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At least 883 records · Page 49Linked to original sources

Triton's surface-atmosphere energy balance

We explore the energetics of Triton's surface-atmosphere system using a model that includes the turbulent transfer of sensible heat as well as insolation, reradiation, and latent heat transport. The model relies on a 1° by 1° resolution hemispheric bolometric albedo map of Triton for determining the atmospheric temperature, the N 2 frost emissivity, and the temperatures of unfrosted portions of the surface consistent with a frost temperature of ≅38 K. For a physically plausible range of heat transfer coefficients, we find that the atmospheric temperature roughly 1 km above the surface is approximately 1 to 3 K hotter than the surface. Atmospheric temperatures of 48 K suggested by early analysis of radio occultation data cannot be obtained for plausible values of the heat transfer coefficients. Our calculations indicate that Triton's N 2 frosts must have an emissivity well below unity in order to have a temperature of ≅38 K, consistent with previous results. We also find that convection over small hot spots does not significantly cool them off, so they may be able to act as continous sources of buoyancy for convective plumes, but have not explored whether the convection is vigorous enough to entrain particulate matter thereby forming a dust devil. Our elevated atmospheric temperatures make geyser driven plumes with initial upward velocities ≤10 m s −1 stagnate in the lower atmosphere. These “wimpy” plumes provide a possible explanation for Triton's “wind streaks.”

Icarus↗

A time-space model of graphite mineral systems

Increasing demand for graphite in energy storage systems warrants review of graphite ore genesis in a mineral systems framework. Orogenic graphite encompasses the metamorphic and orogenic mineral systems that produce flake graphite and hydrothermal vein (lump and chip) graphite deposits, respectively. A common feature of orogenic graphite deposits is an association with upper amphibolite- to granulite-facies metasedimentary rocks in continent-continent or continent-island arc collisional orogens. Orogenic flake graphite deposits form primarily through graphitization of organic carbon during regional metamorphism, but strain localization and partial melting of pelitic protoliths are likely important processes for graphite grade and quality enrichment. Orogenic vein graphite deposits precipitate from hydrothermal fluids, possibly derived from metamorphism or anatexis at depth. Decarbonation reactions in mixed calcareous-carbonaceous metasedimentary sequences are the most likely carbon sources for the veins. In contrast, intrusion-related graphite includes magmatic-hydrothermal and metamorphic mineral systems that form primarily in continental arc settings via the interaction of magmas with carbonaceous sedimentary packages. Magmatic-hydrothermal flake graphite deposits are hosted in plutonic and volcanic rocks, and result from the exsolution of CO 2 -CH 4 -rich fluids from melts contaminated by such packages. Contact metamorphism of carbonaceous sedimentary rocks by plutons produces some microcrystalline (amorphous) graphite deposits, including many in China. Compilation of geologic data from known graphite deposits globally suggests that pulses of carbon deposition in the Paleoproterozoic, Mesoproterozoic, and Neoproterozoic provided source carbon material. Subsequent supercontinent orogenesis at ca. 2,100 to 1,700 Ma (Columbia), ca. 1,300 to 1,000 Ma (Rodinia), and ca. 650 to 500 Ma (Gondwana) resulted in the genesis of orogenic flake and vein graphite deposits, where favorable geologic components overlapped with organic ± carbonate carbon-rich strata. Cryogenian deposition of graphite protoliths and Cryogenian – Cambrian metamorphic mineralization account for nearly 75% of all known resources globally and coincide with profound carbon isotope excursions and climate variability, implying a link with the global carbon budget. Comparatively few graphite deposits are associated with Pangea-forming orogens, attributed to less exhumation and/or denudation. High-temperature metasedimentary belts containing organic carbon-rich protoliths are most favorable for hosting orogenic flake graphite deposits, whereas sequences that also contain carbonate protoliths are favorable for orogenic graphite veins. Continent-scale orogenic belts may host both deposit types along with vanadium deposits. Use of a time-space mineral systems framework for graphite deposits can improve exploration models needed to ensure future supply of this critical mineral and provide insights into Earth’s long-term carbon cycle.

Mineralium Deposita↗

Geology and mineral resources of central Antioquia Department (Zone IIA), Colombia

This report summarizes the geology of an area of some 6000 square kilometers in the northern part of the Central Cordillera of the Colombian Andes. The area, in north-central Department of Antioquia, was mapped between 1964 and 1968 as part of the Inventario Minero Nacional (IMN) project. Mineral resources are summarized within a larger area, designated as subzone ILK of IMN Zone If, which comprises almost 22,000 sq. kin, including the area mapped geologically by IMN and additional areas mapped by other agencies. The oldest formation is a micaceous paragneiss of early Paleozoic or possibly late Precambrian age. A thick geosynclinal sedimentary series accumulated during the Paleozoic Era and became regionally metamorphosed to greenschist (locally amphibolite) facies during the Permian or early Triassic; these schists and gneisses are designated collectively as the Valdivia Group. The Permian(?) orogenic episode included intrusion of concordant syntectonic plutons, mostly of tonalitic composition. Rocks of unequivocal Triassic or Jurassic age are not recognized. The Cretaceous is well represented by both igneous and sedimentary assemblages. Eugeosynclinal alpine ophiolites comprising submarine basalt flows and numerous intrusions of gabbro and serpentinite are prominent in the Lower Cretaceous, together with flysch composed of marine shale and lesser sandstone and conglomerate. The Upper Cretaceous is represented along the west border of the mapped area by submarine basalt flows and pyroclastic rocks, locally Interbedded with fine-grained clastic sedimentary beds, and lenses of dark laminated chert, at least part of which is radiolarian. The Late Cretaceous was marked by an orogenic event that profoundly folded and faulted all rocks and in the Central Cordillera caused low-grade metamorphism, the overprint of which is hardly observable in pre-Cretaceous rocks elsewhere. The Late Cretaceous orogeny culminated with discordant intrusion of the epizonal tonalitic Antioquian batholith. Displacement along the great Romeral wrench fault may have begun in the Cretaceous. Plutonism continued into the Cenozoic, exemplified by the hornblende-diorite Sabanalarga pluton. Intermontane basins were filled with molasse derived from the erosion of adjacent highlands; Tertiary sedimentation in marshy areas included organic carboniferous matter subsequently converted to lignite or subbituminous coal. The Sabanalarga fault system originated in the Late Tertiary; intermittent displacement continued on the older wrench faults such as the Romeral. Epeirogenic uplift, which probably began in the Pliocene and continued through the Pleistocene and Holocene, brought on renewed erosion which has sculptured the mountains into their present form. Mineral resources in subzone IIA are varied but not of outstanding importance. Gold and silver mining, significant in past centuries, is minor today. Ferruginous laterite on serpentinite once considered as a potential source of iron ore is not economically exploitable. IMN has explored nickeliferous laterite at the extreme northwest corner of subzone IIA; this is a potential resource, exploitable only after exhaustion of the larger and richer nickel laterite deposit at Cerro Matoso, farther to the north and outside the boundaries of Zone If. Known deposits of mercury, chromium, manganese, and copper are small, with limited economic potential. Nonmetallic resources include raw materials for cement, including portland cement. Saprolite clay is widely used in making common red brick and tile, still a dominant construction material in all but the most modern multistory buildings. Aggregate materials are varied and abundant. Kaolin of good quality near La Union is important as a ceramic raw mineral filler. Tertiary subbituminous coal beds are an important energy resource in western subzone IIA, and have a good potential for greater development. Deposits of sodic feldspar, talc, decorative stone, and silica a

Open-File Report↗

Map showing outcrops of basaltic rocks of early Quaternary and Tertiary age, Basin and Range province, Southern California

This map report is one of a series of geologic and hydrologic maps covering all or parts of States within the Basin and Range province of the western United States. The map reports contain detailed information on subjects that characterize the geohydrology of the province, including the ground-water hydrology/ ground-water quality, surface distribution of selected rock types, tectonic conditions, areal geophysics, Pleistocene lakes and marshes, and mineral and energy resources. This is a part of the U.S. Geological Survey's program for geologic and hydrologic evaluation of the province to identify prospective regions for further study relative to isolation of high-level nuclear waste (Bedinger, Sargent, and Reed, 1984). This map was prepared from published geologic maps and reports utilizing the project guidelines defined in Sargent and Bedinger (1984). As used in this study, basaltic rocks include basaltic andesite and basalt. The map shows the known occurrences of basaltic rocks largely of Tertiary age. Locally, however, where basalts of Quaternary age were not differentiated from those of Tertiary age, the younger basalts have been included on the map. The Description of Map Units includes the geologic and, if available, radiometric age; lithology; thickness where available; and sources of data for the basaltic units in outlined and numbered areas within the counties of the study area. No information was available on the rock outcrops that are unnumbered. The listed radiometric ages do not necessarily represent the entire age range of a unit.

California↗

Heterogeneity in migration strategies of the whooping crane

Migratory birds use numerous strategies to successfully complete twice-annual movements between breeding and wintering sites. Context for conservation and management can be provided by characterizing these strategies. Variations in strategy among and within individuals support population persistence in response to changes in land use and climate. We used location data from 58 marked Whooping Cranes (Grus americana) from 2010–2016 to characterize migration strategies in the U.S. Great Plains and Canadian Prairies and southern boreal region, and to explore sources of heterogeneity in their migration strategy, including space use, timing, and performance. Whooping Cranes completed approximately 3,900-km migrations that averaged 29 days during spring and 45 days during autumn, while making 11–12 nighttime stops. At the scale of our analysis, individual Whooping Cranes showed little consistency in stopover sites used among migration seasons (i.e., low site fidelity). In contrast, individuals expressed a measure of consistency in timing, especially migration initiation date. Whooping Cranes migrated at different times based on age and reproductive status, where adults with young initiated autumn migration after other birds, and adults with and without young initiated spring migration before subadult birds. Time spent at stopover sites was associated with migration bout length and time spent at previous stopover sites, suggesting Whooping Cranes acquired energy resources at some stopover sites that they used to fuel migration. Whooping Cranes were faithful to a defined migration corridor but showed less fidelity in their selection of nighttime stopover sites; hence, spatial targeting of conservation actions may be better informed by associations with landscape and habitat features rather than documented past use at specific locations. The preservation of variation in migration strategies existing within this species that experienced a severe population bottleneck suggests that Whooping Cranes have maintained a capacity to adjust strategies when confronted with future changes in land use and climate.

Great Plains, Canadian Prairies↗

Water-quality conditions, and constituent loads and yields in the Cambridge drinking-water source area, Massachusetts, water years 2005–07

The source water area for the drinking-water supply of the city of Cambridge, Massachusetts, encompasses major transportation corridors, as well as large areas of light industrial, commercial, and residential land use. Because of ongoing development in the drinking-water source area, the Cambridge water supply has the potential to be affected by a wide variety of contaminants. The U.S. Geological Survey (USGS) has monitored surface-water quality in the Hobbs Brook and Stony Brook Basins, which compose the drinking-water source area, since 1997 (water year 1997) through continuous monitoring and discrete sample collection and, since 2004, through systematic collection of streamwater samples during base-flow and stormflow conditions at five primary sampling stations in the drinking-water source area. Four primary sampling stations are on small tributaries in the Hobbs Brook and Stony Brook Basins; the fifth primary sampling station is on the main stem of Stony Brook and drains about 93 percent of the Cambridge drinking-water source area. Water samples also were collected at six secondary sampling stations, including Fresh Pond Reservoir, the final storage reservoir for the raw water supply. Storm runoff and base-flow concentrations of calcium (Ca), chloride (Cl), sodium (Na), and sulfate (SO 4 ) were estimated from continuous records of streamflow and specific conductance for six monitoring stations, which include the five primary sampling stations. These data were used to characterize current water-quality conditions, estimate loads and yields, and describe trends in Cl and Na in the tributaries and main-stem streams in the Hobbs Brook and Stony Brook Basins. These data also were used to describe how streamwater quality is affected by various watershed characteristics and provide information to guide future watershed management. Water samples were analyzed for physical properties and concentrations of Ca, Cl, Na, and SO 4 , total nitrogen (TN), total phosphorus (TP), caffeine, and a suite of 59 polar pesticides. Values of physical properties and constituent concentrations varied widely, particularly in samples from tributaries. Median concentrations of Ca, Cl, Na, and SO4 in samples collected in the Hobbs Brook Basin (39.8, 392, 207, and 21.7 milligrams per liter (mg/L), respectively) were higher than those for the Stony Brook Basin (17.8, 87.7, 49.7, and 14.7 mg/L, respectively). These differences in major ion concentrations are likely related to the low percentages of developed land and impervious area in the Stony Brook Basin. Concentrations of dissolved Cl and Na in samples, and those estimated from continuous records of specific conductance (particularly during base flow), often were greater than the U.S. Environmental Protection Agency (USEPA) secondary drinking-water guideline for Cl (250 mg/L), the chronic aquatic-life guideline for Cl (230 mg/L), and the Commonwealth of Massachusetts, Executive Office of Energy and Environmental Affairs drinking-water guideline for Na (20 mg/L). Mean annual flow-weighted concentrations of Ca, Cl, and Na were generally positively correlated with the area of roadway land use in the subbasins. Correlations between mean annual concentrations of Ca and SO 4 in base flow and total roadway, total impervious, and commercial-industrial land uses were statistically significant. Concentrations of TN (range of 0.42 to 5.13 mg/L in all subbasins) and TP (range of 0.006 to 0.80 mg/L in all subbasins) in tributary samples did not differ substantially between the Hobbs Brook and Stony Brook Basins. Concentrations of TN and TP in samples collected during water years 2004–07 exceeded proposed reference concentrations of 0.57 and 0.024 mg/L, in 94 and 56 percent of the samples, respectively. Correlations between annual flow-weighted concentrations of TN and percentages of recreational land use and water-body area were statistically significant; however, no significant relation was found between TP and available land-use information. The volume of streamflow affected water-quality conditions at the primary sampling stations. Turbidity and concentrations of TP were positively correlated with streamflow. In contrast, concentrations of major ions were negatively correlated with streamflow, indicating that these constituents were diluted during stormflows. Concentrations of TN were not correlated with streamflow. Twenty-five pesticides and caffeine were detected in water samples collected in the drinking-water source area and in raw water collected from the Cambridge water-treatment facility intake at the Fresh Pond Reservoir. Imidacloprid, norflurazon, and siduron were the most frequently detected pesticides with the frequency of detections ranging from about 24 to 41 percent. Caffeine was detected in about 37 percent of water samples at concentrations ranging from 0.003 to 1.82 micrograms per liter (μg/L). Although some of the detected pesticides degrade rapidly, norflurazon and siduron are relatively stable and are able to immigrate though the serial reservoir system. Concentrations of 2,4-D, carbaryl, imazaquin, MCPA (2-methyl-4-chlorophenoxyacetic acid), metsulfuron-methyl, norflurazon, siduron, and caffeine were detected more frequently in stormflow samples than in base-flow samples. Concentrations of pesticides did not exceed USEPA drinking-water guidelines or other health standards and were several orders of magnitude less than the lethal exposure level established for several fish species common to the drinking-water source area. Imidacloprid, an insecticide, was the only pesticide with a concentration exceeding available long-term aquatic-life guidelines. Several pesticides correlated significantly with the amount of recreational, residential, and commercial area in the tributary subbasins. Mean annual base-flow concentrations of caffeine correlated significantly with parking-lot land use. For most tributaries, about 70 percent of the annual loads of Ca, Cl, Na, and SO 4 were associated with base flow. Upward temporal trends in annual loads of Cl and Na were identified on the basis of data for water years 1998 to 2008 for the outlet of the Cambridge Reservoir in the Hobbs Brook Basin; however, similar trends were not identified for the main stem of Stony Brook downstream from the reservoir. The proportions of the TN load attributed to base flow and stormflow were similar in each tributary. In contrast, more than 83 percent of the TP loads in the tributaries and about 73 percent of the TP load in main stem of Stony Brook were associated with stormflow. Mean annual yields of Ca, Cl, Na, and SO 4 in the Stony Brook Reservoir watershed, which represents most of the drinking-water source area, were 14, 85, 46, and 9 metric tons per square kilometer, respectively. Mean annual yields among the individual tributary subbasins varied extensively. Mean annual yields for the respective constituents increased with an increase in roadway and parking-lot area in the tributary subbasins. Mean annual yields of TN in the tributary subbasins ranged from about 740 to more than 1,200 kilograms per square kilometer and exceeded the yield for the main stem of Stony Brook at USGS station 01104460 upstream from the Stony Brook Reservoir. Mean annual yields estimated for the herbicides 2,4-D and imidacloprid ranged from 34 to 310 grams per square kilometer (g/km 2 ) and 3 to 170 g/km 2 , respectively. Annual loads for 2,4-D were entirely associated with stormflow. The largest annual load for imidacloprid was estimated for the main stem of Stony Brook; however, the highest annual yield for this pesticide, as well as for benomyl, carbaryl, metalaxyl, and propiconazole, was estimated for a tributary to the Stony Brook Reservoir that drains largely residential and recreational areas. Mean annual yields for the herbicide siduron ranged from 6.9 to 35 g/km 2 with most of the loads associated with stormflow. Mean annual yields for the insecticide diuron ranged from 2.1 to 4.4 g/km 2 . Annual yields of caffeine ranged from 11 to 410 g/km 2 .

Massachusetts↗

Fluid-driven uplift at Long Valley Caldera, California: Geologic perspectives

Since persistent seismicity began in the Sierra Nevada adjacent to Long Valley caldera in 1978–1980, intracaldera unrest has been marked by (1) episodes of uplift totaling ~ 83 cm, centered on the middle Pleistocene resurgent dome, and (2) recurrent earthquake swarms along a 12-km-long segment of the caldera's ring-fault zone that is contiguous with both the dome and the Sierran seismogenic domain. Others have attributed the recent unrest to magmatic intrusion(s), but it is argued here that evidence for new magma is lacking and that ongoing uplift and ring-fault-zone seismicity are both promoted by ascent of aqueous fluid released by second boiling of the residue of the enormous Pleistocene rhyolitic reservoir terminally crystallizing at depths ≥ 10 km. For 2 Myr, eruptive vent clusters migrated southwestward from Glass Mountain to Mammoth Mountain. There has been no eruption on the resurgent dome since 500 ka, and since 230 ka volcanism has been restricted to the caldera's west moat and contiguous Sierran terrain, both outside the structural caldera. High-temperature hydrothermal activity in the central caldera waned after ~ 300 ka, cooling the Pleistocene rhyolitic focus to the extent that drilling on the resurgent dome found mid-caldera temperature to be only 100 °C and isothermal at depths of 2–3 km. Beneath most of the resurgent dome, there is little seismicity at any depth, no emission of magmatic CO 2 or other magmatic gases, no elevated 3 He/ 4 He ratios, and only normal to below-normal heat flow. Most of the 75-km-long ring-fault zone is likewise aseismic, excepting only the 12-km segment contiguous with the extracaldera seismogenic domain in the Sierra. Since 1980, the Sierran seismicity has released 3.6 times more cumulative seismic energy than have intracaldera earthquakes. The caldera seismicity is not driven by stresses associated with the adjacent uplift but, instead, by the extracaldera tectonic stressfield. Sierran seismicity activated the directly contiguous south-moat segment of the ring-fault zone, which had originated in the caldera-forming eruption at 767 ka and everywhere else remains sealed. Hypocenter relocation studies of 1000s of earthquakes along the seismic segment have resolved recurrent upward-migrating swarms within networks of cryptic faults, apparently triggered by rapidly ascending pulses of high-pressure low-viscosity aqueous fluid. Entering the brittle crust at depths of 8–10 km, such fluid is just what should be expected from second boiling of the late-stage CO 2 -poor rhyolitic residue. The fluid provides the pressure source above the apex of the crystallizing caldera-wide pluton and then escapes laterally to the newly reactivated southern segment of the ring-fault zone, its only available permeable pathway, where it mediates the ongoing south-moat seismicity.

California↗

Comparative effects of energy-related saline wastewaters and sodium chloride on hatching, survival, and fitness-associated traits of two amphibian species

Salinity (sodium chloride [NaCl]) is a prevalent and persistent contaminant that negatively affects freshwater ecosystems. Although most studies focus on effects of salinity from road salts (primarily NaCl), high-salinity wastewaters from energy extraction (wastewaters) could be more harmful because they contain NaCl and other toxic components. Many amphibians are sensitive to salinity, and their eggs are thought to be the most sensitive life-history stage. However, there are few investigations with salinity that include eggs and larvae sequentially in long-term exposures. We investigated the relative effects of wastewaters from a large energy reserve, the Williston Basin (USA), and NaCl on northern leopard ( Rana pipiens ) and boreal chorus ( Pseudacris maculata ) frogs. We exposed eggs and tracked responses through larval stages (for 24 days). Wastewaters and NaCl caused similar reductions in hatching and larval survival, growth, development, and activity, while also increasing deformities. Chorus frog eggs and larvae were more sensitive to salinity than leopard frogs, suggesting species-specific responses. Contrary to previous studies, eggs of both species were less sensitive to salinity than larvae. Our ecologically relevant exposures suggest that accumulating effects can reduce survival relative to starting experiments with unexposed larvae. Alternatively, egg casings of some species may provide some protection against salinity. Notably, effects of wastewaters on amphibians were predominantly due to NaCl rather than other components. Therefore, findings from studies with other sources of increased salinity (e.g., road salts) could guide management of wastewater-contaminated ecosystems, and vice versa, to mitigate effects of salinization.

Montana, Wyoming↗

Potential impacts of groundwater pumping on stream temperature are greatest in streams with substantial cold groundwater inflows

Groundwater pumping-induced reductions in streamflow (known as ‘streamflow depletion’) have been documented worldwide, but potential impacts of streamflow depletion on stream temperature are not well understood. Here, we use two types of models to identify potential impacts of pumping on stream temperature across the conterminous United States (CONUS) to determine which aspects of a stream's annual thermograph (thermal signatures) can be used to monitor and manage streamflow depletion impacts on stream temperature. We used long-term streamflow and stream temperature data from 30 streamgages across CONUS and surrogate models of streamflow depletion to analyse potential stream temperature impacts at each site. We compared two different stream temperature modelling approaches: (i) a process-based energy balance model and (ii) statistical regression models based on air temperature and stream discharge. We calculated a suite of thermal signatures under depleted and non-depleted conditions for each stream and found that maximum annual 7-day temperature and annual temperature range are potentially the most sensitive to streamflow depletion, with potential changes of at least 2°C at > 70% of the sites when using the process-based model. We also found that the regression-based models predicted much less sensitivity of stream temperature to streamflow depletion than the process-based model. This work provides an initial evaluation and sensitivity analysis of the potential impacts of streamflow depletion on stream temperature. We demonstrate that stream temperature may be most sensitive to pumping in streams with a high proportion of flow sourced from relatively cold groundwater inputs, and that regression-based stream temperature models may underpredict stream temperature changes caused by streamflow depletion.

conterminous United States↗

Hydrodynamics of a bathymetrically complex fringing coral reef embayment: Wave climate, in situ observations, and wave prediction

This paper examines the relationship between offshore wave climate and nearshore waves and currents at Hanalei Bay, Hawaii, an exposed bay fringed with coral reefs. Analysis of both offshore in situ data and numerical hindcasts identify the predominance of two wave conditions: a mode associated with local trade winds and an episodic pattern associated with distant source long-period swells. Analysis of 10 months of in situ data within the bay show that current velocities are up to an order of magnitude greater during long-period swell episodes than during trade wind conditions; overall circulation patterns are also fundamentally different. The current velocities are highly correlated with incident wave heights during the swell episodes, while they are not during the modal trade wind conditions. A phase-averaged wave model was implemented with the dual purpose of evaluating application to bathymetrically complex fringing reefs and to examine the propagation of waves into the nearshore in an effort to better explain the large difference in observed circulation during the two offshore wave conditions. The prediction quality of this model was poorer for the episodic condition than for the lower-energy mode, however, it illustrated how longer-period swells are preferentially refracted into the bay and make available far more nearshore wave energy to drive currents compared to waves during modal conditions. The highly episodic circulation, the nature of which is dependent on complex refraction patterns of episodic, long-period swell has implications for flushing and sediment dynamics for incised fringing reef-lined bays that characterize many high islands at low latitudes around the world.

Hawai'i↗

Do postlarval amphidromous fishes transport marine‐derived nutrients and pollutants to Caribbean streams?

Diadromous fishes are known biotransport vectors that can move nutrients, energy and contaminants in an upstream direction in lotic ecosystems. This function has been demonstrated repeatedly in anadromous salmonids, but the role of other diadromous species, especially tropical taxa, as biotransport vectors is less studied. Amphidromous fish species exhibit potential to act as upstream vectors of nutrients and contaminants in their postlarval and juvenile stages, but this role is largely unknown because of limited understanding of larval growth habitats. Moreover, because some species are harvested in artisanal fisheries as postlarvae, and postlarvae are consumed by riverine and estuarine predators, heavy contaminant loads may present a human or wildlife health concern. This research incorporates stable isotope and contaminant analyses to infer larval habitats and contaminant accumulation of amphidromous fishes on the Caribbean island of Puerto Rico. The isotopic signatures of postlarval amphidromous fishes indicated marine basal sources and food web components, rather than those from riverine habitats. Additionally, postlarvae did not contain concentrations of anthropogenic pollutants that would be of ecological or human health concern. These findings are the first and strongest evidence that amphidromous fish postlarvae function as biotransport vectors of marine nutrients into and up river ecosystems without posing a health threat to the receiving food web or human consumers.

Ecology of Freshwater Fish↗

Sand resources, regional geology, and coastal processes of the Chandeleur Islands Coastal System: An evaluation of the Breton National Wildlife Refuge

Breton National Wildlife Refuge, the Chandeleur Islands chain in Louisiana, provides habitat and nesting areas for wildlife and is an initial barrier protecting New Orleans from storms. The U.S. Geological Survey (USGS) in partnership with the University of New Orleans Pontchartrain Institute for Environmental Sciences undertook an intensive study that included (1) an analysis of island change based on historical maps and remotely sensed shoreline and topographic data; (2) a series of lidar surveys at 3- to 4-month intervals after Hurricane Katrina to determine barrier island recovery potential; (3) a discussion of sea level rise and effects on the islands; (4) an analysis of sea floor evolution and sediment dynamics in the refuge over the past 150 years; (5) an assessment of the local sediment transport and sediment resource availability based on the bathymetric and subbottom data; (6) a carefully selected core collection effort to groundtruth the geophysical data and more fully characterize the sediments composing the islands and surrounds; (7) an additional survey of the St. Bernard Shoals to assess their potential as a sand resource; and (8) a modeling study to numerically simulate the potential response of the islands to the low-intensity, intermediate, and extreme events likely to affect the refuge over the next 50 years. Results indicate that the islands have become fragmented and greatly diminished in subaerial extent over time: the southern islands retreating landward as they reorganize into subaerial features, the northern islands remaining in place. Breton Island, because maintenance of the Mississippi River-Gulf Outlet (MRGO) outer bar channel requires dredging, is deprived of sand sufficient to sustain itself. Regional sediment transport trends indicate that large storms are extremely effective in transporting sand and controlling the shoreline development and barrier island geometry. Sand is transported north and south from a divergent zone near Monkey Bayou at the southern end of the Chandeleur Islands. Numerical simulation of waves and sediment transport supports the geophysical results and indicates that vast areas of the lower shoreface are affected and are undergoing erosion during storm events, that there is little or no fair weather mechanism to rework material into the littoral system, and that as a result, there is a net loss of sediment from the system. Lidar surveys revealed that the island chain immediately after Hurricane Katrina lost about 84 percent of its area and about 92 percent of its prestorm volume. Marsh platforms that supported the islands’ sand prior to the storm were reduced in width by more than one-half. Repeated lidar surveys document that in places the shoreline has retreated about 100 m under the relatively low-energy waves since Hurricanes Katrina and Rita; however, this retreat is nonuniform. Recent high-resolution geophysical surveys of the sea floor and subsurface within 5–6 km of the Chandeleur Islands during 2006 and 2007 show that, in addition to the sand that is rebuilding portions of the island chain, a large volume of sand is contained in Hewes Point, in an extensive subtidal spit platform that has formed at the northern end of the Chandeleur Islands. Hewes Point appears to be the depositional terminus of the alongshore transport system. In the southern Chandeleurs, sand is being deposited in a broad tabular deposit near Breton Island called the southern offshore sand sheet. These two depocenters account for approximately 70 percent of the estimated sediment volume located in potential borrow sites. An additional large potential source of sand for restoration lies in the St. Bernard Shoals, which are estimated to contain approximately 200 × 10 6 m 3 of sand. Successful restoration planning for the Breton National Wildlife Refuge should mimic the natural processes of early stages of barrier island evolution including lateral transport to the flanks of the island chain from a centralized sand source that will ultimately enhance the ability of the islands to naturally build backbarrier marsh, dunes, and a continuous sandy shoreline. Barrier island sediment nourishment should be executed with the understanding that gulf shoreline erosion is inevitable but that island area can be maintained and enhanced during retreat (thus significantly prolonging the life of the island chain) with strategic sand placement.

Louisiana↗

Imaging P and S attenuation in the Sacramento-San Joaquin Delta region, northern California

We obtain 3-D Qp and Qs models for the Delta region of the Sacramento and San Joaquin Rivers, a large fluvial-agricultural portion of the Great Valley located between the Sierra Nevada batholith and the San Francisco Bay - Coast Ranges region of active faulting. Path attenuation t* values have been obtained for P and S data from 124 distributed earthquakes, with a longer variable window for S based on the energy integral. We use frequency dependence of 0.5 consistent with other studies, and weakly favored by the t* S data. A regional initial model was obtained by solving for Q as a function of velocity. In the final model, the Great Valley basin has low Q with very low Q (<50) for the shallowest portion of the Delta. There is an underlying strong Q contrast to the ophiolite basement which is thickest with highest Q under the Sacramento basin, and a change in structure is apparent across the Suisun Bay as a transition to thinner ophiolite. Moderately low Q is found in the upper crust west of the Delta region along the faults in the eastern North Bay Area, while, moderately high Q is found south of the Delta, implying potentially stronger ground motion for earthquake sources to the south. Very low Q values in the shallow crust along parts of the major fault zones may relate to sediment and abundant microfractures. In the lower crust below the San Andreas and Calaveras-Hayward-Rodgers Creek fault zones, the observed low Q is consistent with grain-size reduction in ductile shear zones and is lowest under the San Andreas which has large cumulative strain. Similarly moderately low Q in the ductile lower crust of the Bay Area block between the major fault zones implies a broad distributed shear zone.

California↗

Groundwater flow, heat transport, and water table position within volcanic edifices: Implications for volcanic processes in the Cascade Range

The position of the water table within a volcanic edifice has significant implications for volcano hazards, geothermal energy, and epithermal mineralization. We have modified the HYDROTHERM numerical simulator to allow for a free-surface (water table) upper boundary condition and a wide range of recharge rates, heat input rates, and thermodynamic conditions representative of continental volcano-hydrothermal systems. An extensive set of simulations was performed on a hypothetical stratovolcano system with unconfined groundwater flow. Simulation results suggest that the permeability structure of the volcanic edifice and underlying material is the dominant control on water table elevation and the distribution of pressures, temperatures, and fluid phases at depth. When permeabilities are isotropic, water table elevation decreases with increasing heat flux and increases with increasing recharge, but when permeabilities are anisotropic, these effects can be much less pronounced. Several conditions facilitate the ascent of a hydrothermal plume into a volcanic edifice: a sufficient source of heat and magmatic volatiles at depth, strong buoyancy forces, and a relatively weak topography-driven flow system. Further, the plume must be connected to a deep heat source through a pathway with a time-averaged effective permeability ???1 ?? 10-16 m2, which may be maintained by frequent seismicity. Topography-driven flow may be retarded by low permeability in the edifice and/or the lack of precipitation recharge; in the latter case, the water table may be relatively deep. Simulation results were compared with observations from the Quaternary stratovolcanoes along the Cascade Range of the western United States to infer hydrothermal processes within the edifices. Extensive ice caps on many Cascade Range stratovolcanoes may restrict recharge on the summits and uppermost flanks. Both the simulation results and limited observational data allow for the possibility that the water table beneath the stratovolcanoes is relatively deep.

Journal of Geophysical Research B: Solid Earth↗

Nanoscale molecular fractionation of organic matter within unconventional petroleum source beds

Fractionation of petroleum during migration through sedimentary rock matrices has been observed across lengths of meters to kilometers. Selective adsorption of specific chemical moieties at mineral surfaces and/or the phase behavior of petroleum during pressure changes typically are invoked to explain this behavior. Such phenomena are of interest as they impact both the quality and recoverability of petroleum resources. Given the current emphasis on unconventional (continuous) resources, there is a need to understand petroleum fractionation occurring during expulsion and migration at the nanometer to micron scale, due to the fine-grained nature of petroliferous mudrocks. Here, organic matter compositional differences observed within kukersites (petroleum source beds containing acritarch Gloeocapsomorpha prisca) and the overlying carbonate reservoir layer from the Ordovician Stonewall Formation are explored using a suite of spectroscopic methods, primarily through atomic force microscopy based infrared spectroscopy (AFM-IR). AFM-IR is capable of providing spatial resolutions approaching 50 nm and allows for assessment of the molecular fingerprint of kukersite organic matter across transition zones from organic-rich ‘source’ layers into neighboring carbonate ‘reservoir’ layers ~150 μm away. Results indicate that organic matter composition begins to vary immediately following expulsion from source layers, with loss of carbonyl groups and a concomitant decrease in alkyl chain-length, as migration distance increases. These chemical transitions correlate with a decrease in fluorescence intensity, increase in solid bitumen reflectance, and increase in Raman aromaticity proxies (D-G band separation) in the organic matter. Our findings are consistent with the retention of polar compounds onto mineral grains during expulsion and migration, following primary cracking and bituminization of the Gloeocapsomorpha prisca kerogen.

Energy and Fuels↗

Reflected seismic waves and their effect on strong shaking during the 1989 Loma Prieta, California, earthquake

Our data indicate that critical and postcritical reflections from crustal layers and the Moho produced increased shaking at discrete distances along the San Francisco Peninsula during the 1989 Loma Prieta earthquake. These reflections may have produced an increase in amplitude that is as much as 10 times greater than that of the direct arrival. Peak amplitude-distance patterns measured from explosive sources, synthetic seismograms, aftershocks, and the mainshock of the 1989 Loma Prieta earthquake indicate that (1) point sources, such as explosions, produce similar peak amplitude-distance relations as distributed, double-couple sources when the crustal structure is approximately a Poisson solid; (2) peak amplitudes from smaller point sources (explosions) may be scaled to those of larger sources (earthquakes); and (3) reflections caused a pattern of high amplitudes at specific distances along the San Francisco Peninsula that geographically correlates with areas of reported damage following from the Loma Prieta mainshock. Our study indicates that critical and postcritical reflections were stronger influences on the locations of strong shaking than local geology because a number of sites around the San Francisco Bay that are underlain by unconsolidated sediments experienced much less shaking than sites that were underlain by hard rock. Furthermore, some severely shaken hard-rock sites were farther from the epicenter than many of the less severely shaken “soft-sediment” sites. Models of the regional crustal structure and seismic-wave propagation paths may be useful in identifying sites around the San Francisco Bay region that are at risk due to reflected seismic energy, and this type of analysis may be useful in other seismically active regions.

California↗

Ship Shoal as a prospective borrow site for barrier island restoration, coastal south-central Louisiana, Usa: Numerical wave modeling and field measurements of hydrodynamics and sediment transport

Ship Shoal, a transgressive sand body located at the 10 m isobath off south-central Louisiana, is deemed a potential sand source for restoration along the rapidly eroding Isles Dernieres barrier chain and possibly other sites in Louisiana. Through numerical wave modeling we evaluate the potential response of mining Ship Shoal on the wave field. During severe and strong storms, waves break seaward of the western flank of Ship Shoal. Therefore, removal of Ship Shoal (approximately 1.1 billion m 3 ) causes a maximum increase of the significant wave height by 90%–100% and 40%–50% over the shoal and directly adjacent to the lee of the complex for two strong storm scenarios. During weak storms and fair weather conditions, waves do not break over Ship Shoal. The degree of increase in significant wave height due to shoal removal is considerably smaller, only 10%–20% on the west part of the shoal. Within the context of increasing nearshore wave energy levels, removal of the shoal is not significant enough to cause increased erosion along the Isles Dernieres. Wave approach direction exerts significant control on the wave climate leeward of Ship Shoal for stronger storms, but not weak storms or fairweather. Instrumentation deployed at the shoal allowed comparison of measured wave heights with numerically derived wave heights using STWAVE. Correlation coefficients are high in virtually all comparisons indicating the capability of the model to simulate wave behavior satisfactorily at the shoal. Directional waves, currents and sediment transport were measured during winter storms associated with frontal passages using three bottom-mounted arrays deployed on the seaward and landward sides of Ship Shoal (November, 1998–January, 1999). Episodic increases in wave height, mean and oscillatory current speed, shear velocity, and sediment transport rates, associated with recurrent cold front passages, were measured. Dissipation mechanisms included both breaking and bottom friction due to variable depths across the shoal crest and variable wave amplitudes during storms and fair-weather. Arctic surge fronts were associated with southerly storm waves, and southwesterly to westerly currents and sediment transport. Migrating cyclonic fronts generated northerly swell that transformed into southerly sea, and currents and sediment transport that were southeasterly overall. Waves were 36% higher and 9% longer on the seaward side of the shoal, whereas mean currents were 10% stronger landward, where they were directed onshore, in contrast to the offshore site, where seaward currents predominated. Sediment transport initiated by cold fronts was generally directed southeasterly to south-westerly at the offshore site, and southerly to westerly at the nearshore site. The data suggest that both cold fronts and the shoal, exert significant influences on regional hydrodynamics and sediment transport.

Journal of Coastal Research↗

Continuous gravity and tilt reveal anomalous pressure and density changes associated with gas pistoning within the summit lava lake of Kīlauea Volcano, Hawaiʻi

Gas piston events within the summit eruptive vent of Kīlauea Volcano, Hawai‘i, are characterized by increases in lava level and by decreases in seismic energy release, spattering, and degassing. During 2010–2011, gas piston events were especially well manifested, with lava level rises of tens of meters over the course of several hours, followed by a sudden drop to preevent levels. The changes in lava level were accompanied by directly proportional changes in gravity, but ground deformation determined from tilt was anticorrelative. The small magnitude of the gravity changes, compared to the large changes in volume within the vent during gas pistons, suggests that pistoning involves the accumulation of a very low‐density (100–200 kg/m 3 ) foam at the top of the lava column. Co‐event ground tilt indicates that rise in lava level is paradoxically associated with deflation (the opposite is usually true), which can be modeled as an increase in the gas content of the magma column between the source reservoir and the surface. Gas pistoning behavior is therefore associated with not only accumulation of a shallow magmatic foam but also more bubbles within the feeder conduit, probably due to the overall decrease in gas emissions from the lava lake during piston events.

Hawai'i↗