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At least 883 records · Page 49Linked to original sources
USGS1983

Role of fluid mixing and fault-related sulfide in the origin of the Ray Point uranium district, south Texas

The Lamprecht and Felder deposits are roll-type deposits hosted by the Miocene Oakville Sandstone. Four distinct stages of FeS 2 mineral formation are recognized: (1) a generation of isotopically light (delta 34 S < -20 per mil) preore pyrite, (2) a generation of isotopically light (delta 34 S < -20 per mil) marcasite that formed mostly before, but also during ore deposition, (3) a postore generation of isotopically heavy pyrite (delta 34 S > 0 per mil), and (4) a yet later generation of marcasite with isotopically light sulfur close to the values of stages 1 and 2. Complex zone of mixing between saline brines migrating up the fault from depth and oxygenated meteoric water recharging at the outcrop. Bacterial activity.

Economic Geology↗
USGS1983

The mobility and distribution of heavy metals during the formation of first cycle red beds

Holocene-Pliocene sequence sampled in northern Baja California. Geochemical data supported by petrographic, X-ray, and SEM observations of mineralogical transformations, fission-track radiography, and uranium decay series measurements. Results indicate that metal content of the studied samples is inherited from constituent detrital minerals and that reddening of whole-rock samples does not promote major open-system migration of heavy metals. The amount of secondary iron oxides and the fraction of whole-rock metals associated with the oxides increase during red-bed development. Results suggest that developed red beds which are well flushed by suitable pore fluids may be sources of significant quantities of heavy metals.

Economic Geology↗
USGS1983

Hydrothermal alteration of graywacke and basalt by 4 m NaCl

Separate experiments at 350 degrees C and 500 bars at a rock/fluid ratio of 1/10. Illite, dolomite, and quartz amounting to 67 percent of the original graywacke, were converted to albite and smectite. The rock gained Na and released Ca, K, heavy metals, and CO 2 to solution. In sharp contrast, the reaction of 4 m NaCl with basalt produced only minor alteration. Albitization of graywacke produces H (super +) whereas albitization of basalt apparently consumes H (super +) . All experiments to date that have reacted basalt with sea water, natural brine, and fully saturated NaCl over a variety of conditions have been unsuccessful in producing a spilite alteration assemblage.

Economic Geology↗
USGS1984

Textural and stable isotope studies of the Big Mike cupriferous volcanogenic massive sulfide deposit, Pershing County, Nevada

The massive ore contains two major generations of pyrite, a fine and a coarse grained, both of which show a striking variety of textures involving quartz. Framboidal pyrite in the argillite host rock has delta 34 S values of approximately -24 per mil indicating the presence of a euxinic environment. The delta 34 S values of fine-grained pyrite in the massive ore range from degrees 6.4 to + or -2.0 per mil; those of coarse-grained pyrite range from -3.5 to + or -5.5 per mil. A significant portion of the isotopically light sulfur for the early, fine-grained hydrothermal pyrite in the massive lens was probably derived from framboidal biogenic pyrite in interflow sediments of the underlying greenstone pillow lavas. Microcrystalline quartz in massive ore, hanging-wall jasper, footwall hydrothermal chert and coarse quartz from hanging-wall and footwall stringer zones have delta 18 O values between 15.6 and 19.6 per mil; one sample of vein hematite has a value of 4.4 per mil. The combined sulfur and oxygen isotope and textural data indicate that much of the material in the massive lens originally precipitated as fine-grained pyrite or as a precursor iron sulfide along with some silica from a hydrothermal plume similar to those recently observed at the East Pacific Rise spreading center at lat 21 degrees N. The primary material underwent recrystallization, mineralization, and late-stage quartz deposition in the presence of later fluids which had distinctly different sulfur isotope compositions.

Economic Geology↗
USGS1984

Systematics of stretching of fluid inclusions; I. Fluorite and sphalerite at 1 atmosphere confining pressure

More than 1,300 measurements on fluid inclusions in fluorite and sphalerite indicate that stretching proceeds systematically and predictably. In order to generate internal pressures that are sufficiently high to cause stretching, most inclusions must be heated beyond their initial homogenization temperatures, i.e., overheated. The amount of overheating necessary to initiate stretching depends on the P-V-T-X properties of the inclusion fluid, the inclusion size and shape, physical properties of the host mineral, and the confining pressure. In the range of homogenization temperatures and salinities examined in this study, the amount of overheating necessary to initiate stretching of inclusions in fluorite is inversely related to inclusion volume. The results of this study show that the measured homogenization temperature of a fluid inclusion may be considerably higher than the true homogenization temperature if the internal pressure reached sufficiently high values during previous testing in the laboratory or, less likely, during postentrapment thermal events in nature. The systematic relationship between the internal pressure necessary to initiate stretching and the inclusion volume provides a means of recognizing previously stretched inclusions and estimating the magnitude of postentrapment thermal events. Furthermore, reproducibility of homogenization temperature measurements, lack of microscopically observable fractures in the inclusion walls, and the lack of a noticeable increase in the vapor bubble size after heating are insufficient to prove that an inclusion has not stretched.

Economic Geology↗
USGS1984

The Balmat-Edwards zinc-lead deposits; synsedimentary ore from Mississippi Valley-type fluids

Reconstruction of some aspects of the initial environment of ore deposition through detailed S, C, and O isotope studies of the Fowler orebody, and through reconnaissance trace element and S isotope studies of sphalerite concentrates and composite samples of ore from 22 orebodies; and (2) evaluation of the effects of high-grade metamorphism on the stable isotope geochemistry of both the ore and gangue minerals of a massive sulfide orebody. The delta 34 S values of pyrite, sphalerite, and galena in the Fowler orebody range from 11.5 to 17.5 per mil; anhydrite associated with ore ranges from 25.6 to 27.0 per mil. Average equilibration temperatures calculated from the delta 34 S differences between coexisting sulfur-bearing phases are 388 degrees C for pyrite-sphalerite, 338 degrees C for sphalerite-galena, 329 degrees C for pyrite-galena, and 602 degrees C for anhydrite-pyrite; all pairs display narrow temperature distributions. The delta 13 C and delta 18 O values of carbonates from the Fowler orebody range from -1.6 to 1.4 per mil and from 24.8 to 27.0 per mil, respectively; quartz delta 18 O values range from 23.0 to 27.0 per mil. The delta 34 S values of sphalerite concentrated from composite samples of the orebodies range from 12.7 to 14.7 per mil. This narrow range contrasts sharply with the wide variability of associated evaporitic anhydrite lenses, which range from 8 to 28 per mil. A stratigraphic increase in the delta 34 S value of the evaporitic anhydrite at Balmat, and large sulfide iron-formation occurrences near Balmat, imply that bacterial sulfate reduction occurred on an unusually large scale during Balmat sedimentation. The presence of such an increase in a sedimentary section may constitute a valuable exploration guide.

Economic Geology↗
USGS1984

Application of mineral-solution equilibria to geochemical exploration for sandstone-hosted uranium deposits in two basins in west central Utah

A geochemical survey utilizing mainly ground waters was conducted in the Milford and Beaver basins. Waters were collected mainly from wells and springs at 100 sites and analyzed for major and minor elements. A computer model (WATEQ3) was used to calculate the redox potential and the state of saturation of the waters with respect to uraninite, coffinite, and other mineral phases. Several areas in the basins were shown to have ground-water environments of reducing redox potentials which are favorable for precipitation of reduced uranium minerals. In addition, the ground waters in some of these areas were shown to be saturated or near saturation with respect to uraninite and coffinite. These areas do not necessarily coincide with areas containing the highest concentrations of uranium in ground water. The methods described in this study for hydrogeochemical exploration for sandstone-hosted uranium deposits may have wide application, particularly throughout those filled basins in the western United States where nearby sources for uranium exist.

Economic Geology↗
USGS1984

U-Pb isotope systematics and apparent ages of uranium ores, Ambrosia Lake and Smith Lake districts, Grants mineral belt, New Mexico

Orebodies occur in continental sandstones of the Upper Jurassic Morrison Formation and comprise two main types of mineralization; primary ore formed early in the history of the host rock and resulted in tabular, peneconcordant orebodies rich in organic material; redistributed ore apparently was formed by oxidative destruction and reconcentration of primary ore at some time after Laramide deformation and resulted in roll-type orebodies lacking organic material. U-Pb isotope ages of four redistributed ores from the Ambrosia Lake District give concordant to nearly concordant ages of 3.3 to 12.5 m.y., supporting the concept that most redistributed ore formed in the late Tertiary or later. U-Pb isotope ages of primary ores from the Ambrosia Lake District show pronounced normal discordance, evidently due to coupled, continuous loss of Pb and radioactive daughters of 238 U. Data for ores from the Smith Lake District consistently give pre-Tertiary apparent ages.

Economic Geology↗
USGS1984

U-Th-Pb isotope chronology of sulfide ores and rocks in the early Proterozoic metavolcanic belt of northern Wisconsin

Lead was probably derived from 3.7-b.y.-old source material about 1.8 to 1.9 b.y. ago. Data on metavolcanic and granitic rocks from the belt show that the U-Th-Pb systems in most were reset about 1.6 b.y. ago; a time of shearing and retrogressive metamorphism. A concordia plot of the whole-rock lead data shows that many of the rocks lost lead relative to uranium and thorium during the interval 200 to 400 m.y. ago. Similar ores might be sought between the northern Wisconsin metavolcanic belt and the Upper Mississippi Valley because the lead lost from the basement there might be available for ore formation in overlying units. The lead in the early Proterozoic metavolcanic belt of northern Wisconsin seems to have been derived from the same mantle parent as the late Archean metavolcanic belts of northeastern Minnesota and southern Ontario.

Economic Geology↗
USGS1984

Geophysical methods as mapping tools in a strata-bound gold deposit: Haile mine, South Carolina slate belt

Very low frequency electromagnetic, magnetic, and induced polarization methods. The very low frequency electromagnetic resistivity data show high resistivity zones that correlate with siliceous units known to host the gold. The magnetic data clearly identify the mafic and ultramafic dikes which cut metasediments and also fill faults that offset them. The induced polarization method allows examination of the mineralized metasediments in two dimensions by giving vertical sections of resistivity and percent frequency effect, parameters which correlate with silica and pyrite content, respectively. Lithologic units as well as ore zones can thus be mapped in this terrain which is deeply weathered and partially covered by coastal plain sediments.

Economic Geology↗
USGS1984

Uranium mineralization in response to regional metamorphism at Lilljuthatten, Sweden

Analyses of six mineralized and five nonmineralized whole-rock drill core samples from the uranium deposit at Lilljuthatten yield a lead-lead isochron age of 420 + or - 1 m.y. This age corresponds to the last stage of the Caledonian Orogeny. None of the isotopic systems examined have completely retained the intrusive age of the Olden Granite, but data for several systems suggest an age of approximately 1,650 m.y. Indications that Caledonian hydrothermal activity strongly affected most of the Olden Granite. A model for the genesis of the ore deposit is proposed as follows: (1) derivation of a highly evolved granite by partial melting of crustal materials about 1,650 m.y. ago; (2) pervasive hydrothermal alteration and fracturing of the granite in response to the Caledonian Orogeny approximately 420 m.y. ago; (3) mobilization of uranium and lead in response to circulation of heated fluids; (4) precipitation of these elements in open fractures; and (5) recent modification of the Caledonian uranium distribution as a result of exposure to near-surface conditions.

Economic Geology↗
USGS1984

Deformation, geochemistry, and origin of massive sulfide deposits, Gossan lead district, Virginia

The Gossan Lead district is a 28-km-long, northeast-trending belt of discontinuous massive sulfide deposits in the Blue Ridge province of southwestern Virginia. The deposits, hosted by the Ashe Formation of late Proterozoic age, consist of strata-bound lenses and layers of massive pyrrhotite, minor chalcopyrite, sphalerite, and pyrite, and rare arsenopyrite and galena. Deposits were mined principally in the Iron Ridge and Betty Baker segments, respectively, at the southwestern and northeastern ends of the belt. Detailed mapping of the Gossan Howard, Huey, and Bumbarger pits in the Iron Ridge segment indicates that the deposits occur at one horizon and have been variously folded and brecciated after sulfide deposition. The Gossan Howard consists of a single, gently dipping lens of sulfide. The Huey deposit is complexly folded and locally contains tectonically thickened ore. The Bumbarger deposit is a lens as much as 40 m thick--the thickest known in the district. This deposit contains abundant coarse breccia fragments of wall rock around which the massive sulfide has flowed (during deformation and metamorphism), probably thickening the original deposit significantly. In the northeastern part of the district, drill holes intersect several sulfide layers that possibly are structurally repeated.The Ashe Formation in the district is a sequence of metasedimentary rocks and local conformable lenses of amphibolite and actinolite-chlorite schist. The metasedimentary rocks include metapelite, quartz-feldspar granofels (metagraywacke), and minor quartzite and carbonaceous schist, and are interpreted as marine turbidites. The amphibolites and other mafic rocks have chemical compositions similar to low Ti tholeiitic basalt, with a high Y/Nb (>10) and high average contents of Co (40 ppm), Cr (403 ppm), Ni (211 ppm), and V (247 ppm). Immobile trace element signatures (Ti-Y-Zr; Th-Hf-Ta; Ti-Cr) suggest a magmatic affinity with midocean ridge basalt (MORB); rare earth elements (REE) have low abundance levels (10X-15X chondrite), broadly flat patterns [(La/Yb) N = 0.7-1.1], and a slight depletion in the light elements similar to midocean ridge basalts. An amphibolite from a much higher stratigraphic level, south of the district, differs significantly from the mafic rocks closer to the sulfide zone in having the chemical signature of a transitional, slightly alkalic tholeiite with high TiO 2 (3.87 wt %), Fe 2 O 3 (16.4 wt %), and P 2 O 5 (0.56 wt %), low Y/Nb (3.3), and a highly fractionated rare earth element distribution [(La/Yb) N = 3.9] similar to continental basalt.Some silicate wall rocks of the deposits are mineralogically and chemically unusual, and differ substantially from the clastic metasediments of the Ashe Formation. Such rocks are composed mainly or wholly of plagioclase feldspar, biotite, chlorite, muscovite, or spessartine-rich garnet. The unusual lithologies form local strata-bound lenses in the footwall and/or hanging wall of the deposits, typically within 10 m of massive sulfide. The plagioclase rocks (3.4-7.6 wt % Na 2 O) consist largely of granoblastic albite-oligoclase (Ab (sub 78-90) ) with minor quartz and biotite; rare earth elements are highly fractionated [(La/Yb) N = 6.8-7.1] and their patterns resemble those of the quartz-feldspar granofels (metagraywacke) from the district.The biotite schists, locally monomineralic, have FeO/(FeO + MgO) = 0.5 and contain high phosphorus (1 wt % P 2 O 5 ) and fluorine (0.5 wt % F), present in fluorapatite. The chlorite schist is essentially all ripidolite; rare earth elements are highly fractionated, and have a large negative Eu anomaly. The spessartine-rich rocks (6.3-8.9 wt % MnO) are in places interlayered with the other unusual wall rocks and consist of abundant Mn-rich garnet (Sp 50 Al 23 Gr 19 Py 8 ) and minor quartz, plagioclase, pyrrhotite, and biotite. The distinctive mineralogy and chemistry of these rocks suggest that they represent metamorphosed alteration zones and/or intermixed chemical and clastic sediments.The sulfide deposits are interpreted as syngenetic in origin but modified in form by deformation which accompanied metamorphism. The great length of the mineralized district parallel to the regional strike and the flyschoid (turbidite) nature of the host rocks suggest that sedimentation and initial sulfide deposition took place in a deep, elongate marine basin or graben overlying a crustal rift zone. A rift underlying the sedimentary pile is consistent with the occurrence of mafic metavolcanic rocks of midocean ridge basalt affinity and could also have served as the feeder system for a line of hydrothermal vents on the sea floor that generated the sulfide deposits.

Economic Geology↗
USGS1985

Paragenesis and tectonic significance of base and precious metal occurrences along the San Andreas fault at Point Delgada, California

Studies of sulfide vein mineralization at Point Delgada, California, suggest that the mineralizing process was intimately associated with the San Andreas fault system and/or plate-margin tectonism. The deposits occur along north-south to northeast-southwest-trending tension faults that intersect and cross a major northwest-trending fault previously considered to be a major trace of the San Andreas fault. Galena and sphalerite are concentrated near the intersection of the principal mineralized vein with the fault, suggesting that brecciated rocks at this intersection acted as a major conduit for hydrothermal circulation. Fluid inclusion data show that the sulfide mineralization occurred at a depth of at least 400 m, probably at a temperature of about 250 degrees C. Mineralization fluids were in the salinity range of 10.5 to 5.2 equivalent weight percent NaCl. Sodium and potassium were depleted from the mineralizing fluids in the early stages of mineralization, and traces of argentian tetrahedrite and cassiterite in the fluid inclusions probably account for some of the anomalous values of silver and tin in galena and sphalerite. The age of mineralization, based on K-Ar dating of adularia, is 13.8 + or - 0.4 m.y. This age suggests that the purported trace of the San Andreas fault crossed by the sulfide veins has been largely inactive since middle Miocene time. Lead isotope and geochemical data suggest that base and precious metals in the sulfide veins were derived largely from arc-related sedimentary rocks. The heat source for hydrothermal circulation may have been associated with intrusion of asthenosphere into a triangular slab window opened southeast of the northward-propagating Mendocino triple junction shortly before 13.8 m.y. ago.

Economic Geology↗