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Water-quality assessment of south-central Texas: Occurrence and distribution of volatile organic compounds in surface water and ground water, 1983-94, and implications for future monitoring

The study area of the South-Central Texas study unit of the National Water-Quality Assessment Program comprises the Edwards aquifer in the San Antonio region and its catchment area. The first phase of the assessment includes evaluation of existing water-quality data for surface water and ground water, including volatile organic compounds, to determine the scope of planned monitoring. Most analyses of volatile organic compounds in surface water are from the National Pollutant Discharge Elimination System sites in San Antonio, Texas. Nine volatile organic compounds were detected at the six sites. The three compounds with the most detections at National Pollutant Discharge Elimination System sites are 1,2,4-trimethylbenzene, toluene, and xylene. Analysis of volatile organic compounds in ground water was limited to Edwards aquifer wells. Twenty-eight volatile organic compounds were detected in samples from 89 wells. The five most commonly detected compounds in samples from wells, in descending order, are tetrachloroethene, trichloroethene, bromoform, chloroform, and dibromochloromethane. Detections of volatile organic compounds in surface water and ground water within the South-Central Texas study area are limited to site-specific sources associated with development; therefore, planned monitoring for possible detections of volatile organic compounds as part of the National Water-Quality Assessment Program will emphasize areas of expanding population and development. Monitoring of volatile organic compounds is planned at National Pollutant Discharge Elimination System sites, at basic fixed surface-water sites, and in the ground-water study-unit surveys.

Texas

The Saudi Geological Survey-U.S. Geological Survey northern Harrat Rahat project—Styles, rates, causes, and hazards of volcanism near Al Madīnah al Munawwarah, Kingdom of Saudi Arabia

Active volcanic systems pose serious hazards to people and property including inundation and incineration by lava, blanketing by tephra (volcanic ash), exposure to noxious volcanic gases, and damage from shallow earthquakes triggered by ascending molten material (magma). To improve understanding of volcanism and associated seismicity on the western Arabia Plate, the Saudi Geological Survey and the U.S. Geological Survey conducted a multi-year investigation of the northern Harrat Rahat volcanic field adjacent to the city of Al Madīnah al Munawwarah, Kingdom of Saudi Arabia. Project components included creation of a high-resolution digital topographic base; interpretation of eruptive history supported by detailed geologic mapping, paleomagnetism, and abundant high-precision geochronology of volcanic deposits; assessments of eruptive styles and volcanic hazards by physical volcanology; investigation of the origins of magmas in the mantle and of their differentiation in the crust revealed by chemical and isotopic petrology; gravity and magnetotelluric surveys to reveal crustal structures and to search for magma reservoirs; and regional and local seismic tomography and analyses of seismic hazards. Project results are presented in this Professional Paper as chapters written for technical scientific audiences. This initial chapter introduces the project and briefly summarizes results in plain language for readers who have more general backgrounds.

Al Madīnah al Munawwarah

Characterization of the hydrogeologic framework, groundwater-flow system, geochemistry, and aquifer hydraulic properties of the shallow groundwater system in the Wilcox and Lorraine process areas of the Wilcox Oil Company Superfund site near Bristow, Oklahoma, 2022

The Wilcox Oil Company Superfund site (hereinafter referred to as “the site”) was formerly an oil refinery northeast of Bristow in Creek County, Oklahoma. Historical refinery operations contaminated the soil, surface water, streambed sediments, alluvium, and groundwater with refined and stored products at the site. The Wilcox and Lorraine process areas are where the highest concentrations of volatile organic compounds, semivolatile organic compounds, polycyclic aromatic hydrocarbons, and trace elements (including metals) (collectively hereinafter referred to as “contaminants”) were measured in a local shallow perched groundwater system within the alluvium (hereinafter referred to as the “alluvial aquifer”) at the site during previous site assessments. In order to understand the potential migration of contaminants through the soil and groundwater in these areas, the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency, investigated aquifer characteristics of the alluvial aquifer in the Wilcox and Lorraine process areas of the site to (1) document hydraulic conductivity and other aquifer characteristics of the alluvial aquifer that govern contaminant fate and transport, (2) describe the geospatial extent and concentration of the contaminants in the alluvial aquifer in the Wilcox and Lorraine process areas, and (3) describe the geochemical controls pertaining to oxidation and reduction governing the fate and transport and the degradation potential of contaminants in the groundwater. Various data were compiled and collected to evaluate the aquifer characteristics at the site including the hydrogeologic framework, groundwater-flow system, geochemistry, and hydraulic properties of the aquifer. A total of 20 new (2022) groundwater monitoring wells were installed at the site to collect data used to supplement groundwater-level altitude and groundwater-quality data collected from older, existing groundwater monitoring wells and piezometers. Data compiled and collected for the study were used to evaluate the characteristics of the alluvial aquifer at the site. These aquifer characteristics are defined by the hydrogeologic framework, groundwater-flow system, geochemistry, and hydraulic properties of the aquifer.

Oklahoma

Sensitivity of benthic biota and toxicity of cadmium, cobalt, copper, nickel, lead, and zinc mixtures in Washington, United States, and British Columbia, Canada

Relative sensitivities and responses of juvenile white sturgeon ( Acipenser transmontanus ), Hyalella azteca , two families of mayfly (Ephemerellidae, Heptageniidae), one family of caddisfly (Brachycentridae), and a natural community of benthic macroinvertebrates (BMI) to multiple metals are predicted using previously collected laboratory and field samples and a metal mixture model. Biological responses in single metal exposures are used to parameterize toxicity functions, which include accumulations of hydrogen and selected metals on biological receptors, intrinsic potencies of hydrogen and metals, sensitivities of organisms, and times of exposure. The model then is used to predict responses in multiple metal laboratory exposures and field-collected porewater. The following sensitivity sequence in porewater was determined based on endpoints of survival or total abundance: juvenile white sturgeon greater than (>) Ephemerellidae family > Hyalella azteca > Heptageniidae family about equal to (~) benthic macroinvertebrate community > Brachycentridae family. The fraction of porewater samples that are predicted to have adverse impacts on benthic biota (20-percent or greater negative response) depends on organism sensitivities and metal toxicities, and ranges from 44 to 48 percent for juvenile white sturgeon, 23 to 26 percent for the Ephemerellidae family, 16 to 22 percent for Hyalella azteca , 5 to 8 percent for the Heptageniidae family and BMI community, and 0 percent for the caddisfly family. The most toxic porewater in the upper Columbia River Basin (UCR) is at the backwater bar site at Deadmans Eddy and China Bend. The model also indicates that the element responsible for the most toxic conditions in UCR porewater is copper for all organisms, except Hyalella azteca and the metal-insensitive Brachycentridae family. Copper and lead result in the most toxic conditions for Hyalella azteca . This approach and results can aid in assessing metal toxicity and its potential risk to aquatic biota in ecosystems impacted by historical mining activities.

British Columbia, Washington

Geochemistry and thermometry of magnetite veins and replacements in iron ore deposits from the Iron Springs district, SW Utah, USA: Relation to magmatic and hydrothermal processes

Ore-genesis, texture, chemical compositions, and thermometry of magnetite were used to better evaluate the origins of iron ore deposits across the Iron Spring district, Utah. Trace element compositions, determined by LA-ICP-MS, were used to calculate temperatures based on X Mg numbers and characterize the trace element signatures of magmatic and hydrothermal magnetite. Magnetite occurs as coarser crystalline grains within veins, breccias, and cavities along with finer crystalline replacements. Magnetite is most commonly intergrown with apatite, phlogopite, and carbonate in veins, breccias, and cavities where apatite occurs separately from the other gangue minerals. The results using empirical trace element discrimination diagrams generally suggest that the magnetite is overall of hydrothermal origin regardless of textural variations or field relationships. The X Mg numbers of the magnetite in the magnetite-apatite ores, however, are suggestive of high temperature magmatic conditions; whereas those of vein, breccia, and replacement occurrences containing other gangue minerals are suggestive of lower temperature hydrothermal processes.

Utah

Geologic framework, hydrostratigraphy, and ichnology of the Blanco, Payton, and Rough Hollow 7.5-minute quadrangles, Blanco, Comal, Hays, and Kendall Counties, Texas

During 2023, the U.S. Geological Survey, in cooperation with the Edwards Aquifer Authority, revised an initial characterization completed during 2015–16 of the geologic framework, hydrostratigraphy, and ichnology of the Edwards and Trinity aquifers in the Blanco, Payton, and Rough Hollow 7.5-minute quadrangles in Blanco, Comal, Hays, and Kendall Counties, Texas. The purpose of this report is to present the updated geologic framework, hydrostratigraphy, and ichnology of the Trinity and Edwards Groups in those quadrangles. Rocks exposed in the study area are of the Lower Cretaceous Trinity Group and lower part of the Fort Terrett Formation of the Lower Cretaceous Edwards Group. The faulting and fracturing in the study area are part of the Balcones Fault Zone, an extensional system of faults active during the Paleocene to middle Eocene that generally trends southwest to northeast in south-central Texas. Hydrostratigraphically, the rocks exposed in the study area contain a section of the Edwards (Balcones Fault Zone) aquifer, upper zone of the Trinity aquifer, and middle zone of the Trinity aquifer. In the study area, the only hydrostratigraphic units of the Edwards (Balcones Fault Zone) aquifer remaining are (from top to bottom) VII and VIII, which cap several hills. The mapped hydrostratigraphic units of the upper zone of the Trinity aquifer are (from top to bottom) the cavernous, Camp Bullis, upper evaporite, fossiliferous, and lower evaporite. The mapped hydrostratigraphic units of the middle zone of the Trinity aquifer are (from top to bottom) the Bulverde, Little Blanco, Twin Sisters, Doeppenschmidt, Herff Falls (where present), Rust, Honey Creek, Hensell, and Cow Creek hydrostratigraphic units.

Texas

Method for estimating water use and interbasin transfers of freshwater and wastewater in an urbanized basin

Techniques for management of drainage basins that use water budgets to balance available water resources with actual or anticipated water use require accurate and precise estimates of basin withdrawals, interbasin transfers of freshwater, unaccounted-for use, water use, consumptive use, inflow and infiltration, basin return flow, and interbasin transfers of wastewater. Frequently, interbasin transfers of freshwater and wastewater are not included in basin water budgets because they occur within public water-delivery and wastewater-collection systems. A new 10-step method was developed to improve estimates of inflow and infiltration and interbasin transfers using readily available statewide data. The accuracy and precision of water-use estimates determined by this method are improved through careful application of coefficients for small users and the use of metered values for large users. The method was developed and tested with data for the Ten Mile River Basin in southeastern Massachusetts. This report uses examples from the basin to illustrate each step of the method.

Massachusetts

SUTRA— A code for simulation of saturated-unsaturated, variable-density groundwater flow with solute or energy transport—Documentation of the version 4.0 enhancements—Freeze-thaw capability, saturation and relative-permeability relations, spatially varying properties, and enhanced budget and velocity outputs

Version 4.0 of the Saturated-Unsaturated Transport (SUTRA) software code provides the capability to simulate the freezing and thawing of groundwater during energy transport simulations under saturated and unsaturated conditions. In addition to the types of hydrogeologic processes that SUTRA has been able to simulate in the past, this version can be used to study the effects of the freeze-thaw process on the flow and energy dynamics of hydrogeologic systems. The freeze-thaw simulation capability accounts for the latent heat of fusion and allows thermal property values to vary with changing total-water saturation, liquid-water saturation, and ice saturation. It allows the effective permeability of the porous medium to change as a result of freezing and thawing. This version also provides several user-selectable relations for the dependence of total-water saturation on fluid pressure, the dependence of liquid-water saturation on temperature during freezing and thawing, and the dependence of relative permeability on liquid saturation, as well as three user-selectable formulae for defining the bulk thermal conductivity of a mixture of solid grains, liquid water, ice, and air. For unsaturated simulations without freezing, the selectable total-water saturation relations eliminate the need for the user to program these and their associated relative-permeability functions, as had been required in previous SUTRA versions. Optional nonlinear dependence of fluid density on temperature, which covers the range from supercooled (about −50 degrees Celsius) to superheated (about 400 degrees Celsius), is also provided. Additionally, this version makes it possible to spatially vary parameters that, in previous versions of SUTRA, were required to be spatially uniform: solid-matrix properties, adsorption parameters, and parameters for production of solute mass or energy. Spatial variation is also allowed for the newly included freeze-thaw process parameters. Additional enhancements provide (1) output of water-mass and energy budgets that include values of all component terms in the governing balance equations, and (2) output of Darcy velocities (fluid fluxes), in addition to the velocity output provided by previous SUTRA versions. These enhanced outputs allow fuller interpretation of simulation results, especially for freeze-thaw phenomena. The set of processes simulated by this version of SUTRA are useful for studying a wide range of hydrogeologic system types, conditions, and questions. For cryohydrogeologic simulations, however, this version of the code is limited in that (1) it does not simulate thermomechanical effects of freeze-thaw, (2) pressure changes due to water density change during freezing are neglected, (3) ice saturation cannot exceed the initial porosity of the simulated medium, and (4) cryosuction, the migration of liquid water toward freezing fronts, is neglected. Furthermore, this version does not account for air flow or for water vaporization and sublimation under unsaturated conditions.

Techniques and Methods

Bedrock geologic map of the Bellows Falls 7.5- x 15-minute quadrangle, Windham and Windsor Counties, Vermont, and Sullivan and Cheshire Counties, New Hampshire

Introduction The bedrock geology of the Bellows Falls 7.5- x 15-minute quadrangle, Vermont and New Hampshire, consists of polydeformed Ordovician to Devonian metasedimentary, metavolcanic, and metaplutonic rocks of the Connecticut Valley trough, Bronson Hill anticlinorium (or Bronson Hill terrane), and the Central Maine terrane. Previous work in this area includes a 1:62,500-scale published map and text (1946), State geologic maps of New Hampshire (1997) and Vermont (2011), and various maps and reports presented largely as parts of field trip guidebooks. A provisional open-file map of the geology of the Vermont part of the Bellows Falls 7.5- x 15-minute quadrangle, completed in 1997, is incorporated and revised on this map based on additional fieldwork. This study recognizes three major structural levels from west to east and from lowest to highest: (1) autochthonous rocks of the Connecticut Valley trough; (2) allochthonous rocks of the New Hampshire sequence and Bronson Hill arc in the Monroe thrust sheet (or nappe), including the Skitchewaug nappe; and (3) allochthonous rocks of the Fall Mountain thrust sheet or nappe.

New Hampshire, Vermont

Characterization of the water resources of the Pamunkey River watershed in Virginia—A review of water science, management, and traditional ecological knowledge

In central Virginia, the Pamunkey Indian Tribe and Reservation are facing increasingly complex water resource issues related to quantity and quality. Documentation of surface-water, groundwater, water quality, land subsidence, sea-level rise, and river ecology issues in the Pamunkey River watershed and incorporation of traditional ecological knowledge into these research topics may improve understanding of the water resources broadly. This report summarizes the relevant traditional ecological knowledge and scientific literature to elucidate gaps in the total combined knowledge of a suite of water science topics concerning the Pamunkey River watershed. This suite of water science topics includes some of the issues that the Pamunkey Indian Tribe and Reservation are facing within the watershed: fragmentation of streams and management of streamflow, flooding, degrading water quality, groundwater extraction, relative sea-level rise, rapid changes in ecosystems, loss of ecological and biological diversity, and climate change. Gaps in total combined knowledge are pervasive throughout each of these water resource topics. Identifying these knowledge gaps can help inform future research and management strategies.

Virginia

A decade of shaking in the Garden City: The dynamics of preparedness, perceptions, and beliefs in Canterbury, New Zealand, and implications for earthquake information

This study explored earthquake preparedness over time - before, during, and 10 years after the Canterbury Earthquake Sequence (CES) in Aotearoa New Zealand (NZ). Surveys of Canterbury residents were conducted in 2009, 2013 and again in 2021, using variables derived from Community Engagement Theory (CET). The surveys measured earthquake perceptions and beliefs, participation and engagement, and preparedness actions. Results were compared across the three samples. Findings indicate that perceptions and beliefs (e.g. risk perception, outcome expectancy beliefs), and types of preparedness actions taken (e.g. collection of survival items, structural preparedness, community and agency relationships), differed over time, depending on people’s experiences before, during, and after the CES. For example, during and after the CES people were more likely to believe that preparing provided a benefit to daily life, but less likely to think it could reduce property damage, perhaps due to people’s experiences of disruption and damage during the earthquakes. An understanding of such dynamics can assist with the provision and timing of risk and preparedness information. This study highlights the importance of providing applicable and actionable preparedness information, that is relevant to people’s experiences, throughout an earthquake sequence. Such information might evolve and change in focus over time depending on risks and needs. Focus could also be given to information that builds peoples beliefs and capacities to undertake preparedness in evolving situations. Understanding preparedness in the context of different experiences and timeframes is useful in helping update models such as the CET, where the dynamics of time might be better incorporated.

Canterbury

Methodology for compilation of previously published contour data showing the altitude of the base of Dakota Sandstone on the Colorado Plateau, Arizona, Colorado, New Mexico, and Utah

Structure contours and other geologic information from numerous published geologic maps were digitized and compiled into a digital dataset showing the configuration of a single stratigraphic datum, the base of the Dakota Sandstone and its equivalents across the Colorado Plateau. The principal maps compiled in digital form are a series of 1:250,000-scale 1 degree (°) × 2° quadrangle maps published by the U.S. Geological Survey, augmented by other geologic maps published at various map scales. The compiled digital dataset contains geologic map polygons of the Dakota Sandstone and regional stratigraphic equivalents, the location of faults and fold axes, structure contour lines that define the altitude of the base of the unit and bedding orientation data computed from the structure contour lines. This report provides the scientific rationale for compilation of these data and describes the compilation methodology for each of the data elements. This report provides an extended description of the data compilation in a companion U.S. Geological Survey digital data release of spatial data and attributes associated with the contoured surface and associated geologic data layers.

Arizona, Colorado, New Mexico, Utah

Colored shaded-relief bathymetric and acoustic-backscatter maps of Jenkinson Lake with orthomosaic of the Sly Park Creek and Hazel Creek area, California

The Caldor Fire was ignited on August 14, 2021, and burned almost 222,000 acres (898 square kilometers) in forested terrain of the central and western Sierra Nevada, California. During the subsequent two months, the fire burned nearly all of Sly Park Creek watershed in El Dorado County. The El Dorado Irrigation District manages the water supply for the area using storage in Jenkinson Lake, a 1.6-kilometer- (1.0-mile-) wide and 3.6-kilometer- (2.2-mile-) long reservoir, located south of the town of Pollock Pines. Several weeks after the fire, the U.S. Geological Survey began investigations into post-fire landscape responses, including sediment yield, by measuring new sediment deposition in Jenkinson Lake. This study focused on the collection and processing of bathymetric and acoustic-backscatter data, as well as onshore aerial imagery in and around Jenkinson Lake, to support wildfire science after the Caldor Fire. A colored shaded-relief bathymetric map (sheet 1) and an acoustic backscatter map (sheet 2) show the lake floor morphology and backscatter intensities.

California

Seabed maps showing topography, ruggedness, backscatter intensity, sediment mobility, and the distribution of geologic substrates in quadrangle 2 of the Stellwagen Bank National Marine Sanctuary region offshore of Boston, Massachusetts

The U.S. Geological Survey, in cooperation with the National Marine Sanctuary Program of the National Oceanic and Atmospheric Administration, has conducted seabed mapping and related research in the Stellwagen Bank National Marine Sanctuary (SBNMS) region since 1993. The area being mapped using geophysical and geological data includes the SBNMS and the surrounding region, which totals approximately 3,700 square kilometers (km 2 ) and is subdivided into 18 quadrangles. The seabed is a glaciated terrain that is topographically and texturally diverse. Quadrangle 2, the subject of this scientific investigations map, has a mapped area of 209 km 2 and has water depths that range from about 19 meters (m) on the Stellwagen Bank crest to about 68 m in the Stellwagen Basin. Seven map types, each at a scale of 1:25,000, depict seabed topography, ruggedness, backscatter intensity, distribution of geologic substrates, sediment mobility, distribution of fine- and coarse-grained sand, and substrate mud content. These maps show the distribution of geologic substrates across the southwestern part of Stellwagen Bank, in Stellwagen Basin to the west and southwest of the bank, and in Little Stellwagen Basin and the western part of Race Point Channel to the south of the bank. Interpretations of multibeam sonar bathymetric and seabed backscatter imagery, photographs, video imagery, and grain-size analyses were used to create the geology-based maps. Data from 733 stations were analyzed, including 656 sediment samples. The geologic substrate maps of quadrangle 2 show the distribution of 19 geologic substrates that represent a wide range of textures, such as rippled and immobile sand, immobile muddy sand and sandy mud, sand that partially veneers gravel, and a boulder ridge. Mapped substrates are characterized by sediment grain-size composition, surface morphology, substrate layering, the mobility or immobility of substrate surfaces, and water depth range. This scientific investigations map portrays the major geological elements (substrates, topographic features, and processes) of environments in quadrangle 2. It is intended to provide a foundation for research into present and past sediment transport processes in a complex terrain, provide insights into the ecological requirements of invertebrate and vertebrate species that utilize the various substrates, and support seabed management in the region.

Massachusetts

Design and function of the Autonomous Benthic Imaging and Surveying System (ABISS) for remote sensing of lake and seabed environments

Lake and seabed environments are home to fisheries and other biota that are important to ecosystems and economies, yet these environments and the species that use them are difficult to accurately assess and monitor. Traditional benthic survey techniques, like bottom trawling used by the U.S. Geological Survey, are limited by substrate constraints, poor spatial resolution and precision, and operational depth limits, hindering accurate assessment of benthic species and habitats. In response to these limitations, the U.S. Geological Survey developed the Autonomous Benthic Imaging and Surveying System, a camera system integrated into underwater vehicles, to capture high-resolution images of the lakebed. The system uses color and stereo cameras to collect imagery, which can be analyzed using computational methods to detect organisms and (or) characterize habitat features, such as geologic substrate types. The system has been integrated into autonomous underwater vehicles and into an underwater housing used by self-contained underwater breathing apparatus (SCUBA) divers. Although the engineering of the system was motivated by the need for data collection in the Great Lakes, it has potential to collect high quality data in any aqueous setting with sufficient water clarity and safe operating conditions. The Autonomous Benthic Imaging and Surveying System can operate across diverse depths and light conditions to map and quantify ecological patterns that were difficult or impossible to assess using traditional methods. The Autonomous Benthic Imaging and Surveying System offers the potential for accurate and precise monitoring and assessment of native benthic biota, invasive species, and habitat, potentially providing natural resource managers with improved information to support decision making about benthic resource management.

Great Lakes

Seabed maps showing topography, ruggedness, backscatter intensity, sediment mobility, and the distribution of geologic substrates in quadrangle 5 of the Stellwagen Bank National Marine Sanctuary region offshore of Boston, Massachusetts

The U.S. Geological Survey, in cooperation with the National Marine Sanctuary Program of the National Oceanic and Atmospheric Administration, has conducted seabed mapping and related research in the Stellwagen Bank National Marine Sanctuary (SBNMS) region since 1993. The area being mapped using geophysical and geological data includes the SBNMS and the surrounding region, which totals approximately 3,700 square kilometers (km 2 ) and is subdivided into 18 quadrangles. The seabed is a glaciated terrain that is topographically and texturally diverse. Quadrangle 5, the subject of this scientific investigations map, has an area of 211 km 2 and has water depths that range from 23 meters (m) on the Stellwagen Bank crest to 105 m in the Stellwagen Basin. Seven map types, each at a scale of 1:25,000, depict seabed topography, ruggedness, backscatter intensity, distribution of geologic substrates, sediment mobility, distribution of fine- and coarse-grained sand, and substrate mud content. These maps show the distribution of geologic substrates on the crest and western flank of the south-central part of Stellwagen Bank and in Stellwagen Basin to the west. Interpretations of multibeam sonar bathymetric and seabed backscatter imagery, photographs, video imagery, and grain-size analyses were used to create the geology-based maps. Data from 729 stations were analyzed, including 620 sediment samples. The geologic substrate maps of quadrangle 5 show the distribution of 20 substrates that represent a wide range of textures, such as mobile and rippled sand, immobile sand, sand that partially veneers gravel, boulder ridges, and mud. Mapped substrates are characterized by sediment grain-size composition, surface morphology, substrate layering, the mobility or immobility of substrate surfaces, and water depth range. This scientific investigations map portrays the major geological elements (substrates, topographic features, and processes) of environments in quadrangle 5. It is intended to provide a foundation for research into present and past sediment transport processes in a complex terrain, provide insights into the ecological requirements of invertebrate and vertebrate species that utilize the various substrates, and to support seabed management in the region.

Massachusetts