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At least 865 records · Page 48Linked to original sources
USGS1995

Ground-water use by public-supply systems in Tennessee, 1990

Ground-water use by public water-supply systems during 1990 was inventoried in Tennessee. Ground- water withdrawals were estimated to average 269 million gallons per day (Mgal/d), or 38 percent of the total public-supply water use. This volume represents an increase of 34 percent in the use of ground water for public supply since 1980 when public-supply withdrawals were 200 Mgal/d. About 212 Mgal/d (79 percent) were withdrawn from the Tertiary sand and Cretaceous sand aquifers in western Tennessee. The largest ground-water with- drawals for public-supply occurred in Shelby County (154 Mgal/d or 57 percent of the total withdrawals for public supply). Thirty-four of the 267 principal public water-supply systems withdrew 1 Mgal/d or more and accounted for 83 percent of ground water withdrawn for public supply.

Tennessee↗
USGS1978

Development of a relation for steady-state pumping rate for Eagle Valley ground-water basin, Nevada

Eagle Valley is a topographic and ground-water basin in the west-central area of Nevada. The demand for water in the valley is approaching the limits of the locally available resource, which is the water yield of 9,000 acre-feet per year from the adjacent mountain areas. The steady-state pumping rate from the ground-water basin is defined as the rate that just balances ground-water recharge and discharge. The recharge of water after agricultural or municipal use is a contribution toward overall ground-water recharge and, therefore, to the steady-state pumping rate. However, because the recharge factors are different for municipal and agricultural use, the total quantity of ground-water recharge from the beneficial use of water depends on the type of water use. Consequently, the steady-state pumping rate depends on the type of water use.

Nevada↗
USGS2005

Variability of differences between two approaches for determining ground-water discharge and pumpage, including effects of time trends, Lower Arkansas River Basin, southeastern Colorado, 1998-2002

In the mid-1990s, the Colorado Division of Water Resources (CDWR) adopted rules governing measurement of tributary ground-water pumpage for the Arkansas River Basin. The rules allowed ground-water pumpage to be determined using one of two approaches?power conversion coefficient (PCC) or totalizing flowmeters (TFM). In addition, the rules allowed a PCC to be applied to the electrical power usage up to 4 years in the future to estimate ground-water pumpage. As a result of concerns about potential errors in applying the PCC approach forward in time, a study was done by the U.S. Geological Survey, in cooperation with CDWR and Colorado Water Conservation Board, to evaluate the variability in differences in pumpage between the two approaches, including the effects of time trends. This report compared measured ground-water pumpage using TFMs to computed ground-water pumpage using PCCs by developing statistical models of relations between explanatory variables, such as site, time, and pumping water level, and dependent variables, which are based on discharge, PCC, and pumpage. When differences in pumpage (diffP) were computed using PCC measurements and power consumption for the same year (1998-2002), the median diffP, depending on the year, ranged from +0.1 to -2.9 percent; the median diffP for the entire period was -1.5 percent. However, when diffP was computed using PCC measurements applied to the next year's power consumption, the median diffP was -0.3 percent; and when PCC measurements were applied 2, 3, or 4 years into the future, median diffPs were +1.8 percent for a 2-year forward lag and +5.3 percent for a 4-year forward lag, indicating that pumpage computed with the PCC approach, as generally applied under the ground-water pumpage measurement rules by CDWR, tended to overestimate pumpage as compared to pumpage using TFMs when PCC measurement was applied to future years of measured power consumption. Analyses were done to better understand the causes of the time trend; an estimate of the overall trend with time (uncorrected for pumping water-level changes) yielded a trend of about 2.2 percent per lag year for diffP. A separate analysis that incorporated a surface-water diversion term in the statistical model rendered the time-trend term insignificant, indicating that the time trend in the models served as a surrogate for other variables, some of which reflect underlying hydrologic conditions. A more precise explanation of the potential causes of the time trend was not obtained with the available data. However, the model results with the surface-water diversion term indicate that much of the trend of 2.2 percent per lag year in diffP resulted from applying a PCC to estimate pumpage under hydrologic conditions different from those under which the PCC was measured. Although there is no evidence to conclude that the upward time trend determined in the data for this 5-year period would hold in the future, historical static ground-water levels in the study area generally have exhibited small variations over multidecadal time scales. Therefore, the approximately 2 percent per lag year trend determined in these data is expected to be a reasonable guideline for estimating potential errors in the PCC approach resulting from temporally varying hydrologic conditions between time of PCC measurement and pumpage estimation. Comparisons also were made between total, or aggregated, pumpage for a network of wells as computed by the PCC approach and the TFM approach. For 100 wells and a lag of 4 years between PCC measurement and pumpage estimation, there was a 95-percent probability that the difference between total network pumpage measured by the PCC approach and that measured using a TFM would be between 5.2 and 14.4 percent. These estimates were based on a bias of 2.2 percent per lag year estimated for the period 1998-2002 during which hydrologic conditions were known to have changed. Using the same assumptions, the estimated d

Scientific Investigations Report↗
USGS2005

Geochemistry and the understanding of ground-water systems

Geochemistry has contributed significantly to the understanding of ground-water systems over the last 50 years. Historic advances include development of the hydrochemical facies concept, application of equilibrium theory, investigation of redox processes, and radiocarbon dating. Other hydrochemical concepts, tools, and techniques have helped elucidate mechanisms of flow and transport in ground-water systems, and have helped unlock an archive of paleoenvironmental information. Hydrochemical and isotopic information can be used to interpret the origin and mode of ground-water recharge, refine estimates of time scales of recharge and ground-water flow, decipher reactive processes, provide paleohydrological information, and calibrate ground-water flow models. Progress needs to be made in obtaining representative samples. Improvements are needed in the interpretation of the information obtained, and in the construction and interpretation of numerical models utilizing hydrochemical data. The best approach will ensure an optimized iterative process between field data collection and analysis, interpretation, and the application of forward, inverse, and statistical modeling tools. Advances are anticipated from microbiological investigations, the characterization of natural organics, isotopic fingerprinting, applications of dissolved gas measurements, and the fields of reaction kinetics and coupled processes. A thermodynamic perspective is offered that could facilitate the comparison and understanding of the multiple physical, chemical, and biological processes affecting ground-water systems.

Hydrogeology Journal↗
USGS2008

Science to Help Understand and Manage Important Ground-Water Resources

Throughout California, as pressure on water resources continues to grow, water-supply agencies are looking to the state?s biggest ?reservoir? ? its ground-water basins ? for supply and storage. To better utilize that resource, the Sweetwater Authority and other local partners, including the city of San Diego and Otay Water Districts, are working with the U.S. Geological Survey (USGS) to develop the first comprehensive study of the coastal ground-water resources of southern San Diego County. USGS research is providing the integrated geologic and hydrologic knowledge necessary to help effectively utilize this resource on a coordinated, regional basis. USGS scientists are building a real-time well-monitoring network and gathering information about how the aquifers respond to different pumping and recharge-management strategies. Real-time ground-water levels are recorded every hour and are viewable on a project web site (http://ca.water.usgs.gov/sandiego/index.html). Data from the wells are helping to define the geology and hydrogeology of the area, define ground-water quality, and assess ground-water levels. The wells also are strategi-cally placed and designed to be usable by the local agencies for decades to come to help manage surface-water and ground-water operations. Additionally, the knowledge gained from the USGS study will help local, state, and federal agencies; water purveyors; and USGS scientists to understand the effects of urbanization on the local surface-water, ground-water, and biological resources, and to better critique ideas and opportuni-ties for additional ground-water development in the San Diego area.

Fact Sheet↗
USGS2007

Hydrogeologic Setting and Ground-Water Flow in the Leetown Area, West Virginia

The Leetown Science Center is a research facility operated by the U.S. Geological Survey that occupies approximately 455-acres near Kearneysville, Jefferson County, West Virginia. Aquatic and fish research conducted at the Center requires adequate supplies of high-quality, cold ground water. Three large springs and three production wells currently (in 2006) supply water to the Center. The recent construction of a second research facility (National Center for Cool and Cold Water Aquaculture) operated by the U.S. Department of Agriculture and co-located on Center property has placed additional demands on available water resources in the area. A three-dimensional steady-state finite-difference ground-water flow model was developed to simulate ground-water flow in the Leetown area and was used to assess the availability of ground water to sustain current and anticipated future demands. The model also was developed to test a conceptual model of ground-water flow in the complex karst aquifer system in the Leetown area. Due to the complexity of the karst aquifer system, a multidisciplinary research study was required to define the hydrogeologic setting. Geologic mapping, surface- and borehole-geophysical surveys, stream base-flow surveys, and aquifer tests were conducted to provide the hydrogeologic data necessary to develop and calibrate the model. It would not have been possible to develop a numerical model of the study area without the intensive data collection and methods developments components of the larger, more comprehensive hydrogeologic investigation. Results of geologic mapping and surface-geophysical surveys verified the presence of several prominent thrust faults and identified additional faults and other complex geologic structures (including overturned anticlines and synclines) in the area. These geologic structures are known to control ground-water flow in the region. Results of this study indicate that cross-strike faults and fracture zones are major avenues of ground-water flow. Prior to this investigation, the conceptual model of ground-water flow for the region focused primarily on bedding planes and strike-parallel faults and joints as controls on ground-water flow but did not recognize the importance of cross-strike faults and fracture zones that allow ground water to flow downgradient across or through less permeable geologic formations. Results of the ground-water flow simulation indicate that current operations at the Center do not substantially affect either streamflow (less than a 5-percent reduction in annual streamflow) or ground-water levels in the Leetown area under normal climatic conditions but potentially could have greater effects on streamflow during long-term drought (reduction in streamflow of approximately 14 percent). On the basis of simulation results, ground-water withdrawals based on the anticipated need for an additional 150 to 200 gal/min (gallons per minute) of water at the Center also would not seriously affect streamflow (less than 8 to 9 percent reduction in streamflow) or ground-water levels in the area during normal climatic conditions. During drought conditions, however, the effects of current ground-water withdrawals and anticipated additional withdrawals of 150 to 200 gal/min to augment existing supplies result in moderate to substantial declines in water levels of 0.5-1.2 feet (ft) in the vicinity of the Center's springs and production wells. Streamflow was predicted to be reduced locally by approximately 21 percent. Such withdrawals during a drought or prolonged period of below normal ground-water levels would result in substantial declines in the flow of the Center's springs and likely would not be sustainable for more than a few months. The drought simulated in this model was roughly equivalent to the more than 1-year drought that affected the region from November 1998 through February 2000. The potential reduction in streamflow is a result of capture of ground water tha

Scientific Investigations Report↗
USGS1997

Ground-water resources of the Cahaba River basin in Alabama - Subarea 7 of the Apalachicola-Chattahoochee-Flint and Alabama-Coosa-Tallapoosa river basins

Drought conditions in the 1980's focused attention on the multiple uses of the surface- and ground-water resources in the Apalachicola-Chattahooochee-Flint and Alabama-Coosa-Tallapoosa River basins in Georgia, Alabama, and Florida. State and Federal agencies also have proposed projects that would require additional water resources and revise operating practices within the river basins. The existing and proposed water projects create conflicting demands for water by the States and emphasize the problem of water-resource allocation. This study was initiated to describe ground-water availablity in the Cahaba River basin in Alabama, Subarea 7 of the Apalachicola-Chattahoochee-Flint and Alabama-Coosa-Tallapoosa River basins, and to estimate the possible effects of increased ground-water use within the basin. Subarea 7 encompasses about 1,030 square miles in north-central Alabama. Subarea 7 encompasses parts of the Piedmont, Valley and Ridge, and Coastal Plain physiographic provinces. The Piedmont Province is underlain by a two-component aquifer system that is composed of a fractured, crystalline-rock aquifer characterized by little or no primary porosity or permeability; and the overlying regolith, which can behave as a porous-media aquifer. The Valley and Ridge Province is underlain by fracture- and solution-conduit aquifer systems, similar in some ways to those in the Piedmont Province. Fracture-conduit aquifers predominante in the well-consolidated sandstones and shales of Paleozoic age; solution-conduit aquifers dedominate in the carbonate rocks of Paleozoic age. The Coastal Plain is underlain by southward-dipping, poorly consolidated deposits of sand, gravel, and clay of fluvial and marine origin. The conceptual model described for this study qualitatively subdivides the ground-water flow system into local (shallow), intermediate, and regional (deep) flow regimes. Ground- water discharge to tributaries mainly is from local and intermediate flow regimes and varies seasonally. The regional flow regime probably approximates steady-state conditions and discharges chiefly to major drains such as the Cahaba River. Ground-water discharge to major drains originates from all flow regimes. Mean-annual ground-water discharge to streams (baseflow) is considered to approximate the long-term, average recharge to ground water. The mean-annual baseflow was estimated using an atuomated hydrograph-separation method, and represents discharge from the local, intermediate, and regional flow regimes of the ground-water flow system. Mean-annual baseflow in Georgia was estimated to be 763 cubic feet per second at Centreville, Ala., where the Cahaba River exits Subarea 7 into Subarea 8. Mean-annual baseflow represented about 48 percent of total mean-annual stream discharge for the period of record. Stream discharge for selected sites on the Cahaba River and its tributaries were compiled for the years 1941, 1954, and 1986, during which sustained droughts occurred throughout most of the Apalachicola-Chattahoochee-Flint and Alabama-Coosa-Tallapoosa River basin area. Stream discharges were assumed to be sustained entirely by baseflow during the latter periods of these droughts. Estimated baseflow near the end of these droughts averaged about 21 percent of the estimated mean-annual baseflow in Subarea 7 (ranged from about 16 to 25 percent for individual drought years). The potential exists for the development of ground-water resources on a regional scale throughout Subarea 7. Estimated ground-water use in 1990 was about 2 percent of the estimated mean-annual baseflow, and 9.7 percent of the average drought baseflow near the end of the droughts of 1941, 1954, and 1986. Because ground- water use in Subarea 7 represents a relatively minor percentage of ground- water recharge, even a large increase in ground-water use in Subarea 7 is likely to have little effect on ground-water and surface-water occurrernce in Alabama. Indications of long-term ground-water dec

Open-File Report↗
USGS1966

The changing pattern of ground-water development on Long Island, New York

Ground-water development on Long Island has followed a pattern that has reflected changing population trends, attendant changes in the use and disposal of water, and the response of the hydrologic system to these changes. The historic pattern of development has ranged from individually owned shallow wells tapping glacial deposits to large-capacity public-supply wells tapping deep artesian aquifers. Sewage disposal has ranged from privately owned cesspools to modern large-capacity sewage-treatment plants discharging more than 70 mgd of water to the sea. At present (1965), different parts of long Island are characterized by different stages of ground-water development. In parts of Suffolk County in eastern long Island, development is similar to the earliest historical stages. Westward toward New York City, ground-water development becomes more intensive and complex, and the attendant problems become more acute. The alleviation of present problems and those that arise in the future will require management decisions based on the soundest possible knowledge of the hydrologic system, including an understanding of the factors involved in the changing pattern of ground-water development on the island.

Circular↗
USGS1963

Ground-water contamination and legal controls in Michigan

The great importance of the fresh ground-water resources of Michigan is evident because 90 percent of the rural and about 70 percent of the total population of the State exclusive of the Detroit metropolitan area are supplied from underground sources. The water-supply and public-health problems that have been caused by some cases of ground-water contamination in the State illustrate the necessity of protecting this vital resource. Manmade and natural contaminants, including many types of chemical and organic matter, have entered many of the numerous aquifers of the State. Aquifers have been contaminated by waste-laden liquids percolating from the surface or from the zone of aeration and by direct injection to the aquifer itself. Industrial and domestic wastes, septic tanks, leaking sewers, flood waters or other poor quality surface waters, mine waters, solids stored or spread at the surface, and even airborne wastes all have been sources of ground-water contamination in Michigan. In addition, naturally occurring saline waters have been induced into other aquifers by overpumping or unrestricted flow from artesian wells, possibly by dewatering operations, and by the deepening of surface stream channels. Vertical migration of saline waters through open holes from formations underlying various important aquifers also has spoiled some of the fresh ground waters in the State. In spite of the contamination that has occurred, however, the total amount of ground water that has been spoiled is only a small part of the total resource. Neither is the contamination so widespread as that of the surface streams of Michigan. Overall legal authority to control most types of ground-water contamination in the State has been assigned by the Michigan Legislature to the Water Resources Commission, although the Department of Conservation and the Health Department also exercise important water-pollution control functions. The Michigan Supreme Court, in an important case upholding the power of the Water Resources Commission to control pollution of ground water, in effect has introduced the doctrine of reasonable use into the law of the State. Excluding controls administered by the Department of Conservation on activities of the oil and gas industry, however, legal controls have not been used abate intrusion of natural saline waters into fresh-water aquifers in response to pumping and other manmade changes in the hydrologic regimen.

Michigan↗
USGS1981

Effects of irrigation pumping on the ground-water system in Newton and Jasper Counties, Indiana

Flow in the ground-water system in Newton and Jasper Counties, Indiana, was simulated in a quasi-three-dimensional model in a study of irrigation use of ground water in the two counties. The ground-water system consists of three aquifers: (1) a surficial coarse sand aquifer known as the Kankakee aquifer, (2) a limestone and dolomite bedrock aquifer, and (3) a sand and gravel bedrock valley aquifer. Irrigation pumping, derived primarily from the bedrock, was estimated to be 34.8 million gallons per day during peak irrigation in 1977. Acreage irrigated with ground water is estimated to be 6,200 acres. A series of model experiments was used to estimate the effects of irrigation pumping on ground-water levels and streamflow. Model analysis indicates that a major factor controlling drawdown due to pumping in the bedrock aquifer are the variations in thickness and in vertical hydraulic conductivity in a semiconfining unit overlying the bedrock. Streamflow was not significantly reduced by hypothetical withdrawals of 12.6 million gallons per day from the bedrock aquifer and 10.3 million gallons per day in the Kankakee aquifer. Simulation of water-level recovery after irrigation pumping indicated that a 5-year period of alternating between increasing pumping and recovery will not cause serious problems of residual drawdown or ground-water mining.

Indiana↗
USGS2009

Evaluation of the effects of precipitation on ground-water levels from wells in selected alluvial aquifers in Utah and Arizona, 1936-2005

Increased withdrawals from alluvial aquifers of the southwestern United States during the last half-century have intensified the effects of drought on ground-water levels in valleys where withdrawal for irrigation is greatest. Furthermore, during wet periods, reduced withdrawals coupled with increased natural recharge cause rising ground-water levels. In order to manage water resources more effectively, analysis of ground-water levels under the influence of natural and anthropogenic stresses is useful. This report evaluates the effects of precipitation patterns on ground-water levels in areas of Utah and Arizona that have experienced different amounts of ground-water withdrawal. This includes a comparison of water-level records from basins that are hydrogeologically and climatologically similar but have contrasting levels of ground-water development. Hydrologic data, including records of ground-water levels, basin-wide annual ground-water withdrawals, and precipitation were examined from two basins in Utah (Milford and central Sevier) and three in Arizona (Aravaipa Canyon, Willcox, and Douglas). Most water-level records examined in this study from basins experiencing substantial ground-water development (Milford, Douglas, and Willcox) showed strong trends of declining water levels. Other water-level records, generally from the less-developed basins (central Sevier and Aravaipa Canyon) exhibited trends of increasing water levels. These trends are likely the result of accumulating infiltration of unconsumed irrigation water. Water-level records that had significant trends were detrended by subtraction of a low-order polynomial in an attempt to eliminate the variation in the water-level records that resulted from ground-water withdrawal or the application of water for irrigation. After detrending, water-level residuals were correlated with 2- to 10-year moving averages of annual precipitation from representative stations for the individual basins. The water-level residual time series for each well was matched with the 2- to 10-year moving average of annual precipitation with which it was best correlated and the results were compared across basins and hydrologic settings. Analysis of water-level residuals and moving averages of annual precipitation indicate that ground-water levels in the Utah basins respond more slowly to precipitation patterns than those from the Arizona basins. This is attributed to the dominant mechanism of recharge that most directly influences the respective valley aquifers. Substantial recharge in the Utah basins likely originates as infiltrating snowmelt in the mountain block far from the valley aquifer, whereas mountain-front recharge and streambed infiltration of runoff are the dominant recharge mechanisms operating in the Arizona basins. It was determined that the fraction of water-level variation caused by local precipitation patterns becomes more difficult to resolve with increasing effects of ground-water pumping, especially from incomplete records. As the demand for ground water increases in the southwestern United States, long-term records of ground-water levels have the potential to provide valuable information about the precipitation-driven variation in water levels, which has implications to water management related to water availability.

Arizona, Utah↗
USGS1964

Geology and ground-water resources of southeastern New Hampshire

The continued growth and development of southeastern New Hampshire, an area of about 390 square miles adjacent to the Atlantic Ocean, will depend partly on effectively satisfying the demand for water, which has increased rapidly since World War II. The report identifies and describes the principal geologic units with respect to the occurrence of ground water. These units include bedrock and the various unconsolidated deposits that mantle the bedrock surface discontinuously throughout the area. The bedrock formations, consisting of igneous and metamorphic rocks, chiefly of Paleozoic age, form a single water-bearing unit. Ground water is in joints and fractures. The fractures are small and scattered and therefore impart only a low permeability to the rocks. Wells in the bedrock commonly produce small but reliable supplies of ground water at depths of less than 150 feet. The yields of about 80 wells inventoried for this report ranged from 1? to 100 gpm (gallons per minute) and the median was 912 gpm. Depths ranged from 45 to 600 feet. The unconsolidated deposits consist of glacial drift of Pleistocene age; swamp deposits, alluvium, and beach deposits of Recent age; and eolian deposits of Pleistocene -and Recent age. For this report the glacial drift is divided into till, ice-contact deposits, marine deposits, and outwash and shore deposits. Glacial till forms a discontinuous blanket, commonly less than 15 but in some hills (drumlins) as much as about 200 feet thick. It has a low permeability but, because of its widespread outcrop area, it has been utilized as a source of water for numerous domestic supplies. Because most wells in till are shallow, many fail to meet modern demands during dry summers. Ice-contact deposits locally form kames, kame terraces, kame plains, and ice-channel fillings throughout the area. They overlie bedrock and till and range in thickness from less than 1 foot to as much as 190 feet. In general, the ice-contact deposits are coarse textured and permeable, but variations in- the physical and hydrologic properties of a single deposit and from deposit to deposit are common. Ice-contact deposits are the source of the larger ground-water supplies in southeastern New Hampshire. Marine deposits underlie lowlands and valleys to a distance of about 20 miles inland from the present coastline. They commonly overlie bedrock and till and at places overlie or are interbedded with ice-contact deposits. Marine deposits range in thickness from less than 1 foot to possibly 75 feet. They are fine textured and impermeable; they do not yield water to wells in southeastern New Hampshire but generally act as a barrier to ground-water movement. Outwash and shore deposits form broad sand plains or gently sloping terraces of small extent. At most places the outwash and shore deposits, which range in thickness from less than 1 foot to about 50 feet, overlie marine deposits, but at some places they overlie bedrock, till, or ice-contact deposits. The outwash and shore deposits are fine textured and moderately permeable. They commonly yield enough ground water to meet the needs of farms, homes, and small industries. Alluvium underlies the flood plains and channels of the principal streams and overlies bedrock and older unconsolidated deposits wherever streams cross the older units. The alluvium generally is not tapped by wells. Beach deposits occupy areas along the Atlantic Ocean between promontories of bedrock or till. In general beach deposits are permeable and are a source of water supplies for domestic use. Yields of wells are limited, however, by the danger of drawing in salty water. Recharge in southeastern New Hampshire is derived principally from precipitation on outcrop areas of ice-contact deposits and outwash and shore deposits during the nongrowing season. Ground water is discharged naturally by springs, by effluent seepage to streams and other bodies of surface water, and by evapotranspiration. It

Water Supply Paper↗
USGS1999

Use of environmental tracers to evaluate ground-water age and water-quality trends in a buried-valley aquifer, Dayton area, southwestern Ohio

Chlorofluorocarbons (CFC method) and tritium and helium isotopes (3H-3He method) were used as environmental tracers to estimate ground-water age in conjunction with efforts to develop a regional ground-water flow model of the buried-valley aquifer in the Dayton area, southwestern Ohio. This report describes results of CFC and water-quality sampling, summarizes relevant aspects of previously published work, and describes the use of 3H-3He ages to characterize temporal trends in ground-water quality of the buried-valley aquifer near Dayton, Ohio. Results of CFC sampling indicate that approximately 25 percent of the 137 sampled wells were contaminated with excess CFC's that rendered the ground water unsuitable for age dating. Evaluation of CFC ages obtained for the remaining samples indicated that the CFC compounds used for dating were being affected by microbial degradation. The degradation occurred under anoxic conditions that are found in most parts of the buried-valley aquifer. As a result, ground-water ages derived by the CFC method were too old and were inconsistent with measured tritium concentrations and independently derived 3H-3He ages. Limited data indicate that dissolved methane may play an important role in the degradation of the CFC's. In contrast, the 3H-3He technique was found to yield ground-water ages that were chemically and hydrologically reasonable. Ground-water ages derived by the 3H-3He technique were compared to values for selected water- quality characteristics to evaluate temporal trends in ground-water quality in the buried- valley aquifer. Distinct temporal trends were not identified for pH, alkalinity, or calcium and magnesium because of rapid equilibration of ground-water with calcite and dolomite in aquifer sediments. Temporal trends in which the amount of scatter and the number of outlier concentrations increased as ground-water age decreased were noted for sodium, potassium, boron, bromide, chloride, ammonia, nitrate, phosphate, sulfate, and organic carbon. Elevated concentrations of these constituents in shallow ground water are probably related to human activities. Temporal trends in which concentrations declined as ground-water age increased may reflect natural processes that reduce constituent concentrations to low levels. For example, the absence of nitrate detections in ground water recharged before 1980 may indicate natural removal of nitrate by bacterially mediated denitrification. Temporal trends observed for dissolved oxygen, iron, nitrate and silica indicate that these constituents may help identify recently (post-1990) recharged ground water.

Ohio↗
USGS1997

Ground-water resources of the Tallapoosa River basin in Georgia and Alabama - Subarea 5 of the Apalachicola-Chattahoochee-Flint and Alabama-Coosa-Tallapoosa river basins

Drought conditions in the 1980's focused attention on the multiple uses of the surface- and ground-water resources in the Apalachicola-Chattahoochee-Flint (ACT) and Alabama-Coosa-Tallapoosa (ACT) River basins in Georgia, Alabama, and Florida. State and Federal agencies also have proposed projects that would require additional water resources and revise operating practices within the river basins. The existing and proposed water projects create conflicting demands for water by the States and emphasize the problem of water-resource allocation. This study was initiated to describe ground-water availability in the Tallapoosa River basin of Georgia and Alabama, Subarea 5 of the ACF and ACT River basins, and to estimate the possible effects of increased ground-water use within the basin. Subarea 5 encompasses about 4,675 square miles (mi2) in Georgia and Alabama and contains parts of the Piedmont and Coastal Plain physiographic provinces. The Piedmont Province is underlain by a two-component aquifer system that is composed of a fractured, crystalline-rock aquifer and the overlying porous-media regolith aquifer. The Coastal Plain is underlain by a porous-media aquifer formed from the poorly consolidated deposits of sand, gravel, and clay. The conceptual model described for this study qualitatively subdivides the ground-water flow system into local (shallow), intermediate, and regional (deep) flow regimes. Ground-water discharge to tributaries mainly is from local and intermediate flow regimes and varies seasonally. The regional flow regime probably approximates steady-state conditions and discharges chiefly to major drains such as the Tallapoosa River, and in upstream areas, also to the Little Tallapoosa River and the Tallapoosa River. Ground-water discharge to major drains originates from all flow regimes. Mean-annual ground-water discharge to steams (baseflow) is considered to approximate the long-term, average recharge to ground water. The mean-annual baseflow was estimated using an automated hydrograph- separation method, and represents discharge from the local, intermediate, and regional flow regimes of the ground- water flow system. Mean-annual baseflow in Georgia was estimated to be 534 cubic feet per second (from the headwaters to the Georgia-Alabama State line), 3,250 ft3/s in Alabama, and 3,780 ft3/s for all of Subarea 5 (at the Subarea 5-Subarea 8 boundary). Stream discharge for selected sites on the Tallapoosa River and its tributaries were compiled for the years 1941, 1954, and 1986, during which sustained droughts occurred throughout most of the ACF-ACT area. Stream discharges were assumed to be sustained entirely by baseflow during the latter periods of these droughts. Estimated stream discharges near the end of the 1941, 1954, and 1986 drought years were 48, 15, and 85 ft3/s, respectively, at the Georgia-Alabama State line; and 481 , 126, and 448 ft3/s, respectively, at the mouth of the Tallapoosa River. Estimated baseflow near the end of the individual drought years was about 9 percent of the estimated mean-annual baseflow in Subarea 5. The potential exists for the development of ground-water resources on a regional scale throughout Subarea 5. Estimated ground-water use in 1990 was less than 1 percent of the estimated mean-annual baseflow, and about 6 percent of baseflow during the droughts of 1941, 1954, and 1986. Because ground-water use in Subarea 5 represents a relatively minor percentage of ground-water recharge, even a large increase in ground-water use in Subarea 5 in one State is likely to have little effect on ground-water and surface-water occurrence in the other. Indications of long-term ground-water levels declines were not observed; however, the number and distribution of observation wells for which long-term water-level measurements are available in Subarea 5 are insufficient to draw conclusions.

Alabama, Georgia↗
USGS1995

Similar agricultural areas, different ground-water quality, Red River of the North Basin, 1993-95

The U.S. Geological Survey has studied the ground-water quality within two areas of the Red River of the North Basin in southeastern North Dakota and west-central Minnesota. Although both areas are underlain by sandy surficial aquifers over which intensive irrigated agriculture dominates the land use, their ground-water quality differs. Ground water from the eastern study area has significantly higher concentrations of nitrate and agricultural herbicides than does ground water from the western area. Major differences in rainfall and minor differences in soils, depth to ground water, and agricultural practices between these two areas can account for the differences measured in ground-water quality. These same factors may indicate changes in ground-water quality from agricultural land uses in other surficial aquifers in the Red River of the North Basin.

Minnesota, North Dakota, South Dakota↗
USGS2002

Comparison of vapor concentrations of volatile organic compounds with ground-water concentrations of selected contaminants in sediments beneath the Sudbury River, Ashland, Massachusetts, 2000

A mixed plume of contaminants in ground water, including volatile organic compounds (VOCs), semi-volatile organic compounds (SVOCs), and metals, near the former Nyanza property in Ashland, Massachusetts, discharges to the Sudbury River upstream and downstream of Mill Pond and a former mill raceway. Polyethylene-membrane vapor-diffusion (PVD) samplers were installed in river-bottom sediments to determine if PVD samplers provide an alternative to ground-water sampling from well points for identifying areas of detectable concentrations of contaminants in sediment pore water near the ground-water and surface-water interface. In August and September 2000, the PVD samplers were installed near well points at depths of 8 to 12 inches in both fine and coarse sediments, whereas the well points were installed at depths of 1 to 5 feet in coarse sediments only. Comparison between vapor and water samples at 29 locations upstream from Mill Pond show that VOC vapor concentrations from PVD samplers in coarse river-bottom sediments are more likely to correspond to ground-water concentrations from well points than PVD samplers installed in fine sediments. Significant correlations based on Kendall's Tau were shown between vapor and ground-water concentrations for trichloroethylene and chlorobenzene for PVD samplers installed in coarse sediments where the fine organic layer that separated the two sampling depths was 1 foot or less in thickness. VOC concentrations from vapor samples also were compared to VOC, SVOC, and metals concentrations from ground-water samples at 10 well points installed upstream and downstream from Mill Pond, and in the former mill raceway. Chlorobenzene vapor concentrations correlated significantly with ground-water concentrations for 5 VOCs, 2 SVOCs, and 10 metals. Trichloroethylene vapor concentrations did not correlate with any of the other ground-water constituents analyzed at the 10 well points. Chlorobenzene detected by use of PVD samplers appears to be a strong indicator of the presence of VOCs, SVOCs, and metals in ground water sampled from well points at this site. Results from PVD samplers indicate that contaminant concentrations in water from well points installed 1 to 5 ft below fine sediments may not reflect concentrations in pore water less than 1 foot below the river bottom. There is insufficient information available to determine if VOC concentrations detected in PVD samplers are useful for identifying detectable aqueous concentrations of SVOCs and metals in sediment pore water at this site. Samples of pore water from a similar depth as PVD samplers are needed for confirmation of this objective.

Open-File Report↗
USGS2003

Natural remediation potential of arsenic-contaminated ground water

Migration of leachate from a municipal landfill in Saco, Maine has resulted in arsenic concentrations in ground water as high as 647 μg/L . Laboratory experimental data indicate the primary source of arsenic to be reductive dissolution of arsenic-enriched iron oxyhydroxides in the aquifer by organic carbon in landfill leachate. A core from an uncontaminated part of the aquifer yielded no dissolved iron or arsenic when leached with oxic ground water. Eluent ground water spiked with organic carbon in order to create reducing conditions mobilized both ferrous iron and arsenite from this core. The landfill was capped in early 1998 to eliminate the source of leachate. Cores from the contaminated portion of the aquifer were collected and leached with uncontaminated ground water in the laboratory to simulate natural remediation conditions. Data from these experiments show that significant concentrations of labile organic carbon have accumulated on aquifer solids, causing significant biological oxygen demand. In laboratory leaching experiments of the most contaminated core, the organic carbon caused complete consumption of the influent dissolved oxygen (6 mg/L) for 220 pore volumes. Arsenic leaching from contaminated cores rapidly decreased in concentration initially in response to flushing with uncontaminated ground water. Subsequent leaching produced more gradual decreases in dissolved arsenic concentrations, controlled by a combination of reductive dissolution of arsenic-enriched iron oxyhydroxides and adsorption/desorption. In leachate from the most contaminatedcore, arsenic concentrations exceeded the new United States Environmental Protection Agency drinking-water standard of 10 μg/L for more than 200 pore volumes. A geochemical model simulated the concentration of selected constituents as uncontaminated ground water eluted through contaminated aquifer solids. Concentrations of dissolved oxygen, arsenic, and iron, in leachate from one core were used to calibrate the model. This model was validated by successfully simulating constituent concentrations in leachate from cores collected from other contaminated areas of this aquifer.

Saco↗
USGS1992

Ground water chemistry and geochemical modeling of water-rock interactions at the Osamu Utsumi mine and the Morro do Ferro analogue study sites, Poços de Caldas, Minas Gerais, Brazil

Surface and ground waters, collected over a period of three years from the Osamu Utsumi uranium mine and the Morro do Ferro thorium/rare-earth element (Th/REE) deposits, were analyzed and interpreted to identify the major hydrogeochemical processes. These results provided information on the current geochemical evolution of ground waters for two study sites within the Poços de Caldas Natural Analogue Project. The ground waters are a K–Fe–SO 4 –F type, a highly unusual composition related to intense weathering of a hydrothermally altered and mineralized complex of phonolites. Tritium and stable isotope data indicate that ground waters are of meteoric origin and are not affected significantly by evaporation or water–rock interactions. Recharging ground waters at both study sites demonstrate water of less than about 35 years in age, whereas deeper, more evolved ground waters are below 1 TU but still contain in most cases detectable tritium. These deeper ground waters may be interpreted as being of 35 to 60 or more years in age, resulting mainly from an admixture of younger with older ground waters and/or indicating the influence of subsurface produced tritium. Geochemical processes involving water–rock–gas interactions have been modeled using ground water compositions, mineralogic data, ion plots and computations of speciation, non-thermodynamic mass balance and thermodynamic mass transfer. The geochemical reaction models can reproduce the water chemistry and mineral occurrences and they were validated by comparing the results of thermodynamic mass transfer calculations (using the PHREEQE program, Parkhurst et al., 1980). The results from the geochemical reaction models reveal that the dominant processes are production of CO 2 in the soil zone through aerobic decay of organic matter, dissolution of fluorite, calcite, K-feldspar, albite, chlorite and manganese oxides, oxidation of pyrite and sphalerite, and precipitation of ferric oxides, silica and kaolinite. Gibbsite precipitation can be modeled for the shallow (recharge) water chemistry at Morro do Ferro, consistent with known mineralogy. Recharge waters are undersaturated with respect to barite and discharging waters and deeper ground waters are saturated to supersaturated with respect to barite demonstrating a strong solubility control. Strontium isotope data demonstrate that sources other than calcium-bearing minerals are required to account for the dissolved strontium in the ground waters. These may include K-feldspar, smectite–chlorite mixed-layer clays and goyazite [SrAl 3 (PO 4 ) 2 (OH) 5 • H 2 O]. 1992.

Journal of Geochemical Exploration↗