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At least 847 records · Page 47Linked to original sources
USGS1963

The atomic ratios of natural ferruginous biotites with reference to 'the stability relations of the ferruginous biotite, annite'

The atomic ratios given by Eugster and Wones (1962) for analyses of high FeO-low MgO micas cited by Foster (1960) are in error. The recalculated atomic ratios herein presented show that only three of the thirteen have low (OH+F), and only one has characteristics that may possibly be due to loss of water during determination. None of the analyses exhibit characteristics suggestive of oxidation of iron and loss of H, as in progression towards oxyannite. The average recalculated octahedral occupancy is 2.69, not 2.91 as in the previous calculation. The differences between atomic ratios calculated on the basis ot determined H 2 O + and F and those calculated on the basis of the theoretical O 10 (OH) 2 content are not great enough to change the essential compositional character of these micas as interpreted by Foster (1960). However, they do affect significantly the calculated octahedral occupancy.

Journal of Petrology↗
USGSDate not supplied

Garnet types from the Cazadero area, California

This is the third in a series of papers on glaucophane schists from the Franciscan Formation near Cazadero, California. Previous papers describe three distinct types of glaucophane-bearing Franciscan metamorphic rocks near Cazadero. The purpose of this study is to investigate the garnets present in metamorphic types III (bedrock schists) and IV (tectonic blocks) as defined by Coleman & Lee (1963). Twenty-four garnet analyses are presented. Sixteen of these are from (aragonite-bearing) type III glaucophane schists, and eight are from type IV glaucophane schists. Type IV rocks include California eclogites. Type III rocks include metabasalt, metachert, metashale, meta-ironstone, and metacarbonate that were formed under high pressure and relatively low temperature. These rocks contain garnets that display a wide range of composition, but the dominant molecules represented are consistently almandine, spessartine, and grossular. Type IV rocks are mainly metabasalts that were probably formed under higher temperatures and pressures than type III rocks. There is a distinct difference between garnets from type III rocks and those from type IV (including eclogites); the lattercontain less spessartine and more pyrope, and the dominant molecules are almandine and grossular. The four analyses of garnets from California eclogites have an average pyrope content of about ten molecular per cent, and they extend the range of composition reported for eclogite garnets. Quantitative spectrographic determinations of minor elements are listed for each of the garnets described. The values determined for some of the minor elements have a wide range and a capricious distribution over a few feet of outcrop area. As a group, both the garnets from type III rocks and those from type IV are pyralspites with large contents (as much as 35 molecular per cent) of ugrandite. This unusual admixture of the pyralspite and ugrandite garnet series may have resulted in part from the conditions (high pressures and relatively low temperatures) under which the enclosing rocks were recrystallized.

California↗
USGS2000

Magma mixing, recharge and eruption histories recorded in plagioclase phenocrysts from El Chichón Volcano, Mexico

Consistent core-to-rim decreases of 87 Sr/ 86 Sr ratios and coincident increases in Sr concentrations in plagioclase phenocrysts of varying size (∼1 cm to 2 mm) are reported from samples of the 1982 and pre-1982 (∼200 ka) eruptions of El Chichón Volcano. Maximum 87 Sr/ 86 Sr ratios of ∼0·7054, significantly higher than the whole-rock isotopic ratios (∼0·7040–0·7045), are found in the cores of plagioclase phenocrysts, and minimum 87 Sr/ 86 Sr ratios of ∼0·7039 are found near some of the rims. Plagioclase phenocrysts commonly display abrupt fluctuations in An content (up to 25 mol %) that correspond to well-developed dissolution surfaces. The isotopic, textural and compositional characteristics suggest that these plagioclase phenocrysts grew in a system that was periodically recharged by higher-temperature magma with a lower 87 Sr/ 86 Sr ratio and a higher Sr concentration. Rim 87 Sr/ 86 Sr ratios in plagioclase phenocrysts of rocks from the 200 ka eruption indicate that, at that time, the magma had already attained the lowest recorded 87 Sr/ 86 Sr value of the system (∼0·7039). In contrast, cores from plagioclase phenocrysts of the 1982 eruption, inferred to have grown in the past few thousand years, have the highest recorded 87 Sr/ 86 Sr ratios of the system. Collectively, the Sr isotopic data (for plagioclase and whole rock), disequilibrium textural features of the phenocrysts, known eruption frequencies, and inferred crystal-residence times of the plagioclases are best interpreted in terms of an intermittent magma chamber model. Similar processes, including crustal contamination, magma mixing, periodic recharge by addition of more mafic magma to induce plagioclase disequilibrium (possibly triggering eruption) and subsequent re-equilibration, apparently were operative throughout the 200 ky history of the El Chichón magma system.

Chiapas↗
USGS2002

The Fish Canyon magma body, San Juan volcanic field, Colorado: Rejuvenation and eruption of an upper-crustal batholith

More than 5000 km 3 of nearly compositionally homogeneous crystal-rich dacite (∼68 wt % SiO 2 : ∼45% Pl + Kfs + Qtz + Hbl + Bt + Spn + Mag + Ilm + Ap + Zrn + Po) erupted from the Fish Canyon magma body during three phases: (1) the pre-caldera Pagosa Peak Dacite (an unusual poorly fragmented pyroclastic deposit, ∼200 km 3 ); (2) the syn-collapse Fish Canyon Tuff (one of the largest known ignimbrites, ∼5000 km 3 ); (3) the post-collapse Nutras Creek Dacite (a volumetrically minor lava). The late evolution of the Fish Canyon magma is characterized by rejuvenation of a near-solidus upper-crustal intrusive body (mainly crystal mush) of batholithic dimensions. The necessary thermal input was supplied by a shallow intrusion of more mafic magma represented at the surface by sparse andesitic enclaves in late-erupted Fish Canyon Tuff and by the post-caldera Huerto Andesite. The solidified margins of this intrusion are represented by holocrystalline xenoliths with Fish Canyon mineralogy and mineral chemistry and widely dispersed partially remelted polymineralic aggregates, but dehydration melting was not an important mechanism in the rejuvenation of the Fish Canyon magma. Underlying mafic magma may have evolved H 2 O–F–S–Cl-rich fluids that fluxed melting in the overlying crystal mush. Manifestations of the late up-temperature magma evolution are: (1) resorbed quartz, as well as feldspars displaying a wide spectrum of textures indicative of both resorption and growth, including Rapakivi textures and reverse growth zoning (An 27–28 to An 32–33 ) at the margins of many plagioclase phenocrysts; (2) high Sr, Ba, and Eu contents in the high-SiO 2 rhyolite matrix glass, which are inconsistent with extreme fractional crystallization of feldspar; (3) oscillatory and reverse growth zoning toward the margins of many euhedral hornblende phenocrysts (rimward increases from ∼5·5–6 to 7·7–8·5 wt % Al 2 O 3 ). Homogeneity in magma composition at the chamber-wide scale, contrasting with extreme textural and chemical complexities at the centimeter–millimeter scale, is consistent with a dynamic environment, wherein crystals with a variety of growth and resorption histories were juxtaposed shortly before eruption by convective currents.

Colorado↗
USGS2003

Petrogenesis of mesozoic, peraluminous granites in the Lamoille canyon area, Ruby mountains, Nevada, USA

Two groups of closely associated, peraluminous, two-mica granitic gneiss were identified in the area. The older, sparsely distributed unit is equigranular (EG) with initial ε Nd ∼ − 8·8 and initial 87 Sr/ 86 Sr ∼0·7098. Its age is uncertain. The younger unit is Late Cretaceous (∼80 Ma), pegmatitic, and sillimanite-bearing (KPG), with ε Nd from −15·8 to −17·3 and initial 87 Sr/ 86 Sr from 0·7157 to 0·7198. The concentrations of Fe, Mg, Na, Ca, Sr, V, Zr, Zn and Hf are higher, and K, Rb and Th are lower in the EG. Major- and trace-element models indicate that the KPG was derived by muscovite dehydration melting (<35 km depth) of Neoproterozoic metapelitic rocks that are widespread in the eastern Great Basin. The models are broadly consistent with anatexis of crust tectonically thickened during the Sevier orogeny; no mantle mass or heat contribution was necessary. As such, this unit represents one crustal end-member of regional Late Cretaceous peraluminous granites. The EG was produced by biotite dehydration melting at greater depths, with garnet stable in the residue. The source of the EG was probably Paleoproterozoic metagraywacke. Because EG magmatism probably pre-dated Late Cretaceous crustal thickening, it required heat input from the mantle or from mantle-derived magma.

Nevada↗
USGS1965

Solubility measurements in the system CaSO4-NaCL-H2O at 35°, 50°, and 70°cand one atmosphere pressure

The solubilities in the system CaSO 4 - NaCl -H 2 O, at 1 atm pressure and 35° , 50° , and 70°C, have been determined by approaching the solubility curves from both the undersaturation and supersaturation sides. The experimental runs are of long duration, as much as 3 months; these rates should be commensurate with those of the appropriate geological processes, and so the results should be directly applicable to the interpretation of evaporite deposits.

Journal of Petrology↗
USGS1965

Ages of minerals from metamorphic and igneous rocks near Iron Mountain, Michigan

More than 100 independent isotopic ages have been determined for minerals from an area in northern Michigan about 35 miles square. Granites, pegmatites, and metamorphosed sedimentary and volcanic rocks have yielded Rb-Sr ages for feldspar, muscovite, and biotite, K-Ar ages for hornblende, muscovite, biotite, and feldspar, and U-Pb and Th-Pb ages for zircon. It was anticipated that we would learn from the measurements both the intrusive and metamorphic history of the area and would be able to place limits on the age of the Precambrian sediments in this area. The conclusions may be summarized as follows: (1) Granites and pegmatites with approximate ages of 2,700 and 1,900 m.y. have been found. (2) The major mineral -forming metamorphic event occurred between 1,800 and 2,000 m.y. ago. (3) The Precambrian sedimentary rocks called Animikie are older than 1, 900 m.y. and younger than 2,700 m.y. (4) Biotite Rb-Sr and K-Ar ages and muscovite K-Ar ages were strongly modified by the equivalent of a rise in temperature approximately 1,350 m.y. ago, although no mineral -forming event in this interval has been observed. (5) The K-Ar system was further affected by a thermal rise at about 1,100 m.y. This later event is probably recorded geologically by a few diabase dikes.The resistance to post-formation thermal events shown by the various minerals and decay systems tested may be classified as follows (lowest to highest): feldspar K-Ar, biotite K-Ar, muscovite K-Ar, biotite Rb-Sr, zircon U 238 -Pb 206 , zircon Th-Pb 208 , zircon U 235 -Pb 207 , muscovite Rb-Sr, feldspar Rb-Sr. The few hornblende K-Ar measurements indicate that the resistance of this system is about comparable to that of muscovite and feldspar Rb-Sr. The Pb 207 -Pb 206 age derived from the two U-Pb ages is somewhat more resistant to change than the feldspar Rb-Sr ages .

Michigan↗
USGS1968

Alkali amphiboles from the blueschists of Cazadero, California

Alkali amphiboles from Type III and Type IV metamorphic zones in blueschist facies rocks of Cazadero, California, and from comparable New Caledonian rocks have been characterized by X-ray crystallographic, optical, and chemical methods. The composition of any particular alkali amphibole is strongly controlled by the bulk composition of the host rock. Within the blueschist facies, metamorphic zones are not characterized by changes in amphibole composition. All the alkali amphiboles studied herein belong to the C2/m space group and complete miscibility between glaucophane and riebeckite has been demonstrated for the conditions prevailing during metamorphism in the Cazadero and New Caledonian blueschists. Linear relationships are found between unit-cell dimensions and variations in composition between glaucophane and riebeckite. The alkali amphiboles of glaucophane compositions belong to the high pressure-low temperature series, glaucophane II-riebeckite. Limited miscibility of actinolite in glaucophane may be characteristic of blueschist facies metamorphism.

California↗
USGS1968

Article navigation zonal distribution of variations in structural state of alkali feldspar within the Rader Creek pluton, Boulder Batholith, Montana

The granodioritic Rader Creek pluton of the composite Boulder batholith contains microperthitic alkali feldspar of bulk composition Or 65 to Or 86 with a structurally variable potassic phase. Complete cell parameters, 2V measurements, and bulk composition are given for 11 feldspar samples. The 131 and 131 reflections for these and 58 additional samples show the following structural types in the potassic phase: orthoclase only; orthoclase with subordinate maximum or near-maximum microcline (obliquity = 0.75–1.00); orthoclase with subordinate intermediate microcline (obliquity = 0.64–0.71); and intermediate microcline (obliquity = 0.56–0.77) with subordinate orthoclase. Within the pluton different feldspar structural types occur in zones whose boundaries are approximately parallel to contacts with younger intrusive rocks cutting the Rader Creek pluton but are, in places, nearly perpendicular to zonation within the pluton defined by rock composition. In general, the orthoclase zone is closest to the contact with younger intrusives; the intermediate microcline zone is the most distant. Bulk compositions of alkali feldspar are more potassic in the orthoclase zone than elsewhere. The data suggest a complex history for the alkali feldspar, involving at least two stages: 1. Exsolution and partial inversion of orthoclase to intermediate microcline during cooling of the Rader Creek pluton; 2. Transformation of the intermediate-microcline assemblage to orthoclase during reheating of the pluton at the time of intrusion of younger plutons of the batholith. The transitional stage in this transformation is characterized by orthoclase co-existing with subordinate microcline, whose obliquity usually approaches that of maximum microcline.

Montana↗
USGS1968

Hornblendes from granitic rocks of the central Sierra Nevada batholith, California

Twenty samples of hornblendes from rocks of 14 plutonic units in the central Sierra Nevada and Inyo Mountains, California, have been studied in detail. Optical, density, single-crystal and powder X-ray diffraction, and major and minor element chemical data are reported.The compositions of the hornblendes show only limited correlation with the chemistry of the rocks in which they occurred. Hornblendes from granitic rocks of the eastern Sierra Nevada and Inyo Mountains have a wide range of tetrahedral aluminum content which is often as low as three-quarters of an atom per formula unit, whereas hornblendes from younger granitic rocks elsewhere in the Sierra Nevada batholith contain more than one atom of tetrahedral aluminum per formula unit. Because an increase of aluminum in tetrahedral co-ordination is considered indicative of higher temperatures of crystallization, the observed differences in the hornblendes suggest that older plutonic rocks of the batholith may have been metamorphosed regionally or may have been affected by widespread hydrothermal action prior to consolidation of later granitic rocks.

California↗
USGS2022

The geochemical and textural transition between the Reef Package and its hanging wall, Stillwater Complex, Montana, USA

The highest grade Pd-Pt deposit on Earth, the J-M Reef, is hosted in coarse-grained to pegmatoidal cumulates called the Reef Package. Decades of mine development of the J-M Reef have revealed that a distinct discontinuity in rock fabric marks the top of the rock unit that hosts economic-grade sulfide mineralization. Mine geologists refer to this discontinuity as the hanging wall contact. This contact is the top of the Reef Package and is always locatable—either by the change in rock fabric or by distinctive hanging wall textures of silicate minerals—even when the reef sulfide mineralization is absent. This rather subtle textural feature is used reliably by mine geologists to follow the Reef during exploration and mine development. Although some high tenor sulfides (>1000 ppm Pd in 100% sulfide) are found sporadically in the hanging wall cumulates, these accumulations are too small to be economically viable. We present quantitative rock fabric data for four Reef Package and hanging wall intersections collected by electron back-scattered diffraction (EBSD). Plagioclase fabrics in the hanging wall are characterized by low variance in grain sizes and a strong point maximum concentration of (010) and a perpendicular girdle distribution of [100] consistent with an axial B-type fabric. These fabrics are indicative of either compaction of the crystal mush or crystal settling of nucleated crystals, the bulk magma in a chamber. Conversely, the fabrics of the Reef Package show higher variance grain in size distributions and weak to undeveloped preferred orientation of plagioclase crystals that did not undergo significant alignment or textural equilibration of plagioclase grains. The absence of foliation in the Reef Package stands in contrast both to hanging wall fabrics and to other reported EBSD datasets of plagioclase crystals orientations from the Bushveld Complex, the Skaergaard Intrusion, and the Rum Intrusion. Furthermore, plagioclase crystal size distributions for the Reef Package show flatter slopes and convex profiles with fewer crystals at small size fractions indicating the dissolution of small crystals during partial melting and textural coarsening (i.e . Ostwald ripening) and crystal growth. Crystal growth was favored over the nucleation of new crystals during prolonged interaction with a hot infiltrating melt into the resident mush resulting in the coarse-grained textures of the Reef Package cumulates. The hanging wall contact represents a boundary between partially remelted crystal mush of the Reef Package, where sulfide mineralization formed and accumulated, and an overlying essentially barren cumulate pile. The hanging wall cumulates formed following the cessation of footwall erosion and the resumption of crystal accumulation by normal magma chamber processes.

Montana↗
USGS2022

The Shallow Magmatic Plumbing System of the Deccan Traps, Evidence from Plagioclase Megacrysts and Their Host Lavas

We investigate the shallow plumbing system of the Deccan Traps Large Igneous Province using rock and mineral data from Giant Plagioclase Basalt (GPB) lava flows from around the entire province, but with a focus on the Saurashtra Peninsula, the Malwa Plateau, and the base and top of the Western Ghats (WG) lava pile. GPB lavas in the WG typically occur at the transition between chemically distinct basalt formations. Most GPB samples are evolved basalts, with high Fe and Ti contents, and show major and trace elements and Sr-Nd-Pb isotopic compositions generally similar to those of previously studied Deccan basalts. Major element modeling suggests that high-Fe, evolved melts typical of GPB basalts may derive from less evolved Deccan basalts by low-pressure fractional crystallization in a generally dry magmatic plumbing system. The basalts are strongly porphyritic, with 6–25% of mm- to cm-sized plagioclase megacrysts, frequently occurring as crystal clots, plus relatively rare olivine and clinopyroxene. The plagioclase crystals are mostly labradoritic, but some show bytownitic cores (general range of anorthite mol%: 78–55). A common feature is a strong Fe enrichment at the plagioclase rims, indicating interaction with an Fe-rich melt similar to that represented by the matrix compositions (FeOt up to 16–17 wt%). Plagioclase minor and trace elements and Sr isotopic compositions analyzed by laser ablation inductively coupled plasma mass spectrometry show evidence of a hybrid and magma mixing origin. In particular, several plagioclase crystals show variable 87 Sr/ 86 Sr i , which only partially overlaps with the 87 Sr/ 86 Sr i of the surrounding matrix. Diffusion modeling suggests residence times of decades to centuries for most plagioclase megacrysts. Notably, some plagioclase crystal clots show textural evidence of deformation as recorded by electron back-scatter diffraction analyses and chemical maps, which suggest that the plagioclase megacrysts were deformed in a crystal-rich environment in the presence of melt. We interpret the plagioclase megacrysts as remnants of a crystal mush originally formed in the shallow plumbing system of the Deccan basalts. In this environment, plagioclase acquired a zoned composition due to the arrival of chemically distinct basaltic magmas. Prior to eruption, a rapidly rising but dense Fe-rich magma was capable of disrupting the shallow level crystal mush, remobilizing part of it and carrying a cargo of buoyant plagioclase megacrysts. Our findings suggest that basaltic magmas from the Deccan Traps, and possibly from LIPs in general, are produced within complex transcrustal magmatic plumbing systems with widespread crystal mushes developed in the shallow crust.

Journal of Petrology↗
USGS2022

Barometers behaving badly: Assessing the influence of analytical and experimental uncertainty on clinopyroxene thermobarometry calculations at crustal conditions

The composition of clinopyroxene and clinopyroxene-liquid (Cpx-Liq) pairs are frequently used to calculate crystallization/equilibration pressures in igneous systems. While canonical uncertainties are often assigned to calculated pressures based on fits to calibration or test datasets, the sources of these uncertainties (and thus ways to reduce them) have not been rigorously assessed. We show that considerable uncertainties in calculated pressures arise from analytical error associated with Electron Probe Microanalyser (EPMA) measurements of Cpx. Specifically, low X-ray counts during analysis of elements with concentrations <1 wt% resulting from insufficient count times and/or low beam currents yield highly imprecise measurements (1σ errors of 10–40% for Na 2 O).

Journal of Petrology↗
USGS2024

To mix or not to mix: Details of magma storage, recharge, and remobilization during the Pacheco stage at Misti Volcano, Peru (≤21–2 ka)

We investigate ten of the most recent tephra-fall deposits emplaced between ≤21–2 ka from the Pacheco stage of Misti volcano, Peru, to elucidate magma dynamics and explosive eruption triggers related to magma storage, recharge, and remobilization. Whole-rock, glass, and mineral textures and compositions indicate the presence of broadly felsic, intermediate, and mafic magmas in a chemically and thermally stratified magma storage system (Zones 1–3) that interact to differing extents prior to eruption. Intermediate magmas are defined by plagioclase + amphibole + two-pyroxenes + Fe-Ti oxides and phase equilibria indicate they formed at ~300–600 MPa and ~950–1000 °C. Intermediate magmas dominate the Pacheco stage and either erupted alone as hybridized magmas or mingled with minor volumes of cool felsic magmas (~800 °C) in which only plagioclase + Fe-Ti oxides are stable. Felsic magmas do not exclusively comprise any tephra-fall deposit emplaced during the Pacheco stage but were remobilized by recharge and mixing with intermediate magmas in order to erupt. Furthermore, felsic-hosted amphibole cognate to the intermediate magmas are reacted despite the felsic magmas being water saturated, which suggests they are staged above the amphibole stability limit (≤200 MPa). The cryptic presence of mafic magmas is indicated by high-An plagioclase cores (An 74–88 ), rare anhedral olivine (Fo 77–80 ), and possibly high Mg# augite and amphibole (up to Mg# 84 and 77, respectively). The dearth of basalt to basaltic andesite melts recorded in erupted glasses and exclusivity of high-An plagioclase to crystal cores signals mafic magmas are staged deeper in the crust than the intermediate magmas. Periodic interactions between these magmas tracked via glass compositions and crystal exchange reveal an alternation between the production of mingled magmas and their eruption shortly after a recharge event, followed by a period of homogenization and eruption of hybridized magmas. As such, we identify magma recharge as a key mechanism by which half of the explosive eruptions were triggered in the Pacheco stage. A >100 °C increase in Misti’s fumarole temperatures from 1967 to 2018 coincident with changes in fumarolic gas composition is consistent with degassing of a mafic recharge magma, signaling that Misti could produce similar explosive eruptions in the future.

Misti Volcano↗
USGS2024

Crystal resorption as a driver for mush maturation: An experimental investigation

The thermal state of a magma reservoir controls its physical and rheological properties: at storage temperatures close to the liquidus, magmas are dominated by melt and therefore mobile, while at lower temperatures, magmas are stored as a rheologically locked crystal network with interstitial melt (crystal mush). Throughout the lifetime of a magmatic system, temperature fluctuations drive transitions between mush-dominated and melt-dominated conditions. For example, magma underplating or magma recharge into a crystal mush supplies heat, leading to mush disaggregation and an increase in melt fraction via crystal resorption, before subsequent cooling reinstates a crystal mush via crystal accumulation and recrystallisation. Here, we examine the textural effects of such temperature-driven mush reprocessing cycles on the crystal cargo. We conducted high-P-T resorption experiments during which we nucleated, grew, resorbed, and recrystallised plagioclase crystals in a rhyolitic melt, imposing temperature fluctuations typical for plumbing systems in intermediate arc volcanoes (20–40 °C). The experiments reproduce common resorption textures and show that plagioclase dissolution irreversibly reduces 3D crystal aspect ratios, leading to more equant shapes. Comparison of our experimental results with morphologies of resorbed and unresorbed plagioclase crystals from Mount St. Helens (MSH) (USA) reveals a consistent trend in natural rocks: unresorbed plagioclase crystals (found in MSH dacite, basalt and quenched magmatic inclusions [QMIs]) have tabular shapes, while plagioclase crystals with one or more resorption horizons (found in MSH dacite, QMIs, and mush inclusions) show more equant shapes. Plagioclase crystals showing pervasive resorption (found in the dacite and mush inclusions) have even lower aspect ratios. We therefore suggest that crystal mush maturation results in progressively more equant crystal shapes: the shapes of plagioclase crystals in a magma reservoir will become less tabular every time they are remobilised and resorbed. This has implications for magma rheology and, ultimately, eruptibility, as crystal shape controls the maximum packing fraction and permeability of a crystal mush. We hypothesise that a mature mush with more equant crystals due to multiple resorption–recrystallisation events will be more readily remobilised than an immature mush comprising unresorbed, tabular crystals. This implies that volcanic behaviour and pre-eruptive magmatic timescales may vary systematically during thermal maturation of a crustal magmatic system, with large eruptions due to rapid wholesale remobilisation of mushy reservoirs being more likely in thermally mature systems.

Washington↗
USGS2024

Reexamining the Honolulu Volcanics: Hawai‘i's classic case of rejuvenation volcanism

Rejuvenated volcanism is a worldwide phenomenon occurring on many oceanic islands in all of the major ocean basins. This plume-related volcanism follows the main edifice-building stage after a hiatus of variable duration (e.g. 0.6–2 Myrs in Hawai'i). The Honolulu Volcanics (HV), the classic case of rejuvenated volcanism, involved monogenetic eruptions from at least 48 vent areas. Previous studies inferred these vents were aligned along 3 to 11 rifts oriented orthogonal to the propagation direction of the Hawaiian plume. HV basalts are known for having high MgO contents (greater than 10 wt %) and upper mantle xenoliths. Thus, HV magmas are assumed to be relatively primitive and to have ascended rapidly (less than 1 day) through the crust. However, new analyses of olivine cores in basalts from 24 HV vents are mostly too low in forsterite content (74–86 mol %) to be in equilibrium with mantle melts. Olivine and clinopyroxene in HV basalts commonly show reverse zoning indicating magma mixing prior to eruption. These results are inconsistent with the rapid ascent of HV magmas directly from their mantle source. Many of the HV magmas underwent storage (probably in the lower crust or uppermost mantle), crystal fractionation and magma mixing prior to eruption. New 40 Ar/ 39 Ar dates were determined for 11 HV lavas to evaluate their eruptive history. These ages, 80 to 685 ka, combined with our previous and other 40 Ar/ 39 Ar ages for HV lavas reveal long gaps (greater than 50 kyr) between some eruptions. Our comprehensive, whole-rock major and trace element database (63 XRF analyses, 57 ICPMS analyses) of basalts from 37 vents show remarkable compositional diversity with no obvious spatial pattern or temporal trends. The two most recent eruptive sequences have the greatest diversity (basanite and melilitite compositions). HV basanites show systematic trace element trends that may reflect mixing of multiple source components. The nephelinites and melilitites require a complex source history that may have involved residual accessory minerals during mantle melting and a metasomatic component that was not carbonatitic. The new ages and geochemical data show eruptions along most of the previously proposed rift systems were unrelated (except for the Koko Rift). Therefore, geodynamic models that relate HV volcanism to these rift systems are invalid. Lava volumes for two HV eruptions were estimated at 0.11 and 0.23 km 3 using surface mapping and water well data. Similar size, recent monogenetic eruptions in Auckland, New Zealand, were inferred to have lasted several months. Thus, if another HV eruption were to occur, which is possible given the long hiatus between eruptions, it would be extremely disruptive for the nearly 1 million residents of Honolulu. None of the existing geodynamic models fully explain the age duration, volumes and the locations of Hawai'i's rejuvenated volcanism. Thus, the cause of this secondary volcanism remains enigmatic.

Hawaii↗
USGS2024

Insights on arc magmatic systems drawn from natural melt inclusions and crystallization experiments at P H2O =800 MPa under oxidizing conditions

Whole rock compositions at Buldir Volcano, western Aleutian arc, record a strong, continuous trend of iron depletion with decreasing MgO, classically interpreted as a calc-alkaline liquid line of descent. In contrast, olivine-hosted melt inclusions have higher total iron (FeO * ) than whole rocks and show little change in FeO* with decreasing MgO. To investigate this discrepancy and determine the conditions required for strong iron depletion, we conducted oxygen fugacity (ƒO 2 ) buffered, water-saturated crystallization experiments at 800 MPa and ƒO 2 = QFM + 1.6 ± 0.4 (1σ⁠) (where QFM refers to the quartz-fayalite-magnetite buffer) on a high-Al, basaltic starting material modeled after a Buldir lava. Experimental conditions were informed by olivine-hosted melt inclusions that record minimum entrapment pressures as high as 570 MPa, >6 wt % H2O, and ƒO 2 of QFM + 1.4 (±0.2), making Buldir one of the most oxidized and wettest arc volcanoes documented globally. The experiments produce melts with Si-enrichment and Fe-depletion signatures characteristic of evolved, calc-alkaline magmas at the lowest MgO, although FeO * remains roughly constant over most of the experimental temperature range. Experiments saturate CrAl-spinel and olivine at 1160°C, followed by clinopyroxene and Al-spinel at 1085°C, hornblende at 1060°C, and, finally, plagioclase and magnetite between 1040°C and 960°C. Hornblende crystallization, not magnetite, generates the largest increase in SiO2 and largest decrease in FeO * in coexisting melts. Compositions of melt inclusions are consistent with experimental melts and reflect crystallization of a basaltic parent magma at high P H2O . In contrast, the whole rock compositional trends are influenced by magma mixing and phenocryst redistribution and accumulation. The crystallization experiments and natural liquids (melt inclusions and groundmass glass) from Buldir suggest that for an oxidized, hydrous primary basalt starting composition, significant Fe depletion from the melt will not occur until intermediate to late stages of magma crystallization (< ~4.5 wt % MgO). We conclude that the Buldir whole rock trend cannot be reproduced by crystallization at arc-relevant oxygen fugacities and is not a true liquid line of descent, warranting caution when interpreting volcanic trends globally.

Journal of Petrology↗
USGS2024

Awakening of Maunaloa linked to melt shared from Kilauea’s mantle source

Maunaloa—the largest active volcano on Earth—erupted in 2022 after its longest known repose period (~38 years) and two decades of volcanic unrest. This eruptive hiatus at Maunaloa encompasses most of the ~35-year-long Puʻuʻōʻō eruption of neighboring Kīlauea, which ended in 2018 with a collapse of the summit caldera and an unusually voluminous (~1 km 3 ) rift eruption. A long-term pattern of such anticorrelated eruptive behavior suggests that a magmatic connection exists between these volcanoes within the asthenospheric mantle source and melting region, the lithospheric mantle, and/or the volcanic edifice. The exact nature of this connection is enigmatic. In the past, the distinct compositions of lavas from Kīlauea and Maunaloa were thought to require completely separate magma pathways from the mantle source of each volcano to the surface. Here, we use a nearly 200-yr record of lava chemistry from both volcanoes to demonstrate that melt from a shared mantle source within the Hawaiian plume may be transported alternately to Kīlauea or Maunaloa on a timescale of decades. This process led to a correlated temporal variation in 206 Pb/ 204 Pb and 87 Sr/ 86 Sr at these volcanoes since the early 19th century with each becoming more active when it received melt from the shared source. Ratios of highly over moderately incompatible trace elements (e.g., Nb/Y) at Kīlauea reached a minimum from ~2000 to 2010, which coincides with an increase in seismicity and inflation at the summit of Maunaloa. Thereafter, a reversal in Nb/Y at Kīlauea signals a decline in the degree of mantle partial melting at this volcano and suggests that melt from the shared source is now being diverted from Kīlauea to Maunaloa for the first time since the early to mid-20th century. These observations link a mantle-related shift in melt generation and transport at Kīlauea to the awakening of Maunaloa in 2002 and its eruption in 2022. Monitoring of lava chemistry is a potential tool that may be used to forecast the behavior (e.g., eruption rate and frequency) of these adjacent volcanoes on a timescale of decades. A future increase in eruptive activity at Maunaloa is likely if the temporal increase in Nb/Y continues at Kīlauea.

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