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At least 865 records · Page 48Linked to original sources

Measurement of field-saturated hydraulic conductivity on fractured rock outcrops near Altamura (Southern Italy) with an adjustable large ring infiltrometer

Up to now, field studies set up to measure field-saturated hydraulic conductivity to evaluate contamination risks, have employed small cylinders that may not be representative of the scale of measurements in heterogeneous media. In this study, a large adjustable ring infiltrometer was designed to be installed on-site directly on rock to measure its field-saturated hydraulic conductivity. The proposed device is inexpensive and simple to implement, yet also very versatile, due to its large adjustable diameter that can be fixed on-site. It thus allows an improved representation of the natural system's heterogeneity, while also taking into consideration irregularities in the soil/rock surface. The new apparatus was tested on an outcrop of karstic fractured limestone overlying the deep Murge aquifer in the South of Italy, which has recently been affected by untreated sludge disposal, derived from municipal and industrial wastewater treatment plants. The quasi-steady vertical flow into the unsaturated fractures was investigated by measuring water levels during infiltrometer tests. Simultaneously, subsurface electrical resistivity measurements were used to visualize the infiltration of water in the subsoil, due to unsaturated water flow in the fractures. The proposed experimental apparatus works well on rock outcrops, and allows the repetition of infiltration tests at many locations in order to reduce model uncertainties in heterogeneous media. ?? 2009 Springer-Verlag.

Environmental Earth Sciences↗

Clay-catalyzed reactions of coagulant polymers during water chlorination

The influence of suspended clay/solid particles on organic-coagulant reactions during water chlorination was investigated by analyses of total product formation potential (TPFP) and disinfection by-product (DBP) distribution as a function of exchanged clay cation, coagulant organic polymer, and reaction time. Montmorillonite clays appeared to act as a catalytic center where the reaction between adsorbed polymer and disinfectant (chlorine) was mediated closely by the exchanged clay cation. The transition-metal cations in clays catalyzed more effectively than other cations the reactions between a coagulant polymer and chlorine, forming a large number of volatile DBPs. The relative catalytic effects of clays/solids followed the order Ti-Mont > Fe-Mont > Cu-Mont > Mn-Mont > Ca-Mont > Na-Mont > quartz > talc. The effects of coagulant polymers on TPFP follow the order nonionic polymer > anionic polymer > cationic polymer. The catalytic role of the clay cation was further confirmed by the observed inhibition in DBP formation when strong chelating agents (o-phenanthroline and ethylenediamine) were added to the clay suspension. Moreover, in the presence of clays, total DBPs increased appreciably when either the reaction time or the amount of the added clay or coagulant polymer increased. For volatile DBPs, the formation of halogenated methanes was usually time-dependent, with chloroform and dichloromethane showing the greatest dependence. ?? 2003 Elsevier Inc. All rights reserved.

Journal of Colloid and Interface Science↗

Chemical composition of leachates from hydraulic fracturing proppants from surficial releases in southeastern New Mexico

Resin-coated proppants (RCPs) are used in hydraulic fracturing of oil and gas wells to improve well performance; however, these proppants could be a cause for environmental concern if they are disposed of improperly. In this study, we investigate the water-leachable organic and inorganic constituents from proppants collected from surficial releases of RCPs in southeastern New Mexico. Significant concentrations of nonvolatile dissolved organic matter (>100 mg C/L) and phenolic compounds (>50 mg phenol/L) were identified in one of the proppant leachates, with further gas chromatography–mass spectrometry analysis identifying isomers of bisphenol F, a known endocrine disruptor analogous to bisphenol A, as the main organic constituents within this leachate. Fluorescence excitation–emission matrices analyses of proppant leachates identified several peaks associated with phenolic compounds, similar to previously studied oilfield wastewaters. Precursors of polyurethane production, including the inhalation sensitizer methylene diphenyl diisocyanate, were identified in the leachate from another proppant sample. An understanding of leachable compounds from RCPs is vital to management of environmental contamination from surficial releases, protecting the public and industry workers from associated hazards, and identifying the sources of organic compounds in oilfield wastewaters.

New Mexico↗

Zinc adsorption effects on arsenite oxidation kinetics at the birnessite-water interface

Arsenite is more toxic and mobile than As(V) in soil and sediment environments, and thus it is advantageous to explore factors that enhance oxidation of As(III) to As(V). Previous studies showed that manganese oxides, such as birnessite (??-MnO2), directly oxidized As(III). However, these studies did not explore the role that cation adsorption has on As(III) oxidation. Accordingly, the effects of adsorbed and nonadsorbed Zn on arsenite (As(III)) oxidation kinetics at the birnessite-water interface were investigated using batch adsorption experiments (0.1 g L-1; pH 4.5 and 6.0; I = 0.01 M NaCl). Divalent Zn adsorption on synthetic ??-MnO 2 in the absence of As(III) increased with increasing pH and caused positive shifts in electrophoretic mobility values at pH 4-6, indirectly suggesting inner-sphere Zn adsorption mechanisms. Arsenite was readily oxidized on birnessite in the absence of Zn. The initial As(III) oxidation rate constant decreased with increasing pH from 4.5 to 6.0 and initial As(III) concentrations from 100 to 300 ??M. Similar pH and initial As(III) concentration effects were observed in systems when Zn was present (i.e., presorbed Zn prior to As(III) addition and simultaneously added Zn-As(III) systems), but As(III) oxidation reactions were suppressed compared to the respective control systems. The suppression was more pronounced when Zn was presorbed on the ??-MnO 2 surfaces as opposed to added simultaneously with As(III). This study provides further understanding of As(III) oxidation reactions on manganese oxide surfaces under environmentally applicable conditions where metals compete for reactive sites.

Environmental Science & Technology↗

Humic acid facilitates the transport of ARS-labeled hydroxyapatite nanoparticles in iron oxyhydroxide-coated sand

Hydroxyapatite nanoparticles (nHAP) have been widely used to remediate soil and wastewater contaminated with metals and radionuclides. However, our understanding of nHAP transport and fate is limited in natural environments that exhibit significant variability in solid and solution chemistry. The transport and retention kinetics of Alizarin red S (ARS)-labeled nHAP were investigated in water-saturated packed columns that encompassed a range of humic acid concentrations (HA, 0–10 mg L –1 ), fractional surface coverage of iron oxyhydroxide coatings on sand grains (λ, 0–0.75), and pH (6.0–10.5). HA was found to have a marked effect on the electrokinetic properties of ARS-nHAP, and on the transport and retention of ARS-nHAP in granular media. The transport of ARS-nHAP was found to increase with increasing HA concentration because of enhanced colloidal stability and the reduced aggregate size. When HA = 10 mg L –1 , greater ARS-nHAP attachment occurred with increasing λ because of increased electrostatic attraction between negatively charged nanoparticles and positively charged iron oxyhydroxides, although alkaline conditions (pH 8.0 and 10.5) reversed the surface charge of the iron oxyhydroxides and therefore decreased deposition. The retention profiles of ARS-nHAP exhibited a hyperexponential shape for all test conditions, suggesting some unfavorable attachment conditions. Retarded breakthrough curves occurred in sands with iron oxyhydroxide coatings because of time-dependent occupation of favorable deposition sites. Consideration of the above effects is necessary to improve remediation efficiency of nHAP for metals and actinides in soils and subsurface environments.

Environmental Science & Technology↗

Soil physical, hydraulic, and thermal properties in interior Alaska, USA: Implications for hydrologic response to thawing permafrost conditions

Boreal forest regions are a focal point for investigations of coupled water and biogeochemical fluxes in response to wildfire disturbances, climate warming, and permafrost thaw. Soil hydraulic, physical, and thermal property measurements for mineral soils in permafrost regions are limited, despite substantial influences on cryohydrogeologic model results. This work expands mineral soil property quantification in cold regions through soil characterization from the discontinuous permafrost zone of interior Alaska, USA. Values extend beyond the range of prior measurement magnitudes in analogous regions, highlighting the importance of this dataset. Rocky and silty upland soil landscape classifications and wildfire disturbance provided guiding frameworks for the sampling and analysis for potential implications for the hydrologic response to thawing permafrost. Bulk density, soil organic matter, soil–particle size distributions (sand, silt, and gravel fractions), and soil hydraulic properties of van Genuchten parameters alpha and N had moderate evidence of differences between silty and rocky classifications. Burned and unburned sites had only moderate evidence of differences for silt fraction. Field-saturated hydraulic conductivity (Kfs) was more variable at burned sites compared to unburned sites, which corresponded to observations of greater rooting depths at burned sites and observations of root paths in soil cores for Kfs measurement. Soil thermal properties suggested that gravel content may reduce the accuracy of commonly used estimation methods for thermal conductivity . This work provides soil parameter constraints necessary for hypothesis testing and site-specific prediction with cryohydrogeologic models to examine controls on active layer and permafrost dynamics in upland boreal forests.

Alaska↗

Runoff in the Santa Ynez River Basin, California, following the excessive rainfall of 1940–41

This paper reports briefly on the runoff‐characteristics of the Santa Ynez River in Santa Barbara County, California, following the excessive rainfall in the winter of 1940–41; also, it contrasts these conditions of 1940–41 with earlier years of less rainfall. The data for this report were compiled in connection with an investigation of the water‐resources of Santa Barbara County which is being conducted by the United States Geological Survey in cooperation with the County of Santa Barbara.

California↗

Radium accumulation in carbonate river sediments at oil and gas produced water discharges: Implications for beneficial use as disposal management

In the western U.S., produced water from oil and gas wells discharged to surface water augments downstream supplies used for irrigation and livestock watering. Here we investigate six permitted discharges on three neighboring tributary systems in Wyoming. During 2013-16, we evaluated radium activities of the permitted discharges and the potential for radium accumulation in associated stream sediments. Radium activities of the sediments at the points of discharge ranged from approximately 200-3600 Bq/kg with elevated activities above the background of 74 Bq/kg over 30 km downstream of one permitted discharge. Sediment as deep as 30 cm near the point of discharge had radium activities elevated above background. X-ray diffraction and targeted sequential extraction of radium in sediments indicate that radium is likely coprecipitated with carbonate, and to a lesser extent sulfate minerals. PHREEQC modeling predicts radium coprecipitation with aragonite and barite, but over-estimates the latter compared to observations of downstream sediment, where carbonate predominates. Mass-balance calculations indicate over 3 billion Bq of radium activity (226Ra+228Ra) is discharged each year from five of the discharges, combined, with only 5 percent of the annual load retained in stream sediments within 100m of the effluent discharges; the remaining 95 percent of the radium is transported farther downstream as sediment-associated and aqueous species

Environmental Science↗

Survey of intersex largemouth bass from impoundments in Georgia USA

Intersex fish are increasingly being reported worldwide, primarily in rivers that receive treated wastewater, but few studies have investigated intersex in waters that do not receive wastewater. In a recent reconnaissance survey of intersex fish in North America, a high rate of intersex was reported for Largemouth Bass Micropterus salmoides in some southeastern U.S. rivers; however, the occurrence of intersex in impoundments has not been well described, especially on a statewide scale. Therefore, our objective for this project was to survey the occurrence of intersex Largemouth Bass in a variety of impoundment habitats across Georgia. Largemouth Bass were collected from 11 impoundments without direct municipal or agricultural wastewater inputs. Gonads from all male Largemouth Bass were evaluated for the incidence and severity of the intersex condition based on presence and arrangement of testicular oocytes. Overall 48% of male Largemouth Bass collected from impoundments were intersex, which was found in 9 of the 11 impoundments. Among impoundments, incidence of intersex ranged from 0 to 82% of the males sampled and surface area of the impoundment was a significant predictor of intersex incidence. Intersex fish were smaller than normal males, but population-level effects of intersex and causative factors of endocrine disruption in the impoundments remain unknown. The high incidence of intersex males in small impoundments demonstrates that the condition is not confined to rivers and suggests that factors other than those previously associated with intersex (i.e., municipal wastewater) may be involved.

Georgia↗

Trophic pathways supporting Arctic grayling in a small stream on the Arctic Coastal Plain, Alaska

Beaded streams are prominent across the Arctic Coastal Plain (ACP) of Alaska, yet prey flow and food web dynamics supporting fish inhabiting these streams are poorly understood. Arctic grayling ( Thymallus arcticus ) are a widely distributed upper-level consumer on the ACP and migrate into beaded streams to forage during the short 3-month open-water season. We investigated energy pathways and key prey resources that support grayling in a representative beaded stream, Crea Creek. We measured terrestrial invertebrates entering the stream from predominant riparian vegetation types, prey types supporting a range of fish size classes, and how riparian plants and fish size influenced foraging habits. We found that riparian plants influenced the quantity of terrestrial invertebrates entering Crea Creek; however, these differences were not reflected in fish diets. Prey type and size ingested varied with grayling size and season. Small grayling (<15 cm fork length (FL)) consumed mostly aquatic invertebrates early in the summer, and terrestrial invertebrates later in summer, while larger fish (>15 cm FL) foraged most heavily on ninespine stickleback ( Pungitius pungitius ) throughout the summer, indicating that grayling can be insectivorous and piscivorous, depending on size. These findings underscore the potential importance of small streams in Arctic ecosystems as key summer foraging habitats for fish. Understanding trophic pathways supporting stream fishes in these systems will help interpret whether and how petroleum development and climate change may affect energy flow and stream productivity, terrestrial–aquatic linkages and fishes in Arctic ecosystems.

Alaska↗

Micromorphology and stable-isotope geochemistry of historical pedogenic siderite formed in PAH-contaminated alluvial clay soils, Tennessee, U.S.A

Alluvial clay soil samples from six boreholes advanced to depths of 400-450 cm (top of limestone bedrock) from the Chattanooga Coke Plant (CCP) site were examined micromorphologically and geochemically in order to determine if pedogenic siderite (FeCO3) was present and whether siderite occurrence was related to organic contaminant distribution. Samples from shallow depths were generally more heavily contaminated with polycyclic aromatic hydrocarbons (PAHs) than those at greater depth. The upper 1 m in most boreholes consisted of mixtures of anthropogenically remolded clay soil fill containing coal clinker, cinder grains, and limestone gravel; most layers of coarse fill were impregnated with creosote and coal tar. Most undisturbed soil (below 1 m depth) consisted of highly structured clays exhibiting fine subangular blocky ped structures, as well as redox-related features. Pedogenic siderite was abundant in the upper 2 m of most cores and in demonstrably historical (< 100 years old) soil matrices. Two morphologies were identified: (1) sphaerosiderite crystal spherulites ranging from 10 to 200 um in diameter, and (2) coccoid siderite comprising grape-like "clusters" of crystals 5-20 ??n in diameter. The siderite, formed in both macropores and within fine-grained clay matrices, indicates development of localized anaerobic, low-Eh conditions, possibly due to microbial degradation of organic contaminants. Stable-isotope compositions of the siderite have ??13C values spanning over 25%o (+7 to - 18%o VPDB) indicating fractionation of DIC by multiple microbial metabolic pathways, but with relatively constant ??18O values from (-4.8 ?? 0.66%o VPDB) defining a meteoric sphaerosiderite line (MSL). Calculated isotope equilibrium water ??18O values from pedogenic siderites at the CCP site are from 1 to 5 per mil lighter than the groundwater ??18O values that we estimate for the site. If confirmed by field studies in progress, this observation might call for a reevaluation of low-temperature siderite-water 18O fractionations. Investigations at the CCP site thus provide valuable information on the geochemical conditions under which siderite can form in modern soils, and thus insight on controls on siderite formation in ancient soils. Copyright ?? 2010, SEPM (Society for Sedimentary Geology).

Journal of Sedimentary Research↗

National Water Quality Assessment Program; the Santee Basin and coastal drainage, North Carolina and South Carolina

In 1991, the U.S. Geological Survey (USGS), U.S. Department of the Interior, began a National Water-Quality Assessment Program (NAWQA). The long-term goals of NAWQA are to describe the status of and trends in the quality of a large representative part of the Nation's surface- and ground-water resources and to identify all the major factors that affect the quality of these resources. In addressing these goals, NAWQA produces water-quality information that is useful to policymakers and managers at State, Federal, and local levels. NAWQA emphasis is on regional scale water-quality problems. The program does not diminish the need for smaller scale studies and monitoring designed and conducted by State, Federal, and local agencies. NAWQA, however, provides a large-scale framework for conducting many of these activities and an understanding about regional and national water-quality conditions that cannot be acquired from these other programs and studies. Studies of 60 hydrologic systems that include parts of most major river basins and aquifer systems are the building blocks of the national assessment. The areas of the 60 study units range in size from 1,000 to more than 60,000 square miles (mi 2 ) and represent 60 to 70 percent of the Nation's water use and population served by public water supplies. Twenty investigations were begun in 1991, 20 investigations began in 1994, and 20 are planned to begin in 1997. The assessment activities in the Santee River Basin and Coastal Drainage began in 1994.

North Carolina, South Carolina↗

Results From a Microbial Source-Tracking Study at Villa Angela Beach, Cleveland, Ohio, 2007

During the 2007 recreational season at Villa Angela Beach in Cleveland, Ohio, scientists with the U.S. Geological Survey (USGS) and the Northeast Ohio Regional Sewer District (NEORSD) found high Escherichia coli (E. coli) concentrations that were not easily explained by results obtained to date in ongoing investigations of recreational water quality at the beach. To help understand the sources behind these elevated E. coli concentrations, the USGS and NEORSD sampled beach-area water for Bacteroides DNA markers. Bacteroides are a group of enteric bacteria that are being used in microbial source tracking, in hope that host-associated DNA markers could be used to indicate potential sources of E. coli in the Villa Angela environment. The USGS Ohio Water Microbiology Laboratory analyzed a total of 13 source samples (sewage and waterfowl feces) and 33 beach-area water and sand samples for three Bacteroides DNA markers. This report lists the results of those analyses, along with environmental conditions at Villa Angela on the dates that samples were collected.

Open-File Report↗

New Mexico district work-effort analysis computer program

The computer program (CAN 2) described in this report is one of several related programs used in the New Mexico District cost-analysis system. The work-effort information used in these programs is accumulated and entered to the nearest hour on forms completed by each employee. Tabulating cards are punched directly from these forms after visual examinations for errors are made. Reports containing detailed work-effort data itemized by employee within each project and account and by account and project for each employee are prepared for both current-month and year-to-date periods by the CAN 2 computer program. An option allowing preparation of reports for a specified 3-month period is provided. The total number of hours worked on each account and project and a grand total of hours worked in the New Mexico District is computed and presented in a summary report for each period. Work effort not chargeable directly to individual projects or accounts is considered as overhead and can be apportioned to the individual accounts and projects on the basis of the ratio of the total hours of work effort for the individual accounts or projects to the total New Mexico District work effort at the option of the user. The hours of work performed by a particular section, such as General Investigations or Surface Water, are prorated and charged to the projects or accounts within the particular section. A number of surveillance or buffer accounts are employed to account for the hours worked on special events or on those parts of large projects or accounts that require a more detailed analysis. Any part of the New Mexico District operation can be separated and analyzed in detail by establishing an appropriate buffer account. With the exception of statements associated with word size, the computer program is written in FORTRAN IV in a relatively low and standard language level to facilitate its use on different digital computers. The program has been run only on a Control Data Corporation 6600 computer system. Central processing computer time has seldom exceeded 5 minutes on the longest year-to-date runs.

Open-File Report↗

Basin characteristics, history of stream gaging, and statistical summary of selected streamflow records for the Rapid Creek basin, western South Dakota

The report presents a summary of basin characteristics affecting streamflow, a history of the U.S. Geological Survey 's stream-gaging program, and a compilation of discharge records and statistical summaries for selected sites within the Rapid Creek basin. It is the first in a series which will investigate surface-water/groundwater relations along Rapid Creek. The summary of basin characteristics includes descriptions of the geology and hydrogeology, physiography and climate, land use and vegetation, reservoirs, and water use within the basin. A recounting of the U.S. Geological Survey 's stream-gaging program and a tabulation of historic stream-gaging stations within the basin are furnished. A compilation of monthly and annual mean discharge values for nine currently operated, long-term, continuous-record, streamflow-gaging stations on Rapid Creek is presented. The statistical summary for each site includes summary statistics on monthly and annual mean values, correlation matrix for monthly values, serial correlation for 1 year lag for monthly values, percentile rankings for monthly and annual mean values, low and high value tables, duration curves, and peak-discharge tables. Records of monthend contents for two reservoirs within the basin also are presented. (USGS)

Open-File Report↗

Geohydrology and potential for upward movement of saline water in the Cocoa well field, East Orange County, Florida

The Floridan aquifer system, an approximately 2,000-foot thick sequence of Eocene-age limestone and dolomite, is the main source of water supply in central Florida. Hydraulic conductivity is different in strata of different lithology and is the basis for separating the aquifer system into the Upper Floridan aquifer, a middle semi-confining unit, and the Lower Floridan aquifer. The coastal city of Cocoa withdraws about 26 million gallons of water per day from the Upper Floridan aquifer from a well field in east Orange County, about 25 miles inland. About 60 million gallons per day are withdrawn from the Upper Floridan aquifer and 56 million gallons per day from the Lower Floridan aquifer in the Orlando area, about 15 miles west of the Cocoa well field. Wells drilled in the Cocoa well field from 1955-61 yielded water with chloride concentrations ranging from 25-55 milligrams per liter. Soon after the wells were put in service, chloride concentrations increased; therefore, new wells were drilled further inland. Chloride concentrations in water from many of the new wells also have increased. Possible sources of saline water are lateral movement of relict seawater in the Upper Floridan aquifer from the east, regional upconing of saline water from the Lower Floridan aquifer or underlying older rocks, or localized upward movement of saline water through fractures. Several test wells were drilled to provide information about chloride concentration changes with depth and to monitor changes with time, including a multi-zone well drilled in 1965 (well C) and two wells drilled in the 1990's (wells R and S). Chloride concentrations have increased in the zone pumped by the supply wells (the upper 500 feet of the aquifer) and in the 1,351 to 1,357-foot deep zone of well C, but not in the two intervening zones. This indicates that the source of saline water is located laterally, rather than vertically, from the pumped zone in the area of well C. The potential for upward movement of saline water depends on the direction of the vertical hydraulic gradient and on the vertical hydraulic conductivity of the aquifer. A series of aquifer tests was run in 1993-94 and existing water-level and water-quality data were analyzed to evaluate the potential for upward movement of saline water in the well field. The transmissivity of the upper 500 feet of the aquifer is about 100,000 feet squared per day (the horizontal hydraulic conductivity is about 200 feet per day) and the storage coefficient is about 2x10-4. Horizontal hydraulic conductivities determined from slug tests of the three deepest zones of well C ranged from 20-50 feet per day. Vertical hydraulic conductivities probably do not exceed 0.05 feet per day. The vertical hydraulic gradient is determined by comparing water levels in the various zones, but because of density differences, unadjusted water levels in the deepest zone investigated cannot be directly compared to water levels in the overlying freshwater zones. The difference between environmental-water heads (adjusted for density differences) in the saline-water zone of well C and the overlying freshwater zone were calculated from measured water levels for the period 1966 to 1994. During most of this time period, the gradient was downward, indicating that saline water did not move upward. Upconing of saline water probably is not taking place in the center and western part of the well field, based on the low vertical hydraulic conductivity values estimated for the middle semi-confining unit, the generally downward vertical hydraulic gradient, and the constant chloride concentrations in the intermediate zones of well C. However, there is no information about the extent of the zone of low vertical hydraulic conductivity or about the direction of the vertical hydraulic gradient in the eastern part of the well field. Thus, increased chloride concentrations in supply wells in the eastern part of the well field could be caused either by lateral movement of saline water from the east, or by upward movement from the Lower Floridan aquifer if the low conductivity zone is thin or breached by fractures, or by a combination of both lateral and vertical movement.

Florida↗

Report of hydrologic investigations in the Three Sisters area of central Oregon, Summer 2001

An ongoing episode of crustal uplift centered in the Separation Creek drainage of the Three Sisters area, central Oregon Cascades, may result from a magmatic intrusion that began in 1998. An investigation of springs in this drainage in summer 2001 revealed slightly elevated water temperatures and chloride (Cl-) concentrations of up to about 5?C and 20 milligrams per liter (mg/L), respectively, above background. The total discharge of anomalous Cl- in Separation Creek was 9.2 grams per second, which in combination with the temperature-Cl- relation in the springs results in a total advective heat discharge of 16 MW (megawatts). Comparison with similar findings obtained a decade earlier suggests that total Cl- and heat discharges in the groundwater drainage are unaffected by the current uplift. However, the isotopic composition of the dissolved inorganic carbon (DIC) in the spring waters (delta carbon-13 (13C) = -9.03 to -11.6?; carbon-14 (14C) <25 pmC) combined with helium-3/helium-4 (3He/4He) ratios near 8 RA and C/3He ratios <1010 in two of the springs are indicative of a magmatic source. The high 3He/4He ratios indicate that the magmatic gas is derived from a relatively recent, if not ongoing, intrusion. The concentration of magmatic carbon is low, a few millimoles per liter (mmol/L) at most, with an average value of 1.53 mmol/L for all the springs sampled in the drainage. Combining this average with the late-summer water flow in Separation Creek suggests a discharge of 21 tonnes/day of magmatic carbon dioxide (CO2). The presence of magmatic carbon in the shallow groundwater system, and the fact that DIC is uncorrelated with Cl-, suggests that some magmatic gas could escape diffusely through the soils.

Water-Resources Investigations Report↗

Effects of agricultural best-management practices on the Brush Run Creek headwaters, Adams County, Pennsylvania, prior to and during nutrient management

The U.S. Geological Survey, in cooperation with the Susquehanna River Basin Commission and the Pennsylvania Department of Environmental Resources, investigated the effects of agricultural best-management practices on surface-water quality as part of the U.S. Environmental Protection Agency's Chesapeake Bay Program. This report characterizes a 0.63-square- mile agricultural watershed underlain by shale, mudstone, and red arkosic sandstone in the Lower Susquehanna River Basin. The water quality of the Brush Run Creek site was studied from October 1985 through September 1991, prior to and during the implementation of nutrient management designed to reduce sediment and nutrient discharges into Conewago Creek, a tributary to the Chesapeake Bay. The original study area was 0.38 square mile and included an area immediately upstream from a manure lagoon. The study area was increased to 0.63 square mile in the fall of 1987 after an extensive tile-drain network was discovered upstream and downstream from the established streamflow gage, and the farm owner made plans to spray irrigate manure to the downstream fields. Land use for about 64 percent of the 0.63 square mile watershed is cropland, 14 percent is pasture, 7 percent is forest, and the remaining 15 percent is yards, buildings, water, or gardens. About 73 percent of the cropland was used to produce corn during the study. The average annual animal population consisted of 57,000 chickens, 1,530 hogs, and 15 sheep during the study. About 59,340 pounds of nitrogen and 13,710 pounds of phosphorus were applied as manure and commercial fertilizer to fields within the subbasin during the 3-year period prior to implementation of nutrient management. During nutrient management, about 14 percent less nitrogen and 57 percent less phosphorus were applied as commercial and manure fertilizer. Precipitation totaled 209 inches, or 13 percent less than the long-term normal, during the 6-year study. Concentrations of total ammonia in precipitation were as high as 2.7 mg/L (milligrams per liter); in dry deposition the concentrations were as high as 5.4 mg/L, probably because of the ammonia that had volatilized from the manure-storage lagoon. Nitrate nitrogen in the upper 4 feet of the soil ranged from 17 to 452 pounds per acre and soluble phosphorus content ranged from 0.29 to 65 pounds per acre. The maximum concentration of total nitrogen was 2,400 mg/L on September 10, 1986, in discharge from the tile drain near the streamflow gage. Median concentrations of total nitrogen and dissolved nitrite plus nitrate in base flow at the water-quality gage were 14 mg/L and 4.4 mg/L, respectively; prior to nutrient management and during nutrient management, median concentrations were 14 mg/L and 6.2 mg/L, respectively. Significant reductions in total phosphorus and suspended-sediment concentrations occurred at the water-quality gage. The maximum concentrations of total phosphorus (160 mg/L) and suspended sediment (3,530 mg/L) were measured at a tile line above the water-quality gage. Concentrations of total nitrogen, dissolved ammonia, and total phosphorus in base flow increased during dry periods when discharges from the tile drain were not diluted. During nutrient management, only base-flow loads of suspended sediment increased. Total streamflow was about 121.8 inches. About 81 percent was storm runoff. Loads of total nitrogen, total phosphorus in stormflow, and suspended sediment increased 14, 44, and 41 percent during nutrient management, respectively. A load of about 787,780 pounds of sediment, 22,418 pounds of nitrogen, and 5,479 pounds of phosphorus was measured during 214 sampled stormflow days that represented 84 percent of the stormflow. About 812,924 pounds of sediment, 38,421 pounds of nitrogen, and 6,377 pounds of phosphorus were discharged during the 6-year study.

Pennsylvania↗