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Evaluation of nutrient, alkalinity, and acid-neutralizing capacity stabilities in water samples analyzed by the U.S. Geological Survey National Water Quality Laboratory, 2023–24

The U.S. Geological Survey evaluated the stability of water-sample chemical analysis of nutrient, alkalinity, and acid-neutralizing capacity constituents with respect to the duration between sample collection and laboratory analysis, also known as the sample holding time. A study began in the spring of 2023 to evaluate the sample stability, between 2 and 180 days after sample collection, of the chemical properties and chemical constituents of alkalinity as calcium carbonate, filtered; acid-neutralizing capacity as calcium carbonate, unfiltered; total ammonia as nitrogen, filtered; total ammonia plus organic nitrogen as nitrogen, filtered and unfiltered; nitrite as nitrogen, filtered; nitrate plus nitrite as nitrogen, filtered; total nitrogen, filtered and unfiltered; orthophosphate as phosphorous, filtered; and total phosphorus as phosphorus (filtered and unfiltered) in water. Both surface water and groundwater matrices were represented. Sample instability varied by observed property and matrix; therefore, providing general guidance for sample holding time is not possible based on matrices alone. No correlations between field measurements of sample characteristics and sample instability were observed. Although observations for some properties indicate sample stability that exceeds the recognized U.S. Geological Survey National Water Quality Laboratory method holding times, this is not necessarily the case for matrices and seasonal characteristics that were not investigated. Based on the limited number of six sample sources used in this study, some patterns emerge for the 12 observed properties studied. Five observed properties generally indicate stability for as many as 180 days after sampling (total nitrogen as nitrogen, both filtered and unfiltered; orthophosphate as phosphorus, filtered; and phosphorus as phosphorus, both filtered and unfiltered). Other observed properties indicate stability for as many as 180 days for some matrices, but not for others. Finally, some observed properties indicate instability well before 180 days.

Scientific Investigations Report

Sources of water and salts for the Zuni Salt Lake in west-central New Mexico

The Zuni Salt Lake is located in a maar in west-central New Mexico and contains hypersaline water that has long been used by Native Americans for religious purposes and the collection of salt. There have been several investigations suggesting different sources for the water and salt to the lake. Springs, seeps, and ephemeral streamflow have all been observed to contribute freshwater to the lake, and brackish to hypersaline seeps have been documented along the banks of the lake. This report summarizes the findings of a study that characterizes the lake’s hydrology, its water and salinity sources, and the hydrogeologic conceptual model. Regional groundwater levels indicate that each of the aquifers in the area have the potential to discharge groundwater to the lake. There is also evidence of vertical groundwater flow pathways at the maar that were likely created by the igneous intrusion that fractured the intersecting aquifers. A detailed water budget was constructed from continuous lake stage, precipitation, and evaporation data to estimate the groundwater inflow to the Zuni Salt Lake. It was determined that groundwater inflow to the lake is 441 ±94 acre-feet per year, which composes as much as 77 percent of the total inflows. The high sodium and chloride concentrations measured in two hypersaline samples collected near the lake indicate that the majority of the dissolved solids entering the lake are from a hypersaline groundwater source. The geochemical and isotopic compositions measured in the lake and surrounding features support the interpretation that hypersaline groundwater is the primary source of salts to the lake, which is likely sourced from the older (and deeper) Permian units. The hypersaline groundwater samples collected during this investigation have a unique aqueous chemistry relative to each of the mapped aquifers, and variability in groundwater compositions is interpreted to result from differences in minerology and residence time.

New Mexico

Continental-scale prediction of hydrologic signatures and processes

Understanding how dominant hydrologic processes and their drivers vary across diverse continental-scale landscapes is critical for hydrologic modeling and water management applications. Our research addresses this question by synthesizing large-sample watershed datasets, Caravan and GAGES-II, and developing random forest models to identify patterns in hydrologic function. We assessed dominant processes by examining hydrologic signatures – summary indicators of watershed function derived from hydroclimatic time series and random forest models across 14 146 gauged United States watersheds. The results reveal clear continental-scale gradients in hydrologic processes, including baseflow, overland flow, storage, and water balance losses. Our map of dominant processes highlights, for example, the transition from baseflow to fast responses and back to baseflow along the elevation gradient from the Appalachian spine, through the Piedmont, to the Eastern Coastal Plain; a distinct outer ring around the Great Lakes region; and sharp contrasts between coastal and inland processes in the West. Variable importance analysis from random forest models show that processes in the western U.S. are primarily controlled by climate, whereas in the eastern U.S., soil, geology, and topography play larger roles, with distinct human influences apparent in urban areas. Our approach of estimating dominant processes and their drivers facilitates extending process knowledge from research watersheds to the continental scale, assessing current hydrological understanding, and evaluating hydrological model structures.

conterminous United States

Hydrogeology of the Chickasaw National Recreation Area, Murray County, Oklahoma

The Travertine District (Park) of the Chickasaw National Recreation Area, operated and maintained by the National Park Service, is near the City of Sulphur in south-central Oklahoma. The Park was established in 1902 because of its unique hydrologic setting, which includes Rock Creek, Travertine Creek, numerous mineralized and freshwater springs, and a dense cover of riparian vegetation. Since the turn of the century several flowing artesian wells have been drilled within and adjacent to the Park. Discharge from many of these springs and the numbers of flowing wells have declined substantially during the past 86 years. To determine the cause of these declines, a better understanding of the hydrologic system must be obtained. The U.S. Geological Survey, in cooperation with the National Park Service, has appraised hydrologic information obtained for the Park from several studies conducted during 1902-87. The principal geologic units referred to in this report are the Arbuckle Group and the overlying Simpson Group. These rocks are of Upper Cambrian to Middle Ordovician age and are composed of dolomitic limestone, with some sandstones and shales in the Simpson Group. Surface geologic maps give a general understanding of the regional subsurface geology, but information about the subsurface geology within the Park is poor. The Simpson and Arbuckle aquifers are the principal aquifers in the study area. The two aquifers are not differentiated readily in some parts of the study area because of the similarity of the Simpson and Arbuckle rocks; thus, both water-bearing units are referred to frequently as the Arbuckle-Simpson aquifer. The aquifers are confined under the Park, but are unconfined east and south of the Park. Precipitation on the outcrop area of the Arbuckle aquifer northeast and east of the Park recharges the freshwater springs (Antelope and Buffalo Springs) near the east boundary of the Park. The source of water from mineralized springs located in the central part of the Park, and flowing wells within and north of the Park, is believed to be a mix of waters from rocks of the Arbuckle and Simpson Groups. The source of water from two highly mineralized springs, Bromide and Medicine, that ceased to flow in the early 1970’s is believed to be from the Simpson Group. Water-quality characteristics reflect the sources of ground water in the study area. The highly mineralized springs near the western end of the Park are a sodium chloride type with dissolved solids greater than 4,500 mg/L. The freshwater springs near the eastern end of the Park are a calcium bicarbonate type with total dissolved solids of less than 400 mg/L. Flow from the artesian wells has declined substantially during the past 86 years and the wells are estimated to currently discharge only about 10 percent of the total flow reported in 1939. The depletion is believed to be caused by a gradual lowering of the hydraulic head within the aquifer. The influence on the hydrologic system of local municipal and industrial pumping from the Arbuckle-Simpson aquifer is difficult to discern because the system is much more sensitive to precipitation than to pumpage. Ground-water levels and spring flows in this region respond rapidly to precipitation. The effects of withdrawals from the City of Sulphur and Oklahoma Gas and Electric Company power-plant water-well fields are not discernible at wells and springs. The hydrologic system may be influenced by pumping, particularly during extended dry periods of several years, but the impact of pumping on the system cannot be determined without further investigation.

Oklahoma

Analyzing spatial distributions and alignments of pitted cone features in Utopia Planitia on Mars

Martian geomorphology and surface features provide links to understanding past geologic processes such as fluid movement, local and regional tectonics, and feature formation mechanisms. Pitted cones are common features in the northern plains basins of Mars. They have been proposed to have formed from upwelling volatile-rich fluids, such as magma or water-sediment slurries. In this study, we map the spatial distributions of pitted cone features across the Utopia Planitia (UP) basin. Using the Average Nearest Neighbor technique, we find that pitted cone features appear to be clustered across the basin, occurring in a narrow band around the circumferential rim of UP. Additionally, we find that pitted cone features also appear to be aligned in chains that are sub-parallel with the basin margin. Parallel bands of cones generally follow elevation contours of the UP basin, which suggests elevation or a correlated factor plays a major role in pitted cone and cone chain formation. We propose that pitted cones and cone chains may be related to vertical fractures formed around the UP basin rim from subsidence of infilling basin material.

Icarus

Beyond the mangroves: A global synthesis of tidal forested wetland types, drivers and future information opportunities

There is increasing awareness of the global diversity of tidal forested wetlands (TFWs) and their significance in the provision of ecosystem services. These ecosystems, including mangrove forests, tidal freshwater forested wetlands, supratidal forests and transitional forests together span multiple climatic zones, geomorphic settings, and inundation and salinity regimes. We utilise case studies across five continents to demonstrate the state of knowledge among TFWs. Intertidal mangroves are the best-defined of the TFWs thanks to decades of research on their geomorphology, hydrology and ecology across their broad distribution. Non-mangrove forest settings, however, demonstrate more diverse hydrological, biochemical and vegetation conditions. In many cases, non-mangrove forests are situated at upper intertidal or supratidal elevations, where surface waters and groundwater are subject to interactions between tides freshwater inputs. Salinity datasets show variations ranging from tidal freshwater forested wetlands and ‘low-salinity mangroves’ to mesohaline or marine salinities, often with high temporal variability. While the floristic composition of non-mangrove forests vary among biogeographic regions, locally dominant TFW species are commonly distributed beyond the tidal niche into non-tidal wetland and upland forests. This presents challenges for traditional remote sensing approaches to ecosystem mapping, which are mostly lacking for non-mangrove forests. Geomorphic approaches and developments in machine learning offer opportunities to address this.

Preprint

Ages and trace element fertility of porphyry-related mineralization in the Philipsburg polymetallic district, Montana, with a comparison to Butte

The Philipsburg mining district is a Mo-Cu porphyry system with associated Cordilleran polymetallic veins. Geochronology was employed to date the porphyry (~66 Ma, U/Pb in zircon) and molybdenite mineralization from the veins (~76 Ma, Re-Os). Age results suggest that the two-mineralization events model proposed by Lund et al. (2018) for the Butte district can be applied to the Philipsburg deposit. Furthermore, common fertility indicators from zircon trace elements were analyzed with variable success to characterize the existing Mo-Cu mineralization of the Philipsburg porphyry. This raises concerns about the benefits of this method and/or the importance of sampling, which could impact exploration for similar porphyry deposits.

Montana

Background and geologic model for the 2024 U.S. Geological Survey assessment of undiscovered conventional petroleum resources in the Norphlet Formation, U.S. Gulf Coast

The Upper Jurassic Norphlet Formation is a stratigraphic unit located in the subsurface of the United States Gulf coastal plain and offshore Gulf of America (Gulf of Mexico). The Norphlet consists of clastic sediments derived from the southern Appalachian highlands, and was deposited in a continental dryland setting on the margins of the early Gulf of America rift basin. The formation contains a variety of sedimentary facies, including facies representing updip alluvial fans, wadis, red beds, and a widespread erg, or eolian sand sea. The erg facies form the primary reservoirs from which hydrocarbons sourced from the overlying Smackover Formation are produced. Development of the Norphlet began in earnest in the late 1960s, with new discoveries, including large fields at Flomaton, Hatters Pond, and Mobile Bay, continuing through the 2000s–2010s with the discovery of major oil fields in the offshore Desoto Canyon area. Onshore, Norphlet hydrocarbon traps typically are faulted salt anticlines, although many fields also have a stratigraphic trapping component because of the preservation of dune-scale bedforms. Thermal maturity across the Norphlet play varies significantly with depth, resulting in oil production transitioning downdip to natural gas liquids production, then dry gas production; production depths reach to greater than 21,000 feet. A 2024 U.S. Geological Survey assessment divided the Norphlet into four conventional assessment units defined by the type and frequency of trapping mechanisms, sedimentology, and thermal maturity of each area, with little potential for hydrocarbon development observed west of the Mississippi River. Although petroleum resources in the Norphlet were revised downward, it is probable that significant resources remain to be discovered.

Alabama, Florida, Mississippi

Avak Creek oil occurrence, North Slope, Alaska: Newly discovered oil seep on Native lands, near village of Utqiagvik

An unknown occurrence of oil was detected near Avak Creek on Native lands on the North Slope of Alaska. Determining the source of oil was imperative for allowing stakeholders (Federal, State, and local government agencies and the landowner, an Alaska Native corporation) to make timely and informed decisions and mount a mitigation response, if required. The regional and local geological framework of the Avak Creek site was constructed using seismic surveys, well data, and basin modeling results, to identify local petroleum systems, map structural geometry and faults, define source rock thermal maturity distributions, and infer likely oil-migration pathways. Molecular hydrocarbon fingerprints (biomarkers, diamondoids, compound-specific isotopes) of the oil were compared to those of local and regional oil seeps, exploration well tests, and produced oils. Biomarker acid distributions characterized the history and extent of petroleum biodegradation. Integrating subsurface and geochemical parameters, the oil is interpreted to be a natural seep generated locally, predominantly from the Brookian Lower Cretaceous Hue Shale/gamma-ray zone, rather than an anthropogenic source of pollution. Results highlight sophisticated analytical technologies used to characterize complex, compositionally altered hydrocarbons. Results also advance our understanding of Brookian source rock distribution, subsurface petroleum migration pathways, and Arctic Alaska petroleum systems.

Alaska

Apatite (U-Th)/He thermochronology from Marsh Creek anticline reconciles Cenozoic and Holocene strain patterns and elucidates the Cenozoic canning displacement zone of Arctic Alaska

The northeastern Brooks Range is a vast fold-thrust belt that records the northernmost expression of Cenozoic deformation in Alaska, likely with complex dynamic linkages to distant tectonic elements. The principal focus of this manuscript is the Marsh Creek anticline (MCA), which is a large and recently active structure within the broader northeastern Brooks Range. The MCA is a complex, polyphase structure mostly buried beneath the Arctic coastal plain. We present apatite (U-Th)/He (AHe) dates from six outcrop samples, all near the structural crest of the anticline, as well as supporting detrital zircon U/Pb (ZUPb) age spectra from five outcrop samples. The AHe sample transect spans ~3 km of structural relief. The four shallowest AHe samples are not reset. However, the two deepest samples exhibit low intrasample variability among replicates and strong date versus grain radius correlations, suggesting post-depositional burial heating to within the AHe partial retention zone. Inverse thermal history modeling of these data resolves a protracted phase of exhumational cooling that began around 33–28 Ma. Detrital ZUPb age spectra from Paleogene strata support an interpretation of diverse inherited thermal histories recorded by the AHe data, and they are also consistent with extant reconstructions of Paleogene sediment dispersal. Placed into regional context, the results constrain a phase of increasing structural relief in the northeastern Brooks Range fold-thrust belt that began by the Eocene. The relief developed in a zone characterized by diminishing structural relief to the west called the Canning displacement zone. Although this zone was active since the Eocene, several structures including the studied part of the MCA were rapidly exhumed in the Oligocene. Lastly, we argue for kinematic compatibility between Cenozoic contraction and active strike-slip in the northeastern Brooks Range, with the temporal change in strain style likely reflecting the increase in structural relief and topography.

Alaska

Methods for quantifying interactions between groundwater and surface water

Driven by the need for integrated management of groundwater (GW) and surface water (SW), quantification of GW–SW interactions and associated contaminant transport has become increasingly important. This is due to their substantial impact on water quantity and quality. In this review, we provide an overview of the methods developed over the past several decades to investigate GW–SW interactions. These methods include geophysical, hydrometric, and tracer techniques, as well as various modeling approaches. Different methods reveal valuable information on GW–SW interactions at different scales with their respective advantages and limitations. Interpreting data from these techniques can be challenging due to factors like scale effects, heterogeneous hydrogeological conditions, sediment variability, and complex spatiotemporal connections between GW and SW. To facilitate the selection of appropriate methods for specific sites, we discuss the strengths, weaknesses, and challenges of each technique, and we offer perspectives on knowledge gaps in the current science.

Annual Review of Environment and Resources

Monitoring and assessment of urban stormwater best management practices at selected Chicago public schools in Chicago, Illinois, from September 1, 2016, to July 1, 2017

The Space to Grow program helps transform aging and neglected schoolyards of Chicago Public Schools into outdoor community spaces with the goal of promoting health and learning while addressing neighborhood flooding issues. Virgil I. Grissom Elementary School and Donald L. Morrill Math and Science School were selected in 2014 for schoolyard upgrades and the installation of various green infrastructure (GI) improvements. The U.S. Geological Survey installed sensors to measure precipitation, groundwater levels, and stormwater runoff volumes from September 1, 2016, to July 1, 2017. At Virgil I. Grissom Elementary School, about 933,000 gallons of water fell on the schoolyard during the monitoring period. No discharge was recorded coming from the GI sewer lines, but backflow indicated water was flowing from the sewer line draining the impervious running track into the combined manhole structure and backwards into the GI retention basins (as designed). This design allowed for a 100-percent capture rate. Native soil at Virgil I. Grissom Elementary School also was conducive to rapid infiltration. Soil borings at Virgil I. Grissom Elementary School indicated about 10.5 feet (ft) of fine sand overlying silty clay to a depth of at least 16 ft. At Donald L. Morrill Math and Science School, about 1,120,000 gallons of water fell on the schoolyard during the monitoring period. About 72.5 precent of this water was discharged into the sewer system, and the other 27.5 percent was captured by the GI. Unlike Virgil I. Grissom Elementary School, the soil profile at Donald L. Morrill Math and Science School consisted of about 5 ft of clay loam overlying stiff blue clay to a depth of at least 12 ft. The sewer line coming from the GI under the football field was at the bottom of the reservoir. This design seemed to allow water to flow out of the line before being absorbed by the retention basin.

Illinois

Water-quality characteristics of the Red River of the North and tributaries in the Fargo-Moorhead metropolitan area, North Dakota, 2019–22

The Flood Risk Management Project was initiated in 2008 in the Fargo-Moorhead metropolitan area to reduce flood risk, flood damages, and flood protection costs in the Fargo-Moorhead metropolitan area. In cooperation with the U.S. Army Corps of Engineers, the U.S. Geological Survey initiated a water-quality monitoring study to describe the water-quality characteristics of the Red River of the North and its tributaries in the Fargo-Moorhead metropolitan area during the preconstruction period of the Flood Risk Management Project from October 1, 2019, to October 1, 2022. The monitoring study included the collection of discrete and continuous water-quality data and streamflow monitoring at selected sites that integrated and enhanced existing monitoring programs within the study area. Discrete samples collected at 10 sites in the Fargo-Moorhead metropolitan area were analyzed for major ions, trace elements, nutrients, suspended sediment, pesticides, and fecal indicator bacteria. In general, major ion concentrations were higher at sites on the tributaries (Wild Rice, Sheyenne, and Maple Rivers) compared to sites on the Red River of the North. In general, bicarbonate, calcium, magnesium, and sulfate represented most of the dissolved ions measured in samples collected at the 10 sites. Calcium, chloride, fluoride, potassium, silica, and sodium were also measured in samples, but they represented a smaller portion of the total dissolved ions. Sulfate was the most dominant dissolved ion that had the highest concentrations among the major ions measured in samples. A total of 18 trace elements were analyzed in discrete samples. Several of the trace elements had concentrations below the laboratory reporting level in all of the samples, including antimony, beryllium, cadmium, chromium, silver, and thallium. Sites on the Wild Rice River generally had the highest concentrations of arsenic, barium, boron, manganese, and nickel compared to the other sites. Nutrients analyzed in discrete samples included filtered and unfiltered concentrations of ammonia, nitrate plus nitrite, phosphorus, and organic carbon. The median filtered ammonia concentration at most sites was less than the laboratory reporting level of 0.03 milligram per liter as nitrogen except for the Sheyenne River at Harwood, North Dakota (U.S. Geological Survey [USGS] station 05060400), and Red River of the North near Georgetown, Minnesota (USGS station 05062130). The lowest median unfiltered nitrate plus nitrite concentration was measured at sites on the Red River of the North upstream from the Fargo-Moorhead metropolitan area and the highest median was at sites on the Red River of the North downstream from the Fargo-Moorhead metropolitan area compared to all other sites. The increase in nitrate plus nitrite concentrations could reflect the effect of the wastewater-treatment plant discharge that enters the Red River of the North upstream from the site located downstream from the Fargo-Moorhead metropolitan area and from urban runoff. Phosphorus (unfiltered) concentrations were generally higher at sites on the Maple and Sheyenne Rivers compared to the other sites and were higher at sites on the Red River of the North downstream from the Fargo-Moorhead metropolitan area compared to sites upstream on the Red River of the North. Suspended-sediment concentrations were generally highest at sites in the Sheyenne River and lowest in the upstream Red River of the North sites. Suspended-sediment concentration was highly variable in samples collected at the 10 sites, mostly influenced by the occurrence of snowmelt and rainfall-runoff events. The Sheyenne River near Kindred, N. Dak. (USGS station 05059000) had the largest range in sediment concentrations in samples collected at the 10 sites. For all sites other than the Sheyenne River near Kindred, N. Dak., 95 percent or more of the suspended sediment had particle diameter sizes less than 0.0625 millimeter in 50 percent of the samples (median). Of the 102 pesticides and pesticide degradates analyzed, 45 constituents had no detectable concentrations in any of the 17 samples collected at five sites. The remaining 57 pesticides had at least one detection in the samples collected at the five sites. The sites on the Wild Rice River (near Abercrombie, N. Dak., USGS station 05053000, and near St. Benedict, N. Dak., USGS station 05053500) and Sheyenne River near Kindred, N. Dak., had fewer pesticide detections compared to the Maple River below Mapleton, N.Dak. (USGS station 05060100) and the Red River of the North at Fargo, N. Dak (USGS station 05054000) and near Georgetown, Minn. Patterns in annual loads generally followed the same pattern as streamflow at the 10 sites for water years 2020–22. A water year is the 12-month period from October 1 to September 30 and is designated by the calendar year in which it ends. The greatest loads for all constituents were delivered at the two downstream sites on the Red River of the North; sites that also had the highest annual streamflows among the sites and the greatest loads were delivered in water year 2020 when the highest streamflows occurred at the sites. Likewise, the least loads for most constituents were at the Maple River and were least in 2021 compared to the other years because of low-streamflow conditions. Water-quality measurements continuously recorded at the Red River of the North at Hickson, N. Dak. (USGS station 05051522); Red River of the North at Fargo, N. Dak.; and Red River of the North near Georgetown, Minn. included water temperature, specific conductance, dissolved oxygen, pH, and turbidity. Specific conductance values were similar for the Red River of the North near Hickson, N. Dak., and Red River of the North at Fargo, N. Dak., when compared to the Red River of the North near Georgetown, Minn. that had higher values than the other two sites. Dissolved oxygen concentrations and pH were similar among the three sites on the Red River. The patterns in turbidity were mostly related to streamflow conditions and were similar among the three sites on the Red River of the North.

Minnesota, North Dakota

Uranium and trace elements in stream sediments as an exploration tool

More than 45 trace elements have been reported in anomalous amounts in the uranium ores. The specific suite of elements associated with any one uranium deposit varies according to deposit type and geologic province. The primary geochemical halo of uranium and associated trace elements in the host rock, together with secondary dispersion halo in soils and alluvium, offers a potential geochemical exploration target. Sediment from streams near low-grade uranium occurrences in arkosic sandstone of the Denver basin, Colorado, and sediment from streams in the igneous and metamorphic terrace near the Midnite mine of eastern Washington have been analyzed for acid-extractable U, Cu,Pb, Zn, Ni, Co, Fe, Mn, Mo, Cd, Cr, Ag, V, and Se, and for total Fe, Mn, Hg, As, and organic C. The -80 mesh fraction of the alluvium downstream from a small uraniferous limonite occurrence in the Denver basin shows anomalous concentrations of U, Pb, As, Ni, Mo, V, Zn, and Se. Anomalous concentrations of U persist farther downstream (as much as 1,000 m) than any of the trace elements. In another stream system southeast of Denver, above-background levels of U, Pb, As, Zn, V, Fe, and Mn occur near a uranium anomaly (defined by other methods) which has no surface mineralization. In the Midnite mine area, sediments of streams draining prospect areas showed anomalous concentrations of uranium (as much as 10 times background), but no accompanying anomalous trace-element concentrations, although analyses of Midnite mine ores show that a broad suite of trace elements are associated with uranium.

Open-File Report

Quantitative evaluations of earthquake early warning performance using “Did You Feel It?” and post-alert surveys

We examine responses to the U.S. Geological Survey’s “Did You Feel It?” (DYFI) survey and its companion earthquake early warning (EEW) questionnaire to assess the performance of the U.S. ShakeAlert EEW system directly from the alert recipients’ perspectives. ShakeAlert rapidly detects earthquakes and develops alert information, but as official alert delivery partners issue these alerts, it is thus difficult to determine how many people were alerted and when. We investigate DYFI reports for six California earthquakes that had EEW alerts and substantial responses to the DYFI EEW questionnaire. Comparisons of ShakeAlert predictions to reported intensities demonstrate that magnitude estimation accuracy is not necessarily indicative of ground-motion prediction accuracy. Perceived warning time distributions indicate that estimating maximum-expected warning times using the S-wave arrival is a reasonable assumption when discussing public EEW performance. However, we also find many reports of shorter warning times, late alerts, and missed alerts than expected based on ShakeAlert publication times, suggesting alert delivery latencies are substantial and highly variable. The novelty of our analysis is that we demonstrate that the DYFI EEW survey provides useful EEW efficacy information—independent of the specific alerting pathway—that can be used to inform our choices for conveying EEW performance.

California

Testing rate‐and‐state predictions of aftershock decay with distance

We analyze aftershocks of the 2019 M 7.1 Ridgecrest mainshock and isolated M 5–6 mainshocks in southern California to test predictions made by the rate‐and‐state friction model of Dieterich (1994) . Rate‐and‐state friction predicts that the seismicity rate after a stress step follows Omori decay, where the Omori c ‐value, which is the saturation in aftershock rate observed at small times, is larger for smaller stress steps. Put in the context of an aftershock sequence, this predicts that the Omori c ‐value will be systematically larger at greater distances from the mainshock. To our knowledge, this predicted effect has not been observed. In part this may be because the Omori c ‐value is difficult to measure because it often reflects short‐term catalog incompleteness rather than a true saturation in aftershock rate. We explore the dependence of the Omori c ‐value on the distance to the mainshock by applying the “ a ‐positive” method ( van der Elst and Page, 2023 ). This method is insensitive to short‐term aftershock incompleteness and allows resolution of the true aftershock rate deep into the mainshock coda. For aftershocks of the Ridgecrest mainshock and stacked M 5–6 mainshocks, we observe systematic differences in early aftershock rates, relative to mainshock distance, consistent with the predictions of rate‐and‐state friction. Furthermore, for the larger Ridgecrest dataset, we observe that aftershocks nearer to the mainshock start earlier, and we resolve a flattening of the Omori curve consistent with a larger Omori c ‐value for the farthest aftershocks, as predicted by Dieterich (1994) .

Seismological Research Letters

Metal mobilization from thawing permafrost to aquatic ecosystems is driving rusting of Arctic streams

Climate change in the Arctic is altering watershed hydrologic processes and biogeochemistry. Here, we present an emergent threat to Arctic watersheds based on observations from 75 streams in Alaska’s Brooks Range that recently turned orange, reflecting increased loading of iron and toxic metals. Using remote sensing, we constrain the timing of stream discoloration to the last 10 years, a period of rapid warming and snowfall, suggesting impairment is likely due to permafrost thaw. Thawing permafrost can foster chemical weathering of minerals, microbial reduction of soil iron, and groundwater transport of metals to streams. Compared to clear reference streams, orange streams have lower pH, higher turbidity, and higher sulfate, iron, and trace metal concentrations, supporting sulfide mineral weathering as a primary mobilization process. Stream discoloration was associated with dramatic declines in macroinvertebrate diversity and fish abundance. These findings have considerable implications for drinking water supplies and subsistence fisheries in rural Alaska.

Alaska

Evaluating groundwater quality influences from oil field operations and other anthropogenic activities in an urban setting, Santa Fe Springs, California

Groundwater quality is often affected by anthropogenic activities in urban settings. This study examines groundwater quality in and around the Santa Fe Springs Oil Field in Los Angeles County, California, where oil and gas production commonly intersects with high density industrial, commercial and residential land uses. Utilizing a combination of new and historical data, we evaluated potential pathways that would allow for oil field formation fluids to migrate into groundwater and whether mixing may have occurred based on the distribution of groundwater and oil field formation fluid tracers in samples. Samples were analyzed for a wide array of constituents including volatile organic compounds, light hydrocarbons, major ions, and various isotopic compositions. Despite evidence of oil field infrastructure providing potential pathways of migration via uncemented annular spaces, casing breaches and historical disposal of oil field formation water in surface ponds, the distribution and occurrence of stable isotopes of water, chloride, boron, and total dissolved solids do not indicate mixing of oil field formation water and groundwater. However, methane isotopic signatures and the presence of heavier alkanes suggest gas from oil-bearing formations have migrated from depth via oil field well infrastructure. Volatile organic compound detections were mainly from manufactured compounds unrelated to oil and gas production, with a relatively limited number of petroleum hydrocarbons also detected. Volatile organic compounds were generally found in wells tapping shallow, modern aged groundwater, indicating anthropogenic activities occurring at or near land surface as the source. Study results suggest that while oil field infrastructure provides migration pathways for oil field formation fluids to be introduced into groundwater, urban land uses not related to oil and gas production are the primary drivers of groundwater quality degradation.

California