference between the unaltered daily mean streamflow and a user-defined target minimum streamflow. Weighted least squares and Tobit regression techniques were used to develop equations for estimating streamflow at ungaged sites at 19 streamflow quantiles with exceedance probabilities ranging from 0.005 to 99.995 percent. Regressions were based on streamflow quantiles and basin characteristics from 36 reference streamgages in and around Connecticut. Four basin characteristics—drainage area, mean of the soil permeability, mean of the average annual precipitation, and ratio of the length of streams that overlay sand and gravel deposits to the total length of streams in the basin—are used as explanatory variables in the equations. At an ungaged site, interpolation between the streamflow quantiles estimated from the regression equations produces a continuous flow-duration curve. A time series of daily mean streamflow at an ungaged site is then estimated by assuming that for each day, the streamflow quantile occurs on the same date at both a reference streamgage and the ungaged site. In a remove-one cross validation, estimated unaltered daily mean streamflow agreed well with observed values at reference streamgages, with a few exceptions. Nash Sutcliffe efficiency ranged from −0.43 to 0.97 with a median value of 0.88. The normalized root-mean-square error ranged from 16.6 to 120.4 percent with a median value of 34.5 percent. An empirical method for estimating 95-percent prediction intervals for unaltered daily and monthly mean streamflow was developed and tested by using the cross-validation data. Prediction intervals for unaltered daily mean streamflow at the cross-validation reference streamgages performed well in most cases. Gaged streamflow values from the cross-validation data fell within the prediction intervals a median 96.6 percent of the time for daily mean time series and 93.9 percent of the time for monthly mean time series. The CT SSWUE computes water-use-adjusted streamflow using spatially referenced water-use information provided by the Connecticut Department of Energy and Environmental Protection. Available water-use information included permitted and registered water withdrawals and permitted wastewater discharges during 1998 to 2015 for the Thames River Basin and central coastal drainage basins. Water-use information was incorporated into the U.S. Geological Survey StreamStats web application for Connecticut and can be used for computing water-use-adjusted streamflow and sustainable net withdrawal at selected points of interest. Altered daily streamflow is computed by applying average daily withdrawals and wastewater discharges to the water balance equation. Average daily surface water withdrawals and wastewater discharges are applied directly to the daily water balance equation. Time-lagged alterations on streamflow from groundwater withdrawals or wastewater discharges are estimated by using a response-coefficient method developed from results of previously published, calibrated groundwater models.

Connecticut↗

Environmental conditions and resources of southwestern Mississippi

The impending phase-out of Saturn V testing by the National Aeronautics and Space Administration at the Mississippi Test Facility (MTF) necessitates consideration of possible alternative uses for the Facility and surrounding region. To make a rapid and up-to-date study of pertinent environmental factors in that region, remote sensing techniques and data were used by discipline specialists in the U. S. Geological Survey, scientists in other Bureaus of the Department of the Interior and other agencies, and the Project Coordinator. Full cooperation was received from officials, planners, and business executives in Mississippi, as well as timely assistance from NASA Headquarters, the Manned Spacecraft Center/Houston, and the MTF staff. Results from a multi-sensor equipped RB-57F high altitude overflight on February 17, 1970, and a simultaneous helicopter overflight were compared with existing photographs, maps, reports, and locally collected field data to complete this report rapidly as a Geographic Applications Project of the EROS Program, U. S. Department of the Interior. Pertinent background materials, including a comprehensive, annotated bibliography of existing studies of the area, are attached. This report considers 19 potential uses of the MTF equipment, staff, and property in relation to 16 environmental factors.

Mississippi↗

An environmental assessment of hydrocarbons in mid-Atlantic shelf sediments: 1975-1976 USGS-BLM program

During 1975-1976, the U.S. Geological Survey (U.S.G.S.), in conjunction with the Bureau of Land Management and the Virginia Institute of Marine Sciences, carried out an environmental assessment program to establish baseline concentration levels of hydrocarbons in the surface sediments of the Mid-Atlantic Shelf where leasing for petroleum exploration is anticipated. Reported here are the results of the individual hydrocarbon analyses for 150 composite surfacesediment samples.

Open-File Report↗

Geophysical bed sediment characterization of the Androscoggin River from the former Chlor-Alkali Facility Superfund Site, Berlin, New Hampshire, to the state border with Maine, August 2009

The former Chlor-Alkali Facility in Berlin, New Hampshire, was listed on the U.S. Environmental Protection Agency National Priorities List in 2005 as a Superfund site. The Chlor-Alkali Facility lies on the east bank of the Androscoggin River. Elemental mercury currently discharges from that bank into the Androscoggin River. The nature, extent, and the speciation of mercury and the production of methyl mercury contamination in the adjacent Androscoggin River is the subject of continuing investigations. The U.S. Geological Survey, in cooperation with Region I of the U.S. Environmental Protection Agency, used geophysical methods to determine the distribution, thickness, and physical properties of sediments in the Androscoggin River channel at a small area of an upstream reference reach and downstream from the site to the New Hampshire&ndash;Maine State border. Separate reaches of the Androscoggin River in the study area were surveyed with surface geophysical methods including ground-penetrating radar and step-frequency electromagnetics. Results were processed to assess sediment characteristics including grain size, electrical conductivity, and pore-water specific conductance. Specific conductance measured during surface- and pore-water sampling was used to help interpret the results of the geophysical surveys. The electrical resistivity of sediment samples was measured in the laboratory with intact pore water for comparison with survey results. In some instances, anthropogenic features and land uses, such as roads and power lines affected the detection of riverbed properties using geophysical methods; when this occurred, the data were removed. Through combining results, detailed riverbed sediment characterizations were made. Results from ground-penetrating radar surveys were used to image and measure the depth to the riverbed, depth to buried riverbeds, riverbed thickness and to interpret material-type variations in terms of relative grain size. Fifty two percent of the riverbed in the study area was covered with gravel and finer sediments. The electrically resistive river water and sediment in this study area were conducive to the penetration of the ground-penetrating radar and step-frequency electromagnetic signals and allowed for effective sediment characterization by geophysical methods. The reach between the former Chlor-Alkali Facility and the Riverside Dam, had small areas of fine sediment (estimated 11 percent of riverbed area), found on the upstream left bank and the downstream right bank, with an electromagnetic conductivity (31.4 millisiemens per meter (mS/m) maximum) that was higher than the upstream reference reach. The greatest electromagnetic conductivity (195 mS/m), pore-water specific conductance (324 mS/m) and lab measured sediment conductivity of (76.8 mS/m, measured with a direct-current resistivity test box) in the study were measured approximately 1 mile (mi) downstream of the site from a sandbar on the left bank. Reaches adjacent to and within 2 mi downstream from the site had elevated electromagnetic conductivity despite having lower estimated percentages of riverbed area covered in sediment (11, 25, and 61 percent, respectively) than the reference reach (97). Typically finer grained sediment with similar mineralogy will be more conductive. The Shelburne Reservoir is approximately 8 mi downstream from the site had the second greatest pore-water specific conductance measured, 45.8 mS/m. Many of the locations with the largest step-frequency electromagnetic values have not been sampled for pore water and sediment.

New Hampshire↗

Water-quality distributions in the East Branch Black River near the Chemical Recovery Systems site in Elyria, Ohio, 2021

Autonomous underwater vehicles are uniquely designed to provide spatially dense water-quality data along with bathymetry and velocimetry. The U.S. Environmental Protection Agency Region 5 requested technical assistance from the U.S. Geological Survey in support of ongoing investigations at the Chemical Recovery Systems site to collect spatially dense water-quality and bathymetry data in the East Branch Black River in Elyria, Ohio. This report was prepared in cooperation with the U.S. Environmental Protection Agency to present the results of the autonomous underwater vehicle survey near the Chemical Recovery Systems site on March 22, 2021. Plots of distributions of water temperature, specific conductance, pH, and dissolved oxygen are presented that may help guide and focus future U.S. Environmental Protection Agency efforts at the site to determine the degree of groundwater/surface-water interaction.

Ohio↗

Methods of analysis by the U.S. Geological Survey National Water Quality Laboratory-Determination of the total phosphorus by a Kjeldahl digestion method and an automated colorimetric finish that includes dialysis

A method to determine total phosphorus (TP) in the same digests prepared for total Kjeldahl nitrogen (TKN) determinations is desribed. The batch, high-temperature (block digester), HG(II)-catalyzed digestion step is similar to U.S. Geological Survey methods I-2552-85/I-4552-85 and U.S. Environmental Protection Agency method 365.4 except that sample and reagent volumes are halved. Prepared digests are desolvated at 220 degrees Celsius and digested at 370 degrees Celsius in separate block digesters set at these temperatures, rather than in a single, temperature-programmed block digester. This approach is used in the method escribed here, which permits 40 calibrants, reference waters, and smaples to be digested and resolvated in about an hour. Orthophosphate ions originally present in samples, along with those released during the digestion step, are determined colorimetrically at a rate of 90 tests per hour by an automated version of the phosphoantimonylmolybdenum blue procedure. About 100 microliters of digest are required per determination. The upper concentration limit is 2 milligrams per liter (mg/L) with a method detection limt of 0.01 mg/L. Repeatability for a sample containing approximately 1.6 mg/L of TP in a high suspended-solids matrix is 0.7 percent. Between-day precision for the same sample is 5.0 percent. A dialyzer in the air-segmented continuous flow analyzer provides on-line digest cleanup, eliminated particulates that otherwise would interfere in the colorimetric finish. An single-channel analyzer can process the resolvated digests from two pairs of block digesters each hour. Paired t-test analysis of TP concentrations for approximately 1,600 samples determined by the new method (U.S. Geologial Survey methods I-2610-91 and I-4610-91) and the old method (U.S. Geological Survey methods I-2600-85 and I-4600-85) revealed positive bias in the former of 0.02 to 0.04 mg/L for surface-water samples in agreement with previous studies. Concentrations of total phosphorus detemrined for ground-water samples by both methods were statistically equivalent.

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