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At least 883 records · Page 49Linked to original sources

Hydrochemical analysis of groundwater using multivariate statistical methods - The Volta region, Ghana

Q and R-mode multivariate statistical analyses were applied to groundwater chemical data from boreholes and wells in the northern section of the Volta region Ghana. The objective was to determine the processes that affect the hydrochemistry and the variation of these processes in space among the three main geological terrains: the Buem formation, Voltaian System and the Togo series that underlie the area. The analyses revealed three zones in the groundwater flow system: recharge, intermediate and discharge regions. All three zones are clearly different with respect to all the major chemical parameters, with concentrations increasing from the perceived recharge areas through the intermediate regions to the discharge areas. R-mode HCA and factor analysis (using varimax rotation and Kaiser Criterion) were then applied to determine the significant sources of variation in the hydrochemistry. This study finds that groundwater hydrochemistry in the area is controlled by the weathering of silicate and carbonate minerals, as well as the chemistry of infiltrating precipitation. This study finds that the ??D and ?? 18 O data from the area fall along the Global Meteoric Water Line (GMWL). An equation of regression derived for the relationship between ??D and ?? 18 O bears very close semblance to the equation which describes the GMWL. On the basis of this, groundwater in the study area is probably meteoric and fresh. The apparently low salinities and sodicities of the groundwater seem to support this interpretation. The suitability of groundwater for domestic and irrigation purposes is related to its source, which determines its constitution. A plot of the sodium adsorption ratio (SAR) and salinity (EC) data on a semilog axis, suggests that groundwater serves good irrigation quality in the area. Sixty percent (60%), 20% and 20% of the 67 data points used in this study fall within the medium salinity - low sodicity (C2-S1), low salinity -low sodicity (C1-S1) and high salinity - low sodicity (C3-S1) fields, which ascribe good irrigation quality to groundwater from this area. Salinities range from 28.1 to 1956 ??S/cm, whilst SAR values fall within the range 0-3. Extremely low sodicity waters of this kind, with salinities lower than 600 ??S/cm, have the tendency to affect the dispersive properties of irrigation soils when used for irrigation. About 50% of the groundwater in the study area fall within this category and need prior treatment before usage. ?? 2009 Korean Society of Civil Engineers and Springer-Verlag Berlin Heidelberg GmbH.

KSCE Journal of Civil Engineering↗

Organic petrology and geochemistry of Eocene Suzak bituminous marl, north-central Afghanistan: Depositional environment and source rock potential

Organic geochemistry and petrology of Eocene Suzak bituminous marl outcrop samples from Madr village in north-central Afghanistan were characterized via an integrated analytical approach to evaluate depositional environment and source rock potential. Multiple proxies suggest the organic-rich (TOC ∼6 wt.%) bituminous marls are ‘immature’ for oil generation (e.g., vitrinite R o < 0.4%, T max < 425 °C, PI ≤ 0.05, C 29 ααα S/S + R ≤ 0.12, C 29 ββS/ββS+ααR ≤ 0.10, others), yet oil seeps are present at outcrop and live oil and abundant solid bitumen were observed via optical microscopy. Whole rock sulfur content is ∼2.3 wt.% whereas sulfur content is ∼5.0–5.6 wt.% in whole rock extracts with high polar components, consistent with extraction from S-rich Type IIs organic matter which could generate hydrocarbons at low thermal maturity. Low Fe-sulfide mineral abundance and comparison of Pr/Ph ratios between saturate and whole extracts suggest limited Fe concentration resulted in sulfurization of organic matter during early diagenesis. From these observations, we infer that a Type IIs kerogen in ‘immature’ bituminous marl at Madr could be generating high sulfur viscous oil which is seeping from outcrop. However, oil-seep samples were not collected for correlation studies. Aluminum-normalized trace element concentrations indicate enrichment of redox sensitive trace elements Mo, U and V and suggest anoxic-euxinic conditions during sediment deposition. The bulk of organic matter observed via optical microscopy is strongly fluorescent amorphous bituminite grading to lamalginite, possibly representing microbial mat facies. Short chain n- alkanes peak at C 14 –C 16 ( n- C 17 / n- C 29 > 1) indicating organic input from marine algae and/or bacterial biomass, and sterane/hopane ratios are low (0.12–0.14). Monoaromatic steroids are dominated by C 28 clearly indicating a marine setting. High gammacerane index values (∼0.9) are consistent with anoxia stratification and may indicate intermittent saline-hypersaline conditions. Stable C isotope ratios also suggest a marine depositional scenario for the Suzak samples, consistent with the presence of marine foraminifera including abundant planktic globigerinida (?) and rare benthic discocyclina (?) and nummulites (?). Biomarker 2α-methylhopane for photosynthetic cyanobacteria implies shallow photic zone deposition of Madr marls and 3β-methylhopane indicates presence of methanotrophic archaea in the microbial consortium. The data presented herein are consistent with deposition of Suzak bituminous marls in shallow stratified waters of a restricted marine basin associated with the southeastern incipient or proto-Paratethys. Geochemical proxies from Suzak rock extracts (S content, high polar content, C isotopes, normal (αααR) C 27–29 steranes, and C 29 /C 30 and C 26 /C 25 hopane ratios) are similar to extant data from Paleogene oils produced to the north in the Afghan-Tajik Basin. This observation may indicate laterally equivalent strata are effective source rocks as suggested by previous workers; however, further work is needed to strengthen oil-source correlations.

Marine and Petroleum Geology↗

Short-Term Effects of the 2008 High-Flow Experiment on Macroinvertebrates in Colorado River Below Glen Canyon Dam, Arizona

Glen Canyon Dam has dramatically altered the physical environment (especially discharge regime, water temperatures, and sediment inputs) of the Colorado River. High-flow experiments (HFE) that mimic one aspect of the natural hydrograph (floods) were implemented in 1996, 2004, and 2008. The primary goal of these experiments was to increase the size and total area of sandbar habitats that provide both camping sites for recreational users and create backwaters (areas of stagnant flow in the lee of return-current eddies) that may be important as rearing habitat for native fish. Experimental flows might also positively or negatively alter the rainbow trout (Oncorhynchus mykiss) sport fishery in the clear tailwater reach below Glen Canyon Dam, Ariz., and native fish populations in downstream reaches (for example, endangered humpback chub, Gila cypha) through changes in available food resources. We examined the short-term response of benthic macroinvertebrates to the March 2008 HFE at three sites [river mile 0 (RM 0, 15.7 miles downriver from the dam), RM 62, and RM 225] along the Colorado River downstream from Glen Canyon Dam by sampling immediately before and then 1, 7, 14, and 30 days after the HFE. We selected these sites because of their importance to management; RM 0 has a valuable trout fishery, and RM 62 is the location of the largest population of the endangered humpback chub in the Grand Canyon. In addition to the short-term collection of samples, as part of parallel investigations, we collected 3 years of monthly (quarterly for RM 62) benthic macroinvertebrate samples that included 15 months of post-HFE data for all three sites, but processing of the samples is only complete for one site (RM 0). At RM 0, the HFE caused an immediate 1.75 g AFDM/m2 (expressed as grams ash-free dry mass, or AFDM) reduction of macroinvertebrate biomass that was driven by significant reductions in the biomass of the two dominant taxa in this reach-Potamopyrgus antipodarum (New Zealand mud snails) and Gammarus lacustris (scuds or side-swimmers)-and also biomass reductions of other common taxa (worms in the families Lumbricidae and Tubificidae). Invertebrate drift estimates during the HFE suggest that reductions in biomass of some taxa were because of export from the reach. Reductions in biomass of P. antipodarum and G. lacustris persisted at least 15 months after the HFE, when this study concluded, and coincided with a significant decline in the annual production of these taxa: P. antipodarum production of 11 to 13 g AFDM/m2/yr in two pre-HFE years versus 2 g AFDM/m2/yr in the post-HFE year, and G. lacustris production of 7 to 8 g AFDM/m2/yr in two pre-HFE years versus 3 g AFDM/m2/yr in the post-HFE year. There were not changes in invertebrate feeding habits in response to the HFE, as our 3-year dataset of invertebrate diets indicated no substantial changes. Our long-term analysis of the composition of the drift indicates that because of a reduction in P. antipodarum in the drift relative to digestible taxa, the quality of the drift as a food resource for fishes increased. At downstream sites, total assemblage biomass did not decline, likely because assemblages were dominated by blackflies (Simulium arcticum), which were not affected by the HFE. Similar to RM 0, G. lacustris and Tubificidae had significantly lower biomass after the HFE at RM 62 and RM 225. Chironomids were also significantly lower following the flood at both downstream sites. Our findings demonstrate that the effects of a HFE on invertebrates may persist up to at least 15 months in the clear tailwater below the dam, whereas in downstream reaches impacts were more short lived. If controlling the abundance of P. antipodarum is a goal of managers, our findings indicate that periodic HFEs on the order of every 2 to 3 years may be an effective strategy for meeting that goal. More frequent HFEs may cause a shift in the state of the benthic invertebrate assemblage of the tailwa

Open-File Report↗

Jadeite deposits of the clear creek area, New Idria district, San Benito county, California

Tectonic inclusions within the New Idria serpentine body contain jadeite in two distinct assemblages: (1) Lenslike inclusions containing a monomineralic green jadeite core surrounded by a calc-silicate rim. (2) Jadeite veins cross-cutting albite-crossite schist inclusions. In these veins jadeite coexists with low albite; green jadeite (Jd 75 Ac+Di+He 25) coexists with low albite within the host schist. Albite schists are related to the pre-metamorphic keratophyres and it can be shown that desilication of such rocks produces a bulk composition similar to that of jadeite. Metamor-phism of keratophyric tectonic inclusions within serpentine produced jadeite-albite schists along margins of the inclusions. Jadeite-albite veins formed from mobilized liquids rich in the jadeite molecule and deficient in water. Geological evidence such as would indicate extreme pressures or temperatures during jadeite formation is lacking; rather, a low silica and dry system allowed its formation at reduced temperatures and pressures.

California↗

Morphometric and histopathological parameters of gonadal development in adult common carp from contaminated and reference sites in Lake Mead, Nevada

This study examined the hypothesis that exposure to sublethal concentrations of contaminants alters the gonadal condition of feral common carp Cyprinus carpio . Adult common carp in Lake Mead, Nevada, were collected from a contaminated site (Las Vegas Bay) that receives municipal and industrial effluent and from a reference site (Overton Arm) with a relatively low level of contamination. Fish were sampled seven times over a 1-year period extending over two separate spawning seasons. Morphometric and histopathological parameters of gonadal and germ cell development were determined. In males, the pattern of seasonal changes in the gonadosomatic index (GSI) was similar between the sites and showed no clear association with site-specific seasonal temperature profiles. However, Las Vegas Bay males had consistently lower GSI values and, on one of the sampling dates, a lower proportion of sperm relative to other germ cell stages (determined histologically). Further, Las Vegas Bay males had a higher incidence of gonadal macrophage aggregates, which are putative tissue biomarkers of contaminant exposure in fishes. In females, seasonal GSI profiles, the frequency of fish with postovulatory follicles (an index of spawning activity), and the timing of new follicle recruitment all showed differences between sites, but these differences generally matched differences in water temperature profile. Also, the peak size-frequency of full-grown follicles did not differ between sites, and estimates of fecundity for the second spawning season indicated that females from the reference site unexpectedly produced a lower number of gametes. Overall, site differences in gonadal condition were observed in carp of both sexes but they seemed to be associated with site differences in contaminant levels only in males. The apparent lack of association between contaminant level and gonadal condition in female carp from mildly mesotrophic Lake Mead may indicate a lack of contaminant effects in females or a confounding effect of the higher nutrient loads in the Las Vegas Bay environment.

Nevada↗

Are large-scale flow experiments informing the science and management of freshwater ecosystems?

Greater scientific knowledge, changing societal values, and legislative mandates have emphasized the importance of implementing large-scale flow experiments (FEs) downstream of dams. We provide the first global assessment of FEs to evaluate their success in advancing science and informing management decisions. Systematic review of 113 FEs across 20 countries revealed that clear articulation of experimental objectives, while not universally practiced, was crucial for achieving management outcomes and changing dam-operating policies. Furthermore, changes to dam operations were three times less likely when FEs were conducted primarily for scientific purposes. Despite the recognized importance of riverine flow regimes, four-fifths of FEs involved only discrete flow events. Over three-quarters of FEs documented both abiotic and biotic outcomes, but only one-third examined multiple taxonomic responses, thus limiting how FE results can inform holistic dam management. Future FEs will present new opportunities to advance scientifically credible water policies.

Frontiers in Ecology and the Environment↗

Post-depositional alteration of titanomagnetite in a Miocene sandstone, south Texas (U.S.A.)

Petrographic and geochemical studies have yielded information on the time-space relationships of the post-depositional alteration of detrital titanomagnetite (Ti-mt) in fine- to medium-grained sandstone from unoriented core samples (taken below the water table at depths of 30–45 m) of the Miocene Catahoula Sandstone, south Texas. Aqueous sulfide introduced from sour gas reservoirs along a growth fault into part of the Catahoula shortly after deposition resulted in the replacement at the periphery of Ti-mt grains by iron disulfide (FeS 2 ) minerals. Remnants of Ti-mt in cores of the partly sulfidized grains show no evidence of earlier hematitic oxidation. After sulfidization, part of the sandstone body was invaded by oxygenated groundwaters flowing down a shallowly inclined (1°) hydrologic gradient. The boundary between oxidized and reduced facies is clearly defined by the distribution of ferric and ferrous iron minerals, and the concentrations of Mo, U, and Se. In oxidized (light-red) strata that had not been previously subjected to sulfidic-reducing conditions but that are correlative with strata containing FeS 2 minerals, Ti-mt has been partly to entirely replaced pseudomorphously by hematite to form martite. The absence of hematitic alteration of Ti-mt in the reduced facies is strong evidence that martite in the oxidized facies formed after deposition.

Texas↗

A complex record of last interglacial sea-level history and paleozoogeography, Santa Rosa Island, Channel Islands National Park, California, USA

Studies of marine terraces and their fossils can yield important information about sea level history, tectonic uplift rates, and paleozoogeography, but some aspects of terrace history, particularly with regard to their fossil record, are not clearly understood. Marine terraces are well preserved on Santa Rosa Island, California, and the island is situated near a major marine faunal boundary. Two prominent low-elevation terraces record the ∼80 ka (marine isotope stage [MIS] 5a) and ∼120 ka (MIS 5e) high-sea stands, based on U-series dating of fossil corals and aminostratigraphic correlation to dated localities elsewhere in California and Baja California. Low uplift rates are implied by an interpretation of these ages, along with their elevations. The fossil assemblage from the ∼120 ka (2nd) terrace contains a number of northern, cool-water species, along with several southern, warm-water species, a classic example of what has been called a thermally anomalous fauna. Low uplift rates in the late Pleistocene, combined with glacial isostatic adjustment (GIA) processes, could have resulted in reoccupation of the ∼120 ka (MIS 5e), 2nd terrace during the ∼100 ka (MIS 5c) high-sea stand, explaining the mix of warm-water (∼120 ka?) and cool-water (∼100 ka?) fossils in the terrace deposits. In addition, however, sea surface temperature (SST) variability during MIS 5e may have been a contributing factor, given that Santa Rosa Island is bathed at times by the cold California Current with its upwelling and at other times is subject to El Niño warm waters, evident in the Holocene SST record. Study of an older, high-elevation marine terrace on the western part of Santa Rosa Island shows more obvious evidence of fossil mixing. Strontium isotope ages span a large range, from ∼2.3 Ma to ∼0.91 Ma. These analyses indicate an age range of ∼500 ka at one locality and ∼ 600 ka at another locality, interpreted to be due to terrace reoccupation and fossil reworking. Consideration of elevations and ages here also yield low, long-term uplift rates, which in part explains the potential for terrace reoccupation in the early Pleistocene. In addition, however, early Pleistocene glacial-interglacial cycles were of much shorter duration, linked to the ∼41 ka obliquity cycle of orbital forcing, a factor that would also enhance terrace reoccupation in regions of low uplift rate. It is likely that other Pacific Coast marine terrace localities of early Pleistocene age, in areas with low uplift rates, also have evidence of fossil mixing from these processes, an hypothesis that can be tested in future studies.

California↗

Sea-level and environmental changes since the last interglacial in the Gulf of Carpentaria, Australia: an overview

The Gulf of Carpentaria is an epicontinental sea (maximum depth 70 m) between Australia and New Guinea, bordered to the east by Torres Strait (currently 12 m deep) and to the west by the Arafura Sill (53 m below present sea level). Throughout the Quaternary, during times of low sea-level, the Gulf was separated from the open waters of the Indian and Pacific Oceans, forming Lake Carpentaria, an isolation basin, perched above contemporaneous sea-level with outlet channels to the Arafura Sea. A preliminary interpretation is presented of the palaeoenvironments recorded in six sediment cores collected by the IMAGES program in the Gulf of Carpentaria. The longest core (approx. 15 m) spans the past 130 ka and includes a record of sea-level/lake-level changes, with particular complexity between 80 and 40 ka when sea-level repeatedly breached and withdrew from Gulf/Lake Carpentaria. Evidence from biotic remains (foraminifers, ostracods, pollen), sedimentology and geochemistry clearly identifies a final marine transgression at about 9.7 ka (radiocarbon years). Before this transgression, Lake Carpentaria was surrounded by grassland, was near full, and may have had a surface area approaching 600 km×300 km and a depth of about 15 m. The earlier rise in sea-level which accompanied the Marine Isotopic Stage 6/5 transgression at about 130 ka is constrained by sedimentological and biotic evidence and dated by optical- and thermoluminescence and amino acid racemisation methods.

Gulf Of Carpentaria↗

Evolution of CAM and C 4 carbon-concentrating mechanisms

Mechanisms for concentrating carbon around the Rubisco enzyme, which drives the carbon-reducing steps in photosynthesis, are widespread in plants; in vascular plants they are known as crassulacean acid metabolism (CAM) and C 4 photosynthesis. CAM is common in desert succulents, tropical epiphytes, and aquatic plants and is characterized by nighttime fixation of CO2. The proximal selective factor driving the evolution of this CO2-concentrating pathway is low daytime CO2, which results from the unusual reverse stomatal behavior of terrestrial CAM species or from patterns of ambient CO2 availability for aquatic CAM species. In terrestrials the ultimate selective factor is water stress that has selected for increased water use efficiency. In aquatics the ultimate selective factor is diel fluctuations in CO2 availability for palustrine species and extreme oligotrophic conditions for lacustrine species. C4 photosynthesis is based on similar biochemistry but carboxylation steps are spatially separated in the leaf rather than temporally as in CAM. This biochemical pathway is most commonly associated with a specialized leaf anatomy known as Kranz anatomy; however, there are exceptions. The ultimate selective factor driving the evolution of this pathway is excessively high photorespiration that inhibits normal C3 photosynthesis under high light and high temperature in both terrestrial and aquatic habitats. CAM is an ancient pathway that likely has been present since the Paleozoic era in aquatic species from shallow-water palustrine habitats. While atmospheric CO2 levels have undoubtedly affected the evolution of terrestrial plant carbon-concentrating mechanisms, there is reason to believe that past atmospheric changes have not played as important a selective role in the aquatic milieu since palustrine habitats today are not generally carbon sinks, and the selective factors driving aquatic CAM are autogenic. Terrestrial CAM, in contrast, is of increasing selective value under extreme water deficits, and undoubtedly, high Mesozoic CO2 levels reduced the amount of landscape perceived by plants as water limited. Late Tertiary and Quaternary reductions in atmospheric CO2, coupled with increasing seasonality, were probably times of substantial species radiation and ecological expansion for CAM plants. C4 photosynthesis occurs in only about half as many families as CAM, and three-fourths of C4 species are either grasses or sedges. Molecular phylogenies indicate C4 is a more recent innovation than CAM and that it originated in the mid-Tertiary, 20–30 Ma, although some data support an earlier origin. While the timing of the origin of C4 remains controversial, the nearly explosive increase in C4 species is clearly documented in the late Miocene, 4–7 Ma. Increasing seasonality has been widely suggested as an important climatic stimulus for this C4 expansion. Alternatively, based on models of photosynthetic quantum yield at different temperatures and CO2 concentration, it has been hypothesized that the late Miocene C4 expansion resulted from declining atmospheric CO2 levels. This model is most appropriate for explaining the transition from C3 grasslands to C4 grasslands but by itself may not be sufficient to explain the more likely scenario of a late Miocene transition from C3 woodland/ savanna to C4 grasslands. A largely unexplored hypothesis is that climatic changes in late Miocene altered disturbance regimes, in particular the incidence of fires, which today are often associated with maintenance of C4 grasslands. Oceanic charcoal sediments that appear to represent Aeolian deposits from continental wildfires follow a strikingly similar pattern of explosive increase in late Miocene. Climate, CO2, and disturbance are not mutually exclusive explanations and probably all acted in concert to promote the expansion of C4 grasslands. More recently, late Quaternary changes in CO2 may have been responsible for driving major changes in the landscape distribution of C4 species. The theory is sound; however, many of the studies cited in support of this model are open to alternative interpretations, and none has eliminated climatic factors as important selective agents. CAM and C4 evolution required coupling of biochemical pathways with structural changes in photosynthetic tissues, succulence in CAM and Kranz in C4. This was apparently accomplished by piecemeal evolution beginning with mechanisms for recapturing respiratory CO2, although this need not have been so in aquatic CAM species. It has been proposed that the extreme rarity of both pathways in the same plant results from biochemical and structural incompatibilities (Sage 2002). Equally important is the fact that the selective environments are quite different, with CAM evolution thriving on stressful sites inhospitable to C3 species whereas C4 evolution has selected for rapid growth capable of outcompeting associated C3 plants.

International Journal of Plant Sciences↗

Transcriptional changes in wild Yukon River Chinook Salmon associated with Ichthyophonus infections

Objective We compared differentially expressed genes in Chinook Salmon Oncorhynchus tshawytscha with three divergent Ichthyophonus statuses (undetected, subclinical infections, or clinical disease; n = 100) to investigate associated transcriptomic responses. Disease associated with the fish parasite Ichthyophonus sp. was first diagnosed in adult Chinook Salmon from the Yukon River in the late 1980s and has subsequently been implicated in premature host mortality. Methods Chinook Salmon tissue sample collections and Ichthyophonus infection data were leveraged from a multi-agency collaboration during summer 2022 at three locations along the main-stem Yukon River that spanned nearly 2,000 km of freshwater migration (lower, middle, and upper river). We sequenced the transcriptome and compared this to infection status based on routine diagnostic procedures. Results Among the 17,569 genes for which messenger RNA was detected, we identified a transcription signature in the skeletal muscle that was associated with Ichthyophonus infections and included 53 differentially expressed genes. The differentially expressed genes and their pathways included those known for involvement in immune functions, energy synthesis, cellular breakdown, and reproduction—all processes that are known to be influenced by senescence during spawning migrations. Conclusions Results demonstrate a clear transcriptional difference between diseased fish (clinical disease group) and those in which Ichthyophonus was undetected, including identifying candidate markers for infection in this population. These results provide a foundation for development of nonlethal biomarkers to evaluate potential Ichthyophonus infections in Chinook Salmon based on gene transcription, protein products, or gene variants (e.g., polymorphisms).

Journal of Aquatic Animal Health↗

Downslope Eulerian mean flow associated with high-frequency current fluctuations observed on the outer continental shelf and upper slope along the northeastern United States continental margin: Implications for sediment transport

Eulerian current measurements made 5-7 m above bottom at six stations along the United States east coast continental margin show a net downslope flow of 1-5 cm s-1. Although the scalar current speed decreases with water depth and toward the bottom, fluctuations in the cross-isobath flow were stronger and increasingly asymmetric near the bottom. Maximum downslope flow exceeded maximum upslope flow by a factor of two to three. The strength of the low-passed downslope flow was proportional to the upslope Reynolds flux of density as well as to the amplitude of the current fluctuations that have periods shorter than 30 h. These flow characteristics may be caused by differential vertical mixing in the bottom boundary layer where a stratified fluid flows upslope (unstable) and downslope (stable). The asymmetry in current strength clearly favors net downslope transport of sediments that move as bedload. ?? 1988.

Continental Shelf Research↗

Modeling water quality in the Anthropocene: Directions for the next-generation aquatic ecosystem models

“Everything changes and nothing stands still” (Heraclitus). Here we review three major improvements to freshwater aquatic ecosystem models — and ecological models in general — as water quality scenario analysis tools towards a sustainable future. To tackle the rapid and deeply connected dynamics characteristic of the Anthropocene, we argue for the inclusion of eco-evolutionary, novel ecosystem and social-ecological dynamics. These dynamics arise from adaptive responses in organisms and ecosystems to global environmental change and act at different integration levels and different time scales. We provide reasons and means to incorporate each improvement into aquatic ecosystem models. Throughout this study we refer to Lake Victoria as a microcosm of the evolving novel social-ecological systems of the Anthropocene. The Lake Victoria case clearly shows how interlinked eco-evolutionary, novel ecosystem and social-ecological dynamics are, and demonstrates the need for transdisciplinary research approaches towards global sustainability.

Current Opinion in Environmental Sustainability↗

Using Landsat satellite data to support pesticide exposure assessment in California

Background The recent U.S. Geological Survey policy offering Landsat satellite data at no cost provides researchers new opportunities to explore relationships between environment and health. The purpose of this study was to examine the potential for using Landsat satellite data to support pesticide exposure assessment in California. Methods and Results We collected a dense time series of 24 Landsat 5 and 7 images spanning the year 2000 for an agricultural region in Fresno County. We intersected the Landsat time series with the California Department of Water Resources (CDWR) land use map and selected field samples to define the phenological characteristics of 17 major crop types or crop groups. We found the frequent overpass of Landsat enabled detection of crop field conditions (e.g., bare soil, vegetated) over most of the year. However, images were limited during the winter months due to cloud cover. Many samples designated as single-cropped in the CDWR map had phenological patterns that represented multi-cropped or non-cropped fields, indicating they may have been misclassified. Conclusions We found the combination of Landsat 5 and 7 image data would clearly benefit pesticide exposure assessment in this region by 1) providing information on crop field conditions at or near the time when pesticides are applied, and 2) providing information for validating the CDWR map. The Landsat image time-series was useful for identifying idle, single-, and multi-cropped fields. Landsat data will be limited during the winter months due to cloud cover, and for years prior to the Landsat 7 launch (1999) when only one satellite was operational at any given time. We suggest additional research to determine the feasibility of integrating CDWR land use maps and Landsat data to derive crop maps in locations and time periods where maps are not available, which will allow for substantial improvements to chemical exposure estimation.

California↗

Integrating active restoration with environmental flows to improve native riparian tree establishment in the Colorado River Delta

Drastic alterations to river hydrology, land use change, and the spread of the nonnative shrub, tamarisk (Tamarix spp.), have led to the degradation of riparian habitat in the Colorado River Delta in Mexico. Delivery of environmental flows to promote native cottonwood (Populus spp.) and willow (Salix spp.) recruitment in human-impacted riparian systems can be unsuccessful due to flow-magnitude constraints and altered abiotic–biotic feedbacks. In 2014, an experimental pulse flow of water was delivered to the Colorado River in Mexico as part of the U.S.-Mexico binational agreement, Minute 319. We conducted a field experiment to assess the effects of vegetation removal, seed augmentation, and environmental flows, separately and in combination, on germination and first-year seedling establishment of cottonwood, willow, and tamarisk at five replicate sites along 5 river km. The relatively low-magnitude flow deliveries did not substantively restore natural fluvial processes of erosion, sediment deposition, and vegetation scour, but did provide wetted surface soils, shallow groundwater, and low soil salinity. Cottonwood and willow only established in wetted, cleared treatments, and establishment was variable in these treatments due to variable site conditions and inundation duration and timing. Wetted soils, bare surface availability, soil salinity, and seed availability were significant factors contributing to successful cottonwood and willow germination, while soil salinity and texture affected seedling persistence over the growing season. Tamarisk germinated and persisted in a wider range of environmental conditions than cottonwood and willow, including in un-cleared treatment areas. Our results suggest that site management can increase cottonwood and willow recruitment success from low-magnitude environmental flow events, an approach that can be applied in other portions of the Delta and to other human-impacted riparian systems across the world with similar ecological limitations.

Colorado River↗

Determining the drivers of suspended sediment dynamics in tidal marsh-influenced estuaries using high-resolution ocean color remote sensing

Sediment budgets are a critical metric to assess coastal marsh vulnerability to sea-level rise and declining riverine sediment inputs. However, calculating accurate sediment budgets is challenging in tidal marsh-influenced estuaries where suspended sediment concentrations (SSC) typically vary on scales of hours and meters, and where SSC dynamics are driven by a complex and often site-specific interplay of hydrodynamic and meteorological conditions. The mapping of SSC using ocean-color remote sensing is well established and can help capture the spatio-temporal variability needed to determine the dominant drivers regulating sediment budgets. However, the coarse spatial resolution of traditional ocean-color sensors (1-km) generally precludes their use in coastal-marsh estuaries. Here, using the Plum Island Estuary (Massachusetts, USA) as an example, we demonstrate that high-spatial-resolution maps of SSC derived from Landsat-8 Operational Land Imager (OLI) and Sentinel-2A/B Multispectral Instruments (MSI) can be used to determine the main drivers of SSC dynamics in tidal marsh-influenced estuaries, despite the long revisit time of these sensors. Local empirical algorithms between SSC and remote sensing reflectance were derived and applied to a total of 46 clear-sky scenes collected by the OLI and the MSI between 2013 and 2018. The analysis revealed that this 5-year record was sufficient to capture a representative range of meteorological and tidal conditions required to determine the main drivers of SSC dynamics in this mid-latitude system. The interplay between river and tidal flows dominated SSC dynamics in this estuary, whereas wind-driven resuspension had more moderate effects. The SSC were higher during spring because of increased river discharge due to snowmelt. Tidal asymmetry also enhanced sediment resuspension during flood tides, possibly favoring deposition on marsh platforms. Together, water level, water-level rate of change, river discharge and wind speed were able to explain > 60% of the variability in the main-channel thalweg-averaged SSC, thereby facilitating future prediction of SSC from these readily available variables. This study demonstrates that the existing multi-year records of high-resolution remote sensing can provide a representative depiction of SSC dynamics in hydrodynamically-complex and small-scale estuaries that moderate-resolution ocean color remote sensing and in situ measurements are unable to capture.

Massachusetts↗

Green River oil shale—concept of origin extended: An interdisciplinary problem being attacked from both ends

A much fuller understanding of the Green River oil shale and its organic chemistry will emerge when the geologists, paleontologists, organic chemists, biologists, paleolimnologists, and biogeochemists, who are now working on it, integrate their findings with those of the others. We know from the geology, paleontology, and paleolimnology that the biologic progenitors of the organic substance in the Green River oil shale could only have been microscopic algae, and other micro-organisms, that grew and accumulated in the central parts of large, shallow lakes that existed under a subtropical climate. The only nonlacustrine organic components were wind-blown, or water borne, pollens and waxy spores. These, however, made up a large and important part of the organic-rich sediment. The geology of the Green River Formation shows that as the algal and pollen-rich sediment was buried deeper and deeper, progressively more of its pore water and dissolved constituents were expressed. Static pressures may have reached as much as 210 kg cm −2 , and the ambient temperature rose, with depth, to somewhere within the range between 90° and 125° C. Beneath the ancient lakes a tectonically quiescent environment persisted for tens of millions of years after their organic sediments had been deeply buried. The organic material of the Green River oil shale can be divided into three fractions—a small bitumen fraction that is extractable with common organic solvents, a major fraction called koerogen that consists of insoluble pyrobitumens, and a somewhat smaller inert fraction that is neither soluble nor does it yield oil on pyrolysis. As all three fractions originated in the same algal, pollen-rich sediment, an explanation for their marked differences must be sought in their geochemical history or from a study of the modern analogues of their progenitors. The components of the bitumen fraction consisted of “biological markers” that were inherited from the Eocene plants and animals in which they originally formed. Diagenesis has changed these hydrogen-rich compounds, but not enough to obscure their provenance. Kerogen presumably became insoluble because its hydrogen-rich components polymerized. My speculation is that the inert fraction was derived from a polyphenolic substance produced in the original algal ooze by “non-enzymatic browning.” Only three Classes of non-marine algae need be considered as progenitors of the Green River oil shale; the Xanthophyceae, the Chlorophyceae, and the Cyanophyceae. Only the Cyanophyceae (the blue-green algae) meet the biologic and paleontologic requirements to have served as the dominant precursors of the Green River oil shale. Several other oil shales clearly were derived from the Xanthophyceae, specifically Botryococcus. The blue-green algal ooze now forming, and accumulating, in Mud Lake, Florida, has been studied biologically and chemically as a possible present-day analogue of the Green River oil shale precursor. In this small lake we have established the fact that a bacterial inhibitor is produced, which inhibits decay of the algae and thereby permits the accumulation of energy-rich organic compounds. We infer that a similar indigenous inhibitor must have acted in the Eocene lakes to permit them to become the huge energy sinks they were. Studies of the organic chemistry of living blue-green algae show that they contain appreciable percentages of fatty acids, hydrocarbons, and very large percentages of proteins. These promising, energy-rich compounds could serve as source materials for potential conversion into oil shale in the geologic future. Certain marine anaerobic bacteria convert fatty acids into aliphatic hydrocarbons. Fresh-water obligate anaerobes should be investigated to see if they also convert fatty acids into hydrocarbons. The part played by aquatic animals that live in, or on, freshwater algal ooze in synthesizing hydrocarbons has not been investigated, but deserves attention. Pollen grains, of course, must be considered an important precursor of hydrocarbons produced on pyrolysis. They contain far higher percentages of long chain hydrocarbons and alcohols than most plant materials. The major problem ahead is to account for the progressive hydrogenation and subsequent polymerization of the relatively oxygen-rich constituents of algae such as the polysaccharides, amino acids, ammo sugars, and fatty acids into the insoluble pyrobitumens that constitute, particularly, the kerogen fraction of the Green River oil shale.

Wyoming↗

Carbon stock trends of baldcypress knees along climate gradients of the Mississippi River Alluvial Valley using allometric methods

Carbon stock trends of the knees of Taxodium distichum likely vary across climate gradients of the southeastern United States and contribute an unknown quantity of “teal” carbon to inland freshwater wetlands. Knee metrics (e.g., density, height, biomass) were measured in mixed T. distichum swamps across the Mississippi River Alluvial Valley (MRAV) from Illinois to Louisiana. Based on their geometric similarity to a cone, the biomasses of field knees were estimated by relating the volume of their measured field dimensions to lab-measured water displacement volume and biomass via volume/mass regressions (biomass (g) = 7.2230149 + 0.292902 × volume). Knees had greater height in flooded conditions (maximum height = 163 cm; Goose Lake, Arkansas), and also in climate normal environments of mid-range precipitation and temperature (p < 0.0001). Overall, knee biomass ha−1 was 7.5 times greater in flooded vs. not flooded conditions (34.6 ± 7.3 vs. 4.6 ± 1.0 Mg ha−1, respectively). The overall mean of knee carbon biomass stock was substantial (flooded vs. not flooded conditions: 18.1 ± 3.7 Mg C ha−1 to 2.9 ± 0.7 Mg C ha−1, respectively; knee/tree live standing biomass: 17.9–5.2%, respectively). Clearly, T. distichum knees should not be ignored in blue (teal) carbon discussions of wetlands. Because knees respond to climate normal conditions, hotter/drier environments in the MRAV could lead to a decline in the contribution of knee carbon stock in the southeastern United States.

Mississippi River Alluvial Valley↗