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At least 883 records · Page 49Linked to original sources

Anatidae brood records in Maine during studies of Anas rubripes (American black duck), 1977–94

This report describes a compilation of brood observations for Anatidae species breeding in Maine during an 18-year period (1977–94) that were made by the U.S. Geological Survey’s Patuxent Wildlife Research Center while it was operated by the U.S. Fish and Wildlife Service. During four focused studies, variables affecting the declining Anas rubripes (Brewster, 1902) (American black duck, hereafter black duck) population were assessed. Broods were observed on seven geographical study sites within four study areas located in three of Maine’s five biophysical regions. For combined studies, 168 wetlands were monitored for broods. The 1,907 recorded broods were distributed among study areas: 185 in Dixmont, 241 in Cherryfield and Beddington, 411 in Moosehorn, Baring Unit and Edmunds Unit, and 849 in Aroostook County, Agricultural and Forested sites. Additionally, 221 broods were recorded in the 117-hectare Downing Bog wetland at the Cherryfield site during annual evening visits made between 1985 and 1991. Twelve Anatidae species, mostly black duck (676), Aix sponsa (Linnaeus, 1758) (wood duck; 265), Aythya collaris (Donovan, 1809) (ring-necked duck; 246), and Lophodytes cucullatus (Linnaeus, 1758) (hooded merganser; 163) were observed. Only 139 broods of Anas platyrhynchos (Linnaeus, 1758) (mallard) were found; all but 9 broods were at the Aroostook County, Agricultural site. Branta canadensis (Linnaeus, 1758) (Canada goose) broods were found at the Aroostook County, Agricultural site (58) and Moosehorn, Baring Unit (97). For the combined studies, 468 of 676 (69.2 percent) of black duck broods reached fledging age (Class IIc-III), whereas 93 of 139 (66.9 percent) of mallard broods reached fledging age. Black ducks used predominantly palustrine, emergent wetland; palustrine, forested wetland; and palustrine, scrub-shrub wetland. Of the 134 mallard broods observed at the Agricultural and Forested sites in Aroostook County, 130 (97.0 percent) were observed at the Agricultural site and 93 (71.5 percent) of them were recorded on two palustrine and two lacustrine, unconsolidated bottom class wetlands. Mean size of black duck, wood duck, and ring-necked duck broods in this report were similar to those reported from historic Maine data.

Maine↗

Influence of natural and human factors on pesticide concentrations in surface waters of the White River Basin, Indiana

Pesticide concentrations in surface waters of the White River Basin are affected by natural and human factors. For example, concentrations of atrazine, a herbicide widely used on corn in the White River Basin, tended to be higher in an agricultural basin with permeable, well-drained soils, than in an agricultural basin with less permeable, more poorly drained soils. Concentrations of butylate, another herbicide used on corn, were substantially higher in an agricultural basin in the southern part of the White River Basin than in an agricultural basin in the central part of the White River Basin, corresponding to the higher use of this compound in southern Indiana. Concentrations of diazinon were substantially higher in a predominantly urban basin than in two predominantly agricultural basins, corresponding to the common use of this insecticide on lawns and gardens in urban areas.

Indiana↗

Nutrients in northern Missouri streams

Nutrients, specifically nitrogen and phosphorus, are necessary for healthy aquatic communities to thrive, but if nutrient concentrations are too high, water quality can be degraded and natural aquatic communities may be destroyed. Nutrients consistently have been listed nationally as one of the top five causes of stream and river impairments, and agriculture consistently has been identified as the leading known source. The Mississippi River watershed was identified as a top priority for nutrient reductions because of the predominant agricultural land use, the associated harmful effects of nutrient loading on local water bodies, and the resulting annual midsummer northern Gulf of Mexico hypoxic “dead” zone. In 2010, the Natural Resources Conservation Service started the Mississippi River Basin Healthy Watersheds Initiative, which offers financial and technical assistance for voluntary conservation practices on agricultural lands. The intention is to reduce nutrient and sediment export to waterways within the Mississippi River watershed. The U.S. Geological Survey Missouri Water Science Center and the Missouri Department of Natural Resources began a cooperative study in 2010 to compare temporal changes in total nitrogen and total phosphorus concentrations in the Lower Grand River. Despite increases in conservation practice funding from the Mississippi River Basin Healthy Watersheds Initiative during 2011–15 for the Lower Grand River, decreases in flow-normalized total nitrogen and total phosphorus concentrations during this same period at the Grand River site were less than at the other long-term Missouri River tributary sites that did not receive additional funding. The flow-normalized total nitrogen and total phosphorus concentrations at the three long-term Missouri River tributary sites were related to the amount of agricultural land use within their watersheds and livestock manure may be a substantial source of stream nitrogen. Monthly total nitrogen and total phosphorus concentrations within the Lower Grand River increased with increased streamflow, indicating that the major sources of nitrogen and phosphorus are runoff or nutrients that are stored in soils within the streambank that mobilize during higher streamflows. Programs such as the Mississippi River Basin Healthy Watersheds Initiative are intended to encourage voluntary agricultural conservation practices to enhance soil health and reduce nutrient export to streams.

Missouri↗

Rio Grande transboundary integrated hydrologic model and water-availability analysis, New Mexico and Texas, United States, and Northern Chihuahua, Mexico

Errata **September 28, 2018: The purpose of a USGS Open-file report (OFR) is dissemination of information that must be released immediately to fill a public need or information that is not sufficiently refined to warrant publication in one of the other USGS series. As part of that refinement process, an error was discovered in one of the input data sets of the Rio Grande Transboundary Integrated Hydrologic Model (RGTIHM) that this OFR was based upon. The error involved the assignment of storage properties to “phantom cells.” Phantom cells are required for most variants of MODFLOW that use a structured finite-difference grid when individual stratigraphic layers are represented as separate layers. Using phantom cells is a common practice that allows separate model layers to be maintained without having to combine stratigraphic layers into equivalent model layers or to use an unstructured grid. Typically, phantom cell horizontal hydraulic conductivities and storage properties are set to a small number and vertical hydraulic conductivities are set to a number large enough to allow vertical flow between the vertically adjacent layers. In the RGTIHM, the specific storage properties of the phantom cells for the upper (RGTIHM layers 3 and 4), middle (RGTIHM layers 5 and 6), and lower (RGTIHM layers 7 and 8) members of the Santa Fe Group were inadvertently assigned a value of 1 feet -1 . The revision of these specific storage values to a small number (1.0 x 10 -09 feet -1 ) required additional trial-and-error model calibration and a new sensitivity analysis. After calibration, the overall model fit remained similar to the fit described in the OFR, but the fit for many individual features such as project water available for diversions at the American Canal and Acequia Madre improved due to the reduction in flow coming from lower layers. Overall, there is still an average net depletion of groundwater flow, and the conclusions of the report are not changed. The revised average annual groundwater flow depletion simulated for the period 1953-2014 is -1,480 acre-feet/year for the entire model region, and -3,660 acre-feet/year for the portion of the model in the United States. The final version of the model will be the basis of the USGS Scientific Investigations Report that will supersede this OFR. An updated Model Archive of RGTIHM is available upon request to the USGS California Water Science Center. The corrected version of the model WAS the basis for the USGS Scientific Investigations Report that SUPERSEDED this Open-File Report.** Abstract Changes in population, agricultural development and practices (including shifts to more water-intensive crops), and climate variability are increasing demands on available water resources, particularly groundwater, in one of the most productive agricultural regions in the Southwest—the Rincon and Mesilla Valley parts of Rio Grande Valley, Doña Ana and Sierra Counties, New Mexico, and El Paso County, Texas. The goal of this study was to produce an integrated hydrological simulation model to help evaluate water-management strategies, including conjunctive use of surface water and groundwater for historical conditions, and to support long-term planning for the Rio Grande Project. This report describes model construction and applications by the U.S. Geological Survey, working in cooperation and collaboration with the Bureau of Reclamation. This model, the Rio Grande Transboundary Integrated Hydrologic Model, simulates the most important natural and human components of the hydrologic system, including selected components related to variations in climate, thereby providing a reliable assessment of surface-water and groundwater conditions and processes that can inform water users and help improve planning for future conditions and sustained operations of the Rio Grande Project (RGP) by the Bureau of Reclamation. Model development included a revision of the conceptual model of the flow system, construction of a Transboundary Rio Grande Watershed Model (TRGWM) water-balance model using the Basin Characterization Model (BCM), and construction of an integrated hydrologic flow model with MODFLOW-One-Water Hydrologic Flow Model (referred to as One Water). The hydrologic models were developed for and calibrated to historical conditions of water and land use, and parameters were adjusted so that simulated values closely matched available measurements (calibration). The calibrated model was then used to assess the use and movement of water in the Rincon Valley, Mesilla Basin, and northern part of the Conejos-Médanos Basin, with the entire region referred to as the “Transboundary Rio Grande” or TRG. These tools provide a means to understand hydrologic system response to the evolution of water use in the region, its availability, and potential operational constraints of the RGP. The conceptual model identified surface-water and groundwater inflows and outflows that included the movement and use of water both in natural and in anthropogenic systems. The groundwater-flow system is characterized by a layered geologic sedimentary sequence combined with the effects of groundwater pumping, operation of the RGP, natural runoff and recharge, and the application of irrigation water at the land surface that is captured and reused in an extensive network of canals and drains as part of the conjunctive use of water in the region. Historical groundwater-level fluctuations followed a cyclic pattern that were aligned with climate cycles, which collectively resulted in alternating periods of wet or dry years. Periods of drought that persisted for one or more years are associated with low surface-water availability that resulted in higher rates of groundwater-level decline. Rates of groundwater-level decline also increased during periods of agricultural intensification, which necessitated increasing use of groundwater as a source of irrigation water. Agriculture in the area was initially dominated by alfalfa and cotton, but since 1970 more water-intensive pecan orchards and vegetable production have become more common. Groundwater levels substantially declined in subregions where drier climate combined with increased demand, resulting in periods of reduced streamflows. Most of the groundwater was recharged in the Rio Grande Valley floor, and most of the pumpage and aquifer storage depletion was in Mesilla Basin agricultural subregions. A cyclic imbalance between inflows and outflows resulted in the modeled cyclic depletion (groundwater withdrawals in excess of natural recharge) of the groundwater basin during the 75-year simulation period of 1940–2014. Changes in groundwater storage can vary considerably from year to year, depending on land use, pumpage, and climate conditions. Climatic drivers of wet and dry years can greatly affect all inflows, outflows, and water use. Although streamflow and, to a minor extent, precipitation during inter-decadal wet-year periods replenished the groundwater historically, contemporary water use and storage depletion could have reduced the effects of these major recharge events. The average net groundwater flow-rate deficit for 1953–2014 was estimated to be about 8,990 acre-feet per year.

New Mexico, Northern Chihuahua, Texas↗

Geology, hydrology, and water quality in the Fresno area, California

The Fresno area comprises about 1.400 square miles lying west of the foothills of the Sierra Nevada and east of the trough of the San Joaquin Valley. The rainfall averages less than 10 inches per year causing agricultural development to depend mainly on surface-water deliveries and ground-water pumpage. Surface-water deliveries and ground-water pumpage, however, vary considerably from year to year. For example, in agricultural year 1958 (April 1, 1958-March 31, 1959) surface-water deliveries were about 1,340,000 acre-feet and agricultural ground-water pumpage was about 1,740,000 acre-feet, but in agricultural year 1960 deliveries were only about 560,000 acre-feet and pumpage was about 2,520,000 acre-feet. Alluvial fans are the dominant geomorphic features in the area. Small alluvial fans have been formed near the foothills by the deposits from the numerous intermittent streams that lie both north and south of the Kings River. Thicker and much more extensive alluvial fans have been formed under most of the area by deposits from the San Joaquin and Kings Rivers. Geologic units in the area consist of consolidated rocks and unconsolidated deposits. In turn, consolidated rocks consist of basement complex of pre-Tertiary age and marine and continental sedimentary rocks of Cretaceous and Tertiary age. Unconsolidated deposits are of both Tertiary and Quaternary age. Most of the geologic units dip gently southwestward approximately paralleling the back slope of the Sierra Nevada. Although some of these geologic units are faulted, especially in the deep subsurface, faulting has not affected the occurrence and movement of fresh ground water. The basement complex crops out along the eastern border of the area and yields only small amounts of water to wells; the marine and continental sedimentary rocks do not crop out in the area and do not yield any water to wells. The unconsolidated deposits are divided into an older series of Tertiary and Quaternary age, and a younger series of Quaternary age. The continental deposits of Tertiary and Quaternary age crop out beneath the extreme southeastern part of the area and yield small amounts of water to wells, and the deposits of Quaternary age crop out over most of the area and yield more than 90 percent of the water pumped from wells. The deposits of Quaternary age in turn are divided into older alluvium, lacustrine and marsh deposits, younger alluvium, flood-basin deposits. and sand dunes. The older alluvium is by far the most important aquifer in the Fresno area. It consists of intercalated lenses of clay, silt, silty and sandy clay, clayey and silty sand, sand, gravel, cobbles, and boulders, and in general it is fine grained near the trough of the valley and beneath the alluvial fans of intermittent streams. In the older alluvium, yields to wells range from less than 20 gpm (gallons per minute) to more than 3,000 gpm. The lacustrine and marsh deposits occur only in the subsurface in the western part of the area. Consisting mostly of silt and clay, they are virtually impermeable and thus restrict the vertical movement of water. These deposits from oldest to youngest are designated the E-clay, the C-clay, and the A-clay. The E-clay is the thickest and most extensive of all the lacustrine and marsh deposits. Because the clays tend to confine ground water in the Fresno area, five water bodies are recognized. These are the unconfined water body, the shallow water body, the confined water body below the A-clay, the confined water body below the C-clay, and the confined water body below the E-clay. The unconfined water body underlies most of the Fresno area. The shallow and confined water bodies underlie parts of the extreme western part of the area. There, heads in successively underlying water bodies are less than those in overlying water bodies, indicating that some ground water moves slowly downward through the clays. From agricultural years 1957 to 1962, outflow in the area exceeded inflow. As a result, for this period, the Fresno area had a net deficit of about 2,890,000 acre-feet. This deficit was made up for mostly by a decline in ground water stored. Water levels in all water bodies have been declining over the years, yet when streamflow and canal deliveries are large they show a general rise. The general movement of ground water in the Fresno area is toward the southwest, although pumping depressions near Fresno and near the western part of the area, cause ground water to move northward, southward, and westward toward them.

California↗

Development of water facilities in the Santa Ana River Basin, California, 1810-1968: a compilation of historical notes derived from many sources describing ditch and canal companies, diversions, and water rights

This report traces by text, maps, and photographs, the development of the water supply in the Santa Ana River basin from its beginning in 1810 or 1811 to 1968. The value of the report lies in the fact that interpretation of the hydrologic systems in the basin requires knowledge of the concurrent state of development of the water supply, because that development has progressively altered the local regimen of both surface water and ground water. Most of the information for the earlier years was extracted and condensed from an investigation made by W. H. Hall, California State Engineer during the years 1878-87. Hall's study described irrigation development in southern California from its beginning through 1888. Information for the years following 1888 was obtained from the archives of the numerous water companies and water agencies in the Santa Ana River basin and from the various depositories of courthouse, county, and municipal records. The history of water-resources development in the Santa Ana River basin begins with the introduction of irrigation in the area by the Spanish, who settled in southern California in the latter part, of the 18th century. The first irrigation diversion from the Santa Ana River was made in 1810 or 1811 by Jose Antonio Yorba and Juan Pablo Peralta. Irrigation remained a localized practice during the Mexican-Californian, or rancho, period following the separation of Mexico from Spain in 1821. Rancho grantees principally raised cattle, horses, and sheep and irrigated only small· plots of feed grain for their livestock and fruit crops for household use. The breakup of the ranchos through sales to Americans, who were migrating to California in ever-increasing numbers following the acquisition of California by the United States in 1848, marked the beginning of a rapid increase in water use and the beginning of widespread irrigation. Many water companies and water agencies were organized to divert the surface flow of the Santa Ana River and its tributaries for irrigation. The Santa Ana River had been a perennial stream, except in years of extreme drought, from its source in the mountains nearly to the Pacific Ocean. With the great increase in population and the accompanying use of water for irrigation, the river was no longer a perennial stream, and it was necessary to supplement the surface-water supply with ground water. Many wells were dug or drilled in the artesian areas of the upper basin; of those wells many originally flowed, but as ground-water pressures and levels declined, an increasing amount of pumping was required. Conservation measures were taken to store some of the surplus winter runoff for use during low runoff years and during summer periods of heavy demand. Conservation facilities included surface-storage reservoirs and water-spreading grounds or percolation basins for utilization of underground storage. The competition for water in the Santa Ana River basin has been accompanied by frequent litigation over water tights, and over the years these water rights have generally been established by court decree. Although the demand for water still increases, the water demand for agricultural use has declined since the mid-1940's in response to the rapid urbanization of agricultural areas. Since that date the continued expansion of communities has encroached significantly into the agricultural areas causing a decrease in water use for agriculture, a more than compensating increase in water use for municipal purposes, and a rapid change in the ownership of water rights. The urbanization of flood plains made floods potentially more damaging than they previously had been when the flood plains were used for agriculture. In recognition of this increased hazard, flood-control facilities such as reservoirs, debris basins, flood-conveyance channels, and levees have been constructed to reduce potential damage. Most of the construction has occurred since the devastating flood of March 1938. By the mid-1940's it was apparent that the local water supply--both surface and ground water--would be insufficient to meet the increasing demand in the basin. To augment the local supply, Colorado River water was purchased from the Metropolitan Water District of Southern California and released to the Santa Ana River beginning in August 1949. Additional supplemental water became available in the early 1970's from northern California through the conveyance facilities of the California Water Project.

California↗

Use and occurrence of pesticides in the Apalachicola-Chattahoochee-Flint River basin, Georgia, Alabama, and Florida, 1960-91

The Apalachicola-Chattahoochee-Flint (ACF) River basin was one of the first 20 study units selected in 1991 by the U.S. Geological Survey for its National Water-Quality Assessment (NAWQA) program. Because pesticide contamination of surface water and ground water is a concern nationwide, a major emphasis of the NAWQA program is to examine the occurrence and distribution of pesticides in the water resources of these study unit basins. An understanding of the types and distribution of land uses; pesticide properties, pest-control practices, and pesticide use; and an evaluation of the occurrence and distribution of pesticides in the water resources of the ACF are necessary to meet this objective of the NAWQA program. This report describes land use and pesticide use at a county level, and the occurrence and distribution of pesticides in the water resources of the ACF River basin on the basis of previously-collected data. About 33 percent of the ACF River basin is used for agriculture, 16 percent is used for silviculture, and about 5 percent of the basin is in urban and suburban settings; primarily the Columbus, Albany, and Atlanta Metropolitan areas. The remainder is in wetlands and non-silvicultural forest. A broad range of synthetic-organic herbicides, insecticides, and fungicides are applied to land in agricultural, silvicultural, urban, and suburban areas. The period of intensive pesticide applications extends from March to October. Pesticide data available for the period from 1971 through 1989 in the U.S. Geological Survey National Water Information System (NWIS) and for the period from 1960 through 1991 in the U.S. Environmental Protection Agency Storage and Retrieval System (STORET) were analyzed to describe the occurrence and distribution of pesticides in water resources of the ACF River basin. Collectively, the NWIS and STORET databases contain about 19,600 individual analyses for pesticide concentration in the ACF River basin. Pesticide concentrations were at or above a minimum reporting level in about five percent of all analyses. Most of the pesticide analyses and most of the analyses having concentrations above minimum reporting levels in these databases are for organochlorine insecticides in samples collected five or more years before this study. With few exceptions, most of organochlorine insecticides are now banned from use in the United States. Concentrations of currently (1991) used pesticides were at or above a minimum reporting level in about 0.3 percent of the analyses. The geographic patterns in the occurrence and distribution of pesticides in the ACF River basin (as defined by data collected during 1960-91) are, as expected, somewhat defined by land-use patterns. DDT (together with DDD and DDE) were detected in wide distribution in the sediments and aquatic biota of primarily mainstem and reservoir sites in the Chattahoochee, Flint, and Apalachicola drainages. DDT was used through 1973 as an insecticide on cotton, fruits, and vegetables; and for mosquito control, so its widespread occurrence in both urban and agricultural settings is consistent with its use. Chlordane, heptachlor, dieldrin, and related compounds were agriculturally used through 1974, but predominantly as termiticides through the late 1980’s. Compounds in these groups have been found in the sediments and aquatic biota of tributary streams draining the Atlanta Metropolitan area and of mainstem reaches and reservoirs of the Chattahoochee River downstream from the Atlanta and Columbus, Ga., Metropolitan areas. The phenoxy-acid herbicides are widely used in residential, commercial/industrial, agricultural, and silvicultural areas of the ACF River basin. Detectable concentrations of 2,4-D were found in most of the surface-waters sampled in the Atlanta Metropolitan area. It is unfortunate that only limited inference can be drawn on temporal patterns. Many of the Federal and State agency pesticide-monitoring programs have been targeted to known sources and areas of contamination, an approach consistent with regulatory requirements focused on human health; and either were synoptic in nature or were conducted during a limited period of time. Thus, the composite temporal picture represented by these sampling efforts is inherently patchy.

Alabama, Florida, Georgia↗

The Beaver Creek story

Beaver Creek watershed in West Tennessee includes about 95,000 acres of the Nation's most productive farmland and most highly erodible soils. In 1989 the U.S. Geological Survey, in cooperation with the Tennessee Department of Agriculture, began a study to evaluate the effect of agricultural activities on water quality in the watershed and for best management practices designed to reduce agricultural nonpoint-source pollution. Agrichemical monitoring included testing the soils, ground water, and streams at four farm sites ranging from 27 to 420 acres. Monitoring stations were operated downstream to gain a better understanding of the water chemistry as runoff moved from small ditches into larger streams to the outlet of the Beaver Creek watershed. Prior to the implementation of best management practices at one of the farm study sites, some storms produced an average suspended-sediment concentration of 70,000 milligrams per liter. After the implementation of BMP's, however, the average value never exceeded 7,000 milligrams per liter. No-till crop production was the most effective best management practice for conserving soil on the farm fields tested. A natural bottomland hardwood wetland and a constructed wetland were evaluated as instream resource-management systems. The wetlands improved water quality downstream by acting as a filter and removing a significant amount of nonpoint-source pollution from the agricultural runoff. The constructed wetland reduced the sediment, pesticide, and nutrient load by approximately 50 percent over a 4-month period. The results of the Beaver Creek watershed study have increased the understanding of the effects of agriculture on water resources. Study results also demonstrated that BMP's do protect and improve water quality.

Open-File Report↗

Selenium

Selenium (Se) was discovered in 1817 in pyrite from copper mines in Sweden. It is a trace element in Earth’s crust, with an abundance of three to seven orders of magnitude less than the major rock-forming elements. Commercial use of selenium began in the United States in 1910, when it was used as a pigment for paints, ceramic glazes, and red glass. Since that time, it has had many other economic uses—notably, in the 1930s and 1940s, when it was used in rectifiers (which change alternating current to direct current), and in the 1960s, when it began to be used in the liner of photocopier drums. In the 21st century, other compounds have replaced selenium in these older products; modern uses for selenium include energy-efficient windows that limit heat transfer and thin-film photovoltaic cells that convert solar energy into electricity. In Earth’s crust, selenium is found as selenide minerals, selenate and selenite salts, and as substitution for sulfur in sulfide minerals. It is the sulfide minerals, most commonly those in porphyry copper deposits, that provide the bulk of the selenium produced for the international commodity market. Selenium is obtained as a byproduct of copper refining and recovered from the anode slimes generated in electrolytic production of copper. Because of this, the countries that have the largest resources and (or) reserves of copper also have the largest resources and (or) reserves of selenium. Because selenium occurs naturally in Earth’s crust, its presence in air, water, and soil results from both geologic reactions and human activity. Selenium is found concentrated naturally in soils that overlie bedrock with high selenium concentrations. Selenium mining, processing, use in industrial and agricultural applications, and disposal may all contribute selenium to the environment. A well-known case of selenium contamination from agricultural practices was discovered in 1983 in the Kesterson National Wildlife Refuge in California. There, waters draining from agricultural fields created wetlands with high concentrations of dissolved selenium in the water. The selenium was taken up by aquatic wildlife and caused massive numbers of embryonic deformities and deaths. Regulatory agencies have since worked to safeguard ecological and human health by creating environmental exposure guidelines based upon selenium concentrations in water and in fish tissue. Any attempt to regulate selenium concentrations requires a delicate balance because selenium occurs naturally and is also a vital nutrient for the health of wildlife, domestic stock, and humans. Selenium is commonly added as a vitamin to animal feed, and in some regions of the United States and the world, it is added as an amendment to soils for uptake by agricultural crops. The important role of selenium in economic products, energy supply, agriculture, and health will continue for well into the future. The challenge to society is to balance the benefits of selenium use with the environmental consequences of its extraction. Increased understanding of the elemental cycle of selenium in the earth may lead to new (or unconventional) sources of selenium, the discovery of new methods of extraction, and new technologies for minimizing the transfer of selenium from rock to biota, so to protect environmental and human health.

Professional Paper↗

The effects of management practices on grassland birds — An introduction to North American grasslands and the practices used to manage grasslands and grassland birds

The Great Plains of North America is defined as the land mass that encompasses the entire central portion of the North American continent that, at the time of European settlement, was an unbroken expanse of primarily herbaceous vegetation. The Great Plains extend from central Saskatchewan and Alberta to central Mexico and from Indiana to the Rocky Mountains. The expanses of herbaceous vegetation are often referred to as native prairie or native grasslands. Native grasslands share the characteristics of a general uniformity in vegetation structure, dominance by grasses and forbs, a near absence of trees and shrubs, annual precipitation ranging from 25 to 100 centimeters, extreme intra-annual fluctuations in temperature and precipitation, and a flat to rolling topography over which fires can spread. To the west of the Great Plains lie the sagebrush communities of the Great Basin, which extend from British Columbia and Saskatchewan to northern Arizona and New Mexico and from the eastern slopes of the Sierra Nevada and Cascade mountain ranges to western South Dakota. Sagebrush communities share similar characteristics to native grasslands, but their location east of the Rocky Mountains creates a more moderating influence from prevailing westerly winds that affect timing of peak precipitation and growth form of dominant vegetation. Native grasslands and sagebrush communities harbor a diverse array of grassland, wetland, and woodland plant and animal communities that are uniquely adapted to the natural forces of the Great Plains and Great Basin, namely the interactive forces of climate, fire, and grazing. The arrival of European settlers to North America brought profound change to native grassland and sagebrush communities, including the establishment of permanent towns and cities, the proliferation of cropland-based agricultural systems, and the suppression of wildfires. The near extirpation of bison by the 1860s paved the way for dramatic changes in the dominant grazers and a shift in the disturbance patterns that historically influenced vegetation structure. The greatest threat to native grasslands and sagebrush communities in modern times is their loss due to conversion to rowcrop agriculture and to urbanization. Concomitant with habitat loss is a precipitous decline in populations of bird species that evolved with, and are uniquely adapted to, the native grassland and sagebrush habitats. Avian population trends are linked strongly to agricultural land use. Besides outright loss of suitable breeding habitat, agricultural practices affect birds through factors such as pesticide exposure, habitat fragmentation, shifts in predator community composition, and occurrence of brood parasites. Bird populations face other stressors, such as loss of habitat to and behavioral avoidance of urbanized areas, roads, and infrastructure associated with energy production. Despite the many anthropogenic changes to North American grassland and sagebrush communities, some bird species are adaptable and opportunistic in their habitat selection and now utilize one or more human-created habitats. Human-created habitats include pastures, hayfields, agricultural terraces, crop buffer strips, field borders, grassed waterways, fencerows, road rights-of-way, airports, reclaimed coal mines, and planted wildlife cover. Fields of seeded grasslands enrolled in Federal long-term set-aside programs, such as the Conservation Reserve Program in the United States and the Permanent Cover Program in Canada, provide important nesting habitat for grassland bird species. The array of habitats used by birds makes habitat and avian management a complex undertaking, and the scale (for example, local, regional, international) at which management actions can be implemented are such that a universal approach to managing grasslands for the conservation of the entire suite of bird species does not exist. Experienced land managers recognize that it is impossible to manage for all bird species simultaneously, and thus, prioritization is necessary towards those habitats or bird species that the manager or management agency ranks highest for a specific region or management unit. The primary tools available for management are burning, grazing, mowing, herbicide application, and idling, but before choosing a particular practice, a manager will want to consider issues of seasonality, intensity, and frequency. Despite the thousands of studies that are cited in this compendium, much remains unknown about the effects of management practices on bird species. The series of species accounts in this compendium review the current state of knowledge regarding management of grassland and sagebrush bird species and summarize information on the effects of management practices on individual species. The accounts do not give definitive statements on the effects of management practices for any particular species, primarily because there are very few replicated studies in which identical management practices have been applied in the same geographical area with consistent results, which are elements necessary to provide concrete recommendations for the management of a particular species in a particular area. Documentation of the effects of management treatments on individual species through statistically sound methods that incorporate multiple years and locations will further scientists’ and land managers’ knowledge far more than 1–2-year studies that are limited in scope as well as time, but studies of that scope and breadth are rare.

Professional Paper↗

Chemistry of ground water in the Silver Springs basin, Florida, with an emphasis on nitrate

The Silver Springs group, in central Marion County, Florida, has a combined average discharge rate of 796 cubic feet per second and forms the headwaters of the Silver River. The springs support a diverse ecosystem and are an important cultural and economic resource. Concentrations of nitrite-plus-nitrate (nitrate-N) in water from the Main Spring increased from less than 0.5 milligrams per liter (mg/L) in the 1960s to about 1.0 mg/L in 2003. The Upper Floridan aquifer supplies the ground water to support spring discharge. This aquifer is at or near land surface in much of the ground-water basin; nutrients leached at land surface can easily percolate downward into the aquifer. Sources of nitrogen in ground water in the Silver Springs basin include atmospheric deposition, fertilizers used by agricultural and urban activities, and human and animal wastes. During 2000-2001, 56 wells in the area contributing recharge to Silver Springs were sampled for major ions, nutrients, and some trace constituents. Selected wells also were sampled for a suite of organic constituents commonly found in domestic and industrial wastewater and for the ratio of nitrogen isotopes (15N/14N) to better understand the sources of nitrate. Wells were selected to be representative of both confined and unconfined conditions of the Upper Floridan aquifer, as well as a variety of land-use types. Data from this study were compared to data collected from 25 wells in 1989-90. Concentrations of nitrate-N in ground water during this study ranged from less than the detection limit of 0.02 to 12 mg/L, with a median of 1.2 mg/L. For data from 1989-90, the range was from less than 0.02 to 3.6 mg/L, with a median of 1.04 mg/L. Water from wells in agricultural land-use areas had the highest median nitrate-N concentration (1.7 mg/L), although it is uncertain if the 12 mg/L maximum concentration was influenced by land-use activities or proximity to a septic tank. The median value for all urban land-use areas was 1.15 mg/L. Because fewer wells were in rangeland or forested areas, those categories were grouped together. The median concentration for that group was 0.09 mg/L. The ratio of 15N/14N in ground-water samples ranged from -0.5 to 11.5 per mil. The median value for ground-water samples from 35 wells, 4.9 per mil, is near the top of the range that indicates inorganic nitrogen sources. In agricultural areas, the median 15N/14N was 4.8 per mil, indicating mostly inorganic (fertilizer) sources. In urban areas, the median 15N/14N was 5.4 per mil, indicating more influence of organic nitrogen (N) sources. Thus, in both agricultural and urban areas, fertilizer is an important inorganic source of N in ground water (and, therefore, in spring water as well). The influence of organic N is more apparent in urban areas than in agricultural areas. Two distinct 15N/14N values were observed in water from the Main Spring, one indicating an inorganic nitrogen source and the other indicating a mixture of sources with a strong influence of organic nitrogen. Thirty-five wells and three springs of the Silver Springs group (the Main Spring, the Abyss, and the Blue Grotto) were sampled for a suite of 63 compounds common in wastewater. A total of 38 compounds was detected, nearly all in very low concentrations. The most frequently detected compound was the insecticide N,N-diethyl-meta-toluamide (DEET), which was detected in water from 27 wells and all three springs. The presence or absence of DEET in ground-water samples did not seem to be related to land use; however, hydrogeologic conditions at the well sites (confined or unconfined) generally did affect the presence or absence of DEET in the ground water. DEET also appears to be a useful tracer for the presence of reused water. Water samples were collected from the Main Spring and two other springs of the Silver Springs group and analyzed for concentrations of dissolved gasses and for chlorofluorocarbons (CFCs), sulfur hexaflu

Scientific Investigations Report↗

Hydrogeology, Chemical Characteristics, and Transport Processes in the Zone of Contribution of a Public-Supply Well in York, Nebraska

In 2001, the U.S. Geological Survey, as part of the National Water Quality Assessment (NAWQA) Program, initiated a topical study of Transport of Anthropogenic and Natural Contaminants (TANC) to PSW (public-supply wells). Local-scale and regional-scale TANC study areas were delineated within selected NAWQA study units for intensive study of processes effecting transport of contaminants to PSWs. This report describes results from a local-scale TANC study area at York, Nebraska, within the High Plains aquifer, including the hydrogeology and geochemistry of a 108-square-kilometer study area that contains the zone of contribution to a PSW selected for study (study PSW), and describes factors controlling the transport of selected anthropogenic and natural contaminants to PSWs. Within the local-scale TANC study area, the High Plains aquifer is approximately 75 m (meter) thick, and includes an unconfined aquifer, an upper confining unit, an upper confined aquifer, and a lower confining unit with lower confined sand lenses (units below the upper confining unit are referred to as confined aquifers) in unconsolidated alluvial and glacial deposits overlain by loess and underlain by Cretaceous shale. From northwest to southeast, land use in the local-scale TANC study area changes from predominantly irrigated agricultural land to residential and commercial land in the small community of York (population approximately 8,100). For the purposes of comparing water chemistry, wells were classified by degree of aquifer confinement (unconfined and confined), depth in the unconfined aquifer (shallow and deep), land use (urban and agricultural), and extent of mixing in wells in the confined aquifer with water from the unconfined aquifer (mixed and unmixed). Oxygen (delta 18O) and hydrogen (delta D) stable isotopic values indicated a clear isotopic contrast between shallow wells in the unconfined aquifer (hereinafter, unconfined shallow wells) and most monitoring wells in the confined aquifers (hereinafter, confined unmixed wells). Delta 18O and delta D values for a minority of wells in the confined aquifers were intermediate between those for the unconfined shallow wells and those for the confined unmixed wells. These intermediate values were consistent with mixing of water from unconfined and confined aquifers (hereinafter, confined mixed wells). Oxidation-reduction conditions were primarily oxic in the unconfined aquifer and variably reducing in the confined aquifers. Trace amounts of volatile organic compounds (VOC), particularly tetrachloroethylene (PCE) and trichloroethylene (TCE), were widely detected in unconfined shallow urban wells and indicated the presence of young urban recharge waters in most confined mixed wells. The presence of degradation products of agricultural pesticides (acetochlor and alachlor) in some confined mixed wells suggests that some fraction of the water in these wells also was the result of recharge in agricultural areas. In the unconfined aquifer, age-tracer data (chlorofluorocarbon and sulfur hexafluoride data, and tritium to helium-3 ratios) fit a piston-flow model, with apparent recharge ages ranging from 7 to 48 years and generally increasing with depth. Age-tracer data for the confined aquifers were consistent with mixing of 'old' water, not containing modern tracers recharged in the last 60 years, and exponentially-mixed 'young' water with modern tracers. Confined unmixed wells contained less than (<) 3 percent (%) young water mixed with a much larger fraction greater than or equal to (>=) 97% of old water. Confined mixed wells contained >30% young water and mean ages ranged from 12 to 14 years. Median concentrations of nitrate (as nitrogen, hereinafter, nitrate-N) were 17.3 and 16.0 mg/L (milligram per liter) in unconfined shallow urban and agricultural wells, respectively, indicating a range of likely nitrate sources. Septic systems are most numerous near the edge of the urban area and appear to be

Scientific Investigations Report↗

Sources, transport, and storage of sediment at selected sites in the Chesapeake Bay Watershed

The Chesapeake Bay Watershed covers 165,800 square kilometers and is supplied with water and sediment from five major physiographic provinces: Appalachian Plateau, Blue Ridge, Coastal Plain, Piedmont, and the Valley and Ridge. Suspended-sediment loads measured in the Chesapeake Bay Watershed showed that the Piedmont Physiographic Province has the highest rates of modern (20th Century) sediment yields, measured at U.S. Geological Survey streamflow-gaging stations, and the lowest rates of background or geologic rates of erosion (~10,000 years) measured with in situ beryllium-10. In the agricultural and urbanizing Little Conestoga Creek Watershed, a Piedmont watershed, sources of sediment using the 'sediment-fingerprinting' approach showed that streambanks were the most important source (63 percent), followed by cropland (37 percent). Cesium-137 inventories, which quantify erosion rates over a 40-year period, showed average cropland erosion of 19.39 megagrams per hectare per year in the Little Conestoga Creek Watershed. If this erosion rate is extrapolated to the 13 percent of the watershed that is in cropland, then cropland could contribute almost four times the measured suspended-sediment load transported out of the watershed (27,600 megagrams per hectare per year), indicating that much of the eroded sediment is being deposited in channel and upland storage. The Piedmont has had centuries of land-use change, from forest to agriculture, to suburban and urban areas, and in some areas, back to forest. These land-use changes mobilized a large percentage of sediment that was deposited in upland and channel storage, and behind thousands of mill dams. The effects of these land-use changes on erosion and sediment transport are still being observed today as stored sediment in streambanks is a source of sediment. Cropland is also an important source of sediment. The Coastal Plain Physiographic Province has had the lowest sediment yields in the 20th Century and with sandy soils, contributes little fine-grained sediment. In the agricultural Pocomoke River Watershed, a Coastal Plain watershed, cesium-137 mass-balance results indicate that erosion and deposition are both occurring on cropland fields. Sources of sediment using the sediment-fingerprinting approach for the Pocomoke River were distributed as follows: cropland (46 percent), ditch beds (34 percent), ditch banks and streambanks (7 percent), and forest (13 percent). Cropland was a source of sediment for the two largest peak flow events, which occurred during harvesting when the ground may have been bare. The Pocomoke River Watershed is heavily ditched and channelized, conditions that are favorable for ditch bed and bank erosion. In the mixed land use (forested, agricultural, and urbanizing) Mattawoman Creek Watershed, a Coastal Plain watershed, sources of sediment using the sediment-fingerprinting approach were distributed as follows: streambanks (30 percent), forest (29 percent), construction (25 percent), and cropland (17 percent). Mattawoman Creek Watershed drains a rapidly developing region with 182 hectares (approximately 1.26 percent of the watershed) under construction. Sediment from construction sites was also determined as a source of sediment in the Mattawoman Creek Watershed. The sediment-fingerprinting source results for the three watersheds analyzed, show that in all watersheds, both the stream corridor and agriculture were significant sources of sediment. Forest as a source of sediment in the Mattawoman Creek Watershed may indicate that these forests are being disturbed and forest soils are eroding. Bare ground can be an important sediment source. Spatial analysis of bare ground in the Little Conestoga Creek Watershed using satellite imagery between 2000 and 2005 showed that the majority of bare ground was classified as pasture. Bare ground was correlated to the growing season with the highest percentages occurring in the early spring (April, 34 percent) and a

Chesapeake Bay Watershed↗

Spatially referenced statistical assessment of dissolved-solids load sources and transport in streams of the Upper Colorado River Basin

The Upper Colorado River Basin (UCRB) discharges more than 6 million tons of dissolved solids annually, about 40 to 45 percent of which are attributed to agricultural activities. The U.S. Department of the Interior estimates economic damages related to salinity in excess of $330 million annually in the Colorado River Basin. Salinity in the UCRB, as measured by dissolved-solids load and concentration, has been studied extensively during the past century. Over this period, a solid conceptual understanding of the sources and transport mechanisms of dissolved solids in the basin has been developed. This conceptual understanding was incorporated into the U.S. Geological Survey Spatially Referenced Regressions on Watershed Attributes (SPARROW) surface-water quality model to examine statistically the dissolved-solids supply and transport within the UCRB. Geologic and agricultural sources of dissolved solids in the UCRB were defined and represented in the model. On the basis of climatic and hydrologic conditions along with data availability, water year 1991 was selected for examination with SPARROW. Dissolved-solids loads for 218 monitoring sites were used to calibrate a dissolved-solids SPARROW model for the UCRB. The calibrated model generally captures the transport mechanisms that deliver dissolved solids to streams of the UCRB as evidenced by R2 and yield R2 values of 0.98 and 0.71, respectively. Model prediction error is approximated at 51 percent. Model results indicate that of the seven geologic source groups, the high-yield sedimentary Mesozoic rocks have the largest yield of dissolved solids, about 41.9 tons per square mile (tons/mi2). Irrigated sedimentary-clastic Mesozoic lands have an estimated yield of 1,180 tons/mi2, and irrigated sedimentary-clastic Tertiary lands have an estimated yield of 662 tons/mi2. Coefficients estimated for the seven landscape transport characteristics seem to agree well with the conceptual understanding of the role they play in the delivery of dissolved solids to streams in the UCRB. Predictions of dissolved-solids loads were generated for more than 10,000 stream reaches of the stream network defined in the UCRB. From these estimates, the downstream accumulation of dissolved solids, including natural and agricultural components, were examined in selected rivers. Contributions from each of the 11 dissolved-solids sources were also examined at select locations in the Grand, Green, and San Juan Divisions of the UCRB. At the downstream boundary of the UCRB, the Colorado River at Lees Ferry, Arizona, monitoring site, the dissolved-solids contribution of irrigated agricultural lands and natural sources were about 45 and 57 percent, respectively. Finally, model predictions, including the contributions of natural and agricultural sources for selected locations in the UCRB, were compared with results from two previous studies.

Arizona, Colorado, Idaho, New Mexico, Utah, Wyomin↗

Water Withdrawals, Use, and Trends in Florida, 2005

In 2005, the total amount of water withdrawals in Florida was estimated at 18,359 million gallons per day (Mgal/d). Saline water accounted for 11,486 Mgal/d (63 percent), and freshwater accounted for 6,873 Mgal/d (37 percent). Groundwater accounted for 4,247 Mgal/d (62 percent) of freshwater withdrawals, and surface water accounted for the remaining 2,626 Mgal/d (38 percent). Surface water accounted for nearly all (99.9 percent) saline-water withdrawals. An additional 660 Mgal/d of reclaimed wastewater was used in Florida during 2005. The largest amount of freshwater was withdrawn from Palm Beach County, and the largest amount of saline water was withdrawn from Pasco County. Fresh groundwater provided drinking water (public supplied and self-supplied) for 16.19 million people (90 percent of Florida's population), and fresh surface water provided drinking water for 1.73 million people (10 percent). The majority of groundwater withdrawals (nearly 60 percent) in 2005 was obtained from the Floridan aquifer system which is present throughout the entire State. The majority of fresh surface-water withdrawals (59 percent) came from the southern Florida hydrologic unit subregion and is associated with Lake Okeechobee and the canals in the Everglades Agricultural Area of Glades, Hendry, and Palm Beach Counties, as well as the Caloosahatchee River and its tributaries in the agricultural areas of Collier, Glades, Hendry, and Lee Counties. Overall, agricultural irrigation accounted for 40 percent of the total freshwater withdrawals (ground and surface), followed by public supply with 37 percent. Public supply accounted for 52 percent of groundwater withdrawals, followed by agricultural self-supplied (31 percent), ommercial-industrial-mining self-supplied (8.5 percent), recreational irrigation and domestic self-supplied (4 percent each), and power generation (0.5 percent). Agricultural self-supplied accounted for 56 percent of fresh surface-water withdrawals, followed by power generation (20.5 percent), public supply (13 percent), recreational irrigation (6 percent), and commercial-industrial self-supplied (4.5 percent). Power generation accounted for nearly all (99.9 percent) saline-water withdrawals. Of the 17.92 million people who resided in Florida during 2005, 41 percent (7.36 million people) resided in the South Florida Water Management District (SFWMD), followed by the St. Johns River Water Management District (SJRWMD) and the Southwest Florida Water Management District (SWFWMD) with 25 percent each (4.46 and 4.44 million people, respectively), the Northwest Florida Water Management District (NWFWMD) with 7.5 percent (1.34 million people), and the Suwannee River Water Management District (SRWMD) with 1.5 percent (0.32 million people). The largest amount of freshwater withdrawals was from the SFWMD, which was one-half (50 percent) of the State's total freshwater withdrawals, followed by the SJRWMD (19 percent), SWFWMD (16 percent), NWFWMD (10 percent), and SRWMD (5 percent). Between 1950 and 2005, the population of Florida increased by 15.15 million (550 percent), and the total water withdrawals (fresh and saline) increased 15,700 Mgal/d (600 percent). More recently, total withdrawals decreased 1,790 Mgal/d (9 percent) between 2000 and 2005, but the total population increased by 1.94 million (12 percent). Between 1990 and 2005, saline-water withdrawals increased 1,120 Mgal/d (11 percent), whereas between 2000 and 2005, saline-water withdrawals decreased 470 Mgal/d (4 percent). Between 1990 and 2005, freshwater withdrawals decreased 710 Mgal/d (9 percent), whereas between 2000 and 2005, freshwater withdrawals decreased 1,320 Mgal/d (16 percent). The use of highly mineralized groundwater as a source of supply, primarily for public supply, also has increased in Florida. This water, referred as nonpotable water, increased from just less than 2 Mgal/d in 1970, to 142 Mgal/d in 2005. Nonpotable water is treated to meet drin

Scientific Investigations Report↗

Relation of water quality to land use in the drainage basins of six tributaries to the lower Delaware River, New Jersey, 2002-07

Concentrations and loads of water-quality constituents in six streams in the lower Delaware River Basin of New Jersey were determined in a multi-year study conducted by the U.S. Geological Survey, in cooperation with the New Jersey Department of Environmental Protection. Two streams receive water from relatively undeveloped basins, two from largely agricultural basins, and two from heavily urbanized basins. Each stream was monitored during eight storms and at least eight times during base flow during 2002-07. Sampling was conducted during base flow before each storm, when stage was first observed to rise, and several times during the rising limb of the hydrographs. Agricultural and urban land use has resulted in statistically significant increases in loads of nitrogen and phosphorus species relative to loads in undeveloped basins. For example, during the growing season, median storm flow concentrations of total nitrogen in the two streams in agricultural areas were 6,290 and 1,760 mg/L, compared to 988 and 823 mg/L for streams in urban areas, and 719 and 333 mg/L in undeveloped areas. Although nutrient concentrations and loads were clearly related to land useurban, agricultural, and undeveloped within the drainage basins, other basin characteristics were found to be important. Residual nutrients entrapped in lake sediments from streams that received effluent from recently removed sewage-treatment plants are hypothesized to be the cause of extremely high levels of nutrient loads to one urban stream, whereas another urban stream with similar land-use percentages (but without the legacy of sewage-treatment plants) had much lower levels of nutrients. One of the two agricultural streams studied had higher nutrient loads than the other, especially for total phosphorous and organic nitrogen. This difference appears to be related to the presence (or absence) of livestock (cattle).

Scientific Investigations Report↗

Characterization of salinity and selenium loading and land-use change in Montrose Arroyo, western Colorado, from 1992 to 2010

Salinity and selenium are naturally occurring and perva-sive in the lower Gunnison River Basin of Colorado, includ-ing the watershed of Montrose Arroyo. Although some of the salinity and selenium loading in the Montrose Arroyo study area is from natural sources, additional loading has resulted from the introduction of intensive irrigation in the water-shed. With increasing land-use change and the conversion from irrigated agricultural to urban land, land managers and stakeholders need information about the long-term effects of land-use change on salinity and selenium loading. In response to the need to advance salinity and selenium science, the U.S. Geological Survey, in cooperation with the Bureau of Reclamation, Colorado River Basin Salinity Control Forum, and Colorado River Water Conservation District, developed a study to characterize salinity and selenium loading and how salinity and selenium sources may relate to land-use change in Montrose Arroyo. This report characterizes changes in salinity and selenium loading to Montrose Arroyo from March 1992 to February 2010 and the magnitude of land-use change between unirrigated desert, irrigated agricultural, and urban land-use/land-cover types, and discusses how the respective loads may relate to land-use change. Montrose Arroyo is an approximately 8-square-mile watershed in Montrose County in western Colorado. Salinity and selenium were studied in Montrose Arroyo in a 2001 study as part of a salinity- and selenium-control lateral project. The robust nature of the historical dataset indicated that Montrose Arroyo was a prime watershed for a follow-up study. Two sites from the 2001 study were used to monitor salinity and selenium loads in Montrose Arroyo in the follow-up study. Over the period of 2 water years and respective irrigation seasons (2008-2010), 27 water-quality samples were collected and streamflow measurements were made at the historical sites MA2 and MA4. Salinity and selenium concen-trations, loads, and streamflow were compared between the pre-lateral-project and post-growth periods and between the post-lateral-project and post-growth periods. No significant differences in streamflow, salinity (concen-tration and load), or selenium (concentration and load) were found at MA4 between the pre-lateral project and post-growth periods or between the post-lateral-project and post-growth periods. The statistical analysis indicated no significant dif-ferences in streamflow or salinity (both concentration and load) between the pre-lateral-project and post-growth periods or between the post-lateral-project and post-growth periods at MA2; however, selenium concentrations and loads were significantly greater between the pre-lateral-project and post-growth periods and between the post-lateral-project and post-growth periods at MA2. Land-use change between MA4 and MA2 may have contributed to the determined differences in selenium values, but the specific mechanisms causing the increases between periods are unknown. The size of the urbanized area in Montrose Arroyo was quantified for 1993, 2002, and 2009 by using a geographic information system (GIS) with imagery from the specified years. The greatest change in land use from 1993 to 2009 was the increase of urban land due to conversion from irrigated agricultural land. The conversion of previously unirrigated desert to urban land or irrigated agriculture could become more common if urbanization and development expands into the eastern part of the watershed because a majority of the un-urbanized land in eastern Montrose Arroyo is unirrigated desert. By applying GIS to the City of Montrose 2008 com-prehensive growth plan, it was estimated that approximately 786 acres of previously irrigated agricultural land will be converted to urban land and 689 acres of unirrigated desert will be converted to urban land under the plan scenario. New development on previously unirrigated land in shale areas would likely increase the potential for mobilization of sele-nium and salinity from new sources to Montrose Arroyo and the Lower Gunnison River Basin.

Scientific Investigations Report↗

Reconnaissance of land-use sources of pesticides in drinking water, McKenzie River, Oregon

The Eugene Water and Electric Board (EWEB) provides water and electricity to the City of Eugene, Oregon, from the McKenzie River. In the spring of 2002, EWEB initiated a pesticide monitoring program in cooperation with the U.S. Geological Survey as part of their Drinking Water Source Protection Plan. Approximately twice yearly pesticide samples were collected from 2002 to 2010 at a suite of sampling sites representing varying land uses in the lower McKenzie River basin. A total of 117 ambient samples were collected from 28 tributary and mainstem sites, including those dominated by forestry, urban, and agricultural activities, as well as the mouths of major tributaries characterized by a mixture of upstream land use. Constituents tested included 175 compounds in filtered water (72 herbicides, 43 insecticides, 10 fungicides, and 36 of their degradation products, as well as 14 pharmaceutical compounds). No attempt was made to sample different site types equivalently; sampling was instead designed primarily to characterize representative storm events during spring and fall runoff conditions in order to assess or confirm the perceived importance of the different site types as sources for pesticides. Sampling was especially limited for agricultural sites, which were only sampled during two spring storm surveys. A total of 43 compounds were detected at least once, with many of these detected only at low concentrations (<0.1 micrograms per liter). Nine compounds were detected at the drinking- water intake, and most of these were reported as estimates less than the laboratory reporting level. Human-health benchmark concentrations were consistently several orders of magnitude higher than detected concentrations at the intake, indicating that pesticide concentrations present a negligible threat to human health. The largest number of pesticide detections occurred during spring storm surveys and primarily were associated with urban stormwater drains. Urban sites also were associated with the highest concentrations, occasionally exceeding 1 microgram per liter. Many of the compounds detected at urban sites were relatively hydrophobic (do not mix easily with water), persistent, and suspected of endocrine disruption. In contrast, forestry compounds were rarely detectable in the McKenzie River, even though forest land predominates in the basin and forestry pesticide use was detected in small tributaries draining forested lands following application. Agricultural pesticide runoff was not well characterized by the limited data available, although a large number of compounds was estimated to be used in the basin and concentrations were moderately high in the few samples collected from small tributaries draining agricultural lands. Results from this analysis indicate that urban pesticide use is potentially an important source for pesticides of concern for drinking water, not limited exclusively to storm conditions. Forestry pesticide use is not considered a likely threat to drinking water quality at the present time (2012). A more complete understanding of agricultural chemicals in runoff in the McKenzie River basin requires further investigation. In addition to evaluating the data collected in this study, a conceptual model describing pesticide contamination in the McKenzie River basin is provided, based on current scientific understanding that is consistent with the data analysis presented in this report. This model is intended to provide a foundation for future monitoring in the basin.

Oregon↗