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USGS2016

Surface-air mercury fluxes across Western North America: A synthesis of spatial trends and controlling variables

Mercury (Hg) emission and deposition can occur to and from soils, and are an important component of the global atmospheric Hg budget. This paper focuses on synthesizing existing surface-air Hg flux data collected throughout the Western North American region and is part of a series of geographically focused Hg synthesis projects. A database of existing Hg flux data collected using the dynamic flux chamber (DFC) approach from almost a thousand locations was created for the Western North America region. Statistical analysis was performed on the data to identify the important variables controlling Hg fluxes and to allow spatiotemporal scaling. The results indicated that most of the variability in soil-air Hg fluxes could be explained by variations in soil-Hg concentrations, solar radiation, and soil moisture. This analysis also identified that variations in DFC methodological approaches were detectable among the field studies, with the chamber material and sampling flushing flow rate influencing the magnitude of calculated emissions. The spatiotemporal scaling of soil-air Hg fluxes identified that the largest emissions occurred from irrigated agricultural landscapes in California. Vegetation was shown to have a large impact on surface-air Hg fluxes due to both a reduction in solar radiation reaching the soil as well as from direct uptake of Hg in foliage. Despite high soil Hg emissions from some forested and other heavily vegetated regions, the net ecosystem flux (soil flux + vegetation uptake) was low. Conversely, sparsely vegetated regions showed larger net ecosystem emissions, which were similar in magnitude to atmospheric Hg deposition (except for the Mediterranean California region where soil emissions were higher). The net ecosystem flux results highlight the important role of landscape characteristics in effecting the balance between Hg sequestration and (re-)emission to the atmosphere.

Science of the Total Environment↗

USGS2000

Preliminary report on the 16 October 1999 M 7.1 Hector mine, California, earthquake

The M w 7.1 Hector Mine, California, earthquake occurred at 9:46 GMT on 16 October 1999. The event caused minimal damage because it was located in a remote, sparsely populated part of the Mojave Desert, approximately 47 miles east-southeast of Barstow, with epicentral coordinates 34.59°N 116.27°W and a hypocentral depth of 5 ± 3 km. Twelve foreshocks, M 1.9-3.8, preceded the mainshock during the previous twelve hours. All of these events were located close to the hypocenter of the mainshock. The Hector Mine earthquake occurred within the Eastern California Shear Zone (ECSZ). By virtue of its remote location, the societal impact of the Hector Mine earthquake was, fortunately, minimal in spite of the event's appreciable size. The ECSZ is characterized by high seismicity, a high tectonic strain rate, and a broad, distributed zone of north-northwest-trending faults (ECSZ; Figure 1 ; Dokka and Travis, 1990 ; Sauber et al., 1986 ; Sauber et al., 1994 ; Sieh et al., 1993 ). Data regarding the slip rates of faults within the ECSZ suggest that on the order of 15% of the Pacific-North American plate motion occurs along this zone ( Sauber et al., 1986 ; Wesnousky, 1986 ). Most of the faults in the ECSZ have low slip rates and long repeat times for major earthquakes, on the order of several thousands to tens of thousands of years. The occurrence of the Hector Mine earthquake within seven years and only about 30 km east of the 1992 M w 7.3 Landers earthquake suggests that the closely spaced surface faults in the ECSZ are mechanically related. The Hector Mine event involved rupture on two previously mapped fault zones—the Bullion Fault and an unnamed, more northerly-trending fault that is informally referred to in this paper as the Lavic Lake Fault (Dibblee, 1966 , 1967a , b ). Traces of the Bullion Fault exhibit evidence of Holocene displacement and were zoned as active in 1988 under California's Mquist-Priolo Earthquake Fault Zoning Act ( Hart and Bryant, 1997 ). The pattern of rupture along more than one named fault was also observed from the 1992 Landers earthquake ( Hauksson et al., 1993 ; Sieh et al., 1994). Much of the fault zone that produced the Hector Mine earthquake had been buried by relatively young stream deposits, and the fault scarps in bedrock have a subdued morphology. It appears that these faults have not experienced significant offset for perhaps 10,000 years or more ( Hart, 1987 ). Planned future investigations will refine the age of the last event on these faults. The portion of the Lavic Lake Fault that ruptured between the northern end of the Bullion Mountains and Lavic Lake had not previously been mapped. However, our field investigations have identified ancient, subdued fault scarps along portions of the 1999 rupture zone in this area. It thus appears that the entire segment of the Lavic Lake Fault that was involved in the 1999 event had ruptured in the past. As is typical for most faults within the Eastern California Shear Zone, the rate of movement along the Lavic Lake Fault may be quite slow (<1 mm/yr) and should produce earthquakes only infrequently. This event is a reminder that faults that have ruptured in late Quaternary time, but that lack evidence of Holocene displacement, can still produce earthquakes in this low-slip-rate tectonic setting. Additionally, the Hector Mine earthquake is noteworthy for a couple of other reasons. First, it clearly produced triggered seismicity over much of southern California, from the rupture zone toward the south-southwest in particular. Second, as we will discuss, the event may provide new data and insight into recently developed paradigms concerning earthquake interactions and the role of static stress changes. Questions such as these will, of course, be the subject of extensive detailed analyses in years to come. Fortunately, the Hector Mine sequence will provide one of the best data sets obtained to date for a significant earthquake in the United States. Because it occurred when major upgrades to both the regional seismic network (TriNet) and the regional geodetic network (SCIGN) were well underway, the Earth science community will have abundant high-quality data with which to explore the important and interesting questions that have been raised. In this paper, we present and discuss the basic data and preliminary results from the Hector Mine earthquake.

California↗

USGS2015

Modeling tidal freshwater marsh sustainability in the Sacramento-San Joaquin Delta under a broad suite of potential future scenarios

In this paper, we report on the adaptation and application of a one-dimensional marsh surface elevation model, the Wetland Accretion Rate Model of Ecosystem Resilience (WARMER), to explore the conditions that lead to sustainable tidal freshwater marshes in the Sacramento–San Joaquin Delta. We defined marsh accretion parameters to encapsulate the range of observed values over historic and modern time-scales based on measurements from four marshes in high and low energy fluvial environments as well as possible future trends in sediment supply and mean sea level. A sensitivity analysis of 450 simulations was conducted encompassing a range of eScholarship provides open access, scholarly publishing services to the University of California and delivers a dynamic research platform to scholars worldwide. porosity values, initial elevations, organic and inorganic matter accumulation rates, and sea-level rise rates. For the range of inputs considered, the magnitude of SLR over the next century was the primary driver of marsh surface elevation change. Sediment supply was the secondary control. More than 84% of the scenarios resulted in sustainable marshes with 88 cm of SLR by 2100, but only 32% and 11% of the scenarios resulted in surviving marshes when SLR was increased to 133 cm and 179 cm, respectively. Marshes situated in high-energy zones were marginally more resilient than those in low-energy zones because of their higher inorganic sediment supply. Overall, the results from this modeling exercise suggest that marshes at the upstream reaches of the Delta—where SLR may be attenuated—and high energy marshes along major channels with high inorganic sediment accumulation rates will be more resilient to global SLR in excess of 88 cm over the next century than their downstream and low-energy counterparts. However, considerable uncertainties exist in the projected rates of sea-level rise and sediment avail-ability. In addition, more research is needed to constrain future rates of aboveground and belowground plant productivity under increased CO<sub>2</sub> concentrations and flooding.

California↗

USGS2019

Using age tracers and decadal sampling to discern trends in nitrate, arsenic and uranium in groundwater beneath irrigated cropland

Repeat sampling and age tracers were used to examine trends in nitrate, arsenic and uranium concentrations in groundwater beneath irrigated cropland. Much higher nitrate concentrations in shallow modern groundwater were observed at both the Columbia Plateau and High Plains sites (median values of 10.2 and 15.4 mg/L as N, respectively) than in groundwater that recharged prior to the onset of intensive irrigation (median values of <1 and <4 mg/L as N, respectively). Repeat sampling of these well networks indicates that high nitrate concentrations in modern, shallow groundwater have been sustained for decades, posing a future risk to older, deeper groundwater used for drinking water. In fact, nitrate concentrations in older modern water (30-60 years since recharge) at the High Plains site have increased in the last decade. Groundwater irrigated areas in the Columbia Plateau tend to have higher nitrate concentrations than surface-water irrigated areas suggesting that repeated dissolution of land applied fertilizer during recirculation may be an important factor causing high nitrate concentrations in groundwater. Mobilization of uranium and arsenic by land surface activities is suggested by the higher concentrations of these constituents in modern, shallow groundwater than in older, deeper groundwater at the Columbia Plateau site. Bicarbonate concentrations in modern groundwater are positively correlated with uranium (r=0.72, p<0.01), suggesting bicarbonate may mobilize uranium in this system. A positive correlation between arsenic and phosphorus concentrations in modern groundwater (r=0.55, p<0.01) suggests that phosphate from fertilizer outcompetes arsenate for sorption sites, mobilizing sorbed arsenic derived from past pesticide use or other sources.

Environmental Science and Technology↗

USGS2020

Use of the smeltCam as an efficient fish sampling alternative within the San Francisco Estuary

Resource managers often rely on long-term monitoring surveys to detect trends in biological data. However, no survey gear is 100% efficient, and many sources of bias can be responsible for detecting or not detecting biological trends. The SmeltCam is an imaging apparatus developed as a potential sampling alternative to long-term trawling gear surveys within the San Francisco Estuary, California, to reduce handling stress on sensitive species like the Delta Smelt ( Hypomesus transpacificus ). Although believed to be a reliable alternative to closed cod-end trawling surveys, no formal test of sampling efficiency has been implemented using the SmeltCam. We used a paired deployment of the SmeltCam and a conventional closed cod-end trawl within the Napa River and San Pablo Bay, a Bayesian binomial N -mixture model, and data simulations to determine the sampling efficiency of both deployed gear types to capture a Delta Smelt surrogate (Northern Anchovy, Engraulis mordax ) and to test potential bias in our modeling framework. We found that retention efficiency—a component of detection efficiency that estimates the probability a fish is retained by the gear, conditional on gear contact—was slightly higher using the SmeltCam (mean = 0.58) than the conventional trawl (mean = 0.47, Probability SmeltCam retention efficiency > trawl retention efficiency = 94%). We also found turbidity did not affect the SmeltCam’s retention efficiency, although total fish density during an individual tow improved the trawl’s retention efficiency. Simulations also showed the binomial model was accurate when model assumptions were met. Collectively, our results suggest the SmeltCam to be a reliable alternative to sampling with conventional trawling gear, but future tests are needed to confirm whether the SmeltCam is as reliable when applied to taxa other than Northern Anchovy over a greater range of conditions.

California↗

USGS2022

Decadal trends of mercury cycling and bioaccumulation within Everglades National Park

Mercury (Hg) contamination has been a persistent concern in the Florida Everglades for over three decades due to elevated atmospheric deposition and the system's propensity for methylation and rapid bioaccumulation. Given declines in atmospheric Hg concentrations in the conterminous United States and efforts to mitigate nutrient release to the greater Everglades ecosystem, it was vital to assess how Hg dynamics responded on temporal and spatial scales. This study used a multimedia approach (water and biota) to examine Hg and methylmercury (MeHg) dynamics across a 76-site network within the southernmost portion of the region, Everglades National Park (ENP), from 2008 to 2018. Atmospheric Hg deposition was evaluated over time using a long-term monitoring station. Hg concentrations across matrices showed that air, water, and biota from the system were inextricably linked. Temporal patterns across matrices were driven primarily by hydrologic and climatic changes in the park and no evidence of a decline in atmospheric Hg deposition from 2008 to 2018 was observed, unlike other regions of the United States. In the Shark River Slough (SRS), excess dissolved organic carbon and sulfate were also consistently delivered from upgradient canals and showed no evidence of decline over the study period. Within the SRS a strong positive correlation was observed between MeHg concentrations in surface water and resident fish. Within distinct geographic regions of ENP (SRS, Marsh, Coastal), the geochemical controls on MeHg dynamics differed and highlighted regions susceptible to higher MeHg bioaccumulation, particularly in the SRS and Coastal regions. This study demonstrates the strong influence that dissolved organic carbon and sulfate loads have on spatial and temporal distributions of MeHg across the ENP. Importantly, improved water quality and flow rates are two key restoration targets of the nearly 30-year Everglades restoration program, which if achieved, this study suggests would lead to reduced MeHg production and exposure.

Florida↗

USGS2001

Trends in long-period seismicity related to magmatic fluid compositions

Sound speeds and densities are calculated for three different types of fluids: gas-gas mixture; ash-gas mixture; and bubbly liquid. These fluid properties are used to calculate the impedance contrast (Z) and crack stiffness (C) in the fluid-driven crack model (Chouet: J. Geophys. Res., 91 (1986) 13,967; 101 (1988) 4375; A seismic model for the source of long-period events and harmonic tremor. In: Gasparini, P., Scarpa, R., Aki, K. (Eds.), Volcanic Seismology, IAVCEI Proceedings in Volcanology, Springer, Berlin, 3133). The fluid-driven crack model describes the far-field spectra of long-period (LP) events as modes of resonance of the crack. Results from our calculations demonstrate that ash-laden gas mixtures have fluid to solid density ratios comparable to, and fluid to solid velocity ratios lower than bubbly liquids (gas-volume fractions <10%). This difference results in synthetic far-field spectra with higher impedance contrasts and narrower spectral bandwidths for ash-laden gas mixture than spectra for bubbly liquids. Spectral characteristics are described in terms of the quality factor Q-1. Q-1 is measured by the ratio of the frequency of the dominant spectral peak to the bandwidth of the peak measured at one half of its amplitude. This factor expresses the losses of energy due to elastic radiation Q-1r and other dissipative mechanisms Q-1i at the source, Q-1 = Q-1r + Q-1i. Spectra for LP events recorded at active volcanoes such as Galeras in Colombia and Kilauea in Hawaii, have Q-1 factors in the range of 0.1-0.002. The Q-1r factors due to radiation loss calculated for a sphere filled with a H2O-CO2 or H2O-SO2 gas mixture, vary between 0.0015 and 0.0040 with a change in wt% H2O at 800-1600 K and 10-50 MPa. For gas-rich mixtures, Q-1r has a strong dependence on resonator geometry (spherical versus rectangular). The spectra from a resonating sphere filled with gas-rich mixture yields values of Q-1r an order of magnitude smaller than those from a rectangular crack. For a resonating crack filled with an ash-gas mixture (or pseudogas), Q-1r varies parabolically from ???0.006 for an ash-rich mixture, to 0.0015 or 0.0023 for a H2O-rich or CO2-rich mixture at 800 K and 25 MPa. For low (<20%) gas-volume fraction fluids (foams, bubbly fluids and ash-rich pseudogases), the magnitudes for Q-1r are independent of crack geometry. Spectra associated with a foam (gas-volume fractions 10-90%) or bubbly basalt (gas-volume fractions <10%) may have a dominant spectral peak with values of Q-1r on the order of 0.01 and 0.1, respectively. The spectra from a resonating sphere filled with a foam containing >20% gas-volume fraction yields values of Q-1r similar to those for a rectangular crack. As with gas-gas and ash-gas mixtures, an increase in mass fraction narrows the bandwidth of the dominant mode and shifts the spectra to lower frequencies. Including energy losses due to dissipative processes in a bubbly liquid increases attenuation. Attenuation may also be higher in ash-gas mixtures and foams if the effects of momentum and mass transfer between the phases were considered in the calculations. ?? 2001 Elsevier Science B. V. All rights reserved.

Journal of Volcanology and Geothermal Research↗

USGS2015

Total- and methyl-mercury concentrations and methylation rates across the freshwater to hypersaline continuum of the Great Salt Lake, Utah, USA

We examined mercury (Hg) speciation in water and sediment of the Great Salt Lake and surrounding wetlands, a locale spanning fresh to hypersaline and oxic to anoxic conditions, in order to test the hypothesis that spatial and temporal variations in Hg concentration and methylation rates correspond to observed spatial and temporal trends in Hg burdens previously reported in biota. Water column, sediment, and pore water concentrations of methylmercury (MeHg) and total mercury (THg), as well as related aquatic chemical parameters were examined. Inorganic Hg(II)-methylation rates were determined in selected water column and sediment subsamples spiked with inorganic divalent mercury ( 204 Hg(II)). Net production of Me 204 Hg was expressed as apparent first-order rate constants for methylation ( k meth ), which were also expanded to MeHg production potential (MPP) rates via combination with tin reducible ‘reactive’ Hg(II) (Hg(II) R ) as a proxy for bioavailable Hg(II). Notable findings include: 1) elevated Hg concentrations previously reported in birds and brine flies were spatially proximal to the measured highest MeHg concentrations, the latter occurring in the anoxic deep brine layer (DBL) of the Great Salt Lake; 2) timing of reduced Hg(II)-methylation rates in the DBL (according to both k meth and MPP) coincides with reduced Hg burdens among aquatic invertebrates (brine shrimp and brine flies) that act as potential vectors of Hg propagation to the terrestrial ecosystem; 3) values of k meth were found to fall within the range reported by other studies; and 4) MPP rates were on the lower end of the range reported in methodologically comparable studies, suggesting the possibility that elevated MeHg in the anoxic deep brine layer results from its accumulation and persistence in this quasi-isolated environment, due to the absence of light (restricting abiotic photo demethylation) and/or minimal microbiological demethylation.

Utah↗

USGS1976

Tectonic aspects of the Guatemala earthquake of 4 February 1976

The locations of surface ruptures and the main shock epicenter indicate that the disastrous Guatemala earthquake of 4 February 1976 was tectonic in origin and generated mainly by slip on the Motagua fault, which has an arcuate roughly east-west trend across central Guatemala. Fault breakage was observed for 230 km. Displacement is predominantly horizontal and sinistral with a maximum measured offset of 340 cm and an average of about 100 cm. Secondary fault breaks trending roughly north-northeast to south-southwest have been found in a zone about 20 km long and 8 km wide extending from the western suburbs of Guatemala City to near Mixco, and similar faults with more subtle surface expression probably occur elsewhere in the Guatemalan Highlands. Displacements on the secondary faults are predominantly extensional and dip-slip, with as much as 15 cm vertical offset on a single fracture. The primary fault that broke during the earthquake involved roughly 10 percent of the length of the great transform fault system that defines the boundary between the Caribbean and North American plates. The observed sinistral displacement is striking confirmation of deductions regarding the late Cenozoic relative motion between these two crustal plates that were based largely on indirect geologic and geophysical evidence. The earthquake-related secondary faulting, together with the complex pattern of geologically young normal faults that occur in the Guatemalan Highlands and elsewhere in western Central America, suggest that the eastern wedge-shaped part of the Caribbean plate, roughly between the Motagua fault system and the volcanic arc, is being pulled apart in tension and left behind as the main mass of the plate moves relatively eastward. Because of their proximity to areas of high population density, shallow-focus earthquakes that originate on the Motagua fault system, on the system of predominantly extensional faults within the western part of the Caribbean plate, and in association with volcanism may pose a more serious seismic hazard than the more numerous (but generally more distant) earthquakes that are generated in the eastward-dipping subduction zone beneath Middle America.

Science↗

USGS2022

Contrasting Common Era climate and hydrology sensitivities from paired lake sediment dinosterol hydrogen isotope records in the South Pacific Convergence Zone

Hydroclimate on ‘Uvea (Wallis et Futuna) is controlled by rainfall associated with the South Pacific Convergence Zone (SPCZ), the southern hemisphere's largest precipitation feature. To extend the short observational precipitation record, the hydrogen isotopic composition of the algal lipid biomarker dinosterol (δ 2 H dinosterol ) was measured in sediment cores from two volcanic crater lakes on ‘Uvea. The modern lakes differ morphologically and chemically but both contain freshwater within the photic zone, support phytoplankton communities inclusive of dinosterol-producing dinoflagellates, and experience identical climate conditions. δ 2 H dinosterol values track lake water isotope ratios, ultimately controlled in the tropics by precipitation amount and evaporative enrichment. However, in 88-m-deep Lac Lalolalo a steadily decreasing trend in sedimentary δ 2 H dinosterol values from −227‰ around year 988 CE to modern values as low as −303‰, suggests this lake's evolution from an active volcanic setting to the present system strongly influenced δ 2 H dinosterol values. Although current hydrology and water isotope systematics may now reflect precipitation and evaporation in this lake, the interaction between these processes and large changes in basin morphology, geochemistry, and hydrology obstruct the recovery of a climate signal from Lac Lalolalo's sedimentary δ 2 H dinosterol records. This work emphasizes the importance of site replication and the use of complementary climate reconstruction tools, especially when using molecular proxies that may be sensitive to more than one environmental parameter. Contrary to its neighbor, duplicate δ 2 H dinosterol records from 23-m-deep Lac Lanutavake varied between −277‰ and −297‰ and indicate slightly drier conditions during the time-period known as the Medieval Climate Anomaly (MCA, 950–1250 CE). The δ 2 H dinosterol signal in Lac Lanutavake was muted compared to published records from ‘Upolu (Samoa) and Efate (Vanuatu) indicating that ‘Uvea's location is not as sensitive to precipitation variability at sites farther from the SPCZ central axis. Lithogenic runoff proxies combined with δ 2 H dinosterol support the interpretation of a relatively dry MCA on ‘Uvea, ‘Upolu, and Efate, potentially due to less intense precipitation, a contracted, or a more zonally oriented SPCZ.

Efate Island, Lac Lalolalo, Lac Lanoto'o, Lac Lanu↗

USGS2025

U.S. national park units as breeding bird habitat: A comparison of species prevalence and land cover across the midwestern and central United States

The value of national parks as bird habitat depends not only on local conditions within the parks, but also on the landscape habitat matrices in which they are located. However, the influences of local and landscape habitat matrices on birds vary by species and have not been quantified. Similarly, the trends of land cover types through time have not been systematically quantified for Midwest Region national parks and the landscapes around them, despite evidence of ongoing habitat loss exacerbated by climate change and human population growth. Managers and policy makers can use this information to understand and sustain the contribution of parks to our Nation’s avifauna. We developed models using North American Breeding Bird Survey (BBS) data collected on routes from across the central United States. The models were used to predict occupancy of bird species of concern in 32 national park units across nine Bird Conservation Regions in the Midwest based on land cover in and around those parks. We then compared these predictions with data collected through National Park Service (NPS) bird surveys at each park to determine if bird species of concern were more or less prevalent than expected. In each park, the mean difference between observed species detections and mean predicted detections indicates that most species are less frequently detected in the parks than predicted. However, when the range of uncertainty of predictions is considered, only 21% of park-bird combinations showed strong evidence (95%) of differing from expectation. Of these, species were less common than expected in the park in all but two cases. These results indicate that some bird species of concern occupy sites in Midwest Region national park units at a rate roughly comparable to sites with similar land cover in the Bird Conservation Region (BCR) in which they occur. However, for one in five species-park combinations, parks appear to be less occupied than comparable sites elsewhere.

Midwest region↗

USGS2023

Estimating population viability of the northern Great Plains piping plover population considering updated population structure, climate change, and intensive management

One challenge in wildlife conservation is understanding how various threats and management actions may influence long-term population viability. This is particularly evident when there is considerable uncertainty regarding population structure and vital rates. Reassessment of current knowledge and population trends is necessary for listed species to improve management actions that benefit conservation. We present an updated population viability analysis for northern Great Plains piping plovers ( Charadrius melodus circumcinctus ) based on the latest scientific data on survival, fecundity, and connectivity. Further, we explore the consequences of potential management actions and the stochastic effects of global climate change on population viability through changes in survival and fecundity. Our results predict elevated risks of extinction after 50 years (0.088 – 0.373) compared to previous predictions (0.033) based on assumed conditions of low connectivity among four major breeding groups structured as a metapopulation. We explored eight scenarios based on empirically-derived, higher connectivity rates and found that the northern Great Plains population never had a mean predicted population growth rate greater than one (0.946 – 0.996). Two scenarios that simulated a reduction in adult survival showed higher extinction probabilities (0.267 – 0.373), whereas two other scenarios that simulated an increase in fecundity exhibited lower extinction probabilities (0.088 – 0.103). These results indicate that viability of the northern Great Plains population of piping plovers could be improved with management actions that increase fecundity as long as adult survival is not simultaneously reduced. Lastly, breeding groups appeared to function less independently when connectivity rates were higher, as the breeding population was divided evenly among breeding groups. This indicates that the presumed metapopulation structure of our study system may need to be re-evaluated, and that empirically-based estimates of connectivity are essential to assessing population viability of mobile species that exhibit a spatially structured distribution.

Frontiers in Bird Science↗

USGS2019

Seasonal use of a nonnatal marine basin by juvenile hatchery chinook salmon

Information on the movement patterns of fishes is essential for managers that are making critical resource decisions. We examined the frequency of a keystone species, Chinook Salmon Oncorhynchus tshawytscha that migrated from different marine basins to the Nisqually River estuary, which lies within the southernmost marine basin (hereafter, “South basin”) in Puget Sound (Washington, USA). Hatchery‐reared juvenile fish were sampled by using beach seine, lampara seine, and fyke nets to determine seasonal trends in frequency, habitat use, and the influence of different capture methods. The captured fish originated from three marine basins, nine Puget Sound rivers, and fourteen hatcheries. The data revealed a consistent pattern showing that most of the tagged fish (72%) were from the nearby Nisqually River (in the South basin), but fish from more northerly marine basins (hereafter, “Outbasin”) were also common. Although the majority of the tagged fish (99%) that were captured during April and May were originally released into rivers adjacent to the South basin, 90% of the fish that were captured in August and September had originated from rivers adjacent to Outbasin locations (up to 130 km distant). A comparison of sampling methods showed that the beach seine produced 27% Outbasin fish compared with 53% that were obtained with the lampara seine. The analysis of habitat use suggested that during June and July, more Outbasin fish (>40%) were captured in delta flats and nearshore habitats than in estuarine emergent marsh habitat (26%). Release location (river basin), but not distance, appeared to be an important factor that influenced the percentage of Outbasin fish that were captured in the South basin. However, it appeared that the fish that were released at light weights and early dates were more likely to be captured. Information on the movement of juvenile salmon to a nonnatal marine basin may help to increase our understanding of features of life history and survival, and it has application elsewhere, as many marine species are artificially propagated, released in large numbers, and have the potential to use nonnatal habitats.

Washington↗

USGS2009

Methane sources and production in the northern Cascadia margin gas hydrate system

The oceanographic and tectonic conditions of accretionary margins are well-suited for several potential processes governing methane generation, storage and release. To identify the relevant methane evolution pathways in the northern Cascadia accretionary margin, a four-site transect was drilled during Integrated Ocean Drilling Program Expedition 311. The δ13C values of methane range from a minimum value of − 82.2‰ on an uplifted ridge of accreted sediment near the deformation front (Site U1326, 1829 mbsl, meters below sea level) to a maximum value of − 39.5‰ at the most landward location within an area of steep canyons near the shelf edge (Site U1329, 946 mbsl). An interpretation based solely on methane isotope values might conclude the 13C-enrichment of methane indicates a transition from microbially- to thermogenically-sourced methane. However, the co-existing CO2 exhibits a similar trend of 13C-enrichment along the transect with values ranging from − 22.5‰ to +25.7‰. The magnitude of the carbon isotope separation between methane and CO2 (εc = 63.8 ± 5.8) is consistent with isotope fractionation during microbially mediated carbonate reduction. These results, in conjunction with a transect-wide gaseous hydrocarbon content composed of > 99.8% (by volume) methane and uniform δDCH4 values (− 172‰ ± 8) that are distinct from thermogenic methane at a seep located 60 km from the Expedition 311 transect, suggest microbial CO2 reduction is the predominant methane source at all investigated sites. The magnitude of the intra-site downhole 13C-enrichment of CO2 within the accreted ridge (Site U1326) and a slope basin nearest the deformation front (Site U1325, 2195 mbsl) is ~ 5‰. At the mid-slope site (Site U1327, 1304 mbsl) the downhole 13C-enrichment of the CO2 is ~ 25‰ and increases to ~ 40‰ at the near-shelf edge Site U1329. This isotope fractionation pattern is indicative of more extensive diagenetic alteration at sites with greater 13C-enrichment. The magnitude of the 13C-enrichment of CO2 correlates with decreasing sedimentation rates and a diminishing occurrence of stratigraphic gas hydrate. We suggest the decreasing sedimentation rates increase the exposure time of sedimentary organic matter to aerobic and anaerobic degradation, during burial, thereby reducing the availability of metabolizable organic matter available for methane production. This process is reflected in the occurrence and distribution of gas hydrate within the northern Cascadia margin accretionary prism. Our observations are relevant for evaluating methane production and the occurrence of stratigraphic gas hydrate within other convergent margins.

Earth and Planetary Science Letters↗

USGS2023

Growth of coal mining operations in the Elk River Valley (Canada) linked to increasing solute transport of Se, NO3-, and SO42- into the transboundary Koocanusa Reservoir (USA-Canada)

Koocanusa Reservoir (KOC) is a waterbody that spans the United States (U.S.) and Canadian border. Increasing concentrations of total selenium (Se), nitrate + nitrite (NO 3 – , nitrite is insignificant or not present), and sulfate (SO 4 2– ) in KOC and downstream in the Kootenai River (Kootenay River in Canada) are tied to expanding coal mining operations in the Elk River Watershed, Canada. Using a paired watershed approach, trends in flow-normalized concentrations and loads were evaluated for Se, NO 3 – , and SO 4 2– for the two largest tributaries, the Kootenay and Elk Rivers, Canada. Increases in concentration (SO 4 2– 120%, Se 581%, NO 3 – 784%) and load (SO 4 2– 129%, Se 443%, NO 3 – 697%) in the Elk River (1979–2022 for NO 3 – , 1984–2022 for Se and SO 4 2– ) are among the largest documented increases in the primary literature, while only a small magnitude increase in SO 4 2– (7.7% concentration) and decreases in Se (−10%) and NO 3 – (−8.5%) were observed in the Kootenay River. Between 2009 and 2019, the Elk River contributed, on average, 29% of the combined flow, 95% of the Se, 76% of the NO 3 – , and 38% of the SO 4 2– entering the reservoir from these two major tributaries. The largest increase in solute concentrations occurred during baseflows, indicating a change in solute transport and delivery dynamics in the Elk River Watershed, which may be attributable to altered landscapes from coal mining operations including altered groundwater flow paths and increased chemical weathering in waste rock dumps. More recently there is evidence of surface water treatment operations providing some reduction in concentrations during low flow times of year; however, these appear to have a limited effect on annual loads entering KOC. These findings imply that current mine water treatment, which is focused on surface waters, may not sufficiently reduce the influence of mine-waste-derived solutes in the Elk River to allow constituent concentrations in KOC to meet U.S. water-quality standards.

Environmental Science and Technology↗

USGS2019

Isotopic and petrologic investigation, and a thermomechanical model of genesis of large-volume rhyolites in arc environments: Karymshina Volcanic Complex, Kamchatka, Russia

The Kamchatka Peninsula of eastern Russia is currently one of the most volcanically active areas on Earth where a combination of >8 cm/yr subduction convergence rate and thick continental crust generates large silicic magma chambers, reflected by abundant large calderas and caldera complexes. This study examines the largest center of silicic 4-0.5 Ma Karymshina Volcanic Complex, which includes the 25 × 15 km Karymshina caldera, the largest in Kamchatka. A series of rhyolitic tuff eruptions at 4 Ma were followed by the main eruption at 1.78 Ma and produced an estimated 800 km 3 of rhyolitic ignimbrites followed by high-silica rhyolitic post-caldera extrusions. The postcaldera domes trace the 1.78 Ma right fracture and form a continuous compositional series with ignimbrites. We here present results of a geologic, petrologic, and isotopic study of the Karymshina eruptive complex, and present new Ar-Ar ages, and isotopic values of rocks for the oldest pre- 1.78 Ma caldera ignimbrites and intrusions, which include a diversity of compositions from basalts to rhyolites. Temporal trends in δ 18 O, 87 Sr/ 86 Sr, and 144 Nd/ 143 Nd indicate values comparable to neighboring volcanoes, increase in homogeneity, and temporal increase in mantle-derived Sr and Nd with increasing differentiation over the last 4 million years. Data are consistent with a batholithic scale magma chamber formed by primarily fractional crystallization of mantle derived composition and assimilation of Cretaceous and younger crust, driven by basaltic volcanism and mantle delaminations. All rocks have 35–45% quartz, plagioclase, biotite, and amphibole phenocrysts. Rhyolite-MELTS crystallization models favor shallow (2 kbar) differentiation conditions and varying quantities of assimilated amphibolite partial melt and hydrothermally-altered silicic rock. Thermomechanical modeling with a typical 0.001 km 3 /yr eruption rate of hydrous basalt into a 38 km Kamchatkan arc crust produces two magma bodies, one near the Moho and the other engulfing the entire section of upper crust. Rising basalts are trapped in the lower portion of an upper crustal magma body, which exists in a partially molten to solid state. Differentiation products of basalt periodically mix with the resident magma diluting its crustal isotopic signatures. At the end of the magmatism crust is thickened by 8 km. Thermomechanical modeling show that the most likely way to generate large spikes of rhyolitic magmatism is through delamination of cumulates and mantle lithosphere after many millions of years of crustal thickening. The paper also presents a chemical dataset for Pacific ashes from ODDP 882 and 883 and compares them to Karymshina ignimbrites and two other Pleistocene calderas studied by us in earlier works.

Kamchatka↗

USGS2001

The role of native birds and other wildlife on the emergence of zoonotic diseases

Wildlife can be an important source of transmission of infectious disease to humans. One potential transmission route involves hunting and fishing, both common activities in the United States and worldwide. For example, during 1996, approximately 11 million Americans, about 40 percent of the total population 16 years of age and older, took part in some recreational activity relating to wildlife and fish. Another potential route of infection focuses on urban and suburban environments. These locations are of special concern because of their increasing role as wildlife habitat, the greater interface between humans and wildlife that takes place within those environments, the paucity of knowledge about disease in those wildlife populations, and the general lack of orderly management for wildlife within those environments. In the wild, several trends are contributing to the growing importance of zoonotic diseases. First, the spectrum of infectious diseases affecting wildlife today is greater than at any time during the previous century. Second, the occurrence of infectious diseases has changed, from sporadic, self-limiting outbreaks that generally resulted in minor losses to frequently occurring events that generally result in major losses of wildlife. Third, disease emergence has occurred on a worldwide scale in a broad spectrum of wildlife species and habitats. Given the scope of the problem, current disease surveillance efforts are inadequate. Few state wildlife agencies allocate personnel and resources to address wildlife disease, despite their statutory responsibility for managing nonmigratory wildlife. Some state agencies provide minimal support for regional programs based at universities. At the federal level, the primary surveillance effort is conducted by the National Wildlife Health Center, operated by the U.S. Geological Survey. Outside of government, some veterinary schools, agriculture diagnostic laboratories, and other programs provide additional information on animal diseases, primarily by examining carcasses of dead wildlife submitted for analysis, and individual university-based researchers carry out a variety of studies. Typically, information about the occurrence of disease in free-ranging wildlife is derived from surveys and mortality events in areas where wildlife observations by agencies and the public are frequent enough to detect their occurrence before carcasses are removed by scavengers and predatory animals. The result is that disease occurrence is grossly underreported, heavily biased toward mortality events, and biased toward species of special concern and interest, such as game and endangered species. Therefore, the available information should be viewed as the “proverbial tip of the iceberg” relative to disease activity within wildlife populations.

National Academy of Science.↗

USGS2016

A synthesis of terrestrial mercury in the western United States: Spatial distribution defined by land cover and plant productivity

A synthesis of published vegetation mercury (Hg) data across 11 contiguous states in the western United States showed that aboveground biomass concentrations followed the order: leaves (26 μg kg − 1 ) ~ branches (26 μg kg − 1 ) > bark (16 μg kg − 1 ) > bole wood (1 μg kg − 1 ). No spatial trends of Hg in aboveground biomass distribution were detected, which likely is due to very sparse data coverage and different sampling protocols. Vegetation data are largely lacking for important functional vegetation types such as shrubs, herbaceous species, and grasses. Soil concentrations collected from the published literature were high in the western United States, with 12% of observations exceeding 100 μg kg − 1 , reflecting a bias toward investigations in Hg-enriched sites. In contrast, soil Hg concentrations from a randomly distributed data set (1911 sampling points; Smith et al., 2013a) averaged 24 μg kg − 1 (A-horizon) and 22 μg kg − 1 (C-horizon), and only 2.6% of data exceeded 100 μg kg − 1 . Soil Hg concentrations significantly differed among land covers, following the order: forested upland > planted/cultivated > herbaceous upland/shrubland > barren soils. Concentrations in forests were on average 2.5 times higher than in barren locations. Principal component analyses showed that soil Hg concentrations were not or weakly related to modeled dry and wet Hg deposition and proximity to mining, geothermal areas, and coal-fired power plants. Soil Hg distribution also was not closely related to other trace metals, but strongly associated with organic carbon, precipitation, canopy greenness, and foliar Hg pools of overlying vegetation. These patterns indicate that soil Hg concentrations are related to atmospheric deposition and reflect an overwhelming influence of plant productivity — driven by water availability — with productive landscapes showing high soil Hg accumulation and unproductive barren soils and shrublands showing low soil Hg values. Large expanses of low-productivity, arid ecosystems across the western U.S. result in some of the lowest soil Hg concentrations observed worldwide.

Science of the Total Environment↗